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At least 757 records · Page 42Linked to original sources

Analysis and visualization of coastal ocean model data in the cloud

The traditional flow of coastal ocean model data is from High Performance Computing (HPC) centers to the local desktop, or to a file server where just the data needed can be extracted via services such as OPeNDAP. Analysis and visualization is then conducted using local hardware and software. This requires moving large amounts of data across the internet as well as acquiring and maintaining local hardware, software and support personnel. Further, as data sets increase in size, the traditional workflow may not be scalable. Alternatively, recent advances make it possible to move data from HPC to the Cloud and perform interactive, scalable, data-proximate analysis and visualization, with simply a web browser user interface. We use the framework advanced by the NSF-funded Pangeo project, a free, open-source Python system which provides multi-user login via JupyterHub and parallel analysis via Dask, both running in Docker containers orchestrated by Kubernetes. Data is stored in the Zarr format, a Cloud-friendly ndarray format that allows performant extraction of data by anyone without relying on data services like OPeNDAP. Interactive visual exploration of data on massive model grids is made possible by new tools in the Python PyViz ecosystem, which can render maps at screen resolution, dynamically updating on pan and zoom operations. Two example are given: (1) calculating the maximum water level at each grid cell from a 53GB, 720 time step, 9 million node triangular mesh ADCIRC simulation of Hurricane Ike; (2) creating a dashboard for visualizing data from the curvilinear orthogonal COAWST/ROMS forecast model.

Journal of Marine Science and Engineering↗

Flow ecology of invasive suckermouth catfish in urbanized ridge-to-reef systems on O’ahu, Hawai’i

Introduction: The effects of flow regimes on the ability of invasive species to establish and maintain populations in the ridge to reef (R2R) systems common to oceanic islands is not well understood. The hydrology of the relatively short, high-gradient, and flashy R2R streams of oceanic islands may be extremely different from that of the continental watersheds invasive species originate from and thus may exert a stronger influence on their ecology. Our objective was to evaluate the effects of annual variability in flow conditions on the growth and recruitment of invasive armored Suckermouth Catfish Hypostomus c.f. watwata in Hawaiian streams. Methods: Suckermouth Catfish were captured from three streams of the Ala Wai Watershed on O’ahu. We then measured, weighed, and extracted the lapilli from each fish. We used back-calculated lengths at age to estimate the effects of interannual variability in flow on growth and recruitment. Results: Individuals ranged from 0–16 years old and grew rapidly in their first 3 years after which growth slowed substantially. The growth of Suckermouth Catfish was positively influenced by flow conditions indicative of wetter years and more stable flow and negatively influenced by flow conditions indicative of drier years and more variable flows. However, the specific annual flow metrics most strongly influencing growth varied by stream. Similarly, recruitment was positively influenced by higher winter flows with lower daily variability. Discussion: The observed effects of flow on Suckermouth Catfish growth and recruitment suggests that they are not particularly well suited for the flow conditions characteristic to R2R systems and that anthropogenic alterations to the hydrology and physical in-stream habitats may have enabled the species to be more successful on O’ahu than it would have been otherwise.

Hawaii↗

Lifetime of an ocean island volcano feeder zone: Constraints from U-Pb dating on coexisting zircon and baddeleyite, and 40Ar/39Ar age determinations, Fuerteventura, Canary Islands

High-precision isotope dilution thermal ionization mass spectrometry (IDTIMS) UPb zircon and baddeleyite ages from the PX1 vertically layered mafic intrusion Fuerteventura, Canary Islands, indicate initiation of magma crystallization at 22.10 0.07 Ma. The magmatic activity lasted a minimum of 0.52 Ma. 40 Ar/ 39 Ar amphibole dating yielded ages from 21.9 0.6 to 21.8 0.3, identical within errors to the UPb ages, despite the expected 1% theoretical bias between 40 Ar/ 39 Ar and UPb dates. This overlap could result from ( i ) rapid cooling of the intrusion (i.e., less than the 0.3 to 0.6 Ma 40 Ar/ 39 Ar age uncertainties) from closure temperatures ( T c ) of zircon (699988C) to amphibole (500600C) ( ii ) lead loss affecting the youngest zircons or ( iii ) excess argon shifting the plateau ages towards older values. The combination of the 40 Ar/ 39 Ar and U/Pb datasets implies that the maximum amount of time PX1 intrusion took to cool below amphibole T c is 0.8 Ma, suggesting PX1 lifetime of 520000 to 800000 Ma. Age disparities among coexisting baddeleyite and zircon (22.10 0.07/0.08/0.15 Ma and 21.58 0.15/0.16/0.31 Ma) in a gabbro sample from the pluton margin suggest complex genetic relationships between phases. Baddeleyite is found preserved in plagioclase cores and crystallized early from low silica activity magma. Zircon crystallized later in a higher silica activity environment and is found in secondary scapolite and is found close to calcite veins, in secondary scapolite that recrystallised from plagioclase. close to calcite veins. Oxygen isotope 18 O values of altered plagioclase are high (+7.7), indicating interaction with fluids derived from host-rock carbonatites. The coexistence of baddeleyite and zircon is ascribed to interaction of the PX1 gabbro with CO 2 -rich carbonatite-derived fluids released during contact metamorphism.

