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Chapter 3: Changes to the Wyoming Basins landscape from oil and natural gas development

Oil and natural gas have been produced in Wyoming since the late 1800s although the rate of extraction has increased substantially in the last two decades. Well pads, roads, and infrastructure built to support resource development alter native vegetation configuration; however, the rate and effect of land cover change resulting from oil and gas extraction has not been quantified across the region. We used a Geographic Information System (GIS) to model development through time and assess change to native vegetation at two spatial extents (field and subbasin) within the Wyoming portion of the Wyoming Basins Ecoregional Assessment (WBEA) area. Since 1900, a minimum of 1,703 km 2 of native vegetation in the WBEA area has been replaced by well pads or roads. Shrublands were, and continue to be, the dominant land cover class and the cover type most affected by oil and gas extraction. Average shrubland patch size has decreased by approximately 10% at the subbasin extent in the WBEA. Core area (≥60 m from edge) size declined by 13% as road development fragmented formerly continuous patches. To date, the majority of land cover change has occurred in formally identified oil and gas fields, which cover about 1% of the WBEA in Wyoming. Approximately 7.5% of shrubland within oil and gas fields has been converted to well pad or a road supporting a well, and shrubland patch size has declined by 45%. Resource reserves, especially natural gas, have been identified outside traditional fields, and development will likely expand as resource development becomes more cost-effective. Revegetation guidelines are in place for development areas addressed by Environmental Impact Assessments although no quantitative data are available to assess how well restoration efforts are restoring landscapes and connecting fragments.

Wyoming↗

Acoustic surveys of Hawaiian Hoary Bats in Kahikinui Forest Reserve and Nakula Natural Area Reserve on the Island of Maui

The Kahikinui Forest Reserve and the adjoining Nakula Natural Area Reserve (KFR-NNAR) was established in 2011 as a conservation area on the leeward slope of Haleakalā Volcano on the island of Maui to protect unique natural features and endangered species including the Hawaiian hoary bat, Lasiurus cinereus semotus . We recorded bat vocalizations from July 2012 to November 2014 using automated echolocation detectors at 14 point locations in the KFRNNAR. Our study area included remnants of recovering mesic montane forest with interspersed grasses (1,250‒1,850 m elevation, hereafter called “forest”) and xeric subalpine shrubland plant communities (1,860‒2,800 m, hereafter called “shrubland”). Monthly detections of Hawaiian hoary bats, Lasiurus cinereus semotus , within the KFR-NNAR identified areas of high and low detection probability as well as foraging activity. Sixty per cent of all detector-nights had confirmed bat vocalizations and included detections in every month of the study. Monthly detection probability values were highest from July to November 2012; these values were significantly greater than values measured in any month thereafter. Pooled values of detection probabilities, mean pulses/night, percentage of nights with feeding activity, and acoustic detections all were greater in the recovering forest zone than corresponding values from the shrublands. Our data provide baseline levels of hoary bat echolocation activity that may be compared with future studies in the KFR-NNAR relative to success criteria for Hawaiian hoary bat habitat restoration.

Hawaii↗

U.S. Geological Survey research in Handcart Gulch, Colorado—An alpine watershed with natural acid-rock drainage

