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At least 739 records · Page 41Linked to original sources
USGS2010

Chemical and textural controls on phosphorus mobility in drylands of southeastern Utah

We investigated several forms of phosphorus (P) in dryland soils to examine the chemical and textural controls on P stabilization on a diverse set of substrates. We examined three P fractions including labile, moderately labile, and occluded as determined by a modified Hedley fractionation technique. The P fractions were compared to texture measurements and total elemental concentrations determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Labile P related to the absence of materials involved in P sorption. Moderately labile P was most strongly associated with high total Al & Fe content that we interpret to represent oxides and 1:1 clay minerals. The occluded P fraction was strongly associated with low total Al & Fe environments and interpreted to represent 2:1 clay minerals where ligand exchange tightly sequesters P. The results indicate that the controls on P fraction distribution are initially closely tied to the chemical and physical properties of the bedrock units that contribute to soil formation. Further, these results suggest that the progression of stabilized P forms in dryland areas differs from the progression observed in mesic environments. Soil development in dryland settings, such as the formation of pedogenic carbonates, may lead to differing controls on P availability and the proportional size of the moderately labile fraction.

Utah↗
USGS2018

Improving understanding of soil organic matter dynamics by triangulating theories, measurements, and models

Soil organic matter (SOM) turnover increasingly is conceptualized as a tension between accessibility to microorganisms and protection from decomposition via physical and chemical association with minerals in emerging soil biogeochemical theory. Yet, these components are missing from the original mathematical models of belowground carbon dynamics and remain underrepresented in more recent compartmental models that separate SOM into discrete pools with differing turnover times. Thus, a gap currently exists between the emergent understanding of SOM dynamics and our ability to improve terrestrial biogeochemical projections that rely on the existing models. In this opinion paper, we portray the SOM paradigm as a triangle composed of three nodes: conceptual theory, analytical measurement, and numerical models. In successful approaches, we contend that the nodes are connected—models capture the essential features of dominant theories while measurement tools generate data adequate to parameterize and evaluate the models—and balanced—models can inspire new theories via emergent behaviors, pushing empiricists to come up with new measurements. Many exciting advances recently pushed the boundaries on one or more nodes. However, newly integrated triangles have yet to coalesce. We conclude that our ability to incorporate mechanisms of microbial decomposition and physicochemical protection into predictions of SOM change is limited by current disconnections and imbalances among theory, measurement, and modeling. Opportunities to reintegrate the three components of the SOM paradigm exist by carefully considering their linkages and feedbacks at specific scales of observation.

Biogeochemistry↗
USGS2009

Water quality of least-impaired lakes in eastern and southern Arkansas

A three-phased study identified one least-impaired (reference) lake for each of four Arkansas lake classifications: three classifications in the Mississippi Alluvial Plain (MAP) ecoregion and a fourth classification in the South Central Plains (SCP) ecoregion. Water quality at three of the least-impaired lakes generally was comparable and also was comparable to water quality from Kansas and Missouri reference lakes and Texas least-impaired lakes. Water quality of one least-impaired lake in the MAP ecoregion was not as good as water quality in other least-impaired lakes in Arkansas or in the three other states: a probable consequence of all lakes in that classification having a designated use as a source of irrigation water. Chemical and physical conditions for all four lake classifications were at times naturally harsh as limnological characteristics changed temporally. As a consequence of allochthonous organic material, oxbow lakes isolated within watersheds comprised of swamps were susceptible to low dissolved oxygen concentrations to the extent that conditions would be limiting to some aquatic biota. Also, pH in lakes in the SCP ecoregion was <6.0, a level exceeding current Arkansas water-quality standards but typical of black water systems. Water quality of the deepest lakes exceeded that of shallow lakes. N/P ratios and trophic state indices may be less effective for assessing water quality for shallow lakes (<2 m) than for deep lakes because there is an increased exposure of sediment (and associated phosphorus) to disturbance and light in the former. ?? 2009 Springer Science+Business Media B.V.

