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At least 793 records · Page 44Linked to original sources
USGS2008

Assessment of Undiscovered Technically Recoverable Oil and Gas Resources of the Bakken Formation, Williston Basin, Montana and North Dakota, 2008

The U.S. Geological Survey (USGS) has completed an assessment of the undiscovered oil and associated gas resources of the Upper Devonian to Lower Mississippian Bakken Formation in the U.S. portion of the Williston Basin of Montana and North Dakota and within the Williston Basin Province. The assessment is based on geologic elements of a total petroleum system (TPS), which include (1) source-rock distribution, thickness, organic richness, maturation, petroleum generation, and migration; (2) reservoir-rock type (conventional or continuous), distribution, and quality; and (3) character of traps and time of formation with respect to petroleum generation and migration. Framework studies in stratigraphy and structural geology and modeling of petroleum geochemistry, combined with historical exploration and production analyses, were used to estimate the undiscovered, technically recoverable oil resource of the Bakken Formation. Using this framework, the USGS defined a Bakken-Lodgepole TPS and seven assessment units (AU) within the system. For the Bakken Formation, the undiscovered oil and associated gas resources were quantitatively estimated for six of these AUs.

Open-File Report↗
USGS2023

The duration and characteristics of magmatic differentiation from basalt to trachyte within the Matan volcanic center, northern Harrat Rahat, Kingdom of Saudi Arabia

A fundamental goal of igneous petrology is to quantify the durations required to produce evolved magmas following influx of basalt into the crust. However, in many cases, complex field relations and (or) the presence of a long-lived magmatic system make it difficult to assess how basaltic inputs relate to more evolved magmas, therefore precluding calculation of meaningful timescales. Here we present field relations, geochemistry, 40 Ar/ 39 Ar ages, and 36 Cl surface-exposure ages for volcanic rocks from the Matan volcanic center, located in the northern part of the Harrat Rahat volcanic field, in the Kingdom of Saudi Arabia. These data document a systematic and repeated temporal progression from alkali basalt to trachyte for the youngest eruptive products. From ~155–17 thousand years ago, the following eruptive sequence occurred four times: (1) alkali basalt, (2) hawaiite, mugearite, or benmoreite, and (3) trachyte. We interpret each eruptive sequence to result from injection of basalt into the crust, and its subsequent differentiation and eruption of progressively evolved magmas. We use the interval time between successive eruptions within a given sequence to calculate the timespans required to produce trachyte from alkali basalt. Differentiation from alkali basalt to intermediate compositions (hawaiite, mugearite, and benmoreite) took ≤3 thousand years (k.y.) on average. Differentiation from intermediate compositions to trachyte took a maximum of 6.7±3.6 to 22.9±1.7 k.y. Thus, the total duration of differentiation was ~10–25 k.y. Timescales presented here are independent of the processes evoked to drive differentiation because they are based solely on the ages and compositions of eruptive products from a system characterized by a simple, repeated differentiation sequence.

northern Harrat Rahat↗
USGS2024

Mantle melting in regions of thick continental lithosphere: Examples from Late Cretaceous and younger volcanic rocks, Southern Rocky Mountains, Colorado (USA)

