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At least 775 records · Page 43Linked to original sources

Application of the FluEgg model to predict transport of Asian carp eggs in the Saint Joseph River (Great Lakes tributary)

The Fluvial Egg Drift Simulator (FluEgg) is a three-dimensional Lagrangian model that simulates the movement and development of Asian carp eggs until hatching based on the physical characteristics of the flow field and the physical and biological characteristics of the eggs. This tool provides information concerning egg development and spawning habitat suitability including: egg plume location, egg vertical and travel time distribution, and egg-hatching risk. A case study of the simulation of Asian carp eggs in the Lower Saint Joseph River, a tributary of Lake Michigan, is presented. The river hydrodynamic input for FluEgg was generated in two ways — using hydroacoustic data and using HEC-RAS model data. The HEC-RAS model hydrodynamic input data were used to simulate 52 scenarios covering a broad range of flows and water temperatures with the eggs at risk of hatching ranging from 0 to 93% depending on river conditions. FluEgg simulations depict the highest percentage of eggs at risk of hatching occurs at the lowest discharge and at peak water temperatures. Analysis of these scenarios illustrates how the interactive relation among river length, hydrodynamics, and water temperature influence egg transport and hatching risk. An improved version of FluEgg, which more realistically simulates dispersion and egg development, is presented. Also presented is a graphical user interface that facilitates the use of FluEgg and provides a set of post-processing analysis tools to support management decision-making regarding the prevention and control of Asian carp reproduction in rivers with or without Asian carp populations.

Michigan↗

The Great Lakes aquatic tissue analysis repository (GLATAR)

Empiricists and modellers use information on energy density, proximate composition, stable isotopes, fatty acids, thiamine, and bioaccumulative tracers (e.g., PCBs and mercury) to understand the state and inter-relationships of aquatic food webs. Data exist in many published and unpublished sources, but are not consolidated in an easily accessible database that would serve as a vital resource to i) provide basic estimates of these diet-derived measures of body composition, ii) understand sources of variation in the underlying data, iii) facilitate exploration and development of data proxies, and iv) assist in study design. We designed GLATAR (Great Lakes Aquatic Tissue Analysis Repository, glatar.org ) to address this need. GLATAR is an open-access, searchable database linked to a web-based toolbox to visualise and generate user-defined summaries on diet-derived ecological metrics, with a focus on taxa of importance to the Great Lakes. GLATAR currently contains over 50,000 records on energy density, chemical tracers, and proximate body composition from 67 species of fish and 72 invertebrate taxa. We hope this user-friendly interface will entice others to upload their published and unpublished data to the repository, enriching the breadth of data accessible to researchers. In this way, GLATAR will become a ‘living’ and interactive resource for empiricists and modellers working in freshwater ecosystems as they make critical decisions related to growth, production, and consumption across a diverse group of economically and ecologically important aquatic species.

Journal of Great Lakes Research↗

Alternative waste residue materials for passive in situ prevention of sulfide-mine tailings oxidation: A field evaluation

Novel solutions for sulfide-mine tailings remediation were evaluated in field-scale experiments on a former tailings repository in northern Sweden. Uncovered sulfide-tailings were compared to sewage-sludge biosolid amended tailings over 2 years. An application of a 0.2 m single-layer sewage-sludge amendment was unsuccessful at preventing oxygen ingress to underlying tailings. It merely slowed the sulfide-oxidation rate by 20%. In addition, sludge-derived metals (Cu, Ni, Fe, and Zn) migrated and precipitated at the tailings-to-sludge interface. By using an additional 0.6 m thick fly-ash sealing layer underlying the sewage sludge layer, a solution to mitigate oxygen transport to the underlying tailings and minimize sulfide-oxidation was found. The fly-ash acted as a hardened physical barrier that prevented oxygen diffusion and provided a trap for sludge-borne metals. Nevertheless, the biosolid application hampered the application, despite the advances in the effectiveness of the fly-ash layer, as sludge-borne nitrate leached through the cover system into the underlying tailings, oxidizing pyrite. This created a 0.3 m deep oxidized zone in 6-years. This study highlights that using sewage sludge in unconventional cover systems is not always a practical solution for the remediation of sulfide-bearing mine tailings to mitigate against sulfide weathering and acid rock drainage formation.

