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Chemical weathering of the Panola Granite: Solute and regolith elemental fluxes and the weathering rate of biotite

Present-day elemental and mineral weathering rates based on solute fluxes are compared quantitatively to past long-term rates determined from solid-state elemental fractionation in a saprolitic granite regolith at Panola, Georgia, USA. Saturated fluid flow across a low-permeability kaolin duripan controls the rate of steady-state unsaturated flow in the underlying saprolite. Water and Cl mass balances and experimental conductivities produce a minimum fluid flux density of 8x10 -2 m yr -1 and a fluid residence time of 12 years. Solute Si flux, based on pore water concentrations and infiltration rates, is 27 mmoles yr -1 , compared to a long-term flux rate of 17 mmoles yr -1 , based on regolith Si loss and reported 36 Cl dating of the regolith surface. Similarities in short- and long-term fluxes imply that parameters influencing silicate weathering, including precipitation, temperature, and vegetative cover, while not necessarily constant, have not significantly impacted Si leaching rates during the last several hundred thousand years. Linear decreases in solid-state Mg with decreasing regolith depth permit the calculation of the long-term biotite weathering rate under isovolumetric steady-state weathering conditions. A rate constant of 3x10 -17 moles m -2 s -1 is up to 5 orders of magnitude slower than that reported for experimental dissolution of biotite, implying very different reaction kinetics during natural weathering. Short-term biotite weathering fails to produce expected increases in solute Mg and K concentrations with increasing depth and fluid residence times in the regolith. This discrepancy indicates that ion exchange disequilibrium and open-system biologic uptake in an aggrading forest ecosystem are of sufficient magnitudes to overwhelm solute fluxes resulting from biotite weathering.

Georgia

Exposure age and erosional history of an upland planation surface in the US Atlantic Piedmont

The upland planation surface in the Piedmont of central New Jersey consists of summit flats, as much as 130 km2 in area, that truncate bedding and structure in diabase, basalt, sandstone, mudstone and gneiss. These flats define a low-relief regional surface that corresponds in elevation to residual hills in the adjacent Coastal Plain capped by a fluvial gravel of late Miocene age. A Pliocene fluvial sand is inset 50 m below the upland features. These associations suggest a late Miocene or early Pliocene age for the surface. To assess exposure age and erosional history, a 4??4 m core of clayey diabase saprolite on a 3 km2 remnant of the surface was sampled at six depths for atmospherically produced cosmogenic 10Be. The measured inventory, assuming a deposition rate of 1??3 x 106 atoms cm-2 a-1, yields a minimum exposure age of 227 000 years, or, assuming continuous surface erosion, a constant erosion rate of 10 m Ma-1. Because the sample site lies about 60 m above the aggradation surface of the Pliocene fluvial deposit, and itself supports a pre-Pliocene fluvial gravel lag, this erosion rate is too high. Rather, episodic surface erosion and runoff bypassing probably have produced an inventory deficit. Reasonable estimates of surface erosion (up to 10 m) and bypassing (up to 50 per cent of total precipitation) yield exposure ages of as much as 6??4 Ma. These results indicate that (1) the surface is probably of pre-Pleistocene age and has been modified by Pleistocene erosion, and (2) exposure ages based on 10Be inventories are highly sensitive to surface erosion and runoff bypassing. Copyright (C) 2000 John Wiley and Sons, Ltd.

Earth Surface Processes and Landforms

The Piedmont landscape of Maryland: a new look at an old problem.

