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USGS2008

Water-quality monitoring and process understanding in support of environmental policy and management

The quantity and quality of freshwater at any point on the landscape reflect the combined effects of many processes operating along hydrological pathways within a drainage basin/watershed/catchment. Primary drivers for the availability of water are landscape changes and patterns, and the processes affecting the timing, magnitude, and intensity of precipitation, including global climate change. The degradation of air, land, and water in one part of a drainage basin can have negative effects on users downstream; the time and space scales of the effects are determined by the residence time along the various hydrological pathways. Hydrology affects transport, deposition, and recycling of inorganic materials and sediment. These components affect biota and associated ecosystem processes, which rely on sustainable flows throughout a drainage basin. Human activities on all spatial scales affect both water quantity and quality, and some human activities can have a disproportionate effect on an entire drainage basin. Aquatic systems have been continuously modified by agriculture, through land-use change, irrigation and navigation, disposal of urban, mining, and industrial wastes, and engineering modifications to the environment. Interdisciplinary integrated basin studies within the last several decades have provided a more comprehensive understanding of the linkages among air, land, and water resources. This understanding, coupled with environmental monitoring, has evolved a more multidisciplinary integrated approach to resource management, particularly within drainage basins.

Conference Paper↗

USGS1979

Satellites monitor Atlanta regional development

Since the adoption of a Regional Development Plan in 1975, the Atlanta Regional Commission has investigated methods for monitoring regional development patterns in a periodic, efficient manner. A promising approach appears to be the use of Landsat satellite data. In cooperation with the Earth Resources Observation Systems (EROS) Data Center, the commission used machine processing of digital temporal overlays of Landsat data collected in 1972, 1974 and 1976 to detect land use and land cover changes in the Atlanta metropolitan area. Results of the analysis revealed the conversion of forested and open space areas to residential, commercial and industrial land use in the urban-rural fringe zone from 1972 to 1974 and from 1974 to 1976. The study indicated that a land use and land cover change-detection program may be used to revise small-area forecasts of land use, population and employment made by planning models.

Atlanta, Georgia↗

USGS2001

Statistical compilation of NAPAP chemical erosion observations

In the mid 1980s, the National Acid Precipitation Assessment Program (NAPAP), in cooperation with the National Park Service (NPS) and the U.S. Geological Survey (USGS), initiated a Materials Research Program (MRP) that included a series of field and laboratory studies with the broad objective of providing scientific information on acid rain effects on calcareous building stone. Among the several effects investigated, the chemical dissolution of limestone and marble by rainfall was given particular attention because of the pervasive appearance of erosion effects on cultural materials situated outdoors. In order to track the chemical erosion of stone objects in the field and in the laboratory, the Ca 2+ ion concentration was monitored in the runoff solution from a variety of test objects located both outdoors and under more controlled conditions in the laboratory. This report provides a graphical and statistical overview of the Ca 2+ chemistry in the runoff solutions from (1) five urban and rural sites (DC, NY, NJ, NC, and OH) established by the MRP for materials studies over the period 1984 to 1989, (2) subevent study at the New York MRP site, (3) in situ study of limestone and marble monuments at Gettysburg, (4) laboratory experiments on calcite dissolution conducted by Baedecker, (5) laboratory simulations by Schmiermund, and (6) laboratory investigation of the surface reactivity of calcareous stone conducted by Fries and Mossotti. The graphical representations provided a means for identifying erroneous data that can randomly appear in a database when field operations are semi-automated; a purged database suitable for the evaluation of quantitative models of stone erosion is appended to this report. An analysis of the sources of statistical variability in the data revealed that the rate of stone erosion is weakly dependent on the type of calcareous stone, the ambient temperature, and the H + concentration delivered in the incident rain. The analysis also showed that the rate of stone erosion is strongly dependent on the rain-delivery conditions and on the surface morphology and orientation.

Open-File Report↗

USGS2011

Analysis of the deconstruction of Dyke Marsh, George Washington Memorial Parkway, Virginia-Progression, geologic and manmade causes, and effective restoration scenarios

