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At least 793 records · Page 44Linked to original sources

Re-evaluating Marine Isotope Stage 5a paleo-sea-level trends from across the Florida Keys reef tract

Unraveling how Global Mean Sea Level (GMSL) fluctuated during past warm periods can improve our understanding of linkages between sea-level fluctuations, orbital forcing, and ice-sheet dynamics. Current estimates of GMSL for Marine Isotope Stages (MIS) 5a and 5c — two warm intervals following the relatively well-documented MIS 5e — contain meters of uncertainty and fewer data due to several challenges. These challenges include concealment of datable in-situ coral facies by MIS 1 deposits and inaccessibility due to submergence by modern sea level. We present a comprehensive dataset based on U–Th dating and stratigraphic correlation of 23 cores totaling over 170 m of recovered coral-reef deposits across the tectonically stable Florida Keys Reef Tract (FKRT). Following detailed facies descriptions, 34 in-situ, minimally altered aragonitic coral samples (≤2.7% calcite) below the Holocene-Pleistocene boundary were targeted for U–Th geochronology. Fourteen closed-system coral U–Th ages from MIS 5a include the commonly used sea-level indicator Acropora palmata , but also the massive coral taxa Pseudodiploria strigosa, Siderastrea siderea, Orbicella spp., and Porites astreoides . Dating yielded ages in the range of 88–81 ka (average 2σ uncertainty of less than 200 years). These ages suggest MIS 5a reef initiation at ∼88 ka BP, a peak near 83 ka with minimum elevations between −6.0 ± 0.5 and −5.6 ± 0.5 m MSL (2σ uncertainty and subsidence-corrected), and reef termination and sea-level fall by ∼81 ka BP. Notably, the range of peak MIS 5a relative sea-level estimates of −6.5 to −5.1 m MSL are more than 2 m shallower (higher) than previous estimates of −11 to −9 m. Our higher resolution regional sea-level reconstruction across four subregions of the Florida Keys reef tract aligns with changes in July insolation at 65° N: a trend that most other records, such as deep-sea sediments, do not have the accuracy and precision to resolve. Three massive coral samples from MIS 5c, consisting of Pseudodiploria clivosa , and Orbicella spp., yielded ages in the range of 104 to 99 ka (average 2σ uncertainty less than 200 years); however, because only one sample met the closed-system criteria, our ability to estimate MIS 5c sea level is relatively limited. More empirical estimates of sea-level from the MIS 5a and MIS 5c intervals based on numerical dating of reliable local sea-level constraints are critical for GMSL calculations and relating changes in sea-level amplitude and timing to global ice volume modeling and glacio-isostatic effects, all of which can improve predictions of future sea-level changes in coastal regions.

Florida↗

Vegetation vs. anoxic controls on degradation of plant litter in a restored wetland

The ability of wetlands to accrete organic matter in response to rising sea level is a key to landscape resilience, especially in light of reduced sediment availability consequent to dam construction and channelization. This study examined the degradation of cattail ( Typha spp.) and tule ( Schoenoplectus acutus ) litters in restored wetlands through the lens of lignin, a major structural biopolymer in vascular plants with degradation characteristics very sensitive to oxic versus anoxic conditions. A series of litterbags were deployed during the first 10 years after flooding of Deep (55 cm) and Shallow (25 cm) restored wetlands. As emergent marsh vegetation spread through the maturing wetlands, anoxic conditions were more prevalent and overall degradation rates of litter in litterbags were lower. In later experiments in the maturing wetlands, lignin was progressively enriched in litter as evidenced by carbon-normalized yields (Λ 8 ) that increased in tule starting materials from 6.3 to 7.1 mg 100 mgOC –1 to as high as 9.9 mg 100 mgOC –1 , and in cattail starting materials from 5.9 to 7.0 mg 100 mgOC –1 to as high as 10.9 mg 100 mgOC –1 . However, in an experiment initiated soon after the restored wetlands were constructed, Λ 8 in tule litter decreased from 6.8 to 3.6 mg 100 mgOC –1 , highlighting the prevalence of initial oxic conditions. With the exception of the early oxic conditions for tule, there was an overall trend of decreasing lignin acid-to-aldehyde ratios with litter degradation, which runs counter to most studies in the literature. We hypothesize that this reflects the utilization of more oxygen-rich lignin components as electron acceptors in redox reactions. No consistent differences were observed in degradation patterns between the Shallow and Deep wetlands. There were distinct differences in lignin degradation in cattail (more resistant) versus tule (less resistant), which indicates that although anoxia may be the dominant control on organic matter accretion in wetlands, specific types of vegetation in restored or constructed wetlands affects organic matter preservation, and hence accretion. Thus, selective management of predominant species in wetlands may prove important for the ability of wetlands to maintain emergent vegetation during sea level rise and to preserve the overall stability of wetland soils.