Handcart Gulch is an alpine watershed along the Continental Divide in the Colorado Rocky Mountain Front Range. It contains an unmined mineral deposit typical of many hydrothermal mineral deposits in the intermountain west, composed primarily of pyrite with trace metals including copper and molybdenum. Springs and the trunk stream have a natural pH value of 3 to 4. The U.S. Geological Survey began integrated research activities at the site in 2003 with the objective of better understanding geologic, geochemical, and hydrologic controls on naturally occurring acid-rock drainage in alpine watersheds. Characterizing the role of groundwater was of particular interest because mountain watersheds containing metallic mineral deposits are often underlain by complexly deformed crystalline rocks in which groundwater flow is poorly understood. Site infrastructure currently includes 4 deep monitoring wells high in the watershed (300– 1,200 ft deep), 4 bedrock (100–170 ft deep) and 5 shallow (10–30 ft deep) monitoring wells along the trunk stream, a stream gage, and a meteorological station. Work to date at the site includes: geologic mapping and structural analysis; surface sample and drill core mineralogic characterization; geophysical borehole logging; aquifer testing; monitoring of groundwater hydraulic heads and streamflows; a stream tracer dilution study; repeated sampling of surface and groundwater for geochemical analyses, including major and trace elements, several isotopes, and groundwater age dating; and construction of groundwater flow models. The unique dataset collected at Handcart Gulch has yielded several important findings about bedrock groundwater flow at the site. Most importantly, we find that bedrock bulk permeability is nontrivial and that bedrock groundwater apparently constitutes a substantial fraction of the hydrologic budget. This means that bedrock groundwater commonly may be an underappreciated component of the hydrologic system in studies of alpine watersheds. Additionally, despite the complexity of the fracture controlled aquifer system, it appears that it can be represented with a relatively simple conceptual model and can be treated as an equivalent porous medium at the watershed scale. Interpretation of existing data, collection of new monitoring data, and efforts to link geochemical and hydrologic processes through modeling are ongoing at the site.

Colorado↗

Developmental instability as an indicator of natural stress on the Pacific Hake (Merlussius productus)

Developmental lnstability (DI) has been proposed as an inexpensive, quickly applied, and sensitive indicator of stress that can be utilized in early warning and in monitoring anthropogenic impacts on fish and other animals and plants. A problem arises, however, to the extent that natural stressors confound the effects of human-induced disturbances. Our objective in this work was to investigate whether a natural stressor, in the form of EI Nino conditions, contributed to DI in the Pacific hake. Right-left (fluctuating> asymmetry of otolith length, width, growth rate, and weight, as well as right-left otolith shape differences, were used as measures of DI. Results show that indeed EI Nino disrupts development, indicating stress. This outcome suggests that DI, as an early warning and monitoring tool for stress, must be used with caution.

Fishery Bulletin↗

A ponderosa pine natural area reveals its secrets

Monument Canyon Research Natural Area preserves an unlogged 259-hectare stand of old-growth ponderosa pine in the Jemez Mountains of New Mexico. This preserve, established in 1932, is the oldest research natural area in the state. This two-tiered forest displays an old-growth density of 100 stems per hectare (Muldavin et al. 1995), with an understory thicket of stagnant saplings and poles that raises the total stand density to an average of 5,954 stems per hectare, with concentrations as high as 21,617 stems per hectare (Fig. 1).

New Mexico↗

Structural equation modeling and natural systems

This book, first published in 2006, presents an introduction to the methodology of structural equation modeling, illustrates its use, and goes on to argue that it has revolutionary implications for the study of natural systems. A major theme of this book is that we have, up to this point, attempted to study systems primarily using methods (such as the univariate model) that were designed only for considering individual processes. Understanding systems requires the capacity to examine simultaneous influences and responses. Structural equation modeling (SEM) has such capabilities. It also possesses many other traits that add strength to its utility as a means of making scientific progress. In light of the capabilities of SEM, it can be argued that much of ecological theory is currently locked in an immature state that impairs its relevance. It is further argued that the principles of SEM are capable of leading to the development and evaluation of multivariate theories of the sort vitally needed for the conservation of natural systems.

Book↗

Behavioral avoidance as evidence of injury to fishery resources: Applications to natural resource damage assessment

