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At least 775 records · Page 43Linked to original sources

Generation of aliphatic acid anions and carbon dioxide by hydrous pyrolysis of crude oils

Two crude oils with relatively high (0.60 wt%) and low (0.18 wt%) oxygen contents were heated in the presence of water in gold-plated reactors at 300??C for 2348 h. The high-oxygen oil was also heated at 200??C for 5711 h. The compositions of aqueous organic acid anions of the oils and of the headspace gases were monitored inn order to investigate the distribution of organic acids that can be generated from liquid petroleum. The oil with higher oxygen content generated about five times as much organic anions as the other oil. The dominant organic anions produced were acetate, propionate and butyrate. Small amounts of formate, succinate, methyl succinate and oxalate were also produced. The dominant oxygen-containing product was CO2, as has been observed in similar studies on the hydrous pyrolysis of kerogen. These results indicate that a significant portion (10-30%) of organic acid anions reported i be generated by thermal alteration of oils in reservoir rocks. The bulk of organic acid anions present in formation waters, however, is most likely generated by thermal alteration of kerogen in source rocks. Kerogen is more abundant than oil in sedimentary basins and the relative yields of organic acid anions reported from the hydrous pyrolysis of kerogen are much higher than the yields obtained for the two oils. ?? 1993.

Applied Geochemistry↗

Thermal alteration of Cretaceous black shale from the Eastern Atlantic. III: Laboratory simulations

Laboratory thermal alteration (pyrolysis) experiments were carried out on composited Cretaceous black shale samples from DSDP Hole 368. Dried rock samples (low water-rock ratio) were heated in an inert atmosphere in the range of 250–500°C and the resultant bitumen and kerogen concentrates were characterized. Pyrobitumen forms initially (250°C), then major hydrocarbon generation occurs from 300–360°C and oxygenated products ( e.g. alkanoic acids) have a maximum yield at 330–360°C with minor generation to 500°C. Dealkylation of the aromatic hydrocarbons to the parent polynuclear aromatic hydrocarbons occurs above 400°C. The kerogens become more aromatic with increasing pyrolysis temperature (atomic H/C decreases from 1.2 to 0.5 and vitrinite reflectance increases to 3%). The temperature ranges of pyrobitumen, bitumen, and PAH formation in dry pyrolysis experiments are of utility in correlating with field data on ore genesis.

Atlantic Ocean, Cape Verde Rise↗

Organic sedimentation in modern lacustrine systems: A case study from Lake Malawi, East Africa

This study examines the relationship between depositional environment and sedimentary organic geochemistry in Lake Malawi, East Africa, and evaluates the relative significance of the various processes that control sedimentary organic matter (OM) in lacustrine systems. Total organic carbon (TOC) concentrations in recent sediments from Lake Malawi range from 0.01 to 8.80 wt% and average 2.83 wt% for surface sediments and 2.35 wt% for shallow core sediments. Hydrogen index (HI) values as determined by Rock-Eval pyrolysis range from 0 to 756 mg HC g−1 TOC and average 205 mg HC g−1 TOC for surface sediments and 228 mg HC g−1 TOC for shallow core samples. On average, variations in primary productivity throughout the lake may account for ~33% of the TOC content in Lake Malawi sediments (as much as 1 wt% TOC), and have little or no impact on sedimentary HI values. Similarly, ~33% to 66% of the variation in TOC content in Lake Malawi sediments appears to be controlled by anoxic preservation of OM (~1–2 wt% TOC), although some component of the water depth–TOC relationship may be due to physical sediment transport processes. Furthermore, anoxic preservation has a minimal effect on HI values in Lake Malawi sediments. Dilution of OM by inorganic sediment may account for ~16% of variability in TOC content in Lake Malawi sediments (~0.5 wt% TOC). The effect of inputs of terrestrial sediment on the organic character of surface sediments in these lakes is highly variable, and appears to be more closely related to the local depositional environment than the regional flux of terrestrial OM. Total nitrogen and TOC content in surface sediments collected throughout the lake are found to be highly correlated (r2 = 0.95), indicating a well-homogenized source of OM to the lake bottom. The recurring suspension and deposition of terrestrial sediment may account for significant amounts of OM deposited in offshore regions of the lake. This process effectively separates denser inorganic sediment from less dense OM and allows terrestrial OM to preferentially be transported farther offshore. The conclusion is that for the organic carbon content in these regions to be elevated a mixed terrestrial-lacustrine origin is required. The hydrodynamic separation of mineral and organic constituents is most pronounced in regions with shallow bathymetric gradients, consistent with previous findings from Lake Tanganyika.