Canary Islands↗

Enhanced CO2 uptake at a shallow Arctic Ocean seep field overwhelms the positive warming potential of emitted methane

Continued warming of the Arctic Ocean in coming decades is projected to trigger the release of teragrams (1 Tg = 10 6 tons) of methane from thawing subsea permafrost on shallow continental shelves and dissociation of methane hydrate on upper continental slopes. On the shallow shelves (<100 m water depth), methane released from the seafloor may reach the atmosphere and potentially amplify global warming. On the other hand, biological uptake of carbon dioxide (CO 2 ) has the potential to offset the positive warming potential of emitted methane, a process that has not received detailed consideration for these settings. Continuous sea−air gas flux data collected over a shallow ebullitive methane seep field on the Svalbard margin reveal atmospheric CO 2 uptake rates (−33,300 ± 7,900 μmol m −2 ⋅d −1 ) twice that of surrounding waters and ∼1,900 times greater than the diffusive sea−air methane efflux (17.3 ± 4.8 μmol m −2 ⋅d −1 ). The negative radiative forcing expected from this CO 2 uptake is up to 231 times greater than the positive radiative forcing from the methane emissions. Surface water characteristics (e.g., high dissolved oxygen, high pH, and enrichment of 13 C in CO 2 ) indicate that upwelling of cold, nutrient-rich water from near the seafloor accompanies methane emissions and stimulates CO 2 consumption by photosynthesizing phytoplankton. These findings challenge the widely held perception that areas characterized by shallow-water methane seeps and/or strongly elevated sea−air methane flux always increase the global atmospheric greenhouse gas burden.

Arctic Ocean↗

The longevity of the South Pacific isotopic and thermal anomaly

The South Pacific is anomalous in terms of the Sr, Nd, and Pb isotope ratios of its hot spot basalts, a thermally enhanced lithosphere, and possibly a hotter mantle. We have studied the Sr, Nd, and Pb isotope characteristics of 12 Cretaceous seamounts in the Magellans, Marshall and Wake seamount groups (western Pacific Ocean) that originated in this South Pacific Isotopic and Thermal Anomaly (SOPITA). The range and values of isotope ratios of the Cretaceous seamount data are similar to those of the island chains of Samoa, Tahiti, Marquesas and Cook/Austral in the SOPITA. These define two major mantle components suggesting that isotopically extreme lavas have been produced at SOPITA for at least 120 Ma. Shallow bathymetry, and weakened lithosphere beneath some of the seamounts studied suggests that at least some of the thermal effects prevailed during the Cretaceous as well. These data, in the context of published data, suggest: (1)|SOPITA is a long-lived feature, and enhanced heat transfer into the lithosphere and isotopically anomalous mantle appear to be an intrinsic characteristic of the anomaly. (2)|The less pronounced depth anomaly during northwesterly plate motion suggests that some of the expressions of SOPITA may be controlled by the direction of plate motion. Motion parallel to the alignment of SOPITA hot spots focusses the heat (and chemical input into the lithosphere) on a smaller cross section than oblique motion. (3)|The lithosphere in the eastern and central SOPITA appears to have lost its original depleted mantle characteristics, probably due to enhanced plume/lithosphere interaction, and it is dominated by isotopic compositions derived from plume materials. (4)|We speculate (following D.L. Anderson) that the origin of the SOPITA, and possibly the DUPAL anomaly is largely due to focussed subduction through long periods of the geological history of the earth, creating a heterogeneous distribution of recycled components in the lower mantle

