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Guidelines and standard procedures for studies of ground-water quality; selection and installation of wells, and supporting documentation

This is the first of a two-part report to document guidelines and standard procedures of the U.S. Geological Survey for the acquisition of data in ground-water-quality studies. This report provides guidelines and procedures for the selection and installation of wells for water-quality studies/*, and the required or recommended supporting documentation of these activities. Topics include (1) documentation needed for well files, field folders, and electronic files; (2) criteria and information needed for the selection of water-supply and observation wells, including site inventory and data collection during field reconnaissance; and (3) criteria and preparation for installation of monitoring wells, including the effects of equipment and materials on the chemistry of ground-water samples, a summary of drilling and coring methods, and information concerning well completion, development, and disposition.

Water-Resources Investigations Report↗

Hydrogeologic data for the lower Connecticut River basin, Connecticut

This report contains geologic, ground-water, and miscellaneous data on the quality of surface water collected for a water-resources inventory of the lower Connecticut River basin, Connecticut. The study was made by the U.S. Geological Survey in fiscal cooperation with the Connecticut Department of Environmental Protection. A companion report (Connecticut Water Resources Bulletin No. 31, in preparation) interprets the factual information presented here or otherwise collected for the study.

Connecticut↗

Hydrogeologic data for the lower Connecticut River basin, Connecticut

This report contains geologic, ground-water, and miscellaneous data on the quality of surface water collected for a water-resources inventory of the lower Connecticut River basin, Connecticut. The study was made by the U.S. Geological Survey in fiscal cooperation with the Connecticut Department of Environmental Protection. A companion report (Connecticut Water Resources Bulletin No. 31, in preparation) interprets the factual information presented here or otherwise collected for the study.

Connecticut↗

Potential for using the Upper Coachella Valley ground-water basin, California, for storage of artificially recharged water

This report presents a preliminary evaluation of the geohydrologic factors affecting storage of water by artificial recharge in the upper Coachella Valley, Calif. The ground-water basin of the upper Coachella Valley seems to be geologically suitable for large-scale artificial recharge. A minimum of 900 ,000 acre-feet of water could probably be stored in the basin without raising basinwide water levels above those that existed in 1945. Preliminary tests indicate that a long-term artificial recharge rate of 5 feet per day may be feasible for spreading grounds in the basin if such factors as sediment and bacterial clogging can be controlled. The California Department of Water Resources, through the Future Water Supply Program, is investigating the use of ground-water basins for storage of State Water Project water in order to help meet maximum annual entitlements to water project contractors. (USGS)

Open-File Report↗

Interaction between ground water and surface water in Taylor Slough and vicinity, Everglades National Park, South Florida: Study methods and appendixes

The data presented in this report are products of an investigation that quantified interactions between ground water and surface water in Taylor Slough in Everglades National Park. Determining the extent of hydrologic interactions between wetland surface water and ground water in Taylor Slough is important because the balance of freshwater flow in the lower part of the Slough is uncertain. Although freshwater flows through Taylor Slough are quite small in comparison to Shark Slough (the larger of the two major sloughs in Everglades National Park), flows through Taylor Slough are especially important to the ecology of estuarine mangrove embayments of northeastern Florida Bay. Also, wetland and ground- water interactions must be quantified if their role in affecting water quality is to be determined. In order to define basic hydrologic characteristics of the wetland, depth of wetland peat was mapped, and hydraulic conductivity and vertical hydraulic gradients in peat were determined. During specific time periods representing both wet and dry conditions in the area, the distribution of major ions, nutrients, and water stable isotopes throughout the slough were determined. The purpose of chemical measurements was to identify an environmental tracer could be used to quantify ground-water discharge.

Florida↗

Ground water in the Raft River Basin, Idaho, with special reference to irrigation use, 1956-60

In the Raft River basin in south-central Idaho, ground-water withdrawals for irrigation have more than doubled since 1955, when data were compiled for a comprehensive report on the area. The present report summerizes data on the ground-water use and changes in the water regimen during the intervening 5 years. Water levels have declined 10 to 20 feet in the areas of heaviest pumping and 3 to 5 feet throughout the remainder of the area. These water-level declines are related to increased ground-water pumpage and below-normal precipitation in the basin. The total pumpage during the 1960 irrigation season is estimated to be about 127,000 acre-feet, of which about half was consumed by crops or evaporated. The remainder returned to the aquifer. Irrigation development is acting to reduce the amount of underflow out of the basin. The water table can be lowered considerably more before underflow from the basin would be reduced substantially.

