Search USGS⌕ Search

SEARCH · Search USGS

Results for “Clays and Clay Minerals”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44Linked to original sources
USGS1989

Hydrogeology and water quality near a solid- and hazardous-waste landfill, Northwood, Ohio

Hydrogeology and water quality of ground water and selected streams were evaluated near a landfill in northwestern Ohio. The landfill is used for codisposal of solid and hazardous waste. Water-level and geologic data were collected from 36 wells and 3 surface-water sites during the period November 1983 to November 1985. Water-quality samples were collected from 18 wells and 3 surface-water sites this during this same period. The primary aquifers in the area are the Greenfield Dolomite and underlying Lockport Dolomite of Silurian age. These bedrock carbonates are overlain by two clay tills of Wisconsin age. The tills are capped by a glacial lake clay. The tills generally are saturated, but do not yield sufficient water to be considered an aquifer. Two wells in the study area yield water, in part, from discontinuous deposits of outwash sand and gravel at the lower till-bedrock interface. Regional ground-water flow is from southwest to northeast; local flow is influenced by a ground-water mound centered under the northernmost cells of the landfill. Water levels in wells penetrating refuse within the landfill and the presence of leachate seeps indicate that the refuse is saturated. Head relations among the landfill, till, and dolomite aquifer indicate a vertical component of flow downward from the landfill to the dolomite aquifer. Water levels near the landfill fluctuate as much as 14 feet per year, in contrast to fluctuations of less than 3 feet per year in wells upgradient landfill. Ground waters from wells completed in the dolomite aquifer and glacial till were found to have major-iron concentrations controlled, in large part, by reaction with calcite, dolomite, and other minerals in the aquifer. Only minor departures from equilibrium mineral saturation were noted for ground water, except in wells affected by cement/grout contamination. Molal ratios of calcuim:magnesium in ground water suggest a similar chemical evolution of waters throughout the dolomite aquifer in the study area. Stable-isotope ratios of oxygen and hydrogen indicate the source of water in the till unit and dolomite aquifer is atmospheric precipitation. Elevated levels of total dissolved solids, boron, ammonia, and iron in the leachate and in wells downgradient of the landfill may indicate mixing of ground water with leachate. Oxygen and hydrogen stable-isotope ratios were used to differentiate waters from the glacial till and dolomite aquifer. Isotope ratios also show a shift off the local mixing line for leachate and for a well just downgradient from the landfill. The shift to heavier values of o D in the well water may be indicative of leachate mixing with ground water. The effect of this mixing denoted by hydrologic, isotopic, and chemical-quality data is limited mostly to elevated levels of the common ions. Analysis did not indicate significant levels of toxic metals or organic contaminants except phenol, which was present at concentrations of from 1 to 5 micrograms per liter in six wells. Analysis of water-quality data from nearby streams suggest that surface leaching from the landfill does not significantly affect stream-water quality, but may contribute to higher level of trace metals in the streambed sediments.

Water-Resources Investigations Report↗
USGS1998

Freshwater resources and saline water near the Sac and Fox Nation tribal lands, eastern Lincoln County, Oklahoma

The purpose of this project was to evaluate the freshwater resources and possible sources of high-chloride and high-sulfate concentrations in parts of the aquifer near the Sac and Fox Nation tribal land in eastern Lincoln County, Oklahoma. Water-quality sampling and borehole geophysical data indicate the potential for fresh ground water on tribal land generally is greatest in the Vanoss Formation, in the SE1/4 sec. 21, T. 14 N., R. 06 E. and in the NE1/4 sec. 22, T. 14 N., R. 06 E. These locations avoid the flood-prone areas and borehole geophysical resistivity logs indicate the altitude of the base of fresh ground water is below 650 ft. The altitude of the base of fresh ground water is indicated to be generally near the surface under the W1/2 sec. 22, T. 14 N., R. 06 E., the SE1/4 sec. 22, SE1/4 SE1/4 NE1/4 sec. 21, and NE1/4 NW1/4 NW1/4 sec. 27. Conditions are more favorable for placement of fresh ground-water wells in sec. 34, T. 14 N., R. 06 E., where the tribe has leased water rights, than on tribal land in secs. 15, 16, 21, and 22, T. 14 N., R. 06 E. Sandstones overlain by or enclosed in thick clay and shale sequences are likely to be somewhat isolated from the flow system and retain some of the residual brine. Borehole geophysical logs suggest that sandstones near CH1, CM1, and WT1 have more clay and shale content than the sandstones near L2. Greater amounts of clay in the sandstones will retard the flushing of residual brines from the sandstones and could result in a shallow base of fresh water near CH1, CM1, and WT1. For these reasons and because circulation of fresh ground water is limited by discharge to the Deep Fork, general water quality under tribal land would probably be poorer than in the area where the tribe has leased water rights. Samples have chloride or sulfate concentrations greater than 250 milligrams per liter in the W1/2 sec. 22, T. 14 N., R. 06 E. Six cluster well samples from tribal land have chloride or sulfate concentrations above the suggested maximum contaminant levels set by U.S. Environmental Protection Agency. Water-quality data indicate there may be more than one source for the salinity in the very saline and briny samples near the tribal land. Two possible sources for chloride and sulfate in water-quality samples are shallow brines and deep oil brines. Probable sources of shallow brines in the study area are: 1) solution of minerals by fresh water moving through the aquifer and 2) residual brines deposited with the sediment. There are no salt or gypsum beds in the Vanoss, Ada, or Vamoosa Formations, but there may be nodules and finely disseminated minerals present in the formations. Residual brines could remain in sand stones and shales that have low hydraulic conductivity and have not been diluted by freshwater recharge. Data suggest both sources have mixed with the fresh ground water from the Vanoss Formation. This is indicated by the relations of the bromide/chloride concentration ratio to chloride concentration, delta deuterium to delta 18oxygen, and by delta 18oxygen to chloride molality relation.

