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USGS2006

Occurrence of trihalomethanes in the nation's ground water and drinking-water supply wells, 1985-2002

This report describes the occurrence of trihalomethanes (THMs) in the Nation's ground water and drinking-water supply wells based on analysis of 5,642 samples of untreated ground water and source water collected or compiled during 1985-2002 by the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. THMs are a group of volatile organic compounds (VOCs) with natural and anthropogenic sources that are of interest because they are associated with acute and chronic health problems in humans. THMs occur in water primarily from chlorination and are classified as disinfection by-products. In this report, the four THMs are discussed in the order of chloroform, bromodichloromethane, dibromochloromethane, and then bromoform; this sequence corresponds to largest to smallest chlorine content and smallest to largest bromine content. Four trihalomethanes were detected in less than 20 percent of samples from studies of (1) aquifers, (2) shallow ground water in agricultural areas, (3) shallow ground water in urban areas, (4) domestic wells, and (5) public wells. Detection frequencies for individual THMs in the five studies ranged from zero for shallow ground water in agricultural areas to 19.5 percent for shallow ground water in urban areas. None of the samples from aquifer studies, domestic wells, or public wells had total THM concentrations (the sum of the concentrations of chloroform, bromodichloromethane, dibromochloromethane, and bromoform) greater than or equal to the U.S. Environmental Protection Agency Maximum Contaminant Level of 80 micrograms per liter (?g/L). Comparisons of results among studies of aquifers, shallow ground water in agricultural areas, and shallow ground water in urban areas were used to describe the occurrence of the four THMs in ground water for three different land-use settings-mixed, agricultural, and urban, respectively. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 7.9 percent of the samples from aquifer studies, 2.2 percent of the samples from shallow ground water in agricultural areas, and 19.5 percent of the samples from shallow ground water in urban areas. In general, detection frequencies and concentrations of the four THMs were greater in shallow ground water in urban areas compared to aquifer studies and to shallow ground water in agricultural areas. For all three of these studies, the most common two-THM mixture at the 0.2-?g/L assessment level was chloroform-bromodichloromethane, and this was the only two-THM mixture found in samples of shallow ground water in agricultural areas. Comparisons of results between studies of domestic wells and public wells were used to describe the occurrence of the four THMs in two different supplies of ground water used for drinking water. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 5.2 percent of the domestic well samples and in 14.7 percent of the public well samples. In general, detection frequencies and THM concentrations were greater in samples from public wells than from domestic wells. At the 0.2-?g/L assessment level, the six possible two-THM mixtures occurred about six times more frequently in samples from public wells than from domestic wells. One of the most common two-THM mixtures in samples from domestic and public wells was bromodichloromethane-dibromochloromethane. Detection frequency is associated with the chlorine content of the THM compound. In general, for each of the five studies, as the chlorine content of the THM compound decreased, the detection frequency at the 0.2-?g/L assessment level also decreased. The exception was the study of public wells in which the detection frequency of the THMs decreased in the following order: chloroform, bromoform, dibromochloromethane, and bromodichloromethane. At the 0.2-?g/L assessment level, the median concentration for one or more of the four THMs ranged from 0.3 ?g/L (shallow ground water in agricultural a

Scientific Investigations Report↗

USGS1978

Progress toward a ground-water-quality monitoring network for Idaho

A ground-water-quality monitoring network is being designed for Idaho. The primary objectives of the network are to (1) determine the present quality of the State's ground water, (2) provide continual monitoring of groundwater quality for water-management purposes, and (3) serve as a warning system of undesirable changes in ground-water quality. Data are compiled for geohydrologic conditions, groundwater quality, cultural elements, and pollution sources. A "Hydrologic Unit Priority Index" is calculated from these data to select priority areas for monitoring purposes. New ground-water-quality data were collected where existing data were lacking and at some sites that were previously sampled. Old and new data at common sites correlated well, indicating that the water quality has not changed significantly. Most ground water in Idaho is of good quality for common uses; however, water quality may pose problems in local areas. The problems result from both natural and human causes. The potential for pollution of the aquifers is expected to be greatest in areas of greatest development. In Idaho, population centers and industries tend to be in areas of privately owned irrigated and arable · land. Therefore, these areas are of primary concern for monitoring ground-water quality. Other areas requiring monitoring include those with second-home development, mining and its related processes, and radioactive-waste disposal.

Idaho↗

USGS1996

Geology and ground-water resources of the Blackfeet Indian Reservation, northwestern Montana

Ground-water resources of the Blackfeet Indian Reservation are facing increased development for domestic and public drinking-water supplies and for industrial use. Along with the increased demand for ground-water data to address water-rights issues, water-quality concerns, and water-management decisions. The increased demand for ground water and ground-water data highlighted the need for a better understanding of the reservations’s ground-water resources. To fulfill this need, a 3-year long investigation of the geology and ground-water resources of the Blackfeet Indian Reservation was made by the U.S. Geological Survey (USGS) in cooperation with the Blackfeet Water Resources Department.

