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At least 793 records · Page 44Linked to original sources
USGS2009

Simulations of Groundwater Flow and Particle Tracking Analysis in the Area Contributing Recharge to a Public-Supply Well near Tampa, Florida, 2002-05

Shallow ground water in the north-central Tampa Bay region, Florida, is affected by elevated nitrate concentrations, the presence of volatile organic compounds, and pesticides as a result of groundwater development and intensive urban land use. The region relies primarily on groundwater for drinking-water supplies. Sustainability of groundwater quality for public supply requires monitoring and understanding of the mechanisms controlling the vulnerability of public-supply wells to contamination. A single public-supply well was selected for intensive study based on the need to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Upper Floridan aquifer in the City of Temple Terrace near Tampa, Florida, and the presence of a variety of chemical constituents in water from the well. A network of 29 monitoring wells was installed, and water and sediment samples were collected within the area contributing recharge to the selected public-supply well to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state groundwater flow model was developed to evaluate the age of groundwater reaching the well and to test hypotheses on the vulnerability of the well to nonpoint source input of nitrate. Particle tracking data were used to calculate environmental tracer concentrations of tritium and sulfur hexafluoride and to calibrate traveltimes and compute flow paths and advective travel times in the model area. The traveltime of particles reaching the selected public-supply well ranged from less than 1 day to 127.0 years, with a median of 13.1 years; nearly 45 percent of the simulated particle ages were less than about 10 years. Nitrate concentrations, derived primarily from residential/commercial fertilizer use and atmospheric deposition, were highest (2.4 and 6.11 milligrams per liter as nitrogen, median and maximum, respectively) in shallow groundwater from the surficial aquifer system and lowest (less than the detection level of 0.06 milligram per liter) in the deeper Upper Floridan aquifer. Denitrification occurred near the interface of the surficial aquifer system and the underlying intermediate confining unit, within the intermediate confining unit, and within the Upper Floridan aquifer because of reducing conditions in this part of the flow system. However, simulations indicate that the rapid movement of water from the surficial aquifer system to the selected public-supply well through karst features (sinkholes) and conduit layers that bypass the denitrifying zones (short-circuits), coupled with high pumping rates, allow nitrate to reach the selected public-supply well in concentrations that resemble those of the overlying surficial aquifer system. Water from the surficial aquifer system with elevated concentrations of nitrate and low concentrations of some volatile organic compounds and pesticides is expected to continue moving into the selected public-supply well, because calculated flux-weighted concentrations indicate the proportion of young affected water contributing to the well is likely to remain relatively stable over time. The calculated nitrate concentration in the selected public-supply well indicates a lag of 1 to 10 years between peak concentrations of nonpoint source contaminants in recharge and appearance in the well.

Scientific Investigations Report↗
USGS1989

Geochemistry of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

The chemical quality of the ground water in the Floridan aquifer system is determined primarily by mineral-water interaction. However, some changes in water quality have been imposed by development, particularly near coastal pumping centers. A total of 601 chemical analyses, all from different wells, most completed in the upper part of the aquifer system, were used to describe the variations in water chemistry and to study the processes responsible for observed changes. The Floridan aquifer system is a vertically continuous sequence of Tertiary carbonate rocks that are of generally high permeability and are hydraulically connected in varying degrees. The rocks are principally limestone and dolomite, but they grade into limy sands and clays near the aquifer system's updip limits. Major minerals in the aquifer system are calcite, dolomite, and, locally, gypsum or quartz; minor minerals include apatite, glauconite, and clay minerals such as kaolinite and montmorillonite. Trace amounts of metallic oxides or sulfides are present in some areas. The aquifer system consists of the Upper and Lower Floridan aquifers, separated in most places by a less permeable confining unit that has highly variable hydraulic properties. Only the Upper Floridan aquifer is present throughout the study area. Freshwater enters the aquifer system in outcrop areas located primarily in central Georgia and north-central Florida. Discharge occurs chiefly to streams and springs and, to a lesser extent, directly into the sea. Most of the flow into and out of the system takes place where it is unconfined or where the upper confining unit is thin. Secondary permeability developed by dissolution of aquifer material is most prominent in these areas of dynamic flow. Dissolved-solids concentrations in water from the Upper Floridan aquifer generally range from less than 25 milligrams per liter near outcrops to more than 25,000 milligrams per liter along the coasts. The dominant cations in the ground water are Ca2+, Mg2+, and Na+; the dominant anions are HCO3-, Cl-, and SO42-, The concentration of Ca2+ is controlled primarily by calcite saturation. Concentrations of Mg2+, NA+, and Cl- are highest where mixing of freshwater and saltwater occurs. Concentrations of HCO3- reflect the control of calcite solubility. The concentration of SO42- is highest where gypsiferous rock units are present in the aquifer system. The major geochemical processes that occur in the Upper Floridan aquifer, based on water-quality maps and computations using a geochemical model, are (1) dissolution of aquifer minerals toward equilibrium, (2) mixing of ground water with recharge, leakage, or seawater, (3) sulfate reduction, and (4) cation exchange between water and aquifer minerals. Similar processes apparently control minor dissolved constituents, although quantification is difficult with the available data. Statistical tests of available nutrient data indicate that concentrations of N (nitrogen) species in unconfined recharge areas may be increasing over time; more detailed studies of all N species are needed to test this hypothesis, however. Data on trace metals, radionuclides, and man-made organic contaminants are limited. Available data indicate that most freshwater within the Upper Floridan is potable, but detection of pesticides in a few samples indicates that the system is susceptible to contamination from the land surface in some areas, particularly where its upper confining unit is thin or absent. Geochemical models were used to examine changes in major chemical elements along selected ground-water paths within the Upper Floridan aquifer. Water in the Upper Floridan aquifer can be categorized into four hydrochemical facies, whose exact distribution is determined by confined or unconfined conditions of the aquifer and by chloride concentrations. The reaction models are considered plausible based on available chemical, isotopic, and hydrologic information, and they