California↗

Physicochemical models of effusive rhyolitic eruptions constrained with InSAR and DEM data: A case study of the 2011-2012 Cordon Caulle eruption

The 9 month long 2011-2012 eruption of Cordon Caulle (Southern Andes, Chile) is the best instrumentally recorded rhyolitic eruption to date and the first time that the effusion of a rhyolitic flow has been observed in detail. We use Interferometric Synthetic Aperture Radar (InSAR), with time-lapse DEMs and numerical models to study the dynamics of coupled magma reservoir deflation and lava effusion. InSAR recorded ~2.2-2.5 m of deflation after the first three days of the eruption, which can be modeled using a spheroidal magma reservoir at a depth of ∼5 km, ∼20 km long, and with a pressure drop of ~20-30 MPa. The source is elongated in the NW-SE direction and its large dimensions imply a large plumbing system spanning neighboring volcanoes and active throughout the eruption, with a slight change halfway through the effusive phase. TanDEM-X DEMs record the extrusion of both the rhyolitic lava flow and the intrusion of a shallow laccolith around the eruptive vent, with a total volume of ~1.2 km3 DRE. The laccolith was emplaced during the first month of the eruption, during both the eruption explosive and effusive stages. Both the reservoir pressure drop and the extruded volume time series follow quasi-exponential trends, and can be explained by a model that couples the reservoir pres- sure decrease, time- and pressured ependent variations in the magma properties inside of the reservoir, and conduit flow. This model predicts both the temporal evolution and amplitude of both time series, and a magma compressibility of ∼10^−10 Pa−1, half the compressibility of the magma of the sub-Plinian explosive phase. Further, we estimate that the reservoir contained 1-3 wt.% dissolved H2O at the onset of lava effusion, with no exsolved CO2 and H2O in the reservoir throughout the eruption. This is in accord with a magma that was significantly degassed after the explosive phase. These remaining volatiles might have been responsible for magma fragmentation, consistent with the hybrid explosive and effusive style observed during the waning of the eruption.

Cordón Caulle↗

Land change, fire, and climate weaken carbon sink in the conterminous U.S.

The land carbon sink of the conterminous United States was evaluated using a bottom-up modeling framework and 30-meter land change data from 1985 to 2020. This cross-scale, cross-landscape, and cross-system approach tracked fractional land cover changes and applied regional model calibration. Results show average terrestrial and aquatic carbon sinks of +110 ± 37 and +19 ± 0.5 teragrams of carbon per year, respectively. The terrestrial carbon sink, showing no clear trend, peaked in the 1990s, with more years as a carbon source since 2000, contradicting recent national and global studies. Land change had the largest impact (−70 ± 5.5 teragrams of carbon per year), exceeding impacts of climate (−33 ± 48 teragrams of carbon per year), wildfire (−7.7 ± 2.4 teragrams of carbon per year), and erosion transport (−1.9 ± 0.13 teragrams of carbon per year). The positive CO2 fertilization effect (+69 ± 12 teragrams of carbon per year) was insufficient to maintain the carbon sink strength. Our framework reveals key paths of carbon loss, with implications for carbon budget and energy policies in the United States and beyond.

conterminous United States↗

U–Pb geochronology of Late Cretaceous and early Tertiary plutons in the northern Coast Mountains batholith

