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USGS1998

Watershed trend analysis and water-quality assessment using bottom-sediment cores from Cheney Reservoir, south-central Kansas

An examination of Cheney Reservoir bottom sediment was conducted in August 1997 to describe long-term trends and document the occurrence of selected constituents at concentrations that may be detrimental to aquatic organisms. Average concentrations of total phosphorus in bottom-sediment cores ranged from 94 to 674 milligrams per kilogram and were statistically related to silt- and (or) clay-size particles. Results from selected sampling sites in Cheney Reservoir indicate an increasing trend in total phosphorus concentrations. This trend is probably of nonpoint-source origin and may be related to an increase in fertilizer sales in the area, which more than doubled between 1965 and 1996, and to livestock production. Few organochlorine compounds were detected in bottom-sediment samples from Cheney Reservoir. DDT, its degradation products DDD and DDE, and dieldrin had detectable concentrations in the seven samples that were analyzed. DDT and DDD were each detected in one sample at concentrations of 1.0 and 0.65 microgram per kilogram, respectively. By far, the most frequently detected organochlorine insecticide was DDE, which was detected in all seven samples, ranging in concentration from 0.31 to 1.3 micrograms per kilogram. A decreasing trend in DDE concentrations was evident in sediment-core data from one sampling site. Dieldrin was detected in one sample from each of two sampling sites at concentrations of 0.21 and 0.22 micrograms per kilogram. Polychlorinated biphenyls were not detected in any bottom-sediment sample analyzed. Selected organophosphate, chlorophenoxy-acid, triazine, and acetanilide pesticides were analyzed in 18 bottom-sediment samples. Of the 23 pesticides analyzed, only the acetanilide herbicide metolachlor was detected (in 22 percent of the samples). Seven bottom-sediment samples were analyzed for major metals and trace elements. The median and maximum concentrations of arsenic and chromium, the maximum concentration of copper, and all concentrations of nickel in the seven samples were in the range where adverse effects to aquatic organisms occasionally occur. No time trends in trace elements were discernable in the August 1997 data.

Water-Resources Investigations Report↗

USGS1990

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the American Falls Reservoir area, Idaho, 1988-89