Alabama, Florida, Georgia, South Carolina↗
USGS2003

Application of a multipurpose unequal probability stream survey in the Mid-Atlantic Coastal Plain

A stratified, spatially balanced sample with unequal probability selection was used to design a multipurpose survey of headwater streams in the Mid-Atlantic Coastal Plain. Objectives for the survey include unbiased estimates of regional stream conditions, and adequate coverage of unusual but significant environmental settings to support empirical modeling of the factors affecting those conditions. The design and field application of the survey are discussed in light of these multiple objectives. A probability (random) sample of 175 first-order nontidal streams was selected for synoptic sampling of water chemistry and benthic and riparian ecology during late winter and spring 2000. Twenty-five streams were selected within each of seven hydrogeologic subregions (strata) that were delineated on the basis of physiography and surficial geology. In each subregion, unequal inclusion probabilities were used to provide an approximately even distribution of streams along a gradient of forested to developed (agricultural or urban) land in the contributing watershed. Alternate streams were also selected. Alternates were included in groups of five in each subregion when field reconnaissance demonstrated that primary streams were inaccessible or otherwise unusable. Despite the rejection and replacement of a considerable number of primary streams during reconnaissance (up to 40 percent in one subregion), the desired land use distribution was maintained within each hydrogeologic subregion without sacrificing the probabilistic design.

Journal of the American Water Resources Associatio↗
USGS2015

Evaluating connection of aquifers to springs and streams, Great Basin National Park and vicinity, Nevada

