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At least 757 records · Page 42Linked to original sources

Age and quality of ground water and sources of nitrogen in the surficial aquifers in Pumpkin Creek Valley, western Nebraska, 2000

Ground water is the source of drinking water for the residents of Pumpkin Creek Valley, western Nebraska. In this largely agricultural area, shallow aquifers potentially are susceptible to nitrate contamination. During the last 10 years, ground-water levels in the North Platte Natural Resources District have declined and contamination has become a major problem for the district. In 2000, the U.S. Geological Survey and the North Platte Natural Resources District began a cooperative study to determine the age and quality of the ground water and the sources of nitrogen in the aquifers in Pumpkin Creek Valley. Water samples were collected from 8 surface-water sites, 2 springs, and 88 ground-water sites during May, July, and August 2000. These samples were analyzed for physical properties, nutrients or nitrate, and hydrogen and oxygen isotopes. In addition, a subset of samples was analyzed for any combination of chlorofluorocarbons, tritium, tritium/helium, sulfur-hexafluoride, carbon-14, and nitrogen-15. The apparent age of ground water in the alluvial aquifer typically varied from about 1980 to modern, whereas ground water in the fractured Brule Formation had a median value in the 1970s. The Brule Formation typically contained ground water that ranged from the 1940s to the 1990s, but low-yield wells had apparent ages of 5,000 to 10,000 years before present. Data for oxygen-18 and deuterium indicated that lake-water samples showed the greatest effects from evaporation. Ground-water data showed no substantial evaporative effects and some ground water became isotopically heavier as the water moved downgradient. In addition, the physical and chemical ground-water data indicate that Pumpkin Creek is a gaining stream because little, if any, of its water is lost to the ground-water system. The water-quality type changed from a sodium calcium bicarbonate type near Pumpkin Creek's headwaters to a calcium sodium bicarbonate type near its mouth. Nitrate concentrations were largest in the alluvial system (median = 5 mg/L) and smallest in the surface-water system (median = 1 mg/L). Most nitrate concentrations exceeding the U.S. Environmental Protection Agency maximum contaminant level for drinking water of 10 mg/L as nitrogen were adjacent to irrigated fields and in areas where alluvial sediments are less than 50 ft thick. Sources of nitrogen in the ground water of the study area included naturally occurring nitrogen, commercial fertilizer, and animal waste. Based on nitrate concentration and delta nitrogen-15, the nitrogen in 65 percent of the water samples appears to have originated from a mixture of commercial fertilizers and animal waste. Some of the smallest nitrate concentrations in the ground-water samples contained some of the largest delta nitrogen-15 values (greater than 10 per mil), which suggests animal waste as the likely source. Commercial fertilizers were the likely source of most of the nitrogen in water samples with nitrate concentrations that exceeded 10 mg/L. The source of the nitrogen in water samples with nitrate concentrations exceeding 10 mg/L, but with delta nitrogen-15 values close to 10 per mil, could not be determined.

Nebraska↗

Sediment transport, terrace incision, and sediment chemistry in subbasins of differing land use, Stinking Water Creek Basin near Rangely, Colorado

In many areas of western Colorado, Late Cretaceous Mancos Shale is a source of sediment, salinity, and selenium to surface water. Natural weathering processes and human activity can expose and move sediments from the Mancos Shale, leading to increased salinity and selenium concentrations in surface water. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, studied four subbasins of Stinking Water Creek near Rangely, Colorado, to provide information regarding landscapes on Mancos Shale that have undergone land-use change. Rangeland grazing is present in all four subbasins. Subbasins A1 and A2 have land use related to energy development and subbasins B1 and B2 do not. Aerial photographs, sediment chemistry, optically stimulated luminescence (OSL) ages, cross-section surveys, and Watershed Erosion Prediction Project (WEPP) modeling were used to characterize the history of land-use change by estimating stream channel incision rates and sediment, salinity, and selenium loads. All subbasins had upper and lower terraces and a modern streambed channel, and these surfaces were dated using OSL. In subbasins A1, A2, and B1, the streambed age was older than the terraces, indicating the channels are incising and widening into the older alluvium. In subbasin B2, however, the streambed age was much younger than the terraces, indicating aggradation is the main process. Differences in channel morphology were not always related to land use but to the subbasin position (upstream compared to downstream). Channels in subbasins A1 and A2 were generally wider and shallower than channels in subbasins B1 and B2. Landscape disturbances related to energy development in subbasins A1 and A2 could have caused channel evolution to progress from incision to widening processes.

