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At least 739 records · Page 41Linked to original sources
USGS1974

Alteration and fluid inclusion studies of the porphyry copper ore body at Bingham, Utah

Distribution patterns for biotitic alteration, sericitic alteration, and distinctive fluid-inclusion types in igneous host rocks of the porphyry copper ore body at Bingham, Utah, have been determined by petrographic examination of about 300 samples. These patterns are related to differences in original rock composition, variations in physical-chemical conditions during periods of intrusion and mineralization, and spatial position within the ore body. The distribution of biotitic (potassium-silicate) alteration assemblages and high-salinity fluid inclusions generally follows the crudely triangular form of the disseminated copper ore zone. Variations in abundance of hydrothermal biotite are attributed to differences in original mafic mineral content of the igneous host rocks. Biotitic alteration and initial copper mineralization were accomplished by high-salinity fluids concentrated during final crystallization of the monzonitic parent magma; genetic continuity between magmatic and hydrothermal stages is indicated . Pervasive sericitic alteration of plagioclase is confined to rocks in the northern one-third of the Bingham stock; a subzone of argillic alteration in the north-central part of the ore body occurs within the broader area of sericitic alteration. Fluids responsible for sericitic and argillic alteration were channeled by a broad zone of northeast-trending fractures. Hydrothermal minerals and high-salinity fluid inclusions occur within a large volume of shattered rock. Boiling of fluids during crystallization of the aplitic porphyry may account for the shattering. Sericitic (and argillic) alteration were apparently super-imposed on the earlier biotitic assemblage as the hydrothermal system cooled. Cooling and hydrolytic alteration were promoted by progressive introduction of meteoric waters. The many generations of inclusions trapped from boiling fluids in the temperature range 400 degrees to 600 degrees C suggest that the system was recharged repeatedly during the period of mineralization. Estimated fluid pressures of about 800 bars in the early stages of mineralization correspond to a lithostatic load of about 3 km; pressures were even lower (less than 200 bars) in the later stages and were probably controlled by hydrostatic conditions. Distribution patterns for biotitic alteration, sericitic alteration, and distinctive fluid-inclusion types in igneous host rocks of the porphyry copper ore body at Bingham, Utah, have been determined by petrographic examination of about 300 samples. These patterns are related to differences in original rock composition, variations in physical-chemical conditions during periods of intrusion and mineralization, and spatial position within the ore body.The distribution of biotitic (potassium-silicate) alteration assemblages and high-salinity fluid inclusions generally follows the crudely triangular form of the disseminated copper ore zone. Variations in abundance of hydrothermal biotite are attributed to differences in original mafic mineral content of the igneous host rocks. Biotitic alteration and initial copper mineralization were accomplished by high-salinity fluids concentrated during final crystallization of the monzonitic parent magma; genetic continuity between magmatic and hydrothermal stages is indicated.Pervasive sericitic alteration of plagioclase is confined to rocks in the northern one-third of the Bingham stock; a subzone of argillic alteration in the north-central part of the ore body occurs within the broader area of sericitic alteration. Fluids responsible for sericitic and argillic alteration were channeled by a broad zone of northeast-trending fractures.Hydrothermal minerals and high-salinity fluid inclusions occur within a large volume of shattered rock. Boiling of fluids during crystallization of the aplitic porphyry may account for the shattering. Sericitic (and argillic) alteration were apparently super-imposed on the earlier biotitic assemblage as the hydrothermal system cooled. Cooling and hydrolytic alteration were promoted by progressive introduction of meteoric waters. The many generations of inclusions trapped from boiling fluids in the temperature range 400 degrees to 600 degrees C suggest that the system was recharged repeatedly during the period of mineralization. Estimated fluid pressures of about 800 bars in the early stages of mineralization correspond to a lithostatic load of about 3 km; pressures were even lower (less than 200 bars) in the later stages and were probably controlled by hydrostatic conditions.

