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Arsenic and mercury contamination related to historical goldmining in the Sierra Nevada, California

Arsenic (As) is a naturally occurring constituent in low-sulphide gold-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) gold (Au) province of California. Concentrations of naturally occurring mercury (Hg) in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay. This review paper provides an overview of As and Hg contamination related to historical Au mining in the Sierra Nevada of California. It summarizes the geology, mineralogy, and geochemistry of the Au deposits, and provides information on specific areas where detailed studies have been done in association with past, ongoing, and planned remediation activities related to the environmental As and Hg contamination. Arsenic is a naturally occurring constituent in low-sulphide Au-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) Au province ( Ashley 2002 ). Because of elevated concentrations of As in accessory iron-sulphide minerals including arsenopyrite (FeAsS) and arsenian pyrite (Fe(S,As) 2 ), As is commonly a contaminant of concern in lode Au mine waste, including waste rock and mill tailings. The principal pathways of human As exposure from mine waste include ingestion of soil or drinking water, and inhalation of dust in contaminated areas ( Mitchell 2014 ). Concentrations of naturally occurring Hg in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits ( Churchill 2000 ) led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay ( Alpers et al. 2005 a ). Conversion of Hg to monomethylmercury (MeHg) by sulphate-reducing and iron-reducing microbes facilitates its bioaccumulation ( Wiener et al. 2003 ). The human Hg exposure pathway of main concern is ingestion of MeHg from sport (non-commercial) fish, especially higher trophic levels such as bass species ( Davis et al. 2008 ). Wildlife exposure to MeHg is also a concern because of chronic and reproductive effects, for example in fish-eating and invertebrate-foraging birds (e.g. Wiener et al. 2003 ; Eagles-Smith et al. 2009 ; Ackerman et al. 2016 ).

California↗

Preliminary report on diamond-drill exploration on Outlaw Mesa, Mesa County, Colorado

Outlaw Mesa is northeast of the Dolores River, about 10 miles southeast of Gateway, Mesa County, Colo. It is an oval-shaped area of about 17 square miles lying mostly within T. 50 N., R. 17 W«, and T. 50 No, R. 18 W., New Mexico principal meridian. The area is accessible by three unimproved roads from Colorado Highway 141. The altitude of the mesa ranges from about 5,500 feet to over 7,000 feet. Total production from Outlaw Mesa from 1914 to 1949 was about 4,000 tons of carnotite ore, having an estimated grade of about 0.50 percent U30Q and 2.5 percent V 2 O 5 . The production from 1949 to October 1951 was about 18,000 tons, having an estimated grade of about 0.35 percent U 3 O 8 and 1.6 percent V 2 O 5 . About 80 percent of the production from 1949 to October 1951 was from deposits discovered by U. S. Geological Survey diamond-drilling in public land, now leased to the Climax Uranium Co. A more complete history of mining and production OE Outlaw Mesa has been given in earlier reports. The results of Geological Survey exploration on Outlaw Mesa are summarized in this preliminary report. A final and more comprehensive report will be transmitted later. No additional drilling is planned.

Colorado↗

Climate change lessons from a warm world

In the early 1970’s to early 1980’s Soviet climatologists were making comparisons to past intervals of warmth in the geologic record and suggesting that these intervals could be possible analogs for 21st century “greenhouse” conditions. Some saw regional warming as a benefit to the Soviet Union and made comments along the lines of “Set fire to the coal mines!” These sentiments were alarming to some, and the United States Geological Survey (USGS) leadership thought they could provide a more quantitative analysis of the data the Soviets were using for the most recent of these warm intervals, the Early Pliocene.

Transactions of the Leicester Literary & Philosoph↗

Aeromagnetic maps of the Mazatzal Wilderness and contiguous roadless areas, Gila, Maricopa, and Yavapai counties, Arizona

The Mazatzal Wilderness and contiguous roadless areas are located in Tonto and Coconino National Forests, west and southwest of Payson, and are almost exactly in the geographic center of Arizona. This is a region of relatively small mining districts and few mines, but occurrences of many different metals are widespread. The Mazatzal Mountains constitute the dominant physiographic feature of the wilderness. The eastern slopes of these mountains rise steeply from about 3,500 ft in altitude along the valley of Rye Creek east of the range, to 7,903 ft at Mazatzal Peak. To the west, the range slopes steeply from the crest then more gently along the lower flanks to the Werde River, one of the main drainage channels of Arizona. In the northern part of the wilderness, the East Werde River, a tributary of the Verde, occupies a deep canyon that separates the Mazatzal Mountains from mesas to the north. The lowest parts of the wilderness have altitudes of about 2,200 ft and are located near Bartlett Reservoir in the southwestern part of the area studied. Two aeromagnetic surveys were flown and interpreted to aid in the delineation of subsurface lithology and structure: one survey was flown at a low level (1,000 ft above ground) and the other at a high level (9,000 ft above sea level). In addition, the results of a small-scale electromagnetic (EM) survey are briefly discussed; the surface EM survey took place in an area of copper concentrations and past exploration activity to look for evidence of massive sulfide mineralization. Studies of the geology, geochemistry (Marsh and others, 1983a, b, Erickson, 1984), mines and prospects (Ellis, 1982), and mineral resource potential (Wrucke and others, 1983) of the Mazatzal Wilderness and contiguous roadless areas have been published elsewhere.

