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Documentation of the Santa Clara Valley regional ground-water/surface-water flow model, Santa Clara Valley, California

The Santa Clara Valley is a long, narrow trough extending about 35 miles southeast from the southern end of San Francisco Bay where the regional alluvial-aquifer system has been a major source of water. Intensive agricultural and urban development throughout the 20th century and related ground-water development resulted in ground-water-level declines of more than 200 feet and land subsidence of as much as 12.7 feet between the early 1900s and the mid-1960s. Since the 1960s, Santa Clara Valley Water District has imported surface water to meet growing demands and reduce dependence on ground-water supplies. This importation of water has resulted in a sustained recovery of the ground-water flow system. To help support effective management of the ground-water resources, a regional ground-water/surface-water flow model was developed. This model simulates the flow of ground water and surface water, changes in ground-water storage, and related effects such as land subsidence. A numerical ground-water/surface-water flow model of the Santa Clara Valley subbasin of the Santa Clara Valley was developed as part of a cooperative investigation with the Santa Clara Valley Water District. The model better defines the geohydrologic framework of the regional flow system and better delineates the supply and demand components that affect the inflows to and outflows from the regional ground-water flow system. Development of the model includes revisions to the previous ground-water flow model that upgraded the temporal and spatial discretization, added source-specific inflows and outflows, simulated additional flow features such as land subsidence and multi-aquifer wellbore flow, and extended the period of simulation through September 1999. The transient-state model was calibrated to historical surface-water and ground-water data for the period 1970–99 and to historical subsidence for the period 1983–99. The regional ground-water flow system consists of multiple aquifers that are grouped into upper- and lower-aquifer systems. Ground-water inflow occurs as natural recharge in the form of streamflow infiltration and areal infiltration of precipitation along stream channels, artificial recharge from infiltration of imported water at recharge ponds and along selected stream channels, and leakage along selected transmission pipelines. Ground-water outflow occurs as evapotranspiration, stream base flow, discharge through pumpage from wells, and subsurface flow to the San Francisco Bay. The geohydrologic framework of the regional ground-water flow system was represented as six model layers. The hydraulic properties were redefined on the basis of cell-based lithologic properties that were delineated in terms of aggregate thicknesses of coarse-grained, fine-grained, and mixed textural categories. The regional aquifer systems also are dissected by several laterally extensive faults that may form at least partial barriers to the lateral flow of ground water. The spatial extent of the ground-water flow model was extended and refined to cover the entire Santa Clara Valley, including the Evergreen subregion. The temporal discretization was refined and the period of simulation was extended to 1970–99. The model was upgraded to MODFLOW-2000 (MF2K) and was calibrated to fit historical ground-water levels, streamflow, and land subsidence for the period 1970–99. The revised model slightly overestimates measured water levels with an root-mean-square error of -7.34 feet. The streamflow generally shows a good match on gaged creeks and rivers for flows greater than 1.2 cubic feet per second. The revised model also fits the measured deformation at the borehole extensometer site located near San Jose within 16 to 27 percent and the extensometer site near Sunnyvale within 3 percent of the maximum measured seasonal deformation for the deepest extensometers. The total ground-water inflow and outflow of about 225,500 acre-feet per year (acre-ft/yr) for the period 1970–89 and of about 205,300 acre-feet per year for the period for the period 1970–99 is comparable with that of the previous model, 207,200 acre-ft/yr for the period 1970–89. Overall the simulated net change in storage increased by about 189,500 acre-ft/yr for the entire period of simulation, which represents about one and a half years of the 1970–99 average pumping. The changes in ground-water flow and storage generally reflect the major climate cycles and the additional importation of water by Santa Clara Valley Water District, with the basin in recovery since the drought of the late 1980s and early 1990s. The average total recharge rate, from natural and artificial recharge and from streamflow infiltration for the revised model for the entire simulation period 1970–99, was about 157,100 acre-ft/yr, which represents about 59 percent of the inflow to the ground-water flow system. The average rate of artificial recharge of about 77,600 acre-ft/yr represents about 30 percent of the inflow to the ground-water flow system. The average pumpage for the entire 29.75-year simulation period is about 133,400 acre-ft/yr and represents about 69 percent of the outflow from the ground-water flow system. Most of the simulated recharge infiltrates and flows through the uppermost layers (i.e. model layers 1 and 3) of the aquifer system. Most of the water that flows to the deeper model layers is occurring through wellbores, with wellbore flow representing 19 percent of the total ground-water inflow between model layers.

