Results for “Trace Elements Investigations” — Page 42

USGS2003

Trace elements and synthetic organic compounds in streambed sediment and fish tissue in the Great and Little Miami River basins, Ohio and Indiana, 1990-98

Streambed-sediment and fish-tissue samples were collected at eight sites in the Great and Little Miami Basins as part of the U.S. Geological Survey's National Water Quality Assessment Program. The samples were analyzed for trace elements and synthetic organic compounds, including organochlorine insecticides, polychlorinated biphenyls (PCBs), and semivolatile compounds (SVOCs). Data from state-agency investigations within the study unit (more than 200 sites) were incorporated to gain a broader perspective of the occurrence and distribution of contaminants in the study unit. All data were compared to streambed-sediment-quality guidelines and fish-tissue guidelines to identify elevated contaminant concentrations. Guideline exceedances were plotted on distribution maps to identify areas in the study unit that may be of potential concern for wildlife health. Several trace elements were detected in both sediment and fish-tissue samples. In sediment, lead and zinc were most frequently detected at levels that may have adverse effects on aquatic organisms. Generally, only one of the trace elements analyzed for per site exceeded concentrations above which adverse biological effects are frequently anticipated. Organochlorine insecticides were infrequently detected in sediment or fish tissue throughout the study unit. More organochlorine insecticides were detected in fish tissues than in sediment; however, more guidelines were exceeded in sediment. No distinct geographic overlap between sediment and fish-tissue sites was evident with respect to elevated organochlorine insecticide concentrations. Sediment-quality guideline exceedances were generally widespread throughout the study unit, whereas fish-tissue guidelines were exceeded only on the Mad River. PCBs were detected more often in fish tissue than in sediment throughout the study unit. Elevated PCB concentrations in fish tissue were common and widespread. No distinct geographic overlap of PCB exceedances was evident between sediment and fish-tissue sites. In sediments, elevated concentrations were detected most often for SVOCs, particularly for polycyclic aromatic hydrocarbons (PAHs). Areas where SVOC guidelines were frequently exceeded include the Great Miami River main stem from Dayton to south of Hamilton, and the Upper Little Miami River Basin in Greene County. Overall, a higher frequency of trace-element detections in fish tissue and sediment trace-element guideline exceedances was found in the Great Miami River Basin than in the Little Miami River Basin. Organochlorine insecticide guidelines for fish tissue and sediment, as well as PCB and SVOC guidelines for sediment also were exceeded more frequently in the Great Miami River Basin. PCB guideline exceedances for fish tissue were found more often in the Little Miami River Basin.

Water-Resources Investigations Report↗

USGS2014

Updated study reporting levels (SRLs) for trace-element data collected for the California Groundwater Ambient Monitoring and Assessment (GAMA) Priority Basin Project, October 2009-March 2013