Montana↗

USGS2007

Ground water stratification and delivery of nitrate to an incised stream under varying flow conditions

Ground water processes affecting seasonal variations of surface water nitrate concentrations were investigated in an incised first-order stream in an agricultural watershed with a riparian forest in the coastal plain of Maryland. Aquifer characteristics including sediment stratigraphy, geochemistry, and hydraulic properties were examined in combination with chemical and isotopic analyses of ground water, macropore discharge, and stream water. The ground water flow system exhibits vertical stratification of hydraulic properties and redox conditions, with sub-horizontal boundaries that extend beneath the field and adjacent riparian forest. Below the minimum water table position, ground water age gradients indicate low recharge rates (2-5 cm yr-1) and long residence times (years to decades), whereas the transient ground water wedge between the maximum and minimum water table positions has a relatively short residence time (months to years), partly because of an upward increase in hydraulic conductivity. Oxygen reduction and denitrification in recharging ground waters are coupled with pyrite oxidation near the minimum water table elevation in a mottled weathering zone in Tertiary marine glauconitic sediments. The incised stream had high nitrate concentrations during high flow conditions when much of the ground water was transmitted rapidly across the riparian zone in a shallow oxic aquifer wedge with abundant outflow macropores, and low nitrate concentrations during low flow conditions when the oxic wedge was smaller and stream discharge was dominated by upwelling from the deeper denitrified parts of the aquifer. Results from this and similar studies illustrate the importance of near-stream geomorphology and subsurface geology as controls of riparian zone function and delivery of nitrate to streams in agricultural watersheds.

Maryland↗

USGS1996

Water Budget and the Effects of Land-Use Changes on Ground-Water Recharge, Oahu, Hawaii

Detailed water budgets calculated for southern and southeastern Oahu are used with a geographic information system to develop simplified methods for estimating areal water budgets for predevelopment and mid-1980's land use. The methods were applied to estimate water budgets for the Waianae area of western Oahu, and for north-central, southern, and southeastern Oahu. A water budget was calculated for windward Oahu by developing a separate geographic information system model of the area. The water budgets for these areas were combined into a single water budget for the entire island. The geographic information system model was used to calculate mid-1980's ground-water recharge to small areas of specific interest and the distribution of recharge by geologic formation. The most significant changes in the water budget and ground-water recharge have occurred in north-central and southern Oahu as a result of large-scale agricultural development and urbanization by the mid-1980's. Runoff increased by 23 million gallons per day in southern Oahu where extensive urban areas have been developed. Evapotranspiration increased by 8 million gallons per day in southern Oahu and 28 million gallons per day in north-central Oahu as result of the 146 million gallons per day of agricultural irrigation. Ground-water recharge increased in both areas: by about 56 million gallons per day in southern Oahu and by about 32 million gallons per day in north-central Oahu. Predevelopment ground-water recharge to Oahu was an estimated 792 million gallons per day. Changes in land-use practices in the mid-1980's resulted in an estimated island-wide recharge of 880 million gallons per day.

Professional Paper↗

USGS2007

Effects of ground-water withdrawal on Kaunakakai Stream environmental restoration plan, Molokai, Hawaii

The U.S. Army Corps of Engineers, in cooperation with the County of Maui Department of Public Works and Environmental Management, has proposed to construct 2.75 acres of shallow ponds and mudflats near the mouth of Kaunakakai Stream, Moloka`i, Hawai`i to restore habitat for the endangered native Hawaiian Stilt. Kaunakakai Stream is ephemeral upstream from the habitat-restoration site. Where the pond and wetland bottoms are below the water table, the ponds and wetland will be sustained by ground-water discharge during dry-weather conditions. Because ground water is the main source of water for the proposed ponds and wetland, a reduction of ground-water levels and discharge near the mouth of Kaunakakai Stream will have an effect on the availability of habitat. In response to concerns about the possible effects of ground-water withdrawal on the habitat restoration project near the mouth of Kaunakakai Stream, the U.S. Geological Survey undertook the present investigation to estimate, using an existing numerical ground-water-flow model, the changes in ground-water level and coastal discharge caused by redistributed and additional ground-water withdrawals. Steady-state water-level and coastal-discharge changes, relative to recent base-case conditions, were estimated for each of six withdrawal scenarios. Redistributed and additional ground-water withdrawals in the six scenarios were simulated from selected sites in the area between Kualapu`u and `Ualapu`e. For the scenarios tested, model results indicate that withdrawals from existing and proposed wells cause a water-level decline of about 0.1 ft in the vicinity of the Kaunakakai habitat-restoration site. In addition, model results indicate a reduction of ground-water discharge, ranging from 98,000 to 170,000 gal/d, to the model element containing the habitat-restoration site, although the existing spatial discretization in the model is too coarse to reliably estimate the reduction of ground-water discharge to the stream. Reduction in discharge to the habitat-restoration site is likely less than the total indicated by the model element because the site covers a small fraction (about 5 percent) of the area of a model element. Ground-water-level declines near the habitat-restoration site will reduce (1) the available wetted habitat area by an amount that is dependent on the bottom slope of the ponds near their edges, (2) the maximum water depth of the ponds by about 0.1 ft, and (3) the average water depth by an amount that is dependent on the bottom shape of the ponds. The salinity of ground-water discharging into the wetland area likely will increase by an unknown amount in response to increased withdrawals upgradient from the site. A numerical model capable of simulating density-dependent flow and transport is needed to evaluate the effects of withdrawal on salinity in the area.

