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At least 775 records · Page 43Linked to original sources

Thermal infrared (2.5-13.5 μm) spectroscopic remote sensing of igneous rock types on particulate planetary surfaces

Fundamental molecular vibration bands are significantly diminished by scattering. Thus such bands in spectra of fine particulate regoliths (i.e., dominated by <5-&mu;m particles), or regoliths displaying a similar scale of porosity, are difficult to use for mineralogical or rock type identification. Consequently, other spectral features have been sought that may be more useful in spectroscopic remote sensing of composition. We find that mineralogical information is retained in overtones and combination tones of the fundamental molecular vibrations in the 3.0- to 7.0-&mu;m region, but that relatively few minerals have a sufficiently distinctive band structure to be unambiguously identified with currently available techniques. More significantly, identification of general rock type, as defined by the SCFM chemical index (SCFM = SiO 2 /SiO 2 + CaO + FeO + MgO), is possible using spectral features associated with the principal Christiansen frequency and with a region of relative transparency between the Si-O stretching and bending bands. However, environmental factors may affect the appearance and wavelengths of these features. Finally, prominent absorption bands may result from the presence of relatively small amounts of water, hydroxyl or carbonate, because absorption bands exhibited by these materials in the 2.7- to 4.0-&mu;m region, where silicate spectra are otherwise featureless, increase strongly in spectral contrast with decreasing particle size. Such materials are thus detectable in very small amounts in a particulate regolith composed predominantly of silicate minerals.

Journal of Geophysical Research↗

Trace element geochemistry (Li, Ba, Sr, and Rb) using Curiosity's ChemCam: early results for Gale crater from Bradbury Landing Site to Rocknest

The ChemCam instrument package on the Mars rover, Curiosity, provides new capabilities to probe the abundances of certain trace elements in the rocks and soils on Mars using the laser-induced breakdown spectroscopy technique. We focus on detecting and quantifying Li, Ba, Rb, and Sr in targets analyzed during the first 100 sols, from Bradbury Landing Site to Rocknest. Univariate peak area models and multivariate partial least squares models are presented. Li, detected for the first time directly on Mars, is generally low (<15 ppm). The lack of soil enrichment in Li, which is highly fluid mobile, is consistent with limited influx of subsurface waters contributing to the upper soils. Localized enrichments of up to ~60 ppm Li have been observed in several rocks but the host mineral for Li is unclear. Bathurst_Inlet is a fine-grained bedrock unit in which several analysis locations show a decrease in Li and other alkalis with depth, which may imply that the unit has undergone low-level aqueous alteration that has preferentially drawn the alkalis to the surface. Ba (~1000 ppm) was detected in a buried pebble in the Akaitcho sand ripple and it appears to correlate with Si, Al, Na, and K, indicating a possible feldspathic composition. Rb and Sr are in the conglomerate Link at abundances >100 ppm and >1000 ppm, respectively. These analysis locations tend to have high Si and alkali abundances, consistent with a feldspar composition. Together, these trace element observations provide possible evidence of magma differentiation and aqueous alteration.

Journal of Geophysical Research E: Planets↗

Incorporating measurements of vertical land motion in wetland surface elevation change analyses

We compared elevation trajectories from 14 rod surface elevation table (RSET) stations and 60 real-time kinematic (RTK) global positioning system (GPS) transects within the Blackwater National Wildlife Refuge (BNWR) from 2010–2013. The results were similar, 7.3 ± 0.9 (mean ± standard error; RSET) versus 6.2 ± 0.6 mm year −1 (RTK) ( P = 0.216), and were greater than relative sea level rise (RSLR) computed at the nearest long-term tide station (3.9 ± 0.29 mm year −1 ). Despite having shown elevation gain, these wetlands continue to drown and convert to open water. Episodic, multi-day GPS measurements on geodetic control marks at BNWR between 2005 and 2023 revealed a substantial vertical land motion (VLM) signal. From 2005 to 2015, three reference marks used to control the 2010–2013 RTK study lost on average 6.0 ± 0.7 mm year −1 , corresponding to 80% and 94% of the elevation gain measured by the RSET and RTK techniques, respectively. The longer 18-year subsidence trend measured on one of these marks was lower, 3.9 ± 0.7 mm year −1 , highlighting important interannual variability. Wetland elevation change measurements need to account for VLM occurring below the reference marks used to measure elevation change. Estimates from the nearest long-term tide station may not be applicable to the wetland if the tide station is in a different geological setting. At BNWR, VLM was higher than the VLM at the Cambridge tide station, which helps explain why wetlands at BNWR are not keeping pace with RSLR despite the measured high rates of elevation gain.

