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At least 775 records · Page 43Linked to original sources

USGS1991

Geohydrology of the High Plains aquifer system, Cheyenne urban area, Wyoming

The Cheyenne area is on broad tablelands that form part of the High Plains aquifer. Surficial deposits, along with the Ogallala Formation and the White River Group, are included in the High Plains aquifer in the study area, and both unconfined and confined ground-water conditions exist within 100 feet of land surface. During wet years, shallow ground-water problems affect urban development. The High Plains aquifer is considered an aquifer system in the Cheyenne area. Water-yielding sandstone and conglomerate units are surrounded by sequences of clay and silt; although the water-yielding units under confined conditions may be areally extensive, they are not easily identified. Urban development has modified the High Plains aquifer system locally as indicated by the mapped potentiometric surfaces, the perched water zones, and the surface-drainage patterns. That part of the system in the shallow zones is affected by excavations and by structures that penetrate the saturated zones.

Wyoming↗

USGS2010

Interfacing models of wildlife habitat and human development to predict the future distribution of puma habitat

The impact of human land uses on ecological systems typically differ relative to how extensively natural conditions are modified. Exurban development is intermediate-intensity residential development that often occurs in natural landscapes. Most species-habitat models do not evaluate the effects of such intermediate levels of human development and even fewer predict how future development patterns might affect the amount and configuration of habitat. We addressed these deficiencies by interfacing a habitat model with a spatially-explicit housing-density model to study the effect of human land uses on the habitat of pumas ( Puma concolor ) in southern California. We studied the response of pumas to natural and anthropogenic features within their home ranges and how mortality risk varied across a gradient of human development. We also used our housing-density model to estimate past and future housing densities and model the distribution of puma habitat in 1970, 2000, and 2030. The natural landscape for pumas in our study area consisted of riparian areas, oak woodlands, and open, conifer forests embedded in a chaparral matrix. Pumas rarely incorporated suburban or urban development into their home ranges, which is consistent with the hypothesis that the behavioral decisions of individuals can be collectively manifested as population-limiting factors at broader spatial scales. Pumas incorporated rural and exurban development into their home ranges, apparently perceiving these areas as modified, rather than non-habitat. Overall, pumas used exurban areas less than expected and showed a neutral response to rural areas. However, individual pumas that selected for or showed a neutral response to exurban areas had a higher risk of mortality than pumas that selected against exurban habitat. Exurban areas are likely hotspots for puma-human conflict in southern California. Approximately 10% of our study area will transform from exurban, rural, or undeveloped areas to suburban or urban by 2030, and 35% of suitable puma habitat on private land in 1970 will have been lost by 2030. These land-use changes will further isolate puma populations in southern California, but the ability to visualize these changes had provided a new tool for developing proactive conservation solutions.

California↗

USGS2026

Perceptions of parcel-level wildfire risk differ between homeowners and trained assessors in wildland-urban interface communities across the western United States

Wildfire risk mitigation on private property is central to reducing community wildfire vulnerability. Homeowners have control over many of the key factors that contribute to wildfire risk on their parcels, yet vulnerable conditions persist. One potential explanation is a misalignment between homeowners' and trained assessors' perceptions of parcel-level wildfire risk. Prior research has documented a “risk gap” in a single community wherein owners often underestimate their parcel-level wildfire risk; however, it is unclear whether such misalignments are widespread. This study replicates and expands previous research by examining the parcel-level wildfire risk gap in 38 wildland–urban interface (WUI) communities across the Western United States using paired data from household surveys and parcel-level wildfire risk assessments by trained assessors. We find that homeowners and assessors often perceive parcel characteristics differently. Homeowners may systematically mis-weight their importance, tending to underweight key controllable factors such as building materials and defensible space, leading to meaningful divergence from trained assessor ratings. Accordingly, we also find that homeowners generally underestimate overall parcel wildfire risk compared to trained assessors. These results suggest that even when homeowners recognize attributes on their parcels that contribute to wildfire risk, they may not fully grasp how much the attributes contribute to overall parcel risk, potentially failing to recognize the need to undertake meaningful mitigation actions. The findings from this study contribute to the broader natural hazards literature on expert-layperson risk perception gaps and offer insights for improving wildfire communication, education, and mitigation strategies in WUI communities.