Federal agencies that oversee land management for much of the Snake Range in eastern Nevada, including the management of Great Basin National Park by the National Park Service, need to understand the potential extent of adverse effects to federally managed lands from nearby groundwater development. As a result, this study was developed (1) to attain a better understanding of aquifers controlling groundwater flow on the eastern side of the southern part of the Snake Range and their connection with aquifers in the valleys, (2) to evaluate the relation between surface water and groundwater along the piedmont slopes, (3) to evaluate sources for Big Springs and Rowland Spring, and (4) to assess groundwater flow from southern Spring Valley into northern Hamlin Valley. The study focused on two areas—the first, a northern area along the east side of Great Basin National Park that included Baker, Lehman, and Snake Creeks, and a second southern area that is the potential source area for Big Springs. Data collected specifically for this study included the following: (1) geologic field mapping; (2) drilling, testing, and water quality sampling from 7 test wells; (3) measuring discharge and water chemistry of selected creeks and springs; (4) measuring streambed hydraulic gradients and seepage rates from 18 shallow piezometers installed into the creeks; and (5) monitoring stream temperature along selected reaches to identify places of groundwater inflow. The Snake Range was formed by a generally normal-faulted uplift, where late Proterozoic and Cambrian siliciclastic rocks and metamorphic rocks are present at the highest altitudes and younger Paleozoic carbonate rocks are exposed along the flanks. The consolidated rocks are intruded by Jurassic to Tertiary age plutons, which are most common between the Lehman and Snake Creek drainage basins. Older Cenozoic rocks, including Oligocene volcanic rocks and Miocene sedimentary rocks, crop out locally and fill the basins that underlie Snake, Spring, and Hamlin Valleys. Younger Tertiary and Quaternary sedimentary (basin-fill) deposits overlie the older Cenozoic rocks. The rocks and deposits can be divided into three distinct aquifers. These aquifers include (1) basin-fill aquifers that consist of the permeable parts of the Cenozoic basin fill and some fractured or jointed Cenozoic volcanic rocks, (2) an upper carbonate-rock aquifer that consists of upper Paleozoic carbonate rocks overlying a regionally extensive middle Paleozoic siliciclastic confining unit, and (3) a lower carbonate-rock aquifer that consists of lower Paleozoic carbonate rocks. Secondary openings created by faults, shear zones, fractures, and, in the carbonate rocks, karst solution features, largely determine the water-transmitting properties of the volcanic- and carbonate-rock aquifers. The basin-fill aquifers are composed of a wide variety of rock types and have highly variable hydraulic properties. The three aquifers are stratigraphically and structurally heterogeneous, causing large variations in the ability to store and transmit water. The aquifers are separated by confining units in some areas and are in contact with each other in other areas, yet function as a single, composite aquifer system. Basin-fill aquifers most often overlie or adjoin the lower and upper carbonate-rock aquifers. Baker, Lehman and Snake Creek drainage basins were divided into five hydrologic zones on the basis of climate, geology, and topography. The five zones, from highest to lowest altitudes, are the mountain-upland, karst-limestone, upper-piedmont, lower-piedmont, and valley-lowland zones. The primary hydrologic connection between the mountain-upland and the valley-lowland zones is streamflow. Much of the streamflow from the mountain-upland zone is generated above tree line. Groundwater flow increases in the karst-limestone zone because of increased permeability caused by dissolution, which results in increased streamflow losses. Most of the increased groundwater flow is to springs near faults that form the boundary with the upper-piedmont zone. Thus, groundwater flow from the karst-limestone zone to the upper-piedmont zone was only 10 percent of the combined flow of streams and springs that exit the karst-limestone zone. About 60 percent of the water flowing from Rowland Spring in the Lehman Creek drainage basin was from streamflow losses along Baker Creek. The remaining flow from Rowland Spring comes from local recharge in the karst-limestone zone. In the upper-piedmont zone, the water table by Baker, Lehman and Snake Creeks was near the water level in the creeks for several hundred feet downstream from the karst-limestone zone. Water levels in piezometers along Snake Creek downstream from its confluence with Spring Creek were far below the streambed, indicating gravity drainage beneath this section of the creek. Estimated vertical hydraulic conductivity along a 3-mile reach of Snake Creek downstream of this confluence was 0.5 foot per day, which was an order of magnitude less than that estimated for Baker and Lehman Creeks. The low vertical hydraulic conductivity in the streambed along the lower reaches of Snake Creek results from chemical precipitation of calcite caused by off-gassing of carbon dioxide derived from springs at the end of the karst-limestone zone. The younger alluvial deposits thicken rapidly across faults that form the upper boundary of the lower-piedmont zone. The absence of springs or groundwater flow to the creeks upstream of these faults indicates they are not a complete barrier to groundwater flow. The water table was shallow in the valley-lowland zone in the Baker and Lehman Creek drainage basins, whereas the water table was more than 50 feet below land surface in the Snake Creek drainage basin. In contrast to thick basin fill in the valley-lowland zone in the Baker and Lehman Creek drainage basins, fractured and karst limestone underlie basin fill at relatively shallow depths in Snake Creek drainage basin. The underlying limestone acts as a drain for groundwater in the basin fill beneath Snake Creek. A groundwater divide in southern Spring Valley south of Baking Powder Flat separates groundwater flow to the flat from southeastward flow into northern Hamlin Valley. Groundwater flow from southern Spring Valley south of the groundwater divide into northern Hamlin Valley was estimated to range from 6,000 to 11,000 acre-feet per year. This groundwater does not flow to Big Springs in southern Snake Valley; rather, the source of water to Big Springs is groundwater recharge in the Big Spring Wash drainage basin and in nearby smaller drainage basins at the south end of the Snake Range. Groundwater flow from southern Spring Valley continues through the western side of Hamlin Valley before being directed northeast toward the south end of Snake Valley. This flow is constrained by southward-flowing groundwater from Big Spring Wash and northward-flowing groundwater beneath central Hamlin Valley. The redirection to the northeast corresponds to a narrowing of the width of flow in southern Snake Valley caused by a constriction formed by a steeply dipping middle Paleozoic siliciclastic confining unit exposed in the flanks of the mountains and hills on the east side of southern Snake Valley and shallowly buried beneath basin fill in the valley. The narrowing of groundwater flow could be responsible for the large area where groundwater flows to springs or is lost to evapotranspiration between Big Springs in Nevada and Pruess Lake in Utah.

Nevada↗
USGS2022

Geochemical studies of the Green River Formation in the Piceance Basin, Colorado: I. Major, minor, and trace elements

The Eocene Green River Formation contains the largest oil shale deposits in the world and is a welldocumented example of a lacustrine depositional system. In addition, mineral resources associated with oil shale in the Piceance Basin nahcolite [NaHCO3] and dawsonite [NaAl(CO3)(OH)2)] are of current and potential economic value, respectively. Detailed geochemical analysis across the basin can aid in the understanding of the depositional environment, sedimentary processes, and water-chemistry evolution in this system. Quantitative geochemical data for Green River oil shale from the Piceance Basin of Colorado were collected by inductively coupled plasma optical emission spectroscopy and mass spectrometry as part of this study. The basin margin is represented by samples from exposures at Douglas Pass (Garfield County) and the basin center area is characterized by core samples from two drilled wells: the Shell 23X-2 and John Savage 24-1 (Rio Blanco County). Major elements and groups of elements are used as proxies for clastic influx (Si, Al, K, Ti), carbonate deposition (Ca, Mg), salinity (Na), paleo-productivity (P), and redox state (Fe, S), respectively. Minor and trace elements reinforce observations based on major elements, including Rb, Zr, Nb for clastic influx and Mn, Sr for carbonate. Trace elements are used to characterize redox conditions (As, Mo, U, V, Co, Ni, Cu, Zn) and salinity (Rb/K, B/Ga). Chemical distinctions between the basin margin and the basin center, in terms of these components and total organic carbon concentrations, support the model of a permanently stratified lake through most of the depositional interval. A primary purpose of the study was to conduct more extensive sampling to confirm conclusions of a previous reconnaissance study. Geochemical data from this study indicates elevated Na around the basin margin occurring earlier than in the deeper basin. Early in the history of Lake Uinta, the salinity may have been elevated first in the shallower marginal waters, due to increased evaporation, which then led to elevated salinity in the basin center through transport of saline density currents. Other indicators of salinity (Rb/K, B/Ga) do not track Na content in intervals where clay minerals are absent due to diagenetic alteration under hypersaline conditions but may be used to indicate the salinities at which authigenic Na-bearing minerals begin to form. Most Na-rich samples show high proportions of clastic constituents (Si, Al, K, Ti) compared to conventional carbonate constituents (Ca, Mg). Redox-sensitive period IV transition metal elements (V, Co, Ni, Cu, Zn) show only local occurrence of significant enrichment relative to average shale abundances. Analysis of Fe/Al ratios for this dataset suggests that the depletion of these elements may be related to source rocks depleted in mafic constituents, with apparent redox-related enrichments subdued by this effect. The basin margin samples reflect generally oxic bottom waters, with some intervals deposited under more reducing, possibly dysoxic to anoxic conditions. The basin center results indicate more reducing conditions, with Mo and U enrichment factors suggesting operation of a particulate shuttle mechanism that scavenged Mo on Fe/Mn-oxyhydroxides that redissolved at depth, with Mo precipitating along with sulfides and/or organic matter at or near the sediment/water interface.

