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Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

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At least 793 records · Page 44Linked to original sources
USGS2007

Structure and composition of a watershed-scale sediment information network

A 'Watershed-Scale Sediment Information Network' (WaSSIN), designed to complement UNESCO's International Sedimentation Initiative, was endorsed as an initial project by the World Association for Sedimentation and Erosion Research. WaSSIN is to address global fluvial-sediment information needs through a network approach based on consistent protocols for the collection, analysis, and storage of fluvial-sediment and ancillary information at smaller spatial scales than those of the International Sedimentation Initiative. As a second step of implementation, it is proposed herein that the WaSSIN have a general structure of two components, (1) monitoring and data acquisition and (2) research. Monitoring is to be conducted in small watersheds, each of which has an established database for discharge of water and suspended sediment and possibly for bed load, bed material, and bed topography. Ideally, documented protocols have been used for collecting, analyzing, storing, and sharing the derivative data. The research component is to continue the collection and interpretation of data, to compare those data among candidate watersheds, and to determine gradients of fluxes and processes among the selected watersheds. To define gradients and evaluate processes, the initial watersheds will have several common attributes. Watersheds of the first group will be: (1) six to ten in number, (2) less than 1000 km2 in area, (3) generally in mid-latitudes of continents, and (4) of semiarid climate. Potential candidate watersheds presently include the Weany Creek Basin, northeastern Australia, the Zhi Fanggou catchment, northern China, the Eshtemoa Watershed, southern Israel, the Metsemotlhaba River Basin, Botswana, the Aiuaba Experimental Basin, Brazil, and the Walnut Gulch Experimental Watershed, southwestern United States.

International Journal of Sediment Research↗
USGS2017

Enhancing the interpretation of stated choice analysis through the application of a verbal protocol assessment

A stated choice survey was employed to evaluate the relative importance of resource, social, and management attributes by asking visitors to select preferred configurations of these attributes. A verbal protocol assessment was added to consider how respondents interpret and respond to stated choice questions applied to hikers of a popular trail at Acadia National Park. Results suggest that visitors are sensitive to changes in public access to the trail and its ecological conditions, with level of encounters least important. Verbal protocol results identified considerations made by respondents that provide insight to their evaluations of alternative recreation setting configurations. These insights help clarify issues important to visitors that stated choice results on their own do not provide.

Maine↗
USGS2003

Lake Ontario: Food web dynamics in a changing ecosystem (1970-2000)

We examined stressors that have led to profound ecological changes in the Lake Ontario ecosystem and its fish community since 1970. The most notable changes have been reductions in phosphorus loading, invasion by Dreissena spp., fisheries management through stocking of exotic salmonids and control of sea lamprey ( Petromyzon marinus ), and fish harvest by anglers and double-crested cormorants ( Phalacrocorax auritus ). The response to these stressors has led to ( i ) declines in both algal photosynthesis and epilimnetic zooplankton production, ( ii ) decreases in alewife ( Alosa pseudoharengus ) abundance, ( iii ) declines in native Diporeia and lake whitefish ( Coregonus clupeaformis ), ( iv ) behavioral shifts in alewife spatial distribution benefitting native lake trout ( Salvelinus namaycush ), threespine stickleback ( Gasterosteus aculeatus ), and emerald shiner ( Notropis atherinoides ) populations, ( v ) dramatic increases in water clarity, ( vi ) predation impacts by cormorants on select fish species, and ( vii ) lake trout recruitment bottlenecks associated with alewife-induced thiamine deficiency. We expect stressor responses associated with anthropogenic forces like exotic species invasions and global climate warming to continue to impact the Lake Ontario ecosystem in the future and recommend continuous long-term ecological studies to enhance scientific understanding and management of this important resource.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS2002

Activity patterns and time budgets of the declining sea otter population at Amchitka Island, Alaska

Time budgets of predators may reflect population status if time spent foraging varies with local prey abun- dance. We assumed that the sea otter (Enhydra lutris) population at Amchitka Island, Alaska, USA, had been at equilibrium since the early 1960s and collected time budgets of otters to be used to represent future conditions of currently expanding sea otter populations. We used radiotelemetry to monitor activity-time budgets of otters from August 1992 to March 1994. Sea otter activity was directly linked to sex, age, weather condition, season, and time of day. Sea otters differed in percent time foraging among cohorts but not within cohorts. Percent time foraging ranged from 21% for females with very young (≤ 3weeks of age) dependent pups to 52% for females with old (≥10 weeks of age) pups. Otters foraged more and hauled out more as local sea conditions worsened. Adult males spent less time foraging during winter and spring, consistent with seasonal changes in prey selection. Time spent for- aging was similar to that reported for otters in California and an established population in Prince William Sound, Alaska, but greater than that of otters in recently established populations in Oregon and Alaska. Despite current evidence indicating that the population was in decline during our study, we were unable to recognize this change using time budgets. Our results illustrate the importance of stratifying analyses of activity patterns by age and sex cohorts and the complexity inherent in comparisons of behavioral data between different populations relying on distinct prey bases.