Natural Resource Damage Assessment (NRDA) provisions enacted under Comprehensive Environmental Response Compensation and Liability Act (CERCLA) and the Oil Pollution Act (OPA) empower natural resource trustees to seek compensation for environmental injury resulting from the release of oil or hazardous substances. Under NRDA regulations promulgated under CERCLA, fish avoidance behavior is recognized as an accepted injury, and may be used to support damage claims. In support of an ongoing damage assessment, tests were conducted to determine if avoidance of ambient metals concentrations may contribute to reductions in local salmonid populations. In laboratory tests, rainbow trout ( Oncorhynchus mykiss ) and brown trout ( Salmo trutta ) avoided mixtures of metals (Cd, Cu, Pb, and Zn) at concentrations that occur in impacted river reaches at a contaminated site (Clark Fork River, MT). Avoidance of metal contamination may contribute to population reductions and preclude restoration of instream populations by prohibiting movement of fish into contaminated areas of the river from uncontaminated tributaries. Laboratory avoidance tests were performed at two testing facilities. The similar avoidance responses observed at the two laboratories demonstrated the reproducibility of avoidance measures.

Book chapter↗

The Moquah Barrens Research Natural Area: Loss of a pine barrens ecosystem

The Moquah Barrens Research Natural Area (RNA) was established by the Chequamegon National Forest and the Lakes States Forest Experiment Station in 1935 with a research objective well-suited to the needs of the Forest Service and the scientific understanding of ecosystem function prevalent at the time of establishment. The original research plan was never implemented, which led to a joint Forest-Station decision in 1956 to disestablish the RNA. However, that decision was never implemented. A series of management decisions made after 1956 led to the loss of the pine barrens ecosystem originally encompassed by the RNA. This loss is not irretrievable and the work necessary to recover the original ecosystem is possible under existing RNA management guidelines. The experience of the Moquah Barrens RNA can be used by the Forest Service to improve overall management of the entire system of research natural areas. Two main areas of opportunity are identified: 1) implement an improved approach to managing official records associated with RNAs; and 2) adopt a management framework suitable for long-term ecological projects.

Wisconsin↗

Validation of stable isotope ratio analysis to document the biodegradation and natural attenuation of RDX, ESTCP Project ER-201208

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) is a common soil contaminant at current and former military facilities, including many training and testing ranges. Because RDX is readily transported through soils to the subsurface, this nitramine explosive now also impacts groundwater and drinking water at numerous locations across the country. A significant issue with RDX contamination on ranges and at other military installations is that it often occurs over expansive areas, where in situ or ex situ treatment technologies are difficult to implement. One potential alternative for military ranges and other facilities is monitored natural attenuation (MNA), in which contaminant degradation by natural processes, including biodegradation, are evaluated. However, one limitation of this approach for RDX is the inability to accurately evaluate whether the nitramine is biodegrading under field conditions, as rates may be relatively slow. One potential technique to overcome this limitation is the use of compound-specific stable isotope analysis (CSIA), where biological contaminant destruction can be documented as changes in the ratio of stable isotopes of specific elements in a molecule; for RDX, ratios of 15 N/ 14 N and 13 C/ 12 C are relevant. The objective of this project is to validate a CSIA method to confirm and constrain rates of aerobic and anaerobic biodegradation of RDX at field sites. This technique can be utilized by DoD to provide critical data to support MNA as a remedy for treating this energetic in groundwater, and confirm the effectiveness of in situ enhanced bioremediation remedies. The stable isotopic composition of NO 3 - and NO 2 - was also measured when these anions co-occurred with RDX to evaluate whether these potential degradation products from RDX could be used to further demonstrate MNA in the field.

Report↗

Natural bitumen and extra-heavy oil

Crude oil is found in sedimentary rocks throughout the world, except, thus far, in Antarctica. In many places the oil has been degraded, so that it is represented by viscous black oil that is difficult to recover, transport, and refine. Depending upon the degree of degradation the result is extra-heavy oil or, in the extreme case, natural bitumen. Except in Canada, precise quantitative reserves and oilin-place data on a reservoir basis are seldom available because most countries and companies consider such information to be proprietary. Natural bitumen is the oil contained in clastic and carbonate reservoir rocks, most frequently in small deposits at, or near, the earth’s surface. These rocks are commonly referred to as tar sands or oil sands and have been mined since antiquity for use as paving. Occasionally such deposits are extremely large in areal extent and in contained resources, most notably those in northern Alberta, Canada. In 2003 only the Alberta bitumen deposits were being exploited as a source of crude oil. Similarly, reservoirs containing extra-heavy oil are geographically widespread but only one such deposit is sufficiently large to have a major supply and economic impact. That deposit is the Orinoco Oil Belt in Eastern Venezuela. Nowhere else in the world is such a concentration of extra heavy oil known or likely to exist. Definitions of terms used in this commentary may be found immediately prior to Table 4.1. The resource definitions are those of the World Petroleum Congress-Society of Petroleum Engineers-American Association of Petroleum Geologists, with minor additions. One such addition, e.g. is the term Original Reserves, comprised of Proved Reserves plus Cumulative Production, which tends to place new and mature reservoirs on a more nearly comparable basis than either term alone