U–Pb geochronologic studies demonstrate that steeply dipping, sheetlike tonalitic plutons along the western margin of the northern Coast Mountains batholith were emplaced between ~83 and ~57 (perhaps ~55) Ma. Less elongate tonalitic–granodioritic bodies in central portions of the batholith yield ages of 59–58 Ma, coeval with younger phases of the tonalitic sheets. Large granite–granodiorite bodies in central and eastern portions of the batholith were emplaced at 51–48 Ma. Trends in ages suggest that the tonalitic bodies generally become younger southeastward and that, at the latitude of Juneau, plutonism migrated northeastward across the batholith at ~0.9 km/Ma. Variations in the age, shape, location, and degree of fabric development among the various plutons indicate that Late Cretaceous – Paleocene tonalitic bodies were emplaced into a steeply dipping, dip-slip shear zone that was active along the western margin of the batholith. Postkinematic Eocene plutons were emplaced at shallow crustal levels. Inherited zircon components in these plutons range in age from mid-Paleozoic to Early Proterozoic and are coeval with detrital zircons in adjacent metasedimentary rocks. These old zircons, combined with evolved Nd isotopic signatures for most plutons, record assimilation of continental crustal or supracrustal rocks during the generation and (or) ascent of the plutons.

Alaska↗

Sand resources, regional geology, and coastal processes of the Chandeleur Islands Coastal System: An evaluation of the Breton National Wildlife Refuge

Breton National Wildlife Refuge, the Chandeleur Islands chain in Louisiana, provides habitat and nesting areas for wildlife and is an initial barrier protecting New Orleans from storms. The U.S. Geological Survey (USGS) in partnership with the University of New Orleans Pontchartrain Institute for Environmental Sciences undertook an intensive study that included (1) an analysis of island change based on historical maps and remotely sensed shoreline and topographic data; (2) a series of lidar surveys at 3- to 4-month intervals after Hurricane Katrina to determine barrier island recovery potential; (3) a discussion of sea level rise and effects on the islands; (4) an analysis of sea floor evolution and sediment dynamics in the refuge over the past 150 years; (5) an assessment of the local sediment transport and sediment resource availability based on the bathymetric and subbottom data; (6) a carefully selected core collection effort to groundtruth the geophysical data and more fully characterize the sediments composing the islands and surrounds; (7) an additional survey of the St. Bernard Shoals to assess their potential as a sand resource; and (8) a modeling study to numerically simulate the potential response of the islands to the low-intensity, intermediate, and extreme events likely to affect the refuge over the next 50 years. Results indicate that the islands have become fragmented and greatly diminished in subaerial extent over time: the southern islands retreating landward as they reorganize into subaerial features, the northern islands remaining in place. Breton Island, because maintenance of the Mississippi River-Gulf Outlet (MRGO) outer bar channel requires dredging, is deprived of sand sufficient to sustain itself. Regional sediment transport trends indicate that large storms are extremely effective in transporting sand and controlling the shoreline development and barrier island geometry. Sand is transported north and south from a divergent zone near Monkey Bayou at the southern end of the Chandeleur Islands. Numerical simulation of waves and sediment transport supports the geophysical results and indicates that vast areas of the lower shoreface are affected and are undergoing erosion during storm events, that there is little or no fair weather mechanism to rework material into the littoral system, and that as a result, there is a net loss of sediment from the system. Lidar surveys revealed that the island chain immediately after Hurricane Katrina lost about 84 percent of its area and about 92 percent of its prestorm volume. Marsh platforms that supported the islands’ sand prior to the storm were reduced in width by more than one-half. Repeated lidar surveys document that in places the shoreline has retreated about 100 m under the relatively low-energy waves since Hurricanes Katrina and Rita; however, this retreat is nonuniform. Recent high-resolution geophysical surveys of the sea floor and subsurface within 5–6 km of the Chandeleur Islands during 2006 and 2007 show that, in addition to the sand that is rebuilding portions of the island chain, a large volume of sand is contained in Hewes Point, in an extensive subtidal spit platform that has formed at the northern end of the Chandeleur Islands. Hewes Point appears to be the depositional terminus of the alongshore transport system. In the southern Chandeleurs, sand is being deposited in a broad tabular deposit near Breton Island called the southern offshore sand sheet. These two depocenters account for approximately 70 percent of the estimated sediment volume located in potential borrow sites. An additional large potential source of sand for restoration lies in the St. Bernard Shoals, which are estimated to contain approximately 200 × 10 6 m 3 of sand. Successful restoration planning for the Breton National Wildlife Refuge should mimic the natural processes of early stages of barrier island evolution including lateral transport to the flanks of the island chain from a centralized sand source that will ultimately enhance the ability of the islands to naturally build backbarrier marsh, dunes, and a continuous sandy shoreline. Barrier island sediment nourishment should be executed with the understanding that gulf shoreline erosion is inevitable but that island area can be maintained and enhanced during retreat (thus significantly prolonging the life of the island chain) with strategic sand placement.

