Search USGS⌕ Search

SEARCH · Search USGS

Results for “Clear Waters”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44Linked to original sources

Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams

Climate change in the Arctic is altering watershed hydrologic processes and biogeochemistry. Here, we present an emergent threat to Arctic watersheds based on observations from 75 streams in Alaska’s Brooks Range that recently turned orange, reflecting increased loading of iron and toxic metals. Using remote sensing, we constrain the timing of stream discoloration to the last 10 years, a period of rapid warming and snowfall, suggesting impairment is likely due to permafrost thaw. Thawing permafrost can foster chemical weathering of minerals, microbial reduction of soil iron, and groundwater transport of metals to streams. Compared to clear reference streams, orange streams have lower pH, higher turbidity, and higher sulfate, iron, and trace metal concentrations, supporting sulfide mineral weathering as a primary mobilization process. Stream discoloration was associated with dramatic declines in macroinvertebrate diversity and fish abundance. These findings have considerable implications for drinking water supplies and subsistence fisheries in rural Alaska.

Alaska↗

Holocene paleoenvironments of Northeast Iowa

This paper presents the biotic, sedimentary, geomorphic, and climatic history of the upper part of the Roberts Creek Basin, northeastern Iowa for the late—glacial and Holocene, and compares these records with a C—O isotopic sequence from Coldwater Cave, 60 km northwest of Roberts Creek. The biotic record (pollen, vascular plant and bryophyte macrofossils, and insects) is preserved in floodplain alluvium that underlies three constructional surfaces separated by low scarps. Each surface is underlain by a lithologically and temporally distinct alluvial fill. The highest surface is underlain by the Gunder Member of the Deforest Formation, dating from 11 000 to 4000 yr BP; beneath the intermediate level is the Roberts Creek Member, dating from 4000 to 400 yr BP; and the lowest level is underlain by the Camp Creek Member, deposited during the last 380 yr. Pollen and plant macrofossils in the alluvial fill show that a typical late—glacial spruce forest was replaced by Quercus and Ulmus in the early Holocene. This early—to—middle Holocene forest became dominated by mesic elements such as Acer saccharum, Tilia americana, Ostrya virginiana, and Carpinus caroliniana as late as 5500 yr BP; in contrast, the closest sites to the west and north were at their warmest and driest and were covered by prairie vegetation between 6500 and 5500 yr BP. After 5500 yr BP, the forest in the Roberts Creek area was replaced by prairie, as indicated by a rich assemblage of plant macrofossils, although only Ambrosia and Poaceae became abundant in the pollen record. The return of Quercus ≈ 3000 BP (while nonarboreal pollen percentages remained relatively high) indicates that oak savanna prevailed with little change until settlement time. The bryophyte assemblages strongly support the vascular plant record. Rich fen species characteristic of boreal habitats occur only in the late—glacial. They are replaced by a number of deciduous—forest elements when early—to—middle Holocene forests were present, but mosses of forest habitats completely disappear when prairie became dominant. A few deciduous—forest taxa return during the late—Holocene, when oak savanna prevailed. The C—O isotopic record from stalagmite s in Coldwater Cave indicates a relatively stable environment from ≈ 8000 to 5100 yr BP, when the δ 13 C values indicate a change in vegetation dominated by C 3 (predominantly forest) to C 4 (predominantly prairie) plants. About 4900 yr BP, the rise in 18 O values indicates a temperature increase of ≈ 1.5 ° C. The fact that the vegetational change suggested by the δ 13 C values preceded the temperature increase suggests that fire may have been an important factor in converting forest to prairie. Abundant charred seeds and other plant material at Roberts Creek 4830 yr BP support this hypothesis. The 18 O values remain constant from ≈ 5100 to ≈ 3000 yr BP, but the δ 13 C values gradually rise, indicating that soil formed under forest takes at least 2000 yr for its carbon to reach equilibrium after replacement by prairie vegetation. The return of oak to form savanna is reflected in the gradual decline of δ 13 C values in the last 3000 yr BP; O isotopic values drop sharply by ≈ 1 ° C ≈ 2800 yr BP and then were relatively stable. In contrast to the vegetational and isotopic records, the insect assemblages suggest little change in the local environments throughout most of the Holocene. All of the beetle taxa presently occur in eastern Iowa. The relative stability through the Holocene indicates that both open grassland and riparian woodland elements were present throughout. Settlement, land clearing, and land cultivation by EuroAmericans in the region caused rapid erosion of the upland landscape, the deposition of 1—2 m of sediment across the floodplain, a replacement of the native vegetation with ruderal species, a decimation of the native insect fauna, and a degradation of water quality in the stream. These changes in the landscape, vegetation, and insect faunas are as striking as those associated with glacial—interglacial transitions. The timing and direction of changes in the vegetation at Roberts Creek generally correlate well with the carbon and oxygen isotopic record in speleothems at nearby Coldwater Cave and indicate that climate was the main forcing function. However, the contrast between the vegetational change and the stability of the beetle population suggests that climatic changes were subtle. We hypothesize that the factors involved in the Holocene changes were seasonal changes in temperature and precipitation that may not have resulted in much mean annual change. Such changes may have affected the vegetation more than the insect fauna.