Both equilibrium and episodic erosion features can be recognized in the modern landscape. An equilibrium condition is suggested by adjustment of first and second order streams to rock structure and lithology, entrenchment of some streams against gneiss domes, altitudinal zonation of rock types around gneiss domes, correlation of lithology with overburden thickness on uplands, etc. The long-term episodic character of erosion is suggested by clastic wedges on the adjacent Coastal Plain, an upland of low relief that truncates non-carbonate rocks of different lithologies, isovolumetric chemical weathering of alumino-silicate rocks, clastic deposition in marble valleys, and weathering profile truncation by modern drainage. The upland surface preserved in the eastern Piedmont developed by the Late Cretaceous. In the interval from the Late Cretaceous to the Late Miocene, low input of terrigenous sediments to the Coastal Plain, dominance of marine sedimentation, and spotty evidence of saprolite formation on crystalline rocks, suggest that the Maryland Piedmont was an area of low relief undergoing intense weathering. Incised valleys were formed during a cycle of erosion probably initiated in the Late Miocene and extensive colluvial sediments were deposited on hillslopes by periglacial processes during the Pleistocene.-after Authors

Earth Surface Processes and Landforms

Quantifying chemical weathering rates along a precipitation gradient on Basse-Terre Island, French Guadeloupe: new insight from U-series isotopes in weathering rinds

Inside soil and saprolite, rock fragments can form weathering clasts (alteration rinds surrounding an unweathered core) and these weathering rinds provide an excellent field system for investigating the initiation of weathering and long term weathering rates. Recently, uranium-series (U-series) disequilibria have shown great potential for determining rind formation rates and quantifying factors controlling weathering advance rates in weathering rinds. To further investigate whether the U-series isotope technique can document differences in long term weathering rates as a function of precipitation, we conducted a new weathering rind study on tropical volcanic Basse-Terre Island in the Lesser Antilles Archipelago. In this study, for the first time we characterized weathering reactions and quantified weathering advance rates in multiple weathering rinds across a steep precipitation gradient. Electron microprobe (EMP) point measurements, bulk major element contents, and U-series isotope compositions were determined in two weathering clasts from the Deshaies watershed with mean annual precipitation (MAP) = 1800 mm and temperature (MAT) = 23 °C. On these clasts, five core-rind transects were measured for locations with different curvature (high, medium, and low) of the rind-core boundary. Results reveal that during rind formation the fraction of elemental loss decreases in the order: Ca ≈ Na > K ≈ Mg > Si ≈ Al > Zr ≈ Ti ≈ Fe. Such observations are consistent with the sequence of reactions after the initiation of weathering: specifically, glass matrix and primary minerals (plagioclase, pyroxene) weather to produce Fe oxyhydroxides, gibbsite and minor kaolinite. Uranium shows addition profiles in the rind due to the infiltration of U-containing soil pore water into the rind as dissolved U phases. U is then incorporated into the rind as Fe-Al oxides precipitate. Such processes lead to significant U-series isotope disequilibria in the rinds. This is the first time that multiple weathering clasts from the same watershed were analyzed for U-series isotope disequlibrian and show consistent results. The U-series disequilibria allowed for the determination of rind formation ages and weathering advance rates with a U-series mass balance model. The weathering advance rates generally decreased with decreasing curvature: ∼0.17 ± 0.10 mm/kyr for high curvature, ∼0.12 ± 0.05 mm/kyr for medium curvature, and ∼0.11 ± 0.04, 0.08 ± 0.03, 0.06 ± 0.03 mm/kyr for low curvature locations. The observed positive correlation between the curvature and the weathering rates is well supported by predictions of weathering models, i.e., that the curvature of the rind-core boundary controls the porosity creation and weathering advance rates at the clast scale. At the watershed scale, the new weathering advance rates derived on the low curvature transects for the relatively dry Deshaies watershed (average rate of 0.08 mm/kyr; MAP = 1800 mm and MAT = 23 °C) are ∼60% slower than the rind formation rates previously determined in the much wetter Bras David watershed (∼0.18 mm/kyr, low curvature transect; MAP = 3400 mm and MAT = 23 °C) also on Basse-Terre Island. Thus, a doubling of MAP roughly correlates with a doubling of weathering advance rate. The new rind study highlights the effect of precipitation on weathering rates over a time scale of ∼100 kyr. Weathering rinds are thus a suitable system for investigating long-term chemical weathering across environmental gradients, complementing short-term riverine solute fluxes.