Arizona↗

Geologic map of the Granite 7.5' quadrangle, Lake and Chaffee Counties, Colorado

The geologic map of the Granite 7.5' quadrangle, Lake and Chaffee Counties, Colorado, portrays the geology in the upper Arkansas valley and along the lower flanks of the Sawatch Range and Mosquito Range near the town of Granite. The oldest rocks, exposed in the southern and eastern parts of the quadrangle, include gneiss and plutonic rocks of Paleoproterozoic age. These rocks are intruded by younger plutonic rocks of Mesoproterozoic age. Felsic hypabyssal dikes, plugs, and plutons, ranging in age from Late Cretaceous or Paleocene to late Oligocene, locally intruded Proterozoic rocks. A small andesite lava flow of upper Oligocene age overlies Paleoproterozoic rock, just south of the Twin Lakes Reservoir. Gravelly fluvial and fan deposits of the Miocene and lower Pliocene(?) Dry Union Formation are preserved in the post-30 Ma upper Arkansas valley graben, a northern extension of the Rio Grande rift. Mostly north-northwest-trending faults displace deposits of the Dry Union Formation and older rock units. Light detection and ranging (lidar) imagery suggests that two short faults, near the Arkansas River, may displace surficial deposits as young as middle Pleistocene. Surficial deposits of middle Pleistocene to Holocene age are widespread in the Granite quadrangle, particularly in the major valleys and on slopes underlain by the Dry Union Formation. The main deposits are glacial outwash and post-glacial alluvium; mass-movement deposits transported by creep, debris flow, landsliding, and rockfall; till deposited during the Pinedale, Bull Lake, and pre-Bull Lake glaciations; rock-glacier deposits; and placer-tailings deposits formed by hydraulic mining and other mining methods used to concentrate native gold. Hydrologic and geologic processes locally affect use of the land and locally may be of concern regarding the stability of buildings and infrastructure, chiefly in low-lying areas along and near stream channels and locally in areas of moderate to steep slopes. Low-lying areas along major and minor streams are subject to periodic stream flooding. Mass-movement deposits and deposits of the Dry Union Formation that underlie moderate to steep slopes are locally subject to creep, debris-flow deposition, and landsliding. Proterozoic rocks that underlie steep slopes are locally subject to rockfall. Sand and gravel resources for construction and other uses in and near the Granite quadrangle are present in outwash-terrace deposits of middle and late Pleistocene age along the Arkansas River and along tributary streams in glaciated valleys.

Colorado↗

Hydrologic data from wells at or in the vicinity of the San Juan coal mine, San Juan County, New Mexico

In 2010, in cooperation with the Mining and Minerals Division (MMD) of the State of New Mexico Energy, Minerals and Natural Resources Department, the U.S. Geological Survey (USGS) initiated a 4-year assessment of hydrologic conditions at the San Juan coal mine (SJCM), located about 14 miles west-northwest of the city of Farmington, San Juan County, New Mexico. The mine produces coal for power generation at the adjacent San Juan Generating Station (SJGS) and stores coal-combustion byproducts from the SJGS in mined-out surface-mining pits. The purpose of the hydrologic assessment is to identify groundwater flow paths away from SJCM coal-combustion-byproduct storage sites that might allow metals that may be leached from coal-combustion byproducts to eventually reach wells or streams after regional dewatering ceases and groundwater recovers to predevelopment levels. The hydrologic assessment, undertaken between 2010 and 2013, included compilation of existing data. The purpose of this report is to present data that were acquired and compiled by the USGS for the SJCM hydrologic assessment.

New Mexico↗

Geology of the Biwabik Iron Formation and Duluth Complex

The Biwabik Iron Formation is a ???1.9 billion year-old sequence of iron-rich sedimentary rocks that was metamorphosed at its eastern-most extent by ???1.1 billion year-old intrusions of the Duluth Complex. The metamorphic recrystallization of iron-formation locally produced iron-rich amphiboles and other fibrous iron-silicate minerals. The presence of these minerals in iron-formation along the eastern part of what is known as the Mesabi Iron Range, and their potential liberation by iron mining has raised environmental health concerns. We describe here the geologic setting and mineralogic composition of the Biwabik Iron Formation in and adjacent to the contact metamorphic aureole of the Duluth Complex. The effects of metamorphism are most pronounced within a few kilometers of the contact, and decrease progressively away from it. The contact aureole has been divided into four metamorphic zones-each characterized by the composition and crystal structure of the metamorphic minerals it contains. The recrystallization of iron-formation to iron-rich amphibole minerals (grunerite and cummingtonite) and iron-pyroxene minerals (hedenbergite and ferrohypersthene) is best developed in zones that are most proximal to the Duluth Complex contact. ?? 2007 Elsevier Inc. All rights reserved.