Iowa↗

Science needs for determining the effects of climate change on harmful algal blooms in the southeastern United States

The Southeastern United States has many lakes, streams, and reservoirs that serve as important drinking water sources with recreational, agricultural, and ecological uses. However, harmful algal blooms (HABs) are becoming more common in these waters, causing health issues for humans and animals. HABs have been listed as a contaminant of emerging concern, and the magnitude, frequency, and duration of HABs appear to be increasing at the global scale. While it is well known that nutrients stimulate algae growth, it is not clear how climate change and other parameters stimulate the development of toxin production by HABs. The scientific literature describes parameters, such as storm occurrence, temperature, dissolved metals, erosion of soils, increasing length of growing season, discharge, and hydroperiod, that may affect algae growth and toxin production. Climate and hydrologic models address many of the physical and environmental parameters that influence HABs, but no climate models directly address HABs. This report compiles information from the existing literature pertaining to HABs and the modeling and forecasting of HABS. This compilation is done through the incorporation of climate change models. HAB research that involves climate change will require multiple disciplines that bring together ecologists, hydrologists, climatologists, engineers, economists, and new technology. Resource managers could use geographic data about the occurrence and distribution of HABs to develop models that identify waterbodies more vulnerable to HAB events. Development of such models will require teams capable of integrating biological, chemical, and physical factors. Model development will require additional research that can resolve anthropogenic and climate-related environmental factors to identify trends in freshwater HABs. The complexity and interconnectedness of the parameters that influence HAB occurrences will make model development challenging and require rigorous regional calibration.

Open-File Report↗

Biota: Providing often-overlooked connections among freshwater systems

When we think about connections in and among aquatic systems, we typically envision clear headwater streams flowing into downstream rivers, river floodwaters spilling out onto adjacent floodplains, or groundwater connecting wetlands to lakes and streams. However, there is another layer of connectivity moving materials among freshwater systems, one with connections that are not always tied to downgradient flows of surface waters and groundwater. These movements are those of organisms, key components of virtually every freshwater system on the planet. In their movements across the landscape, biota connect aquatic systems in often-overlooked ways.