Environmental Monitoring and Assessment↗
USGS2010

Response of algal metrics to nutrients and physical factors and identification of nutrient thresholds in agricultural streams

Many streams within the United States are impaired due to nutrient enrichment, particularly in agricultural settings. The present study examines the response of benthic algal communities in agricultural and minimally disturbed sites from across the western United States to a suite of environmental factors, including nutrients, collected at multiple scales. The first objective was to identify the relative importance of nutrients, habitat and watershed features, and macroinvertebrate trophic structure to explain algal metrics derived from deposition and erosion habitats. The second objective was to determine if thresholds in total nitrogen (TN) and total phosphorus (TP) related to algal metrics could be identified and how these thresholds varied across metrics and habitats. Nutrient concentrations within the agricultural areas were elevated and greater than published threshold values. All algal metrics examined responded to nutrients as hypothesized. Although nutrients typically were the most important variables in explaining the variation in each of the algal metrics, environmental factors operating at multiple scales also were important. Calculated thresholds for TN or TP based on the algal metrics generated from samples collected from erosion and deposition habitats were not significantly different. Little variability in threshold values for each metric for TN and TP was observed. The consistency of the threshold values measured across multiple metrics and habitats suggest that the thresholds identified in this study are ecologically relevant. Additional work to characterize the relationship between algal metrics, physical and chemical features, and nuisance algal growth would be of benefit to the development of nutrient thresholds and criteria.

Environmental Monitoring and Assessment↗
USGS2018

The influence of land-cover changes on the variability of saturated hydraulic conductivity in tropical peatlands

Understanding the movement of water through peat is essential for effective conservation and management strategies for peatlands. Saturated hydraulic conductivity, K s , describes water movement through the peat profile. However, the spatial variability of K s in tropical peatlands and the effects of land conversion on peat characteristics are poorly understood. Utilizing the slug test method, we estimated hydraulic conductivity in tropical peatlands in West Kalimantan, Indonesia, at three depths (0.75, 3.5, and 5.5 m) across four different land-cover types (undrained forests, recently burned forests, early seral communities, and oil palm ( Elaeis guineensis Jacq.) plantations). We found strong spatial autocorrelation among measurements collected at our 19 study sites and evaluated the relationship between hydraulic conductivity and land-cover types, peat properties, and depth of measurement with a hierarchical linear model. Hydraulic conductivity varied greatly ( c. 0.001–13.9 m d −1 ). The best approximating model for estimating K s contained depth, forest cover, a depth and forest cover interaction, and the von Post degree of decomposition ( K s ~ depth + forest + depth × forest + von Post). Parameter estimates indicated that K s was greater in forested than non-forested sites and decreased with increasing depth and decomposition stage. There was no evidence that K s differed among the non-forested sites or was related to other physical and chemical peat properties. Our results suggest that K s should be measured directly in tropical peatlands rather than estimated as a function of peat properties. Additionally, the strong spatial dependence suggests that similar research designs should examine the sample data for spatial dependence and, if necessary, incorporate hierarchical models.

Mitigation and Adaption Strategies for Global Chan↗
USGS2004

Landsat TM inventory and assessment of waterbird habitat in the southern altiplano of South America

The diverse set of wetlands in southern altiplano of South America supports a number of endemic and migratory waterbirds. These species include endangered endemic flamingos and shorebirds that nest in North America and winter in the altiplano . This research developed maps from nine Landsat Thematic Mapper (TM) images (254,300 km 2 ) to provide an inventory of aquatic waterbird habitats. Image processing software was used to produce a map with a classification of wetlands according to the habitat requirements of different types of waterbirds. A hierarchical procedure was used to, first, isolate the bodies of water within the TM image; second, execute an unsupervised classification on the subsetted image to produce 300 signatures of cover types, which were further subdivided as necessary. Third, each of the classifications was examined in the light of field data and personal experience for relevance to the determination of the various habitat types. Finally, the signatures were applied to the entire image and other adjacent images to yield a map depicting the location of the various waterbird habitats in the southern altiplano . The data sets referenced with a global positioning system receiver were used to test the classification system. Multivariate analysis of the bird communities censused at each lake by individual habitats indicated a salinity gradient, and then the depth of the water separated the birds. Multivariate analysis of the chemical and physical data from the lakes showed that the variation in lakes were significantly associated with difference in depth, transparency, latitude, elevation, and pH. The presence of gravel bottoms was also one of the qualities distinguishing a group of lakes. This information will be directly useful to the Flamingo Census Project and serve as an element for risk assessment for future development.