This report is a synthesis of the latest findings from an ongoing study of Dyke Marsh, an eroding freshwater tidal wetland that is scheduled for federal restoration. Its purpose is to provide an accurate and up-to-date temporal and geological framework for the marsh, of which most is new information (plus a compilation of historical and recent information), that is directly relevant to the restoration effort and also is relevant to short-term and long-term land management decisions regarding this natural resource. Analysis of field evidence, aerial photography, and published maps has revealed an accelerating rate of erosion and marsh loss at Dyke Marsh, which now appears to put at risk the short term survivability of this marsh. The destabilization of Dyke Marsh is outlined here, spanning an approximately 70-year time interval (1940-2010). This freshwater tidal marsh has shifted from a semi-stable net depositional environment (1864-1937) into a strongly erosional one, during a time when it currently is in early-phase planning for comprehensive restoration. The marsh has been deconstructed over the past 70 years by a combination of manmade and natural causes. The marsh initially experienced a strong destabilizing period between 1940 and 1972 by direct dredge mining of the marsh surface. By 1976 the marsh had entered a net destructive phase, where it remains at present. Photoanalysis of time-sequence aerial photographs of Dyke Marsh enabled us to calculate shoreline erosion estimates for this marsh over 19 years (1987-2006), as well as to quantify overall marsh acreage for 6 calendar years spanning an ~70 year interval (1937-2006). Photo overlay of a historic map enabled us to extend our whole-marsh acreage calculations back to 1883. Both sets of analyses were part of a geologic framework study in support of current efforts by the National Park Service (NPS) to restore this urban wetland. Two time intervals were selected for our shoreline erosion analyses, based on image quality and availability: 1987 to 2002, and 2002 to 2006. The more recent time interval shows a marked increase in erosion in the southern part of Dyke Marsh, following a wave-induced breach of a small peninsula that had protected its southern shoreline. Field observations and analyses of annual aerial imagery between 1987 and 2006 revealed a progressive increase in wave-induced erosion that presently is deconstructing Hog Island Gut, the last significant tidal creek network within the Dyke Marsh. These photo analyses documented an overall average westward shoreline loss of 6.0 to 7.8 linear feet per year along the Potomac River during this 19-year time interval. Additionally, photographic evidence documented that lateral erosion now is capturing existing higher order tributaries in the Hog Island Gut. Wave-driven stream piracy is fragmenting the remaining marsh habitat, and therefore its connectivity, relatively rapidly, causing the effective mouth of the Hog Island Gut tidal network to retreat headward visibly over the past several decades. Based on our estimates of total marsh area in the Dyke Marsh derived from 1987 aerial imagery, as much as 12 percent of the central part of the marsh has eroded in the 19 year period we studied (or ~7.5 percent of the original ~78.8 acres of 1987 marshland). Shoreline loss estimates for marsh parcels north and south of our study area have not yet been analyzed, although annual aerial photos from 1987 to 2002 confirm visible progressive shoreline loss in those areas over this same time interval.

Open-File Report↗

USGS1995

Evaluation of nonpoint-source contamination, Wisconsin; selected streamwater-quality data, land-use and best-management practices inventory, and quality assurance and quality control, water year 1993

The objective of the watershed-management evaluation monitoring program in Wisconsin is to evaluate the effectiveness of the best-management practices (BMPs) for rural streams, urban streams, and urban storm sewers. This report is an annual summary of the data collected for the program and a report of the results from several different special studies conducted within this program. Suspended sediment and total phosphorus storm-load data are summarized for eight rural sites and suspended sediment, total phosphorus, total recoverable lead, total recoverable copper, total recoverable zinc, and total recoverable cadmium storm-load data are summarized for four urban sites. Dissolved-oxygen data is summarized and compared with Wisconsin's waterquality standards for summer 1993 for seven rural sites. The dissolved-oxygen concentrations declined to levels below these standards at least one time at all seven sites during summer 1993. Total-recoverable hardness concentrations were compared with dissolved-hardness concentrations at two urban streams and two urban storm sewers. Least-squared linear regressions resulted in stronger relations for low-flow conditions than for high-flow conditions, indicating that most hardness during low flow is dissolved hardness. Pesticide data are summarized for four urban sites and six rural sites. Herbicides were detected at urban and rural sites; whereas insecticides were detected only at urban sites. A land-use and best-management-practice inventory is ongoing for each evaluation monitoring project to track the different sources of nonpoint pollution in each watershed and to document implementation of best-management programs that may cause changes in water quality of streams. Updated information is gathered each year, mapped, and stored in a geographic-information-system data base. The quality-assurance/quality-control plan for the urban watershed-management evaluation program consisted of a series of blank samples. These blank samples were used to identify and isolate contamination by inorganic and organic components throughout the collection and processing of urban streamwater samples. A dissolved trace-metal contamination problem was identified and resolved by using different laboratory- supplied sample bottles. A special study was done to determine the effect of holding time on fecal coliform colony counts. A linear regression indicated that the mean decrease in colony counts over 72 hours was 8.2 percent per day. Results after 24 hours showed that colony counts increased in some samples and decreased in others.

Wisconsin↗

USGS2021

Multiple-scale relationships between vegetation, the wildland–urban interface, and structure loss to wildfire in California

Recent increases in destructive wildfires are driving a need for empirical research documenting factors that contribute to structure loss. Existing studies show that fire risk is complex and varies geographically, and the role of vegetation has been especially difficult to quantify. Here, we evaluated the relative importance of vegetation cover at local (measured through the Normalized Difference Vegetation Index) and landscape (as measured through the Wildland–Urban Interface) scales in explaining structure loss from 2013 to 2018 in California—statewide and divided across three regions. Generally, the pattern of housing relative to vegetation better explained structure loss than local-scale vegetation amount, but the results varied regionally. This is likely because exposure to fire is a necessary first condition for structure survival, and sensitivity is only relevant once the fire reaches there. The relative importance of other factors such as long-term climatic variability, distance to powerlines, and elevation also varied among regions. These suggest that effective fire risk reduction strategies may need to account for multiple factors at multiple scales. The geographical variability in results also reinforces the notion that “one size does not fit all”. Local-scale empirical research on specific vegetation characteristics relative to structure loss is needed to inform the most effective customized plan.