California↗

Ground-water conditions in Utah, spring of 2005

This is the forty-second in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable inter­ested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water with­drawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2004. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources. This report is available online at http://www.waterrights.utah.gov/techinfo/ wwwpub/gw2005.pdf and http://ut.water.usgs.gov/publications/GW2005.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2004

This is the forty-first in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2003. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2003

This is the fortieth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2002. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2002

This is the thirty-ninth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2001. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2001

This is the thirty-eighth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2000. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights and Division of Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 2000

This is the thirty-seventh in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1999. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Rights and Water Resources.

Utah↗

Ground-water conditions in Utah, spring of 1999

This is the thirty-sixth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 1998. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Divisions of Water Rights and Water Resources.

Utah↗

Hydrologic considerations associated with dredging spring ponds in Wisconsin

Spring ponds (small spring-fed bodies of water) are natural features of some glaciated areas and have a continuous flow of ground water entering through their bottoms and exiting through surface outlets. Dredging has been used to restore ponds that have been filled in part or totally by sediment. The purpose of the study was to determine the hydrology of selected spring ponds and the effect that dredging has had on the ponds. Three ponds, Maxwell, Sunshine, and Krause Ponds, in northeastern Wisconsin were studied. Sediments were dredged from Sunshine and Krause Ponds. Maxwell Pond, which was not dredged, was a hydrologic control to aid in distinguishing changes produced by dredging from those that were natural. Ground water from glacial deposits is the source of most of the water flowing in spring ponds and streams in the study area. Average annual ground-water recharge in the study area is about 13 inches. Ground-water discharge contributed 97 percent of the total flow in the Red River, a typical stream in the study area, during the 1973 water year. Ground water and surface water in the study area are of a calcium magnesium bicarbonate type. Dissolved-solids concentration ranges from 170 to 250 milligrams per liter. Temperature of ground water discharging into the spring ponds in the study ranged from 6 to 7 Celsius.

Wisconsin↗

Concentrations and loads of selected trace elements and other constituents in the Rio Grande in the vicinity of Albuquerque, New Mexico, 1994

The Pueblo of Isleta and the New Mexico Environment Department have established water-quality standards for the Rio Grande, which flows through Albuquerque, New Mexico. Trace-element concentrations historically have been greater than maximum permissible concentrations allowed by these standards. It is not known if these concentrations are due to sources from the Albuquerque metropolitan area or are from natural or other sources outside Albuquerque. Accurate water-quality data with lower reporting limits than have been previously available were collected, and instantaneous concentrations and loads were calculated for trace elements and other constituents in the Rio Grande during high-flow and low- flow conditions. Seven sampling sites were selected upstream from, in, and downstream from metropolitan Albuquerque. Concurrent streamflow measurements were made at the time of sampling to determine suspended-sediment loads. Samples were analyzed separately for trace elements dissolved in water (less than 0.4 micrometer in diameter) and for those contained in suspended sediment (greater than 0.1 micrometer in diameter). Sample collection and processing, analytical methods, and quality control are discussed.