Earth and Planetary Science Letters↗

High resolution near-bed observations in winter near Cape Hatteras, North Carolina

The U.S. Geological Survey (USGS) Coastal and Marine Science Center in Woods Hole, Massachusetts, is leading an effort to understand the regional sediment dynamics along the coastline of North and South Carolina. As part of the Carolinas Coastal Change Processes Project, a geologic framework study in June of 2008 by the Woods Hole Coastal and Marine Science Center's Sea Floor Mapping Group focused on the seaward limit of Diamond Shoals and provided high resolution bathymetric data, surficial sediment characteristics, and subsurface geologic stratigraphy. These data also provided unprecedented guidance to identify deployment locations for tripods and moorings to investigate the processes that control sediment transport at Diamond Shoals. Equipment was deployed at three sites from early January, 2009 through early May, 2009: north and south of the shoals at 15 m depth, and at the tip at 24 m depth. Many strong storm systems were recorded during that time period. Mounted on the tripods were instruments to measure surface waves, pressure, current velocity, bottom turbulence, suspended-sediment profiles, and sea-floor sand-ripple bedforms. Many instruments were designed and programmed to sample in high resolution in time and space, as fast as 8 Hz hourly bursts and as small as 6 cm bin sizes in near bottom profiles. A second tripod at the north site also held a visual camera system and sonar imaging system which document seafloor bedforms. The region is known for its dynamics, and one of the tripods tipped over towards the end of the experiment. A preliminary look at the data suggests the region is characterized by high energy. Raw data from a burst recorded at the south site on Mar. 26 th show instantaneous flow speed at 150 cm/s at 0.5 m above the seabed. This paper reports preliminary highlights of the observations, based on raw data, and lessons learned from a deployment of large tripod systems in such a dynamic location.

North Carolina↗

Organic matter integration, overprinting, and the relative fraction of optically active organic carbon in a human-impacted watershed

Rivers continually integrate terrestrial organic matter (OM) into their waters, in a process that transfers 1.9 Pg C yr –1 as the primary linkage between oceanic and terrestrial carbon cycles. Yet rivers are not simple, conservative OM integrators. Patchy local land uses (wetlands, bogs, agriculture) release OM that can disproportionately alter river biogeochemistry and overprint upstream carbon. These releases are quantifiable at the plot scale but remain unpredictable across river reaches and watersheds, critically inhibiting our ability to scale up terrestrial-aquatic linkages to regional/global carbon cycling models. We evaluated OM overprinting distance along a human-influenced watershed to quantify river integration of terrestrial OM and to bridge the quantification gap between habitats and waterway biogeochemistry. We investigated changes in dissolved organic carbon (DOC) concentration and dissolved organic matter (DOM) composition (lignin phenols, fluorescence excitation-emission spectra using parallel factor analysis [PARAFAC], and the relative fraction of optically active DOM [EEM DOC ]). DOC concentrations increased continually ( p < 0.001) downstream, from median 1.0 mg L –1 at 30 km (headwaters) to 3.3 mg L –1 at the river mouth. This rate of increase corresponded to a DOC overprinting distance—the longitudinal distance over which DOC concentrations double—of 13 km. Mainstem DOC overprinting distance ranged from 8 km (winter, rainy season) to 21 km (summer, dry season with irrigation), highlighting stronger overprinting during increased hydraulic connectivity. Stronger overprinting also correlated to higher EEM DOC ( p < 0.001). Overprinting distance effectively quantifies river integration of DOM along the terrestrial-aquatic interface, helping to refine bottom-up carbon cycle estimates, inform upscaling of site-specific fluxes, and to track land use and climate influence on river biogeochemistry.

California↗

Barrier islands influence the assimilation of terrestrial energy in nearshore fishes