California↗

USGS2004

Water-quality and biological conditions in the Lower Boise River, Ada and Canyon Counties, Idaho, 1994-2002

The water quality and biotic integrity of the lower Boise River between Lucky Peak Dam and the river's mouth near Parma, Idaho, have been affected by agricultural land and water use, wastewater treatment facility discharge, urbanization, reservoir operations, and river channel alteration. The U.S. Geological Survey (USGS) and cooperators have studied water-quality and biological aspects of the lower Boise River in the past to address water-quality concerns and issues brought forth by the Clean Water Act of 1977. Past and present issues include preservation of beneficial uses of the river for fisheries, recreation, and irrigation; and maintenance of high-quality water for domestic and agricultural uses. Evaluation of the data collected from 1994 to 2002 by the USGS revealed increases in constituent concentrations in the lower Boise in a downstream direction. Median suspended sediment concentrations from Diversion Dam (downstream from Lucky Peak Dam) to Parma increased more than 11 times, nitrogen concentrations increased more than 8 times, phosphorus concentrations increased more than 7 times, and fecal coliform concentrations increased more than 400 times. Chlorophyll-a concentrations, used as an indicator of nutrient input and the potential for nuisance algal growth, also increased in a downstream direction; median concentrations were highest at the Middleton and Parma sites. There were no discernible temporal trends in nutrients, sediment, or bacteria concentrations over the 8-year study. The State of Idaho?s temperature standards to protect coldwater biota and salmonid spawning were exceeded most frequently at Middleton and Parma. Suspended sediment concentrations exceeded criteria proposed by Idaho Department of Environmental Quality most frequently at Parma and at all but three tributaries. Total nitrogen concentrations at Glenwood, Middleton, and Parma exceeded national background levels; median flow-adjusted total nitrogen concentrations at Middleton and Parma were higher than those in undeveloped basins sampled nationwide by the USGS. Total phosphorus concentrations at Glenwood, Middleton, and Parma also exceeded those in undeveloped basins. Macroinvertebrate and fish communities were used to evaluate the long-term integration of water-quality contaminants and loss of habitat in the lower Boise. Biological integrity of the macroinvertebrate population was assessed with the attributes (metrics) of Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and metrics used in the Idaho River Macroinvertebrate Index (RMI): taxa richness; EPT richness; percent dominant taxon; percent Elmidae (riffle beetles); and percent predators. Average EPT was about 10, and RMI scores were frequently below 16, which indicated intermediate or poor water quality. The number of EPT taxa and RMI scores for the lower Boise were half those for least-impacted streams in Idaho. The fine sediment bioassessment index (FSBI) was used to evaluate macroinvertebrate sediment tolerance. The FSBI scores were lower than those for a site upstream in the Boise River Basin near Twin Springs, a site not impacted by urbanization and agriculture, which indicated that the lower Boise macroinvertebrate population may be impacted by fine sediment. Macroinvertebrate functional feeding groups and percent tolerant species, mainly at Middleton and Parma, were typical of those in areas of degraded water quality and habitat. The biological integrity of the fish population was evaluated using the Idaho River Fish Index (RFI), which consists of the 10 metrics: number of coldwater native species, percent sculpin, percent coldwater species, percent sensitive native individuals, percent tolerant individuals, number of nonindigenous species, number of coldwater fish captured per minute of electrofishing, percent of fish with deformities (eroded fins, lesions, or tumors), number of trout age classes, and percent carp. RFI scores for lower Boise sites indicated a d

Scientific Investigations Report↗

USGS2013

Comparing approaches to spatially explicit ecosystem service modeling: a case study from the San Pedro River, Arizona

Although the number of ecosystem service modeling tools has grown in recent years, quantitative comparative studies of these tools have been lacking. In this study, we applied two leading open-source, spatially explicit ecosystem services modeling tools – Artificial Intelligence for Ecosystem Services (ARIES) and Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) – to the San Pedro River watershed in southeast Arizona, USA, and northern Sonora, Mexico. We modeled locally important services that both modeling systems could address – carbon, water, and scenic viewsheds. We then applied managerially relevant scenarios for urban growth and mesquite management to quantify ecosystem service changes. InVEST and ARIES use different modeling approaches and ecosystem services metrics; for carbon, metrics were more similar and results were more easily comparable than for viewsheds or water. However, findings demonstrate similar gains and losses of ecosystem services and conclusions when comparing effects across our scenarios. Results were more closely aligned for landscape-scale urban-growth scenarios and more divergent for a site-scale mesquite-management scenario. Follow-up studies, including testing in different geographic contexts, can improve our understanding of the strengths and weaknesses of these and other ecosystem services modeling tools as they move closer to readiness for supporting day-to-day resource management.

Arizona;Sonora↗

USGS1998

Surface-water quality at fixed sites in the Western Lake Michigan Drainages, Wisconsin and Michigan, and the effects of natural and human factors, 1993-95

