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At least 793 records · Page 44Linked to original sources

Fresh-water cementation of a 1,000-year-old oolite

Calcite cementation of aragonite ooid sand is producing oolite on Joulters Cays, Bahamas. During the last 1,000 years, calcite cement has formed at an average rate of between 27 and 55 cm 3 /m 3 /yr and is derived from dissolution of ooid aragonite in fresh water. The dissolution-reprecipitation of carbonate minerals in the aquifer results in ground waters of unusually high Sr content. Sea water and mixtures of fresh and sea water appear to inhibit cementation. A pronounced cement fabric change occurs across the water table and has produced an obvious petrographic record of fresh-water diagenesis. Above the water table, cement is typically near grain contact positions, where water is held by capillarity; below the water table, cement is more randomly distributed around grains. At the water table a transition zone, 1 meter thick, marks the boundary between cement textures. No porosity reduction is associated with cementation; calcite cement precipitation is apparently compensated by an equal or greater amount of aragonite dissolution in the interval undergoing cementation. Permeability is more variable above the water table than below it, reflecting early channelling of flow patterns in the vadose zone. Effective permeability below the water table is one to two orders of magnitude higher than above the water table because of entrained gas in the vadose zone. This permeability difference promotes preservation of unstable minerals above the water table and continued diagenetic alteration below the water table.

Joulters Cays↗

Ancient Martian aeolian processes and palaeomorphology reconstructed from the Stimson formation on the lower slope of Aeolis Mons, Gale crater, Mars

Reconstruction of the palaeoenvironmental context of Martian sedimentary rocks is central to studies of ancient Martian habitability and regional palaeoclimate history. This paper reports the analysis of a distinct aeolian deposit preserved in Gale crater, Mars, and evaluates its palaeomorphology, the processes responsible for its deposition, and its implications for Gale crater geological history and regional palaeoclimate. Whilst exploring the sedimentary succession cropping out on the northern flank of Aeolis Mons, Gale crater, the Mars Science Laboratory rover Curiosity encountered a decametre‐thick sandstone succession, named the Stimson formation, unconformably overlying lacustrine deposits of the Murray formation. The sandstone contains sand grains characterized by high roundness and sphericity, and cross‐bedding on the order of 1 m in thickness, separated by sub‐horizontal bounding surfaces traceable for tens of metres across outcrops. The cross‐beds are composed of uniform thickness cross‐laminations interpreted as wind‐ripple strata. Cross‐sets are separated by sub‐horizontal bounding surfaces traceable for tens of metres across outcrops that are interpreted as dune migration surfaces. Grain characteristics and presence of wind‐ripple strata indicate deposition of the Stimson formation by aeolian processes. The absence of features characteristic of damp or wet aeolian sediment accumulation indicate deposition in a dry aeolian system. Reconstruction of the palaeogeomorphology suggests that the Stimson dune field was composed largely of simple sinuous crescentic dunes with a height of ca 10 m, and wavelengths of ca 150 m, with local development of complex dunes. Analysis of cross‐strata dip‐azimuths indicates that the general dune migration direction and hence net sediment transport was towards the north‐east. The juxtaposition of a dry aeolian system unconformably above the lacustrine Murray formation represents starkly contrasting palaeoenvironmental and palaeoclimatic conditions. Stratigraphic relationships indicate that this transition records a significant break in time, with the Stimson formation being deposited after the Murray formation and stratigraphically higher Mount Sharp group rocks had been buried, lithified and subsequently eroded.

Sedimentology↗

A speculative history of the San Andreas fault in the central Transverse Ranges, California

It is generally accepted that the San Andreas fault formed between 4 and 5 Ma and that rocks west of it are now part of the Pacific plate, moving northwest relative to North America at 5 to 6 cm/yr. This model is inconsistent with the geologic record in the central Transverse Ranges. Right-lateral shear began in the vicinity of the San Andreas fault system in early Miocene time. The San Andreas fault system in the central Transverse Ranges has since evolved through three major phases; this development has led to a generally simpler, more throughgoing main trace. Slip rates on the San Andreas system were about 1 cm/yr in the Miocene, increasing to their current level of 3.5 cm/yr between 4 and 5 Ma. The modern San Andreas fault still only accounts for just over half the current relative plate rate and retains kinematic complexities inherited from its earliest geometry. The Early San Andreas transform system originated during early Miocene time in one of three transtensive zones that lay interior to the continent and east of the locus of transform motion between the Pacific and North American plates. The current three-fold division of motion in the plate boundary between the San Andreas fault, a coastal system, and an eastern California system dates to this time, as does the “anomalous” trend of the San Andreas fault through the Transverse Ranges. Basins and volcanic centers associated with this transtensive zone became dismembered as faults became integrated into a throughgoing system. Early motion led to juxtaposition of different rocks across faults now recognized as part of the Early San Andreas transform system, and to the development of sedimentary provincialism associated with uplift along the fault zone. Middle Miocene basins, including the Caliente, Cajon, Crowder, and Santa Ana basins that had previously received most of their sediments from sources far to the east, began to reflect local Transverse Ranges provenance. At least 100 km of slip is associated with the Early San Andreas transform system during early and middle Miocene time. Slip across the geometrically complex late Miocene San Gabriel transform system—which includes the San Gabriel, Cajon Valley, and early Punchbowl faults—produced uplift in the proto-Transverse Ranges at a postulated restraining bend in the fault system. Compressional structures associated with this restraining bend include the Squaw Peak and Liebre Mountain thrusts, related east-striking late Miocene reverse faults and folds, and, perhaps, northeast-striking left-lateral faults in the San Gabriel Mountains. Narrow fault-controlled basins formed during this period, including the Ridge basin, Devil’s Punchbowl basin, Mill Creek basin, and part of the Santa Ana Sandstone basin. Offset of structures and relief associated with the proto-Transverse Ranges provides the best evidence for late Miocene restorations of the modern San Andreas fault. As much as 60 km of offset is associated with the late Miocene San Gabriel transform system. Between 4 and 5 Ma, the modern San Andreas fault became the dominant member of the plate boundary system, cutting through the proto-Transverse Ranges and connecting more northerly striking traces to the north and south. The slip rate across the San Andreas fault system accelerated from 1 cm/yr to its current slip rate of 3.5 cm/yr prior to 4 Ma. The Pliocene rocks in the central Transverse Ranges do not contain evidence for relief as great as that of late Miocene or Quaternary time. The Pliocene trace of the modern San Andreas fault may have temporarily “solved” the geometric problem that led to late Miocene uplift. About 90 km of right-lateral displacement occurred on the modern San Andreas fault during Pliocene time. During Quaternary time new regions of localized vertical deformation developed in the Transverse Ranges, apparently as the result of new geometric problems within the Pliocene solution to the restraining geometry of the fault system. Left-lateral motion on east-striking faults, probably due to a northward increase in Basin and Range extension, kinked the San Andreas fault at both ends of the Transverse Ranges, producing regions of extreme shortening and uplift. The development of young right-lateral faults through the Peninsular Ranges, including the San Jacinto and Elsinore faults, also contributed to renewed uplift in the Transverse Ranges. Sixty kilometers of right-lateral slip occurred across the San Andreas fault zone during Quaternary time.