Colorado↗

Surficial geology and geomorphology of Potter County, Pennsylvania

Potter County is located in the Appalachian Plateaus of north-central Pennsylvania and contains the headwaters of the Genesee River, the Allegheny River, and the Susquehanna River. Drift of Wisconsin age covers the northeastern part of the county. This study includes a detailed survev of the surficial deposits of the Genesee quadrangle in north-central Potter County and a reconnaissance of the remainder of the county; a soil survey and a botanical survey were carried on concurrently. The region is a deeply dissected plateau having extensive areas of steeply sloping land separated by narrow ridges and valleys; there is very little level land. Near the junction of the three watersheds the uplands rise to altitudes of more than 2,500 feet. The maximum relief in the Susquehanna drainage is more than 1,500 feet; in the Genesee and Allegheny drainage it. is about 800 feet. Valley walls are steep (15° to 30°), and the uplands have gentle slopes (0.5° to 10°). The drainage pattern is trellised. The climate is continental. Temperatures range from about -30° F. to more than 100° F. The average annual precipitation ranges approximately from 34 to 42 inches. Floods may occur at any season of the year. The large volumes of water from rain or melting snow carried by small streams come from springs. There is little precise data on frost in the ground, but it is probable that the ground seldom freezes in forested areas. The soils of Potter County have relatively immature profiles with poorly developed horizons that commonly have many characteristics inherited from their parent materials. At the great soil group level, the zonal soils are divided into Podzol soils and Brown Podzolic soils. Many soils have a high silt content in the upper part of the profile, apparently derived (at least partly) from a mantle of eolian silt. Mos~ of Potter County is covered by second-growth forests consisting of 40- to 60-year-old hardwood stands. The present forests growing on slopes and summits are composed approximately of 25 species of trees. The northern hardwood region includes most of the county, with an oak-forest region near the borders, principally along its southern margin. Potter County is underlain by sandstone, siltstone, shale, conglomerate, and minor amounts of coal and calcareous rock that range in age from Late Devonian to Pennsylvanian. These rocks form broad open folds that strike northeast. South of the border of the Wisconsin drift, and possibly at two localities inside the drift border, are scattered remnants of ancient soils (here called paleosol), that were formed in preWisconsin time-probably during the Sangamon interglacial stage. This paleosol ranges in texture from clay loam to silt loam, ranges in color from yellowish red to red, includes a few percent to more than 25 percent of rock fragments, and apparently contains a small percentage of gibbsite and varying amounts of kaolinite. Known thicknesses range from 1 to 33 feet. Paleosol was developed on diverse kinds of parent material, such as till, stratified drift, colluvium, and residuum, at altitudes ranging from a few hundred to 2,400 feet. The climatic conditions under which the paleosol formed are uncertain; however, these ancient soils may record an episode of subtropical climatic conditions during which lateritic soils were formed. Perhaps these soils are analogous to the Red-Yellow Podzolic soils of southeastern United States. Except for one possible remnant, no pre-Wisconsin drift has been recognized in Potter County. The Wisconsin glacial deposits of Potter County belong to either the Iowan or Tazewell substages and are dominantly till with minor amounts of glaciofluvial deposits. Erratics of igneous or metamorphic rock comprise less than 0.1 percent of the total number of rock fragments. The till is slightly weathered to depths ranging from 3 to about 12 feet. The drift border is indefinite and has been drawn at the southern limit of erratics or well-rounded or striated pebbles and is only locally marked by a terminal moraine or by a distinct change in the surficial deposits. The drift border is relatively straight and crosses the Genesee quadrangle in a northwesterly direction with little regard for the major topographic features, thus suggesting that the Wisconsin ice sheet had a relatively straight and steep front. Over most of the unglaciated part of Potter County, the bedrock is concealed beneath rubble that probably was formed during the Iowan or Tazewell substage, almost contemporaneously with the adjacent drift. In general, the rubble is thickest and most extensive within about 10 miles of the drift border, becoming thinner and less continuous farther away. The apparent parallelism between a belt of thick periglacial deposits and the drift border suggests that the deposits result from climatic factors in operation while the Wisconsin ice sheet was nearby. Ancient soil structures or patterned ground occur at, or near, the surface of both the periglacial deposits and the adjacent drift. These ancient soil structures are so similar to modern forms in arctic or alpine environments that they are considered to be the result of vigorous frost action. Many of the structures are believed to be a result of down-slope movement of debris by solifluction, facilitated by a frozen subsoil as much as 10 feet deep. Perennially frozen ground may have been present, but this is not a prerequisite. The periglacial deposits underlie long smooth slopes that extend from ridge crest to valley bottom. Flood plains are absent near the headwaters of many streams, the valley walls forming a V-shaped profile. While frost action was in progress, forests probably were restricted to flood plains, lower slopes, and scattered upland areas. Large parts of the upland were bare or partly covered by tundra vegetation; elsewhere, there were scattered trees but no dense forest. 1 2 SURFICIAL GEOLOGY AND GEOMORPHOLOGY OF POTTER COUNTY, PENNSYLVANIA Recent alluvium and alluvial fans include sand and sandy loams, 1 to 3 feet thick, that overlie gravel. The alluvium contains organic matter and lenses of finer materials. Thickness ranges from a few to more than 100 feet. Along the principal streams the alluvium probably overlies Pleistocene deposits. Most of the alluvial fans are composed of unstratified rubbly, pebbly, cobbly. or bouldery sandy loams to silty clay loams with local lenses of stratified sand and gravel. The alluvial fans mapped in the Genesee quadrangle probably include both Wisconsin stage and Recent deposits. The summits of the A.ppalachian Plateaus in north-central Pennsylvania have long been recognized as the remnants or traces of one or more peneplains. To test this hypothesis, a restored contour map was prepared to show the configuration of a supposed peneplain on the assumption that the plateau tops are remnants of such an old erosion surface. The restored contours delineate a surface that corresponds roughly to rock structure. In general, the uplands slope parallel to the dip of the bedrock. The major streams, such as the West Branch Susquehanna River, cross the ridges and valleys of the restored surface in such a way that it is difficult to suppose that the restored surface was ever graded to these streams. On the contrary, it is probable that the restored surface never existed and that the plateau tops are structurally controlled surfaces held up by sandstone and conglomerate beds in the Pottsville and Pocono formations. The plateau tops may have been lowered by erosion as much as 200 feet during the Pleistocene-in other words, after the major streams were incised. If this portion of the Appalachian Plateaus was ever reduced to a peneplain, such a hypothetical surface must have lain many hundreds of feet above the uplands of the present day. The only alternative that might involve peneplanation is the improbable hypothesis that the plateau tops are remnants of a slightly deformed peneplain and that the peneplain was folded along the axes of the Appalachian orogeny. This remote possibility is not supported by any known evidence. The geomorphic analysis yields no new data on the origin of the cross-axial drainage. Regardless of whether the plateaus are peneplain remnants or are structurally controlled surfaces, the beginning of the major southeastward-flowing streams long antedates the existing landscape. The geomorphic history of Potter County begins with an assumed long interval of erosion during the Mesozoic and early Cenozoic eras, for which no record remains in this area. The southeast master drainage was established by the latter part of the Tertiary period (perhaps at a much earlier date), probably as the result of the northwestward migration of the Atlanticinterior divide. In late Pliocene(?) time, areas adjacent to parts of the West Branch Susquehanna River-and probably elsewhere-had a moderate relief ranging from 300 to 700 feet. Some segments of the West Branch meandered across a broad valley that lay about 900 feet above the present streams. The landscape probably was covered by deep residual soils, perhaps by saprolite. The early Pleistocene history of Potter County is essentially unknown. No deposits of the Kansan stage are known except for a possible trace of pre-Illinoian drift on the uplands in central Potter County (Ayers Hill quadrangle). Some deposits in central and eastern Pennsylvania may be of Kansan age. It is probable that the assumed Aftonian regolith was removed by mass movements and other processes during the Kansan stage, thus resulting in a lowering of the plateau tops by as much as 10 feet. By the close of the Yarmouth(?) interglacial stage the major streams were incised to essentially their present depths. The climates of the Yarmouth interglacial stage probably produced deep residual soils over the landscape, parts of which may still be preserved in the paleosol remnants of the present day. No Illinoian drift is known in Potter County, but drift assigned to this stage occurs in areas to the northwest and to the southeast. Some valleys, such as Kettle Creek valley, were filled with sand and gravel alluvium to depths of as much as 150 feet above their present flood plains. It is assumed that the Yarmouth residual soils were removed by mass movements and other processes induced by a periglacial climate, thus lowering the plateau tops by as much as 10 feet. During the Sangamon interglacial stage, deep (10-to-20 foot) residual soils or paleosol were developed in Potter County and probably throughout much of Pennsylvania, perhaps as a result of lateritic weathering in a subtropical climate. It is possible that the paleosol was largely removed by mass movements and by running water during late Sangamon time. During either the Iowan or Tazewell substages of the Wisconsin (perhaps the Iowan), the ice sheet advanced into the northeastern part of Potter County. The drift is similar to the Olean drift (local usage). The paleosol was almost completely removed by mass movements and other processes induced· by a periglacial climate, prior to drift deposition. This removal probably resulted in a lowering of the plateau tops by as much as 10 feet since Sangamon time. Nearly contemporaneously with drift deposition, the periglacial deposits were formed by frost heaving, solifluction, and fluvial transport in areas outside the drift border. Soil structures or patterned ground were developed on both the drift and the periglacial deposits. It is probable that the forests in the periglacial area were greatly restricted and that large areas on the uplands were essentially treeless. Little is known about the history of Potter County in postOlean time. Presumably, forests completely covered the county by the onset of the next substage, during which the Binghamton drift of MacClintock and Apfel was deposited. This drift also is found in southern New York State. The formation of the alluvium and alluvial fans probably began in the Tazewell substage and continued during the Recent epoch. Since these deposits were formed there has been very little dissection. There is little, if any, difference between soils developed on periglacial deposits and soils developed on drift. The roots of fallen trees have disturbed the soil horizons, and it is unlikely that the existing soil profiles are more than 500 years old. The forested landscape of Potter County has a distinctive microrelief ranging from a few inches to a few feet of mounds and pits produced by the roots of fallen trees. Most mounds and pits range from 10 to 20 feet in length and from 6 to 15 feet in width. On level land, many mounds are oriented with their long axes trending northward, and in some areas the orientation is random. On slopes, the mounds are oriented with their long axes at right angles to the maximum slope as a result of trees falling downslope. The toppling of trees increases the permeability of surficial deposits and mixes and destroys the soil horizons. The microrelief is a factor in forest development. The toppling of trees on slopes is a significant agent of slope erosion. The process loosens, breaks up, or overturns the upper 2 to 3 feet of the forest soil, and it tends to make the surficial layer more stony and to produce features resembling soil structures.