Regulatory Toxicology and Pharmacology↗

Ground geophysical study of the Buckeye mine tailings, Boulder watershed, Montana

The Buckeye mine site is located in the Boulder River watershed along Basin Creek, in northern Jefferson County, Montana. This project is part of the Boulder River watershed Abandoned Mine Lands Initiative, and is a collaborative effort between the U.S. Geological Survey and Bureau of Land Management in the U.S. Department of the Interior, and the U.S. Forest Service in the U.S. Department of Agriculture. The site includes a large flotation milltailing deposit, which extends to the stream and meadows below the mine. These tailings contain elevated levels of metals, such as silver, cadmium, copper, lead, and zinc. Metal-rich fluvial tailings containing these metals, are possible sources of ground and surface water contamination. Geophysical methods were used to characterize the sediments at the Buckeye mine site. Ground geophysical surveys, including electromagnetics, DC resistivity, and total field magnetic methods, were used to delineate anomalies that probably correlate with subsurface metal contamination. Subsurface conductivity was mapped using EM-31 and EM-34 terrain conductivity measuring systems. The conductivity maps represent variation of concentration of dissolved solids in the subsurface from a few meters, to an approximate depth of 30 meters. Conductive sulfides several centimeters thick were encountered in a shallow trench, dug in an area of very high conductivity, at a depth of approximately 1 to1.5 meters. Laboratory measurements of samples of the sulfide layers show the conductivity is on the order of 1000 millisiemens. DC resistivity soundings were used to quantify subsurface conductivity variations and to estimate the depth to bedrock. Total field magnetic measurements were used to identify magnetic metals in the subsurface. The EM surveys identified several areas of relatively high conductivity and detected a conductive plume extending to the southwest, toward the stream. This plume correlates well with the potentiometric surface and direction of ground water flow, and with water quality data from monitoring wells in and around the tailings. The electrical geophysical data suggests there has been vertical migration of high dissolved solids. A DC sounding made on a nearby granite outcrop to the north of the mine showed that the shallow conductivity is on the order of 5 millisiemens/m. Granite underlying the mine tailings, with similar electrical properties as the outcropping area, may be more than 30 meters deep.

Montana↗

Estimation of volume and mass and of changes in volume and mass of selected chat piles in the Picher mining district, Ottawa County, Oklahoma, 2005-10

From the 1890s through the 1970s the Picher mining district in northeastern Ottawa County, Oklahoma, was the site of mining and processing of lead and zinc ore. When mining ceased in about 1979, as much as 165–300 million tons of mine tailings, locally referred to as “chat,” remained in the Picher mining district. Since 1979, some chat piles have been mined for aggregate materials and have decreased in volume and mass. Currently (2013), the land surface in the Picher mining district is covered by thousands of acres of chat, much of which remains on Indian trust land owned by allottees. The Bureau of Indian Affairs manages these allotted lands and oversees the sale and removal of chat from these properties. To help the Bureau of Indian Affairs better manage the sale and removal of chat, the U.S. Geological Survey, in cooperation with the Bureau of Indian Affairs, estimated the 2005 and 2010 volumes and masses of selected chat piles remaining on allotted lands in the Picher mining district. The U.S. Geological Survey also estimated the changes in volume and mass of these chat piles for the period 2005 through 2010. The 2005 and 2010 chat-pile volume and mass estimates were computed for 34 selected chat piles on 16 properties in the study area. All computations of volume and mass were performed on individual chat piles and on groups of chat piles in the same property. The Sooner property had the greatest estimated volume (4.644 million cubic yards) and mass (5.253 ± 0.473 million tons) of chat in 2010. Five of the selected properties (Sooner, Western, Lawyers, Skelton, and St. Joe) contained estimated chat volumes exceeding 1 million cubic yards and estimated chat masses exceeding 1 million tons in 2010. Four of the selected properties (Lucky Bill Humbah, Ta Mee Heh, Bird Dog, and St. Louis No. 6) contained estimated chat volumes of less than 0.1 million cubic yards and estimated chat masses of less than 0.1 million tons in 2010. The total volume of all selected chat piles was estimated to be 18.073 million cubic yards in 2005 and 16.171 million cubic yards in 2010. The total mass of all selected chat piles was estimated to be 20.445 ± 1.840 million tons in 2005 and 18.294 ± 1.646 million tons in 2010. All of the selected chat piles decreased in volume and mass for the period 2005 through 2010. Chat piles CP022 (Ottawa property) and CP013 (Sooner property) had some within-property chat-pile redistribution, with both chat piles having net decreases in volume and mass for the period 2005 through 2010. The Sooner property and the St. Joe property had the greatest volume (and mass) changes, with 1.266 million cubic yards and 0.217 million cubic yards (1.432 ± 0.129 million tons and 0.246 ± 0.022 million tons) of chat being removed, respectively. The chat removed from the Sooner and St. Joe properties accounts for about 78 percent of the chat removed from all selected chat piles and properties. The total volume and mass removed from all selected chat piles for the period 2005 through 2010 were estimated to be 1.902 million cubic yards and 2.151 ± 0.194 million tons, respectively.