Water-Resources Investigations Report↗
USGS1973

Water resources of the Big Sioux River Valley near Sioux Falls, South Dakota

The major sources of water in the Big Sioux River valley between Sioux Falls and Dell Rapids, S.Dak., are the Big Sioux River and the glacial outwash aquifer beneath the flood plain. The river and the aquifer are hydraulically connected. The Big Sioux River has an average annual discharge of 246 cubic feet per second, on the average exceeds bankfull stage every 2.3 years, and has moderate basin storage.. Periods of low flow are common in the late summer, fall, and winter. A low flow of 0.1 cubic foot per second has been recorded. The outwash aquifer is composed of permeable sand, sand and gravel, and some boulders. The aquifer underlies an area of 33 square miles and commonly has a saturated thickness of less than 30 feet. Aquifer tests and measurements of streamflow indicate a rate of streambed infiltration of about 6 gallons per day per square foot. Analyses of streambed samples and interpretations of lithology from an electric log indicate that the streambed sediments in the diversion channel of the Big Sioux River consist largely of relatively impermeable silts and clays. Under normal climatic conditions, most of the water pumped by the city of Sioux Falls is water that entered the aquifer by streambed infiltration. To evaluate the importance of the aquifer in the hydrologic system, both an electrical analog model and a digital model were programmed for storage depletion alone. These models were used to determine the water-level declines in the aquifer that would result from 1 year of withdrawal at a rate of 9-10 million gallons per day. Both models indicated that the existing well field can yield water at that rate for more than 1 year. The analog model was also used to determine the maximum average daily yield of the aquifer-river system for a 2-year period modeled for the minimum recorded stream discharge and for streambed infiltration as the only recharge. The maximum average yield under these conditions would be less than 24 million gallons per day. Most of the water pumped during this period would be from aquifer storage. Water from the river is generally less mineralized, softer, and easier to treat than ground water. Water pumped from wells near the river is similar in quality to the river water, but does not have the objectionable odors or tastes often present in water from the river.

South Dakota↗
USGS2002

Interpretation of K-Ar dates of illitic clays from sedimentary rocks aided by modeling

K-Ar dates of illitic clays from sedimentary rocks may contain "mixed ages," i.e., may have ages that are intermediate between the ages of end-member events. Two phenomena that may cause mixed ages are: (1) long-lasting reaction during the burial illitization of smectite: and (2) physical mixing of detrital and diagenetic components. The first phenomenon was investigated by simulation of illitization reactions using a nucleation and growth mechanism. These calculations indicate that values for mixed ages are related to burial history: for an equivalent length of reaction time, fast burial followed by slow burial produces much older mixed ages than slow burial followed by fast. The type of reaction that occurred in a rock can be determined from the distribution of ages with respect to the thickness of illite crystals. Dating of artificial mixtures confirms a non-linear relation between mixed ages and the proportions of the components. Vertical variation of K-Ar age dates from Gulf Coast shales can be modeled by assuming diagenetic illitization that overprints a subtle vertical trend (presumably of sedimentary origin) in detrital mineral content.

American Mineralogist↗
USGS1987

Water resources of the Rio Grande de Añasco-lower valley, Puerto Rico

A large amount of water suitable for most uses is available in the lower Rio Grande de Anasco Valley, the major source of which is the Rio Grande de Anasco which contributes about 95% of the surface water inflow to the lower valley. River flow at El Espino exceeds 100 cu ft/sec about 85% of the time and 200 cu ft/sec 50% of the time. Average daily flow for the driest months of the year (February, March, and April), is almost always <100 cu ft/sec. In contrast, the average daily flow for the wettest, months of the year (September, October, and November), is > 120 cu ft/sec. During the study period, flows of the Rio Canas averaged about 5 cu ft/sec. The lower valley is underlain by igneous rocks that have been eroded to depths of 350 ft or more below sea level. The valley is filled with 250 ft or more of limestone and clay, that in turn is overlain by as much as 100 ft of alluvium. The amount of groundwater available is unknown. There are large volumes of water in the saturated mostly fine-grained alluvium of Zone II, but as a whole the alluvium does not yield water readily to wells. Sand and gravel deposits associated with former river channels yield an estimated 100 to 150 gal/min to wells. The principal source of groundwater is the limestone of Zone III, that reportedly yields as much as 500 gal/min to wells. The quality of surface water especially that of Rio Grande de Anasco was very good. Specific conductance seldom exceeds 250 microsiemens/cm, even at low flows. Both salinity and sodium are low, falling in the Cl-S1 irrigation water classification. Water quality in the lower 5,000 ft or so of the river was affected by saltwater encroachment from the sea. The water quality of the other streams and canals in the lower valley was variable depending on susceptibility of saltwater encroachment, contamination from man-made sources, and concentration of minerals by evapotranspiration. Specific conductance however seldom exceeded 500 microsiemens/cm and the water usually falls in the C1-S2 classification. The quality of groundwater in the alluvial aquifer was about the same as that of the water of the Rio Grande de Anasco except where encroached by saltwater or contaminated. The water from the limestone was more mineralized than that of the alluvium (about 600 to 700 microsiemens/cm), and was somewhat similar to that of the smaller streams and canals in the valley.

