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Questa baseline and pre-mining ground-water quality investigation. 10. Geologic influences on ground and surface waters in the lower Red River watershed, New Mexico

This report is one in a series that presents results of an interdisciplinary U.S. Geological Survey (USGS) study of ground-water quality in the lower Red River watershed prior to open-pit and underground molybdenite mining at Molycorp’s Questa mine. The stretch of the Red River watershed that extends from just upstream of the town of Red River, N. Mex., to just above the town of Questa includes several mineralized areas in addition to the one mined by Molycorp. Natural erosion and weathering of pyrite-rich rocks in the mineralized areas has created a series of erosional scars along this stretch of the Red River that contribute acidic waters, as well as mineralized alluvial material and sediments, to the river. The overall goal of the USGS study is to infer the premining ground-water quality at the Molycorp mine site. An integrated geologic, hydrologic, and geochemical model for ground water in the mineralized—but unmined—Straight Creek drainage (a tributary of the Red River) is being used as an analog for the geologic, geochemical, and hydrologic conditions that influenced ground-water quality and quantity in the Red River drainage prior to mining. This report provides an overall geologic framework for the Red River watershed between Red River and Questa, in northern New Mexico, and summarizes key geologic, mineralogic, structural and other characteristics of various mineralized areas (and their associated erosional scars and debris fans) that likely influence ground- and surface-water quality and hydrology. The premining nature of the Sulphur Gulch and Goat Hill Gulch scars on the Molycorp mine site can be inferred through geologic comparisons with other unmined scars in the Red River drainage.

New Mexico

Water-resources investigations of the U.S. Geological Survey in Arkansas, fiscal year 1981

During fiscal year 1981 there were 20 water-resources investigations in progress by the Arkansas District of the U. S. Geological Survey 's Water Resources Division. Investigations that mainly involved data collection included surface-water gaging, water-level measuring, water-quality sampling, sediment sampling, and water-use inventorying. Interpretive studies included three that were principally of ground-water resources, four that were of surface-water flow charateristics, four that were of surface-water quality characteristics, and three that were interdisciplinary.

Arkansas

Computer input and output files associated with ground-water-flow simulations of the Albuquerque Basin, central New Mexico, 1901-95, with projections to 2020; (supplement three to U.S. Geological Survey Water-resources investigations report 94-4251)

This report presents the computer input files required to run the three-dimensional ground-water-flow model of the Albuquerque Basin, central New Mexico, documented in Kernodle and others (Kernodle, J.M., McAda, D.P., and Thorn, C.R., 1995, Simulation of ground-water flow in the Albuquerque Basin, central New Mexico, 1901-1994, with projections to 2020: U.S. Geological Survey Water-Resources Investigations Report 94-4251, 114 p.) and revised by Kernodle (Kernodle, J.M., 1998, Simulation of ground-water flow in the Albuquerque Basin, 1901-95, with projections to 2020 (supplement two to U.S. Geological Survey Water-Resources Investigations Report 94-4251): U.S. Geological Survey Open-File Report 96-209, 54 p.). Output files resulting from the computer simulations are included for reference.

Open-File Report

National Field Manual for the Collection of Water-Quality Data. U.S. Geological Survey Techniques of Water-Resources Investigations, Book 9

The mission of the Water Resources Discipline of the U.S. Geological Survey (USGS) is to provide the information and understanding needed for wise management of the Nation's water resources. Inherent in this mission is the responsibility to collect data that accurately describe the physical, chemical, and biological attributes of water systems. These data are used for environmental and resource assessments by the USGS, other government agenices and scientific organizations, and the general public. Reliable and quality-assured data are essential to the credibility and impartiality of the water-resources appraisals carried out by the USGS. The development and use of a National Field Manual is necessary to achieve consistency in the scientific methods and procedures used, to document those methods and procedures, and to maintain technical expertise. USGS field personnel use this manual to ensure that the data collected are of the quality required to fulfill our mission.

Techniques of Water-Resources Investigations

Water-resources investigations of the U.S. Geological Survey in Missouri, fiscal year 1981

Water-resources investigations of the U.S. Geological Survey in Missouri consist of collecting hydrologic data and making interpretative investigations. The data and the results of the investigations are published or released by either the U.S. Geological Survey or by cooperating agencies. This report describes the data-collection activities and investigations in Missouri for the 1981 fiscal year and provides an extensive list of water-resources references for the State of Missouri.

Missouri

Water-resources investigations in North Dakota; fiscal year 1984

The U.S. Geological Survey, through its Water Resources Division, investigates the occurrence, quantity, quality, distribution, and movement of the surface and underground water that composes the Nation's water resources. This publication contains a brief description of the ongoing investigations of the North Dakota District. Much of the Geological Survey program is conducted in cooperation with other Federal agencies and several state agencies. The publications resulting from the program are listed periodically in a miscellaneous release titled, "Water Resources Investigations of the U.S. Geological Survey, 19XX." The last such release was issued in 1982. They are also listed in a monthly nationwide release titled, "New Publications of the Geological Survey, List XXX--Publications issued in month 19XX."