Alaska, Colorado, New Mexico, Utah, Wyoming↗

USGS2008

Bottom-Sediment Accumulation and Quality in Shawnee Mission Lake, Johnson County, Kansas, 2006

Shawnee Mission Lake is an artificial impoundment central to Shawnee Mission Park, the largest public park in Johnson County, Kansas. The Shawnee Mission Lake watershed has remained relatively undeveloped since the completion of the dam in 1962. However, recent (1990?2006) urban development has been a cause for concern regarding the quantity and quality of sediment entering the reservoir. The U.S. Geological Survey collected two cores of bottom sediment to assess sediment accumulation and quality in Shawnee Mission Lake. Results from this study indicate that sediment accumulation has remained relatively constant from 1970?2006 at the downstream portion of the reservoir. Runoff from urban portions of the watershed are likely responsible for larger concentrations of selected trace elements in more recently deposited reservoir sediment. Information provided in this report can be used by Johnson County officials to help determine the current and future recreational capacity of the lake.

Scientific Investigations Report↗

USGS2007

Water quality of the St. Clair River, Lake St. Clair, and their U.S. tributaries, 1946-2005

The St. Clair River/Lake St. Clair waterway forms an international boundary between the United States and Canada. The waters of the area are an important part of the cultural heritage of the area and serves as an important water-supply and power-generating resource; the waterway also supports an economy based largely on recreation, agriculture, and manufacturing. This report was undertaken as part of the Lake St. Clair Regional Monitoring Project for the purpose of providing a comprehensive assessment of the hydrological, chemical, and physical state of the surface water of Lake St. Clair and its tributaries. The data varied in focus and density over the period of compilation which in many cases this variation prevented the completion of statistical analyses because data did not meet minimum comparability or quality requirements for those tests. Comparison of water quality of the Belle, Black, Clinton, and Pine River Basins, as well as basins of minor rivers in the study area, showed that water quality in many of the tributaries, particularly the Clinton River and some of the minor rivers, was degraded compared to the water quality of the St. Clair River/Lake St. Clair waterway. Data analyses included comparison of nutrients, chloride, specific conductance, turbidity, biochemical oxygen demand (BOD), and pesticides among the basins and the St. Clair River. Median concentrations of total nitrate were well below the recommended USEPA total nitrogen ambient water-quality criterion of 0.54 mg/L as N for nutrient ecoregion VII for all study-area streams except the Clinton River. More than 93 percent of the phosphorus concentrations for the Belle, Black, Pine and minor river basins and 84 percent of the phosphorus concentrations for the Clinton River Basin are greater than the USEPA recommended ambient total phosphorus criterion of 0.033 mg/L for rivers and streams. Nine chloride concentrations exceeded the USEPA criterion maximum concentration (CMC) for chloride set at 860 mg/L for all study-area streams, with the six largest being in the Belle River Basin. Higher chloride concentrations were increasingly common from 2002 to 2005. The urban minor river basins had the highest median specific conductance, whereas the agricultural Pine River Basin had the lowest median specific conductance. The median values of BOD for the five basins in the study area ranged from 2.4 mg/L for the Pine River Basin to 3.2 mg/L for the Black and Clinton River Basins, whereas the median for the St. Clair River was 0.5 mg/L. In 1985, the highest concentrations of pesticides were found in samples from the mouth of the Clinton River; however, in 1996–98, the majority of high pesticide concentrations were found in samples from the Black River. Changing land-use patterns, specifically conversion of agricultural lands to urban/residential lands in the Clinton River Basin, may explain this difference. Trend analysis was done for four stream sites where adequate data were available. These analyses identified no significant water-quality changes at a stream site on the Black River, where land-use patterns have changed little in the past few decades. This stands in marked contrast to trend analysis for three stream sites in the Clinton River Basin, which has undergone significant land-use change. The changes at the Clinton River stream sites, ranging from 5 to 13 significant trends, were generally decreases in nutrients and increases in total dissolved solids (TDS) and chloride. The greater flow volume of the St. Clair River/Lake St. Clair waterway is able to assimilate incoming dissolved and suspended constituents from tributaries with little effect upon its overall water quality, although incomplete mixing may result in localized water-quality impairment downstream from tributary confluences. Mixing effects on Lake St. Clair water quality was also demonstrated in analysis of Escherichia coli ( E. coli ) data collected at paired nearshore/offshore sites, which reflected similarity in water quality among many paired sites.