Hawai'i↗

USGS1962

An application of thermometry to the study of ground water

Except for studies of temperature data related to ground-water developments that induce infiltration from streams, little attention has been given to the possibility of using temperature fluctuations as a tool for studying the elements of the hydrologic cycle involving ground water. The temperature of the water discharged from large installations that induce river infiltration through alluvial deposits depends primarily on the following factors: (a) the porosity of the aquifer, (b) the specific heat of the rocks or mineral grains making it up, (c) the temperature of the ground water in storage, (d) the temperature of the river water, and (e) the amount of mixing that occurs as a result of pumping. In six installations of this type, where the annual rivertemperature fluctuations ranged from 44° to 52°F, the average range in groundwater temperature was 22 °F. The cycles of ground-water temperature lagged behind the river-temperature cycles by 1 to 5 1 / 2 months. Under the conditions that existed, the lag of the minima of the cycles was much greater than that of the maxima, largely because of variations in pumpage and of the effect of viscosity differences on the rate of flow. An experimental study was made at Worthington in southwestern Minnesota to determine whether temperature fluctuations could be used to study rates and directions of ground-water movement or to evaluate recharge conditions. Three shallow glacial-outwash aquifers were studied by measuring temperatures at approximately monthly intervals in three municipal-supply wells whose average yields were about 60 to 150 gpm (gallons per minute). Temperatures were read with an accuracy of 0.01° to 0.02°C, and the data were analyzed graphically and correlated in detail with lake levels, lake temperatures, precipitation, and groundwater levels. Thermographs for 2 wells, 1 completed in a semiconfined aquifer about 200 feet from Okabena Lake and the other in a water-table aquifer about 850 feet from the lake, indicate that pumping induces water to move from the lake into the aquifers. A larger percentage of cold lake water was mixed with ground water from January to March 1958 than from January to March 1959. On the assumption that the cold or warm lake water was a distinct mass, the average time required for water to move from the lake to the well 200 feet away, under the prevailing hydraulic gradient, was 2 to 4 months; and to the well 850 feet away, 5 to 7 months. The thermograph for a well 1,800 feet from the lake, completed in an artesian aquifer that is confined by relatively impervious glacial till, indicates that the till acts as an insulating medium. However, despite the apparently low permeability of the till, the thermograph suggests that the lowering of artesian pressure, which results from pumping, induces warmer water to move downward through the till. The infiltration of relatively warm spring and summer rainfall can be detected on the thermographs of all the wells. The precise measurement of fluctuations in ground-water temperature, based on monthly readings in shallow glacial-outwash aquifers (up to about 70 feet deep), is useful in the study of ground-water movement and recharge. In addition to the study of natural phenomena in the hydrologic cycle, thermometry may be used as a tool in making detailed studies of (1) the effects of inducing the infiltration of surface water, (2) artificial recharge, (3) the effects of injecting petroleum products or radioactive or other wastes into the ground, and (4) ground-water movement in mines.