Journal of Wildlife Management↗
USGS2022

In situ soil moisture sensors in undisturbed soils

Soil moisture directly affects operational hydrology, food security, ecosystem services, and the climate system. However, the adoption of soil moisture data has been slow due to inconsistent data collection, poor standardization, and typically short record duration. Soil moisture, or quantitatively volumetric soil water content (SWC), is measured using buried, in situ sensors that infer SWC from an electromagnetic response. This signal can vary considerably with local site conditions such as clay content and mineralogy, soil salinity or bulk electrical conductivity, and soil temperature; each of these can have varying impacts depending on the sensor technology., Furthermore, poor soil contact and sensor degradation can affect the quality of these readings over time. Unlike more traditional environmental sensors, there are no accepted standards, maintenance practices, or quality controls for SWC data. As such, SWC is a challenging measurement for many environmental monitoring networks to implement. Here, we attempt to establish a community-based standard of practice for in situ SWC sensors so that future research and applications have consistent guidance on site selection, sensor installation, data interpretation, and long-term maintenance of monitoring stations., The videography focuses on a multi-agency consensus of best-practices and recommendations for the installation of in situ SWC sensors. This paper presents an overview of this protocol along with the various steps essential for high-quality and long-term SWC data collection. This protocol will be of use to scientists and engineers hoping to deploy a single station or an entire network.

Journal of Visualized Experiments↗
USGS2016

Determination of polydimethylsiloxane–water partition coefficients for ten 1-chloro-4-[2,2,2-trichloro-1-(4-chlorophenyl)ethyl]benzene-related compounds and twelve polychlorinated biphenyls using gas chromatography/mass spectrometry

Polymer-water partition coefficients (Kpw) of ten DDT-related compounds were determined in pure water at 25 °C using commercial polydimethylsiloxane-coated optical fiber. Analyte concentrations were measured by thermal desorption-gas chromatography/full scan mass spectrometry (TD–GC/MSFS; fibers) and liquid injection-gas chromatography/selected ion monitoring mass spectrometry (LI–GC/MSSIM; water). Equilibrium was approached from two directions (fiber uptake and depletion) as a means of assessing data concordance. Measured compound-specific log Kpw values ranged from 4.8 to 6.1 with an average difference in log Kpw between the two approaches of 0.05 log units (∼12% of Kpw). Comparison of the experimentally-determined log Kpw values with previously published data confirmed the consistency of the results and the reliability of the method. A second experiment was conducted with the same ten DDT-related compounds and twelve selected PCB (polychlorinated biphenyl) congeners under conditions characteristic of a coastal marine field site (viz., seawater, 11 °C) that is currently under investigation for DDT and PCB contamination. Equilibration at lower temperature and higher ionic strength resulted in an increase in log Kpw for the DDT-related compounds of 0.28–0.49 log units (61–101% of Kpw), depending on the analyte. The increase in Kpw would have the effect of reducing by approximately half the calculated freely dissolved pore-water concentrations (Cfree). This demonstrates the importance of determining partition coefficients under conditions as they exist in the field.

Journal of Chromatography A↗
USGS2008

Low-Level detections of halogenated volatile organic compounds in groundwater: Use in vulnerability assessments

Concentrations of halogenated volatile organic compounds (VOCs) were determined by gas chromatography (GC) with an electron-capture detector (GC-ECD) and by gas chromatography with mass spectrometry (GC-MS) in 109 groundwater samples from five study areas in the United States. In each case, the untreated water sample was used for drinking-water purposes or was from a monitoring well in an area near a drinking-water source. The minimum detection levels (MDLs) for 25 VOCs that were identified in GC-ECD chromatograms, typically, were two to more than four orders of magnitude below the GC-MS MDLs. At least six halogenated VOCs were detected in all of the water samples analyzed by GC-ECD, although one or more VOCs were detected in only 43% of the water samples analyzed by GC-MS. In nearly all of the samples, VOC concentrations were very low and presented no known health risk. Most of the low-level VOC detections indicated post-1940s recharge, or mixtures of recharge that contained a fraction of post-1940s water. Concentrations of selected halogenated VOCs in groundwater from natural and anthropogenic atmospheric sources were estimated and used to recognize water samples that are being impacted by nonatmospheric sources. A classification is presented to perform vulnerability assessments at the scale of individual wells using the number of halogenated VOC detections and total dissolved VOC concentrations in samples of untreated drinking water. The low-level VOC detections are useful in vulnerability assessments, particularly for samples in which no VOCs are detected by GC-MS analysis.