Colorado↗
USGS2017

Lithological influences on contemporary and long-term regolith weathering at the Luquillo Critical Zone Observatory

Lithologic differences give rise to the differential weatherability of the Earth’s surface and globally variable silicate weathering fluxes, which provide an important negative feedback on climate over geologic timescales. To isolate the influence of lithology on weathering rates and mechanisms, we compare two nearby catchments in the Luquillo Critical Zone Observatory in Puerto Rico, which have similar climate history, relief and vegetation, but differ in bedrock lithology. Regolith and pore water samples with depth were collected from two ridgetops and at three sites along a slope transect in the volcaniclastic Bisley catchment and compared to existing data from the granitic Río Icacos catchment. The depth variations of solid-state and pore water chemistry and quantitative mineralogy were used to calculate mass transfer (tau) and weathering solute profiles, which in turn were used to determine weathering mechanisms and to estimate weathering rates. Regolith formed on both lithologies is highly leached of most labile elements, although Mg and K are less depleted in the granitic than in the volcaniclastic profiles, reflecting residual biotite in the granitic regolith not present in the volcaniclastics. Profiles of both lithologies that terminate at bedrock corestones are less weathered at depth, near the rock-regolith interfaces. Mg fluxes in the volcaniclastics derive primarily from dissolution of chlorite near the rock-regolith interface and from dissolution of illite and secondary phases in the upper regolith, whereas in the granitic profile, Mg and K fluxes derive from biotite dissolution. Long-term mineral dissolution rates and weathering fluxes were determined by integrating mass losses over the thickness of solid-state weathering fronts, and are therefore averages over the timescale of regolith development. Resulting long-term dissolution rates for minerals in the volcaniclastic regolith include chlorite: 8.9 × 10 −14 mol m −2 s −1 , illite: 2.1 × 10 −14 mol m −2 s −1 and kaolinite: 4.0 × 10 −14 mol m −2 s −1 . Long-term weathering fluxes are several orders of magnitude lower in the granitic regolith than in the volcaniclastic, despite higher abundances of several elements in the granitic regolith. Contemporary weathering fluxes were determined from net (rain-corrected) solute profiles and thus represent rates over the residence time of water in the regolith. Contemporary weathering fluxes within the granitic regolith are similar to the long-term fluxes. In contrast, the long-term fluxes are faster than the contemporary fluxes in the volcaniclastic regolith. Contemporary fluxes in the granitic regolith are generally also slightly faster than in the volcaniclastic. The differences in weathering fluxes over space and time between these two watersheds indicate significant lithologic control of chemical weathering mechanisms and rates.

Bisley watersheds↗
USGS2010

The geochemistry of the Fox Hills-Basal Hell Creek Aquifer in southwestern North Dakota and northwestern South Dakota

The Late Cretaceous Fox Hills Formation and the basal portion of the overlying Hell Creek Formation constitute an important aquifer in the Fort Union coal region. Throughout most of southwestern North Dakota and northwestern South Dakota the aquifer is at depths ranging from 1000 to 2000 ft, except for exposures along the Cedar Creek anticline. Water flows in the aquifer from southwest to northeast, with flow rates of a few feet per year. The recharge and discharge areas of the aquifer are separated by a north-south trending transition zone in which significant changes in water chemistry occur. Dissolved constituents in the recharge area (the western part of the study area) are Na + = 18 mmol/l, Cl − = 0.7 mmol/1, SO 4 2− = 2.7 mmol/1, and HCO 3 − = 13 mmol/l (δ 13 C = −12‰) with p H = 8.5. Ca 2+ , Mg 2+ , and K + are each less than 0.1 mmol/l, dissolved O 2 = 0, and traces of H 2 S and CH 4 are present. Computer modeling and carbon isotope data suggest the following reactions in the recharge area. CO 2 derived from lignitic carbon reacts to dissolve carbonate minerals, with cations then being exchanged for Na + on clay minerals. The high p H in the aquifer is the result of buffering by carbonate-ion exchange equilibria. In the discharge area, p H values have declined to 8.3, Cl − has increased from 0.7 to 5.5 mmol/l, with a parallel increase in Na + SO 4 2− has essentially disappeared, HCO 3 − has increased from 13 to 21 mmol/l (δ 13 C = −9‰), CH 4 has attained concentrations greater than 0.5 mmol/l, and small amounts of He are present. Traces of H 2 S are present, and Ca 2+ , Mg 2+ , and K + concentrations remain low throughout the aquifer: These changes can be accounted for by reactions in the aquifer: (1) sulfate reduction to pyrite with lignitic material as the carbon source and (2) continuous buffering of p H by the carbonate-ion exchange equilibria. Chemical and hydrologic data suggest that the increase in NaCl results from upward movement of small volumes of water into the Fox Hills aquifer from the transition zone eastward. Redox reactions in the aquifer are closely analogous to those observed in pore waters of reducing marine sediments. Reactions approach but do not achieve true thermodynamic equilibrium. Measurements of redox potential suggest a downgradient decrease in redox potential. The measurements are not amenable to quantitative interpretation.