Lake Malawi↗

Geology and petroleum potential of the Arctic Alaska petroleum province

The Arctic Alaska petroleum province encompasses all lands and adjacent continental shelf areas north of the Brooks Range–Herald Arch orogenic belt and south of the northern (outboard) margin of the Beaufort Rift shoulder. Even though only a small part is thoroughly explored, it is one of the most prolific petroleum provinces in North America with total known resources (cumulative production plus proved reserves) of c . 28 BBOE. The province constitutes a significant part of a displaced continental fragment, the Arctic Alaska microplate, that was probably rifted from the Canadian Arctic margin during formation of the Canada Basin. Petroleum prospective rocks in the province, mostly Mississippian and younger, record a sequential geological evolution through passive margin, rift and foreland basin tectonic stages. Significant petroleum source and reservoir rocks were formed during each tectonic stage but it was the foreland basin stage that provided the necessary burial heating to generate petroleum from the source rocks. The lion's share of known petroleum resources in the province occur in combination structural–stratigraphic traps formed as a consequence of rifting and located along the rift shoulder. Since the discovery of the super-giant Prudhoe Bay accumulation in one of these traps in the late 1960s, exploration activity preferentially focused on these types of traps. More recent activity, however, has emphasized the potential for stratigraphic traps and the prospect of a natural gas pipeline in this region has spurred renewed interest in structural traps. For assessment purposes, the province is divided into a Platform assessment unit (AU), comprising the Beaufort Rift shoulder and its relatively undeformed flanks, and a Fold-and-Thrust Belt AU, comprising the deformed area north of the Brooks Range and Herald Arch tectonic belt. Mean estimates of undiscovered, technically recoverable resources include nearly 28 billion barrels of oil (BBO) and 122 trillion cubic feet (TCF) of nonassociated gas in the Platform AU and 2 BBO and 59 TCF of nonassociated gas in the Fold-and-Thrust Belt AU.

Alaska↗

Field guide to hydrothermal alteration in the White River altered area and in the Osceola Mudflow, Washington

The Cenozoic Cascades arcs of southwestern Washington are the product of long-lived, but discontinuous, magmatism beginning in the Eocene and continuing to the present (for example, Christiansen and Yeats, 1992). This magmatism is the result of subduction of oceanic crust beneath the North American continent. The magmatic rocks are divided into two subparallel, north-trending continental-margin arcs, the Eocene to Pliocene Western Cascades, and the Quaternary High Cascades, which overlies, and is east of, the Western Cascades. Both arcs are calc-alkaline and are characterized by voluminous mafic lava flows (mostly basalt to basaltic andesite compositions) and scattered large stratovolcanoes of mafic andesite to dacite compositions. Silicic volcanism is relatively uncommon. Quartz diorite to granite plutons are exposed in more deeply eroded parts of the Western Cascades Arc (for example, Mount Rainier area and just north of Mt. St. Helens). Hydrothermal alteration is widespread in both Tertiary and Quaternary igneous rocks of the Cascades arcs. Most alteration in the Tertiary Western Cascades Arc resulted from hydrothermal systems associated with small plutons, some of which formed porphyry copper and related deposits, including copper-rich breccia pipes, polymetallic veins, and epithermal gold-silver deposits. Hydrothermal alteration also is present on many Quaternary stratovolcanoes of the High Cascades Arc. On some High Cascades volcanoes, this alteration resulted in severely weakened volcanic edifices that were susceptible to failure and catastrophic landslides. Most notable is the sector collapse of the northeast side of Mount Rainier that occurred about 5,600 yr. B.P. This collapse resulted in formation of the clay-rich Osceola Mudflow that traveled 120 km down valley from Mount Rainier to Puget Sound covering more than 200 km2. This field trip examines several styles and features of hydrothermal alteration related to Cenozoic magmatism in the Cascades arcs. The morning of the trip will examine the White River altered area, which includes high-level alteration related to a large, early Miocene magmatic-hydrothermal system exposed about 10 km east of Enumclaw, Washington. Here, vuggy silica alteration is being quarried for silica and advanced argillic alteration has been prospected for alunite. Clay-filled fractures and sulfide-rich, fine-grained sedimentary rocks of hydrothermal origin locally are enriched in precious metals. Many hydrothermal features common in high-sulfidation gold-silver deposits and in advanced argillic alteration zones overlying porphyry copper deposits (for example, Gustafson and Hunt, 1975; Hedenquist and others, 2000; Sillitoe, 2000) are exposed, although no economic base or precious metal mineralized rock has been discovered to date. The afternoon will be spent examining two exposures of the Osceola Mudflow along the White River. The Osceola Mudflow contains abundant clasts of altered Quaternary rocks from Mount Rainier that show various types of hydrothermal alteration and hydrothermal features. The mudflow matrix contains abundant hydrothermal clay minerals that added cohesiveness to the debris flow and helped allow it to travel much farther down valley than other, noncohesive debris flows from Mount Rainier (Crandell, 1971; Vallance and Scott, 1997). The White River altered area is the subject of ongoing studies by geoscientists from Weyerhaeuser Company and the U.S. Geological Survey (USGS). The generalized descriptions of the geology, geophysics, alteration, and mineralization presented here represent the preliminary results of this study (Ashley and others, 2003). Additional field, geochemical, geochronologic, and geophysical studies are underway. The Osceola Mudflow and other Holocene debris flows from Mount Rainier also are the subject of ongoing studies by the USGS (for example, Breit and others, 2003; John and others, 2003; Plumlee and others, 2003, Sisson and others, 2003; Vallance and others, 2003). Studies of hydrothermal alteration in the Osceola Mudflow are being used to better understand fossil hydrothermal systems on Mount Rainier and potential hazards associated with this alteration.