Maryland↗

Topographic map of Mars M 25M RKN

NOTES ON BASE This map is based on data from the Mars Orbiter Laser Altimeter (MOLA) (Smith and others, 2001), an instrument on NASA's Mars Global Surveyor (MGS) spacecraft (Albee and others, 2001). The image used for the base of this map represents more than 600 million measurements gathered between 1999 and 2001, adjusted for consistency (Neumann and others, 2001, 2002) and converted to planetary radii. These have been converted to elevations above the areoid as determined from a martian gravity field solution GMM2 (Lemoine and others, 2001), truncated to degree and order 50, and oriented according to current standards (see below). The average accuracy of each point is originally ~100 meters in horizontal position, and ~1 meter in radius (Neumann, 2001). However, the total elevation uncertainty is at least +3 m due to the global error in the areoid (+1.8 meters according to Lemoine and others, 2001) and regional uncertainties in its shape (communication from Neumann, 2002). The measurements were converted into a digital elevation model (DEM) (communication from Neumann, 2002; Neumann and others, 2001; Smith and others, 2001) using Generic Mapping Tools software (Wessel and Smith, 1998), with a resolution of 0.015625 degrees per pixel or 64 pixels per degree. In projection, the pixels are 926.17 meters in size at the equator. PROJECTION The Mercator projection is used between latitudes +57°, with a central meridian at 0° and latitude equal to the nominal scale at 0°. The Polar Stereographic projection is used for the polar regions north of the +55° parallel and south of the –55° parallel with a central meridian set for both at 0°. The adopted equatorial radius is 3,396.19 km (Duxbury and others 2002; Seidelmann and others 2002). COORDINATE SYSTEM The MOLA data were initially referenced to an internally consistent inertial coordinate system, derived from tracking of the MGS spacecraft. By adopting appropriate values for the orientation of Mars as defined by the International Astronomical Union (IAU) and the International Association of Geodesy (IAG) (Seidelmann and others, 2002), these inertial coordinates were converted into the planet-fixed coordinates (longitude and latitude) used on this map. These values include the orientation of the north pole of Mars (including the effects of precession), the rotation rate of Mars, and a value for W0 of 176.630°, where W0 is the angle along the equator to the east, between the 0° meridian and the equator's intersection with the celestial equator at the standard epoch J2000.0 (Seidelmann and others, 2002). This value of W0 was chosen (Duxbury and others, 2002) in order to place the 0° meridian through the center of the small (~500 m) crater Airy-0, located in the crater Airy (de Vaucouleurs and others, 1973; Seidelmann and others, 2002). Longitude increases to the east, and latitude is planetocentric as allowed by IAU/IAG standards (Seidelmann and others, 2002) and in accordance with current NASA and USGS standards (Duxbury and others, 2002). A secondary grid (printed in red) has been added to the map as a reference to the west longitude/planetographic latitude system that is also allowed by IAU/IAG standards (Seidelmann and others, 2002) and has also been used for Mars. The figure adopted to compute this secondary grid is an oblate spheroid with an equatorial radius of 3,396.19 km and a polar radius of 3,376.2 km (Duxbury and others, 2002; Seidelmann and others, 2002). MAPPING TECHNIQUES To create the topographic base image, the original DEM produced by the MOLA team in Simple Cylindrical projection with a resolution of 64 pixels per degree was projected into the Mercator and Polar Stereographic pieces. A shaded relief was generated from each DEM with a sun angle of 30° from horizontal and a sun azimuth of 270°, as measured clockwise from north, and a vertical exaggeration of 100%. Illumination is from the west, which follows a long-standing USGS tradition for planetary maps. This allows for continuity in the shading between maps and quadrangles, and most closely resembles lighting conditions found on imagery. The DEM values were then mapped to a smooth global color look-up table. Note that the chosen color scheme simply represents elevation changes and is not intended to imply anything about surface characteristics (e.g., past or current presence of water or ice). These two files were then merged and scaled to 1:25 million for the Mercator portion and 1:15,196,708 for the two Polar Stereographic portions, with a resolution of 300 dots per inch. The projections have a common scale of 1:13,923,113 at +56° latitude. NOMENCLATURE Names on this sheet are approved by the IAU and have been applied for features clearly visible at the scale of this map. For a complete list of the IAU-approved nomenclature for Mars, see the Gazetteer of Planetary Nomenclature at http://planetarynames.wr.usgs.gov/. Font color was chosen for readability. Names followed by an asterisk are provisionally approved. *M 25M RKN: Abbreviation for Mars, 1:25,000,000 series, shaded relief (R), with color (K) and nomenclature (N) (Greeley and Batson, 1990)