Skellefte�;Stockholm↗

A seepage meter designed for use in flowing water

Seepage meters provide one of the most direct means to measure exchange of water across the sediment-water interface, but they generally have been unsuitable for use in fluvial settings. Although the seepage bag can be placed inside a rigid container to minimize velocity head concerns, the seepage cylinder installed in the sediment bed projects into and disrupts the flow field, altering both the local-scale fluid exchange as well as measurement of that exchange. A low-profile seepage meter designed for use in moving water was tested in a seepage meter flux tank where both current velocity and seepage velocity could be controlled. The conical seepage cylinder protrudes only slightly above the sediment bed and is connected via tubing to a seepage bag or flowmeter positioned inside a rigid shelter that is located nearby where current velocity is much slower. Laboratory and field tests indicate that the net effect of the small protrusion of the seepage cylinder into the surface water flow field is inconsequentially small for surface water currents up to 65 cm s-1. Current velocity affects the variability of seepage measurements; seepage standard deviation increased from ???2 to ???6 cm d-1 as current velocity increased from 9 to 65 cm s-1. Substantial bias can result if the shelter is not placed to minimize hydraulic gradient between the bag and the seepage cylinder.

Journal of Hydrology↗

Subsurface transport of orthophosphate in five agricultural watersheds, USA

Concentrations of dissolved orthophosphate (ortho P) in the unsaturated zone, groundwater, tile drains, and groundwater/stream water interfaces were assessed in five agricultural watersheds to determine the potential for subsurface transport. Concentrations of iron oxides were measured in the aquifer material and adsorption of ortho P on oxide surfaces was assessed by geochemical modeling. Attenuation of ortho P in these aquifers was attributed primarily to sorption onto iron oxides, and in one location onto clay minerals. Only one location showed a clear indication of phosphorus transport to a stream from groundwater discharge, although groundwater did contribute to the stream load elsewhere. Subsurface ortho P movement at a site in California resulted in a plume down gradient from orchards, which was attenuated by a 200 m thick riparian zone with natural vegetation. Iron oxides had an effect on phosphorus movement and concentrations at all locations, and groundwater chemistry, especially pH, exerted a major control on the amount of phosphorus adsorbed. Groundwater pH at a site in Maryland was below 5 and that resulted in complete sequestration of phosphorus and no movement toward the stream. Geochemical modeling indicated that as the surfaces approached saturation, groundwater concentrations of ortho P rise rapidly.

Journal of Hydrology↗

Quantity and quality of groundwater discharge in a hypersaline lake environment

Geophysical and geochemical surveys were conducted to understand groundwater discharge to Great Salt Lake (GSL) and assess the potential significance of groundwater discharge as a source of selenium (Se). Continuous resistivity profiling (CRP) focusing below the sediment/water interface and fiber-optic distributed temperature sensing (FO-DTS) surveys were conducted along the south shore of GSL. FO-DTS surveys identified persistent cold-water temperature anomalies at 10 separate locations. Seepage measurements were conducted at 17 sites (mean seepage rate = 0.8 cm/day). High resistivity anomalies identified by the CRP survey were likely a mirabilite (Na 2 SO 4 ·10H 2 O) salt layer acting as a semi-confining layer for the shallow groundwater below the south shore of the lake. Positive seepage rates measured along the near-shore areas of GSL indicate that a ∼1-m thick oolitic sand overlying the mirabilite layer is likely acting as a shallow, unconfined aquifer. Using the average seepage rate of 0.8 cm/day over an area of 1.6 km 2 , an annual Se mass loading to GSL of 23.5 kg was estimated. Determination of R/Ra values (calculated 3 He/ 4 He ratio over the present-day atmospheric 3 He/ 4 He ratio) <1 and tritium activities of 1.2–2.0 tritium units in groundwater within and below the mirabilite layer indicates a convergence of regional and local groundwater flow paths discharging into GSL. Groundwater within and below the mirabilite layer obtains its high sulfate salinity from the dissolution of mirabilite. The δ 34 S and δ 18 O isotopic values in samples of dissolved sulfate from the shallow groundwater below the mirabilite are almost identical to the isotopic signature of the mirabilite core material. The saturation index calculated for groundwater samples using PHREEQC indicates the water is at equilibrium with mirabilite. Water samples collected from GSL immediately off shore contained Se concentrations that were 3–4 times higher than other sampling sites >25 km offshore from the study site and may be originating from less saline groundwater seeps mixing with the more saline water from GSL. Additional evidence for mixing with near shore seeps is found in the δD and δ 18 O isotopic values and Br:Cl ratios. Geochemical modeling for a water sample collected in the vicinity of the study area indicates that under chemically reducing conditions, arsenic- (As) bearing minerals could dissolve while Se-bearing minerals will likely precipitate out of solution, possibly explaining why the shallow groundwater below and within the mirabilite salt layer contains low concentrations of Se (0.9–2.3 μg/L).