California↗

Reduced injection rates and shallower depths mitigated induced seismicity in Oklahoma

The proximity of wastewater disposal to the Precambrian basement is a critical factor influencing induced earthquake rates in the Central United States, but the impact of reducing injection depths has not been widely demonstrated. Beginning in 2015, state regulatory efforts in Oklahoma and Kansas mandated that wells injecting into the lower Arbuckle Group, a basal sedimentary unit, be backfilled with cement (i.e. “plugged back”) so that they inject into shallower formations. This plug back activity gives us a unique opportunity to investigate the relationship between injection depth and induced seismicity rate. To evaluate the impact that decreased injection rates and plug backs had on the seismicity rates, we create a suite of rate-state earthquake models. Observed seismicity rates are best fit when only lower Arbuckle volumes are considered, suggesting the lower Arbuckle injectors were primarily responsible for the seismicity and that plug backs were effective at isolating the injected volumes to shallower formations. Our models demonstrate that if these wells had not been plugged back, seismicity rates would be multiple times larger than they are today. We find that the combination of well plug backs and injection volume decreases can be effective strategies for reducing induced seismicity rates.

Oklahoma↗

Significance of the precambrian basement and late Cretaceous thrust nappes on the location of tertiary ore deposits in the Oquirrh Mountains, Utah

The Oquirrh Mountains are located in north central Utah, in the easternmost part of the Basin and Range physiographic province, immediately south of the Great Salt Lake. The range consists of a northerly trending alignment of peaks 56 km long. Tooele and Rush Valleys flank the Oquirrh Mountains on the western side and Salt Lake and Cedar Valleys lie on the eastern side. The world class Bingham mine in the central part of the range hosts disseminated copper-bearing porphyry, skarn, base-and precious-metal vein and replacement ore deposits. The district includes the outlying Barneys Canyon disseminated-gold deposits. Disseminated gold in the Mercur mining district in the southern part of the range has become exhausted. The Ophir and Stockton base- and precious-metal mining districts in the range north of Mercur also are inactive. A geologic map of the range (Tooker and Roberts, 1998), available at a scale of 1:50,000, is a summation of U.S. Geological Survey (USGS) studies. Information about the range and its mining areas is scattered. This report summarizes map locations, new stratigraphic and structural data, and reexamined data from an extensive published record. Unresolved controversial geological interpretations are considered, and, for the first time, the complete geological evidence provides a consistent regional basis for the location of the ore deposits in the range. The geological setting and the siting of mineral deposits in the Oquirrh Mountains began with the formation of a Precambrian craton. Exposures of folded Proterozoic basement rocks of the craton, in the Wasatch Mountains east of Salt Lake City, were accreted and folded onto an Archean crystalline rock terrane. The accretion suture lies along the north flank of the Uinta Mountains. The western part of the accreted block was offset to northern Utah along a north-trending fault lying approximately along the Wasatch Front (Nelson and others, 2002), thereby creating a prominant basement barrier or buttress east of the Salt Lake area. The accretion suture along the north flank of the Uinta Anticline overlaps an earlier Precambrian east-west mobile zone, the Uinta trend (Erickson, 1976, Bryant and Nichols, 1988 and John, 1989), which extends westward across western Utah and into Nevada. A trace of the trend underlies the middle part of the Oquirrh Mountains. Its structure is recognized by disrupted Paleozoic stratigraphic units and fold and fault evidence of thrust faulting, intermittent local uplift and erosion, the alignment of Tertiary intrusives and associated ore deposits. Geologic readjustments along the trend continued intermittently through the Paleozoic, Cenozoic, Tertiary, and the development of clastic deposits along the shores of Pleistocene Lake Bonneville. Paleozoic sedimentary rocks were deposited on the craton platform shelf in westernmost Utah and eastern Nevada as the shelf subsided gradually and differentially. Debris was shed into two basins separated by the uplifted Uinta trend, the Oquirrh Basin on the south and Sublette Basin on the north. Sediments were derived from the craton to the east, the Antler orogenic zone on the west (Roberts, 1964), and locally from uplifted parts of the trend itself. Thick accumulations of clastic calcareous quartzite, shale, limestone, and dolomite of Lower and Upper Paleozoic ages are now exposed in the Oquirrh Mountains, the result of thrust faults. Evidence of decollement thrust faults in in the Wasatch Mountains during the Late Cretaceous Sevier orogeny, recognized by Baker and others (1949) and Crittenden (1961, is also recognized in the Oquirrh Mountains by Roberts and others (1965). During the late Cretaceous Sevier Orogeny, nappes were thrust sequentially along different paths from their western hinterland to the foreland. Five distinct nappes converged over the Uinta trend onto an uplifted west-plunging basement buttress east of the Oquirrh Mountains area: the Pass Canyon, Bingham,