Louisiana↗

Increasing chloride in rivers of the conterminous U.S. and linkages to potential corrosivity and lead action level exceedances in drinking water

Corrosion in water-distribution systems is a costly problem and controlling corrosion is a primary focus of efforts to reduce lead (Pb) and copper (Cu) in tap water. High chloride concentrations can increase the tendency of water to cause corrosion in distribution systems. The effects of chloride are also expressed in several indices commonly used to describe the potential corrosivity of water, the chloride-sulfate mass ratio (CSMR) and the Larson Ratio (LR). Elevated CSMR has been linked to the galvanic corrosion of Pb whereas LR is indicative of the corrosivity of water to iron and steel. Despite the known importance of chloride, CSMR, and LR to the potential corrosivity of water, monitoring of seasonal and interannual changes in these parameters is not common among water purveyors. We analyzed long-term trends (1992–2012) and the current status (2010–2015) of chloride, CSMR, and LR in order to investigate the short and long-term temporal variability in potential corrosivity of US streams and rivers. Among all sites in the trend analyses, chloride, CSMR, and LR increased slightly, with median changes of 0.9 mg L − 1 , 0.08, and 0.01, respectively. However, urban-dominated sites had much larger increases, 46.9 mg L − 1 , 2.50, and 0.53, respectively. Median CSMR and LR in urban streams (4.01 and 1.34, respectively) greatly exceeded thresholds found to cause corrosion in water distribution systems (0.5 and 0.3, respectively). Urbanization was strongly correlated with elevated chloride, CSMR, and LR, especially in the most snow-affected areas in the study, which are most likely to use road salt. The probability of Pb action-level exceedances (ALEs) in drinking water facilities increased along with raw surface water CSMR, indicating a statistical connection between surface water chemistry and corrosion in drinking water facilities. Optimal corrosion controlwill require monitoring of critical constituents reflecting the potential corrosivity in surface waters.

Science of the Total Environment↗

Air, land, and water variables associated with the first appearance and current spatial distribution of toxic Prymnesium parvum blooms in reservoirs of the Southern Great Plains, USA

This study examined the association of air, land, and water variables with the first historical occurrence and current distribution of toxic Prymnesium parvum blooms in reservoirs of the Brazos River and Colorado River, Texas (USA). One impacted and one reference reservoir were selected per basin. Land cover and use variables were estimated for the whole watershed (WW) and a 0.5-km zone on either side of streams (near field, NF). Variables were expressed in annual values. Principal component and trend analyses were used to determine (1) differences in environmental conditions before and after the 2001 onset of toxic blooms in impacted reservoirs (study period, 1992–2017), and (2) traits that uniquely discriminate impacted from reference reservoirs (2001–2017). Of thirty-three variables examined, two positively aligned with the reoccurring appearance of blooms in impacted reservoirs (air CO 2 and herbicide Glyphosate) and another two negatively aligned (insecticides Terbufos and Malathion). Glyphosate use was observed throughout the study period but a turning point for an upward trend occurred near the year of first bloom occurrence. While the relevance of the decreased use of insecticides is uncertain, prior experimental studies reported that increasing concentrations of air CO 2 and water Glyphosate can enhance P. parvum growth. Consistent with prior findings, impacted reservoirs were of higher salinity than reference reservoirs. In addition, their watersheds had far lower wetland cover at NF and WW scales. The value of wetlands in reducing harmful algal bloom incidence by reducing nutrient inputs has been previously recognized, but wetlands can also capture pesticides. Therefore, a diminished wetland cover could magnify Glyphosate loads flowing into impacted reservoirs. These observations are consistent with a scenario where rising levels of air CO 2 and Glyphosate use contributed to the establishment of P. parvum blooms in reservoirs of relatively high salinity and minimal wetland cover over their watersheds.