Groundwater samples have been collected in California as part of statewide investigations of groundwater quality conducted by the U.S. Geological Survey for the Groundwater Ambient Monitoring and Assessment (GAMA) Priority Basin Project (PBP). The GAMA-PBP is being conducted in cooperation with the California State Water Resources Control Board to assess and monitor the quality of groundwater resources used for drinking-water supply and to improve public knowledge of groundwater quality in California. Quality-control samples (source-solution blanks, equipment blanks, and field blanks) were collected in order to ensure the quality of the groundwater sample results. Olsen and others (2010) previously determined study reporting levels (SRLs) for trace-element results based primarily on field blanks collected in California from May 2004 through January 2008. SRLs are raised reporting levels used to reduce the likelihood of reporting false detections attributable to contamination bias. The purpose of this report is to identify any changes in the frequency and concentrations of detections in field blanks since the last evaluation and update the SRLs for more recent data accordingly. Constituents analyzed were aluminum (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), boron (B), cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), lithium (Li), manganese (Mn), molybdenum (Mo), nickel (Ni), selenium (Se), silver (Ag), strontium (Sr), thallium (Tl), tungsten (W), uranium (U), vanadium (V), and zinc (Zn). Data from 179 field blanks and equipment blanks collected from March 2006 through March 2013 by the GAMA-PBP indicated that for trace elements that had a change in detection frequency and concentration since the previous review, the shift occurred near October 2009, in conjunction with a change in the capsule filters used by the study. Results for 89 field blanks and equipment blanks collected from October 2009 through March 2013 were evaluated for potential contamination bias by using the same approach developed by Olsen and others (2010). Some data collected by the National Water-Quality Assessment (NAWQA) Program for the Southern California Coastal Drainages study unit were included to supplement the GAMA-PBP data. The detection frequency and upper threshold of potential contamination bias (BD-90/90) were determined from field-blank and equipment-blank data for each trace element. The BD-90/90 is the 90th percentile concentration of potential extrinsic contamination calculated by using the binomial probability distribution for greater than 90 percent confidence. Additionally, data from laboratory blanks and blind blanks analyzed by the National Water Quality Laboratory (NWQL) during water years 2010 through 2013, and compiled by the USGS Branch of Quality Systems (BQS), were considered for each trace element. These results were compared to each constituent’s reporting level to determine whether an SRL was necessary to minimize the potential for detections in the groundwater samples, attributed principally to contamination bias. Results of the evaluation were used to set SRLs for trace-element data for about 1,135 samples of groundwater collected by the GAMA-PBP between October 2009 and March 2013. Ten trace elements analyzed (Sb, As, Be, B, Cd, Li, Se, Ag, Tl, and U) had blank results that did not necessitate establishing SRLs during this review or the review by Olsen and others (2010). Five trace elements analyzed (Al, Ba, Cr, Sr, and V) had blank results that necessitated establishing an SRL during the previous review but did not need an SRL starting October 2009. One trace element (Fe) had field and laboratory-blank results that necessitated keeping the previous SRL (6 micrograms per liter [μg/L]). Two trace elements (Ni and W) had quality-control results that warranted decreasing the previous SRL, and five trace elements (Cu, Pb, Mn, Mo, and Zn) had field, laboratory, or blind blank results that warranted establishing an SRL for the first time or increasing the previous SRL. SRLs for Cu (2.1 μg/L), Pb (0.82 μg/L), Mn (0.66 μg/L), Mo (0.023 μg/L), Ni (0.21 μg/L), W (0.023 μg/L), and Zn (6.2 μg/L) were changed to these levels starting October 2009, based on the BD-90/90 concentration for field blanks or the 99th percentile concentration for laboratory or blind blanks. The SRL for Fe was maintained at 6 μg/L, based on the minimum laboratory reporting level for iron. SRLs for these eight constituents were at least an order of magnitude below the regulatory benchmarks established for drinking water for health and aesthetic purposes; therefore, the practice of reporting concentrations below the SRLs as less than or equal to (≤) the measured value would not prevent the identification of values greater than the drinking-water benchmarks. Co was detected in 99 percent of field blanks, and with a BD-90/90 concentration of 0.38 μg/L, all groundwater results starting October 2009 were coded as “reviewed and rejected.” Co does not currently have a regulatory benchmark for drinking water. The primary sources of contamination for trace elements inferred from this review are the equipment or processes used in the field to collect the samples or in the laboratory. In particular, contamination in field blanks of Co and Mn was attributed to the high-capacity 0.45-micrometer pore-size capsule filters that were in regular use beginning in October 2009 by several USGS programs, including the GAMA-PBP and NAWQA Program, for filtering samples for analysis of trace elements. The SRLs determined in this report are intended to be used for GAMA groundwater-quality data for samples collected October 2009 through March 2013, or for as long as quality-control data indicate contamination similar to what was observed in this report; quality-control data should be continuously reviewed and SRLs re-assessed on at least a study-unit basis.

California↗

USGS2005

Petrogenesis of the Apollo 14 high-alumina basalts: Implications from ion microprobe analyses

In this study, ion microprobe analyses of individual minerals are used to investigate the petrogenesis of the Apollo 14 high-Al basalts. We use trace element concentrations from individual minerals in the Apollo 14 high-Al basalts to evaluate both endogenic and exogenic models. The data show that if the Apollo 14 high-Al basalts were produced by melting within the lunar mantle, these basalts cannot be related to one another by closed-system fractional crystallization of a single basaltic melt. Rather, the trace element data show that variable amounts of a KREEP component were added to the basalts by either assimilation, mixing into mantle sources, or impact melting. Single-stage assimilation–fractional crystallization models can only explain the data from this study if an excessively large mass of urKREEP is assimilated into the parent magma before olivine crystallization. Alternatively, the trace element data can be explained if the Apollo 14 high-Al basalts were produced by melting multiple Al-rich mantle sources that contain different amounts of urKREEP. Finally, for impact melting to be a relevant process, the data require that multiple large impact melts be formed from mixed KREEP-rich target lithologies. The resulting impact melts must then crystallize to produce basalts with igneous textures, high Al 2 O 3 concentrations, uniform major element compositions, and a wide range of incompatible trace element concentrations.

Geochimica et Cosmochimica Acta↗

USGS1983

SUBMICROSCOPIC ( less than 1 mu m) MINERAL CONTENTS OF VITRINITES IN SELECTED BITUMINOUS COAL BEDS.

An important aspect of the petrographic description of coal is the characterization of coal quality, including chemical attributes. For geologic investigations, data on the concentrations, distribution, and modes of occurrence of minor and trace elements provide a basis for reconstructing the probable geochemical environment of the swamp material that was converted into peat, and the geochemical conditions that prevailed during and subsequent to coalification. We have been using electron (EPMA) and proton (PIXE) microprobe analytical methods to obtain data on the chemical characteristics of specific coal constituents in their original associations within coal samples. The present study is aimed at evaluation of the nature of mineral occurrences and heterogeneous elemental concentrations within vitrinites. Vitrinites are usually the most abundant, and therefore most important, maceral group in bituminous coal. 8 refs.