Wetlands Ecology and Management↗
USGS2025

Evaluating uncertainties with sample-collection method and source selection in sediment fingerprinting: an example from a Great Lakes tributary

Purpose Identifying suspended-sediment (SS) sources, seasonal variability, and phosphorus (P) transported with SS is critical information for basin managers, although there may be concerns about comparability between flow-integrated SS samples used for sediment fingerprinting and discrete samples used for concentrations and loads in basins where SS is mostly silt + clay and(or) one land-use predominates. Objectives were to determine if (1) sample-collection method and (2) source consideration influenced apportionment of the largest SS source. Methods Concurrent-replicate, SS samples were collected during 2022 from the East River, Wisconsin using an automated sampler, commonly used for water-quality sampling, and passive samplers, frequently used for SS fingerprinting. Samples were evaluated for differences in physical and chemical characteristics that may affect source apportionment. Considered sources included three upland land-use (cropland, forest, and roads), two in-channel (streambank and streambed sediment), and one that connects uplands to the stream channel (gullies). Source apportionment used established methods in the SedSAT tool. Source scenarios included land-use + streambank (4src), 4src + gully, 4src + streambed, and 4src + gully + streambed (6src). Results There were no statistically significant differences in median grain size, organic carbon, or sediment-bound P as a function of collection method. In-channel sources were the largest proportional SS source, regardless of season, hydrologic condition, collection method, or source scenario. Source verification highlighted which source fingerprints were most accurately defined and implications for SS target apportionment. Conclusion Varying the source scenarios for sediment fingerprinting indicated that improved management of hydrologic connectivity between upland land use and the stream channel has the potential to mitigate SS loads.

Wisconsin↗
USGS2022

Whole-ecosystem experiment illustrates short timescale hydrodynamic, light, and nutrient control of primary production in a terminal slough

Estuaries are among the most productive of aquatic ecosystems. Yet the collective understanding of patterns and drivers of primary production in estuaries is incomplete, in part due to complex hydrodynamics and multiple controlling factors that vary at a range of temporal and spatial scales. A whole-ecosystem experiment was conducted in a deep, pelagically dominated terminal channel of the Sacramento-San Joaquin Delta (California, USA) that seasonally appears to become nitrogen limited, to test whether adding calcium nitrate would stimulate primary productivity or increase phytoplankton density. Production did not respond consistently to fertilization, in part because nitrate and phytoplankton were dispersed away from the manipulated area within 1–3 days. Temporal and spatial patterns of gross primary production were more strongly related to stratification and light availability (i.e., turbidity) than nitrogen, highlighting the role of hydrodynamics in regulating system production. Similarly, chlorophyll was positively related not only to stratification but also to nitrogen—with a positive interaction—suggesting stratification may trigger nutrient limitation. The average rate of primary production (4.3 g O 2 m −2 d −1 ), metabolic N demand (0.023 mg N L −1 d −1 ), and ambient dissolved inorganic nitrogen concentration (0.03 mg N L −1 ) indicate that nitrogen can become limiting in time and space, especially during episodic stratification events when phytoplankton are isolated within the photic zone, or farther upstream where water clarity increases, dispersive flux decreases, and stratification is stronger and more frequent. The role of hydrodynamics in organizing habitat connectivity and regulating physical and chemical processes at multiple temporal and spatial scales is critical for determining resource availability and evaluating biogeochemical processes in estuaries.

California↗
USGS2019

Identifying natural and anthropogenic variability of uranium at the well scale, Homestake Superfund site, near Milan, New Mexico, USA

The San Mateo Creek Basin in New Mexico, USA is located within the Grants Mineral Belt-an area with numerous uranium (U) ore deposits, mines, and milling operations. Six monitoring wells set in an alluvial aquifer near the Homestake Mining Co. Superfund site in the lower San Mateo Creek Basin were logged with a suite of borehole geophysical tools including spectral gamma-ray (SGR), vertically profiled with passive samplers for U and selenium (Se) concentrations, and purged sampled for same constituents. The integrated approach allowed for an assessment on the role of heterogeneity (both physical and chemical) in determining U concentrations in groundwater. Uranium, as measured with SGR logging, is ubiquitous in the alluvial aquifer and the underlying Chinle Group. Aqueous U concentrations appear to be inversely related to thorium (Th) concentrations, as measured by the SGR log, indicating the possibility that U is bound in or adsorbed to clays in the aquifer. The stratigraphy of the alluvium likely plays a role in elevated concentrations of aqueous U. Interbedded clay and sand layers allow for the mobilization of U in oxic sandy layers from U adsorbed in sediments in reduced clay layers. The stratigraphy also plays a role in the degree of mixing of groundwater in the formation and well. Mixing can obscure the ability to identify U sources. Mixing is exacerbated by the relatively long screens (> 20 ft long or > 6.1 m) of the monitoring wells.