Streamwater samples were collected from April 1993 through July 1995 at 11 fixed sites in the Western Lake Michigan Drainages Study Unit of the U.S. Geological Survey's National Water-Quality Assessment Program. Water samples were collected monthly at all Fixed Sites, and an additional two to four samples were collected each year during periods of high flow. Streamflow was monitored continuously at the Fixed Sites for the duration of the study period. This report describes field techniques used to collect the water samples, and the analytical methods used for laboratory analyses, statistical analyses of the data, and an attempt to determine the effect of natural and anthropogenic factors on concentrations of nutrients and selected major ions and suspended solids. Locations of eight of the Fixed Sites were selected to represent areas with unique combinations of land use/land cover, surficial deposits, and bedrock geology and are referred to as 'indicator sites.' The remaining three sites were located near the mouths of major rivers and are referred to as 'integrator sites.' The integrator sites represent a large part of the total flow from the Study Unit to Green Bay and western Lake Michigan, and drain various combinations of land use, bedrock, and surficial deposits. These data indicate that land use and surficial deposits may be the primary factors affecting nitrate and total phosphorus concentrations in this Study Unit. Median concentrations of nitrate at the forested sites were less than the National Median Concentration (NMC), and those at urban fixed sites were similar to the NMC. Median nitrate concentrations at the Tomorrow River, North Branch Milwaukee River, and Duck Creek agricultural indicator sites were twice the NMC, but median concentrations at the remaining agricultural indicator sites were similar to the NMC. Nitrate concentrations at one agricultural indicator site exceeded the U. S. Environmental Protection Agency (USEPA) maximum contaminant level in three run-off samples in the growing seasons of 1994 and 1995. Median concentrations of total phosphorus at the forested indicator sites were below the NMC. Tomorrow River was the only agricultural indicator site where the median total-phosphorus concentration was less than the NMC; median concentrations at the remaining agricultural Fixed Sites were similar to the NMC and exceeded 0.1 mg/L, the USEPA suggested total-phosphorus concentration in flowing water. The USEPA recommends that total-phosphorus concentration not exceed this limit to discourage excessive aquatic plant growth in flowing waters. Median total-phosphorus concentration at the urban indicator site was less than the urban NMC. Median concentrations for both nitrate and total phosphorus at the mouth of the Fox River and the Milwaukee River integrator sites were similar to the NMC for the dominant land use, agriculture, within their basins, and were lower than that at the Menominee River integrator site with a dominant forest land use. During this study, potassium concentrations were generally highest in areas of clay-dominated surficial deposits, silica was generally highest in areas of sandy surficial deposits, iron generally highest in areas of igneous/metamorphic bedrock, and calcium generally highest in areas of carbonate bedrock. The highest median fluoride concentration occurred at an urban site that receives treated water.

Michigan, Wisconsin↗

USGS1997

Level II scour analysis for Bridge 2 (BENNCYPARK0002) on Park Street, crossing Furnace Brook, Bennington, Vermont

This report provides the results of a detailed Level II analysis of scour potential at structure BENNCYPARK0002 on the Park Street crossing of Furnace Brook, Bennington, Vermont (figures 1–8). A Level II study is a basic engineering analysis of the site, including a quantitative analysis of stream stability and scour (U.S. Department of Transportation, 1993). Results of a Level I scour investigation also are included in Appendix E of this report. A Level I investigation provides a qualitative geomorphic characterization of the study site. Information on the bridge, gleaned from Vermont Agency of Transportation (VTAOT) files, was compiled prior to conducting Level I and Level II analyses and is found in Appendix D. The site is in the Green Mountain section of the New England physiographic province in southwestern Vermont. The 12.8-mi 2 drainage area is a predominantly rural and forested basin. The bridge site is located within an urban setting in the Town of Bennington with buildings, homes, lawns, and pavement on the overbanks. In the study area, Furnace Brook has a mildly sinuous channel located on a delta and has a slope of approximately 0.01 ft/ft, an average channel top width of 35 ft and an average bank height of 4 ft. The predominant channel bed materials are gravel and cobble with a median grain size (D 50 ) of 58.4 mm (0.192 ft). The geomorphic assessment at the time of the Level I and Level II site visit on August 6, 1996, indicated that the reach was unstable. However, in the immediate vicinity of the bridge the reach has been stabilized with bank protection. Upstream of the protection, there is bank cutting and channel scour. The Park Street crossing of Furnace Brook is a 29-ft-long, two-lane bridge consisting of one 26-foot concrete span (Vermont Agency of Transportation, written communication, December 14, 1995). The width of the bridge opening parallel to the downstream bridge face is 25.3 feet. The bridge is supported by vertical, concrete abutments with no wingwalls. The upstream channel is skewed approximately 45 degrees to the opening while the opening-skew-to-roadway is 10 degrees. Scour countermeasures at the site include type-2 stone fill (less than 36 inches diameter) on the right banks upstream and downstream of the bridge and type-3 stone fill (less than 48 inches diameter) on the upstream left bank. Additional details describing conditions at the site are included in the Level II Summary and Appendices D and E. Scour depths and recommended rock rip-rap sizes were computed using the general guidelines described in Hydraulic Engineering Circular 18 (Richardson and others, 1995). Total scour at a highway crossing is comprised of three components: 1) long-term streambed degradation; 2) contraction scour (due to accelerated flow caused by a reduction in flow area at a bridge) and; 3) local scour (caused by accelerated flow around piers and abutments). Total scour is the sum of the three components. Equations are available to compute depths for contraction and local scour and a summary of the results of these computations follows. There was no contraction scour computed for any of the modelled flows. Computed left abutment scour ranged from 2.5 to 5.6 ft. with the worst-case scour occurring at the 500- year discharge. Computed right abutment scour ranged from 5.6 to 8.4 ft. with the worst- case scour also occurring at the 100-year discharge. Additional information on scour depths and depths to armoring are included in the section titled “Scour Results”. Scoured- streambed elevations, based on the calculated scour depths, are presented in tables 1 and 2. A cross-section of the scour computed at the bridge is presented in figure 8. Scour depths were calculated assuming an infinite depth of erosive material and a homogeneous particle- size distribution. It is generally accepted that the Froehlich equation (abutment scour) gives “excessively conservative estimates of scour depths” (Richardson and others, 1995, p. 47). Usually, computed scour depths are evaluated in combination with other information including (but not limited to) historical performance during flood events, the geomorphic stability assessment, existing scour protection measures, and the results of the hydraulic analyses. Therefore, scour depths adopted by VTAOT may differ from the computed values documented herein.