Open-File Report↗

Color-coded contour map of Mars M 25M RKN

NOTES ON BASE This map is based on data from the Mars Orbiter Laser Altimeter (MOLA) (Smith and others, 2001), an instrument on NASA's Mars Global Surveyor (MGS) spacecraft (Albee and others, 2001). The image used for the base of this map represents more than 600 million measurements gathered between 1999 and 2001, adjusted for consistency (Neumann and others, 2001, 2002) and converted to planetary radii. These have been converted to elevations above the areoid as determined from a martian gravity field solution GMM2 (Lemoine and others, 2001), truncated to degree and order 50, and oriented according to current standards (see below). The average accuracy of each point is originally ~100 meters in horizontal position, and ~1 meter in radius (Neumann, 2001). However, the total elevation uncertainty is at least +3 m due to the global error in the areoid (+1.8 meters according to Lemoine and others, 2001) and regional uncertainties in its shape (communication from Neumann, 2002). The measurements were converted into a digital elevation model (DEM) (communication from Neumann, 2002; Neumann and others, 2001; Smith and others, 2001) using Generic Mapping Tools software (Wessel and Smith, 1998), with a resolution of 0.015625 degrees per pixel or 64 pixels per degree. In projection, the pixels are 926.17 meters in size at the equator. PROJECTION The Mercator projection is used between latitudes +57°, with a central meridian at 0° and latitude equal to the nominal scale at 0°. The Polar Stereographic projection is used for the polar regions north of the +55° parallel and south of the –55° parallel with a central meridian set for both at 0°. The adopted equatorial radius is 3,396.19 km (Duxbury and others 2002; Seidelmann and others 2002). COORDINATE SYSTEM The MOLA data were initially referenced to an internally consistent inertial coordinate system, derived from tracking of the MGS spacecraft. By adopting appropriate values for the orientation of Mars as defined by the International Astronomical Union (IAU) and the International Association of Geodesy (IAG) (Seidelmann and others, 2002), these inertial coordinates were converted into the planet-fixed coordinates (longitude and latitude) used on this map. These values include the orientation of the north pole of Mars (including the effects of precession), the rotation rate of Mars, and a value for W0 of 176.630°, where W0 is the angle along the equator to the east, between the 0° meridian and the equator's intersection with the celestial equator at the standard epoch J2000.0 (Seidelmann and others, 2002). This value of W0 was chosen (Duxbury and others, 2002) in order to place the 0° meridian through the center of the small (~500 m) crater Airy-0, located in the crater Airy (de Vaucouleurs and others, 1973; Seidelmann and others, 2002). Longitude increases to the east, and latitude is planetocentric as allowed by IAU/IAG standards (Seidelmann and others, 2002) and in accordance with current NASA and USGS standards (Duxbury and others, 2002). A secondary grid (printed in red) has been added to the map as a reference to the west longitude/planetographic latitude system that is also allowed by IAU/IAG standards (Seidelmann and others, 2002) and has also been used for Mars. The figure adopted to compute this secondary grid is an oblate spheroid with an equatorial radius of 3,396.19 km and a polar radius of 3,376.2 km (Duxbury and others, 2002; Seidelmann and others, 2002). MAPPING TECHNIQUES To create the topographic base image, the original DEM produced by the MOLA team in Simple Cylindrical projection with a resolution of 64 pixels per degree was projected into the Mercator and Polar Stereographic pieces. A shaded relief was generated from each DEM with a sun angle of 30° from horizontal and a sun azimuth of 270°, as measured clockwise from north, and a vertical exaggeration of 100%. Illumination is from the west, which follows a long-standing USGS tradition for planetary maps. This allows for continuity in the shading between maps and quadrangles, and most closely resembles lighting conditions found on imagery. The DEM values were then mapped to a smooth global color look-up table. Note that the chosen color scheme simply represents elevation changes and is not intended to imply anything about surface characteristics (e.g., past or current presence of water or ice). These two files were then merged and scaled to 1:25 million for the Mercator portion and 1:15,196,708 for the two Polar Stereographic portions, with a resolution of 300 dots per inch. The projections have a common scale of 1:13,923,113 at +56° latitude. Contours were created from the DEM at a 1-kilometer interval. Contours for features with a diameter of 3 km or less (features too small for this map scale) were removed. The contours were then simplified by removing points along the contours spaced less than 1 km apart. NOMENCLATURE Names on this sheet are approved by the IAU and have been applied for features clearly visible at the scale of this map. For a complete list of the IAU-approved nomenclature for Mars, see the Gazetteer of Planetary Nomenclature at http://planetarynames.wr.usgs.gov/. Font color was chosen for readability. Names followed by an asterisk are provisionally approved. M 25M RKN: Abbreviation for Mars, 1:25,000,000 series, shaded relief (R), with color (K) and nomenclature (N) (Greeley and Batson, 1990).

Open-File Report↗

Effect of nitrate, organic carbon, and temperature on potential denitrification rates in nitrate-rich riverbed sediments

A study conducted in 1994 as part of the US Geological Survey's National Water-Quality Assessment Program, South Platte River Basin investigation, examined the effect of certain environmental factors on potential denitrification rates in nitrate-rich riverbed sediments. The acetylene block technique was used to measure nitrous oxide (N2O) production rates in laboratory incubations of riverbed sediments to evaluate the effect of varying nitrate concentrations, organic carbon concentrations and type, and water temperature on potential denitrification rates. Sediment incubations amended with nitrate, at concentrations ranging from 357 to 2142 ??mol l-1 (as measured in the field), produced no significant increase (P > 0.05) in N2O production rates, indicating that the denitrification potential in these sediments was not nitrate limited. In contrast, incubations amended with acetate as a source of organic carbon, at concentrations ranging from 0 to 624 ??mol l-1, produced significant increases (P < 0.05) in N2O production rates with increased organic carbon concentration, indicating that the denitrification potential in these sediments was organic carbon limited. Furthermore, N2O production rates also were affected by the type of organic carbon available as an electron donor. Acetate and surface-water-derived fulvic acid supported higher N2O production rates than groundwater-derived fulvic acid or sedimentary organic carbon. Lowering incubation temperatures from 22 to 4??C resulted in about a 77% decrease in the N2O production rates. These results help to explain findings from previous studies indicating that only 15-30% of nitrate in groundwater was denitrified before discharging to the South Platte River and that nitrate concentrations in the river generally were higher in winter than in summer.