New Mexico↗
USGS1987

Critical behavior of dilute NaCl in H2O

The compositions of the saturated vapor and liquid phases are measured for the system NaCl-H 2 O at 380°C, which is close to the critical point of pure water. The shape of the phase equilibrium curve is classical, which confirms a conclusion reached earlier on the basis of less accurate data. This implies that the long-range forces introduced by the NaCl suppress the non-classical effects present in pure H 2 O. An empirical equation of a classical type fits these data.

Chemical Physics Letters↗
USGS1989

Artificial recharge of groundwater and its role in water management

This paper summarizes and discusses the various aspects and methods of artificial recharge with particular emphasis on its uses and potential role in water management in the Arabian Gulf region. Artificial recharge occurs when man's activities cause more water to enter an aquifer, either under pumping or non-pumping conditions, than otherwise would enter the aquifer. Use of artificial recharge can be a practical means of dealing with problems of overdraft of groundwater. Methods of artificial recharge may be grouped under two broad types: (a) water spreading techniques, and (b) well-injection techniques. Successful use of artificial recharge requires a thorough knowledge of the physical and chemical characteristics of the aquifier system, and extensive onsite experimentation and tailoring of the artificial-recharge technique to fit the local or areal conditions. In general, water spreading techniques are less expensive than well injection and large quantities of water can be handled. Water spreading can also result in significant improvement in quality of recharge waters during infiltration and movement through the unsaturated zone and the receiving aquifer. In comparison, well-injection techniques are often used for emplacement of fresh recharge water into saline aquifer zones to form a manageable lens of fresher water, which may later be partially withdrawn for use or continue to be maintained as a barrier against salt-water encroachment. A major advantage in use of groundwater is its availability, on demand to wells, from a natural storage reservoir that is relatively safe from pollution and from damage by sabotage or other hostile action. However, fresh groundwater occurs only in limited quantities in most of the Arabian Gulf region; also, it is heavily overdrafted in many areas, and receives very little natural recharge. Good use could be made of artificial recharge by well injection in replenishing and managing aquifers in strategic locations if sources of freshwater could be made available for the artificial-recharge operations.

Desalination↗
USGS1987

Evidence for Late-Paleozoic brine migration in Cambrian carbonate rocks of the central and southern Appalachians: Implications for Mississippi Valley-type sulfide mineralization

Many Lower Paleozoic limestones and dolostones in the Valley and Ridge province of the central and southern Appalachians contain 10 to 25 weight percent authigenic potassium feldspar. This was considered to be a product of early diagenesis, however, 40 Ar 39 Ar "> 40 Ar 39 Ar analyses of overgrowths on detrital K-feldspar in Cambrian carbonate rocks from Pennsylvania, Maryland, Virginia, and Tennessee yield Late Carboniferous-Early Permian ages (278–322 Ma). Simple mass balance calculations suggest that the feldspar could not have formed isochemically, but required the flux of multiple pore volumes of fluid through the rocks, reflecting regional fluid migration events during the Late-Paleozoic Alleghanian orogeny. Microthermometric measurements of fluid inclusions in overgrowths on detrital K-feldspar and quartz grains from unmineralized rocks throughout the study area indicate homogenization temperatures from 100° to 200°C and freezing point depressions of −14° to −18.5°C (18–21 wt.% NaCl equiv). The apparent similarity of these fluids to fluid inclusions in ore and gangue minerals of nearby Mississippi Valley-type (MVT) deposits suggests that the regional occurrences of authigenic K-feldspar and MVT mineralization may be genetically related. This hypothesis is supported by the discovery of authigenic K-feldspar intergrown with sphalerite in several mines of the Mascot-Jefferson City District, E. Tennessee. Regional potassic alteration in unmineralized carbonate rocks and localized occurrences of MVT mineralization are both explainable by a gravity-driven flow model, in which deep brines migrate towards the basin margin under a hydraulic gradient established during the Alleghanian orogeny. The authigenic K-feldspar may reflect the loss of K during disequilibrium cooling of the ascending brines. MVT deposits are probably localized manifestations of the same migrating fluids, occurring where the necessary physical and chemical traps are present.