Open-File Report

Water-resources investigations in Wisconsin

PROBLEM: Surface-water information is needed for surveillance, planning, design, hazard warning, operation, and management in water-related fields such as water supply, hydroelectric power, flood control, irrigation, bridge and culvert design, wildlife management, pollution abatement, flood-plain management, and water-resources development. An appropriate data base is necessary to provide this information. OBJECTIVE: The objectives of this study are to provide continuous discharge records for selected rivers at specific sites to supply the needs for regulation, analytical studies, definition of statistical properties, trends analysis, determination of the occurrence, and distribution of water in streams for planning. The project is also LOCATION: Statewide PROJECT CHIEF: Barry K. Holmstrom PERIOD OF PROJECT: July 1913-Continuing designed to determine lake levels and to provide discharge for floods, low-flow conditions, and for waterquality investigations. Requests for streamflow data and information relating to streamflow in Wisconsin are answered. Basic data are published annually in the report "Water Resources Data-Wisconsin."

Wisconsin

Water-resources investigations of the U.S. Geological Survey in Montana, October 1979 through September 1980

This report describes water-resources investigations of the U.S. Geological Survey in Montana, October 1979 through September 1980. Programs consist of (1) collecting hydrologic data on a continuing basis, (2) conducting water-resources appraisals of surface and ground water, (3) conducting supportive research in hydrology and related fields, (4) disseminating water data and results of investigations to the public, (5) coordinating acquisition of water data by Federal agencies, and (6) providing technical assistance in hydrologic fields to other government agencies. (USGS)

Open-File Report

Questa baseline and pre-mining ground-water quality investigation. 2. Low-flow (2001) and snowmelt (2002) synoptic/tracer water chemistry for the Red River, New Mexico

Water analyses are reported for 259 samples collected from the Red River, New Mexico, and its tributaries during low-flow(2001) and spring snowmelt (2002) tracer studies. Water samples were collected along a 20-kilometer reach of the Red River beginning just east of the town of Red River and ending at the U.S. Geological Survey streamflow-gaging station located east of Questa, New Mexico. The study area was divided into three sections where separate injections and synoptic sampling events were performed during the low-flow tracer study. During the spring snowmelt tracer study, three tracer injections and synoptic sampling events were performed bracketing the areas with the greatest metal loading into the Red River as determined from the low-flow tracer study. The lowflow tracer synoptic sampling events were August 17, 20, and 24, 2001. The synoptic sampling events for the spring snowmelt tracer were March 30, 31, and April 1, 2002. Stream and large inflow water samples were sampled using equal-width and depth-integrated sampling methods and composited into half-gallon bottles. Grab water samples were collected from smaller inflows. Stream temperatures were measured at the time of sample collection. Samples were transported to a nearby central processing location where pH and specific conductance were measured and the samples processed for chemical analyses. Cations, trace metals, iron redox species, and fluoride were analyzed at the U.S. Geological Survey laboratory in Boulder, Colorado. Cations and trace metal concentrations were determined using inductively coupled plasma-optical emission spectrometry and graphite furnace atomic absorption spectrometry. Arsenic concentrations were determined using hydride generation atomic absorption spectrometry, iron redox species were measured using ultraviolet-visible spectrometry, and fluoride concentrations were determined using an ion-selective electrode. Alkalinity was measured by automated titration, and sulfate, chloride, and bromide were analyzed by ion chromatography at the U.S. Geological Survey laboratory in Salt Lake City, Utah.

New Mexico

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in Bowdoin National Wildlife Refuge and adjacent areas of the Milk River basin, northeastern Montana, 1986-87

Concentrations of trace elements, radiochemicals, and pesticides in the Bowdoin National Wildlife Refuge lakes generally were not substantially larger than those in the water supplied from Dodson South Canal or in irrigation drainage. Concentrations of arsenic (47 micrograms/L), uranium (43 microg/L), and vanadium (51 microg/L) in Dry Lake Unit, and boron (1,000 microg/L) in Lake Bowdoin were notably larger than at other sites. Zinc concentrations in an irrigation drain (56 microg/L) and two shallow domestic wells (40 and 47 microg/L) were elevated relative to other sites. Concentrations of gross alpha radiation (64 picocuries/L) and gross beta radiation (71 picocuries/L) were elevated in Dry Lake Unit. Pesticides concentrations at all sites were 0.08 microg/L or less. Water use guidelines concentrations for boron, cadmium, uranium, zinc, and gross alpha radiation were slightly exceeded at several sites. In general, trace-constituent concentrations measured in the water do not indicate any potential toxicity problems in Bowdoin National Wildlife Refuge; however, highwater conditions in 1986 probably caused dilution of dissolved constituents compared to recent dry years. Trace element concentrations in bottom sediments of the refuge lakes were generally similar to background concentrations in the soils. The only exception was Dry Lake Unit, which had concentrations of chromium (99 micrograms/g), copper (37 microg/g), nickel (37 microg/g), vanadium (160 microg/g), and zinc (120 microg/g) that were about double the mean background concentrations. The maximum selenium concentration in bottom sediment was 0.6 microg/g. Pesticide concentrations in bottom sediments were less than analytical detection limits at all sites. With few exceptions, concentrations of trace elements and pesticides in biota generally were less than values known to produce harmful effects on growth or reproduction.

