SEARCH · Search USGS

Results for “Electronics”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 721 records · Page 40Linked to original sources

USGS1997

An interactive program for computer-aided map design, display, and query: EMAPKGS2

EMAPKGS2 is a user-friendly, PC-based electronic mapping tool for use in hydrogeologic exploration and appraisal. EMAPKGS2 allows the analyst to construct maps interactively from data stored in a relational database, perform point-oriented spatial queries such as locating all wells within a specified radius, perform geographic overlays, and export the data to other programs for further analysis. EMAPKGS2 runs under Microsoft?? Windows??? 3.1 and compatible operating systems. EMAPKGS2 is a public domain program available from the Kansas Geological Survey. EMAPKGS2 is the centerpiece of WHEAT, the Windows-based Hydrogeologic Exploration and Appraisal Toolkit, a suite of user-friendly Microsoft?? Windows??? programs for natural resource exploration and management. The principal goals in development of WHEAT have been ease of use, hardware independence, low cost, and end-user extensibility. WHEAT'S native data format is a Microsoft?? Access?? database. WHEAT stores a feature's geographic coordinates as attributes so they can be accessed easily by the user. The WHEAT programs are designed to be used in conjunction with other Microsoft?? Windows??? software to allow the natural resource scientist to perform work easily and effectively. WHEAT and EMAPKGS have been used at several of Kansas' Groundwater Management Districts and the Kansas Geological Survey on groundwater management operations, groundwater modeling projects, and geologic exploration projects. ?? 1997 Elsevier Science Ltd.

Computers & Geosciences↗

USGS2000

Identification of a small, naked virus in tumor-like aggregates in cell lines derived from a green turtle, Chelonia mydas, with fibropapillomas

Serial cultivation of cell lines derived from lung, testis, periorbital and tumor tissues of a green turtle (Chelonia mydas) with fibropapillomas resulted in the in vitro formation of tumor-like cell aggregates, ranging in size from 0.5 to 2.0 mm in diameter. Successful induction of tumor-like aggregates was achieved in a cell line derived from lung tissue of healthy green turtles, following inoculation with cell-free media from these tumor-bearing cell lines, suggesting the presence of a transmissible agent. Thin-section electron microscopy of the cell aggregates revealed massive collagen deposits and intranuclear naked viral particles, measuring 5095 nm in diameter. These findings, together with the morphological similarity between these tumor-like cell aggregates and the naturally occurring tumor, suggest a possible association between this novel virus and the disease. Further characterization of this small naked virus will clarify its role in etiology of green turtle fibropapilloma, a life-threatening disease of this endangered marine species.

Journal of Virological Methods↗

USGS2002

Trace element abundances in major minerals of Late Permian coals from southwestern Guizhou province, China

Fourteen samples of minerals were separated by handpicking from Late Permian coals in southwestern Guizhou province, China. These 14 minerals were nodular pyrite, massive recrystallized pyrite, pyrite deposited from low-temperature hydrothermal fluid and from ground water; clay minerals; and calcite deposited from low-temperature hydrothermal fluid and from ground water. The mineralogy, elemental composition, and distribution of 33 elements in these samples were studied by optical microscopy, scanning electron microscope equipped with energy-dispersive X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), cold-vapor atomic absorption spectrometry (CV-AAS), atomic fluorescence spectrometry (AFS), inductively coupled-plasma mass spectrometry (ICP-MS), and ion-selective electrode (ISE). The results show that various minerals in coal contain variable amounts of trace elements. Clay minerals have high concentrations of Ba, Be, Cs, F, Ga, Nb, Rb, Th, U, and Zr. Quartz has little contribution to the concentration of trace elements in bulk coal. Arsenic, Mn, and Sr are in high concentrations in calcite. Pyrite has high concentrations of As, Cd, Hg, Mo, Sb, Se, Tl, and Zn. Different genetic types of calcite in coal can accumulate different trace elements; for example Ba, Co, Cr, Hg, Ni, Rb, Sn, Sr, and Zn are in higher concentrations in calcite deposited from low-temperature hydrothermal fluid than in that deposited from ground water. Furthermore, the concentrations of some trace elements are quite variable in pyrite; different genetic types of pyrites (Py-A, B, C, D) have different concentrations of trace elements, and the concentrations of trace elements are also different in pyrite of low-temperature hydrothermal origin collected from different locations. The study shows that elemental concentration is rather uniform in a pyrite vein. There are many micron and submicron mosaic pyrites in a pyrite vein, which is enriched in some trace elements, such as As and Mo. The content of trace element in pyrite vein depends upon the content of mosaic pyrite and of trace elements in it. Many environmentally sensitive trace elements are mainly contained in the minerals in coal, and hence the physical coal cleaning techniques can remove minerals from coal and decrease the emissions of potentially hazardous trace elements. ?? 2002 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology↗