Idaho↗

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin - Ground-water quality in three different land-use areas, 1996-98

The surficial sand and gravel aquifer is susceptible to effects from land-use in the Upper Mississippi River Basin study unit of the National Water-Quality Assessment (NAWQA) Program. The purpose of this report is to describe the ground-water quality and the assessment of how different land-uses affect the shallow ground-water quality in the surficial sand and gravel aquifer. Ground-water quality was compared in three different land-use areas; an urban residential/commercial area on the edge of the Anoka Sand Plain in a portion of the Twin Cities metropolitan area (urban study), an intensive agricultural area in the Anoka Sand Plain (agricultural study), and a forested area in the Bemidji-Bagley Sand Plain (forested study). Ground water was sampled and analyzed for about 200 constituents, including physical parameters, major ions, selected trace elements, nutrients, dissolved organic carbon, selected pesticides, selected volatile organic compounds (VOCs), and tritium. The urban study wells were sampled during June and July 1996. The agricultural study wells were sampled during May and September 1998. The forested study wells were sampled during June 1998. The depth to water below the land surface generally was less than 20 ft in all three land-use studies. The median pH value in the urban study was 7.2, with medians in the agricultural and forested studies at 7.4 and 7.5, respectively. The median specific conductance was significantly greater in the urban study than in the agricultural and forested studies (914, 553, and 487 µS/cm respectively). The median dissolved oxygen concentration in the urban study (0.9 mg/L) was significantly less than the median in the agricultural or forested studies (5.3 and 2.3 mg/L respectively). Alkalinities in the agricultural study, with a median of 178 mg/L as CaCO 3 , were significantly less than medians in the urban or forested studies (261 and 246 mg/L as CaCO 3 , respectively). The water composition in the surficial aquifer in all three land-use studies is dominated by calcium, magnesium, and bicarbonate. Sulfate and chloride concentrations in water samples were significantly greater in the urban study than in the agricultural or forested studies, and concentrations in the forested study were least. Most of the water samples in all three land-use studies were very hard (greater than 180 mg/L as CaCO 3 ). Nitrate-nitrogen concentrations were greatest in the agricultural study, in which 38 percent of water samples exceeded the U.S. Environmental Protection Agency’s maximum contaminant level (MCL) for nitrate-nitrogen. Nitrate-nitrogen was greater than the MCL in 3 percent of urban study samples. None of the forested study samples exceeded the MCL for nitrate-nitrogen. Concentrations of phosphorus generally were less than 0.05 mg/ L, with no significant differences between the land-uses. A total of 19 pesticides were detected in water samples from one or more land-use study wells, with 11 pesticides detected in the urban study, 14 detected in the agricultural study, and 4 detected in the forested study. Atrazine, deethylatrazine, and simazine were the only pesticides detected in all three land-use studies. A significantly greater percentage of pesticide detections were present in water samples from the agricultural study than from the urban or forested studies (86.2, 56.7, and 46.7 percent, respectively). Prometon was the most frequently detected pesticide in the urban study. Atrazine and deethylatrazine were the most frequently detected pesticides in the agricultural and forested studies. Twenty-one VOCs were detected in water samples from one or more land-use study wells, with 19 detected in the urban study, 7 detected in the agricultural study, and none detected in the forested study. Chloromethane, trichloromethane, methylbenzene, trichlorofluoromethane, and benzene were all detected in both the urban and agricultural studies. A significantly greater percentage of VOC detections were present in water samples from the urban study than from the agricultural study (90 and 50 percent, respectively). Carbon disulfide was the most frequently detected VOC in the urban study. The compound 1,2,3,4-tetramethyl benzene was the most frequently detected VOC in the agricultural study. Tritium concentrations indicate that the water in the surficial sand and gravel aquifer has been recharged since 1953. Median tritium concentrations ranged from 11.6 to 12.8 tritium units. No significant difference in tritium concentrations was present between the three land-use studies. Comparisons of previous land-use studies in Minnesota with the three NAWQA land-use studies generally indicated the same patterns. Ground-water quality in surficial sand and gravel aquifers is affected by land-use practices. Ground water in urban studies has greater specific conductances, alkalinities, chloride, sodium, sulfate, and dissolved solid concentrations than agricultural or forested/undeveloped studies. Nitrate-nitrogen was detected in greater concentrations in agricultural studies than in urban studies, with concentrations in the forested/undeveloped studies less than in the agricultural or the urban studies. Agricultural studies have the greatest detection rates, numbers, and total concentrations of pesticides. Pesticide detection rates and total pesticide concentrations in the urban studies were less than in the agricultural studies, with the most frequently detected pesticides (prometon and dicamba) different than those in the agricultural studies (atrazine and deethylatrazine). A greater number of VOCs were detected in urban studies and at greater concentrations than in agricultural studies. Few pesticides or VOCs were detected in forested/undeveloped studies.