Water Supply Paper↗

USGS2001

Ground-water flow in the shallow aquifer system at the Naval Weapons Station Yorktown, Virginia

The Environmental Directorate of the Naval Weapons Station Yorktown, Virginia, is concerned about possible contamination of ground water at the Station. Ground water at the Station flows through a shallow system of layered aquifers and leaky confining units. The units of the shallow aquifer system are the Columbia aquifer, the Cornwallis Cave confining unit, the Cornwallis Cave aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer. The Eastover-Calvert confining unit separates the shallow aquifer system from deeper confined aquifers beneath the Station. A three-dimensional, finite-difference, ground-water flow model was used to simulate steady-state ground-water flow of the shallow aquifer system in and around the Station. The model simulated ground-water flow from the peninsular drainage divide that runs across the Lackey Plain near the southern end of the Station north to King Creek and the York River and south to Skiffes Creek and the James River. The model was calibrated by minimizing the root mean square error between 4 7 measured and corresponding simulated water levels. The calibrated model was used to determine the ground-water budget and general directions of ground-water flow. A particle-tracking routine was used with the calibrated model to estimate groundwater flow paths, flow rates, and traveltimes from selected sites at the Station. Simulated ground-water flow velocities of the Station-area model were small beneath the interstream areas of the Lackey Plain and Croaker Flat, but increased outward toward the streams and rivers where the hydraulic gradients are larger. If contaminants from the land surface entered the water table at or near the interstream areas of the Station, where hydraulic gradients are smaller, they would migrate more slowly than if they entered closer to the streams or the shores of the rivers where gradients commonly are larger. The ground-water flow simulations indicate that some ground water leaks downward from the water table to the Yorktown confining unit and, where the confining unit is absent, to the Yorktown-Eastover aquifer. The velocities of advective-driven contaminants would decrease considerably when entering the Yorktown confining unit because the hydraulic conductivity of the confining unit is small compared to that of the aquifers. Any contaminants that moved with advective ground-water flow near the groundwater divide of the Lackey Plain would move relatively slowly because the hydraulic gradients are small there. The direction in which the contaminants would move, however, would be determined by precisely where the contaminants entered the water table. The model was not designed to accurately simulate ground-water flow paths through local karst features. Beneath Croaker Flat, ground water flows downward through the Columbia aquifer and the Yorktown confining unit into the Yorktown-Eastover aquifer. Analyses of the movement of simulated particles from two adjacent sites at Croaker Flat indicated that ground-water flow paths were similar at first but diverged and discharged to different tributaries of Indian Field Creek or to the York River. These simulations indicate that complex and possibly divergent flow paths and traveltimes are possible at the Station. Although the Station-area model is not detailed enough to simulate ground-water flow at the scales commonly used to track and remediate contaminants at specific sites, general concepts about possible contaminant migration at the Station can be inferred from the simulations.

Virginia↗

USGS1998

Hydrogeology, water quality, water budgets, and simulated responses to hydrologic changes in Santa Rosa and San Simeon Creek ground-water basins, San Luis Obispo County, California

Santa Rosa and San Simeon Creeks are underlain by thin, narrow ground-water basins that supply nearly all water used for local agricultural and municipal purposes. The creeks discharge to the Pacific Ocean near the northwestern corner of San Luis Obispo County, California. The basins contain heterogeneous, unconsolidated alluvial deposits and are underlain by relatively impermeable bedrock. Both creeks usually stop flowing during the summer dry season, and most of the pumpage during that time is derived from ground-water storage. Annual pumpage increased substantially during 1956?88 and is now a large fraction of basin storage capacity. Consequently, dry-season water levels are lower and the water supply is more vulnerable to drought. The creeks are the largest source of ground-water recharge, and complete basin recharge can occur within the first few weeks of winter streamflow. Agricultural and municipal pumpages are the largest outflows and cause dry-season water-level declines throughout the San Simeon Basin. Pumping effects are more localized in the Santa Rosa Basin because of subsurface flow obstructions. Even without pumpage, a large quantity of water naturally drains out of storage at the upper ends of the basins during the dry season. Ground water is more saline in areas close to the coast than in inland areas. Although seawater intrusion has occurred in the past, it probably was not the cause of high salinity in 1988?89. Ground water is very hard, and concentrations of dissolved solids, chloride, iron, and manganese exceed drinking-water standards in some locations. Probability distributions of streamflow were estimated indirectly from a 120-year rainfall record because the periods of record for local stream-gaging stations were wetter than average. Dry-season durations with recurrence intervals between 5 and 43 years are likely to dry up some wells but not cause seawater intrusion. A winter with no streamflow is likely to occur about every 32 years and to result in numerous dry wells, seawater intrusion, and subsidence. Digital ground-water-flow models were used to estimate several items in the ground-water budgets and to investigate the effects of pumpage and drought. The models also were used to investigate the hydrologic effects of selected water-resources management alternatives. Selection of alternatives was not constrained by issues related to water rights, which were under dispute during the study. Increases in the area and intensity of irrigation could increase agricultural water demand by 26 to 35 percent, an increase that would lower water levels by as much as 10 feet and possibly cause subsidence in the lower Santa Rosa Basin. An additional municipal well in the lower Santa Rosa Basin could withdraw 100 acre-feet per year without causing seawater intrusion, but subsidence might occur. Transferring 270 acre-feet per year of treated wastewater from a percolation area near the coast to an area about 0.5 mile upstream of the municipal well field in the San Simeon Basin could raise upstream water levels by as much as 12 feet without causing significant water-table mounding or seawater intrusion. Decreases in agricultural pumping after a winter without streamflow could prevent seawater intrusion while allowing municipal pumping to continue at normal rates.