Utah↗

Practical limitations on the use of diurnal temperature signals to quantify groundwater upwelling

Groundwater upwelling to streams creates unique habitat by influencing stream water quality and temperature; upwelling zones also serve as vectors for contamination when groundwater is degraded. Temperature time series data acquired along vertical profiles in the streambed have been applied to simple analytical models to determine rates of vertical fluid flux. These models are based on the downward propagation characteristics (amplitude attenuation and phase-lag) of the surface diurnal signal. Despite the popularity of these models, there are few published characterizations of moderate-to-strong upwelling. We attribute this limitation to the thermodynamics of upwelling, under which the downward conductive signal transport from the streambed interface occurs opposite the upward advective fluid flux. Governing equations describing the advection&ndash;diffusion of heat within the streambed predict that under upwelling conditions, signal amplitude attenuation will increase, but, counterintuitively, phase-lag will decrease. Therefore the extinction (measurable) depth of the diurnal signal is very shallow, but phase lag is also short, yielding low signal to noise ratio and poor model sensitivity. Conversely, amplitude attenuation over similar sensor spacing is strong, yielding greater potential model sensitivity. Here we present streambed thermal time series over a range of moderate to strong upwelling sites in the Quashnet River, Cape Cod, Massachusetts. The predicted inverse relationship between phase-lag and rate of upwelling was observed in the field data over a range of conditions, but the observed phase-lags were consistently shorter than predicted. Analytical solutions for fluid flux based on signal amplitude attenuation return results consistent with numerical models and physical seepage meters, but the phase-lag analytical model results are generally unreasonable. Through numerical modeling we explore reasons why phase-lag may have been over-predicted by the analytical models, and develop guiding relations of diurnal temperature signal extinction depth based on stream diurnal signal amplitude, upwelling magnitude, and streambed thermal properties that will be useful in designing future experiments.

Journal of Hydrology↗

Multi-scale preferential flow processes in an urban streambed under variable hydraulic conditions

Spatially preferential flow processes occur at nested scales at the sediment-water interface (SWI), due in part to sediment heterogeneities, which may be enhanced in flashy urban streams with heavy road sand influence. However, several factors, including the flow-rate dependence of preferential hyporheic flow and discrete groundwater discharge zones are commonly overlooked in reach-scale models of groundwater/surface water exchange. Using a series of controlled-head tracer-injection experiments coupled with cm-scale geophysics within the highly reactive upper 30 cm of the hyporheic zone of an urban stream, we quantified the flow dependence of local less-mobile porosity volume, mass-transfer rate coefficient, and the resulting local residence time in the less-mobile pore space at three controlled downward fluid fluxes (0.8, 2, and 3 m/d). Experiments were performed in two adjacent streambed locations, representing different sediment bulk vertical permeability. Less-mobile porosity parameters were generally substantial and similar between the two streambed locations; though a more competent, thin, organic layer at ∼15 cm depth in one location strongly impacted tracer loading, flushing dynamics, and local residence times. Increased downward flux led to (1) a decrease in less-mobile porosity residence time in all experiments, and (2) an increase in less-mobile porosity fraction for most experiments. Additionally, at the larger stream reach-scale, surface electrodes for electrical resistivity measurement were installed along 22 m of the wetted stream channel. These surface electrode measurements were collected during a natural storm flow event, which revealed widespread, short-term, flushing (e.g. <3 h) of the hyporheic zone with stream water, followed by longer-term (e.g. >60 h) flushing of the SWI with riparian zone groundwater. Flow dependence of preferential hyporheic zone flowpaths, like in the controlled tracer experiments, was also observed in these reach-scale electrical resistivity tomography measurements. Our findings reveal that the spatial and temporal dependence of preferential flow processes create highly dynamic SWI conditions that will affect the physical and coupled biogeochemical functions of the SWI in urbanized, sand-impacted streams.