Utah↗
USGS2022

The Coles Hill uranium deposit, Virginia, USA: Geology, geochemistry, geochronology, and genetic model

The Coles Hill uranium deposit with an indicated resource of about 130 million lbs. of U 3 O 8 is the largest unmined uranium deposit in the United States. The deposit is hosted in the Taconian (approximately 480 – 450 Ma) Martinsville igneous complex, which consists of the Ordovician Leatherwood Granite (granodiorite) and Silurian Rich Acres Formation (diorite). The host rock was metamorphosed to orthogneiss during the Alleghanian orogeny (approximately 325 – 260 Ma) when it also underwent dextral strike-slip movement along the Brookneal shear zone. During the Triassic, extensional tectonics led to the development of the Dan River Basin that lies east of Coles Hill. The mineralized zone is hosted in brittle structures in the footwall of the Triassic Chatham fault that forms the western edge of the basin. Within brittle fracture zones, uranium silicate and uranium-bearing fluorapatite with traces of brannerite form veins and breccia fill with chlorite, quartz, calcite, titanium oxide, pyrite, and calcite. Uranium silicates also coat and replace primary titanite, zircon, ilmenite, and sulfides. Sodium metasomatism preceded and accompanied uranium mineralization, pervasively altering host rock, and forming albite from primary feldspar, depositing limpid albite rims on feldspar, altering titanite to titanium oxide and calcite and forming riebeckite. Various geothermometers suggest temperatures of less than approximately ~200°C during mineralization. In situ U-Pb analyses of titanite, Ti-oxide, and apatite, and Rb/Sr and U/Pb isotope-systematics of whole rock samples resolve the timing of geologic processes affecting Coles Hill. The host Leatherwood granite containing primary euhedral titanite is dated at 450 – 445 Ma, in agreement with previously obtained ages from zircon in the Martinsville igneous complex. A regional metamorphic event at 330 – 310 Ma formed anhedral titanite and some apatite, re-equilibrated whole rock Rb/Sr and U-Pb isotopes and is interpreted to have coincided with movement along the Brookneal shear zone. During shearing and metamorphism primary refractory uranium-bearing minerals including titanite, zircon, and uranothorite were recrystallized and uranium was liberated and incorporated locally into hematite, clay, and other fine-grained minerals. Uranium mineralization was accompanied by a metasomatic episode between 250 and 200 Ma that reset the Rb-Sr and U-Pb isotope systems, forming titanite and apatite that are associated and in places intimately intergrown with uranium silicate dating mineralization. This event coincides with rifting that formed the Dan River Basin and was a precursor to the breakup of Pangea. Based on the close spatial and temporal association of uranium with apatite, we conclude that uranium was carried as a uranyl-phosphate complex. The release of calcium during sodium metasomatic alteration of primary calcic feldspar and titanite in the host rock initiated successive reactions in which uranium and phosphate in mineralizing fluids combined with calcium to form U-enriched fluorapatite. Excess uranium was locally reduced by coupled redox reactions involving ferrous iron and sulfide minerals in the host rock, forming uranium silicates. Based on the deposit mineralogy, oxygen isotope geochemistry and trace element characteristics of uranium silicate and gangue minerals the primary mineralizing fluids likely included connate and/or meteoric water sourced from the local Dan River Basin. High heat flow related to Mesozoic rifting may have driven these (P-Na-F-rich) brines through local aquifers and into basin margin faults, transporting uranium from the basin or mobilizing uranium from previously formed U-minerals in the Brookneal shear zone, or from U-enriched older basement rock.

Virginia↗
USGS2018

Application of imaging spectroscopy for mineral exploration in Alaska: A study over porphyry Cu deposits in the eastern Alaska Range

The U.S. Geological Survey tested the utility of imaging spectroscopy (also referred to as hyperspectral remote sensing) as an aid to regional mineral exploration efforts in remote parts of Alaska. Airborne imaging spectrometer data were collected in 2014 over unmined porphyry Cu deposits in the eastern Alaska Range using the HyMap™ sensor. Maps of the distributions of predominant minerals, made by matching reflectance signatures in the remotely sensed data to reference spectra in the shortwave infrared region, do not uniquely discriminate individual rock units. However, they do highlight hydrothermal alteration associated with porphyry deposits and prospects hosted mostly within the Nabesna pluton. In and around porphyry Cu deposits at Orange Hill and Bond Creek, unique spectral signatures are related to variations in chlorite and white mica abundance and their chemical composition. This is best revealed in the longer-wavelength 2,200-nm Al-OH absorption feature positions in pixels spectrally dominated by white mica proximal to porphyry deposits. Similar spectral signatures of chlorite and white mica wavelength positions were also recognized away from the porphyry deposits; follow-up sampling identified these satellite areas to also contain Cu-Mo-Au mineralized rock. Our study confirms that airborne imaging spectroscopy has application for regional mineral exploration in exposed mountainous terrain in Alaska.