Oklahoma↗

Cobalt-copper deposits of the Blackbird district, Lemhi County, Idaho

The Blackbird district is in east-central Idaho, about 20 miles west-southwest of Salmon. The area is one of deeply weathered, flat-topped upland surfaces cut by several steep-walled valleys, which are tributary to the canyon of Panther Creek. Most of the area has a heavy vegetative cover and outcrops are relatively scarce except in the walls of the steeper valleys. The rocks of the district consist mostly of metamorphosed sedimentary rocks of the pre-Cambrian Yellowjacket formation (Belt series); a part of the Cretaceous Idaho batholith cuts across the northern part of the district, and acid porphyry dikes and metamorphosed basic rocks cut the Yellowjacket rocks. Structurally, the sedimentary rocks are divided by faults into three, roughly north-south blocks. The center one (Blackbird structural block) appears to have been more tightly squeezed than the others into relatively tight folds, with the development of widespread schistosity (flow cleavage). The rocks of the two outside blocks are in more open folds. In general they are nonschistose, except for the north end of the western block, where there are schistose rocks cut by several north-dipping thrust faults. The northern parts of the central and western blocks contain considerable garnet, chloritoid, and cordierite. The Blackbird structural block is cut by a number of mineralized shear zones. Those dipping moderately northeast and striking northwest, and those dipping steeply and striking north and northeast; appear to be most important. The mineralized rock contains chalcopyrite, cobaltite, pyrite, and pyrrhotite into a gangue of quartz, biotite, tourmaline, ankerite, and muscovite; the deposits were formed mostly by replacement of the shear zones. In addition, the block is cut by north-dipping thrust faults of west to northwest strike, and a number of high-angle faults. The district was first prospected about 1893; considerable developmont was done at the Brown Bear mine in 1899-1902, at the Haynes-Stellite in l917-1920, and at the Uncle Sam mine in 1938-1941, During World War II, the U.S. Bureau of Mines explored in the district with bulldozer and diamond drill., and the U.S. Geological Survey mapped the district and logged the drill cores. The Howe Sound Co. also did some diamond drilling in the district, and in 1945 the Calera Mining Co., Blackbird Division (subsidiary of Howe Sound Co.), started underground development at the Calera adit. Although the district has had very little production to the present, it is believed that a large tonnage of copper-cobalt ore exists in the district which should permit mining to be continued over a long period. The report contains brief descriptions of all the accessible workings in the district, of which the most important are Calera, Brown Bear, Uncle Sam, and Hawkeye mines. In the Calera adit, about 1,700 feet of the mineralized zone, ranging in width from 3 feet to 40 feet and averaging about 15 feet; have been explored (August 1946); the zone lies on a wide northwest-striking shear zone dipping moderately ( 60° ±) northeast. The Brown Bear adit is in a wide, mineralized, north-south shear zone in which are higher-grade pods plunging 25° to 35° north. The Uncle Sam mine explores a relatively narrow north-south shear zone in which are two or three north-plunging ore shoots. The Hawkeye mine is in a broad zone of mineralized schist in which are several north-plunging lenses of ore.

Idaho↗

Groundwater flow model for Western Chippewa County–Including analysis of water resources related to industrial sand mining and irrigated agriculture