USGS2003

Applicability of tetrazolium salts for the measurement of respiratory activity and viability of groundwater bacteria

A study was undertaken to measure aerobic respiration by indigenous bacteria in a sand and gravel aquifer on western Cape Cod, MA using tetrazolium salts and by direct oxygen consumption using gas chromatography (GC). In groundwater and aquifer slurries, the rate of aerobic respiration calculated from the direct GC assay was more than 600 times greater than that using the tetrazolium salt 2-(4-iodophenyl)-3-(4-nitrophenyl)-5-phenyl tetrazolium chloride (INT). To explain this discrepancy, the toxicity of INT and two additional tetrazolium salts, sodium 3′-[1-(phenylamino)-carbonyl]-3,4-tetrazolium]-bis(4-methoxy-6-nitro) benzenesulfonic acid hydrate (XTT) and 5-cyano-2,3-ditolyl tetrazolium chloride (CTC), to bacterial isolates from the aquifer was investigated. Each of the three tetrazolium salts was observed to be toxic to some of the groundwater isolates at concentrations normally used in electron transport system (ETS) and viability assays. For example, incubation of cells with XTT (3 mM) caused the density of four of the five groundwater strains tested to decline by more than four orders of magnitude. A reasonable percentage (>57%) of cells killed by CTC and INT contained visible formazan crystals (the insoluble, reduced form of the salts) after 4 h of incubation. Thus, many of the cells reduced enough CTC or INT prior to dying to be considered viable by microscopic evaluation. However, one bacterium ( Pseudomonas fluorescens ) that remained viable and culturable in the presence of INT and CTC, did not incorporate formazan crystals into more than a few percent of cells, even after 24 h of incubation. This strain would be considered nonviable based on traditional tetrazolium salt reduction assays. The data show that tetrazolium salt assays are likely to dramatically underestimate total ETS activity in groundwater and, although they may provide a reasonable overall estimate of viable cell numbers in a community of groundwater bacteria, some specific strains may be falsely considered nonviable by this assay due to poor uptake or reduction of the salts.

Massachusetts↗

USGS1997

Quantitative analysis of major elements in silicate minerals and glasses by micro-PIXE

The Guelph micro-PIXE facility has been modified to accommodate a second Si(Li) X-ray detector which records the spectrum due to light major elements (11 ??? Z ??? 20) with no deleterious effects from scattered 3 MeV protons. Spectra have been recorded from 30 well-characterized materials, including a broad range of silicate minerals and both natural and synthetic glasses. Sodium is mobile in some of the glasses, but not in the studied mineral lattices. The mean value of the instrumental constant H for each of the elements Mg, Al, and Si in these materials is systematically 6-8% lower than the H-value measured for the pure metals. Normalization factors are derived which permit the matrix corrections requisite for trace-element measurements in silicates to be based upon pure metal standards for Mg, Al and Si, supplemented by well-established, silicate mineral standards for the elements Na, K and Ca. Rigorous comparisons of electron microprobe and micro-PIXE analyses for the entire, 30-sample suite demonstrate the ability of micro-PIXE to produce accurate analysis for the light major elements in silicates. ?? 1997 Elsevier Science B.V.