Water Resources Impact↗

Rare earth, major and trace element composition of Leg 127 sediments

The relative effects of paleoceanographic and paleogeographic variations, sediment lithology, and diagenetic processes on the final preserved chemistry of Japan Sea sediments are evaluated by investigating the rare earth element (REE), major element, and trace element concentrations in 59 squeeze-cake whole-round and 27 physical-property sample residues from Sites 794, 795, and 797, cored during ODP Leg 127. The most important variation in sedimentary chemical composition is the increase in SiO2 concentration through the Pliocene diatomaceous sequences, which dilutes most other major and trace element components by various degrees. This biogenic input is largest at Site 794 (Yamato Basin), moderately developed at Site 797 (Yamato Basin), and of only minor importance at Site 795 (Japan Basin), potentially reflecting basinal contrasts in productivity with the Yamato Basin recording greater biogenic input than the Japan Basin and with the easternmost sequence of Site 794 lying beneath the most productive waters. There are few systematic changes in solid-phase chemistry resulting from the opal-A/opal-CT or opal-CT/quartz silica phase transformations. Most major and trace element concentrations are controlled by the aluminosilicate fraction of the sediment, although the effects of diagenetic silica phases and manganese carbonates are of localized importance. REE total abundances (IREE) in the Japan Sea are strongly dependent upon the paleoceanographic position of a given site with respect to terrigenous and biogenic sources. REE concentrations at Site 794 overall correspond well to aluminosilicate chemical indices and are strongly diluted by SiO2 within the upper Miocene-Pliocene diatomaceous sequence. Eu/Eu* values at Site 794 reach a maximum through the diatomaceous interval as well, most likely suggesting an association of Eu/Eu* with the siliceous component, or reflecting slight incorporation of a detrital feldspar phase. XREE at Site 795 also is affiliated strongly with aluminosilicate phases and yet is diluted only slightly by siliceous input. At Site 797, ΣRE E is not as clearly associated with the aluminosilicate fraction, is correlated moderately to siliceous input, and may be sporadically influenced by detrital heavy minerals originating from the nearby rifted continental fragment composing the Yamato Rise. Ce/Ce* profiles at all three sites increase essentially monotonically with depth and record progressive diagenetic LREE fractionation. The observed Ce/Ce* increases are not responding to changes in the paleoceanographic oxygenation state of the overlying water, as there is no independent evidence to suggest the proper Oceanographic conditions. Ce/Ce* correlates slightly better with depth than with age at the two Yamato Basin sites. The downhole increase in Ce/Ce* at Sites 794 and 797 is a passive response to the diagenetic transfer of LREE (except Ce) from sediment to interstitial water. At Site 795, the overall lack of correlation between Ce/Ce* and La/Y^ suggests that other processes mask the diagenetic behavior of all LREEs. First-order calculations of the Ce budget in Japan Sea waters and sediment indicate that ~20% of the excess Ce adsorbed by settling particles is recycled within the water column and that an additional -38% is recycled at or near the seafloor. Thus, because the remaining excess Ce is only -10% of the total Ce, there is not a large source of Ce to the deeply buried sediment, further suggesting that the downhole increase in Ce/Ce* is a passive response to diagenetic behavior of the other LREEs. The REE chemistry of Japan Sea sediment therefore predicts successive downhole addition of LREEs to deeply buried interstitial waters.

Conference Paper↗

Groundwater chemistry and water-rock interactions at Stripa

Groundwaters from near surface to a depth of 1232 m in the Stripa granite have been sampled and analyzed for major and trace constituents. The groundwater composition consists of two general types: a typical recharge water of Ca-HCO 3 type (<300 m depth) and a deeper Na-Ca-Cl type (>700 m depth) of high pH (8–10) that reaches a maximum of 1250 mg/L in total dissolved solids (TDS). Intermediate depths show mixtures of the two types that are highly fracture-dependent rather than depth-dependent. Any borehole can vary significantly and erratically in TDS for either a horizontal or vertical direction. The general transition from Ca-HCO 3 type to Na-Ca-Cl type correlates with the depth profile for hydraulic conductivity that drops from 10 −8 m/s to 10 −11 m/s or lower. Thermomechanical stress (from heater experiments) clearly shows an effect on the groundwater composition that could be caused by changing flow paths, leakage of fluid inclusions or both. Dissolution and precipitation of calcite, fluorite and barite, aluminosilicate hydrolysis, and addition of a saline source (possibly fluid inclusion leakage) play the major roles in defining the groundwater composition. The low permeability of the Stripa granite has produced a groundwater composition that appears intermediate between the dilute, shallow groundwaters typical of recharge in a crystalline rock terrain and the saline waters and brines typical of cratonic shield areas at depth.

Geochimica et Cosmochimica Acta↗

Survey of beaver-related restoration practices in rangeland streams of the western USA