A groundwater flow model for western Chippewa County, Wisconsin, was developed by the Wisconsin Geological and Natural History Survey (WGNHS) and the U.S. Geological Survey (USGS) using the computer program MODFLOW. The model is the result of a five-year groundwater study commissioned by Chippewa County in 2012 to evaluate the effects of industrial sand mining and irrigated agriculture on the county’s water resources. The study incorporates existing data and newly acquired data from fieldwork conducted within the study area. The groundwater model may be useful for future investigations, such as evaluation of proposed high-capacity well sites, development of municipal wellhead protection plans, and studies that seek to further quantify surface water-groundwater relationships. The model conceptualizes the hydrostratigraphy of western Chippewa County as six stacked layers. Each layer is distinct, beginning with unlithified glacial material at the surface, and alternating between sandstones (that act as aquifers) and shale units (that serve as aquitards). The model is bounded below by Precambrian crystalline bedrock and its perimeter was derived from a regional-scale groundwater flow model. The MODFLOW model represented average conditions during 2011–2013 with “steady-state” assumptions, meaning that simulated water levels do not fluctuate seasonally or from year to year. Steady-state models simplify natural variability, making results of scenario simulations easier to interpret and compare while also maximizing effects of stressors because the simulated stress is always applied (not halted after a few months or years). Model calibration used the parameter estimation code (PEST), and calibration targets included heads (groundwater levels) and streamflows. Calibration focused on 2011–2013 because a large amount of head and streamflow data were available for that period. The MODFLOW model explicitly simulates all sources and sinks of water, including groundwater/surface-water interaction with streamflow routing. Model input included estimates of aquifer hydraulic conductivity and a spatial groundwater recharge distribution developed using a GIS-based soil-water-balance (SWB) model applied to the model area. Groundwater withdrawals were simulated for 269 high-capacity wells across the entire model domain, which includes western Chippewa County and adjacent portions of Dunn, Barron, and Rusk Counties. Collectively, these wells withdrew about 1.14 million gallons per year between 2011 and 2013. Once the model was calibrated, it was applied to two distinct scenarios of increased groundwater withdrawals: one evaluating hydrologic effects of more intensive industrial sand mining and the second evaluating the hydrologic effects of more intensive agricultural irrigation practices. Each scenario was developed with input from Chippewa County and a stakeholder group established expressly for this study. The scenarios were designed to represent reasonable future buildout conditions for both mining and irrigated agriculture. The mining scenario underscores the potential hydrologic effects related to changing land-use practices (i.e., hilltops and farmland becoming sand mines), while the irrigated agriculture scenario illustrates the potential hydrologic effects of intensifying existing land-use practices (i.e., installing new wells to irrigate farm fields). While each scenario evaluated distinctly different conditions, modeling results demonstrated the potential of both scenarios to lower the water table and reduce baseflows in headwater streams within the modeled area. In the case of irrigated agriculture, hydrologic effects were associated directly with groundwater withdrawals. By assuming that irrigation did not decrease, this steady-state simulation represented a sustained future effect. By contrast, hydrologic effects of industrial sand mining were the result of both groundwater withdrawals at mines and land-use changes that effectively reduced recharge to groundwater over distinct phases of active mining. This scenario included a post-mining phase, during which groundwater withdrawals stopped and mined areas were reclaimed to undeveloped prairie grass cover. If reclamation to undeveloped prairie indeed occurs as simulated, long-term increases in the water table and stream baseflows are possible. In this sense, the scenario representing build out of irrigated agriculture led to long-term baseflow declines while the future buildout of industrial sand mining led to declines that dissipated following mine reclamation to undisturbed prairie. Future investigations in similar hydrogeologic settings may find the following insights gleaned from this study useful: ❚❚ The characterization of hydrogeologic properties, delineation of hydrogeologic units, and calibration of groundwater flow models benefited from incorporation of accurate well construction reports, high-quality borehole geophysical logs, and streamflow gaging data. ❚❚ Infiltration testing performed in active mining areas provided evidence that reducing the degree and extent of compaction and enhancing areas designed to retain and infiltrate stormwater runoff could potentially reduce runoff and increase groundwater recharge. ❚❚ Similarly, reclaiming mined areas to prairie grasses would be expected to reduce runoff and increase groundwater recharge by reducing compaction and improving soil structure and vegetation that can slow runoff and enhance infiltration.