Major- and trace-element data together with Nd and Sr isotopic compositions and 40 Ar/ 39 Ar age determinations were obtained for Late Cretaceous and younger volcanic rocks from north-central Colorado, USA, in the Southern Rocky Mountains to assess the sources of mantle-derived melts in a region underlain by thick (≥150 km) continental lithosphere. Trachybasalt to trachyandesite lava flows and volcanic cobbles of the Upper Cretaceous Windy Gap Volcanic Member of the Middle Park Formation have low εNd(t) values from −3.4 to −13, 87 Sr/ 86 Sr(t) from ~0.705 to ~0.707, high large ion lithophile element/high field strength element ratios, and low Ta/Th (≤0.2) values. These characteristics are consistent with the production of mafic melts during the Late Cretaceous to early Cenozoic Laramide orogeny through flux melting of asthenosphere above shallowly subducting and dehydrating oceanic lithosphere of the Farallon plate, followed by the interaction of these melts with preexisting, low εNd(t), continental lithospheric mantle during ascent. This scenario requires that asthenospheric melting occurred beneath continental lithosphere as thick as 200 km, in accordance with mantle xenoliths entrained in localized Devonian-age kimberlites. Such depths are consistent with the abundances of heavy rare earth elements (Yb, Sc) in the Laramide volcanic rocks, which require parental melts derived from garnet-bearing mantle source rocks. New 40 Ar/ 39 Ar ages from the Rabbit Ears and Elkhead Mountains volcanic fields confirm that mafic magmatism was reestablished in this region ca. 28 Ma after a hiatus of over 30 m.y. and that the locus of volcanism migrated to the west through time. These rocks have εNd(t) and 87 Sr/ 86 Sr(t) values equivalent to their older counterparts (−3.5 to −13 and 0.7038–0.7060, respectively), but they have higher average chondrite-normalized La/Yb values (~22 vs. ~10), and, for the Rabbit Ears volcanic field, higher and more variable Ta/Th values (0.29–0.43). The latter are general characteristics of all other post– 40 Ma volcanic rocks in north-central Colorado for which literature data are available. Transitions from low to intermediate Ta/Th mafic volcanism occurred diachronously across southwest North America and are interpreted to have been a consequence of melting of continental lithospheric mantle previously metasomatized by aqueous fluids derived from the underthrusted Farallon plate. Melting occurred as remnants of the Farallon plate were removed and the continental lithospheric mantle was conductively heated by upwelling asthenosphere. A similar model can be applied to post–40 Ma magmatism in north-central Colorado, with periodic, east to west, removal of stranded remnants of the Farallon plate from the base of the continental lithospheric mantle accounting for the production, and western migration, of volcanism. The estimated depth of the lithosphere-asthenosphere boundary in north-central Colorado (~150 km) indicates that the lithosphere remains too thick to allow widespread melting of upwelling asthenosphere even after lithospheric thinning in the Cenozoic. The preservation of thick continental lithospheric mantle may account for the absence of oceanic-island basalt–like basaltic volcanism (high Ta/Th values of ~1 and εNd[t] > 0), in contrast to areas of southwest North America that experienced larger-magnitude extension and lithosphere thinning, where oceanic-island basalt–like late Cenozoic basalts are common.

Geosphere↗
USGS2002

Is there a basin-centered gas accumulation in Cotton Valley group sandstones, Gulf Coast basin, U.S.A.?

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is reevaluating the resource potential of selected domestic basin-centered gas accumulations. Basin-centered gas accumulations are characterized by presence of gas in extensive low-permeability (tight) reservoirs in which conventional seals and trapping mechanisms are absent, abnormally high or low reservoir pressures exist, and gas-water contacts are absent. In 1995, the USGS assessed one basin-centered gas play and two conventional plays within the trend of Jurassic and Cretaceous Cotton Valley Group fluvial-deltaic and barrier island/strand plain sandstones across the onshore northern Gulf of Mexico Basin. Detailed evaluation of geologic and production data provides new insights into these Cotton Valley plays. Two Cotton Valley sandstone trends are identified based on reservoir properties and gas-production characteristics. Transgressive blanket sandstones across northern Louisiana have relatively high porosity and permeability and do not require fracture stimulation to produce gas at commercial rates. South of this trend, and extending westward into eastern Texas, massive sandstones of the Cotton Valley trend exhibit low porosity and permeability and require fracture stimulation. The high permeability of Cotton Valley blanket sandstones is not conducive to the presence of basin-centered gas, but low permeability massive sandstones provide the type of reservoir in which basin-centered gas accumulations commonly occur. Data on source rocks, including burial and thermal history, are consistent with the interpretation of potential basin centered gas within Cotton Valley sandstones. However, pressure gradients throughout most of the blanket- and massive sandstone trends are normal or nearly normal, which is not characteristic of basin-centered gas accumulations. The presence of gas-water contacts in at least seven fields across the blanket-sandstone trend together with relatively high permeabilities and high gas-production rates without fracture stimulation indicate that fields in this trend are conventional. Within the tight massive-sandstone trend, permeability is sufficiently low that gas-water transition zones are vertically extensive and gas-water contacts either have not been encountered or are poorly defined. With increasing depth through these transition zones, gas saturation decreases and water saturation increases until eventually gas saturations become sufficiently low that, in terms of ultimate cumulative production, wells are noncommercial. Such progressive increase in water saturation with depth suggests that poorly defined gas-water contacts probably are present below the depth at which wells become noncommercial. The interpreted presence of gas-water contacts within the tight, Cotton Valley massive-sandstone trend suggests that gas accumulations in this trend, too, are conventional, and that a basin-centered gas accumulation does not exist within Cotton Valley sandstones in the northern Gulf Basin.