Increased concern about the quality of irrigation drainage and its potential effects on human health, fish, and wildlife prompted the Department of the Interior to begin a program during late 1985 to identify irrigation-induced water-quality problems that might exist in the Western States. During `988, the Task Group on Irrigation Drainage selected the American Falls Reservoir area, Idaho, for study to determine whether potentially toxic concentrations of trace elements or organochlorine compounds existed in water, bottom sediment, and biota. The 91-square mile American Falls Reservoir has a total capacity of 1.7 million acre-feet and is used primarily for irrigation-water supply and power generation. Irrigated land upstream from the reservoir totals about 550,000 acres. Total water inflow to the reservoir is about 5.8 million acre-feet per year, of which about 63 percent is from surface-water runoff, 33 percent is from ground-water discharge, and about 4 percent is from ungaged tributaries, canals, ditches, sloughs, and precipitation. Ground-water discharge to the reservoir originates, in part, from irrigation of land upstream from and adjacent to the reservoir. The 1988 water year was a drought year, and water discharge was about 34 percent less than during 1939-88. Water samples were collected during the post-irrigation (October 1987) and irrigation (July 1988) seasons and were analyzed for major ions and trace elements. Bottom-sediment samples were collected during the irrigation season and were analyzed for trace elements and organochlorine compounds. Biota samples were collected during May, June, July, and August 1988 and were analyzed for trace elements and organochlorine compounds. Dissolved-solids concentrations in water ranged from 216 to 561 milligrams per liter. The similarity of dissolved-solids concentrations between the irrigation and post-irrigation seasons can be attributed to the large volume of ground-water discharge in the study area. Most trace-element concentrations in water were near analytical reporting limits; none exceeded State or Federal water-quality standards or criteria. Trace elements that were present at all sites in analytically detectable concentrations (in micrograms per liter) included arsenic (2 to 7), boron (40 to 130), uranium (0.7 to 3.5), vanadium (1 to 6) and zinc (less than 3 to 42). The ranges of arsenic, cadmium, and mercury concentrations in water analyzed during previous investigations. Selenium concentrations ranged from less than 1 (the reporting limit) to 6 micrograms per liter and did not exceed State of Federal water-quality standards or criteria. Concentrations of most trace elements in bottom sediment were similar to geometric mean concentrations in study area soils and were within the expected 95-percent range of concentrations in soils in the Western United States. Mercury concentrations in 9 of the 18 bottom-sediment samples exceeded the 95th-percentile concentration for mercury in area soils. Selenium concentration for selenium in area soils and, in 1 sample, exceeded the upper limit of the expected 95-percent range for selenium in Western United States soils. Most organochlorine compunds in bottom sediment were lower than analytical reporting limits. Only DDE (0.2 micrograms per kilogram) and DDT (0.3 micrograms per kilogram) were detected in bottom sediment from the Portneuf River. Except for mercury and selenium, concentrations of most trace elements in biota were not considered high enough to be harmful to humans or wildlife. Some mercury concentrations in fish exceeded the U.S. Fish and Wildlife Service National Contaminant Biomonitoring Program 85th-percentile concentration and were at levels that might not be safe for human consumption, especially for pregnant women. Elevated mercury concentrations in fish-eating waterbirds, such as double-crested cormorants, indicates biomagnification in the food chain. Selenium concentrations generally were low except in mallard livers (6.6 to 41.8 micrograms per gram, dry weight). This range is within the range of selenium concentrations (19 to 43 micrograms per gram, dry weight) reported in livers of ducks from Kesterson National Wildlife Refuge, California, where waterbird deformities, moralities, and reproductive impairment were observed. Selenium concentrations in mayfly nymphs were at or near dietary concentrations (5 to 8 micrograms per gram, dry weight) that had adverse reproductive effects on mallards during laboratory toxicity studies. p,p'DDE was detected in all waterbird eggs and juvenile mallared carcasses. Highest concentrations were in cormorant eggs (0.59 to 5.70 micrograms per gram, wet weight). p,p'DDE concentrations in four of five cormorant eggs exceeded the National Academy of Sciences, National Academy of Engineering criterion for protection of aquatic wildlife (1 microgram per gram, wet weight, for p,p'DDT and its metabolites). p,p'DDE was detected in all fish samples except rainbow trout. p,p'DDE was detected in one sample of Utah suckers. No concentrations of p,p'DDE or p,p'DDT in fish exceeded the criterion for protection of aquatic life. Total PCB's were detected in all cormorant eggs and all fish samples. PCB's were not detected in other waterbird eggs. PCB concentrations in cormorant eggs (0.28 to 1.8 micro per gram, wet weight) were lower than concentrations that would be expected to cause adverse effects. Two of the three carp samples contained PCB concntrations higher than the recommended level for protection of fish and wildlife (0.4 micrograms per gram, wet weight). Eggshell thinning was noted in cormorant and mallard eggs but was not considered great enough to cause reporductive problems. Observations of the general health of fish and waterbird populations during the study indicated that the area did not appear to have a serious contaminant problem that could be associated with irrigation grainage. No waterbird or fish die-offs were observed, and nesting waterbird populations were noted to be increasing. Selenium concentrations in mallard livers, however, are of concern, as are p,p'DDE residues in cormorant eggs.

Idaho↗

USGS2015

Rates of As and trace-element mobilization caused by Fe reduction in mixed BTEX–ethanol experimental plumes

Biodegradation of organic matter, including petroleum-based fuels and biofuels, can create undesired secondary water-quality effects. Trace elements, especially arsenic (As), have strong adsorption affinities for Fe(III) (oxyhydr)-oxides and can be released to groundwater during Fe-reducing biodegradation. We investigated the mobilization of naturally occurring As, cobalt (Co), chromium (Cr), and nickel (Ni) from wetland sediments caused by the introduction of benzene, toluene, ethylbenzene, and xylenes (BTEX) and ethanol mixtures under iron- and nitrate-reducing conditions, using in situ push–pull tests. When BTEX alone was added, results showed simultaneous onset and similar rates of Fe reduction and As mobilization. In the presence of ethanol, the maximum rates of As release and Fe reduction were higher, the time to onset of reaction was decreased, and the rates occurred in multiple stages that reflected additional processes. The concentration of As increased from <1 μg/L to a maximum of 99 μg/L, exceeding the 10 μg/L limit for drinking water. Mobilization of Co, Cr, and Ni was observed in association with ethanol biodegradation but not with BTEX. These results demonstrate the potential for trace-element contamination of drinking water during biodegradation and highlight the importance of monitoring trace elements at natural and enhanced attenuation sites.