Wisconsin↗

Geologic map of the Wrangell-Saint Elias National Park and Preserve, Alaska

Wrangell-Saint Elias National Park and Preserve, the largest national park within the U.S. National Park Service system, extends from the northern Pacific Ocean to beyond the eastern Alaska Range into interior Alaska. It features impressively spectacular scenery such as high and craggy mountains, active and ancient volcanoes, expansive ice fields, immense tidewater glaciers, and a myriad of alpine glaciers. The park also includes the famous Kennecott Mine, a world-class copper deposit that was mined from 1911 to 1938, and remnant ghost town, which is now a National Historic Landmark. Geologic investigations encompassing Wrangell-Saint Elias National Park and Preserve began in 1796, with Dmitriv Tarkhanov, a Russian mining engineer, who unsuccessfully ventured up the Copper River in search of rumored copper. Lieutenant H.T. Allen (1897) of the U.S. Army made a successful epic summer journey with a limited military crew up the Copper River in 1885, across the Alaska Range, and down the Tanana and Yukon Rivers. Allen?s crew was supported by a prospector named John Bremner and local Eyak and Ahtna native guides whose tribes controlled access into the Copper River basin. Allen witnessed the Ahtnas? many uses of the native copper. His stories about the copper prompted prospectors to return to this area in search of the rich copper ore in the years following his journey. The region boasts a rich mining and exploration history prior to becoming a park in 1980. Several U.S. Geological Survey geologists have conducted reconnaissance surveys in the area since Allen?s explorations. This map is the result of their work and is enhanced by more detailed investigations, which began in the late 1950s and are still continuing. For a better understanding of the processes that have shaped the geology of the park and a history of the geologic investigations in the area, we recommend U.S. Geological Survey Professional Paper 1616, ?A Geologic Guide to Wrangell-Saint Elias National Park and Preserve, Alaska,? an exceptionally well illustrated and informative book by Gary R. Winkler, 2000. Geologically, the park consists of a collage of seven tectonostratigraphic terranes that formed south in the equatorial Pacific Ocean and rafted northward on oceanic plates, eventually accreting to Alaska and the North American continent. Each terrane features a distinct stratigraphy and is separated from neighboring terranes by major strike-slip or thrust faults.

Alaska↗

Geochemical Characteristics of TP3 Mine Wastes at the Elizabeth Copper Mine Superfund Site, Orange County, Vermont

Remediation of the Elizabeth mine Superfund site in the Vermont copper belt poses challenges for balancing environmental restoration goals with issues of historic preservation while adopting cost-effective strategies for site cleanup and long-term maintenance. The waste-rock pile known as TP3, at the headwaters of Copperas Brook, is especially noteworthy in this regard because it is the worst source of surface- and ground-water contamination identified to date, while also being the area of greatest historical significance. The U.S. Geological Survey (USGS) conducted a study of the historic mine-waste piles known as TP3 at the Elizabeth mine Superfund site near South Strafford, Orange County, VT. TP3 is a 12.3-acre (49,780 m2) subarea of the Elizabeth mine site. It is a focus area for historic preservation because it encompasses an early 19th century copperas works as well as waste from late 19th- and 20th century copper mining (Kierstead, 2001). Surface runoff and seeps from TP3 form the headwaters of Copperas Brook. The stream flows down a valley onto flotation tailings from 20th century copper mining operations and enters the West Branch of the Ompompanoosuc River approximately 1 kilometer downstream from the mine site. Shallow drinking water wells down gradient from TP3 exceed drinking water standards for copper and cadmium (Hathaway and others, 2001). The Elizabeth mine was listed as a Superfund site in 2001, mainly because of impacts of acid-mine drainage on the Ompompanoosuc River.

Open-File Report↗

Mining claim activity on federal land in the contiguous United States, 1976 through 2004

Statistical compilations of mining claim activity on Federal Land derived from the Bureau of Land Management's LR2000 database have been published by the U.S Geological Survey. This report updates Causey (2005) by adding statistics for an additional year of mining claim records, incorporating any corrections in older data done by BLM, adding a Public Land Survey spatial database for South Dakota, and improving correlation of the statistics to spatial databases in Washington and Nevada. The statistics compiled from the LR2000 database are counts of number of active mining claims in a section each year from 1976 to 2004 for all states within the contiguous United States. Claims are broken down by lode and placer types and a dataset is provided summarizing all claims including millsite and tunnel-site claims. One table presents data by case type, case status, and number of claims in a section. This report includes a spatial database for each state in which mining claims were recorded. A field is present in both datasets that allows the statistical data to be joined to the spatial databases so that spatial displays and analysis can be done using appropriate software. The data show how mining claim activity has changed in intensity, space, and time. Variations can be examined on a state, as well as a national level. The data are tied to a section of land, approximately 640 acres, which allows it to be used at regional, as well as local scale. It is restricted in that it only encompasses Federal land.

Arizona, Arkansas, California, Colorado, Florida, ↗

Mineral resources of the Minarets Wilderness and adjacent areas, Madera and Mono counties, California