Journal of Hydrology↗

Warmwater fish in small standing waters

This chapter describes standardized sampling techniques for routine monitoring and population assessment of warmwater sport and prey fishes in small standing water bodies. Although water temperature regulates growth, survival, and reproduction of fishes, there are no specific criteria that define a warmwater fish community. Dodds (2002) noted that warmwater fish communities tend to be dominated by sunfishes, temperate basses, and catfishes. Perches and pikes are common to coolwater fish communities, and trouts and salmons are characteristic of coldwater fish communities. For this chapter, we focus on species that prefer water temperatures greater than 15°C. Coolwater fishes that are important in small natural lakes or impoundments and not incorporated in other chapters are also included. As with warmwater fish, there is also no stringent definition of a small standing water body. Small standing waters generally contain less complex habitats and fish communities than large standing waters. For this chapter, an area of 200 ha was selected as the maximum surface area for small standing waters, but surface-area designations may vary regionally. Other than a strict definition based on surface area, the manageability of less complex fish communities in small water bodies along with differences in their physical and limnological characteristics, as described below, help separate them from larger water bodies. On a broad scale, there are four generic types of small standing water bodies: impoundments (ponds), natural lakes, excavated pits, and dugouts. An impoundment is created by damming a perennial, intermittent, or ephemeral stream in a watershed. A natural lake is a depression in the landscape that gathers water, either by seepage, runoff, direct precipitation, or a combination of sources. An excavated pit results from groundwater seepage into an excavated site that was mined for gravel, sand, rock, or fill for construction. A dugout (referred to as a tank in the Southwest) is created by collection of surface water or well water in an excavated site built for the purpose of watering livestock.

Book chapter↗

GSFLOW - Coupled Ground-Water and Surface-Water Flow Model Based on the Integration of the Precipitation-Runoff Modeling System (PRMS) and the Modular Ground-Water Flow Model (MODFLOW-2005)

The need to assess the effects of variability in climate, biota, geology, and human activities on water availability and flow requires the development of models that couple two or more components of the hydrologic cycle. An integrated hydrologic model called GSFLOW (Ground-water and Surface-water FLOW) was developed to simulate coupled ground-water and surface-water resources. The new model is based on the integration of the U.S. Geological Survey Precipitation-Runoff Modeling System (PRMS) and the U.S. Geological Survey Modular Ground-Water Flow Model (MODFLOW). Additional model components were developed, and existing components were modified, to facilitate integration of the models. Methods were developed to route flow among the PRMS Hydrologic Response Units (HRUs) and between the HRUs and the MODFLOW finite-difference cells. This report describes the organization, concepts, design, and mathematical formulation of all GSFLOW model components. An important aspect of the integrated model design is its ability to conserve water mass and to provide comprehensive water budgets for a location of interest. This report includes descriptions of how water budgets are calculated for the integrated model and for individual model components. GSFLOW provides a robust modeling system for simulating flow through the hydrologic cycle, while allowing for future enhancements to incorporate other simulation techniques.

Techniques and Methods↗

Developing a temporal database of urban development for the Baltimore/Washington region

The U.S. Geological Survey (USGS), the University of Maryland Baltimore County (UMBC), and the U.S. Bureau of the Census are working together as a multiagency, multidisciplinary team in developing a temporal database that documents the growth of the Baltimore-Washington metropolitan region. This database consists of urban development, principal transportation, shoreline, and population density change. The urban development theme, considered a primary data layer in the study of urban land transformation resulting from human impact on the land, is the focus of this paper. The Baltimore-Washington Spatial Dynamics and Human Impacts Study builds on earlier research efforts that mapped urban land use change for the San Francisco Bay area (Acevedo and Bell, 1994; Bell and others, 1995; Kirtland and others, 1994). In developing a temporal database (Acevedo and others, in press), the team participants hope to provide data that can be used to study patterns of urban growth; assess ecological, environmental, and climatic impacts of urban change; and model and predict future urbanization patterns and impacts (Clarke and others, 1996). Both the San Francisco and Baltimore-Washington regions were selected because of the rapid urban growth and resulting impacts on their ecosystems. The Chesapeake Bay region in particular has undergone extensive environmental agitation due to the hydrologic problems that have arisen from the increase in impermeable surfaces and structures, that is buildings and pavement that physically cover the soil. Because of the inability of water to percolate into the ground, little purification occurs by filtration. Water runs over paved surfaces and quickly washes high levels of toxins directly into the water system. Toxins like gasoline, oil, and fertilizer have dramatically affected the local streams, rivers, and the bay. ABSTRACT The U.S. Geological Survey, the University of Maryland Baltimore County, and the U.S. Bureau of the Census are developing a temporal database to study urban development in the Baltimore-Washington region. The primary data layer, the extent of urban or built-up areas, was compiled using a geographic information system and historical maps, remotely sensed data, digital land use data, and census information from a variety of sources. Urban land use change has been documented by the Baltimore-Washington Spatial Dynamics & Human Impact Study Team for the last 200 years. The methods, definitions, and collection criteria used to define urban or built-up areas were developed by a multi-disciplinary team that also ensures consistency in collection techniques and documentation methods for subsequent application in other regions. Animation techniques were used to visualize the database and to document the evolution of the region's urban landscape. The database is an important tool to urban and regional planners, ecologists, and global change researchers for measuring trends in urban sprawl, analyzing patterns of water pollution, understanding the impacts of development on ecosystems, and developing predictive modeling techniques to better forecast areas of urban growth. This paper describes the techniques used to map the extent of urban areas for Phase I and does not discuss Phase II in detail because the work is still in progress. In this study, urban development is defined as areas of intensive use, with much of the land covered by structures. The built-up areas are characterized by the existence of a systematic street pattern, and the relative concentration of buildings and associated intensive use areas, such as parking lots. Using this definition, urban development does not refer to political boundaries and may include incorporated or unincorporated areas as well as military reservations. ABSTRACT The U.S. Geological Survey, the University of Maryland Baltimore County, and the U.S. Bureau of the Census are developing a temporal database to study urban development in the Baltimore-Washington region. The primary data layer, the extent of urban or built-up areas, was compiled using a geographic information system and historical maps, remotely sensed data, digital land use data, and census information from a variety of sources. Urban land use change has been documented by the Baltimore-Washington Spatial Dynamics & Human Impact Study Team for the last 200 years. The methods, definitions, and collection criteria used to define urban or built-up areas were developed by a multi-disciplinary team that also ensures consistency in collection techniques and documentation methods for subsequent application in other regions. Animation techniques were used to visualize the database and to document the evolution of the region's urban landscape. The database is an important tool to urban and regional planners, ecologists, and global change researchers for measuring trends in urban sprawl, analyzing patterns of water pollution, understanding the impacts of development on ecosystems, and developing predictive modeling techniques to better forecast areas of urban growth. To build the urban component of the temporal database, a multidisciplinary team was assembled and a phased approach initiated. Expanding on procedures developed for the San Francisco Regional Study (Bell and others, 1995), the team developed data definitions, a classification scheme, compilation criteria, mapping specifications, guidelines for source materials, and metadata specifications to support development of a logically consistent dataset. Extensive documentation procedures were established to ensure consistency in data collection, and for subsequent application to other regions. Phase II was the implementation of the regional mapping effort. ABSTRACT The U.S. Geological Survey, the University of Maryland Baltimore County, and the U.S. Bureau of the Census are developing a temporal database to study urban development in the Baltimore-Washington region. The primary data layer, the extent of urban or built-up areas, was compiled using a geographic information system and historical maps, remotely sensed data, digital land use data, and census information from a variety of sources. Urban land use change has been documented by the Baltimore-Washington Spatial Dynamics & Human Impact Study Team for the last 200 years. The methods, definitions, and collection criteria used to define urban or built-up areas were developed by a multi-disciplinary team that also ensures consistency in collection techniques and documentation methods for subsequent application in other regions. Animation techniques were used to visualize the database and to document the evolution of the region's urban landscape. The database is an important tool to urban and regional planners, ecologists, and global change researchers for measuring trends in urban sprawl, analyzing patterns of water pollution, understanding the impacts of development on ecosystems, and developing predictive modeling techniques to better forecast areas of urban growth. The study area for Phase I consisted of an approximate area of 15- by 15-minute segment centered around the city of Baltimore (fig. 1). Phase I was used as a prototype for the technique development and integration that the multiagency collaborative effort would require. The regional study, Phase II, encompassed a 2-degree square centered on Washington, D.C. With more than 7 million people spread across 39 counties, the Baltimore-Washington region is one the Nation's fastest growing metropolitan areas. The two cities are rapidly merging into one.