Environmental Science & Technology↗

USGS2007

Assessment of elemental concentrations in streams of the New Lead Belt in southeastern Missouri, 2002-05

Concerns about possible effects of lead-mining activities on the water quality of federally protected streams located in southeastern Missouri prompted a suite of multidisciplinary studies to be conducted by the U.S. Geological Survey. As part of this investigation, a series of biological studies were initiated in 2001 for streams in the current mining region and the prospecting area. In this report, results are examined for trace elements and other selected chemical measurements in sediment, surface water, and sediment interstitial (pore) water sampled between 2002 and 2005 in association with these biological studies. Compared to reference sites, fine sediments collected downstream from mining areas were enriched in metals by factors as large as 75 for cadmium, 62 for cobalt, 171 for nickel, 95 for lead, and 150 for zinc. Greatest metal concentrations in sediments collected in 2002 were from sites downstream from mines on Strother Creek, Courtois Creek, and the West Fork Black River. Sediments from sites on Bee Fork, Logan Creek, and Sweetwater Creek also were noticeably enriched in lead. Sediments in Clearwater Lake, at least 75 kilometers downstream from mining activity, had metal concentrations that were 1.5 to 2.1 times greater than sediments in an area of the lake with no upstream mining activity. Longitudinal sampling along three streams in 2004 indicated that sediment metal concentrations decreased considerably a few kilometers downstream from mining activities; however, in Strother Creek some metals were still enriched by a factor of five or more as far as 13 kilometers downstream from the Buick tailings impoundment. Compared with 2002 samples, metals concentrations were dramatically lower in sediments collected in 2004 at an upper West Fork Black River site, presumably because beneficiation operations at the West Fork mill ceased in 2000. Concentrations of metals and sulfate in sediment interstitial (pore) waters generally tracked closely with metal concentrations in sediments. Metals, including cobalt, nickel, lead, and zinc, were elevated substantially in laboratory-produced pore waters of fine sediments collected near mining operations in 2002 and 2004. Passive diffusion samplers (peepers) buried 4 to 6 centimeters deep in riffle-run stream sediments during 2003 and 2005 had much lower pore-water metal concentrations than the laboratory-produced pore waters of fine sediments collected in 2002 and 2004, but each sampling method produced similar patterns among sites. The combined mean concentration of lead in peeper samples from selected sites located downstream from mining activities for six streams was about 10-fold greater than the mean of the reference sites. In most instances, metals concentrations in surface water and peeper water were not greatly different, indicating considerable exchange between the surface water and pore water at the depths and locations where peepers were situated. Passive sampling probes used to assess metal lability in pore waters of selected samples during 2004 sediment toxicity tests indicated that most of the filterable lead in the laboratory-prepared pore water was relatively non-labile, presumably because lead was complexed by organic matter, or was present as colloidal species. In contrast, large percentages of cobalt and nickel in pore water appeared to be labile. Passive integrative samplers deployed in surface water for up to 3 weeks at three sites in July 2005 confirmed the presence of elevated concentrations of labile metals downstream from mining operations on Strother Creek and, to a lesser extent, Bee Fork. These samplers also indicated a considerable increase in metal loadings occurred for a few days at the Strother Creek site, which coincided with moderate increases in stream discharges in the area.

Scientific Investigations Report↗

USGS2015

Pre-eruptive conditions of the Hideaway Park topaz rhyolite: Insights into metal source and evolution of magma parental to the Henderson porphyry molybdenum deposit, Colorado

