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Description and effects of 1988 drought on ground-water levels, streamflow, and reservoir levels in Indiana

Documentation of the 1988 drought in Indiana was undertaken to aid water-management agencies and planners concerned with periods of below-normal precipitation and their effect on commercial, agricultural, and residential water use. Precipitation, temperature, Palmer Drought Severity Indices, and ground- and surface-water levels from water years 1988 and 1989 were compared to the historical record to evaluate severity, extent, and duration of the 1988 drought in Indiana. Three types of drought-climatological, hydrologic, and agricultural--occurred in most of Indiana during water years 1988 and 1989. The drought began toward the end of calendar year 1987 as annual precipitation decreased to 4.6 inches below the long term mean. By the end of September 1988, statewide precipitation deficits had increased to almost 8 inches below normal. High temperatures during the summer months increased the stress on crops, livestock, and people. Northwest Indiana experienced the second warmest June-August on record. Palmer Drought Severity Indices indicated that a moderate-to-severe drought had occurred in Indiana during most of 1988. Ground-water levels were affected substantially in many areas of the State. Record low-water levels were observed at 12 of the 20 monitoring wells included in this report. A go-day ground-water emergency was declared in parts of northwestern Indiana. Streamflow throughout the State was affected to varying degrees by the drought. Annual mean discharge in some rivers was only slightly less than the mean annual discharge, while others flowed at less than half that value. The effects of low streamflows were felt by many as electric power plants reduced or ceased production and public-water utilities requested conservation measures by their customers. Major reservoirs in the State approached or reached record low levels, causing water supplies as well as recreational activities to be diminished. Most major crops produced in Indiana were affected by the dry conditions. Average yields in 1988 ranged from 50 to 86 percent of 1987 yields.

Indiana

Trends and environmental impacts of virtual water trade

Virtual water describes water embedded in the production of goods and offers meaningful insights about the complex interplay between water, trade and sustainability. In this Review, we examine the trends, major players, traded products and key drivers of virtual water trade (VWT). Roughly 20% of water used in global food production is traded virtually rather than domestically consumed. As such, agriculture dominates VWT, with livestock products, wheat, maize, soybean, oil palm, coffee and cocoa contributing over 70% of total VWT. These products are also driving VWT growth, the volume of which has increased 2.9 times from 1986 to 2022. However, the countries leading VWT contributions (with China, the United States, the Netherlands, Germany and India accounting for 34% of the global VWT in 2022) have remained relatively stable over time, albeit with China becoming an increasingly important importer. VWT can mitigate the effects of water scarcity and food insecurity, although there are concerns about the disconnect between consumers and the environmental impacts of their choices, and unsustainable resource exploitation. Indeed, approximately 16% of unsustainable water use and 11% of global groundwater depletion are virtually traded. Future VWT analyses must consider factors such as water renewability, water quality, climate change impacts and socioeconomic implications.

Nature Reviews Earth & Environment

Preconditioned Conjugate-Gradient 2 (PCG2), a computer program for solving ground-water flow equations

This report documents PCG2: a numerical code to be used with the U.S. Geological Survey modular three-dimensional, finite-difference, ground-water flow model. PCG2 uses the preconditioned conjugate-gradient method to solve the equations produced by the model for hydraulic head. Linear or nonlinear flow conditions may be simulated. PCG2 includes two reconditioning options: modified incomplete Cholesky preconditioning, which is efficient on scalar computers; and polynomial preconditioning, which requires less computer storage and, with modifications that depend on the computer used, is most efficient on vector computers. Convergence of the solver is determined using both head-change and residual criteria. Nonlinear problems are solved using Picard iterations. This documentation provides a description of the preconditioned conjugate gradient method and the two preconditioners, detailed instructions for linking PCG2 to the modular model, sample data inputs, a brief description of PCG2, and a FORTRAN listing.

Water-Resources Investigations Report

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Water supply in the conterminous United States, Alaska, Hawaii, and Puerto Rico, water years 2010–20

We present an assessment of water supply across the conterminous United States (CONUS), Alaska, Hawaii, and Puerto Rico covering water years 2010–20. Our analysis drew on two national hydrologic models, the National Hydrologic Model Precipitation-Runoff Modeling System and the Weather Research and Forecasting model hydrologic modeling system. Both models produced estimates of streamflow, evapotranspiration, soil moisture, snow water equivalent, and other hydrologic states and fluxes. The models were driven by the bias-adjusted 4-kilometer-resolution, long-term regional hydroclimate simulation over the conterminous United States dataset (CONUS404). We assessed spatial and temporal error distributions by comparing monthly simulations at the 12-digit hydrologic unit code and regional scale from both models against external benchmarking datasets. Results showed that average annual rainfall across the CONUS was 857 millimeters per year for the period of analysis, with water year 2012 the driest year (729 millimeters) and water year 2019 the wettest year (995 millimeters). Key interannual variability results included the following: (1) the California–Nevada hydrologic region had the highest variability in precipitation and snow accumulation, and (2) the Texas hydrologic region was among hydrologic regions with the highest variability in precipitation. We related interannual variability in precipitation to storage volumes in soil moisture, snow water equivalent, and lakes and reservoirs to highlight areas with little storage and large year-to-year variability in precipitation. These areas included the Southern High Plains, Central High Plains, Texas, Souris–Red–Rainy, Mississippi Embayment, and Midwest regions. Our analysis of groundwater-level data showed that several of these areas overlap aquifers where groundwater levels were considerably lower than historical averages, including the Colorado Plateaus aquifers, the Rio Grande aquifer system, and the Central and Southern regions of the High Plains aquifer. Many of these lowered groundwater levels are continuations of decades-long declines from overpumping that started well before the assessment period. The resulting water budgets and their analyses provide a high-resolution foundational assessment of the mean state and variability of the terrestrial hydrologic cycle across the CONUS and Alaska, Hawaii, and Puerto Rico to support a wide range of water resource management applications.