Texas↗

Uptake of per- and polyfluoroalkyl substances by fish, mussel, and passive samplers in mobile laboratory exposures using groundwater from a contamination plume at a historical fire training area, Cape Cod, Massachusetts

Aqueous film-forming foams historically were used during fire training activities on Joint Base Cape Cod, Massachusetts, and created an extensive per- and polyfluoroalkyl substances (PFAS) groundwater contamination plume. The potential for PFAS bioconcentration from exposure to the contaminated groundwater, which discharges to surface water bodies, was assessed with mobile-laboratory experiments using groundwater from the contamination plume and a nearby reference location. The on-site continuous-flow 21-day exposures used male and female fathead minnows, freshwater mussels, polar organic chemical integrative samplers (POCIS), and polyethylene tube samplers (PETS) to evaluate biotic and abiotic uptake. The composition of the PFAS-contaminated groundwater was complex and 9 PFAS were detected in the reference groundwater and 17 PFAS were detected in the contaminated groundwater. The summed PFAS concentrations ranged from 120 to 140 ng L –1 in reference groundwater and 6100 to 15,000 ng L –1 in contaminated groundwater. Biotic concentration factors (CF b ) for individual PFAS were species, sex, source, and compound-specific and ranged from 2.9 to 1000 L kg –1 in whole-body male fish exposed to contaminated groundwater for 21 days. The fish and mussel CF b generally increased with increasing fluorocarbon chain length and were greater for sulfonates than for carboxylates. The exception was perfluorohexane sulfonate, which deviated from the linear trend and had a 10-fold difference in CF b between sites, possibly because of biotransformation of precursors such as perfluorohexane sulfonamide. Uptake for most PFAS in male fish was linear over time, whereas female fish had bilinear uptake indicated by an initial increase in tissue concentrations followed by a decrease. Uptake of PFAS was less for mussels (maximum CF b = 200) than for fish, and mussel uptake of most PFAS also was bilinear. Although abiotic concentration factors were greater than CF b , and values for POCIS were greater than for PETS, passive samplers were useful for assessing PFAS that potentially bioconcentrate in fish but are present at concentrations below method quantitation limits in water. Passive samplers also accumulate short-chain PFAS that are not bioconcentrated.

Massachusetts↗

Remarkable response of native fishes to invasive trout suppression varies with trout density, temperature, and annual hydrology

Recovery of imperiled fishes can be achieved through suppression of invasives, but outcomes may vary with environmental conditions. We studied the response of imperiled desert fishes to an invasive brown ( Salmo trutta ) and rainbow trout ( Oncorhynchus mykiss ) suppression program in a Colorado River tributary, with natural flow and longitudinal variation in thermal characteristics. We investigated trends in fish populations related to suppression and tested hypotheses about the impacts of salmonid densities, hydrologic variation, and spatial–thermal gradients on the distribution and abundance of native fish species using zero-inflated generalized linear mixed effects models. Between 2012 and 2018, salmonids declined 89%, and native fishes increased dramatically (∼480%) once trout suppression surpassed ∼60%. Temperature and trout density were consistently retained in the top models predicting the abundance and distribution of native fishes. The greatest increases occurred in warmer reaches and in years with spring flooding. Surprisingly, given the evolution of native fishes in disturbance-prone systems, intense, monsoon-driven flooding limited native fish recruitment. Applied concertedly, invasive species suppression and efforts to mimic natural flow and thermal regimes may allow rapid and widespread native fish recovery.

Arizona↗

Modelling regional land change scenarios to assess land abandonment and reforestation dynamics in the Pyrenees (France)

Over the last decades and centuries, European mountain landscapes have experienced substantial transformations. Natural and anthropogenic LULC changes (land use and land cover changes), especially agro-pastoral activities, have directly influenced the spatial organization and composition of European mountain landscapes. For the past sixty years, natural reforestation has been occurring due to a decline in both agricultural production activities and rural population. Stakeholders, to better anticipate future changes, need spatially and temporally explicit models to identify areas at risk of land change and possible abandonment. This paper presents an integrated approach combining forecasting scenarios and a LULC changes simulation model to assess where LULC changes may occur in the Pyrenees Mountains, based on historical LULC trends and a range of future socio-economic drivers. The proposed methodology considers local specificities of the Pyrenean valleys, sub-regional climate and topographical properties, and regional economic policies. Results indicate that some regions are projected to face strong abandonment, regardless of the scenario conditions. Overall, high rates of change are associated with administrative regions where land productivity is highly dependent on socio-economic drivers and climatic and environmental conditions limit intensive (agricultural and/or pastoral) production and profitability. The combination of the results for the four scenarios allows assessments of where encroachment (e.g. colonization by shrublands) and reforestation are the most probable. This assessment intends to provide insight into the potential future development of the Pyrenees to help identify areas that are the most sensitive to change and to guide decision makers to help their management decisions.