The Hideaway Park tuff is the only preserved extrusive volcanic unit related to the Red Mountain intrusive complex, which produced the world-class Henderson porphyry Mo deposit. Located within the Colorado Mineral Belt, USA, Henderson is the second largest Climax-type Mo deposit in the world, and is therefore an excellent location to investigate magmatic processes leading to Climax-type Mo mineralization. We combine an extensive dataset of major element, volatile, and trace element abundances in quartz-hosted melt inclusions and pumice matrix glass with major element geochemistry from phenocrysts to reconstruct the pre-eruptive conditions and the source and evolution of metals within the magma. Melt inclusions are slightly peraluminous topaz rhyolitic in composition and are volatile-charged (≤6 wt % H 2 O, ≤600 ppm CO 2 , &sim;0·3–1·0 wt % F, &sim;2300–3500 ppm Cl) and metal-rich (&sim;7–24 ppm Mo, &sim;4–14 ppm W, &sim;21–52 ppm Pb, &sim;28–2700 ppm Zn, <0·1–29 ppm Cu, &sim;0·3–1·8 ppm Bi, &sim;40–760 ppb Ag, &sim;690–1400 ppm Mn). Melt inclusion and pumice matrix glass chemistry reveal that the Hideaway Park magma evolved by large degrees of fractional crystallization (≤60–70%) during quartz crystallization and melt inclusion entrapment at pressures of ≤300 MPa (≤8 km depth), with little to no crystallization upon shallow ascent and eruption. Filter pressing, crystal settling, magma recharge and mixing of less evolved rhyolite melt, and volatile exsolution were important processes during magma evolution; the low estimated viscosities (&sim;10 5 –10 10  Pa s) of these H 2 O- and F-rich melts probably enhanced these processes. A noteworthy discrepancy between the metal contents in the pumice matrix glass and in the melt inclusions suggests that after quartz crystallization ceased upon shallow magma ascent and eruption, the Hideaway Park magma exsolved an aqueous fluid into which Mo, Bi, Ag, Zn, Mn, Cs, and Y strongly partitioned. Given that the Henderson deposit contains anomalous abundances of not only Mo, but also W, Pb, Zn, Cu, Bi, Ag, and Mn, we suggest that these metals were sourced from similar fluids exsolved from unerupted portions of the same magmatic system. Trace element ratios imply that Mo was sourced deep, from either the lower crust or metasomatized mantle. The origin of sulfur remains unresolved; however, given the extremely low S solubility of rhyolite melts in the shallow crust we favor the possibility that another source of S might supplement or account for that present in the ore deposit, probably the comagmatic, mantle-derived lamprophyres that occur in minor quantities with the voluminous topaz rhyolites in the area. To account for the 437 Mt of MoS 2 (&sim;1·0 × 10 6  t Mo) present in the Henderson ore deposit, a volume of &sim;45 km 3 of Hideaway Park rhyolite magma would have been necessary to supply the Mo (a cylindrical pluton measuring 3·1 km × 6·0 km) along with sparging of &sim;6·8 × 10 5  t of S from &sim;0·05 km 3 of lamprophyre magma. Based on a weighted mean 40 Ar/ 39 Ar age of 27·58 ± 0·24 Ma, similar melt geochemistry, and characteristically F-rich biotite phenocrysts, we conclude that the Hideaway Park tuff was cogenetic with the intrusions at Red Mountain that formed the Henderson deposit.

Colorado↗

USGS2014

40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been migrating toward, and subparallel to, the northeast margin of the Colorado Plateau since the middle Miocene. Quaternary volcanism within this northern Rio Grande rift corridor is evidence that the rift is continuing to evolve.

Colorado↗

USGS1968

Mineral investigations in the Jabal Radwa quadrangle, northwest Hijaz, Saudi Arabia

Wadi sediments in the Jabal Radwa quadrangle in the Northwest Hijaz were sampled for trace element analysis as part of a mineral reconnaissance of Western Saudi Arabia that is being made by the Ministry of Petroleum and Mineral Resources and the U.S. Geological Survey. The Jabal Radwa quadrangle lies between 24?30? and 25?N. latitude and between 38? and 39? longitude. A photomosaic base at a scale of 1:100,000 was used for map compilation. Except for basalt flows of Tertiary or Quaternary age all the rocks of the area are believed to be of Precambrian age. An older group of slightly metamorphosed mafic and felsic volcanic rocks with interbedded metasedimentary rocks is unconformably overlain by argillite and slightly metamorphosed sandstone and conglomerate. The bedded rocks are cut by many intrusions that range in composition from olivine gabbro to syenite but are predominantly granite, granodiorite, and diorite. Little is known of the structure of the rocks. The layered rocks are strongly folded and commonly dip at high angles. Faults are common and many appear to be large; some contacts have been offset several hundred meters. Most of the larger faults trend northeasterly or northwesterly but some trend east and others nearly north.

Open-File Report↗

USGS1988

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Tulare Lake bed area, southern San Joaquin Valley, California, 1986-87

Concentrations of numerous toxic trace elements and pesticides were measured during 1986 in water, sediment, and biota from three areas near the Tulare Lake Bed, southern San Joaquin Valley, California: Kern National Wildlife Refuge, Pixley National Wildlife Refuge, and Westfarmers evaporation ponds about 5 mi west of Kern National Wildlife Refuge, to determine whether toxic constituents in agricultural-irrigation drainage pose a threat to beneficial uses of water, especially to uses by wildlife. Pesticide residues were found to be low at all three areas. Trace element concentrations were found to be comparatively low at the Kern and Pixley National Wildlife Refuge areas and high at the Westfarmers evaporation ponds. Dissolved selenium concentrations were < 1 micrograms/L (ug/L) in areas on and adjacent to the refuges, but ranged from 110 to 360 ug/L in the saline drainwater impounded in the evaporation ponds. The ratio of mean selenium concentrations in biota from Westfarmers ponds compared to biota from Kesterson National Wildlife Refuge (where adverse effects have been documented) is 5 for waterboatman, 2 for avocet liver, 1 for avocet eggs, and < 1 for widgeongrass. The low concentrations measured at Kern and Pixley National Wildlife Refuges suggest that trace elements and pesticides pose little threat to wildlife there; however, impounded subsurface drainage from agricultural irrigation does pose a threat to wildlife at the nearby Westfarmers ponds. Preliminary results of surveys conducted in 1987 indicated that there are adverse biological effects on shorebirds nesting at the ponds, although interpretation of the magnitude of the effects is premature, pending completion of ongoing studies by the U.S. Fish and Wildlife Service. (Author 's abstract)