Puerto Rico↗
USGS1999

Iron in the aquifer system of Suffolk County, New York, 1990-98

High concentrations of dissolved iron in ground water contribute to the biofouling of public-supply wells, and the treatment and remediation of biofouling are costly. Water companies on Long Island, N.Y., spend several million dollars annually to recondition, redevelop, and replace supply wells and distribution lines; treat dissolved iron with sequestering agents or by filtration; and respond to iron-related complaints by customers. This report summarizes the results of studies done by the U.S. Geological Survey, in cooperation with the Suffolk County Water Authority, to characterize the geochemistry and microbiology of iron in the aquifer system of Suffolk County. This information should be helpful for the siting and operation of supply wells. Concentrations of dissolved iron in Long Island's ground water, and the frequency of iron biofouling of wells, are highest in ground-water-discharge zones, particularly near the south shore. Ground water along a deep north-south flowpath of the Magothy aquifer in southwestern Suffolk County becomes anaerobic (oxygen deficient) and Fe(III) reducing at a distance of 8 to 10 kilometers south of the ground-water divide, and this change coincides with the downgradient increase in dissolved iron concentrations. The distribution of organic carbon, and the distribution and local variations in reactivity of Fe(III), in Magothy aquifer sediments have resulted in localized differences in redox microenvironments. For example, Fe(III)-reducing zones are associated with anaerobic conditions, where relatively large amounts of Fe(III) oxyhydroxide grain coatings are present, whereas sulfate-reducing zones are associated with lignite-rich lenses of silt and clay and appear to have developed in response to the depletion of available Fe(III) oxyhydroxides. The sulfate-reducing zones are characterized by relatively low concentrations of dissolved iron (resulting from iron-disulfide precipitation) and may be large enough to warrant water-supply development. Specific-capacity and water-quality data from wells screened in the Magothy aquifer indicate that water from biofouled wells contains higher median concentrations of total and dissolved iron and manganese, total phosphate, and dissolved sulfate, and lower median concentrations of dissolved oxygen and alkalinity, and lower pH, than does water from unaffected wells. Corresponding data from wells screened in the upper glacial aquifer indicate that water from biofouled wells contains higher median concentrations of total and dissolved manganese and dissolved sulfate, and lower pH, than does water from unaffected wells. Filamentous bacteria were detected in 31 (or 72 percent) of the 43 biofilm samples obtained from biofouled wells during reconditioning. The predominant filamentous organism was Gallionella ferruginea, a major biofouling agent in the upper glacial and Magothy aquifers throughout Suffolk County. Mineral-saturation indices indicate that most of the well-encrusting material is deposited when the wells are shut down. Furthermore, the use of treated water (which has a high pH and sometimes high concentrations of dissolved iron) for pump prelubrication when wells are shut down could greatly increase the rate of iron oxidation.

New York↗
USGS2012

Electrical structure of Newberry Volcano, Oregon

From the interpretation of magnetotelluric, transient electromagnetic, and Schlumberger resistivity soundings, the electrical structure of Newberry Volcano in central Oregon is found to consist of four units. From the surface downward, the geoelectrical units are (1) very resistive, young, unaltered volcanic rock, (2) a conductive layer of older volcanic material composed of altered tuffs, (3) a thick resistive layer thought to be in part intrusive rocks, and (4) a lower-crustal conductor. This model is similar to the regional geoelectrical structure found throughout the Cascade Range. Inside the caldera, the conductive second layer corresponds to the steep temperature gradient and alteration minerals observed in the USGS Newberry 2 test hole. Drill hole information on the south and north flanks of the volcano (test holes GEO N-1 and GEO N-3, respectively) indicates that outside the caldera the conductor is due to alteration minerals (primarily smectite) and not high-temperature pore fluids. On the flanks of Newberry the conductor is generally deeper than inside the caldera, and it deepens with distance from the summit. A notable exception to this pattern is seen just west of the caldera rim, where the conductive zone is shallower than at other flank locations. The volcano sits atop a rise in the resistive layer, interpreted to be due to intrusive rocks. The intrusive material has served as a heat source to produce enhanced hydrothermal alteration and, perhaps in the case of the west-flank anomaly, elevated fluid temperatures. While no public drill hole information is available to confirm this hypothesis, the west-flank anomaly appears to be a good geothermal target. In addition to the possibility that a region on the west side of the volcano could be favorable for prospecting, part of the resistive structure under the center of the volcano could be due to a vapor-dominated environment with temperatures above 300°C. In other parts of the Cascades, pervasive alteration has produced mixed layer clays and zeolites, resulting in low-resistivity anomalies. Low resistivities cannot be assumed to indicate high-temperature pore fluids. The use of electrical methods that measure resistivity as a function of excitation frequency, such as spectral induced polarization, may provide a way of obtaining information about the type and extent of alteration.

Journal of Geophysical Research Solid Earth↗
USGS1989

Arsenic in ground-water under oxidizing conditions, south-west United States

Concentrations of dissolved arsenic in ground-water in alluvial basins of Arizona commonly exceed 50 μg L −1 and reach values as large as 1,300 μg L −1 . Arsenic speciation analyses show that arsenic occurs in the fully oxidized state of plus 5 (As+5), most likely in the form of HAsO4 ∼2 , under existing oxidizing and pH conditions. Arsenic in source areas presumably is oxidized to soluble As before transport into the basin or, if after transport, before burial. Probable sources of arsenic are the sulphide and arsenide deposits in the mineralized areas of the mountains surrounding the basins. Arsenic content of alluvial material ranged from 2 to 88 ppm. Occurrence and removal of arsenic in ground-water are related to the pH and the redox condition of the ground-water, the oxidation state of arsenic, and sorption or exchange. Within basins, dissolved arsenic correlates (P<0.01) with dissolved molybdenum, selenium, vanadium, and fluoride and with pH, suggesting sorption of negative ions. The sorption hypothesis is further supported by enrichment of teachable arsenic in the basin-fill sediments by about tenfold relative to the crustal abundance and by as much as a thousandfold relative to concentrations found in ground-water. Silicate hydrolysis reactions, as defined within the alluvial basins, under closed conditions cause increases in pH basinward and would promote desorption. Within the region, large concentrations of arsenic are commonly associated with the central parts of basins whose chemistries evolve under closed conditions. Arsenic does not correlate with dissolved iron (r = 0.09) but may be partly controlled by iron in the solid phase. High solid-phase arsenic contents were found in red clay beds. Large concentrations of arsenic also were found in water associated with red clay beds. Basins that contain the larger concentrations are bounded primarily by basalt and andesite, suggesting that the iron content as well as the arsenic content of the basin fill may play a role in the occurrence of arsenic in ground-water. Under oxidizing conditions in Arizona, arsenic in ground-water appears to be controlled in part by sorption or desorption of HAsO4 ∼2 on active ferric oxyhydroxide surfaces.