Journal of Mountain Science↗

Holocene multidecadal and multicentennial droughts affecting Northern California and Nevada

Continuous, high-resolution δ 18 O records from cored sediments of Pyramid Lake, Nevada, indicate that oscillations in the hydrologic balance occurred, on average, about every 150 years (yr) during the past 7630 calendar years (cal yr). The records are not stationary; during the past 2740 yr, drought durations ranged from 20 to 100 yr and intervals between droughts ranged from 80 to 230 yr. Comparison of tree-ring-based reconstructions of climate change for the past 1200 yr from the Sierra Nevada and the El Malpais region of northwest New Mexico indicates that severe droughts associated with Anasazi withdrawal from Chaco Canyon at 820 cal yr BP (calendar years before present) and final abandonment of Chaco Canyon, Mesa Verde, and the Kayenta area at 650 cal yr BP may have impacted much of the western United States.During the middle Holocene (informally defined in this paper as extending from 8000 to 3000 cal yr BP), magnetic susceptibility values of sediments deposited in Pyramid Lake's deep basin were much larger than late–Holocene (3000–0 cal yr BP) values, indicating the presence of a shallow lake. In addition, the mean δ 18 O value of CaCO 3 precipitated between 6500 and 3430 cal yr BP was 1.6‰ less than the mean value of CaCO 3 precipitated after 2740 cal yr BP. Numerical calculations indicate that the shift in the δ 18 O baseline probably resulted from a transition to a wetter (>30%) and cooler (3–5°C) climate. The existence of a relatively dry and warm middle-Holocene climate in the Truckee River–Pyramid Lake system is generally consistent with archeological, sedimentological, chemical, physical, and biological records from various sites within the Great Basin of the western United States. Two high-resolution Holocene-climate records are now available from the Pyramid and Owens lake basins which suggest that the Holocene was characterized by five climatic intervals. TIC and δ 18 O records from Owens Lake indicate that the first interval in the early Holocene (11,600–10,000 cal yr BP) was characterized by a drying trend that was interrupted by a brief (200 yr) wet oscillation centered at 10,300 cal yr BP. This was followed by a second early-Holocene interval (10,000–8000 cal yr BP) during which relatively wet conditions prevailed. During the early part of the middle Holocene (8000–6500 cal yr BP), high-amplitude oscillations in TIC in Owens Lake and δ 18 O in Pyramid Lake indicate the presence of shallow lakes in both basins. During the latter part of the middle Holocene (6500–3800 cal yr BP), drought conditions dominated, Owens Lake desiccated, and Lake Tahoe ceased spilling to the Truckee River, causing Pyramid Lake to decline. At the beginning of the late Holocene (∼3000 cal yr BP), Lake Tahoe rose to its sill level and Pyramid Lake increased in volume.

Quaternary Science Reviews↗

Variability in shelf sedimentation in response to fluvial sediment supply and coastal erosion over the past 1,000 years in Monterey Bay, CA, United States

Continental shelf environments are uniquely situated to capture some of the most dynamic processes on Earth including climatic variability and anthropogenic modifications to coastal systems. Understanding how these processes have affected sediment delivery and accumulation on the shelf in the past may provide insight into potential changes in the future. To address this, we investigated shelf sedimentation within Monterey Bay, California. Sediment cores were collected from four locations throughout the bay to capture both the modern and late Holocene sedimentological record using grain size analysis, and sediment chronologies determined from 210 Pb, 137 Cs, and 14 C. From the grain size results we focused on the total percent sand, and established a Littoral Sand Fraction (LSF) index to assess sediment contribution from the littoral zone as a result coastal erosion. Grain size results from the multicores consistently showed an increase in sand over the past several decades (post 1970s). For the cores located within the bay proximal to three major rivers, the increase in sand corresponded to a general increase in the LSF over the same period. We attributed these trends to increased sediment contributions to the shelf due to accelerated coastal erosion in the region. This accelerated coastal erosion was likely the combined result of dam construction in the mid-twentieth century that limited fluvial supply to the coast, and a shift in climate toward wetter, stormier period. Applying these sediment characteristics back over the past ∼1,000 years we found that dry climatic periods resulted in deposits that were limited in total sand but enriched in littoral material suggesting elevated coastal erosion. During wet periods deposits were enriched in total sand but limited in littoral sand suggesting elevated fluvial supply and low erosion. Compared to the late Holocene record, the previous several decades represent a shift to a new regime, uncharacteristic of deposits over the past millennia, highlighting the impact humans have had on shelf sedimentation.