We examined the relative importance of landscape features on estuarine fish trophic structure and dependence on terrestrial organic matter (OM terr ) in four barrier island lagoon systems along the Alaskan Beaufort Sea coast. Our study compared two relatively large lagoon systems characterized by high river discharge and relatively free ocean water exchanges (central region near Prudhoe Bay, Alaska) with two highly protected lagoons characterized by low river discharge and limited exchange with ocean waters (eastern region near Kaktovik, Alaska). We hypothesized that freshwater discharge would be a strong determinant of food web structure for both resident marine and diadromous fishes if more discharge increases availability of OM terr relative to lagoons with limited or no river inputs. To consider differences in trophic characteristics in fishes between study regions, we estimated community-wide measures of trophic structure (hereafter, community metrics) and the relative use of OM terr from mixing models using stable isotope composition (δ 13 C and δ 15 N; muscle tissue) among 12 species and identified the influences of region and body size. Fish captured in lagoons well protected by barrier islands had more distinct and diverse isotopic niches relative to those in more exposed lagoons based on community metrics. The use of OM terr by nearshore fishes in both regions was substantial and was >50% for diadromous species. Between regions, OM terr use differed in 6 of the 8 species considered but was not consistently higher in one region. The relative importance of OM terr varied with fish size in 7 of 10 species considered, with more OM terr used by smaller individuals. This work highlights the importance of OM terr to Arctic fishes and fisheries, some of which are of subsistence importance, even when feeding grounds are primarily marine. We propose that landscape features, particularly barrier islands, play an important role in structuring nearshore food webs. Barrier islands may provide a previously undocumented ecosystem service of increasing food web complexity, which may promote system resilience.

Alaska↗

Archive of digital chirp subbottom profile data collected during USGS cruise 10BIM04 offshore Cat Island, Mississippi, September 2010

In September of 2010, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army Corps of Engineers (USACE), conducted a geophysical survey to investigate the geologic controls on barrier island framework of Cat Island, Miss., as part of a broader USGS study on Barrier Island Mapping (BIM). These surveys were funded through the Mississippi Coastal Improvements Program (MsCIP) and the Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazard Susceptibility Project as part of the Holocene Coastal Evolution of the Mississippi-Alabama Region Subtask. This report serves as an archive of unprocessed digital chirp subbottom data, trackline maps, navigation files, GIS files, Field Activity Collection System (FACS) logs, and formal FGDC metadata. Gained (showing a relative increase in signal amplitude) digital images of the seismic profiles are also provided. Refer to the Acronyms page for expansions of acronyms and abbreviations used in this report. The USGS Saint Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier to each cruise or field activity. For example, 10BIM04 tells us the data were collected in 2010 during the fourth field activity for that project in that calendar year. Refer to http://walrus.wr.usgs.gov/infobank/programs/html/definition/activity.html for a detailed description of the method used to assign the field activity identification (ID). All chirp systems use a signal of continuously varying frequency; the EdgeTech SB-512i system used during this survey produces high-resolution, shallow-penetration (typically less than 50 milliseconds (ms)) profile images of sub-seafloor stratigraphy. The towfish contains a transducer that transmits and receives acoustic energy; it was housed within a float system (built at the SPCMSC), which allows the towfish to be towed at a constant depth of 1.07 meters (m) below the sea surface. As transmitted acoustic energy intersects density boundaries, such as the seafloor or sub-surface sediment layers, some energy is reflected back toward the transducer, received, and recorded by a Personal Computer (PC)-based seismic acquisition system. This process is repeated at regular time intervals (for example, 0.125 seconds (s)), and returned energy is recorded for a specific duration (for example, 50 ms). In this way, a two-dimensional (2-D) vertical image of the shallow geologic structure beneath the ship track is produced. Figure 1 displays the acquisition geometry. Refer to table 1 for a summary of acquisition parameters and table 2 for trackline statistics. The archived trace data are in standard Society of Exploration Geophysicists (SEG) SEG Y rev. 0 format (Barry and others, 1975); the first 3,200 bytes of the card image header are in American Standard Code for Information Interchange (ASCII) format instead of Extended Binary Coded Decimal Interchange Code (EBCDIC) format. The SEG Y files may be downloaded and processed with commercial or public domain software such as Seismic Unix (SU) (Cohen and Stockwell, 2010). See the How To Download SEG Y Data page for download instructions. The printable profiles provided here are GIF images that were processed and gained using SU software, and they can be viewed from the Profiles page or from links located on the trackline maps; refer to the Software page for links to example SU processing scripts. The SEG Y files are available on the DVD version of this report or on the Web, downloadable via the USGS Coastal and Marine Geoscience Data System (http://cmgds.marine.usgs.gov). The data are also available for viewing using GeoMapApp (http://www.geomapapp.org) and Virtual Ocean (http://www.virtualocean.org) multi-platform open source software.