Louisiana, Texas↗
USGS1980

Evaporite encrustations and sulphide oxidation products from the southern Antarctic peninsula.

White evaporite encrustations collected from 66 sites scattered over 30 000km2 of S.Antarctic Peninsula are dominantly gypsum and calcite, and subordinate aragonite and thenardite. Natrojarosite occurs as locally developed yellow surface stains on c30% of the white encrustations examined. Water, which forms by the melting of snow blown into cracks in highly fractured rocks by ground blizzards, dissolves soluble ions from minerals in these rocks as it percolates into them. The white encrustations appear to be deposited when this water later rises to the surface by capillary action and evaporates.-from Author Antarctica chemical weathering evaporites sulphide oxidation.

New Zealand Journal of Geology and Geophysics↗
USGS2018

Using high-resolution aeromagnetic surveys to map subsurface hydrogeology in sediment-filled basins: A case study over the Rio Grande Rift, Central New Mexico, USA

High-resolution aeromagnetic surveys were acquired for the Albuquerque basin in the central Rio Grande rift, a basin filled with poorly consolidated sediments. The surveys proved successful in efficiently and economically mapping previously unknown hydrogeologic features of the shallow subsurface. This success suggests that aeromagnetic methods may be useful in hydrogeologic studies of other sediment-filled basins. The aeromagnetic surveys were used primarily to delineate buried igneous rocks and to locate faults within the basin fill, both important for understanding the subsurface hydrogeology. Buried igneous rocks were recognized from their high-frequency, high-amplitude magnetic responses and characteristic map patterns. The horizontal-gradient and local wavenumber methods were used to obtain estimates of their source depths. The aeromagnetic surveys were also successfully used to locate faults within the basin fill. Magnetic signatures associated with faults are produced by the juxtaposition of sediments having differing magnetic properties rather than the products of secondary processes. Expression of faults is abundant throughout the basin, revealing patterns that cannot be mapped at the surface due to widespread cover. A fault signature recognized in the high-resolution data that has multiple inflection points is best explained by a fault with a thin magnetic layer on the upthrown block and thick magnetic layer on the downthrown block, called the thin-thick layers model. Geologically, this signature indicates erosion of the upthrown block or a growth-faulting scenario: fault-controlled sedimentation for faults that offset sediments, and successive accumulation of basalt on the downthrown block for faults that offset volcanic rocks.

New Mexico↗
USGS1981

A transient laboratory method for determining the hydraulic properties of 'tight' rocks-II. Application

In Part I a general analytical solution for the transient pulse test was presented. Part II presents a graphical method for analyzing data from a test to obtain the hydraulic properties of the sample. The general solution depends on both hydraulic conductivity and specific storage and, in theory, analysis of the data can provide values for both of these hydraulic properties. However, in practice, one of two limiting cases may apply in which case it is possible to calculate only hydraulic conductivity or the product of hydraulic conductivity times specific storage. In this paper we examine the conditions when both hydraulic parameters can be calculated. The analyses of data from two tests are presented. In Appendix I the general solution presented in Part I is compared with an earlier analysis, in which compressive storage in the sample is assumed negligible, and the error in calculated hydraulic conductivity due to this simplifying assumption is examined.

International Journal of Rock Mechanics and Mining↗
USGS2019

Chesapeake Bay impact structure—Development of "brim" sedimentation in a multilayered marine target