Basse-Terre Island

Neoarchean paleoweathering of tonalite and metabasalt: Implications for reconstructions of 2.69Ga early terrestrial ecosystems and paleoatmospheric chemistry

Field and laboratory investigations of a 2690.83 Ma ( 207 Pb/ 206 Pb age of Saganaga Tonalite) unconformity exposed in outcrop in northeastern Minnesota, USA, reveal evidence for development of a deep paleoweathering profile with geochemical biosignatures consistent with the presence of microbial communities and weakly oxygenated conditions. Weathering profiles are characterized by a 5–50 m thick regolith that consists of saprolitized Saganaga Tonalite and Paulson Lake succession basaltic metavolcanic rocks retaining rock structure, which is cross-cut by a major unconformity surface marking development of a successor basin infilled with alluvial deposits. The regolith and unconformity are overlain by thick conglomerate deposits that contain both intrabasinal (saprock) as well as extrabasinal detritus. Thin-section microscopy and electron microprobe analyses reveal extensive hydrolysis and sericitization of feldspars, exfoliation and chloritization of biotite, and weathering of Fe-Mg silicates and Cu-Fe sulfides; weathering of Fe-Ti oxides was relatively less intense than for other minerals and evidence was found for precipitation of Fe oxides. Geochemical analyses of the tonalite, assuming immobile TiO 2 during weathering ( τ Ti, j ), show depletion of SiO 2 , Al 2 O 3 , Na 2 O, CaO, MgO, and MnO, and to a lesser degree of K 2 O, relative to least-weathered parent materials. Significant Fe was lost from the tonalite. A paleoatmospheric pCO 2 of 10–50 times PAL is estimated based on geochemical mass-balance of the tonalite profile and assuming a formation time of 50–500 Kyr. Interpretations of metabasalt paleoweathering are complicated by additions of sediment to the profile and extensive diagenetic carbonate (dolomite) overprinting. Patterns of release of P and Fe and retention of Y and Cu in tonalite are consistent with recent laboratory experiments of granite weathering, and with the presence of acidic conditions in the presence of organic ligands (produced, for example, by a primitive microbial community) during weathering. Cu metal in the profile may document lower pO 2 than present day at the surface. Comparison with previous studies of weathered tonalite and basalt (Denison, 2.45–2.22 Ga) in Ontario, Canada, reveal general similarities in paleoweathering with our study, as well as important differences related to lower paleoatmospheric pO 2 and terrestrial biosignature for the older Minnesota profile. A falling water table in the Alpine Lake locality is presumed to have promoted formation of this gossan-like deep-weathering system that extends to 50-m depth.

Minnesota

Nitrogen release from rock and soil under simulated field conditions

A laboratory study was performed to simulate field weathering and nitrogen release from bedrock in a setting where geologic nitrogen has been suspected to be a large local source of nitrate. Two rock types containing nitrogen, slate (1370 mg N kg-1) and greenstone (480 mg N kg-1), were used along with saprolite and BC horizon sand from soils derived from these rock types. The fresh rock and weathered material were used in batch reactors that were leached every 30 days over 6 months to simulate a single wet season. Nitrogen was released from rock and soil materials at rates between 10-20 and 10-19 mo1 N cm-2 s-1. Results from the laboratory dissolution experiments were compared to in situ soil solutions and available mineral nitrogen pools from the BC horizon of both soils. Concentrations of mineral nitrogen (NO3- + NH4+) in soil solutions reached the highest levels at the beginning of the rainy season and progressively decreased with increased leaching. This seasonal pattern was repeated for the available mineral nitrogen pool that was extracted using a KCl solution. Estimates based on these laboratory release rates bracket stream water NO3-N fluxes and changes in the available mineral nitrogen pool over the active leaching period. These results confirm that geologic nitrogen, when present, may be a large and reactive pool that may contribute as a non-point source of nitrate contamination to surface and ground waters. ?? 2001 Elsevier Science B.V. All rights reserved.