Minnesota↗

Simulations of Ground-Water Flow, Transport, Age, and Particle Tracking near York, Nebraska, for a Study of Transport of Anthropogenic and Natural Contaminants (TANC) to Public-Supply Wells

Contamination of public-supply wells has resulted in public-health threats and negative economic effects for communities that must treat contaminated water or find alternative water supplies. To investigate factors controlling vulnerability of public-supply wells to anthropogenic and natural contaminants using consistent and systematic data collected in a variety of principal aquifer settings in the United States, a study of Transport of Anthropogenic and Natural Contaminants to public-supply wells was begun in 2001 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The area simulated by the ground-water flow model described in this report was selected for a study of processes influencing contaminant distribution and transport along the direction of ground-water flow towards a public-supply well in southeastern York, Nebraska. Ground-water flow is simulated for a 60-year period from September 1, 1944, to August 31, 2004. Steady-state conditions are simulated prior to September 1, 1944, and represent conditions prior to use of ground water for irrigation. Irrigation, municipal, and industrial wells were simulated using the Multi-Node Well package of the modular three-dimensional ground-water flow model code, MODFLOW-2000, which allows simulation of flow and solutes through wells that are simulated in multiple nodes or layers. Ground-water flow, age, and transport of selected tracers were simulated using the Ground-Water Transport process of MODFLOW-2000. Simulated ground-water age was compared to interpreted ground-water age in six monitoring wells in the unconfined aquifer. The tracer chlorofluorocarbon-11 was simulated directly using Ground-Water Transport for comparison with concentrations measured in six monitoring wells and one public supply well screened in the upper confined aquifer. Three alternative model simulations indicate that simulation results are highly sensitive to the distribution of multilayer well bores where leakage can occur and that the calibrated model resulted in smaller differences than the alternative models between simulated and interpreted ages and measured tracer concentrations in most, but not all, wells. Results of the first alternative model indicate that the distribution of young water in the upper confined aquifer is substantially different when well-bore leakage at known abandoned wells and test holes is removed from the model. In the second alternative model, simulated age near the bottom of the unconfined aquifer was younger than interpreted ages and simulated chlorofluorocarbon-11 concentrations in the upper confined aquifer were zero in five out of six wells because the conventional Well Package fails to account for flow between model layers though well bores. The third alternative model produced differences between simulated and interpreted ground-water ages and measured chlorofluorocarbon-11 concentrations that were comparable to the calibrated model. However, simulated hydraulic heads deviated from measured hydraulic heads by a greater amount than for the calibrated model. Even so, because the third alternative model simulates steady-state flow, additional analysis was possible using steady-state particle tracking to assess the contributing recharge area to a public supply well selected for analysis of factors contributing to well vulnerability. Results from particle-tracking software (MODPATH) using the third alternative model indicates that the contributing recharge area of the study public-supply well is a composite of elongated, seemingly isolated areas associated with wells that are screened in multiple aquifers. The simulated age distribution of particles at the study public-supply well indicates that all water younger than 58 years travels through well bores of wells screened in multiple aquifers. The age distribution from the steady-state model using MODPATH estimates the youngest 7 percent of the water to have a flow-weighted mean age

Scientific Investigations Report↗

Vulnerability of ground water to contamination, Edwards Aquifer recharge zone, Bexar County, Texas, 1998