New Mexico↗

Lunar analog study using portable gamma-ray neutron detector: Radiochemical mapping of silicic-to-basaltic volcanic terrains in the San Francisco Volcanic Field, Arizona

Studying lunar silicic volcanism provides key insights into the Moon’s crustal evolution, magmatic processes, and volcanic history. The Lunar-VISE (Lunar Vulkan Imaging and Spectroscopy Explorer) mission will investigate the Gruithuisen domes, a unique lunar region hypothesized to have formed through silicic volcanism. Using instruments on a Firefly Aerospace lander and a Honeybee Robotics rover, Lunar-VISE will analyze mineralogy, geochemistry, and surface properties to determine the origin and evolution of the domes, with a gamma-ray and neutron spectrometer (LV-GRNS) among its payload instruments. In preparation for this mission, we conducted preliminary fieldwork using a handheld gamma-ray neutron detector with NaI(Tl) and Cs LiYCl :Ce (CLYC) scintillators. This study focuses on various rhyolitic and basaltic volcanic centers in the San Francisco Volcanic Field (SFVF) near Flagstaff, Arizona—specifically Sugarloaf Peak, Bonito Lava Flow, and Robinson Mountain, a region containing several well-characterized lunar analog sites. The SFVF was selected for this study due to its broad compositional diversity spanning basaltic to rhyolitic compositions, its well-preserved volcanic morphologies, and its extensive use in previous NASA field campaigns and astronaut training exercises, making it an ideal terrestrial laboratory for testing planetary exploration techniques. We measured natural radioactivity, specifically from potassium (K), thorium (Th), and uranium (U) and other elements in their decay chains, which serve as diagnostic tracers of magmatic differentiation and crustal evolution processes, to assess geochemical variability across compositionally diverse terrains. The detector’s sensitivity was assessed across varying concentration levels. Regionally averaged concentrations of radioisotopes were determined by gamma-ray spectroscopy at selected sites. Our measurements reveal significant compositional variations between sites, with Sugarloaf Peak (rhyolitic, silicic dome) exhibiting the highest average radioisotope concentrations (K: 3.29 ± 0.24 wt%, U: 14.35 ± 1.81 ppm, Th: 27.14 ± 2.43 ppm), while Bonito Lava Flow (K: 1.13 ± 0.08 wt%, U: 3.86 ± 0.52 ppm, Th: 7.52 ± 1.02 ppm), and Robinson Mountain (K: 1.46 ± 0.16 wt%, U: 5.59 ± 1.06 ppm, Th: 11.75 ± 1.98 ppm) show lower concentrations aligned with basaltic compositions. Gamma-ray fluxes were elevated by a factor of approximately three to four at Sugarloaf Peak relative to nearby basaltic terrains, consistent with expected geochemical differentiation patterns. Furthermore, at meter scales, proximity to geological features significantly affects measurements. Th concentrations adjacent to a cliff face at Sugarloaf’s base were 28% higher than values measured 3-5 meters away from the same feature, demonstrating localized compositional heterogeneity. Analysis of station-by-station measurements reveals that K, U, and Th concentrations show an elevation trend at Robinson Mountain and generally higher concentrations near Sugarloaf Peak’s summit, suggesting progressive magmatic differentiation and/or the presence of more evolved lithologies at higher elevations. By mapping these elements on Earth using GRNS, we aim to optimize measurement techniques for Lunar-VISE and similar rover-borne missions by demonstrating the applicability of portable GRNS instruments for planetary surface exploration in an analog environment.

Arizona↗

Early detection of invasive plants: principles and practices

Invasive plants infest an estimated 2.6 million acres of the 83 million acres managed by the National Park Service (NPS) in the United States. The consequences of these invasions present a significant challenge for the NPS to manage the agency’s natural resources “unimpaired for the enjoyment of future generations.” More NPS lands are infested daily despite diligent efforts to curtail the problem. Impacts from invasive species have been realized in most parks, resulting in an expressed need to control existing infestations and restore affected ecosystems. There is a growing urgency in the NPS and other resource management organizations to be proactive. The NPS I&M Program, in collaboration with the U.S. Geological Survey (USGS) Status and Trends Program, compiled this document to provide guidance and insight to parks and other natural areas engaged in developing early-detection monitoring protocols for invasive plants. While several rapid response frameworks exist, there is no consistent or comprehensive guidance informing the active detection of nonnative plants early in the invasion process. Early-detection was selected as a primary focus for invasive-species monitoring because, along with rapid response, it is a key strategy for successful management of invasive species. Eradication efforts are most successful on small infestations (that is less than 1 hectare) and become less successful as infestation size increases, to the point that eradication is unlikely for large (that is greater than 1,000 hectares) populations of invasive plants. This document provides guidance for natural resource managers wishing to detect invasive plants early through an active, directed monitoring program. It has a Quick-Start Guide to direct readers to specific chapters and text relevant to their needs. Decision trees and flow charts assist the reader in deciding what methods to choose and when to use them. This document is written in a modular format to accommodate use of individual chapters. It may also be approached in a linear fashion, as a sequence of steps leading to a comprehensive approach to early-detection. Our primary audience comprises resource professionals within the National Park Service (NPS) Inventory and Monitoring (I&M) Program’s networks of parks, but we think that the knowledge and experience captured in this document is more broadly applicable to include other natural areas professionals. We have chosen to emphasize the technical side of invasive species early-detection because this is the arena in which most professionals need more guidance. This approach includes but is not limited to complex techniques that may seem to be just beyond the budgetary and (or) time-bound grasps of some resource professionals. Nonetheless, we have provided low-cost options.