Alaska↗
USGS1979

Petrology, composition, and age of intrusive rocks associated with the Quartz Hill molybdenite deposit, southeastern Alaska

A large porphyry molybdenum deposit (Quartz Hill deposit) was recently discovered in the heart of the Coast Range batholithic complex about 70 km east of Ketchikan, southeastern Alaska. Intrusive rocks associated with the mineral deposit form two composite epizonal to hypabyssal stocks and many dikes in country rocks. The stocks are characterized by a variety of textural rock types varying from equigranular or weakly seriate biotite granite to porphyries with aphanitic or very fine grained and aplitic groundmasses. These rocks contain about equal amounts of quartz, albitic plagioclase, and microperthitic microcline and less than 2.5% biotite. Unaltered rocks contain between 0.2 and 1% CaO, less than 1.7% combined Fe 2 O 3 , FeO, and MgO, and 74.4 to 77.7% SiO 2 . Total alkalis are between 8 and 9%, and K 2 O/Na 2 O is about 1.1. The range of major-oxide variation is small, but it is systematically related to lithology. Many trace-elements, including B, Pb, Sn, and Li have low concentrations. Intrusive rocks associated with the Quartz Hill deposit are more albitic and possibly trace-element depleted compared to some other rocks associated with porphyry molybdenum deposits.All observed metallization and alteration is within the Quartz Hill stock. Molybdenite forms fracture coatings and occurs in veins with quartz. Alteration is widespread and includes development of secondary quartz, pyrite, K-feldspar, biotite, white mica, chlorite, and zeolite. Field relations indicate that the stocks were emplaced after regional uplift and erosion of the Coast Range batholithic complex, and K–Ar data show that intrusion and alteration took place in late Oligocene time, about 27 to 30 Ma ago. Data from the Ketchikan quadrangle indicate that porphyry molybdenum metallization in the Coast Range batholithic complex is associated with regionally extensive but spotty, middle Tertiary or younger, felsic magmatism.

Alaska↗
USGS1955

Uranium occurrences at the Moonlight Mine and Granite Point claims, Humboldt County, Nevada

The Moonlight mine and Granite Foint claims are on the western flank of the Double H Mountains between the Kings River and Quinn, River valleys in northern Humboldt County, Nev. Uranium minerals at the Moonlight mine occur in a vein in intensely altered Tertiary volcanic rocks. The knovm uranium mineralization is spotty and erratic, but ore-grade material is present in the vein. Samples of the vein taken along its outcrop and in the mine shaft contain from less than 0.02 percent to 0.40 percent U308. The uranium minerals change from autunite at the surface to torbernite, 'gummite(?)' and pitchblende below the 90-foot level of the shaft. The Granite Point claims are two miles north of the Moonlight mine at the base of a rhyolite cliff. Radioactivity traverses made along the base and slope of the rhyolite cliff indicate that a large part of the rhyolite is abnormally radioactive. Radioactivity ranges from 0.013 to 0.3 mr/hr and averaged 0.10 mr/hr. in the vicinity of the claims. A sample taken at the base of the rhyolite cliff, at the point of highest radioactivity c6ntains 0.02 percent U3O8.

Trace Elements Memorandum↗
USGS1976

Direct dating of mineralization at Goldfield, Nevada, by potassium-argon and fission-track methods

Potassium-argon dating of hypogene alunite and K-mica from hydrothermally altered rocks at Goldfield, Nevada, yields mineralization ages of 20 to 21 m.y., in good agreement with a mineralization age established by potassium-argon dating of unaltered premineralization and postmineralization volcanic units. Premineralization volcanic units that are pervasively propylitized cannot be dated by the potassium-argon method but yield zircon fission-track ages, and in several cases yield concordant apatite fission-track ages. Two samples from premineralization units yield apatite ages concordant with the age of mineralization established by potassium-argon geochronometry, reflecting annealing of the apatite during the hydrothermal episode.Potassium-argon dating of supergene alunite samples yields imprecise ages in the range 9 to 12 m.y. that probably record the first exposure of their hydrothermally altered host rocks to oxidizing conditions. Potassium-argon dating of postmineralization basalts and silicic tuffs interbedded with conglomerates bearing altered rock clasts shows that the altered area was eroded nearly to present topographic levels by 11 m.y. ago, at which time it was covered by basalt flows now represented only by scattered remnants. Apatites from premineralization volcanic units give fission-track ages of 20 m.y. or more, indicating that no significant thermal event has affected altered rocks at Goldfield since mineralization took place.