The Edwards aquifer, one of the most productive carbonate-rock aquifers in the Nation, is composed of the Kainer and Person Formations of the Edwards Group plus the overlying Georgetown Formation. Most recharge to the Edwards aquifer results from the percolation of streamflow loss and the infiltration of precipitation through porous parts of the recharge zone. Residential and commercial development is increasing, particularly in Bexar County in south-central Texas, atop the densely fractured and steeply faulted recharge zone. The increasing development has increased the vulnerability of ground water to contamination by spillage or leakage of waste materials, particularly fluids associated with urban runoff and (or) septic-tank leachate. This report describes a method of assessing the vulnerability of ground water to contamination in the Edwards aquifer recharge zone. The method is based on ratings of five natural features of the area: (1) hydraulic properties of outcropping hydrogeologic units; (2) presence or absence of faults; (3) presence or absence of caves and (or) sinkholes; (4) slope of land surface; and (5) permeability of soil. The sum of the ratings for the five natural features was used to develop a map showing the recharge zone's vulnerability to ground-water contamination.

Water-Resources Investigations Report↗

A ground-water reconnaissance of the Republic of Ghana, with a description of geohydrologic provinces

This report gives a general summary of the availability and use of ground water and describes the occurrence of ground water in five major geohydrologic provinces lying in the eight administrative regions of Ghana. The identification and delineation of the geohydrologic provinces are based on their distinctive characteristics with respect to the occurrence and availability of ground water. The Precambrian province occupies the southern, western, and northern parts of Ghana and is underlain largely by intrusive crystalline and metasedimentary rocks. The Voltaian province includes that part of the Voltaian sedimentary basin in central Ghana and is underlain chiefly by consolidated sandstone, mudstone, and shale. Narrow discontinuous bands of consolidated Devonian and Jurassic sedimentary rocks near the coast constitute the Coastal Block Fault province. The Coastal Plain province includes semiconsolidated to unconsolidated sediments of Cretaceous to Holocene age that underlie coastal plain areas in southwestern and southeastern Ghana. The Alluvial province includes the Quaternary alluvial deposits in the principal river valleys and on the delta of the Volta River. Because of the widespread distribution of crystalline and consolidated sedimentary rocks of low permeability in the Precambrian, Voltaian, and Coastal Block Fault provinces, it is difficult to develop large or event adequate groundwater supplies in much of Ghana. On the other hand, small (1 to 50 gallons per minute) supplies of water of usable quality are available from carefully sited boreholes in most parts of the country. Also, moderate (50 to 200 gpm) supplies of water are currently (1964) obtained from small-diameter screened boreholes tapping sand and limestone aquifers in the Coastal Plain province in southwestern and southeastern Ghana, but larger supplies could be obtained through properly constructed boreholes. In the Alluvial province, unconsolidated deposits in the larger stream valleys that are now largely undeveloped offer desirable locations for shallow vertical or horizontal wells, which can induce infiltration from streams and yield moderate to large water supplies. The principal factors that limit development of ground-water supplies in Ghana are (1) prevailing low permeability and water-yielding potential of the crystalline and consolidated sedimentary rocks that underlie most of the country, (2) highly mineralized ground water which appears to be widely distributed in the northern part of the Voltaian province, and (3) potential problems of salt-water encroachment in the Coastal Plain province in the Western Region and in the Keta area. On the other hand, weathering has increased porosity and has thus substantially increased the water-yielding potential of the crystalline and consolidated sedimentary rocks in much of central and northern Ghana. Also, with proper construction and development, much larger yields than those now (1964) prevalent could be obtained from boreholes tapping sand and limestone aquifers in the Coastal Plain province.

Water Supply Paper↗

Evaluation of the ground-water flow model for northern Utah Valley, Utah, updated to conditions through 2002