Conference Paper↗

Alaska natural gas hydrate production testing: Test site selection, characterization and testing operations

This Interagency Agreement supports the U.S. Department of Energy (DOE) and its research partners in understanding, predicting, and testing the recoverability and potential production characteristics of onshore natural gas hydrate in the Greater Prudhoe Bay area on the Alaska North Slope (ANS: Prudhoe Bay, Kuparuk River, and Milne Point areas) or other areas deemed suitable by DOE and USGS for potential long-term production testing of gas hydrate. Researchers will accomplish these tasks by evaluating the occurrence and resource potential of the known gas hydrate accumulations in the Eileen trend. Geologic, geochemical, and geophysical (2-D and 3-D seismic surveys) data from northern Alaska and other data sources, including wireline and mud log surveys of wells of opportunity, will be used to assess the occurrence and nature of the known gas hydrate accumulations. The project involves two primary areas of effort: the geologic and engineering assessment of the Eileen gas-hydrate accumulation and support of DOE and its industry partners in evaluating, planning, and preparing for drilling and testing gas hydrate research wells in northern Alaska.

Alaska↗

Quantitative modeling of secondary migration: Understanding the origin of natural gas charge of the Haynesville Formation in the Sabine Uplift area of Louisiana and Texas

The Upper Jurassic (Kimmeridgian) mudstones of the Haynesville Formation in the Sabine Uplift, Louisiana and Texas, are widely considered to be a self-sourced natural gas reservoir; however, additional sources of gas may have charged the mudstones in the Louisiana portion of the uplift. Secondary migration of hydrocarbons into the Sabine Uplift from downdip, gas-generating Jurassic source rocks in the North Louisiana Salt Basin was quantitively modeled in this study. Jurassic source rocks include the Smackover, Haynesville, and Bossier Formations. Thermodynamic equations of state were used to determine thermophysical properties of supercritical methane and water under reservoir conditions. A time-dependent derivation of Darcy’s Law for pressure-driven laminar fluid flow through porous media was used to model secondary migration at reservoir conditions. This study indicates secondary migration requires approximately 100,000 yr for pore fluids to migrate through 1.0 km of carrier beds having representative petrophysical, fluid, and reservoir properties of the Haynesville Formation. As an example migration pathway, the distance from the middle of the North Louisiana Salt Basin to the center of the Sabine Uplift is approximately 96 mi (155 km). Given migration velocities over this distance, 15.5 m.y. is required for hydrocarbons to migrate from the North Louisiana Salt Basin and charge the Haynesville Formation in the Sabine Uplift. This study also indicates supercritical water is 6 times more thermally conductive than methane under reservoir conditions; however, the relatively small volumes of migrated water likely did not transfer sufficient heat for the metagenesis of methane. Based on this study, a component of natural gas charging the Haynesville Formation of the Sabine Uplift area can reasonably be explained by lateral migration and hydrodynamic flow from thermally mature Jurassic source rocks located in adjacent basins.