Nuclear Instruments and Methods in Physics Researc↗

USGS1999

Bacterial respiration of arsenic and selenium

Oxyanions of arsenic and selenium can be used in microbial anaerobic respiration as terminal electron acceptors. The detection of arsenate and selenate respiring bacteria in numerous pristine and contaminated environments and their rapid appearance in enrichment culture suggest that they are widespread and metabolically active in nature. Although the bacterial species that have been isolated and characterized are still few in number, they are scattered throughout the bacterial domain and include Gram- positive bacteria, beta, gamma and epsilon Proteobacteria and the sole member of a deeply branching lineage of the bacteria, Chrysiogenes arsenatus. The oxidation of a number of organic substrates (i.e. acetate, lactate, pyruvate, glycerol, ethanol) or hydrogen can be coupled to the reduction of arsenate and selenate, but the actual donor used varies from species to species. Both periplasmic and membrane-associated arsenate and selenate reductases have been characterized. Although the number of subunits and molecular masses differs, they all contain molybdenum. The extent of the environmental impact on the transformation and mobilization of arsenic and selenium by microbial dissimilatory processes is only now being fully appreciated.

FEMS Microbiology Reviews↗

USGS2001

Progression of natural attenuation processes at a crude-oil spill site . I. Geochemical evolution of the plume

A 16-year study of a hydrocarbon plume shows that the extent of contaminant migration and compound-specific behavior have changed as redox reactions, most notably iron reduction, have progressed over time. Concentration changes at a small scale, determined from analysis of pore-water samples drained from aquifer cores, are compared with concentration changes at the plume scale, determined from analysis of water samples from an observation well network. The small-scale data show clearly that the hydrocarbon plume is growing slowly as sediment iron oxides are depleted. Contaminants, such as ortho -xylene that appeared not to be moving downgradient from the oil on the basis of observation well data, are migrating in thin layers as the aquifer evolves to methanogenic conditions. However, the plume-scale observation well data show that the downgradient extent of the Fe 2+ and BTEX plume did not change between 1992 and 1995. Instead, depletion of the unstable Fe (III) oxides near the subsurface crude-oil source has caused the maximum dissolved iron concentration zone within the plume to spread at a rate of approximately 3 m/year. The zone of maximum concentrations of benzene, toluene, ethylbenzene and xylene (BTEX) has also spread within the anoxic plume. In monitoring the remediation of hydrocarbon-contaminated ground water by natural attenuation, subtle concentration changes in observation well data from the anoxic zone may be diagnostic of depletion of the intrinsic electron-accepting capacity of the aquifer. Recognition of these subtle patterns may allow early prediction of growth of the hydrocarbon plume.