Mississippi↗

An evaluation of tradeoffs in restoring ephemeral vs. perennial habitats to conserve animal populations

Introduction: Habitat loss and degradation pose significant threats to global fish and wildlife populations, prompting substantial investments in habitat creation and restoration efforts. Not all habitats provide equal benefits, leading to challenges in prioritizing restoration actions. For example, juvenile anadromous salmonids require high quality rearing aquatic habitats to achieve the physiological requirements needed to successfully migrate to the ocean. However, there are profound disagreements among anadromous salmon restoration managers whether it is best to focus efforts on restoring in-channel habitats that are available for the entire rearing period or floodplain habitats that, while facilitating greater growth and survival than in-channel habitats, are only available for a few weeks at a time and are typically only activated every two-to-three years. Methods: We used an existing fall-run Chinook salmon decision-support model to evaluate under what conditions floodplain restoration would provide greater benefits than in-channel habitat restoration. The simulations included a wide range of floodplain inundation frequencies and durations and floodplain benefits in the form of increased survival and growth relative to in-channel habitats. Results: The simulations results indicated that in-channel habitat restoration was always the best habitat restoration action when there was no existing in-channel habitat despite simulating a wide range of flood frequency, duration, and growth and survival benefits. Floodplain restoration was generally best when there was sufficient in-channel habitat available to successfully rear most of the juveniles produced by the returning adult salmon. Discussion: We hypothesize that in-channel and floodplain habitats have different roles in salmon population maintenance with in-channel habitats regulating the overall population size and floodplains acting as recurrent resource pulses. Our study provides a quantitative framework to evaluate the benefit of these two habitat types and provides generalizable rulesets that can be used by managers when implementing habitat restoration strategies for species that inhabit both in-channel and floodplain habitats.

California↗

Two centuries of southwest Iceland annually-resolved marine temperature reconstructed from Arctica islandica shells

Iceland's exposure to major ocean current pathways of the central North Atlantic makes it a useful location for developing long-term proxy records of past marine climate. Such records provide more detailed understanding of the full range of past variability which is necessary to improve predictions of future changes. We constructed a 225-year (1791–2015 CE) master shell growth chronology from 29 shells of Arctica islandica collected at 100 m water depth in southwest Iceland (Faxaflói). The growth chronology provides a robust age model for shell oxygen isotope (δ 18 O shell ) data produced at annual resolution for 251 years (1765–2015 CE). The temperature reconstruction derived from δ 18 O shell shows coherence with May–October local surface temperature records and sea surface temperatures in the North Atlantic region, suggesting it is a useful proxy indicator of water temperature variability at 100 m depth within Faxaflói. Field correlations between the shell-based records and gridded sea surface temperature data reveal strong positive correlations between the 1-year lagged shell growth and temperatures within the subpolar gyre post-1972, suggesting a delayed influence of subpolar gyre dynamics on ecological indicators in southwest Iceland in recent decades. However, the shell growth chronology and δ 18 O shell record generally show relatively weak and insignificant correlations with larger region climate indices including the Atlantic Multidecadal Variability, North Atlantic Oscillation, and East Atlantic pattern. Therefore the interannual variations in the newly produced shell-based records appear to reflect more local to regional dynamics around southwest Iceland than large-scale modes of climate variability.

Estuarine, Coastal and Shelf Science↗

Rapid Holocene deposition in the Mackenzie Trough and Barrow Canyon areas in the western Arctic Ocean

The Arctic Ocean and terrestrial environment have recently been reported to be changing drastically, but it is unclear whether these changes are similar to natural variations in the past or how sudden and large the changes are compared to natural variations. This premise served as motivation to collect sediment cores during the summer of 2022 at four sites on the Canadian continental shelf and Alaskan upper continental slope to reconstruct changes in the marine and terrestrial environments to provide a comprehensive picture of the ocean environment during the preindustrial period before anthropogenic influences. We dated the sediments based on the 137 Cs radioactivity of bulk sediments and the 14 C concentrations of mollusk shells. The 137 Cs radioactivity shows a distinct onset corresponding to 1950 Common Era (CE) and the most prominent peak corresponding to 1963 CE. Multiple peaks appeared above the most prominent one, coinciding with nuclear power plant accidents in 1986 and 2011. Inventories of excess 210 Pb in all cores exceed the estimated supply of excess 210 Pb from atmospheric deposition, likely due to the scavenging supply of excess 210 Pb. By comparing 137 Cs and radiocarbon conventional ages, we estimated the local radiocarbon reservoir age value of each site. Using these local radiocarbon reservoir age and the conventional ages of mollusk shell samples, we established the age-depth models by the Bayesian method. The optimal ΔR values were 598, 511, 65, and –60 years at the MT1, MT2, BC2, and BC2-2 sites, respectively. The cores consist of clayey silts continuously deposited with uniquely high sedimentation rates of 0.17 to 0.74 cm y −1 . Variation in the Ca/Ti ratio indicates ~ 20, ~ 30, 50–60, 100–125, and 300-year cycles, likely attributed to the variation in the Aleutian Low that controls the Bering Strait inflow of Pacific waters influencing our core sites. These sediments will be used for further high-resolution, multi-proxy studies with forthcoming results.