Vermont↗

USGS2011

Effects of biologically-active chemical mixtures on fish in a wastewater-impacted urban stream

Stream flow in urban aquatic ecosystems often is maintained by water-reclamation plant (WRP) effluents that contain mixtures of natural and anthropogenic chemicals that persist through the treatment processes. In effluent-impactedstreams, aquatic organisms such as fish are continuously exposed to biologically-activechemicals throughout their life cycles. The North Shore Channel of the Chicago River (Chicago, Illinois) is part of an urban ecosystem in which > 80% of the annual flow consists of effluent from the North Side WRP. In this study, multiple samplings of the effluent and stream water were conducted and fish (largemouth bass and carp) were collected on 2 occasions from the North Shore Channel. Fish also were collected once from the Outer Chicago Harbor in Lake Michigan, a reference site not impacted by WRP discharges. Over 100 organic chemicals with differing behaviors and biological effects were measured, and 23 compounds were detected in all of the water samples analyzed. The most frequently detected and highest concentration (> 100 μg/L) compounds were ethylenediaminetetraacetic acid and 4-nonylphenolmono-to-tetraethoxycarboxylic acids. Other biologically-activechemicals including bisphenol A, 4-nonylphenol, 4-nonylphenolmono-to-tetraethoxylates, 4- tert -octylphenol, and 4- tert -octylphenolmono-to-tetraethoxylates were detected at lower concentrations (< 5 μg/L). The biogenic steroidal hormones 17β-estradiol, estrone, testosterone, 4-androstene-3,17-dione, and cis -androsterone were detected at even lower concentrations (< 0.005 μg/L). There were slight differences in concentrations between the North Side WRP effluent and the North Shore Channel, indicating minimal in-stream attenuation. Fish populations are continuously exposed to mixtures of biologically-activechemicals because of the relative persistency of the chemicals with respect to stream hydraulic residence time, and the lack of a fresh water source for dilution. The majority of male fish exhibited vitellogenin induction, a physiological response consistent with exposure to estrogenic compounds. Tissue-level signs of reproductive disruption, such as ovatestis, were not observed.

Illinois↗

USGS2010

Land-Use Analysis and Simulated Effects of Land-Use Change and Aggregate Mining on Groundwater Flow in the South Platte River Valley, Brighton to Fort Lupton, Colorado

Land use in the South Platte River valley between the cities of Brighton and Fort Lupton, Colo., is undergoing change as urban areas expand, and the extent of aggregate mining in the Brighton-Fort Lupton area is increasing as the demand for aggregate grows in response to urban development. To improve understanding of land-use change and the potential effects of land-use change and aggregate mining on groundwater flow, the U.S. Geological Survey, in cooperation with the cities of Brighton and Fort Lupton, analyzed socioeconomic and land-use trends and constructed a numerical groundwater flow model of the South Platte alluvial aquifer in the Brighton-Fort Lupton area. The numerical groundwater flow model was used to simulate (1) steady-state hydrologic effects of predicted land-use conditions in 2020 and 2040, (2) transient cumulative hydrologic effects of the potential extent of reclaimed aggregate pits in 2020 and 2040, (3) transient hydrologic effects of actively dewatered aggregate pits, and (4) effects of different hypothetical pit spacings and configurations on groundwater levels. The SLEUTH (Slope, Land cover, Exclusion, Urbanization, Transportation, and Hillshade) urban-growth modeling program was used to predict the extent of urban area in 2020 and 2040. Wetlands in the Brighton-Fort Lupton area were mapped as part of the study, and mapped wetland locations and areas of riparian herbaceous vegetation previously mapped by the Colorado Division of Wildlife were compared to simulation results to indicate areas where wetlands or riparian herbaceous vegetation might be affected by groundwater-level changes resulting from land-use change or aggregate mining. Analysis of land-use conditions in 1957, 1977, and 2000 indicated that the general distribution of irrigated land and non-irrigated land remained similar from 1957 to 2000, but both land uses decreased as urban area increased. Urban area increased about 165 percent from 1957 to 1977 and about 56 percent from 1977 to 2000 with most urban growth occurring east of Brighton and Fort Lupton and along major transportation corridors. Land-use conditions in 2020 and 2040 predicted by the SLEUTH modeling program indicated urban growth will continue to develop primarily east of Brighton and Fort Lupton and along major transportation routes, but substantial urban growth also is predicted south and west of Brighton. Steady-state simulations of the hydrologic effects of predicted land-use conditions in 2020 and 2040 indicated groundwater levels declined less than 2 feet relative to simulated groundwater levels in 2000. Groundwater levels declined most where irrigated land was converted to urban area and least where non-irrigated land was converted to urban area. Simulated groundwater-level declines resulting from land-use conditions in 2020 and 2040 are not predicted to substantially affect wetlands or riparian herbaceous vegetation in the study area because the declines are small and wetlands and riparian herbaceous vegetation generally are not located where simulated declines occur. See Report PDF for unabridged abstract.