Michigan↗

USGS2025

Hot stops, cool looks: Aesthetic solutions for thermal comfort at transit stops

Increased urban heat intensifies thermal discomfort, particularly in critical public spaces such as transit stops. This study investigated the predictors of transit users' thermal perceptions in Denver, Colorado—a semi-arid city. Sixty bus stops spanning a gradient of land cover compositions were selected for study. Micrometeorological data, including thermal comfort indices, were collected alongside survey responses from 77 users at 31 unique stops. Survey responses captured thermal sensation votes (TSV) and thermal comfort votes (TCV) as well as aesthetic preference votes (APV) of bus stop structure. Ordinal forest analysis revealed that for both TSV and TCV, aesthetic preferences and thermal comfort indices were the most influential predictors of transit user thermal perception. Multiple ordered logistic regression further demonstrated that, for TSV, higher APV was associated with lower odds of rating a thermal environment as hot (OR = 0.664, p < 0.002) while increased Physiological Equivalent Temperature (PET) raised these odds (OR = 1.101, p < 0.006). An interaction analysis demonstrated that APV significantly moderated the effect of PET on TCV (interaction OR = 1.040, p < 0.041), suggesting that aesthetic preferences are significantly correlated with an alleviation of thermal discomfort under high heat stress. Bivariate analyses further indicated that bus stops with greater tree canopy cover (OR = 1.032, p < 0.025) and higher visible vegetation view factors (OR = 10.350, p < 0.022) were more likely to be rated as aesthetically pleasing. These findings underscore the importance of aesthetic preferences in transit stop planning for urban heat resiliency.

Colorado↗

USGS2020

Identifying sustainable winter habitat for whooping cranes

The only self-sustaining population of endangered whooping cranes ( Grus americana ) requires a network of conservation lands for wintering along the Texas Gulf Coast (USA), so that this increasing population can reach downlisting under the Endangered Species Act (1,000 birds). We identify locations providing the highest quality and most sustainable wintering habitat for these whooping cranes through 2100 by predicting future habitats under three projections of sea level rise (0.6, 1.0 and 2.0 m by 2100), while incorporating two scenarios of future urban development. Our method combines predictions of future habitat quality with current whooping crane density estimates to calculate the potential carrying capacity of whooping cranes for each 10 m pixel within this 17,725 km 2 area. We found whooping cranes used locations with salt marsh at twice the rate of places lacking marsh. Areas > 15 km from development or < 2 km from estuarine water had increased crane use. Predicted area of salt marsh habitat oscillated across time given different rates of sea level rise. One urbanization scenario predicted 3% and the other 1% of the area converting to development by 2100. We estimated the study area can support 4414 (95% CI: 4096-4789) whooping cranes currently, 4795 (95% CI: 4402-5269) with 0.6 m sea level rise, 3559 (95% CI: 3352-3791) with 1 m sea level rise, and 2480 (95% CI: 2375-2592) with 2 m sea level rise by 2100, under the more aggressive urban development scenario. By anticipating climate-induced habitat loss with species population expansion we provide the requisite spatial information for conservation planners to build a sustainable conservation estate for downlisting whooping cranes. By coupling wildlife biology with conservation planning and on-the-ground implementation, our work exemplifies a proactive approach to recover endangered species.