The late Eocene Chesapeake Bay impact structure was formed in a multilayered target of seawater underlain sequentially by a sediment layer and a rock layer in a continental-shelf environment. Impact effects in the “brim” (annular trough) surrounding and adjacent to the transient crater, between the transient crater rim and the outer margin, primarily were limited to the target-sediment layer. Analysis of published and new lithostratigraphic, biostratigraphic, sedimentologic, petrologic, and mineralogic studies of three core holes, and published studies of a fourth core hole, provided information for the interpretation of the impact processes, their interactions and relative timing, their resulting products, and sedimentation in the brim. Most studies of marine impact-crater materials have focused on those found in the central crater. There are relatively few large, complex marine craters, of which most display a wide brim around the central crater. However, most have been studied using minimal data sets. The large number of core holes and seismic profiles available for study of the Chesapeake Bay impact structure presents a special opportunity for research. The physical and chronologic records supplied by study of the sediment and rock cores of the Chesapeake Bay impact indicate that the effects of the initial, short-lived contact and compression and excavation stages of the impact event primarily were limited to the transient crater. Only secondary effects of these processes are evident in the brim. The preserved record of the brim was created primarily in the subsequent modification stage. In the brim, the records of early impact processes (e.g., outgoing tsunamis, overturned flap collapse) were modified or removed by later processes. Transported and rotated, large and small clasts of target sediments, and intervals of fluidized sands indicate that seismic shaking fractured and partially fluidized the Cretaceous and Paleogene target sediments, which led to their inward transport by collapse and lateral spreading toward the transient crater. The succeeding inward seawater-resurge flow quickly overtook and interacted with the lateral spreading, further facilitating sediment transport across the brim and into the transient crater. Variations in the cohesion and relative depth of the target sediments controlled their degree of disaggregation and redistribution during these events. Melt clasts and shocked and unshocked rock clasts in the resurge sediments indicate fallout from the ejecta curtain and plume. Basal parautochthonous remnant sections of target Cretaceous sediments in the brim thin toward the collapsed transient crater. Overlying seawater-resurge deposits consist primarily of diamictons that vary laterally in thickness, and vertically and laterally in maximum grain size. After cessation of resurge flow and re-establishment of pre-impact sea level, sandy sediment gravity flows moved from the margin to the center of the partially filled impact structure (shelf basin). The uppermost unit consists of stratified sediments deposited from suspension. Postimpact clayey silts cap the crater fill and record the return to shelf sedimentation at atypically large paleodepths within the shelf basin. An unresolved question involves a section of gravel and sand that overlies Neoproterozoic granite in the inner part of the brim in one core hole. This section may represent previously unrecognized, now parautochthonous Cretaceous sediments lying nonconformably above basement granite, or it may represent target sediments that were moved significant distances by lateral spreading above basement rocks or above a granite megaclast from the overturned flap. The Chesapeake Bay impact structure is perhaps the best documented example of the small group of multilayer, marine-target impacts formed in continental shelves or beneath epeiric seas.

Chesapeake Bay↗
USGS2017

Niobium and tantalum

Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors. The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce) 2 (Nb,Ti,Ta) 2 (O,OH,F) 7 ), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the mineral tantalite ((Fe,Mn)(Ta,Nb) 2 O 6 ), which is found as an accessory mineral in rare-metal granites and pegmatites that are also enriched in lithium and cesium (termed lithium-cesium-tantalum (LCT)-type pegmatites). Brazil and Canada are the leading nations that produce niobium mineral concentrates, but Brazil is by far the leading producer, accounting for about 90 percent of production, which comes mostly from weathered material derived from carbonatites. Brazil and Canada also have the largest identified niobium resources; additional resources, although they are less well reported, occur in Angola, Australia, China, Greenland, Malawi, Russia, and South Africa. Australia and Brazil have been the leading producers of tantalum mineral concentrates, although recently Ethiopia and Mozambique have also been significant suppliers of tantalum. Artisanal mining of columbite-tantalite (also called coltan) is practiced in many countries, particularly Burundi, the Democratic Republic of the Congo (Congo [Kinshasa]), Nigeria, Rwanda, and Uganda. Brazil has about 40 percent of the identified tantalum resources; other countries and regions with identified tantalum resources include, in decreasing order of resources, Australia, Asia, Russia and the Middle East, Africa, North America, and Europe. Identified niobium and tantalum resources in the United States are small, low grade, and difficult to recover and process, and are thus not commercially recoverable at current prices. Consequently, the United States meets its current and expected future needs for niobium and tantalum through imports of primary mineral concentrates and alloys and through recovery from foreign and domestic alloy scrap that contain the metals. Environmentally, the main issues related to niobium and tantalum mining are land disruptions, the volume of waste materials and their disposal, and the radioactivity of some tailings and waste materials that contain thorium and uranium. Because of the relative biological inertness of niobium and tantalum, human and ecological health concerns are generally minimal under most natural conditions. Demand for both niobium and tantalum is expected to increase as the world economy continues to recover from the downturn that began in 2008. Increased demand for niobium is linked to increased consumption of microalloyed steel, which is used in the manufacture of cars, buildings, ships, and refinery equipment. Demand for these steels will likely increase with continued economic development in such countries as Brazil, China, and India. In addition, increased global demand for cars, cell phones, computers, superconducting magnets, and other high-tech devices will likely spur increased demand for both niobium and tantalum. The estimated global reserves and resources of niobium and tantalum are large and appear more than sufficient to meet global demand for the foreseeable future, possibly the next 500 years. The sale of “conflict coltan” attributed to rebel forces waging a civil war in Congo (Kinshasa) has been of recent concern and has highlighted the need for a transparent and traceable global supply chain that can exclude illegal columbite-tantalite from the conventional market while discerning legitimate artisanal mine production in central Africa.