Montana

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Tulare Lake bed area, southern San Joaquin Valley, California, 1986-87

Concentrations of numerous toxic trace elements and pesticides were measured during 1986 in water, sediment, and biota from three areas near the Tulare Lake Bed, southern San Joaquin Valley, California: Kern National Wildlife Refuge, Pixley National Wildlife Refuge, and Westfarmers evaporation ponds about 5 mi west of Kern National Wildlife Refuge, to determine whether toxic constituents in agricultural-irrigation drainage pose a threat to beneficial uses of water, especially to uses by wildlife. Pesticide residues were found to be low at all three areas. Trace element concentrations were found to be comparatively low at the Kern and Pixley National Wildlife Refuge areas and high at the Westfarmers evaporation ponds. Dissolved selenium concentrations were < 1 micrograms/L (ug/L) in areas on and adjacent to the refuges, but ranged from 110 to 360 ug/L in the saline drainwater impounded in the evaporation ponds. The ratio of mean selenium concentrations in biota from Westfarmers ponds compared to biota from Kesterson National Wildlife Refuge (where adverse effects have been documented) is 5 for waterboatman, 2 for avocet liver, 1 for avocet eggs, and < 1 for widgeongrass. The low concentrations measured at Kern and Pixley National Wildlife Refuges suggest that trace elements and pesticides pose little threat to wildlife there; however, impounded subsurface drainage from agricultural irrigation does pose a threat to wildlife at the nearby Westfarmers ponds. Preliminary results of surveys conducted in 1987 indicated that there are adverse biological effects on shorebirds nesting at the ponds, although interpretation of the magnitude of the effects is premature, pending completion of ongoing studies by the U.S. Fish and Wildlife Service. (Author 's abstract)

Water-Resources Investigations Report

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the lower-Colorado River valley, Arizona, California, and Nevada, 1986-87

The Lower Colorado River Valley Irrigation Drainage Project area included the Colorado River and its environs from Davis Dam to just above Imperial Dam. Water, bottom sediment, and biota were sampled at selected locations within the study area and analyzed for selected inorganic and synthetic organic constituents that are likely to be present at toxic concentrations. With the exceptions of selenium and DDE, this study found sampling locations to be relatively free of large concentrations of toxic constituents that could be a threat to humans, fish, and wildlife. Selenium was the only inorganic constituent to exceed any existing standard, criterion, or guideline for protection of fish and wildlife resources. Concentrations of DDE in double-crested cormorants, however, exceeded the criterion of 1.0 microgram per gram established by the National Academy of Sciences and the National Academy of Engineering for DDT and its metabolites for protection of wildlife. Dissolved-selenium concentrations in water from the lower Colorado River appear to be derived from sources above Davis Dam. At this time, therefore , agricultural practices in the lower Colorado River valley do not appear to exacerbate selenium concentrations. This fact, however, does not mean that the aquatic organisms and their predators are not in jeopardy. Continued selenium loading to the lower Colorado environment could severely affect important components of the ecosystem. (Author 's abstract)

Arizona, California, Nevada

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in and near Stillwater Wildlife Management Area, Churchill County, Nevada, 1986-87

A reconnaissance was initiated in 1986 to determine whether the quality of irrigation-drainage water in and near the Stillwater Wildlife Management Area, Nevada, has caused or has potential to cause harmful effects on human health, fish, wildlife, or other beneficial uses of water. Samples of surface and groundwater, bottom sediment, and biota were collected from sites upstream and downstream from the Fallon agricultural area in the Carson Desert, and analyzed for potentially toxic trace elements. Other analysis included radioactive substances, major dissolved constituents, and nutrients in water, and pesticide residues in bottom sediment and biota. In areas affected by irrigation drainage, the following constituents were found to commonly exceed baseline concentrations or recommended criteria for protection of aquatic life or propagation of wildlife: In water, arsenic, boron, dissolved solids, molybdenum, sodium, and un-ionized ammonia; in bottom sediments, arsenic, lithium, mercury, molybdenum, and selenium; and in biota, arsenic, boron, chromium, copper, mercury, selenium, and zinc. In some wetlands, selenium and mercury appeared to be biomagnified, and arsenic bioaccumulated. Pesticides contamination in bottom sediments and biota was insignificant. Adverse biological effects observed during this reconnaissance included gradual vegetative changes and species loss, fish die-offs, waterfowl disease epidemics, and persistent and unexplained deaths of migratory birds. (USGS)

Water-Resources Investigations Report