Conference Paper↗

USGS1985

Chemical quality of ground water in Yolo and Solano counties, California

Ground-water-quality conditions were investigated in Yolo and Solano Counties during the summers of 1980 and 1981 by sampling 188 representative wells. Chemical analyses of the water samples show that the ground water is suitable for domestic and most agricultural purposes. Water samples from wells near the Sacramento River generally contained lower concentrations of dissolved solids and higher concentrations of trace elements than the rest of the study area. Ninety percent of the water sampled had a dissolved-solids concentration of less than 850 milligrams per liter. Chemical water types varied, with 72 percent of the wells sampled containing either sodium bicarbonate, magnesium bicarbonate, sodium-magnesium bicarbonate , or magnesium-sodium bicarbonate type water. A large part of the study area contains ground water with boron concentrations that exceed tolerance levels for many crops. Other toxic trace elements were present in negligible amounts. (USGS)

Water-Resources Investigations Report↗

USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Organic compounds and trace elements in bed sediment and fish tissue, 1992-93

The occurrence and distribution of contaminants in aquatic systems are major components of the National Water-Quality Assessment (NAWQA) Program. Bed-sediment samples were collected at 18 sites in the Rio Grande Valley study unit between September 1992 and March 1993 to characterize the geographic distribution of organic compounds, including chlorinated insecticides, polychlorinated biphenyls (PCB's), and other chlorinated hydrocarbons, and also trace elements. Two-millimeter-size- fraction sediment was analyzed for organic compounds and less than 63-micron-size-fraction sediment was analyzed for trace elements. Concentrations of p,p'-DDE were detected in 33 percent of the bed-sediment samples. With the exception of DDT-related compounds, no other organochlorine insecticides or polychlorinated biphenyls were detected in samples of bed sediment. Whole-body fish samples were collected at 11 of the bed- sediment sites and analyzed for organic compounds. Organic compounds were reported more frequently in samples of fish, and more types of organic compounds were found in whole-body fish samples than in bed-sediment samples. Concentrations of p,p'-DDE were detected in 91 percent of whole-body fish samples. Polychlorinated biphenyls, cis-chlordane, trans-chlordane, trans- nonachlor, and hexachlorobenzene were other organic compounds detected in whole-body samples of fish from at least one site. Because of the extent of mineralized areas in the Rio Grande Basin arsenic, cadmium, copper, lead, mercury, selenium, and zinc concentrations in bed-sediment samples could represent natural conditions at most sites. However, a combination of natural conditions and human activities appears to be associated with elevated trace-element concentrations in the bed-sediment sample from the site Rio Grande near Creede, Colorado, because this sample exceeded the background trace-element concentrations calculated for this study. Fish-liver samples were collected at 12 of the bed-sediment sites and analyzed for trace elements. Certain trace elements were detected at higher concentrations in fish-liver samples than in bed-sediment samples from the same site. Both bed-sediment and fish-tissue samples are necessary for a complete environmental assessment of the occurrence and distribution of trace elements.

Colorado, New Mexico, Texas↗

USGS2021

Eocene magma plumbing system beneath Cortez Hills Carlin-type gold deposit, Nevada: Is there a deep-seated pluton?

The magmatic-hydrothermal conceptual model for Carlin-type gold deposit genesis calls upon deep-seated Eocene plutons as the primary source of gold-bearing fluids. However, geophysical surveys, geologic mapping, drilling, geochronology, isotopic tracers, and fluid inclusion chemistry have returned ambiguous evidence for the existence of such plutons. The high-grade Cortez Hills gold deposit in northern Nevada hosts shallow, Eocene syn- and postmineralization intrusions, offering an ideal site to investigate the existence of a deep-seated pluton beneath the district. Here, major and trace element analyses of quartz-hosted melt inclusions from four Eocene rhyolite dikes cropping out within the Cortez Hills pit and results from independent thermobarometers provide a window into the subsurface Eocene magmatic plumbing system to test the existence of a deep-seated source pluton. Dissolved volatile contents, melt inclusion entrapment pressures, and thermodynamic phase equilibria indicate that dike magmas were sourced from ~4- to ≥9-km depth from a polybaric magma reservoir residing as a physically and geochemically interconnected crystal mush with extractable or eruptible magma pockets. Magmas ascended adiabatically (nearly isothermally), exsolving fluids, evolving modestly by fractional crystallization, while trapping quartz-hosted melt inclusions steadily from depth to subvolcanic levels where they were emplaced. These data represent the first unequivocal evidence for a deep-seated magma reservoir from which fluid-saturated magma emanated and released magmatic fluids beneath the Cortez district during gold mineralization. However, further investigation into the specific metallogenic potential and metal budget of parental magmas and the partitioning of gold between silicate melt and aqueous fluids will be necessary to provide evidence that exsolved magmatic fluids may have been gold bearing.