Pennsylvania↗

Late Quaternary eolian and alluvial response to paleoclimate, Canyonlands, southeastern Utah

In upland areas of Canyonlands National Park, Utah, thin deposits and paleosols show late Quaternary episodes of eolian sedimentation, pedogenesis, and climate change. Interpretation of the stratigraphy and optically stimulated luminescence ages of eolian and nearby alluvial deposits, their pollen, and intercalated paleosols yields the following history: (1) Eolian deposition at ca. 46 ka, followed by several episodes of alluviation from some time before ca. 40 ka until after 16 ka (calibrated). (2) Eolian deposition from ca. 17 ka to 12 ka, interrupted by periods of pedogenesis, coinciding with late Pleistocene alluviation as local climate became warmer and wetter. (3) A wetter period from 12 to 8.5 ka corresponding to the peak of summer monsoon influence, during which soils formed relatively quickly by infiltration of eolian silt and clay, and trees and grasses were more abundant. (4) A drier period between ca. 8.5 and 6 ka during which sheetwash deposits accumulated and more desertlike vegetation was dominant; some dunes were reactivated at ca. 8 ka. (5) Episodic eolian and fluvial deposition during a wetter, cooler period that began at ca. 6 ka and ended by ca. 3-2 ka, followed by a shift to drier modern conditions; localized mobilization of dune sand has persisted to the present. These interpretations are similar to those of studies at the Chaco dune field, New Mexico, and the Tusayan dune field, Arizona, and are consistent with paleoclimate interpretations of pollen and packrat middens in the region. A period of rapid deposition and infiltration of eolian dust derived from distant igneous source terranes occurred between ca. 12 and 8 ka. Before ca. 17 ka, and apparently back to at least 45 ka, paleosols contain little or no such infiltrated dust. After ca. 8 ka, either the supply of dust was reduced or the more arid climate inhibited translocation of dust into the soils. ?? 2005 Geological Society of America.

Geological Society of America Bulletin↗

Benthic foraminifera from a relict flood tidal delta along the Virginia/North Carolina Outer Banks

Examination of benthic foraminifera from six vibracores collected from a relict flood tidal delta near the Virginia/North Carolina border documents the assemblages associated with a former inlet and provides geologic evidence of this former inlet that once defined the boundary between Virginia and North Carolina along the Outer Banks. Three distinct foraminiferal assemblages were identified. The oldest assemblage contained abundant and diverse forms, dominated by Elphidium excavatum and several other calcareous species typical of shallow nearshore areas. Sediment immediately below and above this diverse calcareous assemblage was barren or nearly barren of foraminifera. A medium-salinity agglutinated marsh assemblage characterized mainly by Trochammina inflata with fewer Tiphotrocha comprimata overlies the uppermost barren unit. The core top assemblage was dominated by low-salinity marsh species Jadammina macrescens, Miliammina petila and Miliammina fusca. A comparison of these vertically-stacked assemblages with the modern geographic distribution of assemblages in the Outer Banks estuarine system and on the nearby continental shelf reveals a succession of depositional environments proceeding from estuarine and flood tidal delta to medium salinity marsh to lower salinity marsh. These changes in depositional environments reflect a rapid and dramatic increase in salinity caused by the opening of an inlet followed by a gradual decrease in salinity due to inlet shoaling and eventual marsh colonization of the flood tidal delta. These changes cannot be determined through sedimentological studies alone; micropaleontological analysis is required. We conclude this distinctive trend of changing depositional environments constitutes paleontological evidence of the origin and evolution of Old Currituck Inlet that breached the barrier spit prior to 1585AD, actively built a flood tidal delta for more than 145 years, and then closed in 1731AD allowing the flood tidal delta to become colonized by marsh species.

North Carolina, Virginia↗

Major hydrostratigraphic contacts of the Truxton basin and Hualapai Plateau, northwestern Arizona, developed from airborne electromagnetic data

The area surrounding the Grand Canyon has spectacular outcrop exposure in the modern canyon walls, leading to stratigraphic contact delineations that are well constrained near canyons yet poorly constrained where the terrain remains undissected and relatively unexplored by boreholes. An airborne electromagnetic and magnetic survey of the western Hualapai Indian Reservation and surrounding areas was undertaken to support the development of a three-dimensional hydrostratigraphic framework of the Truxton basin and Hualapai Plateau. These data were used to develop models of the resistivity structure with total depths of investigation ranging from 200 meters in the most conductive parts of the Truxton basin to more than 600 meters in the higher resistivity areas underlying the Hualapai Plateau. The modeled resistivity structure was used in conjunction with geologic maps, well lithologic records, and results from gravity models of the depth to bedrock to develop high-resolution regional interpretations of the elevation of the Muav Limestone-Bright Angel Shale contact and the top of the crystalline basement. These contacts are conceptualized to serve as the base of the Paleozoic limestone aquifers primarily underlying the Hualapai Plateau and the Tertiary-Quaternary sedimentary and volcanic aquifers of the Truxton basin, respectively.