California↗

International strategic minerals inventory summary report; vanadium

Major world resources of vanadium are described in this summary report of information in the International Strategic Minerals Inventory (ISMI). ISMI is a cooperative data-collection effort of earth-science and mineral-resource agencies in Australia, Canada, the Federal Republic of Germany, the Republic of South Africa, the United Kingdom, and the United States of America. This report, designed to benefit geologists and policy analysts, contains two parts. Part I presents an overview of the resources and potential supply of vanadium based on inventory information. Part II contains tables of some geologic information and mineral-resource and production data collected by ISMI participants. Vanadium's greatest application is as an additive in steel. During 1984, for example, 90 percent of the vanadium produced in the world was consumed in steelmaking. The Soviet Union and China are the only major steel producers of the world that meet significant proportions of their vanadium needs from domestic sources, albeit from relatively low-grade ores. Reliable economically exploitable world resources total greater than 22 million metric tons of vanadium pentoxide. Deposits of the titaniferous magnetite type are the most economically important, and of these the Bushveld Complex of South Africa is the principal vanadium resource. The high-grade tenor of the Bushveld ore renders South Africa the world's leader in vanadium resources and production. Present (1990) major primary production is confined to only four countries: South Africa, the Soviet Union (low-grade ore), the Peoples Republic of China (low-grade ore), and the United States (partly from imported materials). This production trend is likely to continue for many years.

Circular↗

Recycling of water, carbon, and sulfur during subduction of serpentinites: A stable isotope study of Cerro del Almirez, Spain

We use the concentrations and isotope compositions of water, carbon, and sulfur in serpentinites and their dehydration products to trace the cycling of volatiles during subduction. Antigorite serpentinites from the Cerro del Almirez complex, Spain, contain 9–12 wt.% H2O and 910 ± 730 ppm sulfur, and have bulk δ18O values of 8.6 ± 0.4‰, δD = − 54 ± 5‰, and δ34S = 5.0‰, consistent with serpentinization at temperatures of ~ 200 °C by seawater hydrothermal fluids in a seafloor setting. The serpentinites were dehydrated to chlorite–harzburgite (olivine + orthopyroxene + chlorite) at 700 °C and 1.6–1.9 GPa during subduction metamorphism, resulting in loss of water, and sulfur. The chlorite–harzburgites contain 5.7 ± 1.9 wt.% H2O, and have bulk δ18O = 8.0 ± 0.9‰, and δD = − 77 ± 11‰. The rocks contain 650 ± 620 ppm sulfur having δ34S = 1.2‰. Dehydration of serpentinite resulted in loss of 5 wt.% H2O having δ18O = 8–10‰ and δD = − 27 to − 65‰, and loss of 260 ppm sulfur as sulfate, having δ34S = 14.5‰. The contents and δ13C of total carbon in the two rock types overlap, with a broad trend of decreasing carbon contents and δ13C from ~ 1300 to 200 ppm and − 9.6 to − 20.2‰. This reflects mixing between reduced carbon in the rocks (210 ppm, δ13C ≈ − 26‰) and seawater-derived carbonate (δ13C ≈ − 1‰). Our results indicate: 1) Serpentinized oceanic peridotites carry significant amounts of isotopically fractionated water, carbon and sulfur into subduction zones; 2) Subduction of serpentinites to high P and T results in loss of water, and sulfur, which can induce melting and contribute to 18O, D, and 34S enrichments and oxidation of the sub-arc mantle wedge; and 3) Isotopically fractionated water, carbon, and sulfur in serpentinite dehydration products are recycled deeper into the mantle where they can contribute to isotope heterogeneities and may be significant for volatile budgets of the deep Earth.