Water Resources Research↗
USGS2007

Effects of multi-scale environmental characteristics on agricultural stream biota in eastern Wisconsin

The U.S. Geological Survey examined 25 agricultural streams in eastern Wisconsin to determine relations between fish, invertebrate, and algal metrics and multiple spatial scales of land cover, geologic setting, hydrologic, aquatic habitat, and water chemistry data. Spearman correlation and redundancy analyses were used to examine relations among biotic metrics and environmental characteristics. Riparian vegetation, geologic, and hydrologic conditions affected the response of biotic metrics to watershed agricultural land cover but the relations were aquatic assemblage dependent. It was difficult to separate the interrelated effects of geologic setting, watershed and buffer land cover, and base flow. Watershed and buffer land cover, geologic setting, reach riparian vegetation width, and stream size affected the fish IBI, invertebrate diversity, diatom IBI, and number of algal taxa; however, the invertebrate FBI, percentage of EPT, and the diatom pollution index were more influenced by nutrient concentrations and flow variability. Fish IBI scores seemed most sensitive to land cover in the entire stream network buffer, more so than watershed-scale land cover and segment or reach riparian vegetation width. All but one stream with more than approximately 10 percent buffer agriculture had fish IBI scores of fair or poor. In general, the invertebrate and algal metrics used in this study were not as sensitive to land cover effects as fish metrics. Some of the reach-scale characteristics, such as width/depth ratios, velocity, and bank stability, could be related to watershed influences of both land cover and geologic setting. The Wisconsin habitat index was related to watershed geologic setting, watershed and buffer land cover, riparian vegetation width, and base flow, and appeared to be a good indicator of stream quality. Results from this study emphasize the value of using more than one or two biotic metrics to assess water quality and the importance of environmental characteristics at multiple scales.

Wisconsin↗
USGS1996

Effect of whole catchment liming on the episodic acidification of two Adirondack streams

During the fall of 1989 7.7Mg/ha of calcium carbonate was applied on two tributary catchments (40 ha and 60 ha) to Woods Lake, a small (25 ha) acidic headwater lake in the western Adirondack region of New York. Stream-water chemistry in both catchment tributaries responded immediately. Acid-neutralizing capacity (ANC) increased by more than 200 μeq/L in one of the streams and more than 1000 μeq/L in the other, from pre-liming values which ranged from −25 to +40 μeq/L. The increase in ANC was primarily due to increases in dissolved Ca 2+ concentrations. Most of the initial response of the streams was due to the dissolution of calcite that fell directly into the stream channels and adjacent wetlands. A small beaver impoundment and associated wetlands were probably responsible for the greater response observed in one of the streams. After the liming of subcatchmentIV (60 ha), Ca 2+ concentrations increased with increasing stream discharge in the stream during fall rain events, suggesting a contribution from calcite dissolved within the soil and transported to the stream by surface runoff or shallow interflow. Concentrations of other ions not associated with the calcite (e.g. Na + ) decreased during fall rain events, presumably due to mixing of solute-rich base flow with more dilute shallow interflow. The strong relation between changes in Ca 2+ and changes in NO − 3 concentrations during spring snowmelt, (r 2 = 0.93, slope = 0.96, on an equivalent basis) suggests that both solutes had a common source in the organic horizon of the soil. Increases in NO − 3 concentrations during snowmelt were balanced by increases in Ca 2+ that was released either directly from the calcite or from exchange sites, mitigating episodic acidification of the stream. However, high ambient NO − 3 concentrations and relatively low ambient Ca 2+ concentrations in the stream during the spring caused the stream to become acidic despite the CaCO 3 treatment. In stream WO2 (40ha), Ca 2+ concentrations were much higher than in stream WO4 because of the dissolution of calcite which fell directly into the upstream beaver pond and its associated wetlands. Calcium concentrations decreased as both NO − 3 concentrations and stream discharge increased, due to the dilution of Ca-enriched beaver pond water by shallow interflow. Despite this dilution, Ca 2+ concentrations were high enough to more than balance strong acid anion (SO − 4 , NO − 3 , Cl − ) concentrations, resulting in a positive ANC in this stream throughout the year. These data indicate that liming of wetlands and beaver ponds is more effective than whole catchment liming in neutralizing acidic surface waters.