Maryland↗

Digital database architecture and delineation methodology for deriving drainage basins, and a comparison of digitally and non-digitally derived numeric drainage areas

The drainage basin is a fundamental hydrologic entity used for studies of surface-water resources and during planning of water-related projects. Numeric drainage areas published by the U.S. Geological Survey water science centers in Annual Water Data Reports and on the National Water Information Systems (NWIS) Web site are still primarily derived from hard-copy sources and by manual delineation of polygonal basin areas on paper topographic map sheets. To expedite numeric drainage area determinations, the Colorado Water Science Center developed a digital database structure and a delineation methodology based on the hydrologic unit boundaries in the National Watershed Boundary Dataset. This report describes the digital database architecture and delineation methodology and also presents the results of a comparison of the numeric drainage areas derived using this digital methodology with those derived using traditional, non-digital methods. (Please see report for full Abstract)

Techniques and Methods↗

Use of biological characteristics of common carp ( Cyprinus carpio ) to indicate exposure to hormonally active agents in selected Minnesota streams, 1999

The presence of hormonally active agents (HAAs) was determined in selected Minnesota streams using biological characteristics (measures of endocrine disruption) of common carp ( Cyprinus carpio ) exposed to wastewater treatment plant (WWTP) effluent and runoff from agricultural and forested land. Four biological characteristics of common carp were used as indicators of HAAs in the streams selected for this study: (1) high concentrations of vitellogenin in male fish and low concentrations in female fish, (2) high or low plasma concentrations of the sex steroid hormones (17&beta;-estradiol and 11-ketotestosterone), (3) low gonado-somatic index (GSI) (gonad weight divided by total body weight multiplied by 100) values, and (4) abnormal gonad histopathology (high percent of atretic oocytes in female ovaries and high percent ceroid/lipofuscin tissue in male or female gonads). The study design was a paired site approach targeting sites downstream and upstream of WWTP discharges on different streams. Male (221 individuals) and female (201 individuals) common carp were collected using electrofishing techniques from seven streams with sites at two locations (upstream and downstream of WWTPs), and eight sites located downstream of WWTPs with no upstream-paired sites. Samples were collected between August 3 and September 13, 1999. The presence of HAAs in selected Minnesota streams was indicated by biological characteristics in common carp. Biological characteristics used in this study identified WWTP effluent as a potential source of HAAs. Additionally, fish located at sites upstream of WWTP effluent primarily draining agricultural land show indications of HAAs, which may be the result of agricultural runoff or other sources of HAAs. There was variability among all sites and among sites within each site group. Differences among sites may be due to differences in water chemistry or fish exposure time. Natural variation in the biological characteristics may account for some of the differences observed in this study. This study and others indicate the presence of HAAs in surface water and the potential signs of endocrine disruption in resident fish populations. Detailed controlled studies could confirm the effects of particular chemicals such as pesticides or components of WWTPs on fish reproduction and population structure.