This report evaluates the performance of a numerical model of the ground-water system in northern Utah Valley, Utah, that originally simulated ground-water conditions during 1947-1980 and was updated to include conditions estimated for 1981-2002. Estimates of annual recharge to the ground-water system and discharge from wells in the area were added to the original ground-water flow model of the area. The files used in the original transient-state model of the ground-water flow system in northern Utah Valley were imported into MODFLOW-96, an updated version of MODFLOW. The main model input files modified as part of this effort were the well and recharge files. Discharge from pumping wells in northern Utah Valley was estimated on an annual basis for 1981-2002. Although the amount of average annual withdrawals from wells has not changed much since the previous study, there have been changes in the distribution of well discharge in the area. Discharge estimates for flowing wells during 1981-2002 were assumed to be the same as those used in the last stress period of the original model because of a lack of new data. Variations in annual recharge were assumed to be proportional to changes in total surface-water inflow to northern Utah Valley. Recharge specified in the model during the additional stress periods varied from 255,000 acre-feet in 1986 to 137,000 acre-feet in 1992. The ability of the updated transient-state model to match hydrologic conditions determined for 1981-2002 was evaluated by comparing water-level changes measured in wells to those computed by the model. Water-level measurements made in February, March, or April were available for 39 wells in the modeled area during all or part of 1981-2003. In most cases, the magnitude and direction of annual water-level change from 1981 to 2002 simulated by the updated model reasonably matched the measured change. The greater-than-normal precipitation that occurred during 1982-84 resulted in period-of-record high water levels measured in many of the observation wells in March 1984. The model-computed water levels at the end of 1982-84 also are among the highest for the period. Both measured and computed water levels decreased during the period representing ground-water conditions from 1999 to 2002. Precipitation was less than normal during 1999-2002. The ability of the model to adequately simulate climatic extremes such as the wetter-than-normal conditions of 1982-84 and the drier-than-normal conditions of 1999-2002 indicates that the annual variation of recharge to the ground-water system based on streamflow entering the valley, which in turn is primarily dependent upon precipitation, is appropriate but can be improved. The updated transient-state model of the ground-water system in northern Utah Valley can be improved by making revisions on the basis of currently available data and information.

Utah↗

Digital simulation of ground-water flow in the Warwick Aquifer, Fort Totten Indian Reservation, North Dakota

The demand for water from the Warwick aquifer, which underlies the Fort Totten Indian Reservation in northeastern North Dakota, has been increasing during recent years. Therefore, the Spirit Lake Sioux Nation is interested in resolving questions about the quantity and quality of water in the aquifer and in developing a water-management plan for future water use. A study was conducted to evaluate the surface-water and ground-water resources of the Fort Totten Indian Reservation and, in particular, the ground-water resources in the area of the Warwick aquifer. A major component of the study, addressed by this report, was to define the ground-water flow system of the aquifer. The Warwick aquifer consists of outwash deposits of the Warwick outwash plain that are as much as 30 feet thick and buried-valley deposits beneath the outwash plain that are as much as 200 feet thick. The aquifer is bounded on the north and west by end-moraine deposits and Devils Lake, on the south by the Sheyenne River Valley, and on the east by outwash deposits and ravines. The aquifer is underlain by Pierre Shale or by glacial till, clay, or silt. Ground-water gradients generally are small and rarely are more than 3 or 4 feet per mile. From 1982 to 1993, withdrawals from the Devils Lake well field averaged 1.5 cubic feet per second, and withdrawals from irrigation wells averaged 1.29 cubic feet per second. The combined discharge from springs may be about 3 cubic feet per second. During the early 1990s, the Warwick aquifer probably was in a steady-state condition with regard to storage change in the aquifer. A finite-difference, three-dimensional, ground-water flow model provided a reasonable simulation of ground-water flow in the Warwick aquifer. The aquifer was divided vertically into two layers and horizontally into a grid of 83 by 109 cells, each measuring 656 feet (200 meters) per side. The steady-state simulation was conducted using 1992 pumpage rates and October 1992 water levels. The mean absolute difference between simulated and derived water-level altitudes during final calibration of the model was 1.52 feet. The two transient simulations were conducted for 20 time intervals of 1 year each using both the small and large storage estimates, doubled 1992 pumpage from the Devils Lake well field, 1992 irrigation pumpage, and initial water-level altitudes simulated by the October 1992 steady-state simulation. In the simulation using the small storage estimate and doubled pumpage, model cells in the area of the well field went dry after 13 years. Assumptions made in the design of the model generally are supported by the digital simulation. Except in the area of Warwick Springs and smaller springs, lateral and basal boundaries of the aquifer are impermeable. The flow system is dominated by recharge and evapotranspiration. Recharge rates obtained during the calibration process were lower in topographically high areas than in topographically low areas. Hydraulic conductivity in the area of the Devils Lake well field was larger than that in the rest of the aquifer.