western Arctic Ocean↗

Overhauling ocean spatial planning to improve marine megafauna conservation

Tracking data have led to evidence-based conservation of marine megafauna, but a disconnect remains between the many thousands of individual animals that have been tracked and the use of these data in conservation and management actions. Furthermore, the focus of most conservation efforts is within Exclusive Economic Zones despite the ability of these species to move thousands of kilometres across multiple national jurisdictions. To assist the goal of the United Nations General Assembly’s recent effort to negotiate a global treaty to conserve biodiversity on the high seas, we propose the development of a new frontier in dynamic marine spatial management. We argue that a global approach combining tracked movements of marine megafauna and human activities at-sea, and using existing and emerging technologies (e.g., through new tracking devices and big data approaches) can be applied to deliver near real-time diagnostics on existing risks and threats to mitigate global risks for marine megafauna. With technology developments over the next decade expected to catalyse the potential to survey marine animals and human activities in ever more detail and at global scales, the development of dynamic predictive tools based on near real-time tracking and environmental data will become crucial to address increasing risks. Such global tools for dynamic spatial and temporal management will, however, require extensive synoptic data updates and will be dependent on a shift to a culture of data sharing and open access. We propose a global mechanism to store and make such data available in near real-time, enabling a holistic view of space use by marine megafauna and humans that would significantly accelerate efforts to mitigate impacts and improve conservation and management of marine megafauna.

Frontiers in Marine Science↗

Preconditioning by sediment accumulation can produce powerful turbidity currents without major external triggers

Turbidity currents dominate sediment transfer into the deep ocean, and can damage critical seabed infrastructure. It is commonly inferred that powerful turbidity currents are triggered by major external events, such as storms, river floods, or earthquakes. However, basic models for turbidity current triggering remain poorly tested, with few studies accurately recording precise flow timing. Here, we analyse the most detailed series of measurements yet made of powerful (up to 7.2 m s −1 ) turbidity currents, within Monterey Canyon, offshore California. During 18-months of instrument deployment, fourteen turbidity currents were directly monitored. No consistent triggering mechanism was observed, though flows did cluster around enhanced seasonal sediment supply. We compare turbidity current timing at Monterey Canyon (a sandy canyon-head fed by longshore drift) to the only other systems where numerous (>10-100) flows have been measured precisely via direct monitoring; the Squamish Delta (a sandy fjord-head delta), and the Congo Canyon (connected to the mud-dominated mouth of the Congo River). A common seasonal pattern emerges, leading to a new model for preconditioning and triggering of turbidity currents initiating through slope failure in areas of sediment accumulation, such as canyon heads or river mouths. In this model, rapid or sustained sediment supply alone can produce elevated pore pressures, which may persist, thereby predisposing slopes to fail. Once preconditioned, a range of minor external perturbations, such as moderate storm-waves, result in local pore pressure variation, and thus become effective triggers. Major external triggers are therefore not always a prerequisite for triggering of powerful turbidity currents.

Earth and Planetary Science Letters↗

Assessing per- and polyfluoroalkyl substances (PFAS) in sediments and fishes in a large, urbanized estuary and the potential human health implications