Washington↗

Mineral-resource assessments in Alaska; background information to accompany maps and reports about the geology and undiscovered-mineral-resource potential of the Mount Katmai Quadrangle and adjacent parts of the Naknek and Afognak quadrangles, Alaska Peninsula

Geologic and geochemical field studies were carded out from 1983 to 1987 in the Mount Katmai l?x2 ? quadrangle and adjoining region, at the northeast end of the Alaska Peninsula. The region is nearly entirely within Katmai National Park and Preserve and has had almost no mineral production, so prior to this study there were few data by which to assess the mineral potential of the region. This report describes the folio of publications that have resulted from the study: geologic maps, geochemical results, fossil identifications, radiometric rock ages, and an assessment of the undiscovered-mineral-resource potential of the region. The Katmai region is inferred to potentially have three types of undiscovered mineral deposits: porphyry copper (molybdenum), precious-metal vein, and hot-springs gold. These deposit types occur elsewhere on the Alaska Peninsula in similar geologic units. Evidence suggesting their occurrence in the Katmai region is the presence of trace amounts of metals typically associated with these kinds of deposits in bedrock of certain tracts and in sediments of streams draining those tracts. Magma to provide heat, fractures to provide pathways for mineralizing fluids, and altered rock are required by genetic models of these deposit types. Such features do occur in the Katmai tracts. Confirmation of any mineral deposit in the Katmai region requires detailed follow-up sampling and acquisition of subsurface information, which is beyond the scope of this study. However, producing porphyry deposits are unknown elsewhere on the Alaska Peninsula in similar rocks, so if any such deposits occur in the Katmai region, they are likely to be few in number. Conversely, vein deposits are typically small in size so there may be several of such deposits. The properties and thermal history of the sedimentary rocks that could serve as reservoirs for oil or gas are unfavorable in adjacent regions. Thus the potential of the Katmai region for producible quantities of fossil fuels is low. In theory the region has shallow concentrations of geothermal fluids, but specific evidence for their presence is obscured by heavy precipitation and cold young rocks or deposits. Small volumes of coal occur at tidewater sites on the Pacific coast.

Circular↗

Summary appraisals of the nation's ground-water resources – Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snowfall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55° to 118° F (-48.3° to 47.8° C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important freshwater aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock aquifers generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5x10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Freshwater could be stored in saline- or freshwater aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use, and pollution.