Scientific Investigations Report↗

Ground-water conditions in Utah, spring of 2009

This is the forty-sixth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2008. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights. utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/ GW2009.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2008

This is the forty-fifth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2007. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs.gov/publications/GW2008.pdf .

Utah↗

Ground-water conditions in Utah, spring of 2007

This is the forty-fourth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2006. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/ and http://ut.water.usgs.gov/newUTAH/GW2007.pdf.

Utah↗

Ground-water conditions in Utah, spring of 2006

This is the forty-third in a series of annual reports that describe ground-water conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable inter­ested parties to maintain awareness of changing ground-water conditions. This report, like the others in the series, contains information on well construction, ground-water with­drawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of ground water. Supplementary data are included in reports of this series only for those years or areas which are important to a discussion of changing ground-water conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of ground-water development in the State for calendar year 2005. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Resources and Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is available online at http://www.waterrights.utah. gov/techinfo/wwwpub/gw2006.pdf and http://ut.water.usgs. gov/publications/GW2006.pdf.

Utah↗

Characteristics of water quality and streamflow, Passaic River basin above Little Falls, New Jersey

The findings of a problem-oriented river-system investigation of the water-quality and streamflow characteristics of the Passaic River above Little Falls, N.J. (drainage area 762 sq mi) are described. Information on streamflow duration, time-of-travel measurements, and analyses of chemical, biochemical, and physical water quality are summarized. This information is used to define relations between water quality, streamflow, geology, and environmental development in the basin's hydrologic system. The existence, nature, and magnitude of long-term trends in stream quality--as measured by dissolved solids, chloride, dissolved oxygen, biochemical oxygen demand, ammonia, nitrate, and turbidity--and in streamflow toward either improvement or deterioration are appraised at selected sites within the river system. The quality of streams in the upper Passaic River basin in northeastern New Jersey is shown to be deteriorating with time. For example, biochemical oxygen demand, an indirect measure of organic matter in a stream, is increasing at most stream-quality sampling sites. Similarly, the dissolved-solids content, a measure of inorganic matter, also is increasing. These observations suggest that the Passaic River system is being used more and more as a medium for the disposal of industrial and municipal waste waters. Dissolved oxygen, an essential ingredient for the natural purification of streams receiving waste discharges, is undersaturated (that is, below theoretical solubility levels) at all sampling sites and is decreasing with time at most sites. This is another indication of the general deterioration of stream quality in the upper basin. It also indicates that the ability of the river system to receive, transport, and assimilate wastes, although exceeded now only for short periods during the summer months, may be exceeded more continually in the future if present trends hold. Decreasing ratios of ammonia to nitrate in a downstream direction on the main stem Passaic River suggests that nitrification (the biochemical conversion of ammonia to nitrate) as well as microbiological decomposition of organic matter (waste waters) is contributing to the continued and increasing undersaturation of dissolved oxygen in the river system. Passaic River streams are grouped into five general regions of isochemical quality on the basis of predominant constituents and dissolved-solids content during low flows. The predominant cations in all but one region are calcium and magnesium (exceeding 50 percent of total cations) ; in that region, where man's activities probably have altered the natural stream waters, the percentage of sodium and potassium equals that of calcium and magnesium. In two of the five regions, the predominant anion is bicarbonate; a combination of sulfate, chloride, and nitrate is predominant in the other three regions. Dissolved-solids content during low flows generally ranges from 100 to 600 milligrams per liter. Several time-of-travel measurements within the basin are reported. These data provide reasonable estimates of the time required for soluble contaminants to pass through particular parts of the river system. For example, the peak concentration of a contaminant injected into the river system at Chatham during extreme low flow would be expected to travel to Little Falls, about 31 miles, in about 13 days; but at medium flow, in about 5 days.