Journal of Hydrologic Engineering↗
USGS2005

Herbicides and degradates in shallow aquifers of Illinois: Spatial and temporal trends

During the fall of 2000, the occurrence was examined of 16 herbicides and 13 herbicide degradates in samples from 55 wells in shallow aquifers underlying grain producing regions of Illinois. Herbicide compounds with concentrations above 0.05 μg/L were detected in 56 percent of the samples. No concentrations exceeded regulatory drinking water standards. The six most frequently detected compounds were degradates. Water age was an important factor in determining vulnerability of ground water to transport of herbicide compounds. Unconsolidated aquifers, which were indicated to generally contain younger ground water than bedrock aquifers, had a higher occurrence of herbicides (73 percent of samples) than bedrock aquifers (22 percent). Temporal analysis to determine if changes in concentrations of selected herbicides and degradates could be observed over a near decadal period indicated a decrease in detection frequency (25 to 18 percent) between samplings in 1991 and 2000. Over this period, significant differences in concentrations were observed for atrazine (decrease) and total acetochlor (increase). The increase in acetochlor compound concentrations corresponds to an increase in acetochlor use during the study period, while the decrease in atrazine concentrations corresponds to relatively consistent use of atrazine. Changes in frequency of herbicide detection and concentration do not appear related to changes in land use near sampled wells.

Illinois↗
USGS2004

Seasonal Daphnia biomass in winterkill and nonwinterkill glacial lakes of South Dakota

We compared the seasonal biomass (??g dry weight/L) and body size of Daphnia pulex populations between South Dakota lakes that experienced nearly complete winterkill (n = 2) and those that did not experience fish winterkill the previous winter (n = 2). In spring (March-May), D. pulex biomass was substantially lower in winterkill lakes (0.4-1.9 ??g/L) than in nonwinterkill lakes (13.8-129.4 ??g/L). In summer months (June-July), D. pulex biomass increased in all lakes but was generally higher in winterkill lakes (332.1-469. 3 ??g/L) than in nonwinterkill lakes (88.6-204.2 ??g/L). By September, D. pulex biomass was substantially higher in winterkill lakes (243.8 ??g/L) than in nonwinterkill lakes (1.0 ??g/L). The mean size of D. pulex increased significantly from March to August in winterkill lakes but not in nonwinterkill lakes. The seasonal differences in D. pulex biomass and size may have been related to size-selective predation by planktivorous fishes because the ratio of spine length to body length in D. pulex was significantly lower in winterkill lakes (mean, 0.34) than in nonwinterkill lakes (mean, 0.43). Moreover, seasonal patterns in chlorophyll-a biomass were inversely related to D. pulex biomass. The production and subsequent hatching of resting eggs may be important for recolonization of Daphnia populations after severe winter conditions. The survival and growth of zooplanktivorous fish that are stocked to repopulate winterkill lakes may be increased by delaying stocking until Daphnia populations recover from severe winterkill.

North American Journal of Fisheries Management↗
USGS2005

An efficient strategy to estimate intensity and prevalence: Sampling metacercariae in fishes

Accurate estimates of population-level parameters of parasites, such as prevalence and mean intensity, require large sample sizes. The processing of such samples becomes an overwhelming task when parasites are abundant, as with trematode metacercariae in fishes. In the present study, a subsampling method reduced processing time while maintaining an accurate estimation of metacercariae prevalence and intensity across 3 trematode species and 2 fish species. By double sampling, we generated regression models to predict total intensity from a combination of subsamples. The key to this approach lies in choosing the best strategy from a large number of potential subsampling routines. We selected the most efficient routine by weighing the costs and benefits of each. This approach, however, could not provide an estimate of parasite abundance when no parasites occurred in the initial subsample. To estimate prevalence accurately, our subsampling algorithm prescribed an additional sampling sequence using a new, optimal regression model. In addition, we optimized the technique to measure three parasite species infecting a single host simultaneously. This efficient subsampling procedure decreased the overall processing time per host by up to 91% while obtaining accurate ( R 2 > 0.8) estimates for both prevalence and intensity.