Scientific Investigations Report↗

USGS1993

Ground water discharge and the related nutrient and trace metal fluxes into Quincy bay, Massachusetts

Measurement of the rate and direction of ground water flow beneath Wollaston Beach, Quincy, Massachusetts by use of a heat-pulsing flowmeter shows a mean velocity in the bulk sediment of 40 cm d −1 . The estimated total discharge of ground water into Quincy Bay during October 1990 was 1324–2177 m 3 d −1 , a relatively low ground water discharge rate. The tides have only a moderate effect on the rate and direction of this flow. Other important controls on the rate and volume of ground water flow are the limited thickness, geographic extent, and permeability of the aquifer. Comparisons of published streamflow data and estimates of ground water discharge indicate that ground water makes up between 7.4–12.1% of the gaged freshwater input into Quincy Bay. The data from this study suggest the ground water discharge is a less important recharge component to Quincy Bay than predicted by National Urban Runoff Program (NURP) models. The high nitrate and low nitrite and ammonia concentrations in the ground water at the backshore well sites and low nitrate and high nitrite and ammonia concentrations in the water flowing from the foreshore suggests that denitrification is active in the sediments. The low ground water flow rates and low nitrate concentrations in the foreshore samples suggest that little or no nitrate is surviving the denitrification process to affect the planktonic community. Similarly, oxidizing conditions in the aquifer and low trace metal concentrations in the ground water samples suggest that the metals may be precipitating and binding to sedimentary phases before impacting the bay.

Massachusetts↗

USGS2006

Assessment of total nitrogen in the upper Connecticut River basin in New Hampshire, Vermont, and Massachusetts, December 2002–September 2005

A study of total nitrogen concentrations and loads was conducted from December 2002 to September 2005 at 13 river sites in the upper Connecticut River Basin. Ten sites were selected to represent contributions of nitrogen from forested, agricultural, and urban land. Three sites were distributed spatially on the main stem of the Connecticut River to assess the cumulative total nitrogen loads. To further improve the understanding of the sources and concentrations and loads of total nitrogen in the upper Connecticut River Basin, ambient surface water-quality sampling was supplemented with sampling of effluent from 19 municipal and paper mill wastewater-treatment facilities. Mean concentrations of total nitrogen ranged from 0.19 to 2.8 milligrams per liter (mg/L) at river sampling sites. Instantaneous mean loads of total nitrogen ranged from 162 to 58,300 pounds per day (lb/d). Estimated mean annual loads of total nitrogen ranged from 49,100 to 21.6 million pounds per year (lb/yr) with about 30 to 55 percent of the loads being transported during the spring. The estimated mean annual yields of total nitrogen ranged from 1,190 to 7,300 pounds per square mile per year (lb/mi 2 )/yr. Mean concentrations of total nitrogen ranged from 4.4 to 30 mg/L at wastewater-treatment sampling sites. Instantaneous mean loads of total nitrogen from municipal wastewater-treatment facilities ranged from 36 to 1,780 lb/d. Instantaneous mean loads of total nitrogen from paper mill wastewater-treatment facilities ranged from 96 to 160 lb/d. The median concentration of total nitrogen was 0.24 mg/L at forested sites, 0.48 mg/L at agricultural sites, 0.54 mg/L at urban sites, 0.48 mg/L at main-stem sites, and 14 mg/L at wastewater-treatment sites. Concentrations of total nitrogen at forested sites were significantly less than at all other site types (p<0.05). Concentrations of total nitrogen at agricultural, urban, and main stem sites were not significantly different among each other (p>0.05) but were significantly greater (p<0.05) than at forested sites and significantly less than concentrations at wastewater-treatment sites (p<0.05). Total nitrogen concentrations at wastewater-treatment sites were significantly different from all other site types (p<0.05). Annual yields of total nitrogen ranged from 732 to 1,920 (lb/mi 2 )/yr at forested sites; 1,550 to 2,980 (lb/mi 2 )/yr at agricultural sites; 1,280 to 1,860 (lb/mi 2 )/yr at urban sites that were not directly affected by wastewater effluent; 7,090 to 7,770 (lb/mi 2 )/yr at an urban site directly affected by wastewater effluent; and 1,300 to 2,390 (lb/mi 2 )/yr at main-stem sites. In this study, the mean annual load and yield of total nitrogen at the Connecticut River at Wells River, VT, was estimated at 4.47 million lb/yr and 1,690 (lb/mi 2 )/yr, respectively. The mean annual load and yield of total nitrogen at the Connecticut River at North Walpole, NH, was estimated at 9.60 million lb/yr and 1,750 (lb/mi 2 )/yr, respectively. The mean annual load and yield of total nitrogen leaving the upper Connecticut River Basin, as estimated at the Connecticut River at Thompsonville, CT, was 21.6 million lb/yr and 2,230 (lb/mi 2 )/yr, respectively.