Nevada↗
USGS1966

Isotopic study of galenas from the upper Mississippi Valley, the Illinois-Kentucky, and some Appalachian Valley mineral districts

Analyses of lead isotopes in galena in carbonate rock ore deposits collected from several mineralized districts in the Central and Eastern Interior of the United States support previous studies in establishing that the galena is anomalously radiogenic ("J"type")- This study , using care-fully selected samples to test some géologie relationships, shows region-wide and distrietwide systematic variations in isotope ratios. The genetic implications of thèse variations are discussed. Two mechanisms of origin are considered to explain thèse variations in isotopic ratios. One involves mixing of leads from multiple sources, the other calls for variable lead-isotope ratios originating from a single source. Several source materials for the lead ores have been suggested; whether a single source has predominated, or two or more main sources have predominated is still unresolved. Slopes from Pb206/Pb204 versus Pb207/Pb204 plot are compatible with a contribution of lead by the 1300 ± 300 m.y. basement rocks that underlie the deposits. The spatial relationships of alkaline igneous rocks to several of the minerai districts in the Mississippi Valley région suggest a possible mag-matic source for the lead. Isotopic analyses of galenas closely associated with several of the intrusive rocks are similar in isotopic composition to adjacent ore leads, but genetic implications are ambiguous. Galena oc-curring in shales in the Mississippi Valley région outside mineralized districts contains ordinary lead. Théories that call upon such shales to be the major source of the lead in the depoaits of the Mississippi Valley type must explain this distinct différence in isotopic compositions. Galena collected from districts within the Appalachian Ridge and Valley Province contains notably less radiogenic lead than that from the Mississippi Valley minerai districts , and the lead is of the ordinary type.

Illinois, Kentucky↗
USGS2021

Mesozoic magmatism in Montana

From crystalline batholiths with footprints larger than 4,500 km 2 to beds of micron-sized ash particles, a record of Mesozoic magmatism is found throughout Montana. Mesozoic igneous rocks are an important natural resource in the state because of their association with precious metal ores and industrial mineral deposits. Mesozoic magmatism in Montana is a tale of volcanic arc eruptions, pluton emplacement, crustal magma differentiation, melting, and assimilation. Explosive caldera-forming eruptions, magmatic hydrothermal and metamorphic mineralization, tectonic uplift, fluvial erosion, and redeposition of igneous rocks and mineral resources are all chronicled by Mesozoic igneous rocks. This article offers a summary of the types, locations, extents, and ages of Mesozoic igneous rocks in Montana. Then follows a discussion of the generation and emplacement of magmas and intrusive rocks, their geometries, and the style and timing of magmatism. The chapter ends with a summary of what remains unknown and offers suggestions for future research.

Montana↗
USGS1987

White mica geochemistry of the Catheart Mountain porphyry copper deposit, Maine

White micas from hydrothermally altered and mineralized zones in the Catheart Mountain Cu-Mo porphyry deposit have regular compositional variations that are generally related to the contents of copper, total iron, and sulfur in the whole rock. Micas in unmineralized rocks exhibit no such relationship. White mica compositions reflect primarily the control imposed by the celadonitic substitution AIIV +Aiv1 =Si+ (Fe, Mg). The variation in white mica composition in the Catheart Mountain porphyry may be explained by superposition and overprinting of mineral assemblages by ore fluids during mineralization and during the waning stages of hydrothermal alteration. Local bulk compositional differences, changing PHao and fluid compositions during mineralization, and superposition of mineral assemblages along microzoned veins contributed to variation in white mica composition. However, the general relation between white mica composition and base-metal content in the mineralized rocks at Catheart Mountain suggests that identification of this white mica population might be useful as an indicator of mineralization gradients.