Texas↗

USGS2007

Effects of Precipitation and Land Use on Storm Runoff

Storm-runoff quantity and quality were studied in three watersheds located near St. Paul in Ramsey County, Minnesota, from April 15 through September 15 of 1984, 1985, and 1986 to qualitatively determine the effects of precipitation and selected land uses on storm runoff. In respect to precipitation effects, differences in storm-runoff quantity between years in an urban watershed that lacks wetlands appear to be related to the average storm size (amount of precipitation) during the study period of each year. In contrast, the differences in storm-runoff quantity from watersheds that contain wetlands appear to be related to total precipitation during study period of each year. In respect to land use, the differences in storm-runoff quantity appear to be related to the amounts of impervious and wetland area. The watershed that contains the largest amount of impervious area and smallest amount of wetland area has the largest amount of storm runoff.

Water Resources Bulletin↗

USGS2009

Bacteria holding times for fecal coliform by mFC agar method and total coliform and Escherichia coli by Colilert®-18 Quanti-Tray® method

Bacteria holding-time experiments of up to 62 h were performed on five surface-water samples from four urban stream sites in the vicinity of Atlanta, GA, USA that had relatively high densities of coliform bacteria ( Escherichia coli densities were all well above the US Environmental Protection Agency criterion of 126 colonies (100 ml)  − 1 for recreational waters). Holding-time experiments were done for fecal coliform using the membrane filtration modified fecal coliform (mFC) agar method and for total coliform and E. coli using the Colilert ® -18 Quanti-Tray ® method. The precisions of these analytical methods were quantified. Precisions determined for fecal coliform indicated that the upper bound of the ideal range of counts could reasonably be extended upward and would improve precision. For the Colilert ® -18 method, analytical precisions were similar to the theoretical precisions for this method. Fecal and total coliform densities did not change significantly with holding times up to about 27 h. Limited information indicated that fecal coliform densities might be stable for holding times of up to 62 h, whereas total coliform densities might not be stable for holding times greater than about 27 h. E. coli densities were stable for holding times of up to 18 h—a shorter period than indicated from a previous studies. These results should be applicable to non-regulatory monitoring sampling designs for similar urban surface-water sample types.

Environmental Monitoring and Assessment↗

USGS2019

Evaluating restored tidal freshwater wetlands

As restoration of tidal freshwater wetlands has progressed in North America and Eurasia, research findings have continued to emerge on the postrestoration success of these ecosystems. The most common approaches used to restore tidal freshwater wetlands involve excavation or placement of dredged sediment to restore tidal hydrology compatible with vegetation establishment and managed realignment or diversion, which involves reconnecting former wetlands to tides by breaching dikes or levees. Postconstruction monitoring of tidal freshwater wetland restoration projects commonly includes not only studies of hydrology, soil, and vegetation but also geomorphology, microbial communities, seed banks, fish, birds, and invertebrates. Based on a review of assessment approaches and monitoring studies, we present criteria for evaluating tidal freshwater wetland restoration projects. In a case study, we apply these criteria to evaluate restored tidal freshwater wetlands in the highly urbanized Anacostia River watershed (Washington, DC, USA). We conclude that restoration can create tidal freshwater wetlands worldwide that share some structural or functional aspects with natural systems. Soil organic matter and microbial communities may be the slowest components to develop, and watershed urbanizationimposes strong constraints that prevent development of tidal freshwater wetlands similar to those in rural settings.