Arizona↗

Sedex hydrothermal systems triggered upheavals to marine chemistry and mass extinctions: Applications for ore genesis research and mineral exploration

New USGS research reveals that the discharge of metal-rich brine that formed sedex deposits on ancient seafloors had profound effects on global ocean chemistry and biologic evolution. For example, brine expulsion caused short-duration positive excursions (“spikes”) in the global marine Sr isotope record. While these spikes are unexplained by conventional oceanic models, our chronostratigraphic correlations of major sedex events, combined with mass balance evidence and oceanographic modeling, confirm that the flux of radiogenic Sr from sedex brines during ore formation was sufficient to cause these once enigmatic 87Sr/86Sr spikes. Recognition that the timing of peak 87 Sr/ 86 Sr spikes correlates exactly with global δ 13 C (and δ 18 O) spikes, climate change, deposition of metal-rich black shales and ironstones, metal-induced malformation (teratology) of marine organisms, and mass extinctions, establishes a causal relationship between sedex deposits and these dramatic events in earth history. The relationships among these features are not fully understood. However, our new model demonstrates that the flux of key biolimiting nutrients and metals contained in sedex brines exceeds that of the total modern riverine flux to the ocean. Undoubtably, these immense nutrient fluxes spurred ocean eutrophication, which, ultimately, through a series of positive feedback mechanisms, may be a previously unrecognized trigger of global ocean anoxic events (OAEs) that produced these chemical and biological perturbations. A derivative result from this integrative research is the recognition that OAEs resulted in the formation of “bathtub rim” deposits at redox boundaries along continental margins that concentrated various redox sensitive critical minerals. For example, we have identified midcontinent phosphorite deposits that contains heavy REE grades and tonnages that rival any REE deposit in the world. The recognition that sedex-forming fluid expulsion events are recorded in the global marine isotopic, geologic, and biological records, defines a new approach to the study of and exploration for sedex deposits. Traditional ore genesis research, coupled with chronostratigraphic correlation and high-resolution 87 Sr/ 86 Sr isotope chemostratigraphy can be used to answer long-standing questions about geologic processes responsible for formation of these extraordinary deposits. This approach allows us to constrain, for the first time, the age, duration, and fluxes of fluids and metals vented into the ocean by these giant hydrothermal systems. Accordingly, the fact that large mineralizing events are recorded in the marine sedimentary record opens the tantalizing prospect that we have the ability to conduct effective resource assessments and define prospective basins anywhere in the world. This innovative approach allows for identification of favorable stratigraphic ages and basins and remote evaluation of the size (and, thus, the mineral potential) of undiscovered mineral deposits. This methodology could be applied on regional basin-wide assessments, to evaluate sedimentary basin prospectivity, resource favorability of specific horizons therein, and to the evaluation of the potential of early-stage prospects.

Geological Society of Nevada Newsletter↗

Quantitative mineralogy of surface sediments of the Iceland shelf, and application to down-core studies of holocene ice-rafted sediments

Quantitative X-ray diffraction analyses on the < 2 mm sediment fraction from the Iceland shelves are reported for subglacial diamictons, seafloor surface sediments, and the last 2000 cal yr BP from two cores. The overall goal of the paper is to characterize the spatial variability of the mineralogy of the present-day surface sediments (18 non-clay minerals and 7 clay minerals), compare that with largely in situ erosional products typified by the composition of subglacial diamictons, and finally examine the late Holocene temporal variability in mineral composition using multi-mineral compositions. The subglacial diamictons are dominated in the non-clay-mineral fraction by the plagioclase feldspars and pyroxene with 36.7 ?? 6.1 and 17.9 ?? 3.5 wt % respectively, with smectites being the dominant clay minerals. The surface seafloor sediments have similar compositions although there are substantial amounts of calcite, plus there is a distinct band of sites from NW to N-central Iceland that contain 1-6 wt% of quartz. This latter distribution mimics the modern and historic pattern of drift ice in Iceland waters. Principal component analysis of the transformed wt% (log-ratio) non-clay minerals is used to compare the subglacial, surface, and down-core mineral compositions. Fifty-eight percent of the variance is explained by the first two axes, with dolomite, microcline, and quartz being important "foreign" species. These analyses indicate that today the NW-N-central Iceland shelf is affected by the import of exotic minerals, which are transported and released from drift ice. The down-core mineralogy indicates that this is a process that has varied over the last 2000 cal yr BP. Copyright ?? 2007, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

An assessment of seismic monitoring in the United States; requirement for an Advanced National Seismic System

This report assesses the status, needs, and associated costs of seismic monitoring in the United States. It sets down the requirement for an effective, national seismic monitoring strategy and an advanced system linking national, regional, and urban monitoring networks. Modernized seismic monitoring can provide alerts of imminent strong earthquake shaking; rapid assessment of distribution and severity of earthquake shaking (for use in emergency response); warnings of a possible tsunami from an offshore earthquake; warnings of volcanic eruptions; information for correctly characterizing earthquake hazards and for improving building codes; and data on response of buildings and structures during earthquakes, for safe, cost-effective design, engineering, and construction practices in earthquake-prone regions.

Circular↗

Synthesis of the paleoclimatic record from Owens Lake core OL-92

During much of the late Quaternary, Owens Lake overflowed into one or more of four successively lower-elevation basins. Most of the water came from the high, eastern slopes of the southern Sierra Nevada, and changes in the volumes of that water reflect a dominant climatic cycle of ~100 k.y. Variations in the inflow to, and outflow from, Owens Lake since ca. 800 ka left biological, chemical, mineralogical, and geophysical evidence in the sediments of those changes. Biological evidence includes fossil ostracodes, diatoms, fish, and mollusks (and δ 18 O data from their shells) which indicate fresh or brackish lake water on the basis of their modern habitats. Fossil pollens indicate ~20 regional vegetation cycles during the same period. Chemical evidence of high inflow and, commonly, outflow volumes is provided by the low inorganic- and organic-C content of some sediments, reflecting short lake-water residence times; long residence times produced higher and more variable quantities of these components. Mineralogical variations in illite/smectite ratios indicate changes in weathering processes and glacial comminution. High magnetic susceptibility correlates with other criteria that indicate high runoff. Between 810 ka and 645 ka, Owens Lake was fresh, several meters deep, and depositing silt with a few beds of sand; it supported a flora and fauna now found in fresh, sometimes very cool, waters. (Note that most geologic ages describing the OL-92 chronology have been rounded to the nearest 5 or 10 ka.) A shallow-but-freshwater lake may have been the result of accelerated sedimentation during an earlier (>800 ka) glaciation in the Sierra Nevada, choking the basin with sediment nearly to its spillway level. Between 645 ka and 450 ka, the lake was probably even shallower, depositing beds of coarse to fine sand, but overflowing periodically allowing its water to remain fresh. Between 450 ka and 5 ka, Owens Lake was mostly deep, alternating between spilling and being closed part of the time. It deposited silt and clay on its floor, yet underwent detectable variations in salinity caused by climate changes; this part of the record is the most easily interpreted and constitutes the main basis for comparing this paleoclimatic record with other long records. From 5 ka to A.D. 1913, when the Owens River was diverted into an aqueduct, Owens Lake was shallow (~2 m to ~15 m), moderately saline (~5% to <15% salts), and depositing oolites. After 1913, the lake desiccated. Comparison of the Owens Lake water-depth record with that of Searles Lake, two-basins downstream during much of late Pleistocene time, shows that they underwent similar responses to climate, but sedimentation changes documenting those responses commenced thousands of years apart, apparently because changes in precipitation volumes occurred gradually. Owens Lake, at the base of high mountains, was the first to reflect increasing amounts of regional precipitation; Searles, in a more arid environment, was the first to reflect decreasing amounts of precipitation. Devils Hole, 150 km east of Owens Lake, has a well dated isotopic-temperature record that resembles the Owens Lake-depth record. Marine records of Pleistocene glacial fluctuations, which measure high-latitude ice-sheet volumes and thus both precipitation and temperature at those latitudes, also resemble the Owens Lake history. There are, however, differences between the ages of the maxima and minima of climatic events as reconstructed from the Owens Lake core and similar-appearing inflections in the other two records; the differences range from 0 to 33 k.y. and average ~15 k.y. The question arises whether the differences between those ages are results of errors in the time-scale used for the Owens Lake record, or were there significant differences in the times when atmospheric climate change began to affect its different elements. The three records compared here are measurements of different elements and combinations of elements in two latitude belts: the deep-sea marine records measure combinations of temperature and precipitation that determined global ice volumes (at mostly high latitudes), the Devils Hole record measures atmospheric temperatures (in its mid-latitude region), and the Owens Lake record measures effective precipitation (in the same mid-latitude region).