Louisiana, Texas↗

Biology and conservation of the common murre in California, Oregon, Washington, and British Columbia: Vol. 1, Natural history and population trends

Over the past 30 years, the common murre ( Uria aalge californica ) has been recognized as a prominent indicator of marine conservation issues in California, Oregon, Washington, and British Columbia, especially regarding oil pollution, certain fisheries, and human disturbance. To assist the effective management of the common murre and the marine environments in which they live, this summary of available information on the biology and regional status of the common murre has been sponsored by the U.S. Fish and Wildlife Service (Division of Migratory Bird Management). In Volume 1 (Chapter 1), the natural history of the common murre is summarized, drawing heavily on breeding studies from the South Farallon Islands, California, plus a host of detailed breeding studies from the North Atlantic Ocean. Population trends of the common murre are summarized in Volume 1 (Chapter 2), focusing on changes in whole-colony counts determined from aerial photographs between the late 1970s and 1995 in California, Oregon and Washington. Historical data and human impacts to murre colonies since the early nineteenth century are also summarized. Volume 2 will summarize population threats, conservation, and management. Information presented in Volume 1 has been obtained and recorded by a large number of researchers and natural historians over two centuries. From the 1960s to 1995, most work in California, Oregon, and Washington was sponsored by the U.S. Fish and Wildlife Service, Minerals Management Service, and California Department of Fish and Game. Important breeding biology studies were conducted at the South Farallon Islands (Farallon National Wildlife Refuge) by the Point Reyes Bird Observatory, in coordination with the U.S. Fish and Wildlife Service (San Francisco Bay National Wildlife Refuge). Colony surveys in California were conducted mainly by the U.S. Fish and Wildlife Service (San Francisco Bay National Wildlife Refuge), U.S. Geological Survey (Western Ecological Research Center, Dixon Field Station), Humboldt State University, and University of California (Santa Cruz). Colony surveys in Oregon and Washington were conducted mainly by the U.S. Fish and Wildlife Service (Oregon Coast National Wildlife Refuge and Washington Maritime National Wildlife Refuges). In British Columbia, most work from the 1960s to 1995 was sponsored and conducted by the Canadian Wildlife Service and Royal British Columbia Museum.

British Columbia, California, Oregon, Washington↗

Applications of natural language processing to geoscience text data and prospectivity modelling

Geological maps are powerful models for visualizing the complex distribution of rock types through space and time. However, the descriptive information that forms the basis for a preferred map interpretation is typically stored in geological map databases as unstructured text data that are difficult to use in practice. Herein we apply natural language processing (NLP) to geoscientific text data from Canada, the U.S., and Australia to address that knowledge gap. First, rock descriptions, geological ages, lithostratigraphic and lithodemic information, and other long-form text data are translated to numerical vectors, i.e., a word embedding, using a geoscience language model. Network analysis of word associations, nearest neighbors, and principal component analysis are then used to extract meaningful semantic relationships between rock types. We further demonstrate using simple Naive Bayes classifiers and the area under receiver operating characteristics plots (AUC) how word vectors can be used to: (1) predict the locations of “pegmatitic” (AUC = 0.962) and “alkalic” (AUC = 0.938) rocks; (2) predict mineral potential for Mississippi-Valley-type (AUC = 0.868) and clastic-dominated (AUC = 0.809) Zn-Pb deposits; and (3) search geoscientific text data for analogues of the giant Mount Isa clastic-dominated Zn-Pb deposit using the cosine similarities between word vectors. This form of semantic search is a promising NLP approach for assessing mineral potential with limited training data. Overall, the results highlight how geoscience language models and NLP can be used to extract new knowledge from unstructured text data and reduce the mineral exploration search space for critical raw materials.