Biogeochemistry↗
USGS2012

A benthic-macroinvertebrate index of biotic integrity and assessment of conditions in selected streams in Chester County, Pennsylvania, 1998-2009

The Stream Conditions of Chester County Biological Monitoring Network (Network) was established by the U.S. Geological Survey and the Chester County Water Resources Authority in 1969. Chester County encompasses 760 square miles in southeastern Pennsylvania and has a rapidly expanding population. Land-use change has occurred in response to this continual growth, as open space, agricultural lands, and wooded lands have been converted to residential and commercial lands. In 1998, the Network was modified to include 18 fixed-location sites and 9 flexible-location sites. Sites were sampled annually in the fall (October-November) during base-flow conditions for water chemistry, instream habitat, and benthic macroinvertebrates. A new set of 9 flexible-location sites was selected each year. From 1998 to 2009, 213 samples were collected from the 18 fixed-location sites and 107 samples were collected from the 84 flexible-location sites. Eighteen flexible-location sites were sampled more than once over the 12-year period; 66 sites were sampled only once. Benthic-macroinvertebrate data from samples collected during 1998-2009 were used to establish the Chester County Index of Biotic Integrity (CC-IBI). The CC-IBI was based on the methods and metrics outlined in the Pennsylvania Department of Environmental Protection's "A Benthic Index of Biotic Integrity for Wadeable Freestone Streams in Pennsylvania." The resulting CC-IBI consists of scores for benthic-macroinvertebrate samples collected from sites in the Network that related to reference conditions in Chester County. Mean CC-IBI scores for 18 fixed-location sites ranged from 37.21 to 88.92. Thirty-nine percent of the 213 samples collected at the 18 fixed-location sites had a CC-IBI score less than 50; 33 percent, 50 to 70; 28 percent, greater than 70. CC-IBI scores from the 107 flexible-location samples ranged from 23.48 to 99.96. Twenty-five percent of the 107 samples collected at the flexible-location sites had a CC-IBI score less than 50; 33 percent, 50 to 70; and 42 percent, greater than 70. Factors that were found to affect CC-IBI scores are nutrient concentrations, habitat conditions, and percent of wooded and urban land use. A positive relation was determined between mean CC-IBI scores and mean total habitat scores for the 18 fixed-location sites. CC-IBI scores were most strongly affected by stream bank vegetative protection, embeddedness, riparian zone width, and sediment deposition. The highest CC-IBI scores were associated with sites that had greater than 28 percent wooded-wetland-water land use, less than 5 percent urban land use, and no municipal wastewater discharges within 10 miles upstream from the sampling site. The lowest CC-IBI scores were associated with sites where urban land use was greater than 15 percent or a municipal wastewater discharge was within 10 miles upstream from the sampling reach. The Mann Kendall test for trends was used to determine trends in CC-IBI scores and concentrations of nitrate, orthophosphate, and chloride for the 18 fixed-location sites. A positive trend in CC-IBI was determined for six sites, and a negative trend was determined for one site. Positive trends in nitrate concentrations were determined for 4 of the 18 fixed-location sites, and a negative trend in orthophosphate concentrations was determined for 1 of the 18 fixed-location sites. Positive trends in chloride concentrations were determined for 16 of the 18 fixed-location sites.

Pennsylvania↗
USGS2014

Nitrogen deposition effects on diatom communities in lakes from three National Parks in Washington State

The goal of this study was to document if lakes in National Parks in Washington have exceeded critical levels of nitrogen (N) deposition, as observed in other Western States. We measured atmospheric N deposition, lake water quality, and sediment diatoms at our study lakes. Water chemistry showed that our study lakes were ultra-oligotrophic with ammonia and nitrate concentrations often at or below detection limits with low specific conductance (−1 year −1 and were variable both within and across the parks. Diatom assemblages in a single sediment core from Hoh Lake (Olympic National Park) displayed a shift to increased relative abundances of Asterionella formosa and Fragilaria tenera beginning in the 1969–1975 timeframe, whereas these species were not found at the remaining (nine) sites. These diatom species are known to be indicative of N enrichment and were used to determine an empirical critical load of N deposition, or threshold level, where changes in diatom communities were observed at Hoh Lake. However, N deposition at the remaining nine lakes does not seem to exceed a critical load at this time. At Milk Lake, also in Olympic National Park, there was some evidence that climate change might be altering diatom communities, but more research is needed to confirm this. We used modeled precipitation for Hoh Lake and annual inorganic N concentrations from a nearby National Atmospheric Deposition Program station, to calculate elevation-corrected N deposition for 1980–2009 at Hoh Lake. An exponential fit to this data was hindcasted to the 1969–1975 time period, and we estimate a critical load of 1.0 to 1.2 kg N ha −1 year −1 for wet deposition for this lake.

Washington↗
USGS1994

Selected data on characteristics of glacial-deposit and carbonate-rock aquifers, Midwestern Basin and Arches region