Minnesota, Montana, North Dakota, South Dakota↗

California State Waters Map Series — Offshore of Tomales Point, California

In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow (to about 200 m) subsurface geology. Tomales Bay, approximately 20-km long and 1- to 2-km wide, formed along a submerged portion of the San Andreas Fault, which forms a right-lateral transform boundary between the North American and Pacific tectonic plates. The fault juxtaposes Cretaceous granitic rock to the southwest (exposed on Tomales Point) with the Jurassic and Cretaceous Franciscan Complex to the northeast (exposed on the northeast coast of the Tomales Bay), and has an estimated slip rate of about 17 to 30 mm/yr in this area. The destructive great 1906 California earthquake (M7.8, 4/18/1906) is thought to have nucleated on the San Andreas Fault about 60 km to the south, offshore of San Francisco, with the rupture extending northward through Tomales Bay and for an additional about 230 km to the south flank of Cape Mendocino. The northwest coast of Tomales Point is characterized by steep, high (as much as 100 m), barren, granitic cliffs and a rugged shoreline with a few small pocket beaches. There has been as much as 48 m of Tomales Point cliff retreat from 1929–30 to 2002. The granite is overlain by less resistant Tertiary sandstones at Kehoe Beach, the northern end of a continuous, wide, sandy beach backed by a large coastal dune field that extends for about 20 km south to Point Reyes Head. This long beach has a mixed history of accretion and retreat since the late 1800s. Tomales Point relief is asymmetrical so that most small coastal watersheds in the map area drain eastward from Inverness Ridge into Tomales Bay. Many of these steep drainages have small sandy beaches at their mouths. The east coast of Tomales Bay is characterized by more gentle, hummocky, hilly relief underlain by the landslide-prone Franciscan Complex. Keys Creek, the most prominent small watershed entering Tomales Bay from the east, has a small subaqueous delta at its mouth. Central Tomales Bay is relatively flat and underlain by fine sand and silt. The mouth of Tomales Bay is characterized by sand waves, dunes, and flats that have formed in response to strong tidal flow. Sand Point and Dillon Beach are located at the mouth of Tomales Bay and on the southeasternmost shores of Bodega Bay, respectively. The wide beach in this area is backed by an extensive (4.8 km 2 ) sand-dune complex. The enormous volume of sand on the beach and in the dune field is derived from southward littoral drift. This sediment is trapped by Tomales Bay and Tomales Point, which function as the south end of the Bodega Bay littoral cell. The continental shelf in California’s State Waters in the Offshore of Tomales Point map area extends to water depths of about 70 m (mean slope of about 0.7°) and is characterized by extensive, rugged, rocky seafloor. Granitic seafloor has a massive and fractured texture, whereas seafloor sedimentary rock outcrops commonly form distinctive “ribs” created by differential seafloor erosion of dipping beds of variable resistance. Direct sediment supply to this shelf is minimal because littoral drift is blocked to the north by Tomales Bay and Tomales Point, and to the south by the Point Reyes headland. Circulation over the continental shelf in the map area (and in the broader northern California region) is dominated by the southward-flowing California Current, the eastern limb of the North Pacific Gyre. Associated upwelling brings cool, nutrient-rich waters to the surface, resulting in high biological productivity. The current flow generally is southeastward during the spring and summer; however, during the fall and winter, the otherwise persistent northwest winds are sometimes weak or absent, causing the California Current to move farther offshore and the Davidson Current, a weaker, northward-flowing countercurrent, to become active. As a result, net flow over the continental shelf can be more southerly during the spring and summer and more northerly during the fall and winter. Throughout the year, this part of the central California coast is exposed to four wave climate regimes—the north Pacific swell, the southern swell, northwest wind waves, and local wind waves. The north Pacific swell dominates in winter months (typically November through March), with wave heights at offshore buoys ranging from 2 to 10 m and wave periods ranging from 10 to 25 s. During summer months, the largest waves come from the southern swell, generated by storms in the south Pacific and offshore Central America. Characteristically, these swells have smaller wave heights (0.3 to 3 m) and similarly long periods (range 10 to 25 s). Northwest wind waves affect the coast throughout the year, while local wind waves are most common from October to April. These two wind-wave regimes typically have wave heights of 1 to 4 m and short periods (3 to 10 s). Potential marine benthic habitats in the Offshore of Tomales Point map area range from unconsolidated continental-shelf sediment, to rocky continental-shelf substrate, to unconsolidated estuary sediments. Rocky-shelf outcrops and rubble are considered to be promising potential habitats for rockfish and lingcod, both of which are recreationally and commercially important species. Dynamic bedforms, such as the sand waves at the mouth of Tomales Bay, are considered potential foraging habitat for juvenile lingcod and possibly migratory fishes, as well as for forage fish such as Pacific sand lance.