Arizona, California, Nevada, New Mexico↗
USGS1979

Preliminary geologic and geophysical data of the UE25a-3 exploratory drill hole, Nevada Test Site, Nevada

The UE25a-3 drill hole, located in the Calico Hills area, southwestern part of the Nevada Test Site, was drilled as part of an effort to evaluate the Calico Hills area as a possible nuclear waste repository site. The purpose of the drill hole was to verify the existence of an intrusive crystalline body in the subsurface and to determine the stratigraphy, structure, and nature of fractures of the cored rocks. Cored samples were obtained for mineral, chemical, and material property analyses. Continuous cores were taken from 30.5 m (100ft) to total depth of 771.2 m (2,530.1 ft) of units J and I{?) (Late Mississippian age) of the Eleana Formation. The drill hole penetrated 416.1 m (1 ,365ft) of argillite, and 304.5 m (999ft) of thermally altered argillite of unit J, and 50.6 m (166ft) of marble of unit I(?). No crystalline rocks were intersected by the drill hole. Numerous high-angle faults and brecciated zones were intersected by the drill hole. The units cored were intensely fractured with fracture analysis of the core consisting of frequency of fractures, dips of fractures, open and closed (sealed) fractures and types of fracture sealing or coating material. Twenty-four hundred and thirty fractures, representing approximately 30 percent of the fractures present, indicate an average fracture frequency of 13.2 fractures per meter, predominantly high-angle dips with 66 percent of the fractures closed. Fractures in the argillite interval are sealed or coated predominantly with kaolinite, nacrite, and dickite. Calcite, chlorite, and magnetite are present in fractures in the altered argillite interval. Fractures in the marble interval are sealed or coated with calcite, dolomite, and ferruginous clay. The core index indicates that the lower half of the drilled interval is more competent than the upper half. Borehole geophysical logs were run by the Birdwell Division of Seismograph Service Corporation for geologic correlations and lithologic characterizations. The logs include: caliper, density, resistivity, spontaneous potential, Vibroseis, 3-D velocity, neutron, and gamma-ray logs. Lithologic boundaries and structures correlate to responses in the logs.

Nevada↗
USGS1990

Fine-grained rutile in the Gulf of Maine: Diagenetic origin, source rocks, and sedimentary environment of deposition

The Gulf of Maine, an embayment of the New England margin, is floored by shallow, glacially scoured basins that are partly filled with late Pleistocene and Holocene silt and clay containing 0.7 to 1.0 wt percent TiO 2 , chiefly in the form of silt-size rutile. Eleven basins in the gulf are estimated to contain 479 X 10 6 metric tons of TiO 2 (to a depth of 10 m) in the U.S. exclusive economic zone and 168 X 10 6 in Canada, based on analyses of surface sediment and of cores 10 to 20 m long. The U.S. annually consumes approximately 1 X 10 6 metric tons of TiO 2 , of which 73 percent is imported. The inferred amount of fine-grained TiO 2 in the basins is large, and we interpret it to be predominantly rutile; but no attempt has been made yet to mine and beneficiate the fine-grained ore.Sedimentary rocks of Nova Scotia, New Brunswick, and northern Maine contain fine-grained rutile crystals and have been the major source of the fine-grained sediment in the Gulf of Maine basins during and after the Wisconsinan glaciation. We conclude that much of the rutile in the Gulf of Maine mud formed diagenetically in poorly cemented Carboniferous and Triassic coarse-grained sedimentary rocks of Nova Scotia and New Brunswick after the dissolution of titanium-rich detrital minerals (ilmenite, ilmenomagnetite). Another major source of rutile is the generally finer grained Paleozoic sedimentary rocks of northern Maine (and possibly northwestern New Brunswick) which contain recycled diagenetic rutile that most likely originated in sandstones. Additional Wisconsinan sources of fine-grained, diagenetic TiO 2 probably include sedimentary rocks of inferred Triassic age that underlie the Gulf of Maine.The diagenesis of rutlie in coarse sedimentary rocks (especially arkose and graywacke) followed by erosion, segregation, and deposition (and including recycling of fine-grained rutile from shales) can serve as a model for predicting and prospecting for unconsolidated deposits of fine-grained TiO 2 .Gulf of Maine mud is comparable in TiO 2 content to typical shale. A determination of whether the fine-grained TiO 2 in shales primarily occurs as detrital titanium minerals from metamorphic and igneous sources or as recycled, diagenetic titanium oxides from sedimentary sources may assist in interpreting shale provenance and environment of deposition.