Poor condition of many streams and concerns about future droughts in the arid and semi-arid western USA have motivated novel restoration strategies aimed at accelerating recovery and increasing water resources. Translocation of beavers into formerly occupied habitats, restoration activities encouraging beaver recolonization, and instream structures mimicking the effects of beaver dams are restoration alternatives that have recently gained popularity because of their potential socioeconomic and ecological benefits. However, beaver dams and dam-like structures also harbor a history of social conflict. Hence, we identified a need to assess the use of beaver-related restoration projects in western rangelands to increase awareness and accountability, and identify gaps in scientific knowledge. We inventoried 97 projects implemented by 32 organizations, most in the last 10 years. We found that beaver-related stream restoration projects undertaken mostly involved the relocation of nuisance beavers. The most common goal was to store water, either with beaver dams or artificial structures. Beavers were often moved without regard to genetics, disease, or potential conflicts with nearby landowners. Few projects included post-implementation monitoring or planned for longer term issues, such as what happens when beavers abandon a site or when beaver dams or structures breach. Human dimensions were rarely considered and water rights and other issues were mostly unresolved or addressed through ad-hoc agreements. We conclude that the practice and implementation of beaver-related restoration has outpaced research on its efficacy and best practices. Further scientific research is necessary, especially research that informs the establishment of clear guidelines for best practices.

Environmental Management↗

Wave-resolving Shoreline Boundary Conditions for Wave-Averaged Coastal Models

Downscaling broadscale ocean model information to resolve the fine-scale swash-zone dynamics has a number of applications, such as improved resolution of coastal flood hazard drivers, modeling of sediment transport and seabed morphological evolution. A new method is presented, which enables wave-averaged models for the nearshore circulation to include short-wave induced swash zone dynamics that evolve at the wave group scale (i.e. averaged over the short waves). Such dynamics, which cannot be described, by construction through wave-averaged models, play a fundamental role in nearshore hydrodynamics and morphodynamics. The method is based on the implementation of a set of Shoreline Boundary Conditions (SBCs) in wave-averaged models. The chosen set of SBCs allows for proper computation of the short-wave properties at a mean shoreline () taken as the envelope of the actual shoreline. The suitability of the approach is assessed through implementation of the SBCs into the Regional Ocean Modeling System (ROMS) coupled to a spectral wave model (InWave for IG waves and SWAN for wind waves). As the aim is to assess the viability of the approach, the SBCs are implemented only through a one-way coupling to ROMS (i.e. ROMS forcing the SBCs). Four different test cases – with constant, periodic and bichromatic offshore forcing – are run to assess the model performances. The main results of the analysis are: (a) the proposed SBCs can well reproduce the shoreline motion and swash zone dynamics in there for all chosen tests (RMSE and BIAS less than 20 % up to a cross-shore resolution of 4.0 m ( or )) and (b) implementation of the SBCs allows ROMS to accurately simulate the swash zone flows even at a resolution 40 times coarser than that needed by ROMS with its own wet–dry routine to properly describe the same flows. The latter result clearly demonstrates the major computational advantage of using the proposed SBCs. We also show that most of the swash zone dynamics is due to the mean flow (i.e. incoming Riemann variable) and the local (at ) wave height. However, especially in the case of bichromatic waves, the swash zone water volume content also seems to play a crucial role.

Ocean Modeling↗

Formation and evolution of valley-bottom and channel features, Lower Deschutes River, Oregon

Primary geologic and geomorphic processes that formed valley-bottom and channel features downstream from the Pelton-Round Butte dam complex are inferred from a canyon-long analysis of feature morphology, composition, location, and spatial distribution. Major controls on valley-bottom morphology are regional tectonics, large landslides, and outsized floods (floods with return periods greater than 1000 yrs), which include the late Holocene Outhouse Flood and several Quaternary landslide dam failures. Floods with a return period on the order of 100 yrs, including historical floods in 1996, 1964, and 1861, contribute to fan building and flood plain formation only within the resistant framework established by the major controls. Key processes in the formation of channel features, in particular the 153 islands and 23 large rapids, include long-term bedrock erosion, outsized floods, and century-scale floods. Historical analysis of channel conditions since 1911 indicates that the largest islands, which are cored by outsized-flood deposits, locally control channel location, although their margins are substantially modified during annual- to century-scale floods. Islands cored by bedrock have changed little. Islands formed by annual- to century-scale floods are more susceptible to dynamic interactions between tributary sediment inputs, mainstem flow hydraulics, and perhaps riparian vegetation. Temporal patterns of island change in response to the sequence of 20th century flooding indicate that many islands accreted sediment during annual- to decadal-scale floods, but eroded during larger century-scale floods. There is, however, no clear trend of long-term changes in patterns of island growth, movement, or erosion either spatially or temporally within the lower Deschutes River.