Book chapter↗

USGS2025

The joint effect of changes in urbanization and climate on trends in floods: A comparison of panel and single-station quantile regression approaches

Estimates of annual maximum (peak) flow quantiles are needed for basins undergoing changes in both urbanization and climate. Most previous work on the effect of urbanization on peak flows has considered urbanization alone and only the spatial variation in flood quantiles or its mean temporal effect, and most work on the effect of nonstationarity in climate has focused on single-station analyses, which give uncertain results for extreme quantiles. To address these gaps, three approaches to the statistical estimation of the joint effects of changes in impervious cover and climate on the estimation of peak-flow quantiles were compared: single-station quantile regression; a fixed effect panel-quantile regression (pQR) method using a location (mean) shift to homogenize the panel; and a location-scale panel regression model (pQRmom), which accounts for both scale (variance) and location effects. The different approaches were applied to a dataset consisting of instantaneous annual peak flows from 127 minimally nested basins in the midwestern United States with at least 4 % change in imperviousness. The annual maximum daily discharge from a water-balance model was selected as the primary climate predictor; in addition, to provide a comparison of climate predictors, precipitation was also considered. The coefficients from single-station regressions were usually sufficiently certain to determine the effects of climate variation but usually too uncertain to estimate the effects of urbanization. The panel-quantile regression approaches give much more certain results, but their estimates of quantile dependence differ: although both indicate urbanization effects decreasing with decreasing annual exceedance probability (AEP), the pQRmom urbanization coefficients are insignificantly different from zero for AEPs less than 0.10, whereas the pQR coefficients remain positive and are significant except for AEP = 0.01, the smallest AEP value considered. Although the location-scale structure of the pQRmom approach has less flexible quantile dependence than the pQR approach, the pQRmom approach has somewhat lower overall error, and it is found that by subsetting the dataset to homogenize the scale effects, the pQR and pQRmom results become similar, indicating the insignificant urbanization coefficients for small AEPs of the pQRmom results are likely correct for the study dataset.

Arkansas, Illinois, Indiana, Iowa, Michigan, Minne↗

USGS2013

Sand sources and transport pathways for the San Francisco Bay coastal system, based on X-ray diffraction mineralogy

The mineralogical compositions of 119 samples collected from throughout the San Francisco Bay coastal system, including bayfloor and seafloor, area beaches, cliff outcrops, and major drainages, were determined using X-ray diffraction (XRD). Comparison of the mineral concentrations and application of statistical cluster analysis of XRD spectra allowed for the determination of provenances and transport pathways. The use of XRD mineral identifications provides semi-quantitative compositions needed for comparisons of beach and offshore sands with potential cliff and river sources, but the innovative cluster analysis of XRD diffraction spectra provides a unique visualization of how groups of samples within the San Francisco Bay coastal system are related so that sand-sized sediment transport pathways can be inferred. The main vector for sediment transport as defined by the XRD analysis is from San Francisco Bay to the outer coast, where the sand then accumulates on the ebb tidal delta and also moves alongshore. This mineralogical link defines a critical pathway because large volumes of sediment have been removed from the Bay over the last century via channel dredging, aggregate mining, and borrow pit mining, with comparable volumes of erosion from the ebb tidal delta over the same period, in addition to high rates of shoreline retreat along the adjacent, open-coast beaches. Therefore, while previously only a temporal relationship was established, the transport pathway defined by mineralogical and geochemical tracers support the link between anthropogenic activities in the Bay and widespread erosion outside the Bay. The XRD results also establish the regional and local importance of sediment derived from cliff erosion, as well as both proximal and distal fluvial sources. This research is an important contribution to a broader provenance study aimed at identifying the driving forces for widespread geomorphic change in a heavily urbanized coastal-estuarine system.