Water-Resources Investigations Report↗

USGS2005

Simulated water sources and effects of pumping on surface and ground water, Sagamore and Monomoy flow lenses, Cape Cod, Massachusetts

The sandy sediments underlying Cape Cod, Massachusetts, compose an important aquifer that is the sole source of water for a region undergoing rapid development. Population increases and urbanization on Cape Cod lead to two primary environmental effects that relate directly to water supply: (1) adverse effects of land use on the quality of water in the aquifer and (2) increases in pumping that can adversely affect environmentally sensitive surface waters, such as ponds and streams. These considerations are particularly important on the Sagamore and Monomoy flow lenses, which underlie the largest and most populous areas on Cape Cod. Numerical models of the two flow lenses were developed to simulate ground-water-flow conditions in the aquifer and to (1) delineate areas at the water table contributing water to wells and (2) estimate the effects of pumping and natural changes in recharge on surface waters. About 350 million gallons per day (Mgal/d) of water recharges the aquifer at the water table in this area; most water (about 65 percent) discharges at the coast and most of the remaining water (about 28 percent) discharges into streams. A total of about 24.9 Mgal/d, or about 7 percent, of water in the aquifer is withdrawn for water supply; most pumped water is returned to the hydrologic system as return flow creating a state of near mass balance in the aquifer. Areas at the water table that contribute water directly to production wells total about 17 square miles; some water (about 10 percent) pumped from the wells flows through ponds prior to reaching the wells. Current (2003) steady-state pumping reduces simulated ground-water levels in some areas by more than 4 feet; projected (2020) pumping may reduce water levels by an additional 3 feet or more in these same areas. Current (2003) and future (2020) pumping reduces total streamflow by about 4 and 9 cubic feet per second (ft3/s), corresponding to about 5 percent and 9 percent, respectively, of total streamflow. Natural recharge varies with time, over both monthly and multiyear time scales. Monthly changes in recharge cause pond levels to vary between 1 and 2 feet in an average year; annual changes in recharge, which can be much larger than monthly variations, can cause pond levels to vary by more than 10 feet in some areas over a period of years. Streamflow, which also changes in response to changes in recharge, varies by a factor of two over an average year and can vary more over multiyear periods. On average, monthly pumping ranges from 15.8 Mgal/d in March to 45.3 Mgal/d in August. Pumping and the distribution of return flow can seasonally affect the hydrologic system by lowering ground-water and pond levels and by depleting streamflows, particularly in the summer months. Maximum drawdowns in March and August exceed 3 feet and 6 feet, respectively, for current (2003) pumping. Simulated drawdowns from projected (2020) pumping, relative to water levels representing 2003 pumping conditions, exceed 2 feet in March and 5 feet in August. Current (2003) and future (2020) pumping can decrease pond levels in some areas by more than 3 feet; drawdown generally is largest during the month of August of an average year. Over multiyear periods, seasonal pumping can lower pond levels in some areas by more than 4 feet; the effects of seasonal pumping are largest during periods of reduced recharge. Monthly streamflow depletion varies in individual streams but can exceed 2 ft3/s in some streams. The combined effects of seasonal pumping and drought can reduce pond levels by more than 10 feet below average levels. Water levels in Mary Dunn Pond, which is in an area of large current and projected pumping, are predicted (2020) to decline during drought conditions by about 10.6 feet: about 6.9 feet from lower recharge, about 2.3 feet from current (2003) pumping, and about 1.4 feet from additional future (2020) pumping. The results indicate that pumping generally does not cause substantial streamflow depletion and that the primary effect of pumping is on water levels in ponds. Natural changes in recharge account for most of the variation in pond levels; however, pumping can cause substantial declines in the levels of ponds near pumping wells. Also, the effects of pumping and recharge can combine to cause drawdowns of more than 10 feet in some areas.

Massachusetts↗

USGS1992

Ground-water models cannot be validated

Ground-water models are embodiments of scientific hypotheses. As such, the models cannot be proven or validated, but only tested and invalidated. However, model testing and the evaluation of predictive errors lead to improved models and a better understanding of the problem at hand. In applying ground-water models to field problems, errors arise from conceptual deficiencies, numerical errors, and inadequate parameter estimation. Case histories of model applications to the Dakota Aquifer, South Dakota, to bedded salts in New Mexico, and to the upper Coachella Valley, California, illustrate that calibration produces a nonunique solution and that validation, per se , is a futile objective. Although models are definitely valuable tools for analyzing ground-water systems, their predictive accuracy is limited. The terms validation and verification are misleading and their use in ground-water science should be abandoned in favor of more meaningful model-assessment descriptors.