Bulletin↗
USGS1996

Magmatic infiltration and melting in the lower crust and upper mantle beneath the Cima volcanic field, California

Xenoliths of lower crustal and upper mantle rocks from the Cima volcanic field (CVF) commonly contain glass pockets, veins, and planar trains of glass and/or fluid inclusions in primary minerals. Glass pockets occupy spaces formerly occupied by primary minerals of the host rocks, but there is a general lack of correspondence between the composition of the glass and that of the replaced primary minerals. The melting is considered to have been induced by infiltration of basaltic magma and differentiates of basaltic magma from complex conduits formed by hydraulic fracturing of the mantle and crustal rocks, and to have occurred during the episode of CVF magmatism between ∼7.5 Ma and present. Variable compositions of quenched melts resulted from mixing of introduced melts and products of melting of primary minerals, reaction with primary minerals, partial crystallization, and fractionation resulting from melt and volatile expulsion upon entrainment of the xenoliths. High silica melts ( >∼60% SiO 2 ) may result by mixing introduced melts with siliceous melts produced by reaction of orthopyroxene. Other quenched melt compositions range from those comparable to the host basalts to those with intermediate Si compositions and elevated Al, alkalis, Ti, P, and S; groundmass compositions of CVF basalts are consistent with infiltration of fractionates of those basalts, but near-solidus melting may also contribute to formation of glass with intermediate silica contents with infiltration only of volatile constituents.

California↗
USGS2022

Petrogenesis and rare earth element mineralization of the Elk Creek carbonatite, Nebraska, USA

Although carbonatites are the primary source of the world’s rare earth elements (REEs), the processes responsible for ore-grade REE enrichment in carbonatites are still poorly understood. In this study, we present a petrologic, geochemical, and isotopic evaluation of the Elk Creek carbonatite in southeast Nebraska to constrain the origin of REE mineralization. The Elk Creek carbonatite is a multilithologic carbonatite comprised of an early apatite-dolomite carbonatite, a middle/heavy REE-enriched magnetite-dolomite carbonatite, and a late-stage light REE-enriched, barite-dolomite carbonatite, as well as a suite of breccias. Neodymium, strontium, and carbon isotopic data from the early apatite-dolomite carbonatite, ε Nd (T) = 2.3 to 3.4, 87 Sr/ 86 Sr (i) = 0.702704 to 0.702857, and δ 13 C = −3.3 to −3.4, indicate that the parental magma and REEs were derived from the mantle, and textural and chemical data suggest that hydrothermal processes played an important role in reaching ore-grade enrichment. Higher initial 87 Sr/ 86 Sr values (∼0.7041) of REE-mineralized lithologies are evidence that these fluids were derived, in part, from meteoric water that interacted with the country rock. Modeling of the C-O isotopic data reveals that some of the isotopic variation results from closed-system Rayleigh fractionation of an evolving carbonatitic magma between 300 and 500 °C, but an excursion to heavier δ 18 O is likely the result of interaction with H 2 O-CO 2 -fluids at temperatures from 400 to 100 °C. Hydrothermal dolomite has higher 87 Sr/ 86 Sr values than early-formed magmatic dolomite, consistent with metasomatism by fluids derived, in part, from a more radiogenic source such as the Precambrian-age wall rock. Rare earth element mineralization occurs primarily in fine-grained, cavity filling minerals including monazite, bastnäsite, parisite, and synchysite along with barite, dolomite, quartz, and iron oxides. We interpret the LREE enrichment at Elk Creek to be the product of hydrothermal fluids derived from the evolving carbonatite magma and fluids from the wall rock. The REEs likely became enriched in late-stage fluids from the evolving magma as well as being remobilization by the dissolution of earlier formed minerals. Middle/heavy REE-enrichment in the magnetite-dolomite carbonatite is hosted in hydrothermal dolomite and is attributed to variations in the composition of hydrothermal fluids.

Nebraska↗
USGS1983

Ground-followup studies of the 1977 airborne electromagnetic survey in the Assifar and Mulhal areas, Wadi Bidah district, Kingdom of Saudi Arabia

Parts of four airborne electromagnetic (AEM) anomalies were selected for study in order to determine the cause of high conductivity of Precambrian rocks underlying extensive areas in the southern Wadi Bidah district, Kingdom of Saudi Arabia. In the Assifar area, which contains an ancient mine or prospect having the same name, geophysical data suggest that a mineralized body may lie beneath and immediately south of the ancient workings. Many other conductive zones detected during the course of the geophysical survey are thought to be related to metavolcanic rocks containing carbonaceous materials. Detailed geologic mapping, and possibly diamond core drilling, will be necessary to fully evaluate the area. In the Mulhal No. 2 area, located about 2 km south of the Mulhal ancient mine, geophysical studies suggest that mineralized rocks extend about 500 m along strike beneath outcrops of gossanous material. A brief review of the AEM ground-followup studies in the Wadi Bidah district suggests that most, if not all, of the AEM conductors are carbonaceous rocks. Secondary causes of conductivity are intense faulting and shearing.