Journal of Contaminant Hydrology↗

USGS2002

Holocene tephrochronology of the Cold Bay area, southwest Alaska Peninsula

The major-element glass geochemistry of 92 tephra samples from the southwest Alaska Peninsula provides the basis for establishing a Holocene tephrochronology for the region. Electron microprobe analysis has been combined with field descriptions of samples, stratigraphic relationships between tephra samples and sample localities, and glass shard micro-morphology to correlate these sampled distal tephra units throughout the area of Cold Bay and adjacent Morzhovoi Bay. Radiocarbon dating provides age constraints on correlated horizons. Previous research had clearly delineated only one horizon in the region, the so-called 'Funk/Fisher' ash, dating to between 8425 ± 350 and 9130 ± 140 14 C yr BP. In addition to constraining the bimodal andesitic and dacitic glass chemistry of that horizon, this study has recognized six additional tephra layers in the area. Two horizons pre-date the Funk/Fisher ash and four are younger than it. A tephra containing dacitic and andesitic components was identified in the vicinity of Morzhovoi Bay, with a minimum age of 9300 ± 80 14 C yr BP and a maximum age of 10,200 ± 75 14 C yr BP. A rhyolitic horizon composed of cm-sized, rounded pumice clasts was identified in the vicinity of Cold Bay; it has been correlated to the ca 9500 BP eruption of Roundtop volcano on Unimak Island. The four younger tephra beds date to between 6070 ± 340 and 3600 ± 140 14 C yr BP. The oldest of the four is rhyodacitic, followed by a mixed rhyodacitic-andesitic horizon, another rhyodacitic horizon, and finally an andesitic layer. Comparison of all the correlated horizons to proximal samples collected on Unimak Island provides conclusive geochemical evidence that the ca 9100 BP Caldera-forming eruption of Fisher volcano is the source of the Funk/Fisher ash. Correlation between the rhyodacitic tephra horizons and proximal samples from Fisher volcano suggests that Fisher Caldera is the source of one of the rhyodacitic tephra horizons that post-dates the Funk/Fisher ash. Additional tephra samples from the southwest Alaska Peninsula and Unimak Island that were collected prior to this study correlate to the tephra horizons identified in the Cold Bay area and identify one additional horizon.

Quaternary Science Reviews↗

USGS2000

U-Pb geochronology of zircon and monazite from Mesoproterozoic granitic gneisses of the northern Blue Ridge, Virginia and Maryland, USA

Mesoproterozoic granitic gneisses comprise most of the basement of the northern Blue Ridge geologic province in Virginia and Maryland. Lithology, structure, and U-Pb geochronology have been used to subdivide the gneisses into three groups. The oldest rocks, Group 1, are layered granitic gneiss (1153 ?? 6 Ma), hornblende monzonite gneiss (1149 ?? 19 Ma), porphyroblastic granite gneiss (1144 ?? 2 Ma), coarse-grained metagranite (about 1140 Ma), and charnockite (>1145 Ma?). These gneisses contain three Proterozoic deformational fabrics. Because of complex U-Pb systematics due to extensive overgrowths on magmatic cores, zircons from hornblende monzonite gneiss were dated using the sensitive high-resolution ion microprobe (SHRIMP), whereas all other ages are based on conventional U-Pb geochronology. Group 2 rocks are leucocratic and biotic varieties of Marshall Metagranite, dated at 1112??3 Ma and 1111 ?? 2 Ma respectively. Group 3 rocks are subdivided into two age groups: (1) garnetiferous metagranite (1077 ?? 4 Ma) and quartz-plagioclase gneiss (1077 ?? 4 Ma); (2) white leucocratic metagranite (1060 ?? 2 Ma), pink leucocratic metagranite (1059 ?? 2), biotite granite gneiss (1055 ?? 4 Ma), and megacrystic metagranite (1055 ?? 2 Ma). Groups 2 and 3 gneisses contain only the two younger Proterozoic deformational fabrics. Ages of monazite, seprated from seven samples, indicate growth during both igneous and metamorphic (thermal) events. However, ages obtained from individual grains may be mixtures of different age components, as suggested by backscatter electron (BSE) imaging of complexly zoned grains. Analyses of unzoned monazite (imaged by BSE and thought to contain only one age component) from porphyroblastic granite gneiss yield ages of 1070, 1060, and 1050 Ma. The range of ages of monazite (not reset to a uniform date) indicates that the Grenville granulite event at about 1035 Ma did not exceed about 750??C. Lack of evidence for 1110 Ma growth of monazite in porphyroblastic granite gneiss suggests that the Short Hill fault might be a Grenvillian structure that was reactivated in the Paleozoic. The timing of Proterozoic deformations is constrained by crystallization ages of the gneissic rocks. D1 occurred between about 1145 and 1075 Ma (or possibly between about 1145 and 1128 Ma). D2 and D3 must be younger than about 1050 Ma. Ages of Mesoproterozoic granitic rocks of the northern Blue Ridge are similar to rocks in other Grenville terranes of the eastern USA, including the Adirondacks and Hudson Highlands. However, comparisons with conventional U-Pb ages of granulite-grade rocks from the central and southern Appalachians may be specious because these ages may actually be mixtures of ages of cores and overgrowths.