Journal of Hydrology↗

Modeling the dynamic penetration depth of post-1950s water in unconfined aquifers using environmental tracers: Central Valley, California

The penetration depth of post-1950s recharge (D-1950) in aquifers is a marker that is frequently used to identify groundwater that is susceptible to anthropogenic contamination. Here, we compute D-1950 values at wells, interpolate them in space, and project them across time to map the moving front of modern recharge in four dimensions in the Central Valley aquifer system, California, USA. Tracers of groundwater age (tritium, carbon-14, noble gases, sulfur hexafluoride, and chlorofluorocarbons) were collected at 650 wells spatially distributed throughout the Central Valley and were fit to a lumped-parameter model that assumes a logarithmic age-depth profile in the aquifer. For samples where tritium was present (>0.3 tritium units), the model was used to predict D-1950 at wells screened above or across the modern-premodern interface (n = 484). Wells with samples where tritium was absent (≤0.3 tritium units) were used to define the depth beyond which groundwater is completely premodern (n = 166). Predicted D-1950 values were below the depth of screen bottoms for wells where groundwater is completely modern, and above the depth of screen tops for wells where groundwater is completely premodern. The interpolated surface of D-1950 is dynamic, less prone to extreme values, and produces maps with lower interpolation errors due to a higher spatial density of wells than maps based on the depth of premodern groundwater. Between 2005 and 2025, D-1950 is expected to deepen by 11 and 12 m in the northern and southern parts of the Central Valley, respectively. Areas where D-1950 increases rapidly are likely to see increases in nitrate and other anthropogenic contaminants associated with the downward moving front of modern water.

California↗

Incorporating temperature into seepage loss estimates for a large unlined irrigation canal

Quantifying seepage losses from unlined irrigation canals is necessary to improve water use and conservation. The use of heat as a tracer is widely used in quantifying seepage rates across the sediment–water interface. In this study, field observations and two-dimensional numerical models were used to simulate seepage losses during the 2018 and 2019 irrigation season in the Truckee Canal system. Nineteen transects were instrumented with temperature probes and stage recording devices for inverse modeling to derive seepage flux and volumetric losses over the 39 km length of canal. The numerical models for each transect were calibrated and validated using the two-year dataset. Soil zones and observation data were used in each numerical model to help guide calibration of vertical and lateral heat and fluid fluxes. Model simulations were used to derive multivariable regression equations that consider stage, temperature, and hydraulic gradient. The results demonstrate the value of long-term datasets that illustrate the seasonality of groundwater levels, siltation, stage, and temperature on seepage rates. Seepage rates estimated by the numerical models range from 0.16 to 4.6 m 3 /d m −1 . Total annual volumetric losses estimated for 2018 and 2019 were 1.6 × 10 -2 to 1.2 × 10 -2 km 3 , respectively. The seepage losses estimated by this study account for 32 % to 41 % of the inflow volumes. Regression models were able to reproduce seepage time-series simulated by the numerical models reasonably well. In arid environments, water diverted into irrigation canals may be influenced by seasonal variations in temperature sufficient to influence the water accounting of conveyed surface flows.

Nevada↗

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine↗

Impact of gas/liquid phase change of CO2 during injection for sequestration

CO 2 sequestration in deep saline formations is an effective and important process to control the rapid rise in CO 2 emissions. The process of injecting CO 2 requires reliable predictions of the stress in the formation and the fluid pressure distributions – particularly since monitoring of the CO 2 migration is difficult – to mitigate leakage, prevent induced seismicity, and analyze wellbore stability. A key aspect of CO 2 is the gas–liquid phase transition at the temperatures and pressures of relevance to leakage and sequestration, which has been recognized as being critical for accurate predictions but has been challenging to model without ad hoc empiricisms. This paper presents a robust multiphase thermodynamics-based poromechanics model to capture the complex phase transition behavior of CO 2 and predict the stress and pressure distribution under super- and sub- critical conditions during the injection process. A finite element implementation of the model is applied to analyze the behavior of a multiphase porous system with CO 2 as it displaces the fluid brine phase. We find that if CO 2 undergoes a phase transition in the geologic reservoir, the spatial variation of the density is significantly affected, and the migration mobility of CO 2 decreases in the reservoir. A key feature of our approach is that we do not a priori assume the location of the CO 2 gas/liquid interface – or even if it occurs at all – but rather, this is a prediction of the model, along with the spatial variation of the phase of CO 2 and the change of the saturation profile due to the phase change.