Open-File Report↗
USGS2014

Geochemistry of hydrothermal alteration at the Qolqoleh gold deposit, northern Sanandaj–Sirjan metamorphic belt, northwestern Iran: Vectors to high-grade ore bodies

The Qolqoleh orogenic gold deposit in the northern part of the Sanandaj–Sirjan metamorphic belt in northwestern Iran is hosted by a steeply dipping sequence of greenschist facies Cretaceous volcano–sedimentary rocks, including mafic to intermediate metavolcanic rocks, sericite and chlorite schist, and marble. Geochemical and petrochemical data including the ∑ REE, (La/Yb) N and Eu/Eu* ratios were obtained from country rocks, ore-enveloping alteration zones, and mineralized zones to assess the nature of the trace element and rare earth element (REE) interaction between the wall rock and the mineralizing fluid. Quartz–sulfide veins at the deposit are characterized by a pyrite–pyrrhotite–chalcopyrite–sphalerite–arsenopyrite–native gold assemblage. Alteration halos border the mineralized zones and broadly comprise: (1) an outer carbonate–chlorite alteration zone in all rock types, particularly in chlorite schist; (2) a middle sericite–carbonate alteration zone in the sericite schist; and (3) an inner quartz–sulfide alteration zone in sericite schist and mafic to intermediate metavolcanic rocks. The geochemical data indicate that the concentrations of Al 2 O 3 , P 2 O 5 , TiO 2 , Y, and Zr are relatively constant, suggesting that these elements were the least mobile during hydrothermal activity. Using Al 2 O 3 as the immobile component, there is evidence for mobility of trace elements, particularly light REE, TiO 2 , and Zr in the altered wall rocks. The altered rocks show a relatively light REE depletion ((La/Yb) N ≅ 9.41), which clearly correlates with the grades of gold mineralization and intensity of the alteration (3 ppm Au). The depletion of light REE is best indicated by a decrease in (La/Yb) N as shown by ratios of 10.5 to 11.8. Wall rock decarbonation reactions during infiltration of the mineralizing fluid resulted in differential mobilization of REE, from a fluid with initially low REE content. The overall trace element geochemistry of the altered wall rock is controlled by the initial composition of the wall rocks and the ore-fluid composition. Hydrothermal ore-forming fluids are recognized as CO 2 -rich near-neutral reduced fluids with high values of H 2 S, K, and S content. Observed variability in alteration halos at the Qolqoleh deposit points to major differences in REE and trace element content in original host rocks that have interacted with a relatively similar ore fluid. Therefore, depending on the composition of each host rock lithology, the geochemistry of hydrothermal alteration (e.g., ∑ REE content and (La/Yb) N ratios) and alteration mineralogy including the carbonate–sericite–quartz–sulfide assemblages may be used as a primary tool for lithogeochemical exploration for gold deposits in northwestern Iran.

Journal of Geochemical Exploration↗
USGS1976

The zonal distribution of selected elements above the Kalamazoo porphyry copper deposit, San Manuel district, Pinal County, Arizona

There may be many as-yet-undiscovered porphyry copper deposits that exist as blind deposits deep within exposed rock bodies. The Kalamazoo porphyry copper-molybdenum deposit is a blind deposit present at depths up to at least 1,000 m (about 3,200 ft) that contains zoning features common to many of the known porphyry copper deposits found in western North and South America. As the preliminary phase in a geochemical study of the Kalamazoo deposit, whole-rock samples of core and cuttings from two drill holes have been analyzed for 60 different elements. Each hole represents a different major rock unit and each has penetrated completely through all the existing alteration zones and the ore zone. Plots of concentration vs. depth for 17 selected elements show distinct high- or low-concentration zones that are spatially related to the ore zone. For most of the ore-related elements no significant correlation with the two lithologies is apparent. The spatial distribution and abundance of elements such as Co, Cu, S, Se, Mn, Tl, Rb, Zn, B, and Li may be useful in determining the direction for exploration to proceed to locate a blind deposit. Trace element studies should be valuable in evaluating areas containing extensive outcrops of rocks with disseminated pyrite. Elemental zoning should be at least as useful as alteration-mineralization zoning for evaluating rock bodies thought to contain blind deposits similar to the Kalamazoo deposit.