Precambrian Research↗

USGS2000

Ground deformation at Merapi Volcano, Java, Indonesia: distance changes, June 1988-October 1995

Edifice deformations are reported here for the period 1988–1995 at Merapi volcano, one of the most active and dangerous volcanoes in Indonesia. The study period includes a major resumption in lava effusion in January 1992 and a major dome collapse in November 1994. The data comprise electronic distance measurements (EDM) on a summit trilateration network, slope distance changes measured to the upper flanks, and other data collected from 1988 to 1995. A major consequence of this study is the documentation of a significant 4-year period of deformation precursory to the 1992 eruption. Cross-crater strain rates accelerated from less than 3×10 −6 /day between 1988 and 1990 to more than 11×10 −6 /day just prior to the January 1992 activity, representing a general, asymmetric extension of the summit during high-level conduit pressurization. After the vent opened and effusion of lava resumed, strain occurred at a much-reduced rate of less than 2×10 −6 /day. EDM measurements between lower flank benchmarks and the upper edifice indicate displacements as great as 1 m per year over the four years before the 1992 eruption. The Gendol breach, a pronounced depression formed by the juxtaposition of old lava coulées on the southeast flank, functioned as a major displacement discontinuity. Since 1993, movements have generally not exceeded the 95% confidence limits of the summit network. Exceptions to this include 12 cm outward movement for the northwest crater rim in 1992–1993, probably from loading by newly erupted dome lava, and movements as much as 7 cm on the south flank between November 1994 and September 1995. No short-term precursors were noted before the November 1994 lava dome collapse, but long-term adjustments of crater geometry accompanied lava dome growth in 1994. Short-term 2-cm deflation of the edifice occurred following the November 1994 dome collapse.

Journal of Volcanology and Geothermal Research↗

USGS2003

Deformation of the Long Valley Caldera, California: Inferences from measurements from 1988 to 2001

Two periods of volcanic unrest occurred between 1989 and 1998 in the Long Valley Caldera, eastern California. Numerous earthquakes were recorded, and these periods of unrest were documented with high-precision geodetic measurements. The first round of unrest started rapidly in late 1989 and slowly decreased in rate through the early 1990s. For this interval there are both leveling and two-color electronic distance meter (EDM) measurements. The second round of unrest started slowly in mid-1997, climaxed in late 1997, and rapidly returned to quiescence by mid-1998. Deformation was recorded by both the two-color EDM and continuous GPS. Both episodes require inflation at 6-7 km beneath the resurgent dome, and both episodes had roughly 0.1 m extension across the resurgent dome. In addition, the data presented here suggest that there is a deeper, 10-20 km, inflation source beneath the south moat of the caldera. For both episodes, the better-resolved inflation beneath the resurgent dome is a near-vertical, prolate spheroid rather than an isotropic source, which suggests that magma came up through vertical cracks. However, the modeling suggests that the location changed with the depth from 6.0 to 6.7 km for the later episode. In contrast to the earlier episode, the 1997-1998 episode has additional deformation in the south moat, where the simplest model is that of a right-lateral slip on a steeply dipping plane that is defined by the location of earthquakes in the south moat. Models of the time-dependent behavior suggest that slip on this fault occurred from late November through December 1997, corresponding to the time of greatest moment release by the earthquake swarm in the south moat. Confounding the interpretation of these data is an active geothermal field near the center of the EDM network and adjacent to the south moat and resurgent dome. Additional modeling of leveling and EDM data within the geothermal field during a period of low rate of inflation of the dome suggests some methods of adjustments to the EDM data during the inflation episodes. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2003