Economic Geology↗
USGS1932

A preliminary report on the artesian water supply of Memphis, Tennessee

Memphis is located in the part of the Gulf Coastal Plain known as the Mississippi embayment. It is underlain by unconsolidated sand and clay formations of Tertiary and Cretaceous age. The Wilcox group, of Tertiary age, and the Ripley formation, of Cretaceous age, are excellent aquifers, and all the water consumed in Memphis is derived from them. The maximum pumpage from the Wilcox group was reached about 1920; in that year an estimated average of 37,575,000 gallons a day was pumped. In 1928 the average daily pumpage from the Wilcox group was about 33,984,000 gallons, and in addition to this the Memphis Artesian Water Department pumped an average of 4,616,000 gallons a day from the Ripley formation. The static level at Memphis varies with the pumpage and the stage of the Mississippi River. The original static level was about 235 feet above mean sea level. In 1928 the average static level at the Auction Avenue plant was 202 feet above mean sea level, which was about 33 feet lower than the original level. The yield is therefore about a million gallons a day for each foot of drawdown. The drawdown is not excessive, and additional pumpage can be developed without undue lowering of head. The water from both the Wilcox group and the Ripley formation is fairly soft and has a moderately low content of dissolved mineral matter. The iron content is sufficiently high to be objectionable, but the iron is easily removed by aeration followed by either settling or filtration for removal of sediment.

Tennessee↗
USGS2010

Hydrogeology and groundwater quality of Highlands County, Florida

Groundwater is the main source of water supply in Highlands County, Florida. As the demand for water in the county increases, additional information about local groundwater resources is needed to manage and develop the water supply effectively. To address the need for additional data, a study was conducted to evaluate the hydrogeology and groundwater quality of Highlands County. Total groundwater use in Highlands County has increased steadily since 1965. Total groundwater withdrawals increased from about 37 million gallons per day in 1965 to about 107 million gallons per day in 2005. Much of this increase in water use is related to agricultural activities, especially citrus cultivation, which increased more than 300 percent from 1965 to 2005. Highlands County is underlain by three principal hydrogeologic units. The uppermost water-bearing unit is the surficial aquifer, which is underlain by the intermediate aquifer system/intermediate confining unit. The lowermost hydrogeologic unit is the Floridan aquifer system, which consists of the Upper Floridan aquifer, as many as three middle confining units, and the Lower Floridan aquifer. The surficial aquifer consists primarily of fine-to-medium grained quartz sand with varying amounts of clay and silt. The aquifer system is unconfined and underlies the entire county. The thickness of the surficial aquifer is highly variable, ranging from less than 50 to more than 300 feet. Groundwater in the surficial aquifer is recharged primarily by precipitation, but also by septic tanks, irrigation from wells, seepage from lakes and streams, and the lateral groundwater inflow from adjacent areas. The intermediate aquifer system/intermediate confining unit acts as a confining layer (except where breached by sinkholes) that restricts the vertical movement of water between the surficial aquifer and the underlying Upper Floridan aquifer. The sediments have varying degrees of permeability and consist of permeable limestone, dolostone, or sand, or relatively impermeable layers of clay, clayey sand, or clayey carbonates. The thickness of the intermediate aquifer system/ intermediate confining unit ranges from about 200 feet in northwestern Highlands County to more than 600 feet in the southwestern part. Although the intermediate aquifer system is present in the county, it is unclear where the aquifer system grades into a confining unit in the eastern part of the county. Up to two water-bearing units are present in the intermediate aquifer system within the county. The lateral continuity and water-bearing potential of the various aquifers within the intermediate aquifer system are highly variable. The Floridan aquifer system is composed of a thick sequence of limestone and dolostone of Upper Paleocene to Oligocene age. The top of the aquifer system ranges from less than 200 feet below NGVD 29 in extreme northwestern Highlands County to more than 600 feet below NGVD 29 in the southwestern part. The principal source of groundwater supply in the county is the Upper Floridan aquifer. As of 2005, about 89 percent of the groundwater withdrawn from the county was obtained from this aquifer, mostly for agricultural irrigation and public supply. Over most of Highlands County, the Upper Floridan aquifer generally contains freshwater, and the Lower Floridan aquifer contains more mineralized water. The potentiometric surface of the Upper Floridan aquifer is constantly fluctuating, mainly in response to seasonal variations in rainfall and groundwater withdrawals. The potentiometric surface of the Upper Floridan aquifer in May 2007, which represents the hydrologic conditions near the end of the dry season when water levels generally are near their lowest, ranged from about 79 feet above NGVD 29 in northwestern Highlands County to about 40 feet above NGVD 29 in the southeastern part of the county. The potentiometric surface of the Upper Floridan aquifer in September 2007 was about 3 to 10 feet high

Scientific Investigations Report↗
USGS2001

Status of shallow-aquifer mapping in the Northern Front Range Area, Colorado

Mapping of shallow aquifers in the northern Front Range area of Colorado has been completed as part of the U.S. Geological Survey Front Range Infrastructure Resources Project. The aquifer mapping was undertaken as part of a comprehensive effort to better define the mineral, energy, cartographic, biological, and water resources that are critical to the support and development of the area's infrastructure, such as streets. highways, airports, and buildings. The aquifer mapping was undertaken in cooperation with the Colorado Division of Water Resources and the Colorado Water Conservation Board. The shallow aquifers have been mapped in a 2,450-square-mile area extending as an approximately 30-mile-wide band from north of Fort Collins to the Arapahoe-Douglas County line south of Denver (fig. I). The shallow aquifer mapping in the Denver metropolitan area was published in 1996 as Hydrologic Investigations Atlas HA-736 (Robson. 1996). Shallow aquifer mapping in the Greeley-Nunn area was published as HA-746A (Robson, Arnold, and Heiny, 2000a); mapping in the Fort Collins-Loveland area was published as HA-746B (Robson, Arnold, and Heiny, 2000b); mapping in the Fort Lupton-Gilcrest area was published as HA-746C (Robson, Heiny, and Arnold, 2000c); and mapping in the Boulder-Longmont area was published as HA-746D (Robson, Heiny, and Arnold, 2000d). Each of the five atlases contains five map sheets at 1:50,000 scale showing: 1. The thickness and extent of the unconsolidated sediments (loose gravel. sand. silt, and clay) that overlie the bedrock formations in the area (fig. 2). 2. The altitude and configuration of the bedrock surface. 3. The altitude of the water table and direction of ground-water movement. 4. The saturated thickness of the shallow aquifers. 5. The depth to the water table in the shallow aquifers.