Massachusetts, New Hampshire, Vermont↗

USGS2023

Evaluating drivers of hydrology, water quality, and benthic macroinvertebrates in streams of Fairfax County, Virginia, 2007–18

In 2007, the U.S. Geological Survey partnered with Fairfax County, Virginia, to establish a long-term water-resources monitoring program to evaluate the hydrology, water quality, and ecology of Fairfax County streams and the watershed-scale effects of management practices. Fairfax County uses a variety of management practices, policies, and programs to protect and restore its water resources, but the effects of such strategies are not well understood. This report used streamflow, water-quality, and ecological monitoring data collected from 20 Fairfax County watersheds from 2007 through 2018 to assess the effects of management practices, landscape factors, and climatic conditions on observed nutrient, sediment, salinity, and benthic-macroinvertebrate community responses. Urbanization, climatic variability, and an increase in management practices occurred within Fairfax County during the study period. Impervious cover, housing units, wastewater infrastructure, and (or) stormwater infrastructure increased in most study watersheds. Climatic conditions varied among study years; countywide estimates of average-annual air temperature differed by about 3 degrees Celsius, and total precipitation ranged from about 34 to 63 inches per year. The effects of the management practices, implemented to reduce nitrogen, phosphorus, and (or) sediment loads, are considered in this study. These management practices primarily consist of stormwater retrofits and stream restorations; however, stream restorations account for most of the financial investment and expected load reductions. Management practices were implemented in half of the study watersheds, and most practices were installed and reductions credited late in the study period. Changes in hydrologic response during storm events were evaluated over the study period because many management practices that were implemented were designed to achieve nutrient and sediment reductions by slowing or intercepting runoff. The average number and length of storm events was mostly unchanged throughout the monitoring network. Four watersheds with 10 years of streamflow data showed a mixture of trends in stormflow peak, volume, and rate-of-change. Event-mean nutrient and sediment concentrations from these watersheds were evaluated during storm events and generally showed increases in total phosphorus (TP) and suspended sediment and reductions or no changes in total nitrogen (TN). Landscape inputs of nitrogen and phosphorus and the percentage of inputs delivered to streams were estimated for the study watersheds. Estimated phosphorus from fertilizer and nitrogen from atmospheric deposition represented large nutrient inputs in most watersheds; amounts of other nonpoint sources varied based on land use. Estimated nitrogen inputs declined throughout Fairfax County and in most study watersheds from 2008 through 2018; in comparison, phosphorus input changes were relatively small. Most nonpoint-nutrient inputs were retained on the landscape and did not reach streams, with slightly more nitrogen retention than phosphorus, on average. Retention rates were lower for years with more precipitation and streamflow. After adjusting for streamflow, TN and TP loads were generally higher for years with more nutrient inputs. Calculated as a function of flow-adjusted loads, TP retention declined at most stations from 2009 through 2018, in comparison, TN retention was relatively unchanged. Landscape and climatic conditions affected spatial differences and changes in Fairfax County stream conditions from 2009 through 2018. TN concentrations were higher and increases over time were larger in watersheds with elevated septic-system density. TP concentrations were higher in watersheds with more turfgrass; concentrations were lower, but had larger increases over time, in watersheds with deeper soils. Suspended-sediment concentrations were higher in watersheds with greater stream densities. Specific conductance was higher in watersheds with more developed land use and shallower soils. Benthic-macroinvertebrate index of biotic integrity (IBI) scores were lower in watersheds with high road density and had larger increases over time in bigger, more developed watersheds. Annual variability in TN and TP concentrations and benthic-macroinvertebrate IBI scores was affected by precipitation; annual variability in suspended sediment concentrations and specific conductance was affected by air temperature. After accounting for influences from landscape and climatic conditions, expected management-practice effects were not consistently observed in monitored stream responses. These effects were assessed by comparing expected management-practice load reductions with the timing, direction, and magnitude of changes in storm-event hydrology, nutrient and sediment loads, median-annual water-quality conditions, and benthic-macroinvertebrate IBI scores. An important consideration for future investigations of management-practice effects is how to control for water-quality and ecological variability caused by geologic properties, the urban environment, precipitation, and (or) air temperature. The interpretation of management-practice effects in this report was likely influenced by a combination of factors, including (1) the amount, timing, and location of management-practice implementation; (2) unmeasured landscape and climatic factors; (3) uncertain management-practice expectations; (4) hydrologic variability; and (5) analytical assumptions. Through continued data-collection efforts, particularly after management practices have been completed, many of these factors may become less influential in the future.