Oregon↗

Use of medium-range numerical weather prediction model output to produce forecasts of streamflow

This paper examines an archive containing over 40 years of 8-day atmospheric forecasts over the contiguous United States from the NCEP reanalysis project to assess the possibilities for using medium-range numerical weather prediction model output for predictions of streamflow. This analysis shows the biases in the NCEP forecasts to be quite extreme. In many regions, systematic precipitation biases exceed 100% of the mean, with temperature biases exceeding 3°C . In some locations, biases are even higher. The accuracy of NCEP precipitation and 2-m maximum temperature forecasts is computed by interpolating the NCEP model output for each forecast day to the location of each station in the NWS cooperative network and computing the correlation with station observations. Results show that the accuracy of the NCEP forecasts is rather low in many areas of the country. Most apparent is the generally low skill in precipitation forecasts (particularly in July) and low skill in temperature forecasts in the western United States, the eastern seaboard, and the southern tier of states. These results outline a clear need for additional processing of the NCEP Medium-Range Forecast Model (MRF) output before it is used for hydrologic predictions. Techniques of model output statistics (MOS) are used in this paper to downscale the NCEP forecasts to station locations. Forecasted atmospheric variables (e.g., total column precipitable water, 2-m air temperature) are used as predictors in a forward screening multiple linear regression model to improve forecasts of precipitation and temperature for stations in the National Weather Service cooperative network. This procedure effectively removes all systematic biases in the raw NCEP precipitation and temperature forecasts. MOS guidance also results in substantial improvements in the accuracy of maximum and minimum temperature forecasts throughout the country. For precipitation, forecast improvements were less impressive. MOS guidance increases he accuracy of precipitation forecasts over the northeastern United States, but overall, the accuracy of MOS-based precipitation forecasts is slightly lower than the raw NCEP forecasts. Four basins in the United States were chosen as case studies to evaluate the value of MRF output for predictions of streamflow. Streamflow forecasts using MRF output were generated for one rainfall-dominated basin (Alapaha River at Statenville, Georgia) and three snowmelt-dominated basins (Animas River at Durango, Colorado: East Fork of the Carson River near Gardnerville, Nevada: and Cle Elum River near Roslyn, Washington). Hydrologic model output forced with measured-station data were used as "truth" to focus attention on the hydrologic effects of errors in the MRF forecasts. Eight-day streamflow forecasts produced using the MOS-corrected MRF output as input (MOS) were compared with those produced using the climatic Ensemble Streamflow Prediction (ESP) technique. MOS-based streamflow forecasts showed increased skill in the snowmelt-dominated river basins, where daily variations in streamflow are strongly forced by temperature. In contrast, the skill of MOS forecasts in the rainfall-dominated basin (the Alapaha River) were equivalent to the skill of the ESP forecasts. Further improvements in streamflow forecasts require more accurate local-scale forecasts of precipitation and temperature, more accurate specification of basin initial conditions, and more accurate model simulations of streamflow.

Journal of Hydrometeorology↗

Getting ocean acidification on decision makers' to-do lists: dissecting the process through case studies

Much of the detailed, incremental knowledge being generated by current scientific research on ocean acidification (OA) does not directly address the needs of decision makers, who are asking broad questions such as: Where will OA harm marine resources next? When will this happen? Who will be affected? And how much will it cost? In this review, we use a series of mainly US-based case studies to explore the needs of local to international-scale groups that are making decisions to address OA concerns. Decisions concerning OA have been made most naturally and easily when information needs were clearly defined and closely aligned with science outputs and initiatives. For decisions requiring more complex information, the process slows dramatically. Decision making about OA is greatly aided (1) when a mixture of specialists participates, including scientists, resource users and managers, and policy and law makers; (2) when goals can be clearly agreed upon at the beginning of the process; (3) when mixed groups of specialists plan and create translational documents explaining the likely outcomes of policy decisions on ecosystems and natural resources; (4) when regional work on OA fits into an existing set of priorities concerning climate or water quality; and (5) when decision making can be reviewed and enhanced.