California↗

USGS2019

Modelling gully-erosion susceptibility in a semi-arid region, Iran: Investigation of applicability of certainty factor and maximum entropy models

Gully erosion susceptibility mapping is a fundamental tool for land-use planning aimed at mitigating land degradation. However, the capabilities of some state-of-the-art data-mining models for developing accurate maps of gully erosion susceptibility have not yet been fully investigated. This study assessed and compared the performance of two different types of data-mining models for accurately mapping gully erosion susceptibility at a regional scale in Chavar, Ilam, Iran. The two methods evaluated were: Certainty Factor (CF), a bivariate statistical model; and Maximum Entropy (ME), an advanced machine learning model. Several geographic and environmental factors that can contribute to gully erosion were considered as predictor variables of gully erosion susceptibility. Based on an existing differential GPS survey inventory of gully erosion, a total of 63 eroded gullies were spatially randomly split in a 70:30 ratio for use in model calibration and validation, respectively. Accuracy assessments completed with the receiver operating characteristic curve method showed that the ME-based regional gully susceptibility map has an area under the curve (AUC) value of 88.6% whereas the CF-based map has an AUC of 81.8%. According to jackknife tests that were used to investigate the relative importance of predictor variables, aspect, distance to river, lithology and land use are the most influential factors for the spatial distribution of gully erosion susceptibility in this region of Iran. The gully erosion susceptibility maps produced in this study could be useful tools for land managers and engineers tasked with road development, urbanization and other future development.

Science of the Total Environment↗

USGS2000

Volatile organic compounds in storm water from a parking lot

A mass balance approach was used to determine the most important nonpoint source of volatile organic compounds (VOCs) in storm water from an asphalt parking lot without obvious point sources (e.g., gasoline stations). The parking lot surface and atmosphere are important nonpoint sources of VOCs, with each being important for different VOCs. The atmosphere is an important source of soluble, oxygenated VOCs (e.g., acetone), and the parking lot surface is an important source for the more hydrophobic VOCs (e.g., benzene). VOCs on the parking lot surface appear to be concentrated in oil and grease and organic material in urban particles (e.g., vehicle soot). Except in the case of spills, asphalt does not appear to be an important source of VOCs. The uptake isotherm of gaseous methyl tert -butyl ether on urban particles indicates a mechanism for dry deposition of VOCs from the atmosphere. This study demonstrated that a mass balance approach is a useful means of understanding non-point-source pollution, even for compounds such as VOCs, which are difficult to sample.

Journal of Environmental Engineering↗

USGS2007

Ambiguous taxa: Effects on the characterization and interpretation of invertebrate assemblages

Damaged and immature specimens often result in macroinvertebrate data that contain ambiguous parent-child pairs (i.e., abundances associated with multiple related levels of the taxonomic hierarchy such as Baetis pluto and the associated ambiguous parent Baetis sp.). The choice of method used to resolve ambiguous parent-child pairs may have a very large effect on the characterization of invertebrate assemblages and the interpretation of responses to environmental change because very large proportions of taxa richness (73-78%) and abundance (79-91%) can be associated with ambiguous parents. To address this issue, we examined 16 variations of 4 basic methods for resolving ambiguous taxa: RPKC (remove parent, keep child), MCWP (merge child with parent), RPMC (remove parent or merge child with parent depending on their abundances), and DPAC (distribute parents among children). The choice of method strongly affected assemblage structure, assemblage characteristics (e.g., metrics), and the ability to detect responses along environmental (urbanization) gradients. All methods except MCWP produced acceptable results when used consistently within a study. However, the assemblage characteristics (e.g., values of assemblage metrics) differed widely depending on the method used, and data should not be combined unless the methods used to resolve ambiguous taxa are well documented and are known to be comparable. The suitability of the methods was evaluated and compared on the basis of 13 criteria that considered conservation of taxa richness and abundance, consistency among samples, methods, and studies, and effects on the interpretation of the data. Methods RPMC and DPAC had the highest suitability scores regardless of whether ambiguous taxa were resolved for each sample separately or for a group of samples. Method MCWP gave consistently poor results. Methods MCWP and DPAC approximate the use of family-level identifications and operational taxonomic units (OTU), respectively. Our results suggest that restricting identifications to the family level is not a good method of resolving ambiguous taxa, whereas generating OTUs works well provided that documentation issues are addressed. ?? 2007 by The North American Benthological Society.