Water Supply Paper↗

Quality of water from shallow wells in the rice-growing area in southwestern Louisiana, 1999 through 2001

In 1999-2001, the U.S. Geological Survey installed and sampled 27 shallow wells in the rice-growing area in southwestern Louisiana as part of the Acadian-Pontchartrain Study Unit of the National Water-Quality Assessment Program. The purpose of this report is to describe the waulity of water from shallow wells in the rice-growing area and to relate that water quality to natural and anthropogenic activities, particularly rice agriculture. Ground-water samples were analyzed for general ground-water properties and about 150 water-quality constituents, including major inorganic ions, trace elements, nutrients, dissolved organic carbon (DOC), pesticides, radon, chloroflourocarbons, and selected stable isotopes. Dissolved solids concentrations for 17 wells exceeded the U.S. Environmental Protection Agency secondary minimum containment level of 500 milligrams per liter (mg/L) for drinking water. Concentrations for major pesticides generally were less than the maximum contaminant levels for drinking water. Two major inorganic ions, sulfate and chloride, and two trace elements, iron and manganese, had concentrations that were greater than the secondary maximum containment levels. Three nutrient concentrations were greater than 2 mg/L, a level that might indicate contamination from human activities, and one nutrient concentration (that for nitrite plus nitrite as nitrogen) was greater than the maximum contaminant level of 10 mg/L for drinking water. The median concentration for DOC was 0.5 mg/L, indicating naturally-occurring DOC conditions in the study area. Thirteen pesticides and 7 pesticide degradation products were detected in 14 of the 27 wells sampled. Bentazon, 2, 4-D, and molinate (three rice herbicides) were detected in water from four, one, and one wells, respectively, and malathion (a rice insecticide) was deteced in water fromone well. Low-level concentrations and few detections of nutrients and pesticides indicated that ground-water quality was affected slightly by anthropogenic activities. Quality-control samples, including field blanks, replicates, and spikes, indicated no bias in ground-water data from collection on analysis. Radon concentrations for 22 of the 24 wells sampled wer at or greater than the U.S. Environmental Protection Agency proposed maximum contaminant level of 300 picocuries per liter. Chlorofluorocarbon concentrations in selected wells indicated the apparent ages of the ground water varied with depth water level and ranged from about 17 to 49 years. The stable isotopes of hydrogen and oxygen in water molecules indicated the origin of ground water in the study area was rainwater that originated near the study area and that few geochemical or physical processes influenced the stable isotopic composition of the shallow ground water. The Spearman rank correlation was used to detemrine whther significant correlations existed between physical properties, selected chemical constituents, the number of pesticides detected, and the apparent age of water. The depth to ground water was positively correlated to the well depth and inversely correlated to dissolved solids and other constituents, such as radon, indicating the ground water was under unconfined or semiconfined conditions and more dilute with increasing depth. As the depth to ground water increased, the concentrations of dissolved solids and other constituents decreased, possibly because the deeper sands had a greater transmittal of ground water, which, over time, would flush out, or dilute, the concentrations of dissolved solids in the natural sediments. The apparent age of water was correlated inversely with nitrite plus nitrite concentration, indicating that as apparent age increased, the nitrite plus nitrite concentration decreased. No significant correlations existed between the number of pesticides detected and any of the physical or chemica

Water-Resources Investigations Report↗