California↗

Geologic map of northeastern Seattle (part of the Seattle North 7.5' x 15' quadrangle), King County, Washington

This geologic map, approximately coincident with the east half of the Seattle North 7.5 x 15’ quadrangle (herein, informally called the “Seattle NE map”), covers nearly half of the City of Seattle and reaches from Lake Washington across to the Puget Sound shoreline. Land uses are mainly residential, but extensive commercial districts are located in the Northgate neighborhood, adjacent to the University of Washington, and along the corridors of Aurora Avenue North and Lake City Way. Industrial activity is concentrated along the Lake Washington Ship Canal and around Lake Union. One small piece of land outside of the quadrangle boundaries, at the west edge of the Bellevue North quadrangle, is included on this map for geographic continuity. Conversely, a small area in the northeast corner of the Seattle North quadrangle, on the eastside of Lake Washington, is excluded from this map. Within the boundaries of the map area are two large urban lakes, including the most heavily visited park in the State of Washington (Green Lake Park); a stream (Thornton Creek) that still hosts anadromous salmon despite having its headwaters in a golfcourse and a shopping center; parts of three cities, with a combined residential population of about 300,000 people; and the region’s premier research institution, the University of Washington. The north boundary of the map is roughly NE 168th Street in the cities of Shoreline and Lake Forest Park, and the south boundary corresponds to Mercer Street in Seattle. The west boundary is 15th Avenue W (and NW), and the east boundary is formed by Lake Washington. Elevations range from sea level to a maximum of 165 m (541 ft), the latter on a broad till-covered knob in the city of Shoreline near the northwest corner of the map. Previous geologic maps of this area include those of Waldron and others (1962), Galster and Laprade (1991), and Yount and others (1993). Seattle lies within the Puget Lowland, an elongate structural and topographic basin between the Cascade Range and Olympic Mountains. The Seattle area has been glaciated repeatedly during the past two million years by coalescing glaciers that advanced southward from British Columbia. The landscape we see today was molded by cyclic glacial scouring and deposition and later modified by landsliding and stream erosion. The last ice sheet reached the central Puget Sound region about 14,500 years ago, as measured by 14 C dating, and it had retreated from this area by 13,650 14 C yr B.P. (equivalent calendar years are about 17,600 and 16,600 years ago; Porter and Swanson, 1998). Seattle now sits atop a complex and incomplete succession of interleaved glacial and nonglacial deposits that overlie an irregular bedrock surface. These glacial and nonglacial deposits vary laterally in both texture and thickness, and they contain many local unconformities. In addition, they have been deformed by faults and folds, at least as recently as 1,100 years ago, and this deformation further complicates the geologic record. The landforms and near-surface deposits that cover much of the Seattle NE map area record a relatively brief, recent interval of the region’s geologic history. The topography is dominated in the north by a broad, fluted, and south-sloping upland plateau, which gives way to a more complex set of elongated hills in the map’s southern half. The valleys of Pipers Creek, Green Lake, and Thornton Creek mark the transition between these two topographic areas. Most of the uplands are mantled by a rolling surface of sand (unit Qva) and till (unit Qvt) deposited during the last occupation of the Puget Lowland by a continental ice sheet. Beneath these ice sheet deposits is a complex succession of older sediments that extends far below sea level across most of the map area. These older sediments are now locally exposed where modern erosion and landslides have sliced through the edge of the upland, and where subglacial processes apparently left these older sediments largely free of overlying sediments. Lack of overlying sediments is particularly evident on the hillslopes above Thornton Creek, adjacent to Lake Washington, and on the flanks of Capitol Hill.

Washington↗

Geochemistry of amino acids in shells of the clam Saxidomus

Concentrations of amino acids and their corresponding d l "> dl enantiomeric ratios have been measured in shells of the bivalve mollusk Saxidomus from eleven localities, ranging in age from modern to probably more than 500,000 yr, along the Pacific coast of North America. Natural logarithms of amino acid concentrations correlate well with d l "> dl ratios, and the relationship provides a possible guide to the selection of fossils for use in amino acid dating. The relative order of the extents of racemization of amino acids at any given time appears to change with increasing sample age. Application of the amino acid dating method to shells from Whidbey Island, Washington, yields an age of about 80,000 yr, in contrast to the previously determined radiocarbon age of 36,000 yr which was measured on some shell carbonate and considered a minimum age. The amino acid age is compatible with the geologic record in the area.

Alaska, Washington↗

Santa Barbara and Foothill groundwater basins Geohydrology and optimal water resources management—Developed using density dependent solute transport and optimization models