Oceanography↗

Simulating adsorption of U(VI) under transient groundwater flow and hydrochemistry: Physical versus chemical nonequilibrium model

Coupled intragrain diffusional mass transfer and nonlinear surface complexation processes play an important role in the transport behavior of U(VI) in contaminated aquifers. Two alternative model approaches for simulating these coupled processes were analyzed and compared: (1) the physical nonequilibrium approach that explicitly accounts for aqueous speciation and instantaneous surface complexation reactions in the intragrain regions and approximates the diffusive mass exchange between the immobile intragrain pore water and the advective pore water as multirate first-order mass transfer and (2) the chemical nonequilibrium approach that approximates the diffusion-limited intragrain surface complexation reactions by a set of multiple first-order surface complexation reaction kinetics, thereby eliminating the explicit treatment of aqueous speciation in the intragrain pore water. A model comparison has been carried out for column and field scale scenarios, representing the highly transient hydrological and geochemical conditions in the U(VI)-contaminated aquifer at the Hanford 300A site, Washington, USA. It was found that the response of U(VI) mass transfer behavior to hydrogeochemically induced changes in U(VI) adsorption strength was more pronounced in the physical than in the chemical nonequilibrium model. The magnitude of the differences in model behavior depended particularly on the degree of disequilibrium between the advective and immobile phase U(VI) concentrations. While a clear difference in U(VI) transport behavior between the two models was noticeable for the column-scale scenarios, only minor differences were found for the Hanford 300A field scale scenarios, where the model-generated disequilibrium conditions were less pronounced as a result of frequent groundwater flow reversals.

Water Resources Research↗

Changes in depth occupied by Great Lakes lake whitefish populations and the influence of survey design

Understanding fish habitat use is important in determining conditions that ultimately affect fish energetics, growth and reproduction. Great Lakes lake whitefish ( Coregonus clupeaformis ) have demonstrated dramatic changes in growth and life history traits since the appearance of dreissenid mussels in the Great Lakes, but the role of habitat occupancy in driving these changes is poorly understood. To better understand temporal changes in lake whitefish depth of capture ( D w ), we compiled a database of fishery-independent surveys representing multiple populations across all five Laurentian Great Lakes. By demonstrating the importance of survey design in estimating D w , we describe a novel method for detecting survey-based bias in D w and removing potentially biased data. Using unbiased D w estimates, we show clear differences in the pattern and timing of changes in lake whitefish D w between our reference sites (Lake Superior) and those that have experienced significant benthic food web changes (lakes Michigan, Huron, Erie and Ontario). Lake whitefish D w in Lake Superior tended to gradually shift to shallower waters, but changed rapidly in other locations coincident with dreissenid establishment and declines in Diporeia densities. Almost all lake whitefish populations that were exposed to dreissenids demonstrated deeper D w following benthic food web change, though a subset of these populations subsequently shifted to more shallow depths. In some cases in lakes Huron and Ontario, shifts towards more shallow D w are occurring well after documented Diporeia collapse, suggesting the role of other drivers such as habitat availability or reliance on alternative prey sources.

Lake Erie, Lake Huron, Lake Michigan, Lake Ontario↗

Reconstructed historical land cover and biophysical parameters for studies of land-atmosphere interactions within the eastern United States

Over the past 350 years, the eastern half of the United States experienced extensive land cover changes. These began with land clearing in the 1600s, continued with widespread deforestation, wetland drainage, and intensive land use by 1920, and then evolved to the present-day landscape of forest regrowth, intensive agriculture, urban expansion, and landscape fragmentation. Such changes alter biophysical properties that are key determinants of land-atmosphere interactions (water, energy, and carbon exchanges). To understand the potential implications of these land use transformations, we developed and analyzed 20-km land cover and biophysical parameter data sets for the eastern United States at 1650, 1850, 1920, and 1992 time slices. Our approach combined potential vegetation, county-level census data, soils data, resource statistics, a Landsat-derived land cover classification, and published historical information on land cover and land use. We reconstructed land use intensity maps for each time slice and characterized the land cover condition. We combined these land use data with a mutually consistent set of biophysical parameter classes, to characterize the historical diversity and distribution of land surface properties. Time series maps of land surface albedo, leaf area index, a deciduousness index, canopy height, surface roughness, and potential saturated soils in 1650, 1850, 1920, and 1992 illustrate the profound effects of land use change on biophysical properties of the land surface. Although much of the eastern forest has returned, the average biophysical parameters for recent landscapes remain markedly different from those of earlier periods. Understanding the consequences of these historical changes will require land-atmosphere interactions modeling experiments.