Journal of Geochemical Exploration↗
USGS1971

Boulder Creek batholith, Colorado part II: Isotopic age of emplacement and morphology of zircon

Zircon separated from six rocks whose compositions spanned the range of differentiation in the Boulder Creek batholith yielded a “discordia” age of emplacement of 1725 m.y., close to the average PB 207 /Pb 206 age 1720 m.y.) and indicating that the constituent rocks are cogenetic within approximately ± 20 m.y. Statistical studies show that from 20 to 80 percent of the zircon in any one sample (1) is no-neuhedral, (2) has lower (length/width) ratios than the associated euhedral zircon, and (3) in direct contrast to the euhedral, increases markedly interior of the batholith toward contacts with the older metasediments and internal zones of contamination; it is inferred to have been “inherited” via assimilation. Unlike the noneuhedral fraction the euhedral zircon shows a linear decrease in length/width ratio with an increase in SiO 2 content of the containing rocks; it is inferred to be magmatic in origin. Regardless of the relative abundance of inherited versus magmatic zircon, all samples closely fit a single discordia chord, indicating that both zircon fractions formed at about the same time. This conclusion is compatible with field relationships that indicate the emplacement of the syntectonic Boulder Creek rocks took place during a period of metamorphism notable for the widespread development of new minerals in the country rocks. (1) Zircon from a Silver Plume Granite dike intruding the Boulder Creek batholith, (2) zircon from Silver Plume correlatives immediately to the north (Tilton and co-workers), and (3) uraninite from a probable Silver Plume correlative in the Central City district, together yield a sharply defined discordia age of emplacement of 1415 m.y. The separate “discordia” chords for the Boulder Creek and Silver Plume zirconconverge close to their lower intercepts with “concordia” indicative of a one-step lead loss during the Laramide disturbance. The Silver Plume “thermal event” left no age imprint on the Boulder Creek zircon, presumably because insufficient time had elapsed to produce significant metamictization.

Colorado↗
USGS1959

Occurrences of alunite, pyrophyllite, and clays in the Cerro La Tiza area, Puerto Rico

A deposit of hydrothermally altered rocks in the Cerro La Tiza area located between the towns of Comerio and Aguas Buenas, approximately 25 kilometers southwest of San Juan, Puerto Rico, was mapped and studied to determine the principal minerals, their extent distribution and origin, and the possibility of their economic utilization, especially in Puerto Rico. The Cerro la Tiza area is about 7 1 / 2 kilometers long, has an average width of about 1 1 / 2 kilometers and embraces a total area of approximately 15 square kilometers. The principal mineralized zone, a dike-like mass of light-colored rocks surrounded by dark-colored volcanic country rocks, occupies the crest and upper slopes of east-trending Cerro La Tiza ridge and is believed to be of Late Cretaceous or Eocene age. This zone is approximately 5,300 meters long, 430 meters wide and has an area of approximately 225 hectares (556 acres). The rocks of the mineralized zone are of mixed character and consist mainly of massive quartzose rocks and banded quartz-alunite rocks closely associated with foliated pyrophyllitic, sericitic and clayey rocks. The principal minerals in probably order of abundance are quartz, alunite, pyrophyllite, kaolin group clays (kaolinite and halloysite) and sericite. Minerals of minor abundance are native sulfure, diaspore, svanbergite (?), sunyite (?), hematite, goethite, pyrite, rutile (?) and very small quantities of unidentified minerals. The mineralized zone has broken down to deposits of earth-rock debris of Quaternary age that cover much of the slopes and flanks of Cerro La Tiza. This debris consists generally of fragments and boulders with a very large size range embedded in a clayey matrix. The distribution of the earth-rock debris with respect to the present topography and drainage suggests that it may have undergone at least two cycles of erosion. Underlying the earth-rock debris and completely enclosing the mineralized zone are country rocks of probably Late Cretaceous age. These consist principally of low flows and volcanic and flow breccias but contain thin interbedded siltstones and sandstones. The lavas are generally predominant at the western end of the area and the breccias at the eastern end. The mineralized zone and the country rocks are sheared along two predominant directions that are approximately N 70 degrees E and N 70 degrees W. The ridge of Cerro La Tiza appears to be a broad shear zone through which hydrothermal emanations gained access to the country rocks. The emanations are believed to have originated from intrusive rocks that probably underlie the area. The surrounding area contains both large and small exposed intrusive bodies. The largest one is the San Lorenzo batholith of Late Cretaceous or Eocene age whose exposed northwest edge is approximately 19 kilometers southeast of the eastern end of the Cerro La Tiza area. Other zones of hydrothermally altered rocks were discovered along a mineralized belt extending eastward from Cerro La Tiza through the Rio Gurabo Valley nearly to the Vieques Passage bordering the east coast of Puerto Rico. Other zones were discovered north and south of this belt and still others were found circumventing the San Lorenzo batholith. The most abundant minerals of the mineralized zone can be exploited for economic utilization in Puerto Rico. Alunite can be utilized in the manufacture of aluminum sulfate for water purification. It can also be used in the manufacture of alumina refractory materials. Pyrophyllite can be used as a carrier for insecticides and fungicides. It can also be utilized for the manufacture of ceramic products, as a filler in the soap industry and as a carrier for paint pigments. Kaolinite can be used in the ceramic industry and in the manufacture of glass as a substitute for feldspar. Halloysite might be utilized as a catalyst support in the cracking of petroleum. Tonnages of reserve ore on Cerro La Tiza are calculated to be 1,590,000 inferred short tons (1,440,000,000 inferred metric tons) of mixed minerals. These tonnages are based on the assumption that the depth of the mineralized zone is one-half of the exposed width. The deposit is well situated for open pit mining, but because of the existing cover of earth-rock debris, soil foliage, exploration should proceed exploitation for better determination of the most promising areas containing the best concentrations of the minerals sought.