Professional Paper↗
USGS2004

Ancient wet aeolian environments on Earth: Clues to presence of fossil/live microorganisms on Mars

Ancient wet aeolian (wet-sabkha) environments on Earth, represented in the Entrada and Navajo sandstones of Utah, contain pipe structures considered to be the product of gas/water release under pressure. The sediments originally had considerable porosity allowing the ingress of living plant structures, microorganisms, clay minerals, and fine-grained primary minerals of silt and sand size from the surface downward in the sedimentary column. Host rock material is of a similar size and porosity and presumably the downward migration of fine-grained material would have been possible prior to lithogenesis and final cementation. Recent field emission scanning electron microscopy (FESEM) and EDS (energy-dispersive spectrometry) examination of sands from fluidized pipes in the Early Jurassic Navajo Sandstone reveal the presence of fossil forms resembling fungal filaments, some bearing hyphopodium-like structures similar to those produced by modern tropical leaf parasites. The tropical origin of the fungi is consistent with the paleogeography of the sandstone, which was deposited in a tropical arid environment. These fossil fungi are silicized, with minor amounts of CaCO3 and Fe, and in some cases a Si/Al ratio similar to smectite. They exist as pseudomorphs, totally depleted in nitrogen, adhering to the surfaces of fine-grained sands, principally quartz and orthoclase. Similar wet aeolian paleoenvironments are suspected for Mars, especially following catastrophic sediment-charged floods of enormous magnitudes that are believed to have contributed to rapid formation of large water bodies in the northern plains, ranging from lakes to oceans. These events are suspected to have contributed to a high frequency of constructional landforms (also known as pseudocraters) related to trapped volatiles and water-enriched sediment underneath a thick blanket of materials that were subsequently released to the martian surface, forming piping structures at the near surface and constructional landforms at the surface. This constructional process on Mars may help unravel the complex history of some of the piping structures observed on Earth; on Earth, evidence for the constructional landforms has been all but erased and the near-surface piping structures exposed through millions of years of differential erosion and topographic inversion now occur as high-standing promontories. If the features on both Earth and Mars formed by similar processes, especially involving water and other volatiles, and since the piping structures of Earth provided suitable environments for life to thrive in, the martian features in the northern plains should be considered as prime targets for physico/mineral/chemical/microbiological analyses once the astrobiological exploration of the red planet begins in earnest. ?? 2004 Elsevier Inc. All rights reserved.

Icarus↗
USGS1962

Nordstrandite from Guam

NORDSTRANDITE (Al 2 O 3 ·3H 2 O), previously reported only as a synthetic product 1,2 , occurs in Miocene limestone on Guam. In south Guam this limestone forms a cap several hundred feet thick, on the Mount Alifan–Mount Lamlan ridge, and overlies late Eocene and early Miocene basalt flows and volcanic conglomerates. The volcanic rocks below the limestone are deeply weathered. The nordstrandite occurs in secondary solution cavities and is concentrated mainly in the basal part of the limestone near its contact with the weathered basalt. In thin section the nordstrandite crystals are seen as flamboyant aggregates reaching lengths of as much as 0.4 mm. The optical properties of the mineral are as follows: The hardness is about 3 and the specific gravity was determined by Edward J. Young to be 2.436.