Journal of Parasitology↗
USGS2012

Since “Groundwater and surface water–A single resource”: some U.S. Geological Survey advances in modeling groundwater/surface-water interactions

Field and interpretive studies conducted by T.C. Winter and U.S. Geological Survey colleagues, and summarized in the 1998 publication “Groundwater and Surface Water – A Single Resource”, inspired a new generation of research centered on extensions of the groundwater-flow code MODFLOW to more sophisticated simulation of coupled groundwater and surface-water systems. Guided by emerging concerns with water availability, safe yields from wells, health of aquatic habitat, and climate change, the changes to MODFLOW involve: 1) the ability to more precisely and accurately represent the interface between surface and subsurface flows and 2) the consideration of a variety of mechanisms that influence their interaction. A review of the most important changes to the code is supplemented in this article by selected case studies in an effort to show the scope of the advances. The updates discussed include the Streamflow Routing (SFR), Lake (LAK), and Unsaturated-Zone Flow (UZF) Packages in MODFLOW-2005 and the Groundwater Management (GWM), Local Grid Refinement (LGR), and Newton (NWT) formulation versions of MODFLOW-2005. New developments feature the integration of rainfall-runoff modeling with MODFLOW in GSFLOW, coupling of GFLOW and MODFLOW in a hybrid code, and the forthcoming unstructured grid version of MODFLOW. They promise continued advances in the ability to use science to protect the single water resource.

Acque Sotterranee: Italian Journal of Groundwater↗
USGS2015

Sympatric cattle grazing and desert bighorn sheep foraging

Foraging behavior affects animal fitness and is largely dictated by the resources available to an animal. Understanding factors that affect forage resources is important for conservation and management of wildlife. Cattle sympatry is proposed to limit desert bighorn population performance, but few studies have quantified the effect of cattle foraging on bighorn forage resources or foraging behavior by desert bighorn. We estimated forage biomass for desert bighorn sheep in 2 mountain ranges: the cattle-grazed Caballo Mountains and the ungrazed San Andres Mountains, New Mexico. We recorded foraging bout efficiency of adult females by recording feeding time/step while foraging, and activity budgets of 3 age-sex classes (i.e., adult males, adult females, yearlings). We also estimated forage biomass at sites where bighorn were observed foraging. We expected lower forage biomass in the cattle-grazed Caballo range than in the ungrazed San Andres range and lower biomass at cattle-accessible versus inaccessible areas within the Caballo range. We predicted bighorn would be less efficient foragers in the Caballo range. Groundcover forage biomass was low in both ranges throughout the study (Jun 2012–Nov 2013). Browse biomass, however, was 4.7 times lower in the Caballo range versus the San Andres range. Bighorn in the Caballo range exhibited greater overall daily travel time, presumably to locate areas of higher forage abundance. By selecting areas with greater forage abundance, adult females in the Caballo range exhibited foraging bout efficiency similar to their San Andres counterparts but lower overall daily browsing time. We did not find a significant reduction in forage biomass at cattle-accessible areas in the Caballo range. Only the most rugged areas in the Caballo range had abundant forage, potentially a result of intensive historical livestock use in less rugged areas. Forage conditions in the Caballo range apparently force bighorn to increase foraging effort by feeding only in areas where adequate forage remains.

New Mexico↗
USGS2011

Selectivity evaluation for two experimental gill-net configurations used to sample Lake Erie walleyes