Minnesota↗

Advances in ice radar studies of a temperate alpine glacier, South Cascade Glacier, Washington, U.S.A.

South Cascade Glacier, Washington, U.S.A., is one of the most extensively studied glaciers in the Western Hemisphere. In addition to mass-balance measurements, which date to 1958, numerous hydrological investigations have been carried out during the last three decades, and repeated ice-thickness determinations have been made using a variety of techniques. In the late 1960s, the basal topography was initially determined by gravitimetric methods. In the mid-1970s some of the first depth measurements using radar on temperate ice were made. The basal topography was remapped soon after from a series of point radar measurements and boreholes drilled to the glacier bottom. During the 1990s, the ice thickness was remapped using digital recording of continuous profiles that obtained over 5000 ice-thickness measurements. Profiles have been corrected for the finite beamwidth of the antenna radiation pattern and reflections in steep terrain, resulting in a significantly improved depiction of the basal surface and internal structures. The map based on our recent radar profiles confirms the large-scale features of the basal topography previously depicted and reveals more structural detail. A bright reflector was detected at the base of the glacier and could be traced in adjacent profiles. Comparison with results from water-level measurements in boreholes drilled to the bed indicates that the reflector is a subglacial conduit.

Washington↗

Integrating hydrologic and geophysical data to constrain coastal surficial aquifer processes at multiple spatial and temporal scales

Since 1997, repeated, coincident geophysical surveys and extensive hydrologic studies in shallow monitoring wells have been used to study static and dynamic processes associated with surface water-groundwater interaction at a range of spatial scales at the estuarine and ocean boundaries of an undeveloped, permeable barrier island in the Georgia part of the U.S. South Atlantic Bight. Because geophysical and hydrologic data measure different parameters, at different resolution and precision, and over vastly different spatial scales, reconciling the coincident data or even combining complementary inversion, hydrogeochemcial analyses and well-based groundwater monitoring, and, in some cases, limited vegetation mapping to demonstrate the utility of an integrative, multidisciplinary approach for elucidating groundwater processes at spatial scales (tens to thousands of meters) that are often difficult to capture with traditional hydrologic approaches. The case studies highlight regional aquifer characteristics, varying degrees of lateral saltwater intrusion at estuarine boundaries, complex subsurface salinity gradients at the ocean boundary, and imaging of submarsh groundwater discharge and possible free convection in the pore waters of a clastic marsh. This study also documents the use of geophysical techniques for detecting temporal changes in groundwater salinity regimes under natural (not forced) gradients at intratidal to interannual (1998-200 Southeastern U.S.A. drought) time scales.

Book chapter↗

Diazotrophic community structure and function in two successional stages of biological soil crusts from the Colorado Plateau and Chihuahuan Desert

The objective of this study was to characterize the community structure and activity of N 2 -fixing microorganisms in mature and poorly developed biological soil crusts from both the Colorado Plateau and Chihuahuan Desert. Nitrogenase activity was approximately 10 and 2.5 times higher in mature crusts than in poorly developed crusts at the Colorado Plateau site and Chihuahuan Desert site, respectively. Analysis of nifH sequences by clone sequencing and the terminal restriction fragment length polymorphism technique indicated that the crust diazotrophic community was 80 to 90% heterocystous cyanobacteria most closely related to Nostoc spp. and that the composition of N 2 -fixing species did not vary significantly between the poorly developed and mature crusts at either site. In contrast, the abundance of nifH sequences was approximately 7.5 times greater (per microgram of total DNA) in mature crusts than in poorly developed crusts at a given site as measured by quantitative PCR. 16S rRNA gene clone sequencing and microscopic analysis of the cyanobacterial community within both crust types demonstrated a transition from a Microcoleus vaginatus -dominated, poorly developed crust to mature crusts harboring a greater percentage of Nostoc and Scytonema spp. We hypothesize that ecological factors, such as soil instability and water stress, may constrain the growth of N 2 -fixing microorganisms at our study sites and that the transition to a mature, nitrogen-producing crust initially requires bioengineering of the surface microenvironment by Microcoleus vaginatus .

New Mexico, Utah↗

Phreatophytic land-cover map of the northern and central Great Basin Ecoregion: California, Idaho, Nevada, Utah, Oregon, and Wyoming

Increasing water use and changing climate in the Great Basin of the western United States are likely affecting the distribution of phreatophytic vegetation in the region. Phreatophytic plant communities that depend on groundwater are susceptible to natural and anthropogenic changes to hydrologic flow systems. The purpose of this report is to document the methods used to create the accompanying map that delineates areas of the Great Basin that have the greatest potential to support phreatophytic vegetation. Several data sets were used to develop the data displayed on the map, including Shrub Map (a land-cover data set derived from the Regional Gap Analysis Program) and Gap Analysis Program (GAP) data sets for California and Wyoming. In addition, the analysis used the surface landforms from the U.S. Geological Survey (USGS) Global Ecosystems Mapping Project data to delineate regions of the study area based on topographic relief that are most favorable to support phreatophytic vegetation. Using spatial analysis techniques in a GIS, phreatophytic vegetation classes identified within Shrub Map and GAP were selected and compared to the spatial distribution of selected landforms in the study area to delineate areas of phreatophyte vegetation. Results were compared to more detailed studies conducted in selected areas. A general qualitative description of the data and the limitations of the base data determined that these results provide a regional overview but are not intended for localized studies or as a substitute for detailed field analysis. The map is intended as a decision-support aide for land managers to better understand, anticipate, and respond to ecosystem changes in the Great Basin.