The primary source of chronic exposures to per- and polyfluoroalkyl substances (PFASs) in humans is through the ingestion of contaminated foods and drinking water, with fish and other seafood being a major contributor. Nevertheless, there is scant literature on the dietary exposure to PFASs for the general United States (U.S.) population. The Tampa Bay (Florida, USA) region has the highest population density in the State and communities and their attendant support services are arrayed in an urban to semi-rural continuum from the head of the Bay to the ocean mouth. Tampa Bay supports productive recreational and commercial fisheries, providing a diverse community of species. A variety of potential PFAS sources surround Tampa Bay including airports, industry, wastewater treatment plants, fire-fighting training areas and military installations. The objective of this study is to quantify PFASs in sediment and fishes collected from Tampa Bay to further estimate human health risks from dietary exposures. Sediment ( n = 17) and fish (24 species, n = 140) were collected throughout Tampa Bay in 2020 and 2021 and analyzed for 25 PFAS compounds. Concentrations of PFASs in sediments and edible tissues of fish ranged from 36.8 to 2,990 ng kg -1 (dry weight) and 307 to 33,600 ng kg -1 (wet weight), respectively. Generally, levels were highest in Old Tampa Bay and decreased south towards the Gulf of Mexico. Profiles in both matrices were generally dominated by perfluorooctane sulfonic acid (PFOS) with variations by location. Estimated human health risks from the consumption of contaminated fish collected in Tampa Bay exceeded concentration thresholds for minimum risk levels (MRLs) and tolerable weekly intake (TWIs) values for adults and youths. Additionally, concentrations of PFOS in edible fish tissues of several recreationally important species collected in Tampa Bay exceeded consumption guideline levels established by several governmental agencies. In the current context, the elevated levels of PFAS in Tampa Bay and the exceedances of available thresholds for potential human health risks are a cause for concern and justify a more intensive examination especially for more heavily utilized species, particularly those used in subsistence-level fishing, which, as elsewhere may be significantly under documented.

Florida↗

Wide-area debris field and seabed characterization of a deep ocean dump site surveyed by autonomous underwater vehicles

Disposal of industrial and hazardous waste in the deep ocean was a pervasive global practice near coastlines in the 20th century. Uncertainty in the quantity, location, and contents of dumped materials at historical disposal sites underscores ongoing risks to marine ecosystems and human health. This study presents analysis of a 150-km2 wide-area sidescan sonar survey conducted in March 2021 with two autonomous underwater vehicles (AUVs) at an offshore dumpsite in San Pedro Basin, California. Previous camera surveys located 60 barrels and other debris; sediment analysis in the region showed varying concentrations of the insecticidal chemical Dichlorodiphenyl-trichloroethane (DDT), for which an estimated 350-700 metric tons was discarded in the San Pedro Basin between 1947 and 1961. A lack of primary historical documents from Montrose Chemical or California Salvage Company that specify the DDT acid waste disposal method has contributed to the ambiguity surrounding whether the dumping method was via bulk discharge or containerized units. Barrels and debris visually detected during previous surveys by Remotely Operated Vehicles (ROVs) Jason and SuBastian and AUV Sentry served as the basis for ground truth testing and object classification using size and acoustic intensity characteristics. Target detection and classification algorithms were developed using image and signal processing techniques that resulted in the identification of over 74,000 debris targets within the survey region. Statistical, spectral, and machine learning techniques are used to characterize seabed variability and for bottom-type classification. These analytical techniques combined with the survey capabilities of AUVs provide a framework for efficient mapping and characterization of uncharted deep-water disposal sites.

California↗

Ultra-high chlorine in submarine Kı̄lauea glasses: Evidence for direct assimilation of brine by magma

Basaltic glass grains from the submarine south flank of Kı̄lauea, Hawai′i, have Cl concentrations of 0.01–1.68 wt%, the latter being the highest Cl content yet recorded for a Hawaiian glass. The high-Cl glass grains are products of brine assimilation by tholeiite magma. The glasses are grains in a sandstone clast from bedded breccias draping the southwestern margin of Kı̄lauea’s submarine midslope bench. The clast contains two distinct suites of glass grains: abundant degassed tholeiites, perhaps derived from subaerial lavas of Mauna Loa that shattered upon ocean entry, and a smaller population of Kea-type tholeiite ( n =17 analyzed) that erupted subaqueously, based on elevated S (780–1050 ppm), H 2 O (0.42–1.27 wt%), and CO 2 (<30–120 ppm), probably early in Kı̄lauea’s shield-building stage. Ten grains in this group have Cl>1000 ppm, six >5000 ppm, and two grains have >10 000 ppm dissolved Cl. Abundances of H 2 O, Na 2 O, K 2 O, and several trace elements increase regularly with Cl concentration, and we estimate that Cl enrichment was due to up to 13 wt% addition of a brine consisting of 78% H 2 O (wt), 13% Cl, 4.4% Na, 2.6% K, 2.6% Ca, 620 ppm Ba, 360 ppm Sr, 65 ppm Rb, and 7 ppm Pb. The large amounts of brine addition argue against bulk assimilation of low-porosity brine-bearing rock. The brine’s composition is appropriate for a seawater-derived hydrothermal fluid that reacted with basaltic wall rocks at T >100°C, losing Mg and S and gaining K, Ca, Rb, Ba, Sr, and Pb, followed by phase separation near 500°C and ∼50 MPa (5 km below sea level at hydrostatic pressure). Brine was assimilated at or near the depth it formed, as estimated on petrologic grounds, but under lithostatic conditions. The highest extents of assimilation either forced volatile saturation of the magma or enriched already coexisting magmatic vapor in H 2 O. Possible mechanisms for assimilation are: (1) forcible injection of brine into magma during bursting of overpressured pockets heated by new dikes, or (2) intrusion of magma into lenses or sills occupied by trapped brine.