We used length frequencies of captured walleyes Sander vitreus to indirectly estimate and compare selectivity between two experimental gill-net configurations used to sample fish in Lake Erie: (1) a multifilament configuration currently used by the Ohio Department of Natural Resources (ODNR) with stretched-measure mesh sizes ranging from 51 to 127 mm and a constant filament diameter (0.37 mm); and (2) a monofilament configuration with mesh sizes ranging from 38 to 178 mm and varying filament diameter (range = 0.20–0.33 mm). Paired sampling with the two configurations revealed that the catch of walleyes smaller than 250 mm and larger than 600 mm was greater in the monofilament configuration than in the multifilament configuration, but the catch of 250–600-mm fish was greater in the multifilament configuration. Binormal selectivity functions yielded the best fit to observed walleye catches for both gill-net configurations based on model deviances. Incorporation of deviation terms in the binormal selectivity functions (i.e., to relax the assumption of geometric similarity) further improved the fit to observed catches. The final fitted selectivity functions produced results similar to those from the length-based catch comparisons: the monofilament configuration had greater selectivity for small and large walleyes and the multifilament configuration had greater selectivity for mid-sized walleyes. Computer simulations that incorporated the fitted binormal selectivity functions indicated that both nets were likely to result in some bias in age composition estimates and that the degree of bias would ultimately be determined by the underlying condition, mortality rate, and growth rate of the Lake Erie walleye population. Before the ODNR switches its survey gear, additional comparisons of the different gill-net configurations, such as fishing the net pairs across a greater range of depths and at more locations in the lake, should be conducted to maintain congruence in the fishery-independent survey time series.

North American Journal of Fisheries Management↗
USGS1995

Responses of bluegills and black crappies to dissolved oxygen, temperature, and current in backwater lakes of the upper Mississippi River during winter

We conducted a radiotelemetry study to examine the effects of dissolved oxygen (DO), water temperature, and current velocity on winter habitat selection by bluegills Lepomis macrochirus and black crappies Pomoxis nigromaculatus in the Finger Lakes backwater complex, Pool 5, on the upper Mississippi River. When DO was above 2 mg/L, both species selected areas with water temperature greater than 1°C and undetectable current. As dissolved oxygen concentrations fell below 2 mg/L, fish moved to areas with higher DO, despite water temperatures of 1°C and lower and current velocities of 1 cm/s. Areas with water temperature less than 1°C and current velocity greater than 1 cm/s were avoided. To incorporate the winter habitat requirements of bluegills and black crappies into habitat restoration projects, we recommend designs that allow the inflow of oxygenated water to maintain adequate DO without substantially decreasing temperature and increasing current velocity.

Minnesota↗
USGS2023

Biotic and abiotic factors affecting short-term survival of two age-0 Rainbow Trout strains in Colorado streams

Both biotic and abiotic factors can influence the survival and growth of age-0 salmonids. Diseases, such as whirling disease, can also affect salmonid demographics and population dynamics. Here, we conducted a supplementary analysis and evaluated specific stream characteristics that may have been responsible for the differences in growth and survival of two whirling disease resistant Rainbow Trout Oncorhynchus mykiss strains observed by Avila et al. (2018). We used regression modeling to analyze the influence of the biotic and abiotic characteristics of nine streams on the short-term apparent survival and growth of two Rainbow Trout strains, 5,000 German Rainbow Trout and 5,000 German Rainbow Trout × Colorado River Rainbow Trout in each stream. Akaike's information criterion (AIC c ) model selection was used to identify the factors that most affected short-term survival and growth. Average stream temperature had the largest (positive) effect, β temp = 0.060, on short-term survival. Rainbow Trout strain, average stream temperature (β temp = 1.55), competitor biomass (β competitor biomass = −0.002), and predator number (β predator number = 0.01) additively affected short-term growth. Our results indicate that both biotic and abiotic factors are important short-term determinants of Rainbow Trout poststocking performance and may account for the differences in survival and growth that we observed among stocking locations.

North American Journal of Fisheries Management↗
USGS2019

Estimating quick-flow runoff at the monthly timescale for the conterminous United States

The quantitative estimation of the quick-flow runoff component of streamflow is required for many hydrologic applications. Estimation at the monthly timescale and national spatial scale would be particularly useful for national water availability modeling. This paper reviews a sample of commonly used equations for quick-flow runoff, including several currently in use in continental-scale models. The review shows the wide range of equation forms or heuristics currently in use to predict quick-flow runoff, the limited spatial scale over which these equations are often developed or calibrated, and the scarcity of well-tested equations available for quick-flow runoff at the monthly timescale. Data were gathered from a set of 1301 gaged watersheds across the United States to test a range of equations from the literature, along with several alternative equations, to assess and compare their performance in predicting quick-flow runoff at the monthly timescale. The highest-performing equation was selected for application to monthly maps of explanatory variables to produce monthly quick-flow runoff water budget contribution maps. This equation is a regression against precipitation, soil saturated hydraulic conductivity, surficial geology type, and slope data. Its application indicates that average quick-flow runoff across the conterminous United States in the winter exceeds that in the summer by up to a factor of three. The monthly maps were explored and evaluated for the timespan of 2000-2015. The comparison of equation forms and produced monthly maps will be useful for a variety of hydrologic modeling and monitoring applications.