Guam↗
USGS2001

Geologic map of the Chewelah 30' x 60' Quadrangle, Washington and Idaho

This data set maps and describes the geology of the Chewelah 30' X 60' quadrangle, Washington and Idaho. Created using Environmental Systems Research Institute's ARC/INFO software, the data base consists of the following items: (1) a map coverage containing geologic contacts and units, (2) a point coverage containing site-specific geologic structural data, (3) two coverages derived from 1:100,000 Digital Line Graphs (DLG); one of which represents topographic data, and the other, cultural data, (4) two line coverages that contain cross-section lines and unit-label leaders, respectively, and (5) attribute tables for geologic units (polygons), contacts (arcs), and site-specific data (points). In addition, the data set includes the following graphic and text products: (1) A PostScript graphic plot-file containing the geologic map, topography, cultural data, and two cross sections, and on a separate sheet, a Correlation of Map Units (CMU) diagram, an abbreviated Description of Map Units (DMU), modal diagrams for granitic rocks, an index map, a regional geologic and structure map, and a key for point and line symbols; (2) PDF files of the Readme text-file and expanded Description of Map Units (DMU), and (3) this metadata file. The geologic map database contains original U.S. Geological Survey data generated by detailed field observation and by interpretation of aerial photographs. The map was compiled from geologic maps of eight 1:48,000 15' quadrangle blocks, each of which was made by mosaicing and reducing the four constituent 7.5' quadrangles. These 15' quadrangle blocks were mapped chiefly at 1:24,000 scale, but the detail of the mapping was governed by the intention that it was to be compiled at 1:48,000 scale. The compilation at 1:100,000 scale entailed necessary simplification in some areas and combining of some geologic units. Overall, however, despite a greater than two times reduction in scale, most geologic detail found on the 1:48,000 maps is retained on the 1:100,000 map. Geologic contacts across boundaries of the eight constituent quadrangles required minor adjustments, but none significant at the final 1:100,000 scale. The geologic map was compiled on a base-stable cronoflex copy of the Chewelah 30' X 60' topographic base and then scribed. The scribe guide was used to make a 0.007 mil-thick blackline clear-film, which was scanned at 1200 DPI by Optronics Specialty Company, Northridge, California. This image was converted to vector and polygon GIS layers and minimally attributed by Optronics Specialty Company. Minor hand-digitized additions were made at the USGS. Lines, points, and polygons were subsequently edited at the USGS by using standard ARC/INFO commands. Digitizing and editing artifacts significant enough to display at a scale of 1:100,000 were corrected. Within the database, geologic contacts are represented as lines (arcs), geologic units as polygons, and site-specific data as points. Polygon, arc, and point attribute tables (.pat, .aat, and .pat, respectively) uniquely identify each geologic datum.

Miscellaneous Field Studies Map↗
USGS2010

Karst map of Puerto Rico

This map is a digital compilation, combining the mapping of earlier geologists. Their work, cited on the map, contains more detailed descriptions of karst areas and landforms in Puerto Rico. This map is the basis for the Puerto Rico part of a new national karst map currently being compiled by the U.S. Geological Survey. In addition, this product is a standalone, citable source of digital karst data for Puerto Rico. Nearly 25 percent of the United States is underlain by karst terrain, and a large part of that area is undergoing urban and industrial development. Accurate delineations of karstic rocks are needed at scales suitable for national, State, and local maps. The data on this map contribute to a better understanding of subsidence hazards, groundwater contamination potential, and cave resources as well as serve as a guide to topical research on karst. Because the karst data were digitized from maps having a different scale and projection from those on the base map used for this publication, some karst features may not coincide perfectly with physiographic features portrayed on the base map.

Puerto Rico↗
USGS1977

Summary appraisals of the Nation's ground-water resources; Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snow fall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55° to 118°F (-48.3° to 47.8°C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important fresh-water aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground-water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5 x 10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Fresh water could be stored in saline- or fresh-water aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use and pollution.