Nevada↗

USGS2020

Updated study reporting levels (SRLs) for trace-element data collected for the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project, October 2009–October 2018

Groundwater samples have been collected in California as part of statewide investigations of groundwater quality conducted by the U.S. Geological Survey for the Groundwater Ambient Monitoring and Assessment (GAMA) Priority Basin Project (PBP) since 2004. The GAMA-PBP is being conducted in cooperation with the California State Water Resources Control Board to assess and monitor the quality of groundwater resources used for public and domestic drinking-water supply and to improve public knowledge of groundwater quality in California. Quality-control samples (including but not limited to field, equipment, and source-solution blanks) were collected to evaluate and quantify the quality of the groundwater sample results. The GAMA-PBP previously determined study reporting levels (SRLs) for trace-element results based primarily on field blanks collected in California from May 2004 through March 2013. SRLs are raised reporting levels used to reduce the likelihood of reporting false detections attributable to contamination bias. The purpose of this report is to identify any changes in the pattern or magnitude of concentrations or detections in field blanks since the last evaluation that would require changing or ending the use of SRLs implemented in October 2009. Constituents analyzed were aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, chromium, hexavalent chromium, cobalt, copper, iron, lead, lithium, manganese, molybdenum, nickel, selenium, silver, strontium, thallium, uranium, vanadium, and zinc. For this review, data from 167 field blanks collected from October 2009 through October 2018 by the GAMA-PBP for trace elements were compiled. Based on a consistent pattern of decreasing cobalt and manganese concentrations in field blanks from 2009 to 2013, the GAMA-PBP decided to reevaluate all trace-element SRLs, effectively setting an end date for previously defined SRLs. Beginning October 2013, SRLs would be determined from field-blank data collected through October 2018. The detection frequency and upper limit of potential contamination bias (BD-90/90) were determined from field blanks for each trace element. The BD-90/90, that is, the upper 90-percent confidence limit of the 90th percentile concentration of potential extrinsic contamination, was calculated by assuming the binomial probability distribution. These results were compared to each constituent’s detection limit to determine whether an SRL was necessary to minimize the potential for detections in the groundwater samples, attributed principally to contamination bias. Results of the evaluation were used to set SRLs for trace-element data collected by the GAMA-PBP between October 2013 and October 2018. Trace elements prescribed an SRL based on this review were hexavalent chromium, cobalt, copper, lead, and zinc. This review also resulted in the removal of SRLs from iron, manganese, molybdenum, and nickel. Although an SRL for hexavalent chromium could not be evaluated in the earlier reviews because the data were not collected regularly until 2015, one was established herein as 0.34 micrograms per liter (µg/L). The SRL for cobalt, as previously implemented, had been to reject all results; it was changed to 0.16 µg/L following a reduction in cobalt field-blank detection frequency resulting from mitigation steps, starting in 2014, aimed at reducing contamination bias introduced by high-capacity capsule filters used during sample collection. The SRL for copper did not change, and the SRL for lead changed very little based on this review. Lastly, the SRL for zinc was lowered from 6.2 µg/L to 3.9 µg/L.

California↗

USGS2017

Depositional environment and organic matter accumulation of Upper Ordovician–Lower Silurian marine shale in the Upper Yangtze Platform, South China

The main controlling factors of organic matter accumulation in the Upper Ordovician Wufeng–Lower Silurian Longmaxi Formations are complex and remain highly controversial. This study investigates the vertical variation of total organic carbon (TOC) content as well as major and trace element concentrations of four Ordovician–Silurian transition sections from the Upper Yangtze Platform of South China to reconstruct the paleoenvironment of these deposits and to improve our understanding of those factors that have influenced organic matter accumulation in these deposits. The residual TOC content of the Wufeng Formation averages 3.2% and ranges from 0.12 to 6.0%. The overlying lower Longmaxi Formation displays higher TOC content (avg. 4.4%), followed upsection by consistent and lower values that average 1.6% in the upper Longmaxi Formation. The concentration and covariation of redox-sensitive trace elements (Mo, U and V) suggest that organic-rich intervals of the Wufeng Formation accumulated under predominantly anoxic conditions. Organic-rich horizons of the lower Longmaxi Formation were deposited under strongly anoxic to euxinic conditions, whereas organic-poor intervals of the upper Longmaxi Formation accumulated under suboxic conditions. Positive correlations between redox proxies and TOC contents suggest that organic matter accumulation was predominantly controlled by preservation. Barium excess (Ba xs ) values indicate high paleoproductivity throughout the entire depositional sequence, with an increase in the lower Longmaxi Formation. Increased productivity may have been induced by enhanced P recycling, as evidenced by elevated C org /P tot ratios. Mo–U covariation and Mo/TOC values reveal that the Wufeng Formation was deposited under extremely restricted conditions, whereas the Longmaxi Formation accumulated under moderately restricted conditions. During the Late Ordovician, the extremely restricted nature of ocean circulation on the Upper Yangtze Platform in tandem with enhanced stratification of the water column promoted anoxic conditions favorable for the preservation of organic matter. During Early Silurian time, organic matter accumulation was principally controlled by changes in sea level, which affected terrigenous flux, redox conditions, and the degree of nutrition recycling.