Geochimica et Cosmochimica Acta↗
USGS1992

Morphology and genesis of carbonate soils on the Kyle Canyon fan, Nevada, U.S.A.

The physical and chemical properties of soils formed in an arid climate on calcareous alluvium of the Kyle Canyon alluvial fan, southern Nevada, were studied in order to infer the rates and relative importance of various soil-forming processes. These studies included field and microscopic observations and analyses of thin sections, major oxides, extractable iron, and clay minerals. The results are interpreted to reflect five major pedogenic processes: (1) The calcic horizons and calcretes of Kyle Canyon soils form by precipitation of CaCO 3 , derived from eolian dust and alluvium, as clast coats, matrix cement, and massive layers. (2) The A and uppermost B horizons are essentially dust-derived, for they contain large amounts of detrital material not present in the alluvial parent material, and their major-oxide content is similar to that of modern dust. (3) Clay particles are translocated from A into B horizons. (4) Iron-bearing minerals in the near-surface B horizons are slowly oxidized. (5) Carbonate and aluminosilicate grains are both displaced and replaced by pedogenic CaCO 3 ; the silica released by replacement of aluminosilicates may be locally precipitated as amorphous or opaline silica and (or) incorporated into newly formed palygorskite and sepiolite. Rates of soil development at Kyle Canyon are approximate due to uncertainties in age estimates. Some soil field properties change at rates that are similar to rates for soils formed in rhyolitic parent material near Mercury, Nevada. The rate of accumulation of CaCO 3 (3–5 g m −2 yr −1 ) at Kyle Canyon is an order of magnitude faster than that near Mercury, but is comparable to rates calculated for soils in southern New Mexico and Utah.

Nevada↗
USGS2017

Rates of soil development from four soil chronosequences in the southern Great Basin

Four soil chronosequences in the southern Great Basin were examined in order to study and quantify soil development during the Quaternary. Soils of all four areas are developed in gravelly alluvial fans in semiarid climates with 8 to 40 cm mean annual precipitation. Lithologies of alluvium are granite-gneiss at Silver Lake, granite and basalt at Cima Volcanic Field, limestone at Kyle Canyon, and siliceous volcanic rocks at Fortymile Wash. Ages of the soils are approximated from several radiometric and experimental techniques, and rates are assessed using a conservative mathematical approach. Average rates for Holocene soils at Silver Lake are about 10 times higher than for Pleistocene soils at Kyle Canyon and Fortymile Wash, based on limited age control. Holocene soils in all four areas appear to develop at similar rates, and Pleistocene soils at Kyle Canyon and Fortymile Wash may differ by only a factor of 2 to 4. Over time spans of several millennia, a preferred model for the age curves is not linear but may be exponential or parabolic, in which rates decrease with increasing age. These preliminary results imply that the geographical variation in rates within the southern Great Basin-Mojave region may be much less significant than temporal variation in rates of soil development. The reasons for temporal variation in rates and processes of soil development are complexly linked to climatic change and related changes in water and dust, erosional history, and internally driven chemical and physical processes. ?? 1991.

Quaternary Research↗
USGS1989

The geology, botany and chemistry of selected peat-forming environments from temperate and tropical latitudes