Chemical Geology

Mapping the radon potential of the united states: Examples from the Appalachians

The geologic radon potential of the United States was recently assessed by the U.S. Geological Survey. Results indicate that approximately 33% of the U.S. population lives within geologic provinces where the average indoor radon levels have the potential to be greater than 4 pCi/L (147 Bq/m3). Rock types most commonly associated with high indoor radon include: 1) Uraniferous metamorphosed sediments, volcanics, and granite intrusives, especially those that are highly deformed or sheared. 2) Glacial deposits derived from uranium-bearing rocks and sediments. 3) Carboniferous, black shales. 4) Soils derived from carbonate rock, especially in karstic terrain. 5) Uraniferous fluvial, deltaic, marine, and lacustrine deposits. Different geologic terrains of the eastern United States illustrate some of the problems inherent in correlating indoor radon with geology. The Central and Southern Appalachian Highlands of the eastern United States have not been glaciated and most soils there are saprolitic, derived directly from the underlying bedrock. Regression analyses of bedrock geologic and radon parameters yield positive correlations (R > 0.5 to 0.9) and indicate that bedrock geology can account for a significant portion of the indoor radon variation. In glaciated areas of the United States such as the northern Appalachian Highlands and Appalachian Plateau, the correlation of bedrock geology to indoor radon is obscured or is positive only in certain cases. In these glaciated areas of the country, it is the type, composition, thickness, and permeability of glacial deposits, rather than the bedrock geology, that controls the radon source.

Conference Paper

The potential for calcium depletion in forest ecosystems of southeastern United States: Review and analysis

Biogeochemical mass balance assessments of calcium status in southeastern forests indicate that losses through harvesting and soil leaching often exceed inputs from atmospheric deposition and weathering. Many forest soils of the southeastern United States are particularly sensitive because these soils and the underlying saprolite from which these soils are derived are largely depleted of weatherable calcium. At most of the intensively studied sites in the southeastern United States, it is estimated that calcium depletion has already reduced or will likely reduce exchangeable soil calcium reserves to less than the estimated requirement for a merchantable forest stand in 150 years or less. At most sites, calcium uptake into merchantable wood equals or exceeds soil leaching losses. Chronic atmospheric deposition of sulfate and nitrate and declining atmospheric deposition of calcium are likely to accelerate calcium depletion. The southeastern U.S. regional distribution of soil calcium pools and calcium fluxes (deposition and uptake in merchantable wood) indicates that the depletion status of the intensively studied sites is representative of a substantially larger area. Where weathering inputs are insufficient to replace leaching and uptake losses, there is a potential for a regional problem in forest nutrition over the long term.

Alabama, Arkansas, Florida, Georgia, Louisiana, Ma

River terrace evidence of tectonic processes in the eastern North American plate interior, South Anna River, Virginia

We show that long-recognized seismicity in the central Virginia seismic zone of the eastern North American intraplate setting arises primarily from tectonic processes predicted by new, fully coupled plate tectonic geodynamic models. The study leverages much new geophysical and geologic data following the 2011 Mineral, Virginia, earthquake that ruptured a steeply dipping, northwest-verging reverse fault traversed by the South Anna River. The data are primarily assembled from a flight of six fluvial terrace geomorphic markers identified and correlated on texture, relative weathering, and numeric ages including one terrestrial cosmogenic nuclide (TCN) profile and 30 luminescence dates. Terrace thickness, stratigraphic age models, and incision rates downstream and upstream of the 2011 rupture are different. Long-term river incision rates of ∼25–30 m/My are superimposed on regional TCN-determined erosion rates of ∼8.5 m/My; however, there are at least 10 m of tectonically driven incision in the epicentral region at rates of ∼30–94 m/My. The inferred deformation resembles a hanging wall anticline above a blind reverse fault with a diffuse overlying carapace of minor brittle faults, an interpretation supported by seismology as well as bedrock and saprolite mapped across the epicentral region. These results are further supported by channel metrics that show nonuniform channel steepness ( k sn ) and a predicted steady-state channel elevation different from the actual channel elevation across the epicentral region. If all of the observed deformation is a consequence of the fault that ruptured in 2011, the recurrence interval of Mineral-sized events would be ∼5.5 ky.