Natural Resources Research↗

Worldwide estimates of deep natural gas resources based on the U.S. Geological Survey World Petroleum Assessment 2000

The U.S. Geological Survey recently assessed undiscovered conventional gas and oil resources in eight regions of the world outside the U.S. The resources assessed were those estimated to have the potential to be added to reserves within the next thirty years. This study is a worldwide analysis of the estimated volumes and distribution of deep (>4.5 km or about 15,000 ft), undiscovered conventional natural gas resources based on this assessment. Two hundred forty-six assessment units in 128 priority geologic provinces, 96 countries, and two jointly held areas were assessed using a probabilistic Total Petroleum System approach. Priority geologic provinces were selected from a ranking of 937 provinces worldwide. The U.S. Geological Survey World Petroleum Assessment Team did not assess undiscovered petroleum resources in the U.S. For this report, mean estimated volumes of deep conventional undiscovered gas resources in the U.S. are taken from estimates of 101 deep plays (out of a total of 550 conventional plays in the U.S.) from the U.S. Geological Survey's 1995 National Assessment of Oil and Gas Resources. A probabilistic method was designed to subdivide gas resources into depth slices using a median-based triangular probability distribution as a model for drilling depth to estimate the percentages of estimated gas resources below various depths. For both the World Petroleum Assessment 2000 and the 1995 National Assessment of Oil and Gas Resources, minimum, median, and maximum depths were assigned to each assessment unit and play; these depths were used in our analysis. Two-hundred seventy-four deep assessment units and plays in 124 petroleum provinces were identified for the U.S. and the world. These assessment units and plays contain a mean undiscovered conventional gas resource of 844 trillion cubic ft (Tcf) occuring at depths below 4.5 km. The deep undiscovered conventional gas resource (844 Tcf) is about 17% of the total world gas resource (4,928 Tcf) based on the provinces assessed and includes a mean estimate of 259 Tcf of U.S. gas from the U.S. 1995 National Assessment. Of the eight regions, the Former Soviet Union (Region 1) contains the largest estimated volume of undiscovered deep gas with a mean resource of343 Tcf.

Natural Resources Research↗

Study of natural glasses through their behaviour as membrane electrodes

THE low-temperature chemical alteration of natural glass occurs in two stages: an initial stage in which it remains glassy but absorbs as much as 6 per cent water 1 , and a final stage in which devitrification to clay minerals, with release of silica, occurs 2,3 . During the first stage the composition of the glass may change, with gain of K 2 O and water and loss of Na 2 O (Smith, R. L., personal communication). This change is due to ion exchange.

Nature↗

Influence of coupling of sorption and photosynthetic processes on trace element cycles in natural waters

Chemical and biological processes have important roles in the transport and cycling of trace elements in natural waters, but their complex interactions are often not well understood. Trace-element concentrations may, for example, be controlled by adsorption-desorption reactions at mineral surfaces, with the equilibrium strongly influenced by pH. Variations in pH due to photosynthetic activity should result in concentration fluctuations as the adsorption-desorption equilibrium shifts with pH. To investigate these interactions, we have studied the effect of diurnal cycling of pH on dissolved arsenate in a perennial stream contaminated with arsenic. As expected, a diurnal cycle in arsenate concentration was observed, but surprisingly, the arsenate cycle lags several hours behind the pH cycle. Laboratory experiments show that the lag results from a slow approach to sorption equilibrium. Our observations demonstrate that the coupling of photosynthesis and sorption processes may have an important influence on the cycling of many trace elements and emphasize the importance of understanding sorption kinetics in modelling these processes.

Nature↗

Natural occurrence of silicon carbide in a diamondiferous kimberlite from Fuxian

Considerable debate surrounds the existence of silicon carbide in nature, mostly owing to the problem of possible contamination by man-made SiC. Recently, Gurney 1 reviewed reports of rare SiC inclusions in diamonds, and noted that SiC can only be regarded as a probable rather than proven cogenetic mineral. Here we report our observation of clusters of SiC coexisting with diamond in a kimberlite from Fuxian, China. Macrocrysts of α-SiC are overgrown epitaxially by β-SiC, and both polymorphs are structurally well ordered. We have also measured the carbon isotope compositions of SiC and diamonds from Fuxian. We find that SiC is more enriched in 12 C than diamond by 20‰, relative to the PDB standard. Isotope fractionation might have occurred through an isotope exchange reaction in a common carbon reservoir. Silicon carbide may thus ultimately provide information on carbon cycling in the Earth's mantle.

Nature↗