Advances in Water Resources↗

USGS1995

Hydrology and simulation of ground-water flow in southern Utah and Goshen Valleys, Utah

The ground-water resources of southern Utah and Goshen Valleys were assessed from 1988 to 1993 to determine the effects that additional ground-water withdrawals would have on water levels, surface water, and water quality. Recharge, movement, and discharge of ground-water were emphasized. The main ground-water system in southern Utah and Goshen Valleys is in the unconsolidated basin-fill deposits. Recharge to the ground-water system from streams, canals, irrigation, precipitation, intermittent and ephemeral runoff, and subsurface inflow was estimated to be 120,000 acre-feet in southern Utah Valley and 30,000 acre-feet in Goshen Valley in 1990. Discharge from the ground-water system to springs and drains, by evapotranspiration, to wells, streams, canals, Utah Lake, and sewer systems was estimated to be 130,000 acre-feet in southern Utah Valley and 33,000 acre-feet in Goshen Valley in 1990. Release from storage from March 1990 to March 1991 was estimated to be 9,800 acre-feet in southern Utah Valley and 3,400 acre-feet in Goshen Valley. Observed water-level fluctuations indicate that irrigation is not a major source of recharge in either valley and that precipitation is not a major source in Goshen Valley. In southern Utah Valley, water levels in March 1991 were not significantly different from water levels in March 1965. In Goshen Valley, water levels in March 1991 were higher than water levels in March 1965. A three-dimensional, finite-difference, ground-water flow model was used to simulate the ground-water system in the unconsolidated basin-fill deposits of southern Utah and Goshen Valleys. The steady-state conditions of 1949 and annual transient-state conditions from 1949 to 1990 were used to calibrate the model. Model-computed water-level declines of less than 20 feet are projected if municipal well withdrawals increase by 10,000 acre-feet per year. Model-computed water-level declines of 20 feet in southern Utah Valley and 40 to 80 feet in Goshen Valley are projected if well withdrawal is increased by 200 percent of the 1990 withdrawals.

Utah↗

USGS2000

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin - Ground-water quality in three different land-use areas, 1996-98