Minnesota, Montana, North Dakota, South Dakota↗
USGS2011

Hydrogeologic framework and hydrologic budget components of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers an area of about 44,000 square miles in a structural and topographic basin within the drainage of the Columbia River in Washington, Oregon, and Idaho. The primary aquifers are basalts of the Columbia River Basalt Group (CRBG) and overlying sediment. Eighty percent of the groundwater use in the study area is for irrigation, in support of a $6 billion per year agricultural economy. Water-resources issues in the Columbia Plateau include competing agricultural, domestic, and environmental demands. Groundwater levels were measured in 470 wells in 1984 and 2009; water levels declined in 83 percent of the wells, and declines greater than 25 feet were measured in 29 percent of the wells. Conceptually, the system is a series of productive basalt aquifers consisting of permeable interflow zones separated by less permeable flow interiors; in places, sedimentary aquifers overly the basalts. The aquifer system of the CPRAS includes seven hydrogeologic units-the overburden aquifer, three aquifer units in the permeable basalt rock, two confining units, and a basement confining unit. The overburden aquifer includes alluvial and colluvial valley-fill deposits; the three basalt units are the Saddle Mountains, Wanapum, and Grande Ronde Basalts and their intercalated sediments. The confining units are equivalent to the Saddle Mountains-Wanapum and Wanapum-Grande Ronde interbeds, referred to in this study as the Mabton and Vantage Interbeds, respectively. The basement confining unit, referred to as Older Bedrock, consists of pre-CRBG rocks that generally have much lower permeabilities than the basalts and are considered the base of the regional flow system. Based on specific-capacity data, median horizontal hydraulic conductivity (Kh) values for the overburden, basalt units, and bedrock are 161, 70, and 6 feet per day, respectively. Analysis of oxygen isotopes in water and carbon isotopes in dissolved inorganic carbon from groundwater samples indicates that groundwater in the CPRAS ranges in age from modern (<50 years) to Pleistocene (>10,000 years). The oldest groundwater resides in deep, downgradient locations indicating that groundwater movement and replenishment in parts of this regional aquifer system have operated on long timescales under past natural conditions, which is consistent with the length and depth of long flow paths in the system. The mean annual recharge from infiltration of precipitation for the 23-year period 1985-2007 was estimated to be 4.6 inches per year (14,980 cubic feet per second) using a polynomial regression equation based on annual precipitation and the results of recharge modeling done in the 1980s. A regional-scale hydrologic budget was developed using a monthly SOil WATer (SOWAT) Balance model to estimate irrigation-water demand, groundwater flux (recharge or discharge), direct runoff, and soil moisture within irrigated areas. Mean monthly irrigation throughout the study area peaks in July at 1.6 million acre-feet (MAF), of which 0.45 and 1.15 MAF are from groundwater and surface-water sources, respectively. Annual irrigation water use in the study area averaged 5.3 MAF during the period 1985-2007, with 1.4 MAF (or 26 percent) supplied from groundwater and 3.9 MAF supplied from surface water. Mean annual recharge from irrigation return flow in the study area was 4.2 MAF (1985-2007) with 2.1 MAF (50 percent) occurring within the predominately surface-water irrigated regions of the study area. Annual groundwater-use estimates were made for public supply, self-supplied domestic, industrial, and other uses for the period 1984 through 2009. Public supply groundwater use within the study area increased from 200,600 acre-feet per year (acre-ft/yr) in 1984 to 269,100 acre-ft/yr in 2009. Domestic self-supplied groundwater use increased from 54,580 acre-ft/yr in 1984 to 71,160 acre-ft/yr in 2009. Industrial groundwater use decreased from 53,390 acre-ft/yr in 1984 t

Scientific Investigations Report↗
USGS1978

Origin of two clay-mineral facies of the Potomac Group (Cretaceous) in the Middle Atlantic States

Sedimentary clay that crops out in the coastal plains of New Jersey, Delaware, the part of Maryland north and east of Washington, B.C., and the northeast half of Washington, D.C., in the nonmarine Cretaceous Potomac Group is predominantly kaolinite and illite. In contrast, in part of southeastern Maryland, the southwest half of Washington, D.C., and most of eastern Virginia, Potomac Group clay is predominantly montmorillonite. Kaolinite and illite were probably derived by intense acid weathering of metamorphic and granitic rocks to the west during the Cretaceous and were deposited in a well-drained basin. Montmorillonite was most likely produced by deep weathering of a mainly granitic source. Poor drainage and alkaline surface- and ground-water conditions probably accompanied the production, transportation, deposition, and burial of the montmorillonite. Kaolinization of the montmorillonite is taking place now at the surface in northern Virginia.

Delaware, Maryland, New Jersey, Pennsylvania, Virg↗
USGS2002

Environmental impacts of petroleum production: The fate of petroleum and other organics associated with produced water from the Osage-Skiatook Petroleum Environmental Research sites, Osage County, OK