Water-Resources Investigations Report↗

Selected coal-related ground-water data, Wasatch Plateau-Book Cliffs area, Utah

The Wasatch Plateau-Book Cliffs%area as used in this report consists of about 8,000 square miles in east-central Utah. The major geographic features included in the area are the Wasatch Plateau, Book Cliffs, San Rafael Swell, Price River basin, and a small part of the Green River basin (pl. 1). The area is defined by approximate drainage-divide boundaries in the Wasatch Plateau and Book Cliffs, by an arbitrary boundary on the south, and by the Utah-Colorado State line on the east. The Wasatch Plateau-Book Cliffs area includes all the operating coal mines in Utah in 1978. Annual coal production in the area is expected to increase from the current (1978) rate of about 8 million tons to as much as 30 million tons within the next 10 years (J. W. Moffitt, U.S. Geological Survey, oral commun., 1978). Ground water is an important source of water supply in the area. As mining increases and mining-related municipalities grow, many sources of ground-water supply may be subjected to increased demands and possibly degradation of chemical quality. Waddell, Vickers, Upton, and Contratto (1978) reported some ground- water data after a reconnaissance of part of the area. The purpose of this report, which was prepared in cooperation with the U.S. Bureau of Land Management, is to present a more detailed compilation of ground-water-related data that were collected and compiled during October 1976 to March 1978. The report is designed to make the data available in an orderly and usable form for local and regional water managers and other users of water data.

Utah↗

Water-quality assessment of the Potomac River Basin: Analysis of available pesticide data, 1972-1990

A study of available data for the period from 1972 to 1990 was conducted to characterize the occurrence and distribution of pesticides in sur-face water, bottom material, ground water, and fish tissue in the Potomac River Basin. The study was conducted by the Potomac River study unit of the U.S. Geological Survey?s National Water-Quality Assessment (NAWQA) program. Exist-ing data coverage was evaluated to guide future data-collection activities. Data from computer data bases and from published and unpublished reports were obtained from local, State, and Fed-eral agencies in the four Potomac River Basin states and the District of Columbia. Data are available for all environmental media, but geo-graphic and temporal coverage are limited. Clusters of data occur in the north-central parts of the basin, with numerous samples at discrete loca-tions in the Shenandoah and Monocacy River Basins, along the mainstem Potomac River, in the Washington, D.C., area, and in streams along the Potomac Estuary. Much of the available surface-water and bottom-material data are from the ear-lier years of the period of interest, the ground-water data are from the middle years, and the fish-tissue data are distributed over much of the period. Overall, temporal coverage is not sufficient for analysis of trends. Comparisons between different sample media are possible in some areas of the Potomac River Basin, particularly in the northern end of the Great Valley. Residual concentrations of some pesticides have been found in surface water, bottom mate-rial, ground water, and fish tissue. Samples have been analyzed for a total of at least 69 pesticides and related compounds in surface water, bottom material, ground water, and fish tissue. Most con-centrations of the pesticides analyzed during the period from 1972 to 1990 were less than or equal to reporting limits. For surface-water samples, 13 out of 41 pes-ticides and related compounds analyzed had concentrations equal to or greater than the report-ing limits. Compounds reported in surface water included 2,4-D, atrazine, aldrin, chlordane, DDT and related compounds, dieldrin, endrin, lindane, prometone, prometryne, and simazine. For bottom material samples, 19 of 31 pesticides and related compounds analyzed had concentrations equal to or greater than the reporting limits. Compounds reported in bottom material included aldrin, chlor-dane, DDT and related compounds, diazinon, dieldrin, endosulfan, endrin, ethion, heptachlor, heptachlor epoxide, lindane, parathion, and tox-aphene. In ground-water samples, 14 of 39 pesticides and related compounds analyzed had concentrations equal to or greater than the report-ing limits. Compounds reported in ground water included 2,4-D, atrazine, chlordane, cyanazine, DDT and related compounds, diazinon, dieldrin, endosulfan, endrin, heptachlor epoxide, malathion, methyl parathion, simazine. For fish- tissue sam-ples, 30 of the 37 pesticides and related compounds analyzed had concentrations equal to or greater than the reporting limits. Compounds reported included aldrin, chlorpyrifos, dacthal, dieldrin, endrin, HCB, heptachlor, heptachlor epoxide, methoxychlor, mirex, PCA, toxaphene, and those compounds related to chlordane, DDT, and lindane.