Upper Yangtze Platform↗

USGS1987

Ground-water-quality assessment of the Delmarva Peninsula, Delaware, Maryland, and Virginia; project description

In April 1986, the U.S. Geological Survey began a pilot program to assess the quality of the Nation 's surface water and groundwater resources. This National Water-Quality Assessment (NAWQA) program is designed to acquire and interpret information about a wide range of water quality issues. Three groundwater pilot projects have been started, including the project on the Delmarva Peninsula, which covers eastern Maryland and Virginia and most of Delaware. The objectives of the Delmarva project are to: (1) investigate regional groundwater quality on the Delmarva Peninsula, emphasizing a description of the occurrence of trace elements and manmade organic compounds; (2) relate groundwater quality to land use and geohydrologic conditions; and (3) provide a general description of the location, nature, and possible causes of selected water quality problems prevalent in the study area. The shallow aquifer system and the deeper aquifers used for public water supply will be addressed. The shallow aquifer system in the Delmarva Peninsula consists of permeable unconsolidated sand and gravel. Flow systems are localized and small-scale. Farming is common on the peninsula, and the migration of agricultural chemicals to the groundwater system is a local water quality concern. To assess the water quality of the groundwater resources, a regional survey for a wide range of constituents will be conducted in all of the pilot projects to provide a representative sample of groundwater analyses for a national assessment of groundwater quality. Results of this survey may be used as a baseline to monitor future water quality trends. (Lantz-PTT)

Open-File Report↗

USGS2023

A novel non-destructive workflow for examining germanium and co-substituents in ZnS

A suite of complementary techniques was used to examine germanium (Ge), a byproduct critical element, and co-substituent trace elements in ZnS and mine wastes from four mineral districts where germanium is, or has been, produced within the United States. This contribution establishes a comprehensive workflow for characterizing Ge and other trace elements, which captures the full heterogeneity of samples through extensive pre-characterization. This process proceeded from optical microscopy, to scanning electron microscopy and cathodoluminescence (CL) imaging, to electron microprobe analysis, prior to synchrotron-based investigations. Utilizing non-destructive techniques enabled reanalysis, which proved essential for verifying observations and validating unexpected results. In cases where the Fe content was <0.3 wt% in ZnS, cathodoluminescence imaging proved to be an efficient means to qualitatively identify trace element zonation that could then be further explored by other micro-focused techniques. Micro-focused X-ray diffraction was used to map the distribution of the non-cubic ZnS polymorph, whereas micro-focused X-ray fluorescence (μ-XRF) phase mapping distinguished between Ge 4+ hosted in primary ZnS and a weathering product, hemimorphite [Zn 4 Si 2 O 7 (OH) 2 ·H 2 O]. Microprobe data and μ-XRF maps identified spatial relationships among trace elements in ZnS and implied substitutional mechanisms, which were further explored using Ge and copper (Cu) X-ray absorption near-edge spectroscopy (XANES). Both oxidation states of Ge (4+ and 2+) were identified in ZnS along with, almost exclusively, monovalent Cu. However, the relative abundance of Ge oxidation states varied among mineral districts and, sometimes, within samples. Further, bulk XANES measurements typically agreed with micro-focused XANES (μ-XANES) spectra, but unique micro-environments were detected, highlighting the importance of complementary bulk and micro-focused measurements. Some Ge μ-XANES utilized a high energy resolution fluorescence detector, which improved spectral resolution and spectral signal-to-noise ratio. This detector opens new opportunities for exploring byproduct critical elements in complex matrices. Overall, the non-destructive workflow employed here can be extended to other byproduct critical elements to more fully understand fundamental ore enrichment processes, which have practical implications for critical element exploration, resource quantification, and extraction.