Cerro La Tiza↗
USGS1992

Pre-Elsonian mafic magmatism in the Nain Igneous Complex, Labrador: The bridges layered intrusion

Decades of work on the pristine, unmetamorphosed, and well exposed anorthositic, mafic and granitic rocks of the Nain igneous complex, Labrador, have led to the conclusion that all plutonic rocks in that area were emplaced in a short time intercal at about 1300 ± 10 Ma). We report here new isotopic data for mafic intrusive rocks that appear to have crystallized several hundred Ma earlier than the bulk of the plutonic activity in the Nain complex. The Bridges layered intrusion (BLI) is a small (15–20 km 2 ) lens of layered mafic rocks about 1.5 km thick, surrounded and intruded by anorthositic, leuconoritic and leucotroctolitic plutons in the middle of the coastal section of the Nain igneous complex. BLI shows very well developed magmatic structures, including channel scours, slump structures, and ubiquitous modally graded layering. Most rocks, however, show granular textures indicative of recrystallization, presumably caused by emplacement of younger anorthositic rocks. BLI contains cumulate rocks with slightly more primitive mineral compositions (An 60–83 , Fo 66–71 ) than those of other mafic intrusions in the Nain igneous complex, including Kiglapait. Sm-Nd isotopic data for 7 BLI whole-rocks ranging in composition between olivine melagabbro and olivine leucogabbro yield an age of 1667 ± 75 Ma, which we interpret as the time of primary crystallization. The internal isotopic systematics of the BLI have been reset, probably by intrusion of adjacent anorthositic plutons. A SmNd mineral isochron (plag, whole-rock, mafics) for a BLI olivine melagabbro gives an age of 1283 ± 22 Ma, equivalent within error of a mineral array (plag, whole-rock, opx, cpx) for an adjacent, igneous-textured, leuconorite vein (1266 ± 152 Ma). The initial Nd ratio for BLI corresponds to ϵ Nd = −3.18 ± 0.44. Other whole-rock samples, however, some with vein-like alteration (Chlorite, serpentine, amphiboles), show ϵ Nd values as low as −9.1, suggesting variable contamination by direct assimilation of early Archean crustal rocks and/or by fluids that have interacted with such crust. Adjacent anorthositic rocks also show variable ϵ Nd some as low as −14.7, implying larger degrees if crustal assimilation, perhaps by parental magmas during lower crustal ponding prior to emplacement. These contamination effects preclude straightforward determination of the isotopic character of mantle sources for both BLI and the anorthositic rocks.

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