Cerro Del Almirez;Betic Cordillera In Southern Spa↗

Killer whales and marine mammal trends in the North Pacific - A re-examination of evidence for sequential megafauna collapse and the prey-switching hypothesis

Springer et al. (2003) contend that sequential declines occurred in North Pacific populations of harbor and fur seals, Steller sea lions, and sea otters. They hypothesize that these were due to increased predation by killer whales, when industrial whaling's removal of large whales as a supposed primary food source precipitated a prey switch. Using a regional approach, we reexamined whale catch data, killer whale predation observations, and the current biomass and trends of potential prey, and found little support for the prey-switching hypothesis. Large whale biomass in the Bering Sea did not decline as much as suggested by Springer et al., and much of the reduction occurred 50-100 yr ago, well before the declines of pinnipeds and sea otters began; thus, the need to switch prey starting in the 1970s is doubtful. With the sole exception that the sea otter decline followed the decline of pinnipeds, the reported declines were not in fact sequential. Given this, it is unlikely that a sequential megafaunal collapse from whales to sea otters occurred. The spatial and temporal patterns of pinniped and sea otter population trends are more complex than Springer et al. suggest, and are often inconsistent with their hypothesis. Populations remained stable or increased in many areas, despite extensive historical whaling and high killer whale abundance. Furthermore, observed killer whale predation has largely involved pinnipeds and small cetaceans; there is little evidence that large whales were ever a major prey item in high latitudes. Small cetaceans (ignored by Springer et al.) were likely abundant throughout the period. Overall, we suggest that the Springer et al. hypothesis represents a misleading and simplistic view of events and trophic relationships within this complex marine ecosystem. ?? 2007 by the Society for Marine Mammalogy.

Marine Mammal Science↗

Gradients in fish feeding guilds along a reservoir cascade

The river continuum concept predicts a longitudinal gradient in the structure and functioning of rivers. Impoundments potentially change this continuum by reorganizing nutrient transport and storage in the system. To determine if predictions made by the river continuum concept relative to fish assemblage trophic structure hold for a temperate river transformed into a reservoir cascade, we examined longitudinal trends in the distribution of biomass among feeding guilds over 30 reservoirs of the Tennessee River (USA). Fish assemblages were sampled over a 12-year period, and fishes were classified as detritivores, herbivores, invertivores, piscivores, or planktivores. Biomass of all feeding guilds increased with catchment area (i.e., in a downstream direction). However, representation of herbivores and planktivores within the fish assemblage, as indexed by percent biomass composition, increased with catchment area, whereas representation of detritivores, invertivores, and piscivores decreased. In general, the predictions made by the river continuum concept apply to the Tennessee River reservoir cascade despite the major environmental transformation caused by the series of impoundments. However, transformation of lotic into lentic systems promotes autochthonous primary production and proliferation of herbivores and planktivores that reduces relative representation of other guilds. The marked longitudinal pattern in feeding guild structure in the reservoir cascade reflected changes in production sources following impoundment of the river.

Tennessee River↗

Tracing chlorine sources of thermal and mineral springs along and across the Cascade Range using halogen and chlorine isotope compositions

In order to provide constraints on the sources of chlorine in spring waters associated with arc volcanism, the major/minor element concentrations and stable isotope compositions of chlorine, oxygen, and hydrogen were measured in 28 thermal and mineral springs along the Cascade Range in northwestern USA. Chloride concentrations in the springs range from 64 to 19,000 mg/L and View the MathML source values range from +0.2‰ to +1.9‰ (average=+1.0±0.4‰), with no systematic variation along or across the arc, nor correlations with their presumed underlying basement lithologies. Additionally, nine geochemically well-characterized lavas from across the Mt. St. Helens/Mt. Adams region of the Cascade Range (Leeman et al., 2004 and Leeman et al., 2005) were analyzed for their halogen concentrations and Cl isotope compositions. In the arc lavas, Cl and Br concentrations from the volcanic front are higher than in lavas from the forearc and backarc. F and I concentrations progressively decrease from forearc to backarc, similar to the trend documented for B in most arcs. View the MathML source values of the lavas range from −0.1 to +0.8‰ (average = +0.4±0.3‰). Our results suggest that the predominantly positive View the MathML source values observed in the springs are consistent with water interaction with underlying 37Cl-enriched basalt and/or altered oceanic crust, thereby making thermal spring waters a reasonable proxy for the Cl isotope compositions of associated volcanic rocks in the Cascades. However, waters with View the MathML source values >+1.0‰ also suggest additional contributions of chlorine degassed from cooling magmas due to subsurface vapor–liquid HCl fractionation in which Cl is lost to the aqueous fluid phase and 37Cl is concentrated in the ascending magmatic HCl vapor. Future work is necessary to better constrain Cl isotope behavior during volcanic degassing and fluid–rock interaction in order to improve volatile flux estimates through subduction zones.

Cascade Range↗