Scientific Investigations Map↗

Modeling, mapping, and measuring the risk of freshwater invasive species across Alaska

Freshwater ecosystems of the Alaskan Arctic and Subarctic provide resources that are culturally, ecologically, and economically invaluable. Presently, these regions are relatively free of the impacts from invasive species compared to southern latitudes. To date, there have been relatively few verified introductions of aquatic invasive species (AIS) to freshwater ecosystems in Alaska. The expanding list and distribution of AIS has led to significant negative ecological and economic impacts (e.g., waterweed Elodea nuttalli ; E. canadensis and northern pike Esox Lucius introduced outside its native range in Alaska). Escalating human activity across Alaskan lands and waters, coupled with rapidly shifting environmental conditions, increases the potential for new species introductions and subsequent establishment. Creating a proactive framework for well-informed decision-making and action can improve the effectiveness of prevention efforts and bolster decision support tools that help resource managers direct limited resources. Prioritizing AIS that may be introduced and become established, as well as the locations at highest risk of invasion, is foundational to building a proactive invasive species management framework in Alaska. This project sought to identify and prioritize AIS known to be invasive in the contiguous United States, evaluate current and future habitat suitability for AIS in Alaska, and assess potential for AIS to be transported to habitats across Alaska, utilizing similar assessment methods as implemented for Bering Sea marine invasive species and non-native plants in Alaska. To accomplish this goal, the objectives of the project were to: 1) develop a formal ranked list of potential AIS to freshwater systems of Alaska; 2) assess the level of establishment risk for potential AIS by developing habitat suitability models for waterbodies across Alaska; and 3), identify potential pathways and specific vectors for high-risk AIS to invade Alaska and develop a framework for how vector analysis will be completed to understand transport risk. Overall, our goal is horizon scanning which is defined by Roy et al. (2019) as “a systematic examination of potential threats and opportunities, within a given context, and likely future developments, which are at the margin of current thinking and planning.” The scans include pathway analyses and risk screening of species present at pathway origin points, with a focus on identifying species at high risk of being introduced, becoming established, spreading, and causing harm. We refined a list of 28 AIS from a list of hundreds based on characterizations of species’ invasiveness and species’ proximity to Alaska (USGS 2020; GBIF 2022). Next, we evaluated the relative invasiveness of individual species to create an initial AIS ranking. We sought to characterize habitat suitability of AIS by selecting variables that were continental in scale, covering North America to include Alaska as well as the lower 48 states comparing natural discharge, sub-basin average terrain slope (degrees), average silt fraction, average organic carbon, lithological class, and human footprint in sub-basin in 2009. We estimated AIS habitat suitability across the entire state of Alaska using the physiological tolerances of the AIS (Appendix 2). We also evaluated pathways and vectors for the introduction of AIS (Appendix 2). Many pathways and vectors considered did not meet the criteria for Alaska or freshwater systems. Of the 28 ranked species that we categorized as very high, high, and moderate levels of invasiveness; all three risk groups included fish and mollusks (Appendix 2). One commonality of the very high-invasiveness-ranked species was the availability of Ecological Risk Screening Summary documents (USFWS, 2022) produced by U.S. Fish and Wildlife Service (USFWS), except for the goldfish ( Carassius auratus ) and the New Zealand mudsnail ( Potamopyrgus antipodarum ). The Ecological Risk Screening Summary is now available for New Zealand mudsnails. In general, fish species often ranked very high or high in invasiveness and included sportfish and aquarium fish, suggesting the importance of pathways such as aquarium trade, fishing industry, intentional (but illegal) introductions of sportfishes and aquarium fishes for establishment. The technique we used for habitat suitability models necessitated aquatic environmental datasets that were continental in scale, which was often interpolated from very coarse resolution source data layers, particularly in Alaska. Better spatial data representing aquatic environments would likely improve this approach. While the lack of introductions in Alaska and nearby provinces and states is encouraging, the lack of occurrence data for the focal species also created complications for habitat suitability modeling. Despite the challenges, the habitat suitability models indicated limited suitability for warmwater species while some species, such as Brook trout (S alvelinus fontinalis ), have high habitat suitability across Alaska no matter what threshold approach is taken. Some environmental predictors were more important than others. Specifically, the most important predictor variable, ‘frost free days,’ was critical for 15 out of 28 species as expected due to harsh winter conditions in Arctic and Subarctic regions. The second most important predictor was ‘subbasin land surface runoff’, a variable that indicates the amount of discharge and runoff, while the third most important predictor was ‘snow cover’ another indication of winter conditions. Overall, the ability to understand the effect of future climate scenarios on the establishment of AIS was challenging. A detailed dataset of freshwater temperatures and water chemistry (e.g., pH, calcium) would greatly improve the ability to predict invasiveness of freshwater species to Alaska’s ecosystems on a regional basis. Future studies may benefit from a more focused geographic scope examining a group of subbasins or a regional basin rather than the entire state. These drainages could be selected based upon the mostly likely locations of introduction pathways. The two most prevalent pathway risks for AIS are in-state transfer and stowaways/contaminants. Although there are examples of introductions from other pathways, the risk is somewhat mitigated by Alaska’s climate and regulations. However, variable application of protocols for inspection and cleaning of fishing gear, watercraft, and other similar items while traveling into Alaska as well as transferring from waterbody to waterbody within the state creates a substantial risk in introducing invasive species. We plot cumulative invasive vulnerability for all subbasins and for the top 10% of subbasins (Appendix 3).