Water-level changes induced by local and distant earthquakes at Long Valley caldera, California

Distant as well as local earthquakes have induced groundwater-level changes persisting for days to weeks at Long Valley caldera, California. Four wells open to formations as deep as 300 m have responded to 16 earthquakes, and responses to two earthquakes in the 3-km-deep Long Valley Exploratory Well (LVEW) show that these changes are not limited to weathered or unconsolidated near-surface rocks. All five wells exhibit water-level variations in response to earth tides, indicating they can be used as low-resolution strainmeters. Earthquakes induce gradual water-level changes that increase in amplitude for as long as 30 days, then return more slowly to pre-earthquake levels. The gradual water-level changes are always drops at wells LKT, LVEW, and CH-10B, and always rises at well CW-3. At a dilatometer just outside the caldera, earthquake-induced strain responses consist of either a step followed by a contractional strain-rate increase, or a transient contractional signal that reaches a maximum in about seven days and then returns toward the pre-earthquake value. The sizes of the gradual water-level changes generally increase with earthquake magnitude and decrease with hypocentral distance. Local earthquakes in Long Valley produce coseismic water-level steps; otherwise the responses to local earthquakes and distant earthquakes are indistinguishable. In particular, water-level and strain changes in Long Valley following the 1992 M7.3 Landers earthquake, 450 km distant, closely resemble those initiated by a M4.9 local earthquake on November 22, 1997, during a seismic swarm with features indicative of fluid involvement. At the LKT well, many of the response time histories are identical for 20 days after each earthquake, and can be matched by a theoretical solution giving the pore pressure as a function of time due to diffusion of a nearby, instantaneous, pressure drop. Such pressure drops could be produced by accelerated inflation of the resurgent dome by amounts too small to be detected by the two-color electronic distance-measuring network. Opening-mode displacement in the south moat, inferred to have followed a M4.9 earthquake on November 22, 1997, could also create extensional strain on the dome and lead to water-level changes similar to those following dome inflation. Contractional strain that could account for earthquake-induced water-level rises at the CW-3 well is inconsistent with geodetic observations. We instead attribute these water-level rises to diffusion of elevated fluid pressure localized in the south moat thermal aquifer. For hydraulic diffusivities appropriate to the upper few hundred meters at Long Valley, an influx of material at temperatures of 300°C can thermally generate pressure of 6 m of water or more, an order of magnitude larger than needed to account for the CW-3 water-level rises. If magma or hot aqueous fluid rises to within 1 km of the surface in the eastern part of the south moat, then hydraulic diffusivities are high enough to allow fluid pressure to propagate to CW-3 on the time scale observed. The data indicate that seismic waves from large distant earthquakes can stimulate upward movement of fluid in the hydrothermal system at Long Valley.

California↗

USGS2003

Deformation near the Casa Diablo geothermal well field and related processes Long Valley caldera, Eastern California, 1993-2000