Water-Resources Investigations Report↗

USGS1998

Trace-element enrichment in streambed sediment and crayfish, Carson and Truckee rivers, Nevada and California, September 1992

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Water-Resources Investigations Report↗

USGS2003

Sediment deposition and occurrence of selected nutrients, other chemical constituents, and diatoms in bottom sediment, Perry Lake, northeast Kansas, 1969–2001

A combination of bathymetric surveying and bottom-sediment coring was used to investigate sediment deposition and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 26 metals and trace elements, 15 organochlorine compounds, 1 radionuclide, and diatoms in bottom sediment of Perry Lake, northeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1969 through 2001 in the original conservation-pool area of the lake was 2,470 million cubic feet (56,700 acre-feet) and 97,200 million pounds (44,100 million kilograms), respectively. The estimated sediment volume occupied about 23 percent of the original conservation-pool, water-storage capacity of the lake. Mean annual net sediment deposition since 1969 was estimated to be 3,040 million pounds (1,379 million kilograms). Mean annual sediment yield from the Perry Lake Basin was estimated to be 2,740,000 pounds per square mile (4,798 kilograms per hectare). The estimated mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Perry Lake were 7,610,000 pounds per year (3,450,000 kilograms per year) and 3,350,000 pounds per year (1,520,000 kilograms per year), respectively. The estimated mean annual yields of total nitrogen and total phosphorus from the Perry Lake Basin were 6,850 pounds per square mile per year (12.0 kilograms per hectare per year) and 3,020 pounds per square mile per year (5.29 kilograms per hectare per year), respectively. A statistically significant positive trend for total nitrogen deposition in the bottom sediment of Perry Lake was indicated. However, the trend may be due solely to analytical variance. No statistically significant trend for total phosphorus deposition was indicated. Overall, the transport and deposition of these constituents have been relatively uniform throughout the history of Perry Lake. On the basis of nonenforceable sediment-quality guidelines established by the U.S. Environmental Protection Agency, concentrations of arsenic, chromium, copper, and nickel in the bottom sediment of Perry Lake typically exceeded the threshold-effects levels, which represent the concentrations above which toxic biological effects occasionally occur. Most nickel concentrations also exceeded the probable-effects level, which represents the concentration above which toxic biological effects usually or frequently occur. Sediment concentrations of metals and trace elements were relatively uniform over time. Statistically significant positive depositional trends for arsenic and manganese and statistically significant negative depositional trends for beryllium, chromium, titanium, and vanadium were indicated. However, the trends may be due solely to analytical variance. Organochlorine compounds either were not detected or were detected at concentrations less than the threshold-effects levels. Evidence of a negative depositional trend for DDE (degradation product of DDT) was consistent with the history of DDT use. Other organochlorine compounds detected were DDD and dieldrin. Diatom occurrence in the bottom sediment of Perry Lake was dominated by species that are indicators of eutrophic (nutrient-rich) conditions. Thus, it was concluded that eutrophic conditions have existed during much of the history of Perry Lake. However, an increase in the relative percentage abundance of the oligotrophic (nutrient-poor) species, combined with the significant positive depositional trends for two oligotrophic species ( Aulacoseira islandica and Cyclotella radiosa ) and the significant negative depositional trend for one eutrophic species ( Stephanodiscus niagarae ), indicated that conditions in Perry Lake may have become less eutrophic in recent years. Notable changes in human activity within the basin included a substantial decrease in alfalfa production and a substantial increase in soybean production from 1965 to 2000. These and other changes in human activity may have had some effect on the deposition of chemical constituents and diatoms in the bottom sediment of Perry Lake. It is uncertain whether changes in human activity may account, in part, for the possibility of Perry Lake becoming less eutrophic over time as indicated by trends in the deposition of several diatom species in the lake-bed sediment.