Alaska↗

Mineralogical, magnetic and geochemical data constrain the pathways and extent of weathering of mineralized sedimentary rocks

The oxidative weathering of sulfidic rock can profoundly impact watersheds through the resulting export of acidity and metals. Weathering leaves a record of mineral transformation, particularly involving minor redox-sensitive phases, that can inform the development of conceptual and quantitative models. In sulfidic sedimentary rocks, however, variations in depositional history, diagenesis and mineralization can change or overprint the distributions of these trace minerals, complicating the interpretation of weathering signatures. Here we show that a combination of bulk mineralogical and geochemical techniques, micrometer-resolution X-ray fluorescence microprobe analysis and rock magnetic measurements, applied to drill core samples and single weathered fractures, can provide data that enable the development of a geochemically consistent weathering model. This work focused on one watershed in the Upper Colorado River Basin sitting within the Mesaverde Formation, a sedimentary sandstone bedrock with disseminated sulfide minerals, including pyrite and sphalerite, that were introduced during diagenesis and subsequent magmatic-hydrothermal mineralization. Combined analytical methods revealed the pathways of iron (Fe), carbonate and silicate mineral weathering and showed how pH controls element retention or release from the actively weathering fractured sandstone. Drill core logging, whole rock X-ray diffraction, and geochemical measurements document the progression from unweathered rock at depth to weathered rock at the surface. X-ray microprobe analyses of a 1-cm size weathering profile along a fracture surface are consistent with the mobilization of Fe(II) and Fe(III) into acidic pore water from the dissolution of primary pyrite, Fe-sphalerite, chlorite, and minor siderite and pyrrhotite. These reactions are followed by the precipitation of secondary minerals such as of goethite and jarosite, a Fe-(oxyhydr)oxide and hydrous Fe(III) sulfate, respectively. Microscale analyses also helped explain the weathering reactions responsible for the mineralogical transformations observed in the top and most weathered section of the drill core. For example, dissolution of feldspar and chlorite neutralizes the acidity generated by Fe and sulfide mineral oxidation, oversaturating the solution in both Fe-oxides. The combination of X-ray spectromicroscopy and magnetic measurements show that the Fe(III) product is goethite, mainly present either as a coatings on fracture surfaces in the actively weathering region of the core or more homogeneously contained within the unconsolidated regolith at the top of the core. Low-temperature magnetic data reveal the presence of ferromagnetic Fe-sulfide pyrrhotite that, although it occurs at trace concentrations, could provide a qualitative proxy for unweathered sulfide minerals because the loss of pyrrhotite is associated with the onset of oxidative weathering. Pyrrhotite loss and goethite formation are detectable through room-temperature magnetic coercivity changes, suggesting that rock magnetic measurements can determine weathering intensity in rock samples at many scales. This work contributes evidence that the weathering of sulfidic sedimentary rocks follows a geochemical pattern in which the abundance of sulfide minerals controls the generation of acidity and dissolved elements, and the pH-dependent mobility of these elements controls their export to the ground- and surface-water.

Colorado↗

Establishing aquatic restoration priorities using a watershed approach

Since the passage of the Clean Water Act in 1972, the United States has made great strides to reduce the threats to its rivers, lakes, and wetlands from pollution. However, despite our obvious successes, nearly half of the nation’s surface water resources remain incapable of supporting basic aquatic values or maintaining water quality adequate for recreational swimming. The Clean Water Act established a significant federal presence in water quality regulation by controlling point and non-point sources of pollution. Point-sources of pollution were the major emphasis of the Act, but Section 208 specifically addressed non-point sources of pollution and designated silviculture and livestock grazing as sources of non-point pollution. Non-point source pollutants include runoff from agriculture, municipalities, timber harvesting, mining, and livestock grazing. Non-point source pollution now accounts for more than half of the United States water quality impairments. To successfully improve water quality, restoration practitioners must start with an understanding of what ecosystem processes are operating in the watershed and how they have been affected by outside variables. A watershed-based analysis template developed in the Pacific Northwest can be a valuable aid in developing that level of understanding. The watershed analysis technique identifies four ecosystem scales useful to identify stream restoration priorities: region, basin, watershed, and site. The watershed analysis technique is based on a set of technically rigorous and defensible procedures designed to provide information on what processes are active at the watershed scale, how those processes are distributed in time and space. They help describe what the current upland and riparian conditions of the watershed are and how these conditions in turn influence aquatic habitat and other beneficial uses. The analysis is organized as a set of six steps that direct an interdisciplinary team of specialists to examine the biotic and abiotic processes influencing aquatic habitat and species abundance. This process helps develop an understanding of the watershed within the context of the larger ecosystem. The understanding gained can then be used to identify and prioritize aquatic restoration activities at the appropriate temporal and spatial scale. The watershed approach prevents relying solely on site-level information, a common problem with historic restoration efforts. When the watershed analysis process was used in the Whitefish Mountains of northwest Montana, natural resource professionals were able to determine the dominant habitat forming processes important for native fishes and use that information to prioritize, plan, and implement the appropriate restoration activities at the watershed scale. Despite considerable investments of time and resources needed to complete an analysis at the watershed scale, the results can prevent the misdiagnosis of aquatic problems and help ensure that the objectives of aquatic restoration will be met.

Journal of Environmental Management↗