Scientific Investigations Report↗

Rippled scour depressions on the inner continental shelf off central California

Side-scan sonar records taken during the recent Coastal Ocean Dynamics Experiment (CODE) show elongate, shore-normal rippled depressions of low relief on the inner continental shelf off central California between Bodega Bay and Point Arena. These features extend up to 2 km from the coast into water depths of up to 65 m. The proposed mechanism for their generation is storm-generated bottom currents associated with coastal downwelling during the late fall and winter which scour the surficial fine-sand sediment and expose the coarser-sand substrate in the depressions. The zones of most intense erosion and the irregular spacing of the features may be controlled by submerged rock ledges and other prominent coastal features. The large straight-crested ripples within the depressions (heights to 40 cm; wavelengths to 1.7 m) are probably formed by large-amplitude, long-period surface waves generated by winter storms.

California↗

Timing and nature of tertiary plutonism and extension in the Grouse Creek Mountains, Utah

The Grouse Creek -Albion-Raft River metamorphic core complex in northwestern Utah and southern Idaho is characterized by several Tertiary plutons with a range of ages and crosscutting relations that help constrain the timing of extensional deformation. In the Grouse Creek Mountains , at least three distinct, superimposed, extension -related Tertiary deformational events are bracketed by intrusive rocks, followed by a fourth event: motion on range-bounding faults. The Emigrant Pass plutonic complex was emplaced at depths of less than 10 km into Permianage rocks. SHRIMP U-Pb zircon analysis indicates a three-stage intrusion of the complex at 41.3 ± 0.3 Ma, 36.1 ± 0.2 Ma, and 34.3 ± 0.3 Ma. The two youngest phases represent distinctly younger intrusive event(s) than the oldest phase, separated by more than 5 m.y. The oldest phase cuts several metamorphosed and deformed younger-on-older faults, providing a pre-41 Ma age bracket for oldest extension -related deformation in the region. The youngest phase(s) are interpreted to have been intruded during development of a map-scale, N-S-trending recumbent fold, the Bovine Mountain fold, formed during vertical shortening of roof rocks during intrusion. This second event folded older normal faults that are likely pre-41 Ma. Zircons from the youngest part of the pluton show inheritance from Archean basement (~2.5 Ga) and from its Proterozoic sedimentary cover (~1.65 Ga). The Red Butte pluton, emplaced at 15-20 km depth, intruded highly metamorphosed Archean orthogneiss at 25.3 ± 0.5 Ma; cores of some zircons yield latest Archean ages of 2.55 Ga. The pluton is interpreted to have been intruded during a third deformational and metamorphic event that resulted in vertical flattening fabrics formed during NW to EW stretching, ultimately leading to thinning of cover and top-to-the west motion on the Ingham Pass fault. The Ingham Pass fault represents an important structure in the Grouse Creek Mountains , as it juxtaposes two parts of the crust that apparently resided as much as 10 km apart ( in depth) at times as young as the Miocene. The varied structural, metamorphic, and intrusive relations observed in the Grouse Creek Mountains reflect their formation at different levels within the crust. Data from these various levels argue that plutonism has been a key mechanism for transferring heat into the middle and upper crust, and localizing strain during regional extension . Interestingly, events documented here correlate in a broad way with cooling events documented in the Raft River Mountains , although plutons are not exposed there. Major and trace element geochemistry imply a crustal component in all of the studied plutons, indicating significant degrees of crustal melting at depth during extension , and point to mantle heat sources during the timespan of Basin and Range extension as the cause of melting. Basin and Range faulting and final uplift of the range is recorded by apatite fission track ages, averaging 13.4 Ma, and deposition of about 2 km of syn-faulting basin fill deposits along the Grouse Creek fault mapped along the western flank of the range. Similar apatite ages from the Albion Mountains to the north indicate that the western side of the Albion-Raft River- Grouse Creek core complex behaved as a single rigid crustal block at this time.

Utah↗

Time-slice maps showing age, distribution, and style of deformation in Alaska north of 60° N.