Journal of Geophysical Research D: Atmospheres↗

Using hierarchical Bayesian multi-species mixture models to estimate tandem hoop-net based habitat associations and detection probabilities of fishes in reservoirs

Species distribution models are useful tools to evaluate habitat relationships of fishes. We used hierarchical Bayesian multispecies mixture models to evaluate the relationships of both detection and abundance with habitat of reservoir fishes caught using tandem hoop nets. A total of 7,212 fish from 12 species were captured, and the majority of the catch was composed of Channel Catfish Ictalurus punctatus (46%), Bluegill Lepomis macrochirus (25%), and White Crappie Pomoxis annularis (14%). Detection estimates ranged from 8% to 69%, and modeling results suggested that fishes were primarily influenced by reservoir size and context, water clarity and temperature, and land-use types. Species were differentially abundant within and among habitat types, and some fishes were found to be more abundant in turbid, less impacted (e.g., by urbanization and agriculture) reservoirs with longer shoreline lengths; whereas, other species were found more often in clear, nutrient-rich impoundments that had generally shorter shoreline length and were surrounded by a higher percentage of agricultural land. Our results demonstrated that habitat and reservoir characteristics may differentially benefit species and assemblage structure. This study provides a useful framework for evaluating capture efficiency for not only hoop nets but other gear types used to sample fishes in reservoirs.

Oklahoma↗

Influence of the diversion of Bear River into Bear Lake (Utah and Idaho) on the environment of deposition of carbonate minerals

Bear River, the largest river in the Great Basin, had some of its flow diverted into Bear Lake through a series of canals constructed between 1911 and 1918, turning Bear Lake into a reservoir. The prediversion lake had an unusually high Mg2+ : Ca2+ ratio (38 by weight), which resulted in precipitation of CaCO3 as aragonite. The amount and mineralogy of the carbonate did not change immediately after the diversion, but during the middle of the 20th century, high-Mg calcite began to precipitate. In contrast, at the time of diversion there were very distinct changes in the isotopic composition of the carbonate that clearly define the time of diversion within the sediments. Sediment-trap studies show that the CaCO3 polymorph that precipitates in the epilimnion of the lake today is high-Mg calcite. Samples in sediment traps placed 2 m above the bottom of the lake in 45 m of water (bottom traps) contain predominantly aragonite and quartz, with lesser amounts of high-Mg and low-Mg calcite and dolomite. Isotopic evidence from the sediments shows that the aragonite that accumulated in the bottom sediment traps and that constitutes the bulk of postdiversion sediments is reworked and redistributed from shallow sites to deep sites. ?? 2007, by the American Society of Limnology and Oceanography, Inc.

Limnology and Oceanography↗

Remote estimation of surface pCO2 on the West Florida Shelf

Surface p CO 2 data from the West Florida Shelf (WFS) have been collected during 25 cruise surveys between 2003 and 2012. The data were scaled up using remote sensing measurements of surface water properties in order to provide a more nearly synoptic map of p CO 2 spatial distributions and describe their temporal variations. This investigation involved extensive tests of various model forms through parsimony and Principal Component Analysis, which led to the development of a multi-variable empirical surface p CO 2 model based on concurrent MODIS (Moderate Resolution Imaging Spectroradiometer) estimates of surface chlorophyll a concentrations (CHL, mg m −3 ), diffuse light attenuation at 490 nm (Kd_Lee, m −1 ), and sea surface temperature (SST, °C). Validation using an independent dataset showed a p CO 2 Root Mean Square Error (RMSE) of <12 µatm and a 0.88 coefficient of determination (R 2 ) for measured and model-predicted p CO 2 ranging from 300 to 550 µatm. The model was more sensitive to SST than to CHL and Kd_Lee, with a 1 °C change in SST leading to a ~16 µatm change in the predicted p CO 2 . Application of the model to the entire WFS MODIS time series between 2002 and 2014 showed clear seasonality, with maxima (~450 µatm) in summer and minima (~350 µatm) in winter. The seasonality was positively correlated to SST (high in summer and low in winter) and negatively correlated to CHL and Kd_Lee (high in winter and low in summer). Inter-annual variations of p CO 2 were consistent with inter-annual variations of SST, CHL, and Kd_Lee. These results suggest that surface water p CO 2 of the WFS can be estimated, with known uncertainties, from remote sensing. However, while the general approach of empirical regression may work for waters from other areas of the Gulf of Mexico, model coefficients need to be empirically determined in a similar fashion.