The surficial sand and gravel aquifer is susceptible to effects from land-use in the Upper Mississippi River Basin study unit of the National Water-Quality Assessment (NAWQA) Program. The purpose of this report is to describe the ground-water quality and the assessment of how different land-uses affect the shallow ground-water quality in the surficial sand and gravel aquifer. Ground-water quality was compared in three different land-use areas; an urban residential/commercial area on the edge of the Anoka Sand Plain in a portion of the Twin Cities metropolitan area (urban study), an intensive agricultural area in the Anoka Sand Plain (agricultural study), and a forested area in the Bemidji-Bagley Sand Plain (forested study). Ground water was sampled and analyzed for about 200 constituents, including physical parameters, major ions, selected trace elements, nutrients, dissolved organic carbon, selected pesticides, selected volatile organic compounds (VOCs), and tritium. The urban study wells were sampled during June and July 1996. The agricultural study wells were sampled during May and September 1998. The forested study wells were sampled during June 1998. The depth to water below the land surface generally was less than 20 ft in all three land-use studies. The median pH value in the urban study was 7.2, with medians in the agricultural and forested studies at 7.4 and 7.5, respectively. The median specific conductance was significantly greater in the urban study than in the agricultural and forested studies (914, 553, and 487 µS/cm respectively). The median dissolved oxygen concentration in the urban study (0.9 mg/L) was significantly less than the median in the agricultural or forested studies (5.3 and 2.3 mg/L respectively). Alkalinities in the agricultural study, with a median of 178 mg/L as CaCO 3 , were significantly less than medians in the urban or forested studies (261 and 246 mg/L as CaCO 3 , respectively). The water composition in the surficial aquifer in all three land-use studies is dominated by calcium, magnesium, and bicarbonate. Sulfate and chloride concentrations in water samples were significantly greater in the urban study than in the agricultural or forested studies, and concentrations in the forested study were least. Most of the water samples in all three land-use studies were very hard (greater than 180 mg/L as CaCO 3 ). Nitrate-nitrogen concentrations were greatest in the agricultural study, in which 38 percent of water samples exceeded the U.S. Environmental Protection Agency’s maximum contaminant level (MCL) for nitrate-nitrogen. Nitrate-nitrogen was greater than the MCL in 3 percent of urban study samples. None of the forested study samples exceeded the MCL for nitrate-nitrogen. Concentrations of phosphorus generally were less than 0.05 mg/ L, with no significant differences between the land-uses. A total of 19 pesticides were detected in water samples from one or more land-use study wells, with 11 pesticides detected in the urban study, 14 detected in the agricultural study, and 4 detected in the forested study. Atrazine, deethylatrazine, and simazine were the only pesticides detected in all three land-use studies. A significantly greater percentage of pesticide detections were present in water samples from the agricultural study than from the urban or forested studies (86.2, 56.7, and 46.7 percent, respectively). Prometon was the most frequently detected pesticide in the urban study. Atrazine and deethylatrazine were the most frequently detected pesticides in the agricultural and forested studies. Twenty-one VOCs were detected in water samples from one or more land-use study wells, with 19 detected in the urban study, 7 detected in the agricultural study, and none detected in the forested study. Chloromethane, trichloromethane, methylbenzene, trichlorofluoromethane, and benzene were all detected in both the urban and agricultural studies. A significantly greater percentage of VOC detections were present in water samples from the urban study than from the agricultural study (90 and 50 percent, respectively). Carbon disulfide was the most frequently detected VOC in the urban study. The compound 1,2,3,4-tetramethyl benzene was the most frequently detected VOC in the agricultural study. Tritium concentrations indicate that the water in the surficial sand and gravel aquifer has been recharged since 1953. Median tritium concentrations ranged from 11.6 to 12.8 tritium units. No significant difference in tritium concentrations was present between the three land-use studies. Comparisons of previous land-use studies in Minnesota with the three NAWQA land-use studies generally indicated the same patterns. Ground-water quality in surficial sand and gravel aquifers is affected by land-use practices. Ground water in urban studies has greater specific conductances, alkalinities, chloride, sodium, sulfate, and dissolved solid concentrations than agricultural or forested/undeveloped studies. Nitrate-nitrogen was detected in greater concentrations in agricultural studies than in urban studies, with concentrations in the forested/undeveloped studies less than in the agricultural or the urban studies. Agricultural studies have the greatest detection rates, numbers, and total concentrations of pesticides. Pesticide detection rates and total pesticide concentrations in the urban studies were less than in the agricultural studies, with the most frequently detected pesticides (prometon and dicamba) different than those in the agricultural studies (atrazine and deethylatrazine). A greater number of VOCs were detected in urban studies and at greater concentrations than in agricultural studies. Few pesticides or VOCs were detected in forested/undeveloped studies.

Minnesota↗

USGS1993

Isotopic evidence of complex ground-water flow at Yucca mountain, Nevada, USA

Strontium isotopes (expressed as per mill deviation from mean sea water, ??87Sr) reflect interaction between ground water and the aquifer through which it is flowing. In the Cenozoic aquifer of the Yucca Mountain region, ??87Sr values increase from north to south downgradient in the flow system. The largest ??87Sr values occur in the Amargosa Desert where ground water probably encounters alluvial basin fill derived from Precambrian rocks in the Funeral Range. Similarly, large ??87Sr values for ground water in the Paleozoic aquifer at the western end of the Spring Mountains also probably reflect an encounter with Precambrian rocks. In several wells into the volcanic rocks, apparent isotopic disequilibrium between ground water and the producing units suggests that the ground water probably integrates over a substantial part of the saturated section in attaining its strontium isotope signature.

Conference Paper↗

USGS2004

Review of Knowledge on the Occurrence, Chemical Composition, and Potential Use for Desalination of Saline Ground Water in Arizona, New Mexico, and Texas with a Discussion of Potential Future Study Needs

Increasing demand on the limited supplies of freshwater in the desert Southwest, as well as other parts of the United States, has increased the level of interest in saline-water resources. Saline ground water has long been recognized as a potentially important contributor to water supply in the Southwest, as demonstrated by the number of hydrologic, geologic, and engineering studies on the distribution of saline water and the feasibility of desalination. Potential future study needs include investigating and documenting the three-dimensional distribution of salinity and chemical composition of saline-water resources and the hydraulic properties of aquifers containing these saline-water resources, assessing the chemical suitability of saline water for use with existing and anticipated desalination technologies, simulating the effect of withdrawal of saline ground water on water levels and water composition in saline and adjoining or overlying freshwater aquifers, and determining the suitability of target geologic formations for injection of desalination-generated waste.