California↗

Stabilization of volcanic flanks by dike intrusion: An example from Kilauea

Dike propagation and dilation increases the compression of adjacent rocks. On volcanoes, especially oceanic shields, dikes are accordingly thought to be structurally destabilizing. As compression is incremented, volcanic flanks are driven outward or downslope and thus increase their susceptibility to destructive earthquakes and giant landslides. We show, however, that the 2-m-thick dike emplaced along the east rift zone of Kilauea in 1983 actually stabilized that volcano's flank. Specifically, production of flank earthquakes dropped more than twofold after 1983 as maximum downslope motion slowed to 6 cm ?? year-1 from approximately 40 cm ?? year-1 during 1980-1982. As much as 65 cm of deflationary subsidence above Kilauea's summit and upper rift zones accompanied the dike intrusion. According to recent estimates, this deflation corresponds to a reduction in magma-reservoir pressure of approximately 4 MPa, probably about as much as the driving pressure of the 1983 dike. The volume of the dike, approximately 0.10-0.15 km3, is orders of magnitude less than the estimated 200- to 250-km3 volume of Kilauea's reservoir of magma and nearby hot, mushy rock. Thus, deflation of that reservoir reduces the compressional load on the flank over a much larger area than intrusion of the dike adds to it, particularly at the dominant depth of seismicity, 8-9 km. A Coulomb block model for flank motion during intervals between major earthquakes requires the low-angle fault beneath Kilauea's flank to exhibit slip weakening, conducive to earthquake instability. Accordingly, the triggering mechanism of destructive earthquakes, several of which have struck Hawaii during the past 150 years, need not require stresses accumulated by dike intrusions.

Bulletin of Volcanology↗

Geologic time: The age of the Earth

The Earth is very old 4 1/2 billion years or more according to recent estimates. This vast span of time, called geologic time by earth scientists and believed by some to reach back to the birth of the Solar System, is difficult if not impossible to comprehend in the familiar time units of months and years, or even centuries. How then do scientists reckon geologic time, and why do they believe the Earth is so old? A great part of the secret of the Earth's age is locked up in its rocks, and man's centuries-old search for the key led to the beginning and nourished the growth of geologic science.

General Information Product↗

Hard rock uranium potential in Alaska

Discussing the potential of "hardrock" (i.e., non-sedimentary type) uranium deposits in a 586,000 mi 2 portion of the North America Cordillera is a difficult task compounded by the fact that the remoteness of much of the region and the logistical difficulties have resulted in only reconnaissance geologic information being available for large parts of the state. Cobb (1970) has listed known occurrences of uranium and thorium minerals in the state and a somewhat modified version of his compilation showing chiefly hardrock occurrences is given in figure 1; it should be emphasized that these are occurrences only and not necessarily deposits of possible economic significance. The distribution pattern shows a concentration of occurrences in southeastern Alaska and particularly in the interior. The only production of uranium in Alaska from any type of deposit has been from a hardrock deposit, that being the roughly 120,000 tons of ore averaging about one percent U 3 0 8 from the Ross-Adams mine near Bokan Mountain on Prince of Wales Island close to the southern tip of southeastern Alaska. The Bokan Mountain uranium-thorium area includes about 71 mi 2 and is largely underlain by plutonic rocks (MacKevett, 1963). The plutonic rocks range from pyroxenite to peralkaline granite and syenite, but they consist chiefly of diorite, quartz diorite, granodiorite, and quartz monzonite. The peralkaline granite, a small pluton about 3 mi2 in area, is Late Triassic or Early Jurassic in age while the other plutonic rocks are early Paleozoic.