Journal of the North American Benthological Societ↗

USGS2010

U.S. Geological Survey (USGS), Western Region: Coastal ecosystem responses to influences from land and sea, Coastal and Ocean Science

Sea otters and the nearshore ecosystems they inhabit-from highly urbanized California to relatively pristine Alaska-are the focus of a new multidisciplinary study by scientists with the U.S. Geological Survey (USGS) and a suite of international, academic and government collaborators. The Coastal Ecosystem Responses to Influences from Land and Sea project will investigate the many interacting variables that influence the health of coastal ecosystems along the Northeast Pacific shore. These ecosystems face unprecedented challenges, with threats arising from the adjacent oceans and lands. From the ocean, challenges include acidification, sea level rise, and warming. From the land, challenges include elevated biological, geological and chemical pollutants associated with burgeoning human populations along coastlines. The implications of these challenges for biological systems are only beginning to be explored. Comparing sea otter population status indicators from around the northeastern Pacific Rim, will begin the process of defining factors of coastal ecosystem health in this broad region.

Fact Sheet↗

USGS2014

Status and understanding of groundwater quality in the Sierra Nevada Regional study unit, 2008: California GAMA Priority Basin Project

Groundwater quality in the Sierra Nevada Regional (SNR) study unit was investigated as part of the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The study was designed to provide statistically unbiased assessments of the quality of untreated groundwater within the primary aquifer system of the Sierra Nevada. The primary aquifer system for the SNR study unit was delineated by the depth intervals over which wells in the State of California’s database of public drinking-water supply wells are open or screened. Two types of assessments were made: (1) a status assessment that described the current quality of the groundwater resource, and (2) an evaluation of relations between groundwater quality and potential explanatory factors that represent characteristics of the primary aquifer system. The assessments characterize untreated groundwater quality, rather than the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on water-quality data collected by the U.S. Geological Survey from 83 wells in the SNR study unit in 2008 and from 117 wells in 3 small study units within the SNR study unit in 2006–07 and on water-quality data compiled in the State’s database for 1,066 wells sampled in 2006–08. To provide some context for the results, water-quality data were converted to relative-concentrations (RCs), which are the sample concentrations divided by the concentrations of Federal or California regulatory and non-regulatory benchmarks for drinking-water quality. RCs for inorganic constituents (major ions, trace elements, nutrients, and radioactive constituents) were classified as “high” (RC > 1.0, indicating that concentration is above the benchmark), “moderate” (1.0 ≥ RC > 0.5), or “low” (RC ≤ 0.5). For organic constituents (volatile organic compounds and pesticides) and special-interest constituents (perchlorate and N -nitrosodimethylamine [NDMA]), the boundary between moderate and low RCs was set at 0.1. All benchmarks used for organic constituents were health-based, whereas health-based and aesthetic-based benchmarks were used for inorganic constituents. The primary metric used for quantifying regional-scale groundwater quality was “aquifer-scale proportion.” Aquifer-scale proportions were calculated as the areal percentages of the primary aquifer system having high, moderate, and low RCs for a given constituent or class of constituents. The SNR study unit area was classified into four aquifer lithologic types—granitic rocks, metamorphic rocks, sedimentary deposits, and volcanic rocks—and aquifer-scale proportions were calculated on an area-weighted basis for each of the four aquifer lithologies and for the study unit as a whole (aggregated system). The results of the status assessment indicated that inorganic constituents were present at high and moderate RCs in greater proportions in the SNR study unit aggregated primary aquifer system than were organic constituents and that there were significant differences (p < 0.05) between the four aquifer lithologies. One or more inorganic constituents with health-based benchmarks were present at high RCs in 16 percent of the aggregated primary aquifer system and at moderate RCs in 21 percent. Arsenic (9.7 percent), uranium (2.9 percent), boron (2.0 percent), fluoride (1.8 percent), and nitrate (1.4 percent) were the constituents most commonly present at high RCs. For inorganic constituents with aesthetic-based benchmarks, 18 percent of the aggregated primary aquifer system had high RCs of one or more constituent, and 6.8 percent had moderate RCs. Iron (15.8 percent), manganese (15.1 percent), and total dissolved solids (1.3 percent) were the constituents most commonly present at high RCs. Organic constituents were not detected in 72 percent of the primary aquifer system. One or more organic constituents had high RCs in 0.1 percent of the primary aquifer system, moderate RCs in 3.0 percent, and low RCs in 25 percent. Proportions of the four lithologic primary aquifer systems with high or moderate concentrations of organic constituents were not significantly different. Three organic constituents had area-weighted detection frequencies greater than 10 percent in the primary aquifer system as a whole or at least one of the four lithologic primary aquifer systems: the gasoline oxygenate methyl tert -butyl ether, the trihalomethane chloroform, and the herbicide simazine. The special-interest constituent perchlorate was detected at high RCs in 0.01 percent of the primary aquifer system and at moderate RCs in 1.0 percent, and detection frequencies could be accounted for by the distribution of perchlorate under natural conditions. Statistical tests were used to evaluate relations between constituent concentrations and potential explanatory factors descriptive of land use, geography, depth, geochemical conditions, and groundwater age. Higher concentrations of trace elements, radioactive constituents, and constituents with aesthetic-based benchmarks generally were associated with anoxic conditions, higher pH, and location within a particular compositional band in the Sierra Nevada batholith corresponding to the southwestern part of the study unit. High concentrations of organic constituents generally were associated with greater proportions of urban land use. No significant relations were observed between the concentrations of organic constituents and measures of well depth or groundwater age, perhaps because of the high proportions of springs and modern groundwater in the dataset.