Hawaii↗

Archive of digital chirp subbottom profile data collected during USGS cruise 12BIM03 offshore of the Chandeleur Islands, Louisiana, July 2012

From July 23 - 31, 2012, the U.S. Geological Survey conducted geophysical surveys to investigate the geologic controls on barrier island framework and long-term sediment transport along the oil spill mitigation sand berm constructed at the north end and just offshore of the Chandeleur Islands, La. (figure 1). This effort is part of a broader USGS study, which seeks to better understand barrier island evolution over medium time scales (months to years). This report serves as an archive of unprocessed digital chirp subbottom data, trackline maps, navigation files, Geographic Information System (GIS) files, Field Activity Collection System (FACS) logs, and formal Federal Geographic Data Committee (FGDC) metadata. Gained (showing a relative increase in signal amplitude) digital images of the seismic profiles are also provided. Refer to the Abbreviations page for expansions of acronyms and abbreviations used in this report. The USGS St. Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier to each cruise or field activity. For example, 12BIM03 tells us the data were collected in 2012 during the third field activity for that project in that calendar year and BIM is a generic code, which represents efforts related to Barrier Island Mapping. Refer to http://walrus.wr.usgs.gov/infobank/programs/html/definition/activity.html for a detailed description of the method used to assign the field activity ID. All chirp systems use a signal of continuously varying frequency; the EdgeTech SB-424 system used during this survey produces high-resolution, shallow-penetration (typically less than 50 milliseconds (ms)) profile images of sub-seafloor stratigraphy. The towfish contains a transducer that transmits and receives acoustic energy and is typically towed 1 - 2 m below the sea surface. As transmitted acoustic energy intersects density boundaries, such as the seafloor or sub-surface sediment layers, energy is reflected back toward the transducer, received, and recorded by a PC-based seismic acquisition system. This process is repeated at regular time intervals (for example, 0.125 seconds (s)) and returned energy is recorded for a specific duration (for example, 50 ms). In this way, a two-dimensional (2-D) vertical image of the shallow geologic structure beneath the ship track is produced. Figure 2 displays the acquisition geometry. Refer to table 1 for a summary of acquisition parameters and table 2 for trackline statistics. The archived trace data are in standard Society of Exploration Geophysicists (SEG) SEG Y rev. 0 format (Barry and others, 1975); the first 3,200 bytes of the card image header are in ASCII format instead of EBCDIC format. The SEG Y files may be downloaded and processed with commercial or public domain software such as Seismic Unix (SU) (Cohen and Stockwell, 2010). See the How To Download SEG Y Data page for download instructions. The web version of this archive does not contain the SEG Y trace files. These files are very large and would require extremely long download times. To obtain the complete DVD archive, contact USGS Information Services at 1-888-ASK-USGS or infoservices@usgs.gov. The printable profiles provided here are GIF images that were processed and gained using SU software and can be viewed from the Profiles page or from links located on the trackline maps; refer to the Software page for links to example SU processing scripts. The SEG Y files are available on the DVD version of this report or on the Web, downloadable via the USGS Coastal and Marine Geoscience Data System (http://cmgds.marine.usgs.gov). The data are also available for viewing using GeoMapApp (http://www.geomapapp.org) and Virtual Ocean (http://www.virtualocean.org) multi-platform open source software. Detailed information about the navigation system used can be found in table 1 and the Field Activity Collection System (FACS) logs. To view the trackline maps and navigation files, and for more information about these items, see the Navigation page.

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