Alaska↗

Geologic setting of the proposed West Flank Forge Site, California: Suitability for EGS research and development

The proposed West Flank FORGE site is within the China Lake Naval Air Weapons Station (NAWS), China Lake, CA. The West Flank is west of the Coso geothermal field, an area of China Lake NAWS dominated by the Quaternary Coso volcanic field largely comprised of rhyolite domes and their volcaniclastic and epiclastic horizons. The largest dome flow complex, Sugarloaf Mountain, marks the northwestern margin of the geothermal field. The West Flank is situated due west of Sugarloaf. The geologic setting of the West Flank was determined from one deep well (83-11) drilled as a potential production hole in 2009. The bottom-hole temperature (BHT) of well 83-11 approaches 600 oF (315˚C), but flow tests demonstrate very low, non-commercial permeabilities. With the exception of the upper 600 feet of volcaniclastic alluvium, well 83-11 is completed in granitic basement. The West Flank possesses the primary attributes of a FORGE site: non-commercial permeability ( <10 -16 m 2 ), a 175˚ to 225˚C temperature range in crystalline rocks, and a location outside an existing geothermal field The Coso Mountains host the Coso volcanic field and are within a right-releasing stepover between the dextral Airport Lake (ALF) and Little Lake fault zones (LLFZ) and the Wild Horse Mesa and Owens Valley faults. Two distinct fault populations have been identified at Coso: WNW-trending and antithetical, NE-trending strike-slip faults and N- to NNE-trending normal faults. These faults are both high permeability drilling targets at depth within the main (productive) geothermal field and they locally segment the field into distinct hydrothermal regimes. The West Flank may be segmented from the rest of the field by one such northerly trending fault. The overall minimum principal stress orientation in the main geothermal field varies from 103˚ to 108˚; however, the minimum horizontal principal stress in 83-11 is rotated to 081˚.

California↗

Geology and regional setting of the Al Masane ancient mine area, southeastern Arabian Shield, Kingdom of Saudi Arabia

Stratiform zinc-copper massive-sulfide deposits at Al Masane occur in thin dolomitic interbeds within Proterozoic felsic crystal tuff and mafic flows and volcaniclastics. These strata dip steeply westward and are underlain by shale and shaly graywacke to the east and overlain by lapilli crystal tuff to the west. This section is part of the Habawnah fold or mineral belt that extends from the Wadi Wassat area southward into Yemen. Western parts of the Habawnah fold belt, including the Al Masane area, are characterized by a bimodal assemblage of of phenocryst-poor basalts and sodic rhyolite crystal tuff, and by zinc-copper mineral deposits. Strata in the eastern part of the belt, mostly east of the Ashara fault zone, contain abundant phenocryst-rich mafic volcanic rocks, little felsic crystal tuff, and barren or locally nickeliferous massive pyrite deposits. Stratified rocks and gabbro sills of the Al Masane area were isoclinally folded and metamorphosed to the greenschist facies. Structural analysis indicates that foliation, lineation, joints, major and minor folds, and one of three sets of faults formed during a single east-west compressional deformational episode. Axial-plane foliation dips steeply westward and is usually coincident with bedding. Lineation plunges steeply to the northwest throughout the map area and is parallel to the intersection of joints of two major sets and to the intersection of these joints with foliation. Major folds have north-trending, gently plunging axes to which the axis of a minor fold set is essentially parallel. A second minor fold-set has a steeply plunging axis parallel to lineation. The Saadah massive-sulfide body is elongated by a fold of this system. Unmetamorphosed Proterozoic felsic sills, quartz monzonite and gabbro plutons, porphyritic diorite dikes, mafic dikes, and basalt dikes, in that apparent order, have intruded the stratified section. Basalt dikes are offset by southwestward-dipping reverse faults and by faults parallel to bedding. Malachite and metal-oxide-bearing gossans in the Al Masane area were mined in ancient times. Radiocarbon dating of charcoal in slag indicates that the ores were smelted about 1,200 years ago. Gossans are depleted in copper, silver, and zinc, relative to underlying sulfide, by factors of about 0.33, 0.2, and 0.08, respectively. Evaluation of numerous analyses of gossans, carbonates, and silicate rocks indicates that exploration for zinc-copper massive-sulfide deposits in the region should center on detailed geochemical studies of dolomitic beds. Dolomitization of host siliceous shales and tuffs and the formation of the massive-sulfide bodies at Al Masane probably caused by submarine fumarolic hydrothermal activity during periods of relative volcanic quiescence. Further work in the Al Masane region should include a study of the dolomitized areas and a search for other potential alteration "pipe" products (e.g. chlorite) as a guide to location of proximal deposits. Zinc-copper deposits at Al Masane and in the Dhahar-Al Hajrah and Kutam-Farah Garan areas have characteristics in common and are associated with felsic volcanic centers in the western bimodal part of the Habawnah mineral belt. They probably have parallel origins related to sea-floor volcanism. Deposits at Al Masane and Dhahar-Al Hajrah are possibly in the same general stratigraphic interval. Characteristics and distribution of altered rocks at Kutam suggest that the observed structural control of mineralization may represent remobilization. Chemical characteristics of volcanic rocks at Al Masane and elsewhere, along with features such as zinc-copper-iron sulfide mineralization, rhyolite-basalt bimodality, and the quartz phenocryst-rich nature of the felsic rocks, are compatible with an unusually primitive tholeiitic island-arc origin for the strata and mineral deposits of the Habawnah mineral belt.