Groundwater has been a part of the city of Santa Barbara’s water-supply portfolio since the 1800s; however, since the 1960s, the majority of the city’s water has come from local surface water, and the remainder has come from groundwater, State Water Project, recycled water, increased water conservation, and as needed, seawater desalination. Although groundwater from the Santa Barbara and Foothill groundwater basins only accounts for a small percentage of the long-term supply, it is an important source of supplemental water during times of surface-water shortages. During the late 1980s and early 1990s, production wells extracted additional groundwater to compensate for drought related water-delivery shortfalls from other sources; in response, water levels declined substantially in the Santa Barbara and Foothill groundwater basins (below sea level in the Santa Barbara groundwater basin). In coastal basins that have groundwater extraction near shore, seawater intrusion is often a problem. Seawater intrusion in the Santa Barbara groundwater basin is thought to be more limited than in other coastal basins because of an offshore fault that acts as a partial barrier to groundwater flow. During the late 1980s and early 1990s, seawater intrusion was observed in the Santa Barbara groundwater basin, as indicated by increased chloride concentrations at several monitoring wells that ranged from 200 ft to 1,300 ft from the ocean and as close as 2,900 ft to the nearest pumping well. This demonstrated that seawater can intrude into the Santa Barbara groundwater basin when groundwater levels fall below sea level near the coast. The city of Santa Barbara is interested in developing a better understanding of the sustainability of its groundwater supplies. In 2014, California adopted historic legislation to manage its groundwater: the Sustainable Groundwater Management Act (SGMA). The SGMA requires the development and implementation of “Groundwater Sustainability Plans” in 127 priority groundwater basins; although Santa Barbara was not a designated priority basin, the city is taking steps to achieve sustainability. Sustainability was defined in the SGMA in terms of avoiding undesirable results: significant and unreasonable groundwater-level declines, reduction in groundwater storage, seawater intrusion, water-quality degradation, land subsidence, and surface-water depletion. In this project, a cooperative study between the U.S. Geological Survey (USGS) and the city of Santa Barbara, sustainable yield is defined as the volume of groundwater that can be pumped from storage without causing water-level drawdowns and the associated increases in seawater intrusion (as indicated by increases in measured chloride concentrations) at selected wells. In order to estimate the sustainability of Santa Barbara’s groundwater basins, a three-dimensional density-dependent groundwater-flow and solute-transport model (the Santa Barbara Flow and Transport Model, or SBFTM) was developed on the basis of an existing groundwater-flow model. To simulate seawater intrusion to the Santa Barbara Basin under various management strategies, the SBFTM uses the USGS code SEAWAT to simulate salinity transport and variable-density flow. The completed SBFTM was coupled with a management optimization tool, in this case a multi-objective evolutionary algorithm, to determine optimal pumping strategies that maximize the sustainable yield and at the same time satisfy user-defined drawdown and chloride-concentration constraints. As part of this study, a three-dimensional hydrogeologic framework model was developed to quantify the extent and hydrogeologic characteristics of the Santa Barbara and Foothill groundwater basins and to help define the discretization and hydraulic properties used in the SBFTM. The development of the hydrogeologic framework model required the collection and reconciliation of geologic and geophysical data from existing maps, reports, and databases, along with geologic and hydrologic data from recently drilled wells. These data were integrated into a three-dimensional hydrogeologic framework model that defines the stratigraphy and geometry of the aquifer zones and the major geologic structures in the basin. The hydrogeologic framework model also quantifies the variation in sediment grain size within each aquifer zone as the percentage of coarse-grained sediment. Previous studies indicated that there are two principal water-producing zones in the Santa Barbara groundwater basin, the upper and lower producing zones; an additional thin, productive zone was identified as part of this study. This “middle producing zone” is not as areally extensive as the upper and lower producing zones and only exists in the coastal part of Storage Unit I. These producing zones are bounded at depth by less productive shallow, middle, and deep zones. Two versions of the SBFTM were constructed: an initial-condition model and a modern transient model. The initial-condition model is a long-term transient model that simulates flow and solute-transport conditions during a period with limited anthropogenic influences preceeding the modern transient model. The simulation-transient model simulates flow and transport conditions from 1929 through 2013; however, because of data availability, the focus of the model calibration was 1972–2013. The SBFTM was calibrated to measured groundwater levels and drawdown, as well as measured chloride concentrations and change in concentrations, using a combination of automated and trial-and-error parameter-estimation techniques. A sensitivity analysis indicated that, in general, the SBFTM was most sensitive to recharge- and pumping-distribution parameters, specifically those controlling the amount of small-catchment recharge and the distribution of water extraction by hydrogeologic layer for production wells. The model was also sensitive to parameters controlling stream-recharge rates, horizontal and vertical hydraulic conductivity, and porosity. From 1929 to 1971, most of the water entering the area represented by the SBFTM was from creek and small-catchment recharge, and the majority of water leaving the SBFTM area was from pumping, discharge to creeks, and drains. In addition, about 37 percent of the total pumpage came from a net reduction in groundwater storage. From 1972 to 2013, the amount of water entering and leaving the SBFTM was fairly similar as that from 1929 to 1971, except the reduction in pumpage added about 17,000 acre-ft of water to storage. During this later period, there were also times of storage loss. For example, during July 1990, a month when approximately 705 acre-ft of groundwater was pumped in the study area, the pumpage was much greater than all sources of recharge combined, and about 382 acre-ft of water was removed from groundwater storage. Simulated hydraulic heads replicated the observed data to an acceptable matching of the measured water-level, flow direction, and vertical gradients. Simulated hydrographs for selected wells were in good agreement with the measured data, with an average residual of -2.7 ft and a standard deviation of 14.5 ft, indicating that the simulated heads, on average, underestimated the observed water levels. An examination of the model fit indicated that most of the discrepancies were lower simulated heads at wells proximal to production well sites. The simulated chloride concentrations reasonably matched the rising limbs of the measured breakthrough curves in terms of timing and magnitude; however, the simulation overestimated the chloride concentrations on the falling limbs. The overestimation of low chloride concentrations was attributed to the model overestimating the advance of the chloride front during periods of heavy pumping and underestimating the retreat of the chloride front during periods of low pumping. These simulation errors would result in a conservative response by local water managers to seawater intrusion. The SBFTM was used to develop a collection of predictive simulations optimized to produce pumping schedules that maximize yield, subject to a set of constraints and competing objectives. The simulations were grouped as scenarios that differed in their time horizon, initial conditions for groundwater levels and chloride concentrations, as well as precipitation, which was incorporated into the model through simulated recharge. Overall, five scenarios were developed in a multi-objective framework to obtain optimal pumping rates for all of the wells managed by the city, while minimizing excessive drawdown and seawater intrusion. For the current study, complexities in the simulation model and the optimization formulation required additional considerations. Incorporating the solute-transport equations to simulate chloride transport added a highly nonlinear process that is solved iteratively in each time step of the groundwater-flow model. These nonlinearities, coupled with the highly refined grid in the current model, creates challenges for many traditional optimization methods. Therefore, an optimization method was needed that could address nonlinear relationships as well as a very large problem size. Lastly, the optimization problem was reformulated to include multiple objectives without requiring convergence to a single solution. This approach, guided by the city’s objectives, allowed the maximum extraction of information from the complex simulation. Borg, a multi-objective evolutionary algorithm, was chosen as the optimization algorithm for this study for several reasons: (1) it is very computationally efficient; (2) it can run in parallel; (3) it requires little user input; and (4) it can solve for multiple competing objectives. The first three points allow the algorithm to proceed toward the optimal solutions at the fastest possible rate. The fourth point is advantageous for large, complex optimization problems because it is difficult to formulate the optimization problem in a way that produces only one optimal solution. The problem formulation consisted of four competing objectives and a constraint set in accordance with the main concerns of the city. The objectives were maximizing total pumpage, minimizing seawater intrusion, minimizing total drawdown in production wells, and minimizing the maximum drawdown. The constraints were pump capacity, meeting drinking-water standards for chloride, maintaining a specified minimum flowrate to a groundwater treatment plant, and maintaining minimum water levels in pumping wells. The decision variables either were quarterly pumpage by well or total pumpage by basin. Five optimization scenarios were developed that allow the decision makers to evaluate a range of optimal solutions for a variety of water levels and chloride concentrations as well as potential future climatic conditions. Three scenarios (1, 2, and 5) were multi-objective optimization formulations that allowed for variations in management preferences and climatic conditions. The other two scenarios (3 and 4) were designed to examine the optimization results to answer specific questions. Scenario 1 described the best-case sustainable yield assuming a “full” basin (that is, high initial water levels) and typical climate conditions for 10 years. Scenario 2 also started with a “full” basin; however, this was followed by a 10-year drought. Scenario 3 determined if an “empty” basin (that is, low initial water levels) would recover to full conditions (1998 conditions) given climate assumptions and optimal pumping schedules from scenarios 1 and 2. Scenario 4 was designed to produce decision rules that can be used by water managers to help choose an optimal pumping schedule based on measured water-level or chloride data. Scenario 5 identified future pumping schedules based on short-term climate variations during a 2-year management horizon. The results from scenarios 1 and 2 described the differences in maximum pumpage in the basin under typical and dry long-term climate projections, respectively. The scenario 1 results indicated the maximum 10-year pumpage of the basin was about 31,300 acre-ft under typical conditions and controlling simulated seawater intrusion and drawdowns. For scenario 2, less recharge over the 10-year dry climate produced a maximum pumpage estimate of 30,000 acre-ft to control seawater intrusion and drawdowns. The larger pumpage for scenario 1 resulted in more seawater intrusion, but less total drawdown, compared to that of scenario 2. Results for scenarios 3 and 4 showed the basin’s response to management actions combined with climate projections. Both scenarios used the optimal pumping schedules and the 10-year climates from scenarios 1 and 2. The scenario 3 results showed that under minimal pumping, the basin did not fully recover to 1998 water levels within 10 years under either climate scenario. The relatively larger recharge from the typical climate resulted in less drawdown at coastal monitoring wells after the 10-year recovery period than that from the dry climate. The location of the seawater intrusion front was not appreciably different between the scenarios, however. Scenario 4 used the optimal results from scenarios 1 and 2 to produce decision-rule curves that illustrated the pumpage for each basin, given measured levels of chloride concentration or drawdown. This allowed the use of additional measurements at monitoring wells to assess future management decisions on the basis of the sensitivity of observations of drawdown and seawater intrusion to various pumping rates. Scenario 5 allowed managers to investigate the effects of short-term climate variations on optimal pumping schedules. Three specific 2-year simulations were optimized: typical-to-dry (scenario 5A), dry-to-typical (scenario 5B), and dry-to-dry (scenario 5C). The most noteable result from scenario 5 was the overall reduction in optimal pumpage for most schedules in scenario 5C, when the climate is simulated as dry-to-dry. There are also many optimal pumping schedules that produced an overall increase in waterlevels over the two-year simulation period, regardless of climatic condition. Similar to scenario 2, the scenario 5C results represents conservative yield estimates under a minimal-precipitation climatic condition.