The structural architecture of Alaska is the product of a complex history of tectonism that occurred along the Cordilleran and Arctic margins of North America through interactions with ancient and modern ocean plates and with continental elements derived from Laurentia, Siberia, and Baltica. To unravel the tectonic history of Alaska, we constructed maps showing the age, distribution, structural style, and kinematics of contractional and penetrative extensional deformation in Alaska north of latitude 60° N. at a scale of 1:5,000,000. These maps use the Geologic Map of the Arctic (Harrison and others, 2011) as a base map and follow the guidelines in the Tectonic Map of the Arctic project (Petrov and others, 2013) for construction, including use of the International Commission on Stratigraphy time scale (Cohen and others, 2013) divided into 20 time intervals. We find evidence for deformation in 14 of the 20 time intervals and present maps showing the known or probable extent of deformation for each time interval. Maps and descriptions of deformational style, age constraints, kinematics, and information sources for each deformational episode are discussed in the text and are reported in tabular form. This report also contains maps showing the lithologies and structural geology of Alaska, a terrane map, and the distribution of tectonically important units including post-tectonic sedimentary basins, accretionary complexes, ophiolites, metamorphic rocks. These new maps show that most deformational belts in Alaska are relatively young features, having developed during the late Mesozoic and Cenozoic. The oldest episode of deformation recognized anywhere in Alaska is found in the basement of the Farewell terrane (~1.75 Ga). Paleozoic and early Mesozoic deformational events, including Devonian deformation in the Arctic Alaska terrane, Pennsylvanian deformation in the Alexander terrane, Permian deformation in the Yukon Composite (Klondike orogeny) and Farewell terranes (Browns Fork orogeny), Early and Late Jurassic deformation in the Peninsular-Wrangellia terranes, and Early Cretaceous deformation in northern Alaska (early Brookian orogeny) show that within-terrane amalgamation events occurred prior to assembly of Alaska. Widespread episodes of deformation in the Late Cretaceous and early Cenozoic, in contrast, affected multiple terranes, indicating they occurred during or following the time of assembly of most of Alaska. The primary deformational event in northern Alaska was the Late Jurassic and Early Cretaceous (early) Brookian orogeny, which affected most terranes north and west of the early Cenozoic Tintina, Victoria Creek, Kaltag, and Poorman dextral-slip faults in central Alaska. In southern Alaska, formation of the southern Alaska accretionary complex (Chugach, Prince William, Yakutat terranes) and associated magmatism in the Peninsular-Wrangellia terrane began near the Triassic-Jurassic boundary and continued episodically throughout the remainder of the Mesozoic and the Cenozoic. The collision of these terranes with the Farewell and Yukon Composite terranes in central Alaska is recorded by contractional deformation that emanated from the intervening basins in the Late Cretaceous. The boundary between northern and central Alaska is constrained to late Early Cretaceous but is enigmatic and not obviously marked by contractional deformation. Early Cenozoic shortening and transpressional deformation is the most widespread event recorded in Alaska and produced the widespread late Brookian orogenic event in northern Alaska. Middle and late Cenozoic shortening and transpression is significant in southern Alaska inboard of the underthrusting Yakutat terrane at the Pacific margin subduction zone as well as in northeastern Alaska.

Alaska↗

Location of the Green Canyon (Offshore Southern Louisiana) Seismic Event of February 10, 2006

We calculated an epicenter for the Offshore Southern Louisiana seismic event of February 10, 2006 (the 'Green Canyon event') that was adopted as the preferred epicenter for the event by the USGS/NEIC. The event is held at a focal depth of 5 km; the focal depth could not be reliably calculated but was most likely between 1 km and 15 km beneath sea level. The epicenter was calculated with a radially symmetric global Earth model similar to that routinely used at the USGS/NEIC for all earthquakes worldwide. The location was calculated using P-waves recorded by seismographic stations from which the USGS/NEIC routinely obtains seismological data, plus data from two seismic exploration arrays, the Atlantis ocean-bottom node array, operated by BP in partnership with BHP Billiton Limited, and the CGG Green Canyon phase VIII multi-client towed-streamer survey. The preferred epicenter is approximately 26 km north of an epicenter earlier published by the USGS/NEIC, which was obtained without benefit of the seismic exploration arrays. We estimate that the preferred epicenter is accurate to within 15 km. We selected the preferred epicenter from a suite of trial calculations that attempted to fit arrival times of seismic energy associated with the Green Canyon event and that explored the effect of errors in the velocity model used to calculate the preferred epicenter. The various trials were helpful in confirming the approximate correctness of the preferred epicenter and in assessing the accuracy of the preferred epicenter, but none of the trial calculations, including that of the preferred epicenter, was able to reconcile arrival-time observations and assumed velocity model as well as is typical for the vast majority of earthquakes in and near the continental United States. We believe that remaining misfits between the preferred solution and the observations reflect errors in interpreted arrival times of emergent seismic phases that are due partly to a temporally extended source-time function and partly to failure of our travel-time model to account for the extremely complicated velocity structure of the sedimentary section in which the event occurred.

Open-File Report↗

Metamorphism and gold mineralization in the Blue Ridge, southernmost Appalachians

Lode gold mineralization in the Blue Ridge of the southernmost Appalachians is hosted by metavolcanic rocks (e.g., Anna Howe mine, AL; Royal Vindicator mine, GA), metaplutonic rocks (e.g., Hog Mountain mine, AL), and metasedimentary rocks (e.g., Lowe, Tallapoosa, and Jones Vein mines, AL). Most gold occurs in synkinematic quartz + or - plagioclase + or - pyrite + or - pyrrhotite + or - chlorite veins localized along polydeformational faults that juxtapose rocks with significantly different peak metamorphic mineral assemblages.Mineralogy, chemistry, and O and H isotope studies suggest that the three types of host rocks have undergone differing amounts and types of alteration during mineralization. Limited wall-rock alteration in metavolcanic- and metasediment-hosted deposits, and relatively extensive wall-rock alteration in granitoid-hosted deposits, suggests that most deposits formed from fluids that were close to equilibrium with metavolcanic and metasedimentary rocks. Stable isotope compositions of the fluids calculated from vein minerals and vein selvages are consistent with a predominantly metasedimentary fluid source, but vary from deposit to deposit (-22 to -47ppm delta D, 4-5ppm, delta 18 O, and 5-7ppm delta 34 S at Anna Howe and Royal Vindicator; -48 to -50ppm delta D, 9-13ppm delta 18 O, and ca. 19ppm delta 34 S at Lowe and Jones Vein; and -22 to -23ppm delta D, 8-11ppm delta 18 O, 9-10ppm delta 34 S, and -6 delta 13 C at Hog Mountain). Silicate mineral thermobarometry of vein, vein selvage, and wall-rock mineral assemblages indicate that mineralization and regional metamorphism occured at greenschist to amphibolite facies (480 degrees + or - 75 degrees C at Anna Howe, 535 degrees + or - 50 degrees C at 6.4 + or - 1 kbars at Lowe, 530 degrees + or - 50 degrees C at 6.9 + or - 1 kbars at Tallapoosa, and 460 degrees + or - 50 degrees C at 5.5 + or - 1 kbars at Hog Mountain). Oxygen isotope fractionation between vein minerals and selvage minerals consistently records equilibration temperatures that are similar to or slightly lower than those estimated from silicate thermometry.Auriferous veins contain numerous fluid inclusions that were emplaced in several stages and can be subdivided into five compositional types based on salt and CO 2 concentrations. Fluid inclusion isochores for early formed inclusions from these veins intercept the pressure and temperature conditions estimated from silicate mineral thermobarometry and stable isotope thermometry, and are compatible with entrapment at those conditions. These fluids exhibit significant variation in salinity (X (sub NaCl equiv ) ) = 0.0-0.2) and CO 2 (X (sub CO 2 ) = 0.0-0.2), suggesting variation in fluid-wall-rock interaction that accompanied gold deposition during declining temperatures. Less abundant and later fluids within the veins are dominantly CO 2 .The association of gold mineralization with structurally controlled concordant and discordant quartz sulfide veins, and the temperatures and pressures of wall-rock alteration and regional metamorphism indicate that the present distribution of gold is a result of metamorphism during progressive D 2 -D 3 deformation. Isotopic data for alteration envelopes date this event as Alleghanian: 279 + or - 14 Ma (K-Ar whole rock) and 343 + or - 18 Ma (K-Ar biotite) at Lowe; and 315 + or - 18 Ma (Rb-Sr whole-rock isochron; 87 Sr/ 86 Sr i = 0.7061 + or - 0.0008) and 294 + or - 16 Ma (K-Ar whole-rock) at Hog Mountain. Available data are compatible with development of the lodes during early Alleghanian overthrusting of allochthons over sedimentary rocks of the autochthonous North American margin. The implication is that the fluids were derived from metasedimentary and/or metavolcanic formations in the lower parts of the crystalline thrust stack (or possibly from underlying autochthonous sedimentary formations), ascended along permeable fault zones, and were emplaced as veins into dilatent areas in and adjacent to the fault zones.