In 1988, the Geological Survey (USGS) began study to examine the hydrogeologic framework, ground-water-flow systems, water chemistry, and withdrawal response of aquifers in glacial deposits and carbonate rock in the Midwestern Basins and Arches Region in western Ohio and eastern Indiana. As part of this study, data from pumped-well tests and instantaneous-rechange tests (slug tests) of wells completed in the glacial-deposit and carbonate-rock aquifers were compiled from reports and information on file with State agencies, environmental consulting firms, drilling firms, municipalities, universities, and the USGS. The data, from 73 counties in Ohio and Indiana, were entered into a computerized data base in a spreadsheet format and subsequently into a geographic information system (GIS). Aquifer-characteristics data from this compilation include the results of 105 pumped-well tests and 39 slug tests in wells completed in glacial deposits, 174 pumped-well tests in wells completed in the carbonate-rock aquifer, and 4 slug tests in wells completed in limestones and shales of Ordovician age. Transmissivities from the pumped-well tests in wells completed in glacial till and glacial-deposit aquifers (sands and gravels) range from 1.54 to 69,700 feet squared per day. Storage coefficients or specific yields range from 0.00002 to 0.38 at these wells. Horizontal-hydraulic conductivities from the slug tests in wells completed in glacial-deposit aquifers range from 0.33 to 1,000 feet per day. Transmissivities from the pumped-well tests in wells completed in the carbonate-rock aquifer range from 70 to 52,000 feet squared per day. Storage coefficient or specific yields at these wells range from 0.00001 to 0.05. Horizontal hydraulic conductivities from the slug tests in wells completed in limestones and shales of Ordovician age range from 0.0016 to 12 feet per day. These data are summarized in tables and figures within this report. The collection and compilation of selected aquifer-characteristic data for the glacial-deposit and carbonate-rock aquifers within the Midwestern Basin and Arches Region of Shaver (1985) are an essential part of the Midwestern Basins and Arches Regional Aquifer-Systems Analysis (Midwestern Basins and Arches RASA) project of the U.S. Geological Survey (USGS). Specifically, the data are needed to help describe ground-water flow in the regional aquifer system, which isone of the objectives of the Midwestern Basins and Arches RASA project (Bugliosi, 1990). To meet this objective, the Midwestern Basins and Arches RASA began subprojects in the Ohio and Indiana offices of the USGS to collect and compile available aquifer-characteristics data from aquifer tests of the glacial-deposit and carbonate-rock aquifers. The data were not reanalyzed to verify accuracy because of time constraints and insufficient data in many cases.

Illinois, Indiana, Kentucky, Ohio, West Virginia↗
USGS2014

Report of the committee on chemistry of natural waters, 1936–37

The membership of this Committee is as follows: C. S. Howard, Chairman, U. S. Geological Survey, Washington, D.C. D. G. Thompson, U. S. Geological Survey, Washington, D.C. A. C. Lane, 22 Arlington Street, Cambridge, Massachusetts C. S. Scofield, Bureau of Plant Industry, U. S. Dept. Agri., Washington, D. C. I. A. Denison, U.S. Bureau of Standards, Washington, D.C. T. G. Thompson, University of Washington, Seattle, Washington W. P. Kelley, Citrus Experiment Station, Riverside, California In order to provide for close cooperation between the work of the different research‐committees of the American Geophysical Union it was decided to have the chairmen of certain committees serve on other committees. The Chairman of the Committee on the Chemistry of Natural Waters is serving on the Committee of Underground waters and D. G. Thompson as Chairman of the Committee on Underground Waters is serving on the Committee on Chemistry of Natural Waters

Eos, Transactions, American Geophysical Union↗
USGS2016

Multidecadal increases in the Yukon River Basin of chemical fluxes as indicators of changing flowpaths, groundwater, and permafrost

The Yukon River Basin, underlain by discontinuous permafrost, has experienced a warming climate over the last century that has altered air temperature, precipitation, and permafrost. We investigated a water chemistry database from 1982 to 2014 for the Yukon River and its major tributary, the Tanana River. Significant increases of Ca, Mg, and Na annual flux were found in both rivers. Additionally, SO 4 and P annual flux increased in the Yukon River. No annual trends were observed for dissolved organic carbon (DOC) from 2001 to 2014. In the Yukon River, Mg and SO 4 flux increased throughout the year, while some of the most positive trends for Ca, Mg, Na, SO 4 , and P flux occurred during the fall and winter months. Both rivers exhibited positive monthly DOC flux trends for summer (Yukon River) and winter (Tanana River). These trends suggest increased active layer expansion, weathering, and sulfide oxidation due to permafrost degradation throughout the Yukon River Basin.

Yukon River Basin↗
USGS2018

Nutrient dynamics in partially drained arctic thaw lakes

Thaw lakes are ubiquitous on arctic coastal plains (ACPs). While many thaw lakes have steep banks, stable water levels, and static surface areas, others only partially fill their basins and vary in area over the summer. These partially drained lakes (PDLs) are hydrologically connected to the wetlands immediately surrounding them. Heat and nutrient availability limit aquatic productivity on ACPs, and we hypothesized that shallow shorelines and greater hydrologic connectivity with the landscape should result in greater nutrient concentrations and biogeochemical cycling in PDLs. We tested this by monitoring water chemistry in lakes with varying levels of seasonal drainage in sandy and silty peaty lowland sites on the ACP of Alaska. One highly drained lake (N1) was significantly warmer than minimally drained lakes (minDLs) related to earlier ice off, reaching temperatures as high as 16 °C in June when minDLs still contained ice. Ammonia, total dissolved phosphorus, and dissolved organic carbon and nitrogen concentrations were higher in lakes with greater drainage, and concentrations in N1 rivaled those in the small, biologically productive ponds. Many PDLs displayed a midsummer decrease in nutrients consistent with assimilation by the aquatic ecosystem, and a late‐summer increase most likely related to runoff from drained lake margins following precipitation. N1 exported kilograms of ammonium and total dissolved phosphorus to the stream network over the summer. Given increased warming and drying in the arctic, the proportion of PDLs may be changing, which in turn may affect nutrient and organic matter availability in arctic lakes and export to downstream environments.