Journal of Hydrology↗
USGS2024

Phenotypic homogenization and potential fitness constraints following non-native introgression in an endemic sportfish

Introgressive hybridization may lead to contrasting evolutionary outcomes that are difficult to predict since they depend on the fitness effects of endogenous genomic interactions and environmental factors. Conservation of endemic biodiversity may be more effective with require direct measurement of introgressed ancestry and fitness in wild populations, especially for keystone taxa at risk of hybridization following species introductions. We assessed the relationship of non-native ancestry with growth and body condition in the basin-restricted Neosho Bass ( Micropterus velox ; NB), focussing on two streams in the NB native range that are admixed extensively with non-native Smallmouth Bass ( M. dolomieu ; SMB). We quantified the genetic composition of 116 fish from Big Sugar Creek ( N = 46) and Elk River ( N = 70) at 14 microsatellite loci. Using back-calculated total length-at-age estimated from sagittal otoliths, we assessed whether genetic ancestry explained variation in von Bertalanffy growth model parameters, accounting for sex and stream effects. We then assessed the relationship between ancestry and body condition. We found no differences in growth parameters by sex, stream, or ancestry, suggesting phenotypic homogenization which could be mediated by selection on body size. We found a negative correlation between SMB ancestry and condition, including lower condition in Big Sugar Creek, possibly reflecting a trade-off between maximum length and condition with respect to overall fitness. We show that ongoing non-native introgression, which may be augmented by anthropogenic SMB introductions, may attenuate evolutionary differentiation between species and directly influence fitness, possibly having critical implications for long-term persistence and management of adaptive potential in a popular and ecologically important endemic sportfish.

Journal of Evolutionary Biology↗
USGS2022

Perspectives on premetamorphic stratabound tourmalinites

Stratabound tourmalinites are metallogenically important rocks that locally show a close spatial association with diverse types of mineralization, especially volcanogenic massive sulfides (VMS) and clastic-dominated (CD) Zn-Pb deposits. These tourmalinite occurrences pan the geologic record from Eoarchean to Jurassic. Host lithologies are dominated by clastic metasedimentary rocks but in some areas include metavolcanic rocks, marble, or metaevaporites. Stratabound and stratiform (conformable) tourmalinites commonly display sedimentary structures such as graded beds, cross-beds, and rip-up clasts. In most cases, field and microtextural relationships are consistent with a synsedimentary to the early diagenetic introduction of boron as a precursor to tourmaline formation. Whole-rock geochemical data for major, trace, and rare earth elements (REE) provide valuable insights into tourmalinite origins. Al-normalized values relative to those for least-altered host metasedimentary rocks suggest that tourmalinites in proximal settings at or near hydrothermal vent sites characterized by high fluid/rock regimes (e.g., Sullivan Pb-Zn-Ag deposit, Canada) have very different signatures than those in low fluid/rock, distal settings (e.g., Broken Hill Pb-Zn-Ag deposit, Australia). The high fluid/rock regimes at Sullivan show large mass changes of +60 % for Mg and +180 % for Mn, as well as large variations in abundances of light and middle REE. In contrast, tourmalinite formation in low fluid/rock regimes yields minimal Al-normalized changes in major elements, trace elements, and REE. Boron isotope values of tourmalinite-hosted tourmaline vary widely from -26.1 to +27.5 ‰, and are attributed mainly to boron sources (e.g., sediments, evaporites) with generally minor influence from processes such as formational temperature, fluid/rock ratio, and secular variation in seawater δ 11 B values. Laterally extensive stratiform tourmalinites formed mainly by syngenetic or early diagenetic processes on or beneath the seafloor. The syngenetic process is attributed to the interaction of vented B-rich brines with aluminous minerals in sediments, whereas the diagenetic process involves the selective replacement of aluminous sediments by B-rich fluids. Modern examples of tourmalinites, as yet undiscovered, may exist in metalliferous sediments of the Red Sea and the eastern Pacific Ocean, in altered volcaniclastic sediments within active seafloor-hydrothermal systems of the South Pacific, and in hydrothermal mounds and vents associated with mafic sill complexes in extensional basins as in the North Sea and South China Sea. Stratabound tourmalinites that contain base-metal sulfides, high Mn concentrations (>1 wt. % MnO), or positive Eu anomalies can be valuable exploration guides for base-metal sulfide deposits in sedimentary and volcanic terranes.

Journal of Geosciences↗