Maryland, Pennsylvania, Virginia, West Virginia↗

Hydrogeology and hydrogeologic terranes of the Blue Ridge and Piedmont Physiographic Provinces in the eastern United States

Severe and prolonged droughts between 1961 and 1988, combined with increased demands for freshwater supplies in the United States, have resulted in a critical need to assess the potential for development of ground- and surface-water supplies. Rapid industrial growth and urban expansion have caused existing freshwater supplies to be used at or near maximum capacity. Begun in 1978, the Regional Aquifer-System Analysis (RASA) Program of the U.S. Geological Survey (USGS) is a systematic effort to study a number of the Nation's most important aquifer systems, which, in aggregate, underlie much of the country and represent an important component of the Nation's total water supply. The broad objective for each of the 28 studies in the program is to assemble geologic, hydrologic, and geochemical information, to analyze and develop an understanding of the system, and to develop predictive capabilities that will contribute to the effective management of the system. In 1988, as part of the RASA Program, the USGS began a 6-year study of the ground-water resources of parts of 11 States in the Eastern United States (Swain and others, 1991). The study was designated the Appalachian Valley and Piedmont Regional Aquifer-System Analysis (APRASA). The APRASA team investigated ground-water resources primarily in the unglaciated part of the Valley and Ridge, the Blue Ridge, the New England, and the Piedmont Physiographic Provinces (fig. 1). For the purposes of this report, the small area in the New England Physiographic Province that is within the study area in New Jersey and Pennsylvania was considered part of the Piedmont Physiographic Province. The results of the APRASA are contained in about 50 reports and abstracts, including reports on simulation of ground-water flow in three type areas, this atlas, and chapters in Professional Paper 1422. These chapters include the summary (Chapter A), descriptions of recharge rates and surface- and ground-water relations (Chapter B), hydrogeologic terranes in the Valley and Ridge Physiographic Province (Chapter C), and ground-water geochemistry (Chapter D). The purposes of this atlas are to summarize the hydrogeology, to describe an analysis of maps and well records, and to present a classification and map of the hydrogeologic terranes of the Blue Ridge and Piedmont Physiographic Provinces within the APRASA study area. Hydrogeologic terranes are defined for this atlas as regionally mappable areas characterized by similar water-yielding properties of a grouping of selected rock types. The hydrogeologic terranes represent areas of distinct hydrologic character. The terranes are intended to help water users locate and develop adequate water supplies and to help hydrologists interpret the regional hydrogeology. Previous investigations provide maps and descriptions of the geologic units, describe the local quantity and quality of ground water within these units, and establish the statistical methods for comparing the water-yielding properties of these units. State geologic maps show the distribution of geologic units at a scale of 1:500,000 for Alabama (Osborne and others, 1989), Georgia (Lawton and others, 1976), North Carolina (Brown and Parker, 1985), and Virginia (Calver and Hobbs, 1963). State maps show geologic units at a scale of 1:250,000 for Maryland (Cleaves and others, 1968), New Jersey (Lewis and Kummel, 1912), Pennsylvania (Berg and others, 1980), South Carolina (Overstreet and Bell, 1965), Tennessee (Hardeman, 1966), and West Virginia (Cardwell and others, 1968). Quadrangle geologic maps show geologic units at a scale of 1:24,000 for parts of Delaware within the APRASA area (Woodruff and Thompson, 1972, 1975). Many reports have been published describing the groundwater resources of a county, parts of a county, multi-county areas, or river basins. The statistical methods used in this atlas are based largely on those used by Helsel and Hirsch (1992) and by Knopman (1990, p. 7-9). In her analysis of well records in the USGS Ground-Water Site Inventory (GWSI) data base, Knopman (1990) ranked factors that must be taken into account when assessing the water-yielding potential of the rocks in the Valley and Ridge, the Blue Ridge, and the Piedmont Physiographic Provinces in Pennsylvania. Readers are referred to Helsel and Hirsch (1992) and Knopman (1990) for details regarding statistical methods.