Economic Geology↗

Sedimentary sulfur geochemistry of the Paleogene Green River Formation, western USA: Implications for interpreting depositional and diagenetic processes in saline alkaline lakes

The sulfur geochemistry of the lacustrine Paleogene Green River Formation (Colorado, Utah, and Wyoming, USA) is unlike that of most marine and other lacustrine rocks. Distinctive chemical, isotopic, and mineralogical characteristics of the formation are pyrrhotite and marcasite, high contents of iron mineral sulfides strikingly enriched in 34 S, cyclical trends in sulfur abundance and δ 34 S values, and long-term evolutionary trends in δ 34 S values. Analyses that identified and quantified these characteristics include carbonate-free abundance of organic carbon (0.13–47 wt%), total iron (0.31–13 wt%), reactive iron (>70% of total iron), total sulfur (0.02–16 wt%), acid-volatile monosulfide (S Av ), disulfide (S Di > 70% of total sulfur), sulfate (S SO 4 ) and organosulfur (S Org ); isotopic composition of separated sulfur phases (δ 34 S Di,Av up to +49‰); and mineralogy, morphology and paragenesis of sulfide minerals. Mineralogy, morphology, δ 34 S Di,Av , and δ 34 S Org have a distinctive relation, reflecting variable and unique depositional and early diagenetic conditions in the Green River lakes. When the lakes were brackish, dissimilatory sulfate-reducing bacteria in the sediment produced H 2 S, which initially reacted with labile iron to form pyrite framboids and more gradually with organic matter to form organosulfur compounds. During a long-lived stage of saline lake water, the amount of sulfate supplied by inflow decreased and alkalinity and pH of lake waters increased substantially. Extensive bacterial sulfate reduction in the water column kept lake waters undersaturated with sulfate minerals. A very high H 2 S:SO 4 ratio developed in stagnant bottom water aided by the high pH that kinetically inhibited iron sulfidization. Progressive removal of H 2 S by coeval formation of iron sulfides and organosulfur compounds caused the isotopic composition of the entire dissolved sulfur reservoir to evolve to δ 34 S values much greater than that of inflow sulfate, which is estimated to have been +20‰ A six-million-year interval within Lake Uinta cores records this evolution as well as smaller systematic changes in δ 34 S, interpreted to reflect ~ 100,000-year lake-level cycles. When porewater was exceptionally reducing, unstable FeS phases eventually recrystallized to pyrrhotite during diagenesis. A much later reaction related to weathering altered pyrrhotite to marcasite.

Geochimica et Cosmochimica Acta↗

Bedrock geologic map of the Crown Point quadrangle, Essex County, New York, and Addison County, Vermont

The bedrock geology of the 7.5-minute Crown Point quadrangle consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Granulite facies Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of granitic orthogneiss at approximately 1.18–1.15 giga-annum (Ga, billion years before present). The earliest of four phases of deformation (D1) is characterized by gneissosity, rarely preserved F1 isoclinal folds, and migmatite in the host rocks. Subsequent D2 deformation produced a composite penetrative gneissosity, migmatite, and isoclinal F2 folds. Towards the end of D2, felsic magmatism (including the regionally extensive Lyon Mountain Granite Gneiss, abbreviated “LMG”) spread by penetrative migration as semiconcordant alkali feldspar granite sheets subparallel to S2 into previously deformed lithologies. The LMG crystallized at approximately 1.15 Ga and displays synkinematic F2 folds thus constraining the time of D2 deformation. Exhumation during D3 produced F3 folds exhibited in regional domes and basins, such as the Keeney Mountain synform, local reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. D4 created NE- and NW-trending boudinage, local high-grade ductile shear zones, and crosscutting granitic pegmatite dikes. Kilometer (km)-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. The Paleozoic rocks are part of the Early Cambrian to Late Ordovician great American carbonate bank on the ancient margin of Laurentia. Cambrian-Ordovician stratigraphy records an approximately 1-km-thick section and a transition from synrift clastics to passive margin peritidal carbonate buildups to gradually deeper water subtidal to shelf carbonates during foreland basin development associated with the Taconic orogeny. The Paleozoic rocks are weakly folded and block faulted. Large areas of the Champlain Valley are covered by undifferentiated glacial deposits, some of which contain mapped landslides. The map also shows waste rock piles and tailings from historical mining operations and large areas of artificial fill. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondacks, provide a context for historical iron mines in the eastern Adirondacks, and update the stratigraphy of the Champlain Valley in New York and Vermont. This Scientific Investigations Map of the Crown Point 7.5-minute quadrangle consists of a map sheet, an explanatory pamphlet, and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information. The map sheet includes a bedrock geologic map, a correlation of map units, a description of map units, an explanation of map symbols, three cross sections, and a simplified surficial geologic map that includes lidar percent slope. The explanatory pamphlet includes a discussion of the geology. The bedrock geologic map on the map sheet is multi-layered and has been designed to enable the user to turn off the surficial map layer to view the concealed bedrock map units.