Virginia

Origin of some intermittent ponds on quartzite ridges in western North Carolina

Several intermittent ponds and closed depressions as much as 200 feet wide occur on the crests of ridges in gently dipping Cambrian(?) quartzites in the southeastern foothills of the Blue Ridge Mountains near Morganton, North Carolina . The unconsolidated fill and debris in the ponds consists of clayey sand and saprolite with accessory minerals that could have been derived entirely from the quartzite . The pond water contains appreciable quantities of dissolved silica and with the aid of organic substances could have formed the depressions by solution since the beginning of the Pleistocene.

North Carolina

10Be analysis of a Quaternary weathering profile in the Virginia Piedmont

Samples from a residual weathering profile in the Virginia Piedmont have been analyzed for cosmogenic 10 Be. Concentrations are highest in clay-rich soil and decrease exponentially to a depth of about 15 m. Despite uncertainties about the processes by which 10 Be may be intercepted before entering the solum and eroded after incorporation, a minimum age may be calculated for the regolith. This calculation is based on the delivery rate of 10 Be and its decay rate and suggests that this residual profile developed during a period no shorter than 8 × 10 5 yr. The calculated minimum age may be within a factor of 2 of maximum-age estimates based on surface lowering by erosion and on the rate of rock weathering to saprolite. The vertical distribution of 10 Be in the profile could result from a steady-state balance of deposition, weathering, radioactive decay, and erosion.

Geology

Landslides triggered by Hurricane Maria: Assessment of an extreme event in Puerto Rico

Hurricane Maria hit the island of Puerto Rico on 20 September 2017 and triggered more than 40,000 landslides in at least three-fourths of Puerto Rico’s 78 municipalities. The number of landslides that occurred during this event was two orders of magnitude greater than those reported from previous hurricanes. Landslide source areas were commonly limited to surficial soils but also extended into underlying saprolite and bedrock. Slope failures occurred before, during, and after flooding, and many transitioned into long runout debris flows. Steep slopes in hilly and mountainous regions were particularly impacted by landslides due to antecedent soil moisture levels that were 11%–13% higher than average and rainfall totals of at least 250 mm within a 48 h period. High landslide densities were especially widespread across some geologic formations (e.g., granodiorite of the Utuado batholith); however, bedrock geology alone did not determine the location and distribution of landslides caused by Hurricane Maria. While rainfall data collected during Hurricane Maria were inconsistent, satellite-based soil moisture data were correlated with the distribution of landslides. In the future, the use of soil moisture data could enable assessments of regional landslide susceptibility prior to hurricanes or extreme precipitation events.

GSA Today

Catastrophic rockfalls and rockslides in the Sierra Nevada, USA

Despite having a low recorded historical incidence of landsliding, the Sierra Nevada has undergone large prehistoric and historical rockfalls and rockslides that could be potentially catastrophic if they occurred today in the more densely populated parts of the region. Several large documented rockfall and rockslides have been triggered either by strong seismic shaking or long periods of unusually wet weather; however, in several instances no obvious triggering event can be identified. The glaciated topography of the higher elevations of the Sierra Nevada has produced many relatively small falls and slides within relatively hard, massively jointed, granitic rocks; however, where exposed to weathering for long periods after glaciation, the oversteepened rock slopes are prone to uncommonly large falls and slides. At lower elevations on the nonglaciated slopes of the Sierra Nevada, rockslides commonly occur within more weathered granitic rocks, where the strength of the rock mass is typically affected by joint weathering and alteration of the intact rock to saprolite. Historical large rockfalls and rockslides in the Sierra Nevada have created additional secondary natural hazards, including debris flows and floods from the breaching of landslide dams that can be as hazardous as the initial rockfalls and rockslides.