Journal of the Mechanics and Physics of Solids↗

Geodetic observations and modeling of magmatic inflation at the Three Sisters volcanic center, central Oregon Cascade Range, USA

Tumescence at the Three Sisters volcanic center began sometime between summer 1996 and summer 1998 and was discovered in April 2001 using interferometric synthetic aperture radar (InSAR). Swelling is centered about 5 km west of the summit of South Sister, a composite basaltic-andesite to rhyolite volcano that last erupted between 2200 and 2000 yr ago, and it affects an area &sim;20 km in diameter within the Three Sisters Wilderness. Yearly InSAR observations show that the average maximum displacement rate was 3&ndash;5 cm/yr through summer 2001, and the velocity of a continuous GPS station within the deforming area was essentially constant from June 2001 to June 2004. The background level of seismic activity has been low, suggesting that temperatures in the source region are high enough or the strain rate has been low enough to favor plastic deformation over brittle failure. A swarm of about 300 small earthquakes ( M max = 1.9) in the northeast quadrant of the deforming area on March 23&ndash;26, 2004, was the first notable seismicity in the area for at least two decades. The U.S. Geological Survey (USGS) established tilt-leveling and EDM networks at South Sister in 1985&ndash;1986, resurveyed them in 2001, the latter with GPS, and extended them to cover more of the deforming area. The 2001 tilt-leveling results are consistent with the inference drawn from InSAR that the current deformation episode did not start before 1996, i.e., the amount of deformation during 1995&ndash;2001 from InSAR fully accounts for the net tilt at South Sister during 1985&ndash;2001 from tilt-leveling. Subsequent InSAR, GPS, and leveling observations constrain the source location, geometry, and inflation rate as a function of time. A best-fit source model derived from simultaneous inversion of all three datasets is a dipping sill located 6.5 &plusmn; 2.5 km below the surface with a volume increase of 5.0 &times; 10 6 &plusmn; 1.5 &times; 10 6 m 3 /yr (95% confidence limits). The most likely cause of tumescence is a pulse of basaltic magma intruding the upper crust along the brittle&ndash;ductile interface &mdash; a process that must occur episodically beneath the Cascade Range but in the past would have escaped detection in the absence of unusual seismicity. We speculate that such intrusive episodes last from days to years and are separated by quiescent periods of decades to centuries. The likelihood that the current episode at Three Sisters will culminate in an eruption is judged to be low, but the impact of an eruption could be great. The USGS has updated its volcano hazards assessment for the Three Sisters region, notified appropriate agencies and the public, and is helping to prepare an emergency coordination and communication plan.

Central Oregon Cascade Range, Three Sisters volcan↗

Estimating proximity effects to wildfire fuels treatments on house prices in Cibola National Forest, New Mexico, USA

Forested landscapes in the Western United States are subject to growing size and severity of wildfires, in part due to historical management strategies focusing on wildfire suppression. Forest restoration treatments and fuels reductions, including thinning and prescribed burning, can reduce the frequency and intensity of wildfires. Extensive restoration and fuels treatment efforts are underway across many areas in the Southwestern United States, including New Mexico. The tradeoff between amenity values provided by forested landscapes and the wildfire risk associated with forested landscapes is becoming increasingly important to understand as development in the wildland-urban interface increases. Understanding how house proximity, relative to forest restoration or fuels treatments, is capitalized into home sale prices can provide useful information about how individuals value forested landscapes that have been altered to reduce wildfire risk or severity. We use a Hedonic Property Model to estimate the average treatment effect of proximity to forest restoration or fuel treatments in New Mexico, United States. We use matching methods to estimate the average treatment effect of proximity to forest restoration. We find that proximity to the forest has a positive amenity value; however, proximity to recent forest restoration or fuel treatments results in a decrease in house sale prices. We combine the results of our two models and calculate that homes not within one kilometer of a treated forest and within one kilometer of Cibola National Forest sell for an average $73,626 premium. The average premium drops to $22,996 for homes within one kilometer of a forest that has been recently treated and within one kilometer of Cibola National Forest.