New York, Vermont↗

Mercury contamination chronologies from Connecticut wetlands and Long Island Sound sediments

Sediment cores were used to investigate the mercury deposition histories of Connecticut and Long Island Sound. Most cores show background (pre-1800s) concentrations (50–100 ppb Hg) below 30–50 cm depth, strong enrichments up to 500 ppb Hg in the core tops with lower Hg concentrations in the surface sediments (200–300 ppb Hg). A sediment core from the Housatonic River has peak levels of 1,500 ppb Hg, indicating the presence of a Hg point source in this watershed. The Hg records were translated into Hg contamination chronologies through 210 Pb dating. The onset of Hg contamination occurred in ~1840–1850 in eastern Connecticut, whereas in the Housatonic River the onset is dated at around 1820. The mercury accumulation profiles show periods of peak contamination at around 1900 and at 1950–1970. Peak Hg* (Hg*= Hg measured minus Hg background) accumulation rates in the salt marshes vary, dependent on the sediment character, between 8 and 44 ng Hg/cm 2 per year, whereas modern Hg* accumulation rates range from 4–17 ng Hg/cm 2 per year; time-averaged Hg* accumulation rates are 15 ng Hg/cm 2 per year. These Hg* accumulation rates in sediments are higher than the observed Hg atmospheric deposition rates (about 1–2 ng Hg/cm 2 per year), indicating that contaminant Hg from the watershed is focused into the coastal zone. The Long Island Sound cores show similar Hg profiles as the marsh cores, but time-averaged Hg* accumulation rates are higher than in the marshes (26 ng Hg/cm 2 a year) because of the different sediment characteristics. In-situ atmospheric deposition of Hg in the marshes and in Long Island Sound is only a minor component of the total Hg budget. The 1900 peak of Hg contamination is most likely related to climatic factors (the wet period of the early 1900s) and the 1950–1970 peak was caused by strong anthropogenic Hg emissions at that time. Spatial trends in total Hg burdens in cores are largely related to sedimentary parameters (amount of clay) except for the high inventories of the Housatonic River, which are related to Hg releases from hat-making in the town of Danbury. Much of the contaminated sediment transport in the Housatonic River Basin occurs during floods, creating distinct layers of Hg-contaminated sediment in western Long Island Sound. The drop of about 40% in Hg accumulation rates between the 1960s and 1990s seems largely the result of reduced Hg emissions and to a much lesser extent of climatic factors.

Conference Paper↗

Geology and ground-water resources of Hays County, Texas

The Edwards limestone of Early Cretaceous age is the chief aquifer for San Marcos Springs and about 160 other springs and wells in Hays County, along the Balcones fault zone in South-central Texas. Hays County is underlain by a basement of Paleozoic rocks; and in the southeastern part of the county the Hosston and Sligo formations of Early Cretaceous age, correlative with the Coahuila series of Mexico, have been encountered in the subsurface. Rocks exposed in the county are principally Cretaceous and Quaternary sedimentary units, which are assigned to the Trinity, Fredericksburg, and Washita groups in the Comanche series; the Eagle Ford shale, Austin chalk, Taylor marl, and Navarro group in the Gulf series: and the Leona formation and equivalent rocks in the Pleistocene series. Recent alluvium and colluvium locally overlie the older rocks. In addition to the Edwards limestone in the Fredericksburg group, waterbearing rock units in Hays County include the Pearsall formation (Travis Peak of outcrop areas) and the Glen Rose limestone in the Trinity group, the Austin chalk and Taylor marl, and the Quaternary rocks. The surface slope and regional dip are toward the southeast. Several normal strike faults have displaced the Cretaceous rocks downward to the southeast, the aggregate displacement being about 1,700 feet within the county. The boundaries of the Edwards limestone ground-water reservoir are formed by major faults which are the major controls of movement of water. Much of the water discharged at San Marcos Springs is derived from influent seepage from streams and infiltration from precipitation in recharge areas southwest of Hays County. The average underground inflow from Comal County through the Edwards limestone reservoir is estimated as 70,000 acre-feet per year for the period 1934-47. The discharge of San Marcos Springs, averaging about 55 million gallons a day during 1955, greatly exceeds local ground-water recharge within Hays County. Depth to water, direction of movement of water, subsurface location of aquifers, and quality of water in Hays County have been determined from records of 519 wells and springs, drillers' logs of 49 wells, periodic water-level measurements in about 70 wells, and chemical analyses of water samples from 238 wells and springs. Ground water from wells in the Pearsall formation generally contains less than 500 parts per million of dissolved solids. Water from the Glen Rose limestone in some places contains more than 500 parts per million of sulfate and more than 1,000 parts per million of dissolved solids; locally it is high in nitrate also. Except in the southeastern part of the county, water from the Edwards limestone is commonly very hard but is otherwise of good quality for most uses. Analyses of two water samples from the Austin chalk indicate a high content of bicarbonate. Water from the Taylor marl and from Quaternary sediments generally is hard, and locally it contains excessive nitrate. Most wells in Hays County are used for domestic and stock supplies. About 20 wells, most of them in the Edwards limestone, yield water in relatively large amounts for industrial use, irrigation, or public supplies.