Fact Sheet↗
USGS2009

'Natural background' soil water repellency in conifer forests of the north-western USA: Its prediction and relationship to wildfire occurrence

Soils under a wide range of vegetation types exhibit water repellency following the passage of a fire. This is viewed by many as one of the main causes for accelerated post-fire runoff and soil erosion and it has often been assumed that strong soil water repellency present after wildfire is fire-induced. However, high levels of repellency have also been reported under vegetation types not affected by fire, and the question arises to what degree the water repellency observed at burnt sites actually results from fire. This study aimed at determining 'natural background' water repellency in common coniferous forest types in the north-western USA. Mature or semi-mature coniferous forest sites (n = 81), which showed no evidence of recent fires and had at least some needle cast cover, were sampled across six states. After careful removal of litter and duff at each site, soil water repellency was examined in situ at the mineral soil surface using the Water Drop Penetration Time (WDPT) method for three sub-sites, followed by collecting near-surface mineral soil layer samples (0-3 cm depth). Following air-drying, samples were further analyzed for repellency using WDPT and contact angle (?? sl ) measurements. Amongst other variables examined were dominant tree type, ground vegetation, litter and duff layer depth, slope angle and aspect, elevation, geology, and soil texture, organic carbon content and pH. 'Natural background' water repellency (WDPT > 5 s) was detected in situ and on air-dry samples at 75% of all sites examined irrespective of dominant tree species (Pinus ponderosa, Pinus contorta, Picea engelmanii and Pseudotsuga menziesii). These findings demonstrate that the soil water repellency commonly observed in these forest types following burning is not necessarily the result of recent fire but can instead be a natural characteristic. The notion of a low background water repellency being typical for long-unburnt conifer forest soils of the north-western USA is therefore incorrect. It follows that, where pre-fire water repellency levels are not known or highly variable, post-fire soil water repellency conditions are an unreliable indicator in classifying soil burn severity. The terrain and soil variables examined showed, overall, no convincing relationship with the repellency levels observed (R 2 < 0.15) except that repellency was limited in soils (i) developed over meta-sedimentary lithology and (ii) with clay contents >4%. This suggests that water repellency levels cannot be predicted with confidence from common terrain or soil variables. ?? 2009 Elsevier B.V.

Journal of Hydrology↗
USGS2022

Primary deposition and early diagenetic effects on the high saturation accumulation of gas hydrate in a silt dominated reservoir in the Gulf of Mexico

On continental margins, high saturation gas hydrate systems (>60% pore volume) are common in canyon and channel environments within the gas hydrate stability zone, where reservoirs are dominated by coarse-grained, high porosity sand deposits. Recent studies, including the results presented here, suggest that rapidly deposited, silt-dominated channel-levee environments can also host high saturation gas hydrate accumulations. Here we present several sedimentological data sets, including sediment composition, biostratigraphic age from calcareous nannofossils, grain size, total organic carbon (TOC), C/N elemental ratio, δ 13 C-TOC , CaCO 3 , total sulfur (TS), and δ 34 S-TS from sediments collected with pressure cores from a gas hydrate rich, turbidite channel-levee system in the Gulf of Mexico during the 2017 UT-GOM2-1 Hydrate Pressure Coring Expedition. Our results indicate the reservoir is composed of three main lithofacies, which have distinct sediment grain size distributions (type A-silty clay to clayey silt, type B-clayey silt, and type C-sandy silt to silty sand) that are characteristic of variable turbidity current energy regimes within a Pleistocene (< 0.91 Ma) channel-levee environment. We document that the TOC in the sediments of the reservoir is terrestrial in origin and contained within the fine fraction of each lithofacies, while the CaCO 3 fraction is composed of primarily reworked grains, including Cretaceous calcareous nannofossils, and part of the detrital load. The lack of biogenic grains within the finest grained sediment intervals throughout the reservoir suggests interevent hemipelagic sediments are not preserved, resulting in a reservoir sequence of silt dominated, stacked turbidites. We observe two zones of enhanced TS at the top and bottom of the reservoir that correspond with enriched bulk sediment δ 34 S, indicating stalled or slowly advancing paleo-sulfate-methane transition zone (SMTZ) positions likely driven by relative decreases in sedimentation rate. Despite these two diagenetic zones, the low abundance of diagenetic precipitates throughout the reservoir allowed the primary porosity to remain largely intact, thus better preserving primary porosity for subsequent pore-filling gas hydrate. In canyon, channel, and levee environments, early diagenesis may be regulated via sedimentation rates, where high rates result in rapid progression through the SMTZ and minimal diagenetic mineralization and low rates result in the stalling of the SMTZ, enhancing diagenetic mineralization. Here, we observed some enhanced pyritization to implicate potential sedimentation rate changes, but not enough to consume primary porosity, resulting in a high saturation gas hydrate reservoir. These results emphasize the important implications of sedimentary processes, sedimentation rates, and early diagenesis on the distribution of gas hydrate in marine sediments along continental margins.