California↗

Geologic map of the southern Stillwater Range, Nevada

The southern Stillwater Range in west-central Nevada contains the western part of the Oligocene Stillwater-Clan Alpine caldera complex, which extends about 55 kilometers (km) east from the west side of the Stillwater Range to the northwestern Desatoya Mountains. The complex consists of at least seven nested ignimbrite calderas and subjacent plutonic rocks emplaced into a complex basement composed of Mesozoic metasedimentary and metavolcanic rocks and Cretaceous granitic plutons. The calderas formed during large-volume (100s to greater than (>) 2,500 cubic kilometers [km 3 ]) eruptions of silicic ignimbrites between about 30.4 and 25.1 million years before present (Ma). The Job Canyon and Poco Canyon calderas and the western part of the much larger Elevenmile Canyon caldera, and their plutonic roots, are exposed in the southern Stillwater Range. There, the caldera complex was steeply tilted during large-magnitude crustal extension in the middle Miocene, and further exhumed during the late Miocene to Holocene Basin and Range extension that formed the modern Stillwater Range. This tilted crustal section affords an exceptional opportunity to view structural cross sections of ignimbrite calderas and their plutonic roots to paleodepths as much as 9–10 km.

Nevada↗

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth↗

An improved understanding of the Alaska coastal current: The application of a bivalve growth-temperature model to reconstruct freshwater-influenced paleoenvironments

Shells of intertidal bivalve mollusks contain sub-seasonally to interannually resolved records of temperature and salinity variations in coastal settings. Such data are essential to understand changing land-sea interactions through time, specifically atmospheric (precipitation rate, glacial meltwater, river discharge) and oceanographic circulation patterns; however, independent temperature and salinity proxies are currently not available. We established a model for reconstructing daily water temperatures with an average standard error of ???1.3 ??C based on variations in the width of lunar daily growth increments of Saxidomus gigantea from southwestern Alaska, United States. Temperature explains 70% of the variability in shell growth. When used in conjunction with stable oxygen isotope data, this approach can also be used to identify changes in past seawater salinity. This study provides a better understanding of the hydrological changes related to the Alaska Coastal Current (ACC). In combination with ??18Oshell values, increment-derived temperatures were used to estimate salinity changes with an average error of 1.4 ?? 1.1 PSU. Our model was calibrated and tested with modern shells and then applied to archaeological specimens. As derived from the model, the time interval of 988-1447 cal yr BP was characterized by ???1-2 ??C colder and much drier (2-5 PSU) summers. During that time, the ACC was likely flowing much more slowly than at present. In contrast, between 599-1014 cal yr BP, the Aleutian low may have been stronger, which resulted in a 3 ??C temperature decrease during summers and 1-2 PSU fresher conditions than today; the ACC was probably flowing more quickly at that time. The shell growth-temperature model can be used to estimate seasonal to interannual salinity and temperature changes in freshwater-influenced environments through time. ?? 2011 SEPM (Society for Sedimentary Geology).

Palaios↗

Groundwater quality in the Western San Joaquin Valley study unit, 2010: California GAMA Priority Basin Project