Open-File Report↗

USGS1994

Regional hydrology and simulation of deep ground-water flow in the Southeastern Coastal Plain aquifer system in Mississippi, Alabama, Georgia, and South Carolina

The Southeastern Coastal Plain aquifer system is a coastward-sloping, wedge-shaped sand and gravel reservoir exposed in outcrop to a humid climate and drained by an extensive surface-water network. Ground-water pumpage has increased to about 765 cubic feet per second since 1900, causing water-level declines of more than 150 feet in places, while base flow to major streams has decreased about 350 cubic feet per second. The water-level declines and adjustments in recharge and discharge are not expected to seriously restrict future ground-water development.

Alabama, Florida, Georgia, Mississippi, South Caro↗

USGS1999

Conceptual Model and Numerical Simulation of the Ground-Water-Flow System in the Unconsolidated Sediments of Thurston County, Washington

The demand for water in Thurston County has increased steadily in recent years because of a rapid growth in population. Surface-water resources in the county have been fully appropriated for many years and Thurston County now relies entirely on ground water for new supplies of water. Thurston County is underlain by up to 2,000 feet of unconsolidated glacial and non-glacial Quaternary sediments which overlie consolidated rocks of Tertiary age. Six geohydrologic units have been identified within the unconsolidated sediments. Between 1988 and 1990, median water levels rose 0.6 to 1.9 feet in all geohydrologic units except bedrock, in which they declined 1.4 feet. Greater wet-season precipitation in 1990 (43 inches) than in 1988 (26 inches) was the probable cause of the higher 1990 water levels. Ground-water flow in the unconsolidated sediments underlying Thurston County was simulated with a computerized numerical model (MODFLOW). The model was constructed to simulate 1988 ground-water conditions as steady state. Simulated inflow to the model area from precipitation and secondary recharge was 620,000 acre-feet per year (93 percent), leakage from streams and lakes was 38,000 acre-ft/yr (6 percent), and ground water entering the model along the Chehalis River valley was 5,800 acre-ft/yr (1 percent). Simulated outflow from the model was primarily leakage to streams, springs, lakes, and seepage faces (500,000 acre-ft/yr or 75 percent of the total outflow). Submarine seepage to Puget Sound was simulated to be 88,000 acre-ft/yr (13 percent). Simulated ground-water discharge along the Chehalis River valley was simulated to be 12,000 acreft/yr (2 percent). Simulated withdrawals by wells for all purposes was 62,000 acre-ft/yr (9 percent). The numerical model was used to simulate the possible effects of increasing ground-water withdrawals by 23,000 acre-ft/yr above the 1988 rate of withdrawal. The model indicated that the increased withdrawals would come from reduced discharge to springs, seepage faces, and offshore (total of 51 percent of increased pumping) and decreased flow to rivers (46 percent). About 3 percent would come from increased leakage from rivers. Water levels would decline more than 1 foot over most of the model area, more than 10 feet over some areas, and would be at a maximum of about 35 feet. Contributing areas for water discharging at McAllister and Abbott Springs and to pumping centers near Tumwater and Lacey were estimated using a particle-tracking post-processing computer code (MODPATH) and a MODFLOW model calibrated to steady-state (1988) conditions. Water discharging at McAllister and Abbot Springs was determined to come from water entering the ground-water system at the water table in an area of about 20 square miles (mi2) to the west and south of the springs. This water is estimated to come from recharge (both precipitation and secondary) and from leakage from Lake St. Clair and several other surface-water bodies. Southeast of Lacey, about 3,800 acre-ft of ground water were pumped from five municipal wells during 1988. The source of the pumped water was determined to be an area that covers about 1.1 mi2. The water was estimated to come from recharge (both precipitation and secondary) and leakage from surface-water bodies. Along the lower Deschutes River nearly 3,900 acre-ft/yr of ground water were pumped during 1988 from 15 wells for municipal and industrial use. The calculated source of this water was an area that covers about 1.3 mi2. Within the calculated contributing area the pumped ground water comes from recharge (both precipitation and secondary) and leakage from the Deschutes River and several other surface-water bodies.

Water-Resources Investigations Report↗

USGS1977

Ground-water resources of the Lexington, Kentucky, area

Ground water in the Lexington, Kentucky, area occurs in Ordovician Limestones in which cavity development is generally limited to about 100 feet below land surface. Some wells produce about 300 gallons per minute in some of the large stream valleys , about 50 gallons per minute in the rolling upland and small stream valleys, and about 5 gallons per minute on hilltops and steep slopes. Many wells throughout the area do not furnish adequate water for domestic supplies because no significant water-bearing openings are penetrated during drilling. Ground-water use is limited mostly to domestic and stock supplies and a few small public supplies. Ground water is generally a calcium bicarbonate type and in places contains sodium chloride and (or) hydrogen sulfide. Bacterial pollution of ground water is widespread because of direct recharge of polluted runoff and streamflow to cavernous limestones. (Woodard-USGS)

Kentucky↗