Kansas↗

USGS1997

Summary of information on aquatic biota and their habitats in the Willamette Basin, Oregon, through 1995

Available information on aquatic biota of the Willamette Basin was reviewed and summarized to describe current and historical conditions as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Biological parameters emphasized include the status, distribution, and trends of aquatic biota, particularly algae, macroinvertebrates, and fish; the condition of aquatic and riparian habitat in which these biota reside; and the response of these biota to natural and human-associated impacts, including the level, type, and effect of contaminants. Considerable data are available on aquatic biota in the Willamette Basin, although the information is highly uneven relative to taxa and spatial scope. Extensive information exists for high-profile taxa, such as salmonid fishes, but less information is available for macroinvertebrates, and relatively little data exist for algae. Additionally, some areas such as the H.J. Andrews Experimental Forest and the main stem Willamette River have been extensively studied, whereas data are limited for many other areas. The basin supports a diverse aquatic macroinvertebrate fauna. Available data indicate a relatively high diversity of taxa and a high richness of Ephemeroptera, Plecoptera, Trichoptera (EPT) taxa in the upper reaches of the basin. In the lower main stem reaches, macroinvertebrate assemblages are dominated by pollution tolerant organisms and those adapted to low dissolved oxygen levels. Most of the limited data on algae are from sampling in the main stem Willamette River. Diatoms and blue-green algae are the dominant algal forms. Approximately 61 fish species occur in the basin, although nearly half are introduced. Species richness and distribution are highly correlated with elevation, stream gradient, and water temperature. High elevation, cold water, mountain streams are characterized by a few species of salmonids, sculpins, suckers, and whitefish. Low elevation, main stem reaches of major rivers and streams are dominated by warm water species, such as bass, catfish, and several species in the pan fish group. The only species of fish listed as threatened or endangered is the Oregon chub (Oregonichthys crameri). The effect of an expanding human presence in the Willamette Basin has substantially altered aquatic and riparian habitats, and the biota that use or reside in these habitats. Construction of dams, channelization and bank stabilization of rivers, species introductions, supplementations of fisheries through aquaculture, timber harvesting, agricultural activities, and urbanization have contributed to changes in aquatic habitats and biota from historical conditions. Aquatic toxicological investigations in the basin have focused primarily on fish. These studies have addressed chlorinated pesticides, polychlorinated biphenyls (PCBs), dioxins and furans, polycyclic aromatic hydrocarbons (PAHs), and trace elements in aquatic tissue, as well as fish health assessments, skeletal abnormalities, and aquatic toxicological responses. Several pesticides exceeded U.S. Environmental Protection Agency and State water-quality criteria for the protection of aquatic life. Elevated PCB, dioxin, and furan concentrations were associated with point sources, such as pulp and paper mills. Elevated concentrations of mercury in aquatic tissue were associated with several reservoirs. Fish health assessments and skeletal abnormality studies detected high levels of abnormalities in fish from the main stem Willamette River. Few investigations have examined aquatic toxicological responses, such as enzyme induction assays, growth assays, and biomarker studies.

Oregon↗

USGS1973

Inorganic chemical investigation by x-ray fluorescence analysis: The Viking Mars Lander

The inorganic chemical investigation added in August 1972 to the Viking Lander scientific package will utilize an energy-dispersive X-ray fluorescence spectrometer in which four sealed, gas-filled proportional counters will detect X-rays emitted from samples of the Martian surface materials irradiated by X-rays from radioisotope sources ( 55 Fe and 109 Cd). The output of the proportional counters will be subjected to pulse-height analysis by an on-board step-scanning single-channel analyzer with adjustable counting periods. The data will be returned to Earth, via the Viking Orbiter relay system, and the spectra constructed, calibrated, and interpreted here. The instrument is inside the Lander body, and samples are to be delivered to it by the Viking Lander Surface Sampler. Calibration standards are an integral part of the instrument. The results of the investigation will characterize the surface materials of Mars as to elemental composition with accuracies ranging from a few tens of parts per million (at the trace-element level) to a few percent (for major elements) depending on the element in question. Elements of atomic number 11 or less are determined only as a group, though useful estimates of their individual abundances maybe achieved by indirect means. The expected radiation environment will not seriously hamper the measurements. Based on the results, inferences can be drawn regarding (1) the surface mineralogy and lithology; (2) the nature of weathering processes, past and present, and the question of equilibrium between the atmosphere and the surface; and (3) the extent and type of differentiation that the planet has undergone. The Inorganic Chemical Investigation supports and is supported by most other Viking Science investigations.