New Mexico↗

Eddy correlation measurements of submarine groundwater discharge

This paper presents a new, non-invasive means of quantifying groundwater discharge into marine waters using an eddy correlation approach. The method takes advantage of the fact that, in virtually all aquatic environments, the dominant mode of vertical transport near the sediment–water interface is turbulent mixing. The technique thus relies on measuring simultaneously the fluctuating vertical velocity using an acoustic Doppler velocimeter and the fluctuating salinity and/or temperature using rapid-response conductivity and/or temperature sensors. The measurements are typically done at a height of 5–15 cm above the sediment surface, at a frequency of 16 to 64 Hz, and for a period of 15 to 60 min. If the groundwater salinity and/or temperature differ from that of the water column, the groundwater specific discharge (cm d− 1) can be quantified from either a heat or salt balance. Groundwater discharge was estimated with this new approach in Salt Pond, a small estuary on Cape Cod (MA, USA). Estimates agreed well with previous estimates of discharge measured using seepage meters and 222Rn as a tracer. The eddy correlation technique has several desirable characteristics: 1) discharge is quantified under in-situ hydrodynamic conditions; 2) salinity and temperature can serve as two semi-independent tracers of discharge; 3) discharge can be quantified at high temporal resolution, and 4) long-term records of discharge may be possible, due to the low power requirements of the instrumentation.

Massachussetts↗

Perspectives on chemical oceanography in the 21st century: Participants of the COME ABOARD Meeting examine aspects of the field in the context of 40 years of DISCO

The questions that chemical oceanographers prioritize over the coming decades, and the methods we use to address these questions, will define our field's contribution to 21st century science. In recognition of this, the U.S. National Science Foundation and National Oceanic and Atmospheric Administration galvanized a community effort (the Chemical Oceanography MEeting: A BOttom-up Approach to Research Directions, or COME ABOARD) to synthesize bottom-up perspectives on selected areas of research in Chemical Oceanography. Representing only a small subset of the community, COME ABOARD participants did not attempt to identify targeted research directions for the field. Instead, we focused on how best to foster diverse research in Chemical Oceanography, placing emphasis on the following themes: strengthening our core chemical skillset; expanding our tools through collaboration with chemists, engineers, and computer scientists; considering new roles for large programs; enhancing interface research through interdisciplinary collaboration; and expanding ocean literacy by engaging with the public. For each theme, COME ABOARD participants reflected on the present state of Chemical Oceanography, where the community hopes to go and why, and actionable pathways to get there. A unifying concept among the discussions was that dissimilar funding structures and metrics of success may be required to accommodate the various levels of readiness and stages of knowledge development found throughout our community. In addition to the science, participants of the concurrent Dissertations Symposium in Chemical Oceanography (DISCO) XXV, a meeting of recent and forthcoming Ph.D. graduates in Chemical Oceanography, provided perspectives on how our field could show leadership in addressing long-standing diversity and early-career challenges that are pervasive throughout science. Here we summarize the COME ABOARD Meeting discussions, providing a synthesis of reflections and perspectives on the field.

Marine Chemistry↗

The FOBIMO (FOraminiferal BIo-MOnitoring) initiative—Towards a standardised protocol for soft-bottom benthic foraminiferal monitoring studies