A mineral survey of the Minarets Wilderness area and adjacent areas in the central Sierra Nevada, Calif., was conducted during 1973 through 1975. The total area covers about 620 km 2 (237 sq mi) in the Sierra and Inyo National Forests, of which about 440 km 2 (170 sq mi) are within the officially designated Minarets Wilderness. The mineral resource potential was evaluated by geological, geochemical, and geophysical studies by the U.S. Geological Survey, and by examination of mineralized rocks, prospects, and mining claims by the U.S. Bureau of Mines. The results of the survey indicate that the study area has small to moderate submarginal to paramarginal resources of copper, silver, zinc, lead, iron, and tungsten and an unevaluated potential for molybdenum resources. Limestone is present, but not of commercial quantity or quality. No other industrial minerals have been recognized in quantity. Granitic rocks have potential use as decorative stone and sand and gravel could be produced from either alluvial deposits or glacial drift. However, these commodities are more accessible elsewhere at localities closer to markets. The study area has no potential for fossil fuels, and, because of the general geologic environment, the potential for nuclear fuel minerals is considered to be low. The study area has low geothermal potential, even though it is on the western edge of the Mono-Long Valley "Known Geothermal Resource Area" (KGRA). The area is underlain by metavolcanic and metasedimentary rocks that have been intruded by granitic rocks of the Sierra Nevada batholith. Pliocene volcanic rocks are present locally. With few exceptions, the known occurrences of mineralized rock are confined to the metamorphic rocks, and the exceptions appear to be confined to plutonic rocks that are older than the Late Cretaceous granitic rocks that make up the bulk of the batholithic rocks in the study area. Although no mineral production has been recorded from prospects within the study area, mines adjacent to it have produced significant amounts of gold and tungsten. Production figures are incomplete, but mines in the Mammoth mining district (fig. 1) may have produced as much as $1 million worth of gold, silver, and other metals at the then-existing prices. The Monte Cristo mine in the Mammoth district was in production during 1978.

California↗

Descriptive logs of exploratory holes drilled during 1952 by the U.S. Geological Survey in Dubuque County, Iowa

The exploratory holes were drilled as part of a larger geologic investigation, the objective of which is to determine in the Dubuque, Iowa, area the probable occurrence of zinc and lead ore stratigraphically lower than that which has been mined. The primary purpose of the drilling was to supply information required for geologic mapping in upland areas where bedrock exposures are sparse or absent. Where possible, the doles were located also on the extension of known mineralized trends. Seven holes aggregating 1,687 feet were drilled with cable tools. Descriptive logs, prepared by A. E. Flint and C. E. Brown frog binocular microscope study of cuttings that were recovered from the drilling, are accompanied by assay values of significant mineralized samples. Index maps show hole locations.

Iowa↗

Questa baseline and pre-mining ground-water quality investigation. 14. Interpretation of ground-water geochemistry in catchments other than the Straight Creek catchment, Red River Valley, Taos County, New Mexico, 2002-2003

The U.S. Geological Survey, in cooperation with the New Mexico Environment Department, is investigating the pre-mining ground-water chemistry at the Molycorp molybdenum mine in the Red River Valley, New Mexico. The primary approach is to determine the processes controlling ground-water chemistry at an unmined, off-site but proximal analog. The Straight Creek catchment, chosen for this purpose, consists of the same Tertiary-age quartz-sericite-pyrite altered andesite and rhyolitic volcanics as the mine site. Straight Creek is about 5 kilometers east of the eastern boundary of the mine site. Both Straight Creek and the mine site are at approximately the same altitude, face south, and have the same climatic conditions. Thirteen wells in the proximal analog drainage catchment were sampled for ground-water chemistry. Eleven wells were installed for this study and two existing wells at the Advanced Waste-Water Treatment (AWWT) facility were included in this study. Eight wells were sampled outside the Straight Creek catchment: one each in the Hansen, Hottentot, and La Bobita debris fans, four in a well cluster in upper Capulin Canyon (three in alluvial deposits and one in bedrock), and an existing well at the U.S. Forest Service Questa Ranger Station in Red River alluvial deposits. Two surface waters from the Hansen Creek catchment and two from the Hottentot drainage catchment also were sampled for comparison to ground-water compositions. In this report, these samples are evaluated to determine if the geochemical interpretations from the Straight Creek ground-water geochemistry could be extended to other ground waters in the Red River Valley , including the mine site. Total-recoverable major cations and trace metals and dissolved major cations, selected trace metals, anions, alkalinity; and iron-redox species were determined for all surface- and ground-water samples. Rare-earth elements and low-level As, Bi, Mo, Rb, Re, Sb, Se, Te, Th, U, Tl, V, W, Y, and Zr were determined on selected samples. Dissolved organic carbon (DOC), mercury, sulfate stable isotope composition (δ 34 S and δ 18 O of sulfate), stable isotope composition of water (δ 2 H and δ 18 O of water) were measured for selected samples. Chlorofluorocarbons (CFC) and 3 He and 3 H were measured for age dating on selected samples. Linear regressions from the Straight Creek ground-water data were used to compare ground-water chemistry trends in non-Straight Creek ground waters with Straight Creek alluvial ground-water chemistry dilution trends. Most of the solute trends for the ground waters are similar to those for Straight Creek but there are some notable exceptions. In lithologies that contain substantial pyrite mineralization, acid waters form with similar chemistries to those in Straight Creek and all the waters tend to be calcium-sulfate type. Hottentot ground waters contain substantially lower calcium concentrations relative to those in Straight Creek. This anomaly results from the exposure of rhyolite porphyry in the Hottentot scar and weathering zone. The rhyolite contains less calcium than the altered andesites and tuffs in the Straight Creek catchment and probably does not have the abundant gypsum and calcite. The Hansen ground waters have reached gypsum saturation and have similar calcium, magnesium, and beryllium concentrations as Straight Creek ground waters but have lower concentrations of fluoride, manganese, zinc, cobalt, nickel, copper, and lithium. Lower concentrations of elements related to mineralization at Hansen likely reflect the more distal location of Hansen with respect to intrusive centers that provided the heat source for hydrothermal alteration. The other ground water with water chemistry trends that are outside the Straight Creek trends was from an alluvial well from Capulin Canyon (CC2A). Although it had pH values near 6.0 and most major ions similar to the other Capulin Canyon ground waters, it contained high concentrations of fluoride, manganese, aluminum, iron, beryllium, and zinc similar to a mineralized zone and had low alkalinity. Saturation indices indicate that solubility constraints continue to provide upper limits on some solute concentrations. Siderite, ferrihydrite, calcite, gypsum, rhodochrosite, and barite provide limits for concentrations of Fe(II), Fe(III), Ca, Mn, and Ba, respectively. Beryllium concentrations may be subject to an upper concentration limit by the solubility of Be(OH) 2 but these concentrations probably are not reached in the ground waters. Ground-water isotopic data were consistent with the meteoric water line estimated for precipitation in the Red River Valley, indicating that all the ground waters examined in this study were meteoric, recent in origin, and showed no substantial indication of evaporation. Tritium-helium-3 and chlorofluorocarbon (CFC) age dating were partially successful. Generally, dates were consistent with location and depth of wells. Two samples had good agreement between CFC dates and tritium-helium dates, whereas a third reflected either substantial mixing with younger or older waters or complications arising from excess helium-4. The well at La Bobita appeared to contain a large component of modern water, most likely as a result of mixing with water from Red River alluvial deposits.