Alabama, Louisiana, Mississippi↗
USGS2015

Geologic framework and evidence for neotectonism in the epicentral area of the 2011 Mineral, Virginia, earthquake

The epicenters of the main shock and associated aftershocks of the 2011 moment magnitude, M w 5.8 Mineral, Virginia (USA), earthquake, and the updip projection of the possible fault plane that triggered the quakes, are contained in the areas of 2 adjoining 7.5′ quadrangles in the central Virginia Piedmont. These quadrangles have therefore been the focus of concentrated geologic study in the form of bedrock and surficial mapping and near-surface trenching in order to identify potential seismogenic structures. Bedrock mapping has outlined a series of northeast-southwest–trending lithologic belts that include the Ordovician Chopawamsic and Quantico Formations, the narrow neck of the Late Ordovician Ellisville pluton, and mélange zone III of the Mine Run Complex. The region was affected by at least two ductile deformational events, one in the early Paleozoic that was broadly synchronous with the intrusion of the pluton, and one later in the Paleozoic. The earlier deformation produced the Quantico synclinorium and other regional folds, and the later deformation produced faults with associated high-strain zones. Two of these faults have been trenched at their intersection along the east-dipping eastern contact of the Ellisville neck, near where the causative fault for the earthquake projects to the surface. The trenches have exposed abundant evidence of post-Paleozoic fracturing and faulting, including brecciated quartz-tourmaline veins, slickensided thrust and strike-slip faults, and clay-filled fractures. Fluvial and colluvial gravels that overlie these brittle structures have yielded optically stimulated luminescence ages ranging from ca. 27 to 10 ka. These structures are likely representative of surface features associated with Quaternary earthquakes in the Central Virginia seismic zone.

GSA Special Papers↗
USGS1998

Preliminary lithostratigraphy, interpreted geophysical logs and hydrogeologic characteristics of the 98th Street core hole, Albuquerque, New Mexico

Core samples, cuttings, and numerous geophysical logs obtained from the 1560 ft (475.5 m) core hole drilled at 98th Street on the west side of Albuquerque provide key stratigraphic and hydraulicproperty information for the upper clastic sediments of the Santa Fe Group, which form the principal aquifer in the region. The core hole and an adjacent water-level monitoring well were drilled cooperatively by the U.S. Geological Survey (USGS) and the City of Albuquerque and investigated in collaboration with the New Mexico Bureau of Mines and Mineral Resources and the New Mexico Office of the State Engineer to improve understanding of aquifer characteristics and controls on ground-water availability and quality. The 751.5 ft (229 m) of core samples recovered from the core hole are the only undisturbed samples of nonlithified sediments of the upper part of the Santa Fe Group that have been collected in this area. These samples have allowed us, for the first time, to directly observe and characterize the lithic and sedimentologic features of this part of the section, and to correlate the detailed geologic features with geophysical-log characteristics, magnetic susceptibility measurements, hydraulic variables, and trace-element geochemistry. The adjacent well was designed to be an areally representative ground-water level and water-quality monitoring well for the Santa Fe Group aquifer. This report chiefly addresses the lithologic, stratigraphic, and hydrogeologic features determined from the 98th Street core hole; other reports address related characteristics. Previous geologic studies predicted the stratigraphy at the site to be, from the land surface downward: 1) Quaternary alluvial and eolian valley-border sediments; 2) fluvial sand and gravel of the upper unit of the Santa Fe Group (Ceja Member of the Santa Fe Formation of Kelly, 1978; equivalent to the Sierra Ledrones Formation of Machette (1978a); 3) downward-fining basin-floor silty clay deposits and 4) fluvial sandy and silty facies of the middle unit of the Santa Fe Group (the Middle Red Member of Bryan and McCann, 1937, and Lambert, 1968). New geologic interpretations indicate that the drill site is in a fault block bounded by east-dipping normal faults and the oblique Atrisco-Rincon fault zone. Core-hole sampling recovered 760.6 ft (231.8 m) of core, in core segments 2.1-2.375 in. (5.3-6 cm) in diameter, and 0.2-10 ft (6.1 cm-3 m) long. The core hole was cased with centered 3-in. PVC casing, and is available for geophysical logging. The monitoring-well hole contains four piezometers at depths of 1544 ft (470.6 m), 1112 ft (338.9 m), 749 ft (228.3 m), and 458 ft (139.6 m). Sediments in the core are loose to weakly cemented gravel, sand, silt, and clay, and lithified sandstone. Laboratory analyses of particle-size distributions of 28 channel samples show that most silty sand samples are uniformly graded and poorly sorted; medium sand samples are moderately sorted. Six principal sediment types are used to describe the core; these sediment types are repeated in various combinations throughout the core and are used to define 22 lithologic units in the cored interval. The six principal sediment types contain sequences of beds having similar modal grain size and sedimentary structure, and are listed in decreasing abundance: 1) Silty fine sand, poorly sorted, containing a coarse silt matrix. Geophysical logs show highly variable baselines with deflections that are related to clay beds and sequences of silt, clay, and sorted fine sand. Density values of 2.12-2.25 g/cc and porosity values of 30-35 percent are typical. 2) Medium sand, moderately to poorly sorted. Geophysical logs show baselines of low variability with deflections that are related to clay beds and sequences of silt, clay, and sorted fine sand. Density values of 2.05-2.20 g/cc and porosity values of 30-35 percent are typical. 3) Clayey sandy silt, poorly sorted, locally microlaminated clay and silt, generally nonplastic. Geophysical logs show highly variable baselines with deflections that are related to sequences of clay and fine sand. Density values of 2.1-2.2 g/cc and porosity values of 30-40 percent are typical. 4) Silt and clay, characteristically red to reddish brown and medium to high plasticity, massive to indistinctly microlaminated. Geophysical logs show variable baselines with broad, high-amplitude compound spikes that are related to sequences of silt and fine sand. Density values of 2.12-2.25 g/cc and porosity values of >45 percent are typical. 5) Sand and gravel, poorly sorted. Geophysical logs show variable baselines with deflections that are related to sequences of silty and sorted fine sand. 6) Sandstone, fine-to-medium grained, poorly sorted, cemented chiefly by calcite, which fills the original pore space. Geophysical logs show density values >2.25 g/cc and porosity values <30 percent. The 22 lithologic units are correlated with recognized basin-floor fluvial lithofacies (Hawley, 1996), which include sand and gravel (lithofacies I), sand with lenses of pebbly sand, silt, and silty clay (lithofacies II), and interbedded sand, silt, and silty clay (modified lithofacies III, IV, IX). The sediments in the core hole are correlated with three informal lithostratigraphic units. The top unit, 0-19 ft (0-5.8 m) depth, consists of Quaternary eolian sand and valley-border alluvium. Coarsegrained deposits in the 19-97 ft (5.8-29.6 m) interval are correlated with the upper unit of the Santa Fe Group. The fine-grained section in the 97-787 ft (29.6-239.9 m) interval is correlated tentatively with the middle unit of the Santa Fe Group. This section contains thick sequences of laminated red and olivebrown clay and silt overbank deposits (441-787 ft) in the distinctive Atrisco member of Connell and others (1998). The Atrisco is correlated with fine-grained zones in numerous wells throughout the central Albuquerque metropolitan area, and is recognized as a zone that separates the upper Santa Fe aquifer from underlying middle Santa Fe deposits. The lower section of the middle unit of the Santa Fe, 787-1500 ft (239.9-457.2 m) depth, includes an upper sequence of moderately sorted channel-fill medium sand, and a lower sequence of sand, silt, and clay overbank deposits. The age of the cored interval is not known precisely. The upper Santa Fe gravel is related regionally to a through-flowing river system that was established in the Rio Grande rift valleys in Early Pliocene time, >4.5 MA. The middle Santa Fe unit is dated tentatively by correlation with a fossiliferous section, in which sandy beds that directly underlie the upper Santa Fe are Late Miocene (Hemphellian), 4.6- 8.9 MA. Further, the middle Santa Fe unit, with dominantly normal magnetic polarity, may have been deposited during closely spaced normal magnetic chrons 5.9-8.3 Ma. Four hydrostratigraphic units summarize the hydrogeologic framework for the 98th Street site: 1) Quaternary valley-border deposits, 2) upper Santa Fe sand and gravel deposits, 3) middle Santa Fe overbank deposits, and 4) middle Santa Fe channel-sand deposits. Empirical values of horizontal hydraulic conductivity estimated from core samples reveal a previously unknown contrast in hydraulic conductivity in the lowest two hydrostratigraphic units. Correlations among numerous wells show that the distinctively fine-grained Atrisco member, with estimated hydraulic conductivities (K) of <0.02-17 ft/day, is a laterally extensive barrier to vertical ground-water flow. The underlying unit that contains moderately sorted medium sand is a potential aquifer production zone that should be investigated further. Laboratory determination of vertical hydraulic conductivity values for fine-grained core samples range from 10 -2 to 10 -7 ft/day; recompacted sandy samples have K values of 1 to 10 -2 ft/day. Results of tests conducted with increasing effective stress show that K values of all samples decrease with decreasing porosity. Comparison of K values from laboratory, empirical, and calculated geophysical values shows discrepancies of 1-3 orders of magnitude (ft/day), indicating that additional analyses of core samples and geophysical data are necessary for future characterization of the Santa Fe Group aquifer.