Journal of Geophysical Research: Biogeosciences↗
USGS2016

Seasonal variation exceeds effects of salmon carcass additions on benthic food webs in the Elwha River

Dam removal and other fish barrier removal projects in western North America are assumed to boost freshwater productivity via the transport of marine-derived nutrients from recolonizing Pacific salmon ( Oncorhynchus spp.). In anticipation of the removal of two hydroelectric dams on the Elwha River in Washington State, we tested this hypothesis with a salmon carcass addition experiment. Our study was designed to examine how background nutrient dynamics and benthic food webs vary seasonally, and how these features respond to salmon subsidies. We conducted our experiment in six side channels of the Elwha River, each with a spatially paired reference and treatment reach. Each reach was sampled on multiple occasions from October 2007 to August 2008, before and after carcass placement. We evaluated nutrient limitation status; measured water chemistry, periphyton, benthic invertebrates, and juvenile rainbow trout ( O. mykiss ) response; and traced salmon-derived nutrient uptake using stable isotopes. Outside of winter, algal accrual was limited by both nitrogen and phosphorous and remained so even in the presence of salmon carcasses. One month after salmon addition, dissolved inorganic nitrogen levels doubled in treatment reaches. Two months after addition, benthic algal accrual was significantly elevated. We detected no changes in invertebrate or fish metrics, with the exception of 15 N enrichment. Natural seasonal variability was greater than salmon effects for the majority of our response metrics. Yet seasonality and synchronicity of nutrient supply and demand are often overlooked in nutrient enhancement studies. Timing and magnitude of salmon-derived nitrogen utilization suggest that uptake of dissolved nutrients was favored over direct consumption of carcasses. The highest proportion of salmon-derived nitrogen was incorporated by herbivores (18–30%) and peaked 1–2 months after carcass addition. Peak nitrogen enrichment in predators (11–16%) occurred 2–3 months after addition. All taxa returned to background δ 15 N levels by 7 months. Since this study was conducted, both dams on the Elwha River were removed over 2011–2014 to open over 90% of the basin to anadromous fishes. We anticipate that as the full portfolio of salmon species expands through the basin, nutrient supply and demand will come into better balance.

Ecosphere↗
USGS2020

A round-robin evaluation of the repeatability and reproducibility of environmental DNA assays for dreissenid mussels

Resource managers may be hesitant to make decisions based on environmental (e)DNA results alone since eDNA is an indirect method of species detection. One way to reduce the uncertainty of eDNA is to identify laboratory‐based protocols that ensure repeatable and reproducible results. We conducted a double‐blind round‐robin analysis of probe‐based assays for DNA of dreissenid ( Dreissena spp.) mussels, which are prolific aquatic invaders that can cause significant economic and ecological impacts. DNA extract from water samples spiked with known amounts of dreissenid DNA and from water samples collected from waters with and without dreissenids were analyzed by four independent research laboratories. We used results to calculate detection repeatability within laboratories and assays, detection reproducibility among laboratories and assays, and estimated dreissenid DNA copy number precision and accuracy. Laboratory and assay repeatability and reproducibility of detection results were high, 91% and 92%, respectively. The estimated copy numbers were neither precise nor accurate for samples spiked with <773 gene copies. These results suggest that eDNA surveillance of dreissenid mussels, using the protocols evaluated herein, can generate reliable detection data for decision‐making. However, managers should be cautious about using the quantitative information often associated with eDNA detections, especially when DNA is at lower abundance. Our results provide strong support that eDNA has the potential to provide repeatable and reproducible evidence under varying laboratory conditions and for different sample water chemistries. This is reassuring since the demand for eDNA surveillance is widespread and number of laboratories that process eDNA samples is growing steadily.

California, Montana, Nevada, New York, Oregon, Was↗
USGS2014

Expanding metal mixture toxicity models to natural stream and lake invertebrate communities

A modeling approach that was used to predict the toxicity of dissolved single and multiple metals to trout is extended to stream benthic macroinvertebrates, freshwater zooplankton, and Daphnia magna . The approach predicts the accumulation of toxicants (H, Al, Cd, Cu, Ni, Pb, and Zn) in organisms using 3 equilibrium accumulation models that define interactions between dissolved cations and biological receptors (biotic ligands). These models differ in the structure of the receptors and include a 2-site biotic ligand model, a bidentate biotic ligand or 2-pKa model, and a humic acid model. The predicted accumulation of toxicants is weighted using toxicant-specific coefficients and incorporated into a toxicity function called Tox, which is then related to observed mortality or invertebrate community richness using a logistic equation. All accumulation models provide reasonable fits to metal concentrations in tissue samples of stream invertebrates. Despite the good fits, distinct differences in the magnitude of toxicant accumulation and biotic ligand speciation exist among the models for a given solution composition. However, predicted biological responses are similar among the models because there are interdependencies among model parameters in the accumulation–Tox models. To illustrate potential applications of the approaches, the 3 accumulation–Tox models for natural stream invertebrates are used in Monte Carlo simulations to predict the probability of adverse impacts in catchments of differing geology in central Colorado (USA); to link geology, water chemistry, and biological response; and to demonstrate how this approach can be used to screen for potential risks associated with resource development.

Environmental Toxicology and Chemistry↗