New Mexico↗

Preliminary bedrock geologic map of the Port Henry quadrangle, Essex County, New York, and Addison County, Vermont

Introduction The bedrock geology of the 7.5-minute Port Henry quadrangle consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 Ga (giga-annum). In the Port Henry quadrangle, the AMCG metaigneous rocks (Yhg, Ygb, Yanw) intruded older, mostly metasedimentary rocks of the Grenville Complex during the middle to late Shawinigan orogeny (~1,160–1,150 Ma [mega-annum]). All rocks were subsequently metamorphosed to upper amphibolite to granulite facies conditions during the 1,080–1,050 Ma Ottawan orogeny. New mapping reveals four periods of deformation: (1) D1 produced rarely preserved isoclinal folds in the paragneiss and marble and predates AMCG magmatism. (2) Subsequent D2 deformation produced the dominant gneissic fabric preserved in the rock, recumbent folding, and deformed all the Proterozoic units in the map area. Syn- to late-D2 felsic magmatism resulted in the regionally extensive Lyon Mountain Granite Gneiss, which hosts numerous magnetite ore bodies. (3) Mylonitic extensional shear zones and core complex formation marked the beginning of D3 deformation. Protracted D3 deformation resulted in F3 upright folding, dome and basin formation, pegmatite intrusion, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron-ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. (4) D4 created northeast- and northwest-trending local high-grade ductile shear zones and boudinage, northwest-trending regional kilometer (km)-wide ductile shear zones, and crosscutting granitic pegmatite dikes. The development of the late-stage regional shear zones (D4) was likely due to the continuation of extensional doming and uplift from upper amphibolite facies conditions at the end of the Ottawan orogeny. The majority of iron-ore deposits in the Port Henry and adjacent Witherbee quadrangles are in the hanging wall of these extensional shear zones. In the Port Henry quadrangle, the km-wide Cheney Mountain shear zone is the result of D4 deformation. Kilometer-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. The Paleozoic rocks are part of the Early Cambrian to Late Ordovician carbonate bank on the ancient margin of Laurentia. The approximately 1-km-thick Cambrian to Ordovician stratigraphy records a transition from synrift clastics to passive-margin peritidal carbonate buildups to gradually deeper-water subtidal- to shelf-carbonates during foreland basin development associated with the Taconic orogeny. The Paleozoic rocks are weakly folded and block faulted. Large areas of the Champlain Valley are covered by undifferentiated glacial deposits, some of which contain mapped landslides. The map also shows waste rock piles and tailings from historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondacks, provide a context for historical iron mines in the eastern Adirondacks, and update the stratigraphy of the Champlain Valley in New York and Vermont. This Open-File Report includes a bedrock geologic map; a description of map units; a correlation of map units; and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information.

New York, Vermont↗