Peat has been studied in several geologic settings: (1) glaciated terrain in cold temperate Maine and Minnesota, U.S.A.; (2) an island in the Atlantic Ocean off the coast of Maine, where sea level is rising; (3) the warm temperate U.S. Atlantic and Gulf Coastal Plains, where sea level has changed often; and (4) the tropical coast of Sarawak, Malaysia, and the tropical delta of the Batang Hari River, Sumatra, Indonesia. Most of these deposits are domed (ombrotrophic or partly ombrotrophic) bogs in which peat accumulation continued above the surface of the surrounding soil. However, the bogs of the U.S. Atlantic and Gulf Coastal Plains are comparatively not as domed, and many have almost level surfaces. In some bogs, aquatic or semi-aquatic plant materials accumulated, replaced water in the depressions, and formed a surface on which marsh or swamp vegetation could subsequently live, die, and accumulate. In others, the plant materials accumulated initially on level silt or sand surfaces supporting marshes or swamps. As the peat dome formed, plants growing on it changed from luxuriant ones near the base of the dome, where nutrients were brought into the bog by surface and ground water, to stunted ones at the top of the dome, where the raised bogs are fed by nutrient-poor precipitation. The physical and chemical changes that take place in the sequence of environments from the pond stage of deposit development, through the grassy marsh stage, through the forested swamp stage, and finally through the heath dome stage can be measured in terms of acidity and ash, volatile matter, carbon, hydrogen, nitrogen, sulfur and oxygen contents, as well as in the kind and distribution of trace elements. The organic and inorganic contents of the deposits relate to geomorphology, and geomorphology relates to their settings. As models of coal formation, some domed peat deposits may help in solving problems of distribution and character of ancient coal beds. But clearly not all peat deposits are precursors of coal. Most Holocene peat deposits are subject to destruction by erosion, fire and decomposition through microbial and chemical oxidation before burial. The best environments for coal precursors have biomass accumulation, a continuously rising water table within the mass, and minimum influx of clay and silt until preservation by burial. The most suitable settings for future economic coal deposits are domed bogs that accumulate thick, widespread peat having low ash and low sulfur contents. The ombrotrophic peat deposits of tropical Sarawak and Sumatra are thick and extensive, contain low-ash and low-sulfur peat, and have high heating values. They are considered to be the best tropical coal analogs because of their extent and chances of preservation; the base of the peat is below adjacent river levels, and chemical and structural conditions are favorable for accumulation.

International Journal of Coal Geology↗
USGS1991

Facies development in the Lower Freeport coal bed, west-central Pennsylvania, U.S.A.

The Lower Freeport coal bed in west-central Pennsylvania is interpreted to have formed within a lacustrine-mire environment. Conditions of peat formation, caused by the changing chemical and physical environments, produced five coal facies and two mineral-rich parting facies within the coal bed. The coal bed facies are compositionally unique, having developed under varying conditions, and are manifested by megascopic, petrographic, palynologic and quality characteristics. The initial environment of the Lower Freeport peat resulted in a coal facies that is relatively high in ash yield and contains large amounts of lycopod miospores and moderate abundances of cryptotelinite, crypto-gelocollinite, inertinite and tree fern miospores. This initial Lower Freeport peat is interpreted to have been a topogenous body that was low lying, relatively nutrient rich (mesotrophic to eutrophic), and susceptible to ground water and to sediment influx from surface water. The next facies to form was a ubiquitous, clay-rich durain parting which is attributed to a general rise in the water table accompanied by widespread flooding. Following formation of the parting, peat accumulation resumed within an environment that inhibited clastic input. Development of doming in this facies restricted deposition of the upper shale parting to the margins of the mire and allowed low-ash peat to form in the interior of the mire. Because this environment was conducive to preservation of cellular tissue, this coal facies also contains large amounts of crypto-telinite. This facies development is interpreted to have been a transitional phase from topogenous, planar peat formation to slightly domed, oligotrophic (nutrient-poor) peat formation. As domed peat formation continued, fluctuations in the water table enabled oxidation of the peat surface and produced high inertinite concentrations toward the top of the coal bed. Tree ferns became an increasingly important peat contributor in the e upper facies, based on the palynoflora. This floral change is interpreted to have resulted from the peat surface becoming less wet or better drained, a condition that inhibited proliferation of lycopod trees. Accumulation of the peat continued until rising water levels formed a freshwater lake within which clays and silts were deposited. The development of the Lower Freeport peat from a planar mire through transitional phases toward domed peat formation may be an example of the type of peat formation of other upper Middle and Upper Pennsylvanian coal beds.

International Journal of Coal Geology↗
USGS1981

Ne matrix spectra of the sym-C6Br3F3+ radical cation

The electronic absorption and laser excited, wavelength resolved fluorescence spectra of the title cation have been observed in solid Ne matrix and vibrationally analysed. The vibrational structure of the excited B2A2??? state shows close similarity to the parent compound. The X2E??? ground state structure is strongly perturbed and irregular owing to a large Jahn-Teller distortion. The data are analysed in terms of a recently developed, sophisticated multimode Jahn-Teller theoretical model. We have generated the sym-C6Br3F3+ cations in solid Ne matrix and obtained their wavelength resolved emission and absorption spectra. T ground electronic X2E??? state exhibits an irregular and strongly perturbed vibrational structure, which can be successfully modeled using sophisticated multimode Jahn-Teller theory. ?? 1981.

Chemical Physics↗