Alabama, Delaware, Georgia, Maryland, New Jersey, ↗

Ground-water age, flow, and quality near a landfill, and changes in ground-water conditions from 1976 to 1996 in the Swinomish Indian Reservation, northwestern Washington

This report describes the results of two related studies: a study of ground-water age, flow, and quality near a landfill in the south-central part of the Swinomish Indian Reservation; and a study of changes in ground-water conditions for the entire reservation from 1976 to 1996. The Swinomish Indian Reservation is a 17-square-mile part of Fidalgo Island in northwestern Washington. The groundwater flow system in the reservation is probably independent of other flow systems in the area because it is almost completely surrounded by salt water. There has been increasing stress on the ground-water resources of the reservation because the population has almost tripled during the past 20 years, and 65 percent of the population obtain their domestic water supply from the local ground-water system. The Swinomish Tribe is concerned that increased pumping of ground water might have caused decreased ground-water discharge into streams, declines in ground-water levels, and seawater intrusion into the ground-water system. There is also concern that leachate from an inactive landfill containing mostly household and wood-processing wastes may be contaminating the ground water. The study area is underlain by unconsolidated glacial and interglacial deposits of Quaternary age that range from about 300 to 900 feet thick. Five hydrogeologic units have been defined in the unconsolidated deposits. From top to bottom, the hydrogeologic units are a till confining bed, an outwash aquifer, a clay confining bed, a sea-level aquifer, and an undifferentiated unit. The ground-water flow system of the reservation is similar to other island-type flow systems. Water enters the system through the water table as infiltration and percolation of precipitation (recharge), then the water flows downward and radially outward from the center of the island. At the outside edges of the system, ground water flows upward to discharge into the surrounding saltwater bodies. Average annual recharge is estimated to be about 3 inches, or 12 percent of the average annual precipitation. Ground water in the outwash aquifer near the landfill is estimated to be between 15 and 43 years old. Some deeper ground waters and ground water near the discharge areas close to the shoreline are older than 43 years. Analysis of water-quality data collected for this study and review of existing data indicate that material in the landfill has had no appreciable impact on the current quality of ground water outside of the landfill. The water quality of samples from seven wells near to and downgradient from the landfill appears to be similar to the ground-water quality throughout the entire study area. The high iron and manganese concentrations found in most of the samples from wells near the landfill are probably within the range of natural concentrations for the study area. Ground-water pumping during the past 20 years has not caused any large changes in ground-water discharge to streams, ground-water levels, or seawater intrusion into the ground-water system. Ground-water discharge into Snee-oosh Creek and Munks Creek had similar magnitudes in the summers of 1976 and 1996; flows in both creeks during those summers ranged from 0.07 t 0.15 cubic feet per second. Ground-water levels changed minimally between 1976 and 1996. The average water-level change for 20 wells with more than 10 years between measurements was -0.7 feet and the two largest waterlevel declines were 6 and 9 feet. No appreciable seawater intrusion was found in the ground water in 1996, and there was no significant increase in the extent of seawater intrusion from 1976 to 1996. Median chloride concentrations of water samples collected from wells were 22 milligrams per liter in 1976 and 18 milligrams per liter in 1996.

Washington↗

Questa baseline and pre-mining ground-water quality investigation. 10. Geologic influences on ground and surface waters in the lower Red River watershed, New Mexico

This report is one in a series that presents results of an interdisciplinary U.S. Geological Survey (USGS) study of ground-water quality in the lower Red River watershed prior to open-pit and underground molybdenite mining at Molycorp’s Questa mine. The stretch of the Red River watershed that extends from just upstream of the town of Red River, N. Mex., to just above the town of Questa includes several mineralized areas in addition to the one mined by Molycorp. Natural erosion and weathering of pyrite-rich rocks in the mineralized areas has created a series of erosional scars along this stretch of the Red River that contribute acidic waters, as well as mineralized alluvial material and sediments, to the river. The overall goal of the USGS study is to infer the premining ground-water quality at the Molycorp mine site. An integrated geologic, hydrologic, and geochemical model for ground water in the mineralized—but unmined—Straight Creek drainage (a tributary of the Red River) is being used as an analog for the geologic, geochemical, and hydrologic conditions that influenced ground-water quality and quantity in the Red River drainage prior to mining. This report provides an overall geologic framework for the Red River watershed between Red River and Questa, in northern New Mexico, and summarizes key geologic, mineralogic, structural and other characteristics of various mineralized areas (and their associated erosional scars and debris fans) that likely influence ground- and surface-water quality and hydrology. The premining nature of the Sulphur Gulch and Goat Hill Gulch scars on the Molycorp mine site can be inferred through geologic comparisons with other unmined scars in the Red River drainage.

New Mexico↗