Water Supply Paper↗

Downhill from Austin and Ely to Las Vegas: U-Pb detrital zircon suites from the Eocene–Oligocene Titus Canyon Formation and associated strata, Death Valley, California

In a reconnaissance investigation aimed at interrogating the changing topography and paleogeography of the western United States prior to Basin and Range faulting, a preliminary study made use of U-Pb ages of detrital zircon suites from 16 samples from the Eocene–Oligocene Titus Canyon Formation, its overlying units, and correlatives near Death Valley. The Titus Canyon Formation unconformably overlies Neoproterozoic to Devonian strata in the Funeral and Grapevine Mountains of California and Nevada. Samples were collected from (1) the type area in Titus Canyon, (2) the headwaters of Monarch Canyon, and (3) unnamed Cenozoic strata exposed in a klippe of the Boundary Canyon fault in the central Funeral Mountains. Red beds and conglomerates at the base of the Titus Canyon Formation at locations 1 and 2, which contain previously reported 38–37 Ma fossils, yielded mostly Sierran batholith–age detrital zircons (defined by Triassic, Jurassic, and Cretaceous peaks). Overlying channelized fluvial sandstones, conglomerates, and minor lacustrine shale, marl, and limestone record an abrupt change in source region around 38–36 Ma or slightly later, from more local, Sierran arc–derived sediment to extraregional sources to the north. Clasts of red radiolarian-bearing chert, dark radiolarian chert, and quartzite indicate sources in the region of the Golconda and Roberts Mountains allochthons of northern Nevada. Sandstones intercalated with conglomerate contain increasing proportions of Cenozoic zircon sourced from south-migrating, caldera-forming eruptions at the latitude of Austin and Ely in Nevada with maximum depositional ages (MDAs) ranging from 36 to 24 Ma at the top of the Titus Canyon Formation. Carbonate clasts and ash-rich horizons become more prevalent in the overlying conglomeratic Panuga Formation (which contains a previously dated 15.7 Ma ash-flow tuff). The base of the higher, ash-dominated Wahguyhe Formation yielded a MDA of 14.4 Ma. The central Funeral Mountains section exposes a different sequence of units that, based on new data, are correlative to the Titus Canyon, Panuga, and Wahguyhe Formations at locations 1 and 2. An ash-flow tuff above its (unexposed) base provided a MDA of 34 Ma, and the youngest sample yielded a MDA of 12.7 Ma. The striking differences between age-correlative sections, together with map-based evidence for channelization, indicate that the Titus Canyon Formation and overlying units likely represent fluvial channel, floodplain, and lacustrine deposits as sediments mostly bypassed the region, moving south toward the Paleogene shoreline in the Mojave Desert. The profound changes in source regions and sedimentary facies documented in the Titus Canyon Formation took place during ignimbrite flareup magmatism and a proposed eastward shift of the continental divide from the axis of the Cretaceous arc to a new divide in central Nevada in response to thermal uplift and addition of magma to the crust. This uplift initiated south-flowing fluvial systems that supplied sediments to the Titus Canyon Formation and higher units.

Arizona, California, Nevada, Utah↗

Early Tertiary exhumation of the flank of a forearc basin, southwest Talkeetna Mountains, Alaska

New geochronologic and thermochronologic data from rocks near Hatcher Pass, southwest Talkeetna Mountains, Alaska, record earliest Paleocene erosional and structural exhumation on the flank of the active Cook Inlet forearc basin. Cretaceous plutons shed sediments to the south, forming the Paleocene Arkose Ridge Formation. A Paleocene(?)-Eocene detachment fault juxtaposed ~60 Ma metamorphic rocks with the base of the Arkose Ridge Formation. U-Pb (analyzed by Sensitive High Resolution Ion Micro Probe Reverse Geometry (SHRIMP-RG)) zircon ages of the Cretaceous plutons, more diverse than previously documented, are 90.3±0.3 (previously considered a Jurassic unit), 79.1±1.0, 76.1±0.9, 75.8±0.7, 72.5±0.4, 71.9±0.3, 70.5±0.2, and 67.3±0.2 Ma. The cooling of these plutons occurred between 72 and 66 Ma (zircon fission track (FT) closure ~225°C). 40 Ar/ 39 Ar analyses of hornblende, white mica, and biotite fall into this range (Harlan and others, 2003). New apatite FT data collected on a west-to-east transect reveal sequential exhumation of fault blocks at 62.8±2.9, 54±2.5, 52.6±2.8, and 44.4±2.2 Ma. Plutonic clasts accumulated in the Paleocene Arkose Ridge Formation to the south. Detrital zircon (DZ) ages from the formation reflect this provenance: a new sample yielded one grain at 61 Ma, a dominant peak at 76 Ma, and minor peaks at 70, 80, 88, and 92 Ma. The oldest zircon is 181 Ma. Our apatite FT ages range from 35.1 to 50.9 Ma. Greenschist facies rocks now sit structurally between the plutonic rocks and the Arkose Ridge Formation. They are separated from plutonic rocks by the vertical Hatcher Pass fault and from the sedimentary rocks by a detachment fault. Ar cooling ages (Harlan and others, 2003) and new zircon FT ages for these rocks are concordant at 61-57 Ma, synchronous with deposition of the Arkose Ridge Formation. A cooling age of ~46 Ma came from one apatite FT sample. The metamorphic protolith (previously considered Jurassic) was deposited at or after 75 Ma based on new DZ data. The probability curve has a major peak from 76 to 102 Ma, minor peaks at 186, 197, 213, 303, 346, and 1,828, and two discordant grains at ~2,700 Ma. This is similar to DZ populations in the Valdez Group. The short period of time between deposition, metamorphism, and exhumation are consistent with metamorphism in a subduction-zone setting. Ductile and brittle structures in the metamorphic rocks are consistent with exhumation in a transtensional setting.