Regional first-order leveling lines, which extend from Lee Vining, CA, to Tom's Place, CA, have been surveyed periodically since 1957 by the U.S. Geological Survey (USGS), the National Geodetic Survey (NGS), and Caltrans. Two of the regional survey lines, or leveling networks, intersect at the Casa Diablo geothermal well field. These leveling networks, referenced to a distant bench mark (C916) near Lee Vining, provide time-series vertical control data of land-surface deformation that began around 1980. These data are also useful for delineating localized subsidence at Casa Diablo related to reservoir pressure and temperature changes owing to geothermal development that began in 1985. A comparison of differences in bench-mark elevations for five time periods between 1983 and 1997 shows the development and expansion of a subsidence bowl at Casa Diablo. The subsidence coincides spatially with the geothermal well field and temporally with the increased production rates and the deepening of injection wells in 1991, which resulted in an increase in the rate of pressure decline. The subsidence, superimposed on a broad area of uplift, totaled about 310 mm by 1997. The USGS established orthogonal tilt arrays in 1983 to better monitor deformation across the caldera. One tilt array (DBR) was established near what would later become the Casa Diablo geothermal well field. This array responded to magmatic intrusions prior to geothermal development, tilting away from the well field. With the start of geothermal fluid extraction in 1985, tilt at the DBR array reversed direction and began tilting into the well field. In 1991, geothermal power production was increased by a factor of four, and reservoir pressures began a period of steep decline. These changes caused a temporary three-fold increase in the tilt rate. The tilt rate became stable in 1993 and was about 40% lower than that measured in 1991-1992, but still greater than the rates measured during 1985-1990. Data from the local leveling networks spanning the well field and the bounding graben were analyzed for several 2-year periods (1993-1995, 1995-1997, and 1997-1999). Annual rates of change across the normal faults bounding the graben have steadily decreased for each 2-year period between 1993 and 1999, reflecting the slowing decline in geothermal reservoir pressure. Horizontal control data from a two-color electronic distance meter (EDM) defined the lateral extent of subsidence at Casa Diablo. The EDM and leveling data elucidate the localized effect of the shallow source of subsidence and the broader effect of the deeper magmatic inflation source. Data from bench marks common to both the vertical and the horizontal control networks were used to assess the effect of subsidence on the EDM base station (CASA). Modeling of geodetic data collected during periods of little or no magmatic inflation indicated that the CASA two-color EDM station is being drawn toward the well field at a rate of 3-5 mm/yr. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2000

Mode of occurrence of arsenic in four US coals

An integrated analytical approach has been used to determine the mode of occurrence of arsenic in samples of four widely used US coals: the Pittsburgh, Illinois #6, Elkhorn/Hazard, and Wyodak. Results from selective leaching, X-ray absorption fine structure (XAFS) spectroscopy, and electron microprobe analysis show that pyrite is the principal source of arsenic in the three bituminous coals, but the concentration of As in pyrite varies widely. The Wyodak sample contains very little pyrite; its arsenic appears to be primarily associated with organics, as As3+, or as arsenate. Significant (10-40%) fractions of arsenate, derived from pyrite oxidation, are also present in the three bituminous coal samples. This information is essential in developing predictive models for arsenic behavior during coal combustion and in other environmental settings.

Fuel Processing Technology↗

USGS2004

The fine structure of the sperm of the round goby (Neogobius melanostomus)

The fine structural details of the spermatozoon of the round goby are presented for the first time in this study. Scanning and transmission electron microscopic examination of testis reveals an anacrosomal spermatozoon with a slightly elongate head and uniformly compacted chromatin. The midpiece contains a single, spherical mitochondrion. Two perpendicularly oriented centrioles lie in a deep, eccentric nuclear fossa with no regularly observed connection to the nucleus. The flagellum develops bilateral fins soon after emerging from the fossa; each extends approximately 1 μm fro m the axoneme and persists nearly the length of the flagellum.

Journal of Great Lakes Research↗

USGS2005

Embryonic developmental progression in lake trout ( Salvelinus namaycush ) (Walbaum, 1792) and its relation to lake temperature

Developmental progression of lake trout ( Salvelinus namaycush ) embryos was examined with light and scanning electron microscopy. From this examination, key developmental stages were described in detail. The key developmental stages were then applied to individual lake trout egg lots incubated in constant temperatures of 2, 4, 6, 8, and 10°C. We used Belehradek's, Thermodynamic, and Power models, and also developed the Zero model to determine stage specific developmental rates of lake trout eggs for each background temperature. From the models, hatch dates and staging were predicted for temperature regimes from Lake Superior (1990–91) and Lake Huron (1996–97). Based on the existing lake temperature data and the observed spawning dates, the Zero and the Power models predict that post peak spawning may contribute significantly to overall recruitment success for these years.