Virginia↗

USGS2023

Contaminant exposure and transport from three potential reuse waters within a single watershed

Global demand for safe and sustainable water supplies necessitates a better understanding of contaminant exposures in potential reuse waters. In this study, we compared exposures and load contributions to surface water from the discharge of three reuse waters (wastewater effluent, urban stormwater, and agricultural runoff). Results document substantial and varying organic-chemical contribution to surface water from effluent discharges (e.g., disinfection byproducts [DBP], prescription pharmaceuticals, industrial/household chemicals), urban stormwater (e.g., polycyclic aromatic hydrocarbons, pesticides, nonprescription pharmaceuticals), and agricultural runoff (e.g., pesticides). Excluding DBPs, episodic storm-event organic concentrations and loads from urban stormwater were comparable to and often exceeded those of daily wastewater-effluent discharges. We also assessed if wastewater-effluent irrigation to corn resulted in measurable effects on organic-chemical concentrations in rain-induced agricultural runoff and harvested feedstock. Overall, the target-organic load of 491 g from wastewater-effluent irrigation to the study corn field during the 2019 growing season did not produce substantial dissolved organic-contaminant contributions in subsequent rain-induced runoff events. Out of the 140 detected organics in source wastewater-effluent irrigation, only imidacloprid and estrone had concentrations that resulted in observable differences between rain-induced agricultural runoff from the effluent-irrigated and nonirrigated corn fields. Analyses of pharmaceuticals and per-/polyfluoroalkyl substances in at-harvest corn-plant samples detected two prescription antibiotics, norfloxacin and ciprofloxacin, at concentrations of 36 and 70 ng/g, respectively, in effluent-irrigated corn-plant samples; no contaminants were detected in noneffluent irrigated corn-plant samples.

Oklahoma↗

USGS2017

Storms, channel changes, and a sediment budget for an urban-suburban stream, Difficult Run, Virginia, USA

Determining erosion and deposition rates in urban-suburban settings and how these processes are affected by large storms is important to understanding geomorphic processes in these landscapes. Sediment yields in the suburban and urban Upper Difficult Run are among the highest ever recorded in the Chesapeake Bay watershed, ranging from 161 to 376 Mg/km 2 /y. Erosion and deposition of streambanks, channel bed, and bars and deposition of floodplains were monitored between 1 March 2010 and 18 January 2013 in Upper Difficult Run, Virginia, USA. We documented the effects of two large storms, Tropical Storm Lee (September 2011), a 100-year event, and Super Storm Sandy (October 2012) a 5-year event, on channel erosion and deposition. Variability in erosion and deposition rates for all geomorphic features, temporally and spatially, are important conclusions of this study. Tropical Storm Lee was an erosive event, where erosion occurred on 82% of all streambanks and where 88% of streambanks that were aggrading before Tropical Storm Lee became erosional. Statistical analysis indicated that drainage area explains linear changes (cm/y) in eroding streambanks and that channel top width explains cross-sectional area changes (cm 2 /y) in eroding streambanks and floodplain deposition (mm/y). A quasi-sediment budget constructed for the study period using the streambanks, channel bed, channel bars, and floodplain measurements underestimated the measured suspended-sediment load by 61% (2130 Mg/y). Underestimation of the sediment load may be caused by measurement errors and to contributions from upland sediment sources, which were not measured but estimated at 36% of the gross input of sediment. Eroding streambanks contributed 42% of the gross input of sediment and accounted for 70% of the measured suspended-sediment load. Similar to other urban watersheds, the large percentage of impervious area in Difficult Run and direct runoff of precipitation leads to increased streamflow and streambank erosion. This study emphasizes the importance of streambanks in urban-suburban sediment budgets but also suggests that other sediment sources, such as upland sources, which were not measured in this study, can be an important source of sediment.

Virginia↗

USGS2010

Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Relative-concentrations of organic and special interest constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). Inorganic constituent relative-concentrations were classified as “high” (relative-concentration > 1.0), “moderate” (0.5 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as a metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifers that have a relative-concentration greater than 1.0; proportion is calculated on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially-weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the North San Francisco Bay study unit (90-percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high in 14.0 percent of the primary aquifers, moderate in 35.8 percent, and low in 50.2 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (10.0 percent), boron (4.1 percent), and lead (1.6 percent). In contrast, relative-concentrations of organic constituents (one or more) were high in 1.4 percent, moderate in 4.9 percent, and low in 93.7 percent (not detected in 64.8 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of PCE (1.3 percent), TCE (0.1 percent), and 1,1-dichloroethene (0.1 percent). The inorganic constituents with secondary maximum contaminant levels (SMCL), manganese and iron, had relative-concentrations that were high in 40.8 percent and 24.4 percent of the primary aquifers, respectively. Of the 255 organic and special-interest constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (in 10 percent or more of samples), the trihalomethane chloroform and the herbicide simazine, but both were detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, geochemical conditions of the aquifer, and water temperature. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that a majority of the wells that contained nitrate also had an urban or agricultural land-use classification, had a modern or mixed age classification, and had depths to their top perforations <100 ft (30 m). Geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the terminal and deeper parts of the flow system. High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing depth and groundwater age in the North San Francisco Bay study unit. High to moderate relative-concentrations of boron were primarily associated with hydrothermal activity or high-salinity waters in the Napa Sonoma lowlands. Simazine was detected in groundwater classified as modern and mixed age more often than in groundwater classified as pre-modern age, while chloroform was detected most often in groundwater classified as mixed age. Simazine and chloroform also were observed in wells that had surrounding land use classified as agricultural or land use classified as urban, and top of perforation depths less than 100 ft (30 m). Together, the occurrence of chloroform and simazine in shallow wells with modern or mixed groundwater located in urban or agricultural areas suggests that these constituents result from anthropogenic activities during the last 50 years. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic, iron, and total dissolved solids (TDS) concentrations were significantly greater in groundwater having pre-modern-age classification than modern, suggesting that these constituents accumulate with groundwater residence time.

California↗