Icarus↗

USGS2002

Relations of benthic macroinvertebrates to concentrations of trace elements in water, streambed sediments, and transplanted bryophytes and stream habitat conditions in nonmining and mining areas of the upper Colorado River basin, Colorado, 1995-98

Intensive mining activity and highly mineralized rock formations have had significant impacts on surface-water and streambed-sediment quality and aquatic life within the upper reaches of the Uncompahgre River in western Colorado. A synoptic study by the U.S. Geological Survey National Water-Quality Assessment Program was completed in the upper Uncompahgre River Basin in 1998 to better understand the relations of trace elements (with emphasis on aluminum, arsenic, copper, iron, lead, and zinc concentrations) in water, streambed sediment, and aquatic life. Water-chemistry, streambed-sediment, and benthic macroinvertebrate samples were collected during low-flow conditions between October 1995 and July 1998 at five sites on the upper Uncompahgre River, all downstream from historical mining, and at three sites in drainage basins of the Upper Colorado River where mining has not occurred. Aquatic bryophytes were transplanted to all sites for 15 days of exposure to the water column during which time field parameters were measured and chemical water-quality and benthic macroinvertebrate samples were collected. Stream habitat characteristics also were documented at each site. Certain attributes of surface-water chemistry among streams were significantly different. Concentrations of total aluminum, copper, iron, lead, and zinc in the water column and concentrations of dissolved aluminum, copper, and zinc were significantly different between nonmining and mining sites. Some sites associated with mining exceeded Colorado acute aquatic-life standards for aluminum, copper, and zinc and exceeded Colorado chronic aquatic-life standards for aluminum, copper, iron, lead, and zinc. Concentrations of copper, lead, and zinc in streambed sediments were significantly different between nonmining and mining sites. Generally, concentrations of arsenic, copper, lead, and zinc in streambed sediments at mining sites exceeded the Canadian Sediment Quality Guidelines probable effect level (PEL), except at two mining sites where concentrations of copper and zinc were below the PEL. Concentrations of arsenic, copper, iron, and lead in transplanted bryophytes were significantly different between nonmining and mining sites. Bioconcentration factors calculated for 15-day exposure using one-half of the minimum reporting level were significantly different between nonmining and mining sites. In general, concentrations of trace elements in streambed sediment and transplanted bryophytes were more closely correlated than were the concentrations of trace elements in the water column with streambed sediments or concentrations in the water column with transplanted bryophytes. Stream habitat was rated as optimal to suboptimal using the U.S. Environmental Protection Agency Rapid Bioassessment Protocols for all sites in the study area. Generally, stream habitat conditions were similar at nonmining compared to mining sites and were suitable for diverse macroinvertebrate communities. All study sites had optimal instream habitat except two mining sites with suboptimal instream habitat because of disturbances in stream habitat. The benthic macroinvertebrate community composition at nonmining sites and mining sites differed. Mining sites had significantly lower total abundance of macroinvertebrates, fewer numbers of taxa, and lower dominance of Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies), and a larger percentage of tolerant species than did nonmining sites. The predominance of Baetis sp. (mayflies), Hydropsychidae (caddisflies), and large percentage of Orthocladiinae chironomids (midges) at mining sites indicated that these species may be tolerant to elevated trace-element concentrations. The absence of Heptageniidae (mayflies), Chloroperlidae (stoneflies), and Rhyacophila sp. (caddisflies) at mining sites indicated that these species may be sensitive to elevated trace-element concentrations. Comparison of field parameters and

Water-Resources Investigations Report↗

USGS2005

Temporal changes in water quality at a childhood leukemia cluster

Since 1997, 15 cases of acute lymphocytic leukemia and one case of acute myelocytic leukemia have been diagnosed in children and teenagers who live, or have lived, in an area centered on the town of Fallon, Nevada. The expected rate for the population is about one case every five years. In 2001, 99 domestic and municipal wells and one industrial well were sampled in the Fallon area. Twenty-nine of these wells had been sampled previously in 1989. Statistical comparison of concentrations of major ions and trace elements in those 29 wells between 1989 and 2001 using the nonparametric Wilcoxon signed-rank test indicate water quality did not substantially change over that period; however, short-term changes may have occurred that were not detected. Volatile organic compounds were seldom detected in ground water samples and those that are regulated were consistently found at concentrations less than the maximum contaminant level (MCL). The MCL for gross-alpha radioactivity and arsenic, radon, and uranium concentrations were commonly exceeded, and sometimes were greatly exceeded. Statistical comparisons using the nonparametric Wilcoxon rank-sum test indicate gross-alpha and -beta radioactivity, arsenic, uranium, and radon concentrations in wells used by families having a child with leukemia did not statistically differ from the remainder of the domestic wells sampled during this investigation. Isotopic measurements indicate the uranium was natural and not the result of a 1963 underground nuclear bomb test near Fallon. In arid and semiarid areas where trace-element concentrations can greatly exceed the MCL, household reverse-osmosis units may not reduce their concentrations to safe levels. In parts of the world where radon concentrations are high, water consumed first thing in the morning may be appreciably more radioactive than water consumed a few minutes later after the pressure tank has been emptied because secular equilibrium between radon and its immediate daughter progeny is attained in pressure tanks overnight.