Journal of Great Lakes Research↗

USGS1995

Concentrations of dissolved and particulate Polychlorinated Biphenyls in water from the Saginaw River, Michigan

The Saginaw River receives water from a major drainage basin in the east-central portion of the lower peninsula of Michigan. Historically the river has been contaminated with polychlorinated biphenyls (PCBs) from several sources. The present study was conducted to determine the concentrations of PCBs in both the dissolved and particulate phases of water in the lower Saginaw River, as well as the relative contribution of PCBs from the lower portion of the river relative to more upstream locations. Water samples were collected in 1990–1991, during a range of discharge conditions. Suspended particulates were collected from water onto glass-fiber filters by use of a “Penta-plate” filtration apparatus. Filtered water was subsequently passed through XAD-2 macroreticular resin to collect the “dissolved” PCBs. Concentrations of PCBs in both phases were determined by congener specific gas chromatography with electron capture detection. Total concentrations of PCBs ranged from 11 to 31 ng/L. The concentrations of PCBs in the dissolved phase ranged from 1.9 to 16 ng/L. The ratio of total PCBs bound to suspended particulates, relative to dissolved PCBs, was 2:1 and remained fairly constant for discharges less than approximately 400 M 3 /sec. The loading of total PCBs to Saginaw Bay was estimated to be 225 kg/yr, of which approximately 60% was found to be contributed by the lower 8 km of the Saginaw River.

Michigan↗

USGS1997

Iron deposition as acidic groundwater encounters carbonates in the alluvium of Pinal Creek, Arizona, U.S.A.

In a column experiment, acidic groundwater from Pinal Creek Arizona, a Cu mining area, was eluted through a composited alluvial sample obtained from a core that had been removed from a well downgradient of the acidic groundwater. The minerals present in typical grains and flakes in the alluvium before and after the elution were determined by X-ray diffraction (XRD), scanning electron microscopy, and energy dispersive multichannel analyses (EDX). The concentrations of Fe, Ti, Mn, Si, Al, Na, Ca, K, Mg and S in these grains and flakes and in their microcrystalline surface coatings were measured by EDX. In addition to magnetite, hematite, and Fe-Ti oxides, Fe was most concentrated in micas (especially biotite-like flakes) and in the microcrystalline coatings. The measured elements in these microcrystalline coatings were primarily K, Fe, Al, and Si. The microcrystalline coatings on the mica flakes also contained Mg. The approximate 1:3 Mg:Si atomic ratios (ARs) of the biotite-like flakes both before and after the elution would suggest that the Fe deposited during the elution had not substituted for Mg in these flakes. As a result of the elution, assuming no loss of Si, the averaged recorded Fe:Si AR of the microcrystalline coatings increased from (0,46 to 0.58):3.00. Iron deposition on the typical grains and flakes may relate to the presence of Fe in the particle on which it is deposited or to the presence of Fe in the microcrystalline surface coatings before elution. The data here are not sufficient for a statistical evaluation, but elution caused the following trends: (1) The Fe:Si A R increased in the (K,Fe,Al,Si)-microcrystalline surface coatings; (2) For the mica flakes, there was more than a 2-fold increase in the Fe:Si AR for the microcrystalline surface coatings of the Fe-rich biotite-like flakes but no measurable increase of the Fe:Si AR for the microcrystalline surface coatings of the muscovite-like flakes that contained 3-5 times less Fe; (3) Also for the biotite-like flakes, the increase in Fe:Si AR was greater in the flakes that had a higher Fe:Si AR; (4) The Fe deposition on the Fe-rich microcrystalline surface coatings of the feldspar was much greater than on the Fe-poor, beige quartz and feldspar grains that, prior to elution, had only CaSO4 microcrystalline coatings; and (5) No Fe was deposited on Fe-poor grains with no microcrystalline surface coating.

Arizona↗