Continental Shelf Research↗

Geology and ground water in Napa and Sonoma Valleys, Napa and Sonoma Counties, California

Napa and Sonoma Valleys are adjacent alluvium-filled valleys about 40 miles northeast of San Francisco. They occupy alined and structurally controlled depressions in the northern Coast Ranges physiographic province and drain south into San Pablo Bay. The valleys are surrounded and underlain by unconsolidated marine and continental sediments and volcanic rocks of Pliocene and Pleistocene age, which are water bearing in large part and together make up relatively extensive ground-water basins. Napa Valley, the eastern valley, is the larger and has a valley-floor area of about 85 square miles. Sonoma Valley has a valley-floor area of about 35 square miles; in addition, about 10 square miles is unreclaimed tidal marsh. The rock units of Napa and Sonoma Valleys are divided into four classes on the basis of their distribution and relative capacity to yield water: (a) Consolidated virtually non-water-bearing chiefly sedimentary (some metamorphic) rocks that range in age from Jurassic ( ?) to Pliocene; (b) marine shale and sand of the Petaluma formation (Pliocene) and the Merced formation (Pliocene and Pleistocene) that do not crop out within Napa or Sonoma Valleys but perhaps are penetrated by some deep wells drilled in Sonoma Valley; (c) Sonoma volcanics of Pliocene age, parts of which are non-water-bearing and parts of which locally yield large quantities of water; and (d) unconsolidated alluvial deposits mainly of Quaternary age. The deposits of classes (c) and (d) contain the most important aquifers in the area. Most of the water used in these valleys is pumped from wells in the younger and older alluvium in the Huichica and Glen Ellen formations. and in the Sonoma volcanics. The principal aquifers are the younger and older alluvium. but appreciable quantities of water are pumped locally from the Sonoma volcanics. The Huichica and Glen Ellen formations yield water in small quantities and at most places supply water only for limited domestic uses. The younger alluvium COIM3ists of interbedded deposits of unconsolidated gravel. sand, silt. and. locally, peat. These deposits underlie the flood plains and channels of the Napa River. Sonoma Creek, and their tributaries, low alluvial fans or plains graded to these streams. and the tidal marshlands. The older alluvium of Napa and Sonoma Valleys is composed of lenticular deposits of unconsolidated and poorly sorted clay, silt. sand. and gravel. Where exposed, claypan or hardpan soil is characteristically developed at the surface. The Huichica formation is composed of deformed continental beds consisting mostly of yellow silt with some interbedded lenses of silt and gravel, and silt and boulders. At the base are beds of redeposited volcanic material, silt, clay, and lenses of coarse gravel and boulders. The Glen Ellen fcrmation consists of alluvial clay, silt, sand, and gravel in clearly stratified but generally lenticular beds. The Sonoma volcanics constitute a thick and highly variate series of continental volcanic rocks, including andesite, basalt, and minor rhyolite flows and interbedded coarse- to fine-grained pyroclastic tuff and breccia, redeposited tuff and pumice, and diatomaceous mud, silt, and sand. A prominent body of rhyolite flows and tuff with some obsidian and perlitic glass, called the St. Helena rhyolite member, occurs in the upper part. Estimated ground-water pumpage for all uses in the year 1949-50 was about 5,600 acre-feet in Napa Valley and about 2,400 acre-feet in Sonoma Valley. Of this quantity the amounts pumped for irrigation were about 2,900 and 1,900 acre-feet, respectively. Water levels in wells in the central parts of the valleys range from a few feet above the land surface to about 50 feet below, with an average of about 25 feet. The quality of the water in most wells is satisfactory for domestic use and irrigation. Locally at the southern end of the valley some contamination of the native waters is caused by the movement of salty wate

Water Supply Paper↗