Frontiers in Earth Science↗

USGS2008

Sedimentation and occurrence and trends of selected nutrients, other chemical constituents, and diatoms in bottom sediment, Fall River Lake, southeast Kansas, 1948-2006

A combination of available bathymetric-survey information and bottom-sediment coring was used to investigate sedimentation and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, diatoms, and the radionuclide cesium-137 in the bottom sediment of Fall River Lake, southeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1948 through 2006 in the original conservation pool of the reservoir was 470 million cubic feet and 18.8 billion pounds, respectively. The estimated sediment volume occupied about 36 percent of the original conservation-pool, water-storage capacity of the reservoir. Mean annual net sediment deposition since 1948 in the original conservation pool of the reservoir was estimated to be 324 million pounds per year. Mean annual net sediment yield from the Fall River Lake Basin was estimated to be 585,000 pounds per square mile per year. The mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Fall River Lake were estimated to be 648,000 pounds per year and 267,000 pounds per year, respectively. The estimated mean annual net yields of total nitrogen and total phosphorus from the Fall River Lake Basin were 1,170 pounds per square mile per year and 480 pounds per square mile per year, respectively. Throughout the history of Fall River Lake, total nitrogen and total phosphorus concentrations in the deposited sediment were relatively uniform. Trace element concentrations in the bottom sediment of Fall River Lake generally were uniform over time. Arsenic, chromium, nickel, and zinc concentrations typically exceeded the threshold-effects guidelines, which represent the concentrations above which toxic biological effects occasionally occur. Trace element concentrations did not exceed the probable-effects guidelines (available for eight trace elements), which represent the concentrations above which toxic biological effects usually or frequently occur. Diatom occurrence in the bottom sediment of Fall River Lake was dominated by the species Aulacoseira granulata , which is an indicator of eutrophic (nutrient-rich) conditions. The abundance of the diatom Aulacoseira granulata , combined with cyanobacteria evidence and historical water-quality data, indicated that Fall River Lake likely has been eutrophic throughout much of its history.

Kansas↗

USGS1988

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in Bowdoin National Wildlife Refuge and adjacent areas of the Milk River basin, northeastern Montana, 1986-87

Concentrations of trace elements, radiochemicals, and pesticides in the Bowdoin National Wildlife Refuge lakes generally were not substantially larger than those in the water supplied from Dodson South Canal or in irrigation drainage. Concentrations of arsenic (47 micrograms/L), uranium (43 microg/L), and vanadium (51 microg/L) in Dry Lake Unit, and boron (1,000 microg/L) in Lake Bowdoin were notably larger than at other sites. Zinc concentrations in an irrigation drain (56 microg/L) and two shallow domestic wells (40 and 47 microg/L) were elevated relative to other sites. Concentrations of gross alpha radiation (64 picocuries/L) and gross beta radiation (71 picocuries/L) were elevated in Dry Lake Unit. Pesticides concentrations at all sites were 0.08 microg/L or less. Water use guidelines concentrations for boron, cadmium, uranium, zinc, and gross alpha radiation were slightly exceeded at several sites. In general, trace-constituent concentrations measured in the water do not indicate any potential toxicity problems in Bowdoin National Wildlife Refuge; however, highwater conditions in 1986 probably caused dilution of dissolved constituents compared to recent dry years. Trace element concentrations in bottom sediments of the refuge lakes were generally similar to background concentrations in the soils. The only exception was Dry Lake Unit, which had concentrations of chromium (99 micrograms/g), copper (37 microg/g), nickel (37 microg/g), vanadium (160 microg/g), and zinc (120 microg/g) that were about double the mean background concentrations. The maximum selenium concentration in bottom sediment was 0.6 microg/g. Pesticide concentrations in bottom sediments were less than analytical detection limits at all sites. With few exceptions, concentrations of trace elements and pesticides in biota generally were less than values known to produce harmful effects on growth or reproduction.

Montana↗

USGS2011

Sedimentation and occurrence and trends of selected nutrients, other chemical constituents, and cyanobacteria in bottom sediment, Clinton Lake, northeast Kansas, 1977-2009