Alaska↗

Depositional controls on detrital zircon provenance: An example from upper Cretaceous strata, southern Patagonia

Understanding how depositional environments within a sedimentary system redistribute and sequester sediment is critical for interpreting basin-scale provenance trends. However, sedimentary source-to-sink models commonly examine temporal changes and do not consider how variation in sedimentation processes across a dispersal pathway may result in contrasting provenance signatures. In this paper, we demonstrate a down-paleoslope shift in detrital zircon provenance signatures correlated with shallow-marine lithofacies patterns from the Upper Cretaceous La Anita Formation and underlying continental slope lithofacies of the Alta Vista Formation (Magallanes-Austral Basin, southern Patagonia). New stratigraphic, sedimentologic, and lithofacies analysis results from the La Anita Formation suggest an upward shoaling succession, from a (i) storm-influenced shoreface, (ii) fluvially-dominated, wave-influenced delta, and a (iii) high-energy, gravelly foreshore. Stratigraphic sections are paired with U-Pb detrital zircon sandstone samples (N = 20; n = 5219), which provide both maximum depositional ages and provenance characteristics. While all samples contain abundant zircon derived from the Andean volcanic arc (ca. 145–75 Ma), the amount from both Jurassic distal volcanic massifs (ca. 188–162 Ma) and recycled orogenic sources exhumed during the advance of the Cretaceous fold-and-thrust belt (>200 Ma; 157–142 Ma) vary with changes in depositional environment. We argue that down-paleoslope, systematic enriching of local fold-and-thrust belt material within the La Anita Formation is reflective of progressive mixing of grains transported via shallow-marine processes, while distally enriched fluvio-deltaic transported zircons were sourced from large, regional catchments. This suggests that competition between transport processes across a shallow and marginal marine sequence of rocks affects the resulting provenance signatures recorded within a single stratigraphic succession. These data also detail the degree of sediment pathway connectivity between shallow-marine sources and deep-marine sinks. Detrital zircon results from muddy continental slope facies of the Alta Vista Formation are made up entirely locally derived material, while zircon results from deep-water, sand-rich channel facies of the Formation are indistinguishable from coeval fluvio-deltaic zircon signatures. This implies that continental shelf-to-slope connectivity in a sediment dispersal system, via submarine canyons or shelf-edge delta progradation, is necessary for detrital zircon distributions from the shallow-marine realm to propagate into the deeper marine.

Patagonia↗

Geology and ground-water resources of the Ahtanum Valley, Yakima County, Washington

The Ahtanum Valley covers an area of about 100 square miles in an important agricultural district in central Yakima County, Wash. Because the area is semiarid, virtually all crops require irrigation. Surface-water supplies are inadequate in most of the area, and ground water is being used increasingly for irrigation. The purpose of this investigation was the collection and interpretation of data, pertaining to ground water in the area as an aid in the proper development and management of the water resources. The occurrence and movement of ground water in the Ahtanum Valley are directly related to the geology. The valley occupies part of a structural trough (Ahtanum-Moxee subbasin) that is underlain by strongly folded flow layers of a thick sequence of the Yakima basalt. The upper part of the basalt sequence interfingers with, and is conformably overlying by, sedimentary rocks of the Ellensburg formation which are as much as 1,000 feet thick. These rocks are in turn overlying unconformably by cemented basalt gravel as much as 400 feet thick. Unconsolidated alluvial sand and gravel, as much as 30 feet thick, form the valley floor. Although ground water occurs in each of the rock units within the area, the Yakima basalt and the unconsolidated alluvium yield about three-fourths of the ground water currently used. Wells in the area range in depth from a few feet to more than 1,200 feet and yield from less than 1 to more than 1,030 gallons per minute. Although water levels in water-table wells usually are shallow--often less than 5 feet below the land surface--levels in deeper wells tapping confined water range from somewhat above the land surface (in flowing wells) to about 200 feet below. Wells drilled into aquifers in the Yakima basalt, the Ellensburg formation, and the cemented gravel usually tap confined water, and at least 12 wells in the area flow or have flowed in the past. Ground-water levels fluctuate principally in response to changes in stream levels, variations in the flow of irrigation ditches and in rates of water application, variations in local precipitation, and seasonal differences in withdrawals from wells. Annual fluctuations of levels generally are less than 10 feet except in localities of heavy pumping. Periodic measurements of water levels in two observation wells in the area indicate, locally at least, a persistent decline in artesian pressures in confined basalt aquifers, although the record is too short to show whether withdrawal by pumping has reached, or is nearing, an optimum balance with recharge. The aquifers are recharged by precipitation, by infiltration from streams, and by ground-water underflow into the area. Ground water is discharged by seepage to streams, by evapotranspiration, by springs and seeps at the land surface, and, artificially, by withdrawal from wells. It is estimated that the seepage discharge to the Yakima River from the area studied may range from about 20,000 to 25,000 acre-feet per year. The consumptive waste of ground water by phreatophytes probably exceeds 4,000 acre-feet per year and may represent a large reclaimable source of water in the area. The annual withdrawal of ground water from wells in the area for domestic, industrial, irrigation, public, and stock supplies is estimated to be 6,300 acre-feet. The chemical quality of the ground water generally is satisfactory for most purposes, although the water from many wells is harder than is desirable for domestic use.

Washington↗