Open-File Report↗

Isotopic variation in the Tuolumne Intrusive Suite, central Sierra Nevada, California

Granitoid rocks of the compositionally zoned Late Cretaceous Toulumne Intrusive Suite in the central Sierra Nevada, California, have initial87Sr/86Sr values (Sri) and143Nd/144Nd values (Ndi) that vary from 0.7057 to 0.7067 and from 0.51239 to 0.51211 respectively. The observed variation of both Sri and Ndi and of chemical composition in rocks of the suite cannot be due to crystal fractionation of magma solely under closed system conditons. The largest variation in chemistry, Ndi, and Sri is present in the outer-most equigranular units of the Tuolumne Intrusive Suite. Sri varies positively with SiO2, Na2O, K2O, and Rb concentrations, and negatively with Ndi, Al2O3, Fe2O3, MgO, FeO, CaO, MnO, P2O5, TiO2, and Sr concentrations. This covariation of Sri, Ndi and chemistry can be modeled by a process of simple mixing of basaltic and granitic magmas having weight percent SiO2 of 48.0 and 73.3 respectively. Isotopic characteristic of the mafic magma are Sri=0.7047, Ndi=0.51269 and ??18O=6.0, and of the felsic magma are Sri=0.7068, Ndi=0.51212 and ??18O=8.9. The rocks sampled contain from 50 to 80% of the felsic component. An aplite in the outer equigranular unit of the Tuolumne Intrusive Suite apparently was derived by fractional crystallization of plagioclase and hornblende from magma with granudiorite composition that was a product of mixing of the magmas described above. Siliceous magmas derived from the lower crust, having a maximum of 15 percent mantle-derived mafic component, are represented by the inner prophyritic units of the Tuolumne Intrusive Suite. ?? 1986 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

On the in situ aqueous alteration of soils on Mars

Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO4, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface. ?? 2008 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

Using saline or brackish aquifers as reservoirs for thermal energy storage, with example calculations for direct-use heating in the Portland Basin, Oregon, USA

Tools to evaluate reservoir thermal energy storage (RTES; heat storage in slow-moving or stagnant geochemically evolved permeable zones in strata that underlie well-connected regional aquifers) are developed and applied to the Columbia River Basalt Group (CRBG) beneath the Portland Basin, Oregon, USA. The performance of RTES for heat storage and recovery in the Portland Basin is strongly dependent on the operational schedule of heat injection and extraction. We examined the effects of the operational schedule, based on an annual solar hot water supply pattern and a building heating demand model, using heat and fluid flow simulations with SUTRA. We show RTES to be feasible for supply of heating energy for a large combined research/teaching building on the Oregon Health and Science University South Waterfront expansion, an area of planned future development. Initially, heat is consumed to increase the reservoir temperature, and conductive heat loss is high due to high temperature gradients between the reservoir and surrounding rock. Conductive heat loss continues into the future, but the rate of heat loss decreases, and heat recovery efficiency of the RTES system increases over time. Simulations demonstrate the effects of varying heat-delivery rate and temperature on the heat production history of the reservoir. If 100% of building heating needs are to be supplied by combined solar/RTES, then the solar system must be sized to meet building needs plus long-term thermal losses (i.e., conductive losses once the system is heated to pseudo-steady state) from the RTES system. If the solar heating system barely meets these criteria, then during early years, less than 100% of the building demand will be supplied until the reservoir is fully-heated. The duration of supplying less than 100% of building demand can be greatly shortened by pre-heating the reservoir before building heating operations or by adding extra heat from external sources during early years. Analytic solutions are developed to evaluate efficacy and to help design RTES systems (e.g., well-spacing, thermal source sizing, etc.). A map of thermal energy storage capacity is produced for the CRBG beneath the Portland Basin. The simulated building has an annual heat load of ∼1.9 GWh, and the total annual storage capacity of the Portland Basin is estimated to be 43,400 GWh assuming seasonal storage of heat yields water from which 10 °C can be extracted via heat exchange, indicating a tremendous heating capacity of the CRBG.