California↗

USGS1996

Water-quality assessment of the Trinity River Basin, Texas — Pesticides in streams draining an urban and an agricultural area, 1993-95

Water and bed-sediment samples from streams draining an urban and an agricultural area in the Trinity River Basin, Texas, were analyzed. The samples were collected during March 1993?September 1995 by the Trinity River Basin study-unit team of the National Water-Quality Assessment Program. A comparison of pesticide data for water samples from seven streams in the Dallas-Fort Worth urban area with five streams in an agricultural area in the west-central part of the Trinity River Basin showed detections of 24 herbicides in urban-area streams and 19 herbicides in agricultural-area streams and 10 insecticides in each area. Atrazine, a herbicide, was detected in all samples from both areas. Diazinon, an insecticide, was detected in all samples collected in urban-area streams and in about 60 percent of the samples collected in agricultural-area streams. Concentrations of alachlor, atrazine, fluometuron, metolachlor, and pendimethalin (herbicides) were always greater in agricultural-area streams, and prometon and simazine concentrations were always greater in urban-area streams. Atrazine was the only herbicide with concentrations greater than a health advisory limit of 3 micrograms per liter. Concentrations were greater in about 20 percent of the samples; all were in the agricultural area and occurred during spring and during higher streamflow. Diazinon was the only insecticide with concentrations greater than the health advisory of 0.6 microgram per liter. Concentrations were greater in about 15 percent of the samples from the urban area. All exceedances were during spring through early fall and during all ranges of streamflow. In the agricultural area, atrazine and metolachlor concentrations peaked during spring and early summer and increased with increasing streamflow; in the urban area, carbaryl, chlorpyrifos, and diazinon peaked in April and remained relatively high during the summer and increased with increasing streamflow. A comparison of pesticide data for bed-sediment samples from five urban streams and five agricultural streams showed detections of 11 organochlorine insecticides in the urban area and 1 in the agricultural area. All compounds were either DDT-related or one of the components of chlordane except for mirex and dieldrin.

Texas↗