California

Geochemical investigation of weathering processes in a forested headwater catchment: Mass-balance weathering fluxes

Geochemical research on natural weathering has often been directed towards explanations of the chemical composition of surface water and ground water resulting from subsurface water-rock interactions. These interactions are often defined as the incongruent dissolution of primary silicates, such as feldspar, producing secondary weathering products, such as clay minerals and oxyhydroxides, and solute fluxes (Meunier and Velde, 1979). The chemical composition of the clay-mineral product is often ignored. However, in earlier investigations, the saprolitic weathering profile at the South Fork Brokenback Run (SFBR) watershed, Shenandoah National Park, Virginia, was characterized extensively in terms of its mineralogical and chemical composition (Piccoli, 1987; Pochatila et al., 2006; Jones et al., 2007) and its basic hydrology. O'Brien et al. (1997) attempted to determine the contribution of primary mineral weathering to observed stream chemistry at SFBR. Mass-balance model results, however, could provide only a rough estimate of the weathering reactions because idealized mineral compositions were utilized in the calculations. Making use of detailed information on the mineral occurrence in the regolith, the objective of the present study was to evaluate the effects of compositional variation on mineral-solute mass-balance modelling and to generate plausible quantitative weathering reactions that support both the chemical evolution of the surface water and ground water in the catchment, as well as the mineralogical evolution of the weathering profile. ?? 2008 The Mineralogical Society.

Conference Paper

Inversion of induced polarization-affected towed-transient electromagnetic data in a lateritic regolith geology: A case study from western Tanzania

For several decades, induced polarization (IP) effects on transient electromagnetic (TEM) responses have been observed. These effects can manifest as late-time negative transients or as rapidly decaying curves and are usually associated with highly polarizable bodies. If neglected, IP effects can lead to erroneous resistivity models. Recent work allows IP effects to be incorporated into the inversion of TEM data on a more routine basis. In a recent field survey in western Tanzania, strongly IP-affected TEM signals are observed using a towed-transient electromagnetic (tTEM) system. The survey have been carried out to locate drinking water resources in a weathered regolith setting. In these settings, an inversion of tTEM data using a resistivity-only forward model (i.e., IP neglected) cannot fit the data and severely limits the value of the TEM data for hydrogeologic interpretation. To account for IP effects, we have applied a modified version of the Cole-Cole model called the maximum phase angle (MPA) model to invert IP-affected tTEM data. The MPA model incorporates four inversion model parameters: resistivity ( ⁠ ρ "> ρ ), MPA ( ⁠ ϕ max "> ϕ max ⁠ ), relaxation time ( ⁠ τ "> τ ), and frequency exponent ( ⁠ c "> c ). The MPA model fits the data well and improves the reliability of the resistivity model. In much of the surveyed region, the inverted models using MPA display a three-layer system consisting of an upper resistive laterite layer of varying thickness and an intermediate polarizable conductive unit overlying more resistive weathered basement rocks. The conductive polarizable layer is interpreted as a chemically weathered saprolite separating the surficial and deeper aquifers. Overall, tTEM inversion results provide a local understanding of groundwater systems, especially in such regions with very limited subsurface knowledge.

Kaguruka, Kitagata

The stratigraphy and stratigraphic nomenclature of the Goochland Terrane in the Piedmont Province of east-central Virginia

The Goochland terrane is a structurally isolated crustal block in the eastern Piedmont of Virginia. It is composed of the previously named State Farm Gneiss, Montpelier Anorthosite, Sabot Amphibolite, and Maidens Gneiss, but also includes the Scotchtown Gneiss, Teman Gneiss, and Old Bandana Gneiss which are formally named and defined herein. The eastern part of the Goochland terrane is antiformal and cored by Mesoproterozoic rocks (the State Farm Gneiss and the Montpelier Anorthosite). These basement units are overlain by a late Neoproterozoic to early Paleozoic (Ediacaran to Early Cambrian) saprolitic, metavolcanic, and metasedimentary sequence that sequentially includes the Scotchtown Gneiss, Sabot Amphibolite and Maidens Gneiss. The western part of the terrane is synformal and includes in its core two additional units that overlie the Maidens Gneiss: the Teman Gneiss and the Old Bandana Gneiss. Based on mineralogy and zircon grain morphology, the protoliths of the Maidens, Teman, and Old Bandana gneisses were predominantly sedimentary rocks. The protoliths of the Teman Gneiss and Old Bandana Gneiss were deposited unconformably upon the protolith of the Maidens Gneiss. The eastern and western parts of the Goochland terrane are separated by the Dabneys fault, which has considerable east-side-up vertical offset and possibly also significant transverse displacement. Correlation of the upper part of the Goochland terrane (Teman and Old Bandana gneisses) with the Setters and Cockeysville gneisses in the Baltimore region suggests that the Goochland terrane was left about 135 miles (ca. 220 km) southwest of its original North American location, which was to the east of Baltimore, Maryland. This displacement was caused by the oblique collision of the eastern North American continent with the western edge of the Gondwanan craton during the later Carboniferous (Pennsylvanian) Period.