New Mexico↗
USGS1990

Mineral Resources of the Wabayuma Peak Wilderness Study Area, Mohave County, Arizona

The Wabayuma Peak Wilderness Study Area (AZ-020-037/043), for which a mineral survey was requested by the U.S. Bureau of land Management, encompasses 40,118 acres in northwestern Arizona. Fieldwork was carried out in 1986-88 by the U.S. Bureau of Mines and the U.S. Geological Survey to appraise the identified (known) resources and assess the mineral resource potential (undiscovered) of the wilderness study area. Within the Wabayuma Peak Wilderness Study Area are 14 private parcels of land totaling 1,315 acres. The Wabayuma Peak Wilderness Study Area, including the 14 private parcels of land, is herein referred to as the 'wilderness study area' or the 'study area'. The Boriana, Antler, and Copper World mines lie near the east boundary of the study area. The Boriana mine was a major tungsten-producing mine of the United States during World War II. The Antler and Copper World mines produced relatively small amounts of copper and zinc prior to 1970. Copper and zinc were mined within 100 ft of the study area at the Antler mine. The Antler mine contains subeconomic resources of 350,000 to 400,000 short tons of copper-zinc ore; a minimum of 2,000 short tons, at grades of 1 to 4 percent copper and 1 to 2 percent zinc, lie within the study area. No other mineral resources were identified within the study area. Four small tracts in the eastern part and one in the central part of the study area have high resource potential for copper, zinc, and minor lead, silver, and gold in massive sulfide deposits. A large central tract and two eastern tracts have moderate resource potential for the same metals. An eastern and a western tract within the wilderness study area have high resource potential for tungsten, copper, and combinations of beryllium, gold, silver, arsenic, bismuth, molybdenum, tin, indium, thorium, niobium, yttrium, lanthanum, scandium, tantalum, rhenium, lead, zinc, and iron in granite-related tungsten-polymetallic vein deposits. Most of the rest of the study area has moderate resource potential for these metals. A northern tract in the study area has moderate resource potential for gold, copper, and combinations of silver, zinc, lead, tungsten, and molybdenum in polymetallic vein deposits of several types.

Bulletin↗