The European Community Marine Strategy Framework Directive (MSFD) was established to provide guidelines for monitoring the quality of marine ecosystems. Monitoring the status of marine environments is traditionally based on macrofauna surveys, for which standardised methods have been established. Benthic foraminifera are also good indicators of environmental status because of their fast turnover rates, high degree of specialisation, and the preservation of dead assemblages in the fossil record. In spite of the growing interest in foraminiferal bio-monitoring during the last decades, no standardised methodology has been proposed until today. The aim of the FOraminiferal BIo-MOnitoring (FOBIMO) expert workshop, held in June 2011 at Fribourg, Switzerland, which assembled 37 scientists from 24 research groups and 13 countries, was to develop a suite of standard methods. This paper presents the main outcome of the workshop, a list of motivated recommendations with respect to sampling devices, sample storage, treatment, faunal analysis and documentation. Our recommendations fulfil the criteria imposed both by scientific rigour and by the practical limitations of routine studies. Hence, our aim is to standardise methodologies used in bio-monitoring only and not to limit the use of different methods in pure scientific studies. Unless otherwise stated, all recommendations concern living (stained) benthic foraminiferal assemblages. We have chosen to propose two types of recommendations. Mandatory recommendations have to be followed if a study wants to qualify as sound and compatible to the norms. The most important of these recommendations are the interval from 0 to 1 cm below the sediment surface has to be sampled, and an interface corer or box corer that keeps the sediment surface intact is to be used for offshore surveys. A grab sampler must not be deployed in soft sediments. Three replicate samples are to be taken and analysed separately. Samples are to be washed on a 63-μm screen, and the living benthic foraminiferal fauna of the > 125 μm fraction is to be analysed. Splits are to be picked and counted entirely, and all counted foraminifera from at least one replicate per station have to be stored in micropalaeontological slides. Census data, supplementary laboratory data and microslides have to be archived. Advisory recommendations are to sample in autumn, to have a sample size of 50 cm 2 or a tube of 8 cm inner diameter, to use > 70% ethanol as a preservative, rose Bengal at a concentration of 2 grams per litre for staining, and a staining time of at least 14 days. The split size should be defined by a target value of 300 specimens, heavy liquid separation should be avoided, and the 63–125 μm fraction or deeper sediment levels may be considered in some environments. We are convinced that the application of this protocol by a large number of scientists is a necessary first step to a general acceptance of benthic foraminifera as a reliable tool in bio-monitoring studies.

Marine Micropaleontology↗

Benthic foraminifera from the Carnarvon Ramp reveal variability in Leeuwin Current activity (Western Australia) since the Pliocene

Benthic foraminiferal assemblages from a ~300 m deep core from an outer carbonate-ramp site off Western Australia (International Ocean Discovery Program Core U1460A) were examined to reconstruct the paleoceanographic evolution of the Carnarvon Ramp and the warm surficial Leeuwin Current (LC) for the last 3.54 Ma. Of the identified 179 benthic foraminiferal species, occurrences of the 15 most abundant taxa were assessed using Q-mode Cluster Analysis and Non-Metric Dimensional Scaling. Diversity, equitability, planktonic/benthic index, microhabitat preference, and sedimentary parameters such as lithology and sponge spicule content were analyzed to gather information about past intermediate- and surface-water circulation. Relative abundances of infaunal and epifaunal species were applied to indicate changes in organic-matter supply and oxygenation at the sea floor. Influence of upwelling was recognized by a high infaunal species ratio, with dominance by Uvigerina peregrina , Lagena annellatrachia and Trifarina bradyi . Epifaunal species such as Hanzawaia nipponica and Hyalinea florenceae gradually became more abundant around 1.14 Ma, indicating increased ventilation and establishment of the paleo-LC. A more substantial change was initiated by 0.91 Ma as marked by key species Spirorutilus carinatus and Rotorbinella sp. , together with increased faunal diversity, benthic foraminiferal accumulation rates, and evidence for suspension feeding sponges. With the LC flow suppressing upwelling, and better ventilated waters entering the shelf, the environment favored epifaunal agglutinates, rotalids, and miliolids, while buliminids decreased. Under high-flow conditions of the LC, sponge spicules and skeletal carbonate production reached an optimum at ~0.6 Ma before returning to modern conditions. Supported by these observations, we propose the following paleoceanographic evolution of the Carnarvon Ramp: During the late Pliocene to mid Pleistocene (3.54–0.91 Ma) conditions of deep-water upwelling from the Western Australian Current and Indian Ocean Gyre indicate the absence of the capping LC on the outer carbonate ramp. A transitional phase started in the mid Pleistocene (1.14–0.61 Ma). The paleo-LC triggered gradual oxygenation at the sediment-water interface, which coincided with an increase in carbonate sedimentation rates, and waning sea-surface productivity. During a third phase, mid Pleistocene to present (0.91–0 Ma), the LC’s intensity and flow rates peaked at ~0.6 Ma. Benthic foraminiferal accumulation rates reached a high, then decreased to present-day rates. For short periods, sea-surface productivity was moderately enhanced, likely due to fluctuating LC persistence or landward shift during glacial maxima.

Western Australia↗