Water quality in groundwater resources used for public drinking-water supply in the Western San Joaquin Valley (WSJV) was investigated by the USGS in cooperation with the California State Water Resources Control Board (SWRCB) as part of its Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The WSJV includes two study areas: the Delta–Mendota and Westside subbasins of the San Joaquin Valley groundwater basin. Study objectives for the WSJV study unit included two assessment types: (1) a status assessment yielding quantitative estimates of the current (2010) status of groundwater quality in the groundwater resources used for public drinking water, and (2) an evaluation of natural and anthropogenic factors that could be affecting the groundwater quality. The assessments characterized the quality of untreated groundwater, not the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on data collected from 43 wells sampled by the U.S. Geological Survey for the GAMA Priority Basin Project (USGS-GAMA) in 2010 and data compiled in the SWRCB Division of Drinking Water (SWRCB-DDW) database for 74 additional public-supply wells sampled for regulatory compliance purposes between 2007 and 2010. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and SWRCB-DDW regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a spatially weighted, grid-based method to estimate the proportion of the groundwater resources used for public drinking water that has concentrations for particular constituents or class of constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale within the WSJV study unit, and permits comparison of the two study areas to other areas assessed by the GAMA Priority Basin Project statewide. Groundwater resources used for public drinking water in the WSJV study unit are among the most saline and most affected by high concentrations of inorganic constituents of all groundwater resources used for public drinking water that have been assessed by the GAMA Priority Basin Project statewide. Among the 82 GAMA Priority Basin Project study areas statewide, the Delta–Mendota study area ranked above the 90th percentile for aquifer-scale proportions of groundwater resources having concentrations of total dissolved solids (TDS), sulfate, chloride, manganese, boron, chromium(VI), selenium, and strontium above benchmarks, and the Westside study area ranked above the 90th percentile for TDS, sulfate, manganese, and boron. In the WSJV study unit as a whole, one or more inorganic constituents with regulatory or non-regulatory, health-based benchmarks were present at concentrations above benchmarks in about 53 percent of the groundwater resources used for public drinking water, and one or more organic constituents with regulatory health-based benchmarks were detected at concentrations above benchmarks in about 3 percent of the resource. Individual constituents present at concentrations greater than health-based benchmarks in greater than 2 percent of groundwater resources used for public drinking water included: boron (51 percent, SWRCB-DDW notification level), chromium(VI) (25 percent, SWRCB-DDW maximum contaminant level (MCL)), arsenic (10 percent, EPA MCL), strontium (5.1 percent, EPA Lifetime health advisory level (HAL)), nitrate (3.9 percent, EPA MCL), molybdenum (3.8 percent, EPA HAL), selenium (2.6 percent, EPA MCL), and benzene (2.6 percent, SWRCB-DDW MCL). In addition, 50 percent of the resource had TDS concentrations greater than non-regulatory, aesthetic-based SWRCB-DDW upper secondary maximum contaminant level (SMCL), and 44 percent had manganese concentrations greater than the SWRCB-DDW SMCL. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors, inferences from geochemical and age-dating tracer results, and by considering the water-quality results in the context of the hydrogeologic setting of the WSJV study unit. Natural factors, particularly the lithologies of the source areas for groundwater recharge and of the aquifers, were the dominant factors affecting groundwater quality in most of the WSJV study unit. However, where groundwater resources used for public supply included groundwater recharged in the modern era, mobilization of constituents by recharge of water used for irrigation also affected groundwater quality. Public-supply wells in the Westside study area had a median depth of 305 m and primarily tapped groundwater recharged hundreds to thousands of years ago, whereas public-supply wells in the Delta–Mendota study area had a median depth of 85 m and primarily tapped either groundwater recharged within the last 60 years or groundwater consisting of mixtures of this modern recharge and older recharge. Public-supply wells in the WSJV study unit are screened in the Tulare Formation and zones above and below the Corcoran Clay Member are used. The Tulare Formation primarily consists of alluvial sediments derived from the Coast Ranges to the west, except along the valley trough at the eastern margin of the WSJV study unit where the Tulare Formation consists of fluvial sands derived from the Sierra Nevada to the east. Groundwater from wells screened in the Sierra Nevada sands had manganese-reducing or manganese- and iron-reducing oxidation-reduction (redox) conditions. These redox conditions commonly were associated with elevated arsenic or molybdenum concentrations, and the dominance of arsenic(III) in the dissolved arsenic supports reductive dissolution of iron and manganese oxyhydroxides as the mechanism. In addition, groundwater from many wells screened in Sierra Nevada sands contained low concentrations of nitrite or ammonium, indicating reduction of nitrate by denitrification or dissimilatory processes, respectively. Geology of the Coast Ranges westward of the study unit strongly affects groundwater quality in the WSJV. Elevated concentrations of TDS, sulfate, boron, selenium and strontium in groundwater were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by Cretaceous-to-Miocene age, organic-rich, reduced marine shales, known as the source of selenium in WSJV soils, surface water, and groundwater. Low sulfur-isotopic values (δ34S) of dissolved sulfate indicate that the sulfate was largely derived from oxidation of biogenic pyrite from the shales, and correlations with trace element concentrations, geologic setting, and groundwater geochemical modeling indicated that distributions of sulfate, strontium, and selenium in groundwater were controlled by dissolution of secondary sulfate minerals in soils and sediments. Elevated concentrations of chromium(VI) were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by the Franciscan Complex and ultramafic rocks. The Franciscan Complex also has boron-rich, sodium-chloride dominated hydrothermal fluids that contribute to elevated concentrations of boron and TDS. Groundwater from wells screened in Coast Ranges alluvium was primarily oxic and relatively alkaline (median pH value of 7.55) in the Delta–Mendota study area, and primarily nitrate-reducing or suboxic and alkaline (median pH value of 8.4) in the Westside study area. Many groundwater samples from those wells have elevated concentrations of arsenic(V), molybdenum, selenium, or chromium(VI), consistent with desorption of metal oxyanions from mineral surfaces under those geochemical conditions. High concentrations of benzene were associated with deep wells located in the vicinity of petroleum deposits at the southern end of the Westside study area. Groundwater from these wells had premodern age and anoxic geochemical conditions, and the ratios among concentrations of hydrocarbon constituents were different from ratios found in fuels and combustion products, which is consistent with a geogenic source for the benzene rather than contamination from anthropogenic sources. Water stable-isotope compositions, groundwater recharge temperatures, and groundwater ages were used to infer four types of groundwater: (1) groundwater derived from natural recharge of water from major rivers draining the Sierra Nevada; (2) groundwater primarily derived from natural recharge of water from Coast Ranges runoff; (3) groundwater derived from recharge of pumped groundwater applied to the land surface for irrigation; and (4) groundwater derived from recharge during a period of much cooler paleoclimate. Water previously used for irrigation was found both above and below the Corcoran Clay, supporting earlier inferences that this clay member is no longer a robust confining unit. Recharge of water used for irrigation has direct and indirect effects on groundwater quality. Elevated nitrate concentrations and detections of herbicides and fumigants in the Delta–Mendota study area generally were associated with greater agricultural land use near the well and with water recharged during the last 60 years. However, the extent of the groundwater resource affected by agricultural sources of nitrate was limited by groundwater redox conditions sufficient to reduce nitrate. The detection frequency of perchlorate in Delta–Mendota groundwater was greater than expected for natural conditions. Perchlorate, nitrate, selenium, and strontium concentrations were correlated with one another and were greater in groundwater inferred to be recharge of previously pumped groundwater used for irrigation. The source of the perchlorate, selenium, and strontium appears to be salts deposited in the soils and sediments of the arid WSJV that are dissolved and flushed into groundwater by the increased amount of recharge caused by irrigation. In the Delta–Mendota study area, the groundwater with elevated concentrations of selenium was found deeper in the aquifer system than it was reported by a previous study 25 years earlier, suggesting that this transient front of groundwater with elevated concentrations of constituents derived from dissolution of soil salts by irrigation recharge is moving down through the aquifer system and is now reaching the depth zone used for public drinking water supply.

California↗

Seasonal variability in the surface sediments of Mobile Bay, Alabama, recorded by geochemistry and foraminifera, 2009–2010

A study was undertaken in order to document and quantify recent environmental change in Mobile Bay, Alabama. The study was part of the Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazard Susceptibility project, a regional project funded by the Coastal and Marine Geology Program to understand how natural forcings and anthropogenic modifications influence coastal ecosystems and their susceptibility to coastal hazards. Mobile Bay is a large drowned-river estuary that has been modified significantly by humans to accommodate the Port of Mobile. Examples include repeated dredging of a large shipping channel down the central axis of the bay and construction of a causeway across the head of the bay and at the foot of the bayhead delta. In addition to modifications, the bay is also known to have episodic periods of low oxygen (hypoxia) that result in significant mortality to fish and benthic organisms (May, 1973). For this study a series of surface sediment samples were collected. Surface benthic foraminiferal and bulk geochemical data provide the modern baseline conditions of the bay and can be used as a reference to changing environmental parameters in the past (Osterman and Smith, in press) and into the future. This report archives data collected as part of the Mobile Bay Study that may be used in future environmental change studies.

Alabama↗