Oregon↗

Petrologic and experimental evidence for the etching of garnets by organic acids in the upper Jurassic Morrision Formation, northwestern New Mexico

The upper Jurassic Morrison Formation in the southern part of the San Juan Basin contains uniquely etched detrital garnets characterized by smooth, crystallographically controlled faceted surfaces. The etched garnets occur in relatively homogeneous Morrison sandstones in discrete stratigraphic zones that are bounded above and below by sandstones bearing unetched garnets. Diagenetic alterations associated with etched garnets include etched staurolite, skeletal plagioclase, regularly interstratified illite-smectite, iron-rich chlorite, ankerite, albite, diagenetically altered (organic-poor) uranium ore, and extensive secondary porosity. Etching of garnets and partial to complete dissolution of other aluminosilicate minerals were caused by high concentrations of organic acids generated during the maturation of epigenetic organic matter (predominantly type-III kerogen) in the Morrison Formation. The presence of authigenic phases that form near 100 degrees C indicates that temperatures were high enough during diagenesis to cause the thermal degradation of kerogen. The subsequent release of reactive organic acids promoted a variety of water-rock reactions. This hypothesis was corroborated by experiments in which dicarboxylic acid solutions created facets on garnets identical to those developed on naturally etched Morrison garnets. The excellent complexing ability of organic acid anions accounts for the characteristic lack of alteration products on etched surfaces.

Journal of Sedimentary Petrology↗

Assessment of the undiscovered oil and gas of the Senegal province, Mauritania, Senegal, the Gambia, and Guinea-Bissau, northwest Africa

Undiscovered, conventional oil and gas resources were assessed in the Senegal Province as part of the U.S. Geological Survey World Petroleum Assessment 2000 (U.S. Geological Survey World Energy Assessment Team, 2000). Although several total petroleum systems may exist in the province, only one composite total petroleum system, the Cretaceous-Tertiary Composite Total Petroleum System, was defined with one assessment unit, the Coastal Plain and Offshore Assessment Unit, having sufficient data to allow quantitative assessment. The primary source rocks for the Cretaceous-Tertiary Composite Total Petroleum System are the Cenomanian-Turonian marine shales. The Turonian shales can be as much as 150 meters thick and contain Type II organic carbon ranging from 3 to 10 weight percent. In the Senegal Province, source rocks are mature even when situated at depths relatively shallow for continental passive margin basins. Reservoir rocks consist of Upper Cretaceous sandstones and lower Tertiary clastic and carbonate rocks. The Lower Cretaceous platform carbonate rocks (sealed by Cenomanian shales) have porosities ranging from 10 to 23 percent. Oligocene carbonate rock reservoirs exist, such as the Dome Flore field, which contains as much as 1 billion barrels of heavy oil (10? API, 1.6 percent sulfur) in place. The traps are a combination of structural closures and stratigraphic pinch-outs. Hydrocarbon production in the Senegal Province to date has been limited to several small oil and gas fields around Cape Verde (also known as the Dakar Peninsula) from Upper Cretaceous sandstone reservoirs bounded by normal faults, of which three fields (two gas and one oil) exceed the minimum size assessed in this study (1 MMBO; 6 BCFG). Discovered known oil resources in the Senegal Province are 10 MMBO, with known gas resources of 49 BCFG (Petroconsultants, 1996). This study estimates that 10 percent of the total number of potential oil and gas fields (both discovered and undiscovered) of at least the minimum size have been discovered. The estimated mean size and number of assessed, undiscovered oil fields are 13 MMBO and 13 fields, respectively, whereas the mean size and number of undiscovered gas fields are estimated to be 50 BCFG and 11 fields. The mean estimates for undiscovered conventional petroleum resources are 157 MMBO, 856 BCFG, and 43 MMBNGL (table 2). The mean sizes of the largest anticipated undiscovered oil and gas fields are 66 MMBO and 208 BCFG, respectively. The Senegal Province is underexplored considering its large size. The province has hydrocarbon potential in both the offshore and onshore, and undiscovered gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Bulletin↗