We are involved in a multidisciplinary investigation to study the transport, fate, and natural attenuation of inorganic salts, trace metals, radionuclides and organic compounds present in produced water, and their impacts on soil, surface and ground water and the local ecosystem at the Osage-Skiatook Petroleum Environmental Research (OSPER) A and B sites, located in Osage County, OK. About one hectare of land at each of the OSPER A and B sites is affected by salt scarring, soil salinization and brine and petroleum contamination. The main environmental concern results because the sites are adjacent to Skiatook Lake, a 4250-hectare reservoir that provides drinking water to the local communities and is a major recreational fishery. Petroleum wells and tank batteries at the A site have been inactive for some time and the bulk of the hydrocarbon (now degraded and weathered oil) and produced water releases occurred more than 60 years ago. One pit at this site however, contains relatively fresh asphaltic oil and high salinity brine. The B site includes an active production tank battery and adjacent brine and oil pit, an inactive tank battery and an injection well with a small brine pit. For this study oil, gas and/or brine samples were obtained from several oil wells at the B site and areas adjoining the A and B sites, from the two active brine pits at the B site, from the asphaltic pit and adjacent weathered oil pit at the A site and from several of the 40 boreholes (1-71 m deep), recently drilled and completed. Water samples for dissolved organics were obtained from selected boreholes with high salinity water and measurable hydrocarbon gases in the unsaturated zone. Soil and rock core samples were obtained from these selected boreholes to determine the amount and composition of oil sorbed onto the sediments. Finally samples of sediments and/or water from these selected boreholes and from the brine and oil pits were obtained for bacterial characterization. Chemical analysis and bacterial determinations on the collected samples are continuing. Results completed to date show the crude oil source (samples from B and adjacent production wells) is a typical paraffinic-naphthenic light (API gravity of ~35) oil, containing n-alkanes as the dominant components. The four samples examined are identical in their maturity and chemical characteristics. Even though petroleum production is from shallow sandstones (300-600 m depth), these fresh oils show no sign of biodegradation, indicating that bacteria are unable to survive in the associated high salinity (~150,000 mg/L total dissolved solids) brine. Bacterial action, volatilization and water washing are likely responsible for the transformation of source oil to the surficial asphaltic and weathered oil observed at the A site. The leakage of oil with brine from the main active pit at the B site is indicated by the detection of a thin, but discrete oil phase in at least one borehole, the presence of hydrocarbon gases in several boreholes and the smell of oil in many sediment cores from the impacted area located down gradient from this pit. The measured concentrations of DOC, acetate and other organic acid anions, BTEX, phenols and other organics in the source brine are relatively low, but their values in water samples from the impacted areas are not yet available.

Oklahoma↗
USGS1987

Mineralogy and petrology of the Cretaceous- Tertiary boundary clay bed and adjacent clay-rich rocks, Raton Basin, New Mexico and Colorado.

The Cretaceous-Tertiary (K-T) boundary is preserved in a sequence of coal-bearing, fluvial rocks in the lower part of the Raton Formation (Late Cretaceous and Paleocene) at several sites in the east-central part of the Raton Basin. The K-T boundary occurs at the top of a kaolinitic claystone layer, commonly referred to as the "boundary clay layer," in an interval of coal and carbonaceous shale. The boundary is defined by the disappearance of certain fossil-pollen taxa. The boundary clay layer also contains shocked quartz grains and abundance anomalies of iridium, chromium, and other elements. Each of these characteristics support the hypothesis of an asteroid impact at the end of the Cretaceous. Small goyazite spheres were also found in the boundary clay bed; however, their origin is uncertain. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and thin-section petrography have shown that the boundary clay bed exhibits unique mineralogic and petrologic characteristics not possessed by other clay-rich beds in coal-bearing rocks of the Raton Basin. The boundary clay bed is composed primarily of well-crystallized kaolinite but also contains subordinate, randomly interstratified, mixed-layer illite/smectite, both of which appear to have been formed by the alteration of vitreous material in a coal-swamp environment. The bulk mineralogy of the boundary clay bed is similar to that of other kaolinite-rich clay beds (tonsteins) that altered in coal swamps from airfall volcanic ash. The alteration process and diagenetic products of the host material in the boundary clay bed, however, differed from those of the tonsteins, resulting in a unique petrographic fabric. The boundary clay bed is characterized by an overall imbricate fabric that may reflect an original vitreous material that included shards, bubbles, and spheres. The original fallout material of the boundary clay bed first altered to "cabbage-like" microspherules, indicating a halloysite or allophane precursor, and then to well-crystallized kaolinite; the well-crystallized kaolinite is the diagenetic stable phase for these rocks at their maximum burial conditions. In comparison, the vitreous components of the tonsteins were altered directly to coarse vermicular and platey kaolinite. Alteration of the original fallout material in the boundary bed was probably rapid, leading to hydrated, disordered, fine-grained clay minerals that formed into curled spherical or tubular shapes. The factors that produced these unique fabrics in the boundary clay bed existed at all K-T sites in the Raton Basin and were much different from those that formed the coarse platey and vermicular fabrics of ordinary tonsteins. The distinctive character of the boundary clay may be due to the unique nature and chemistry of the fallout material and (or) physical or chemical conditions existing shortly after its deposition.

Journal of Sedimentary Petrology↗