Virginia

U.S. industrial garnet

The United States presently consumes about 16 percent of global production of industrial garnet for use in abrasive airblasting, abrasive coatings, filtration media, waterjet cutting, and grinding. As of 2005, domestic garnet production has decreased from a high of 74,000 t in 1998, and imports have increased to the extent that as much as 60 percent of the garnet used in the United States in 2003 was imported, mainly from India, China, and Australia; Canada joined the list of suppliers in 2005. The principal type of garnet used is almandite (almandine), because of its specific gravity and hardness; andradite is also extensively used, although it is not as hard or dense as almandite. Most industrial-grade garnet is obtained from gneiss, amphibolite, schist, skarn, and igneous rocks and from alluvium derived from weathering and erosion of these rocks. Garnet mines and occurrences are located in 21 States, but the only presently active (2006) mines are in northern Idaho (garnet placers; one mine), southeastern Montana (garnet placers; one mine), and eastern New York (unweathered bedrock; two mines). In Idaho, garnet is mined from Tertiary and (or) Quaternary sedimentary deposits adjacent to garnetiferous metapelites that are correlated with the Wallace Formation of the Proterozoic Belt Supergroup. In New York, garnet is mined from crystalline rocks of the Adirondack Mountains that are part of the Proterozoic Grenville province, and from the southern Taconic Range that is part of the northern Appalachian Mountains. In Montana, sources of garnet in placers include amphibolite, mica schist, and gneiss of Archean age and younger granite. Two mines that were active in the recent past in southwestern Montana produced garnet from gold dredge tailings and saprolite. In this report, we review the history of garnet mining and production and describe some garnet occurrences in most of the Eastern States along the Appalachian Mountains and in some of the Western States where industrial-grade garnet or its possible occurrence has been reported. Other natural and manmade materials compete with garnet in nearly all of the applications for which garnet can be used; garnet, however, has the advantages that it is reusable, nontoxic, and nonreactive. In addition, garnet produces much less dust than other abrasive materials, and spills are relatively benign and easy to clean up.

Bulletin

Stratigraphic test well, Nantucket Island, Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Water Resources Commission and the Nantucket Conservation Foundation, continuously cored 514 m of sediment and volcanic rock in a stratigraphic and water-quality test near the geographic center of Nantucket Island. Stratified sediments were divided texturally into three zones: the upper zone (0-128 m) contains mostly coarse sand and gravel; the middle zone (128-349 m) contains mostly silty clay and a few beds of sand and silt; and the lower zone (349-457 m) contains soft, unconsolidated, clayey sand. Below the lower zone, a saprolite, composed mostly of clay, grades abruptly downward at 470 m into partially altered basalt that extends to the bottom of the hole at 514 m. Calculations based on the Ghyben-Herzberg principle predicted a zone of freshwater 120-150 m thick. This principle is the theory of hydrostatic equilibrium between freshwater and more dense seawater in a coastal aquifer; it states that for each meter of ground-water elevation above sea level, the freshwater lens will depress the saltwater interface about 40 m below sea level. Freshwater or low-salinity brackish water was found in sediments far below the depth predicted by the Ghyben-Herzberg principle. These interstitial waters are probably relict ground water emplaced during times of low sea level during the Pleistocene. (Woodard-USGS)

Circular