A combination of available bathymetric-survey information and bottom-sediment coring was used to investigate sedimentation and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, cyanobacterial akinetes, and the radionuclide cesium-137 in the bottom sediment of Clinton Lake, northeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1977 through 2009 in the conservation (multi-purpose) pool of the reservoir was 438 million cubic feet and 18 billion pounds, respectively. The estimated sediment volume occupied about 8 percent of the conservation-pool, water-storage capacity of the reservoir. Sedimentation in the conservation pool has occurred about 70 percent faster than originally projected at the time the reservoir was completed. Water-storage capacity in the conservation pool has been lost to sedimentation at a rate of about 0.25 percent annually. Mean annual net sediment deposition since 1977 in the conservation pool of the reservoir was estimated to be 563 million pounds per year. Mean annual net sediment yield from the Clinton Lake Basin was estimated to be 1.5 million pounds per square mile per year. Typically, the bottom sediment sampled in Clinton Lake was at least 99 percent silt and clay. The mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Clinton Lake were estimated to be 1.29 million pounds per year and 556,000 pounds per year, respectively. The estimated mean annual net yields of total nitrogen and total phosphorus from the Clinton Lake Basin were 3,510 pounds per square mile per year and 1,510 pounds per square mile per year, respectively. Throughout the history of Clinton Lake, total nitrogen concentrations in the deposited sediment generally were uniform and indicated consistent inputs to the reservoir over time. Likewise, total phosphorus concentrations in the deposited sediment generally were uniform. Although, for two of three coring sites, a possible positive trend in phosphorus deposition was indicated. The Wakarusa River possibly was a larger contributor of nitrogen and phosphorus to Clinton Lake than was Rock Creek. As a principal limiting factor for primary production in most freshwater environments, phosphorus is of particular importance because increased inputs can contribute to accelerated reservoir eutrophication and the production of algal toxins and taste-and-odor compounds. Trace-element concentrations in the bottom sediment of Clinton Lake generally were uniform over time. As is typical for eastern Kansas reservoirs, arsenic, chromium, and nickel concentrations typically exceeded the threshold-effects guidelines, which represent the concentrations above which toxic biological effects occasionally occur. Zinc concentrations frequently exceeded the threshold-effects guideline. Trace-element concentrations did not exceed the probable-effects guidelines (available for eight trace elements), which represent the concentrations above which toxic biological effects usually or frequently occur. Cyanobacterial akinetes (cyanobacteria resting stage) in the bottom sediment of Clinton Lake, combined with historical water-quality data on chlorophyll-a and total phosphorus concentrations, indicated that the reservoir likely has been eutrophic throughout most of its history. A statistically significant increase in cyanobacterial akinetes in the bottom sediment indicated that Clinton Lake may have become more eutrophic over the life of the reservoir. The increase in cyanobacterial akinetes may, in part, be related to a possible increase in total phosphorus concentrations.

Scientific Investigations Report↗

USGS1999

Geomorphological assessment of sediment contamination in an urban stream system

Little is known about the influence of fluvial-geomorphological features on the dispersal of sediment-related contaminants in urban drainage systems. This study investigates the relation between reach-scale geomorphological conditions and network-scale patterns of trace-element concentrations in a partially urbanized stream system in East-Central Illinois, USA Robust statistical analysis of bulk sediment samples reveals levels of Cr, Cu, Pb, Ni, and Zn exceed contamination thresholds in the portion of the watershed in close proximity to potential sources of pollution-in this case storm-sewer outfalls. Although trace-element concentrations decrease rapidly downstream from these sources, substantial local variability in metal levels exists within contaminated reaches. This local variability is related to reach-scale variation in fluvial-geomorphic conditions, which in turn produces variation in the degree of sorting and organic-matter content of bed material. Metal concentrations at contaminated sites also exhibit considerable variability over time. Analytical tests on specific size fractions of material collected at a highly contaminated site indicate that Cr and Ni are concentrated in the 0.063 to 0.250 mm fraction of the sediment. This fraction also has elevated concentration of Zr. SEM analysis shows that the fine sand fraction contains shards of stainless steel within a matrix of zircon sand, an industrial material associated with a nearby alloy casting operation. Samples of suspended load and bedload at the contaminated site also have elevated amounts of trace metals, but concentrations of Ni and Cr in the bedload are less than concentrations in the bed material, suggesting that these trace elements are relatively immobile. Off the other hand, amounts of CU and Zn in the bedload exceed concentrations in the bed material, implying that these trace metals are preferentially mobilized during transport events.

Applied Geochemistry↗

USGS2020

Quantification of trace element loading in the upper Tenmile Creek drainage basin near Rimini, Montana, September 2011

The principle sources of trace elements entering upper Tenmile Creek, Montana, during September 2011, four trace metals and the metalloid arsenic, were identified and quantified by combining and analyzing streamflow data determined from tracer injection with trace-element concentrations and related water-quality data determined from synoptic sampling. The study reach was along upper Tenmile Creek, beginning downstream from the city of Helena’s diversion and extending 5,020 feet downstream. Results from the 2011 study, completed by the U.S. Geological Survey in cooperation with the Montana Department of Environmental Quality, were compared to results from a similar study conducted in 1998 to assess the effectiveness of mine reclamation and remediation work to reduce trace-element loading to upper Tenmile Creek, which has been ongoing throughout the drainage basin. Main-stem concentrations of most trace elements analyzed were generally greater in 1998 than in 2011. However, the State of Montana human-health criteria for total-recoverable cadmium and arsenic were exceeded in parts of upper Tenmile Creek, and concentrations of cadmium and zinc exceeded the acute aquatic-life criteria at all main-stem sites during both studies. Total-recoverable copper concentrations observed in 2011 exceeded the chronic aquatic-life criterion upstream from the Lee Mountain adit, whereas, in 1998, all sites exceeded the acute aquatic-life criteria. Direct comparison of loads from the 1998 and 2011 tracer studies were complicated by the differences in hydrologic conditions. Streamflow in 1998 was about 10 percent of the 2011 streamflow. The Lee Mountain Mine and Susie Lode adit were identified as major contributors of trace elements to upper Tenmile Creek in both studies. However, trace-element loading from the Lee Mountain Mine area was substantially reduced between 1998 and 2011. Total-recoverable loads of all trace elements showed substantial loss in 1998 but increased in 2011 downstream from the Susie Lode adit to the end of the study reach. This reach was one of the primary sources of trace-element loading to upper Tenmile Creek in 2011. This difference indicated that the streambed may act as a sink or a source for trace elements, depending on hydrologic conditions.