Ground Water↗

USGS1950

Interim report of geologic investigation Lost Creek schroekingerite deposits Sweetwater County, Wyoming

No abstract available.

Wyoming↗

USGS1951

Electrical resistivity investigations of carnotite deposits in the Colorado Plateau

No abstract available.

Arizona;Colorado;New Mexico;Utah↗

USGS2006

Particle-associated contaminants in street dust, parking lot dust, soil, lake-bottom sediment, and suspended and streambed sediment, Lake Como and Fosdic Lake watersheds, Fort Worth, Texas, 2004

A previous study by the U.S. Geological Survey of impaired water bodies in Fort Worth, Texas, reported elevated but variable concentrations of particle-associated contaminants (PACs) comprising chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, and trace elements in suspended and bed sediment of lakes and streams affected by urban land use. The U.S. Geological Survey, in cooperation with the City of Fort Worth, collected additional samples during October 2004 to investigate sources of PACs in the watersheds of two impaired lakes: Lake Como and Fosdic Lake. Source materials and aquatic sediment were sampled and analyzed for PACs. Source materials sampled consisted of street dust and soil from areas with residential and commercial land use and parking lot dust from sealed and unsealed parking lots. Aquatic sediment sampled consisted of bottom-sediment cores from the two lakes and suspended and streambed sediment from the influent stream of each lake. Samples were analyzed for chlorinated hydrocarbons (organochlorine pesticides and polychlorinated biphenyls), polycyclic aromatic hydrocarbons, major and trace elements, organic carbon, grain size, and radionuclides.

Texas↗

USGS2009

Relative spatial soil geochemical variability along two transects across the United States and Canada

To support the development of protocols for the proposed North American Soil Geochemical Landscapes project, whose objective is to establish baselines for the geochemistry of North American soils, two continental-scale transects across the United States and Canada were sampled in 2004. The sampling employed a spatially stratified random sampling design in order to estimate the variability between 40-km linear sampling units, within them, at sample sites, and due to sample preparation and analytical chemical procedures. The 40-km scale was chosen to be consistent with the density proposed for the continental-scale project. The two transects, north–south (N–S) from northern Manitoba to the USA–Mexico border near El Paso, Texas, and east–west (E–W) from the Virginia shore north of Washington, DC, to north of San Francisco, California, closely following the 38th parallel, have been studied individually. The purpose of this study was to determine if statistically significant systematic spatial variation occurred along the transects. Data for 38 major, minor and trace elements in A- and C-horizon soils where less than 5% of the data were below the detection limit were investigated by Analysis of Variance (ANOVA). A total of 15 elements (K, Na, As, Ba, Be, Ce, La, Mn, Nb, P, Rb, Sb, Th, Tl and W) demonstrated statistically significant ( p <0.05) variability at the between-40-km scale for both horizons along both transects. Only Cu failed to demonstrate significant variability at the between-40-km scale for both soil horizons along both transects. The patterns of relative variability differ by transect and horizon. The N–S transect A-horizon soils show significant between-40-km scale variability for 29 elements, with only 4 elements (Ca, Mg, Pb and Sr) showing in excess of 50% of their variability at the within-40-km and ‘at-site’ scales. In contrast, the C-horizon data demonstrate significant between-40-km scale variability for 26 elements, with 21 having in excess of 50% of their variability at the within-40-km and ‘at-site’ scales. In 36 instances, the ‘at-site’ variability is statistically significant in terms of the sample preparation and analysis variability. It is postulated that this contrast between the A- and C- horizons along the N–S transect, that is dominated by agricultural land uses, is due to the local homogenization of Ap-horizon soils by tillage reducing the ‘at-site’ variability. The spatial variability is distributed similarly between scales for the A- and C-horizon soils of the E–W transect. For all elements, there is significant variability at the within-40-km scale. Notwithstanding this, there is significant between-40-km variability for 28 and 20 of the elements in the A- and C-horizon data, respectively. The differences between the two transects are attributed to (1) geology, the N–S transect runs generally parallel to regional strikes, whereas the E–W transect runs across regional structures and lithologies; and (2) land use, with agricultural tillage dominating along the N–S transect. The spatial analysis of the transect data indicates that continental-scale maps demonstrating statistically significant patterns of geochemical variability may be prepared for many elements from data on soil samples collected on a 40 x 40 km grid or similar sampling designs resulting in a sample density of 1 site per 1600 km 2 .

Applied Geochemistry↗