Montana↗

USGS1996

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia— A summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

North Carolina, Virginia↗

USGS2022

Groundwater hydrology in the area of Savannah and Gunstocker Creeks in northeastern Hamilton, southern Meigs, and northwestern Bradley Counties, Tennessee, 2007–09

The U.S. Geological Survey, in cooperation with the Savannah Valley Utility District, evaluated the groundwater hydrology of the Valley and Ridge carbonate rock aquifer in northeastern Hamilton, southern Meigs, and northwestern Bradley Counties, Tennessee, from 2007 through 2009. The evaluation included, and built on, the results of test drilling conducted in the area in 1974 to determine the potential for groundwater as a source of public supply for the utility and the results of an investigation conducted to define recharge areas for wells used by groundwater-source public-supply water systems throughout Hamilton County in the early 1990s. Groundwater-level data collected from wells open to the aquifer in the study area were used to prepare potentiometric-surface maps for fall 1992, spring and fall 1993, summer 2008, and spring 2009 conditions. Two primary groundwater basins were delineated from the maps—the larger of which coincides with the watershed of Savannah Creek in the southern part of the study area and the smaller of which coincides with the watershed of Gunstocker Creek in the northern part of the study area. Both basins are characterized by potentiometric surfaces that contain a central area of low-altitude groundwater levels and low gradients relative to the basin margins that reflect the orientation of enhanced permeability along dissolution-enlarged features that have developed parallel to strike in the aquifer. The recharge area of the Savannah Creek groundwater basin is estimated to be about 31 square miles, and the recharge area of the Gunstocker Creek groundwater basin is estimated to be about 17 square miles. Recharge to the aquifer in the Savannah Creek and Gunstocker Creek groundwater basins primarily occurs in the uplands area along White Oak Mountain in the eastern part of the study area and along the western boundaries of the basins. Groundwater flows toward the potentiometric lows in each basin, discharging as base flow to the streams and to springs locally. Groundwater withdrawals for public supply by the utility influence the potentiometric low in the north-central part of the Savannah Creek groundwater basin and disrupt flow in the creek and nearby Anderson Spring, particularly during the summer and fall seasons. No large groundwater withdrawals currently occur in the Gunstocker Creek basin, but there is potential for groundwater supply development in the basin. A conceptual model of the groundwater hydrology of the area developed from the evaluation indicates that Chickamauga Lake is the base-level control on groundwater discharge from the Savannah Creek and Gunstocker Creek basins and that lake stage affects the potentiometric surfaces and groundwater discharge in the most downgradient parts of the basins as a result of inferred hydraulic connection between the aquifer and the lake. The model also infers that captured surface water from sections of Savannah Creek and the Hiwassee River that are embayed by the lake could recharge the aquifer and serve as a source of water withdrawn by wells in each basin if the potentiometric surfaces were lowered to altitudes less than the stage of the lake, particularly under potential future groundwater-development scenarios in the Gunstocker Creek basin. Geochemical analysis of samples collected from six wells for the study indicate that groundwater in the Valley and Ridge aquifer in the area generally is a calcium-magnesium-bicarbonate type, and although the water generally is hard, it is suitable for most uses. Trace-element concentrations were less than primary drinking-water criteria in all the samples. Results of the investigation indicate that options are available for additional groundwater withdrawal in the study area. Water-level data collected since 1975 at the Savannah Valley Utility District Smith Road well site indicate that some additional amount of groundwater is available for withdrawal from the aquifer in the Savannah Creek groundwater basin. The potentiometric low within the Gunstocker Creek groundwater basin indicates that an area with enhanced permeability is present as a northeastern counterpart to the potentiometric low within the Savannah Creek basin. Because the Gunstocker Creek basin is about one-half the total area of the Savannah Creek basin, a commensurate decrease in available groundwater storage is likely. Furthermore, groundwater withdrawal locations in the Gunstocker Creek basin would be closer to—and possibly connected hydraulically to—the Hiwassee River, thus increasing the potential for induced surface-water recharge in the basin if sustained drawdown from pumping lowered groundwater levels to altitudes less than the stage of the river.

Tennessee↗