Professional Paper

Water-quality appraisal of NASQAN stations below impoundments, eastern Tennessee

The National Stream Quality Accounting Network (NASQAN) is a network of stations at which systematic and continuing water-quality data are collected. Major objectives of this U.S. Geological Survey program are (1) to depict areal variability of streamflow and water-quality conditions nationwide on a year-by-year basis and (2) to detect long-term changes in streamflow and stream quality. Several NASQAN stations in East Tennessee are downstream from impoundments which have a significant effect on water quality. NASQAN data obtained from the Tennessee River below Watts Bar Dam and the Clinch River below Melton Hill Dam were compared to water-quality data from the basins upstream. The comparison indicates that NASQAN data obtained below impoundment may not be adequate to describe a composite picture of water quality in the accounting unit. Detention time of storage in the impoundments is believed to moderate the range of constituent values observed at the NASQAN stations. Data obtained upstream and downstream from Watts Bar Dam indicate that the water sampled at the NASQAN station comes from stratified layers of the impoundment and is not representative of an integrated sample of water from the impoundment. Values of total recoverable iron suggest that, because of adsorption to sediments in impoundments, some constituents are not accurately described by sampling below impoundments. Relations between water-quality constituents and flow at stations on the Clinch River and Tennessee River are not well defined due to regulation. Direct load computations for many constituents were therefore not possible, which diminished the utility of data from these NASQAN stations to account for quantity versus quality of the water. Load computations were only possible for ionic constituents through use of a continuous specific-conductance record as an intermediary. Compensation for the effects of discharge prior to application of the Seasonal Kendall test for trends could not be done and identification of trends in water-quality constituents caused by some process (source) change was not possible. Some water-quality trends indicated by data from the Clinch and Tennessee Rivers might reflect the decreasing trend in discharge during the 1972-82 water years. Thus the stations below Watts Bar Dam and below Melton Hill Dam do not adequately meet the NASQAN objective to detect and assess long-term changes in stream quality.

Tennessee

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma

Water, ice, meteorological, and speed measurements at South Cascade Glacier, Washington, 1999 balance year

Winter snow accumulation and summer snow, firn, and ice melt were measured at South Cascade Glacier, Washington, to determine the winter and net balances for the 1999 balance year. The 1999 winter snow balance, averaged over the glacier, was 3.59 meters, and the net balance was 1.02 meters. Since the winter balance record began in 1959, only three winters have had a higher winter balance. Since the net balance record began in 1953, only 2 years have had a greater positive net balance than 1999. Runoff was measured from the glacier and an adjacent non-glacierized basin. Air temperature, precipitation, and humidity were measured nearby, and ice speed was measured. This report makes these data available to the glaciological and climatological community.

Washington

Evaluation of nutrient, alkalinity, and acid-neutralizing capacity stabilities in water samples analyzed by the U.S. Geological Survey National Water Quality Laboratory, 2023–24

The U.S. Geological Survey evaluated the stability of water-sample chemical analysis of nutrient, alkalinity, and acid-neutralizing capacity constituents with respect to the duration between sample collection and laboratory analysis, also known as the sample holding time. A study began in the spring of 2023 to evaluate the sample stability, between 2 and 180 days after sample collection, of the chemical properties and chemical constituents of alkalinity as calcium carbonate, filtered; acid-neutralizing capacity as calcium carbonate, unfiltered; total ammonia as nitrogen, filtered; total ammonia plus organic nitrogen as nitrogen, filtered and unfiltered; nitrite as nitrogen, filtered; nitrate plus nitrite as nitrogen, filtered; total nitrogen, filtered and unfiltered; orthophosphate as phosphorous, filtered; and total phosphorus as phosphorus (filtered and unfiltered) in water. Both surface water and groundwater matrices were represented. Sample instability varied by observed property and matrix; therefore, providing general guidance for sample holding time is not possible based on matrices alone. No correlations between field measurements of sample characteristics and sample instability were observed. Although observations for some properties indicate sample stability that exceeds the recognized U.S. Geological Survey National Water Quality Laboratory method holding times, this is not necessarily the case for matrices and seasonal characteristics that were not investigated. Based on the limited number of six sample sources used in this study, some patterns emerge for the 12 observed properties studied. Five observed properties generally indicate stability for as many as 180 days after sampling (total nitrogen as nitrogen, both filtered and unfiltered; orthophosphate as phosphorus, filtered; and phosphorus as phosphorus, both filtered and unfiltered). Other observed properties indicate stability for as many as 180 days for some matrices, but not for others. Finally, some observed properties indicate instability well before 180 days.

Scientific Investigations Report

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma

Estimating domestic self-supplied water use in Rhode Island, 2014–21

Water withdrawal from private groundwater wells is often unaccounted for in water planning studies, and water from private wells can be a source of exposure to environmental contaminants. The sizes of populations that depend on private wells for domestic water use and the amounts of water that are withdrawn from these wells are generally poorly represented in data collection efforts because of the challenges of locating, metering, or gathering withdrawal information from individual property owners. To address this problem, the U.S. Geological Survey, in cooperation with the Rhode Island Water Resources Board, estimated the volume of water withdrawn from domestic self-supply wells and the populations who use them for the State of Rhode Island at a 30-meter pixel spatial resolution and one-month temporal resolution between July 2014 and June 2021. The number of people reliant on domestic self-supply wells has increased in Rhode Island over the study period; however, the statewide estimate of total water withdrawal has not statistically increased. Withdrawals from private wells are largest in the inland areas of the western part of the State, and the towns of Scituate and Charlestown have the highest estimated withdrawals. Statewide monthly withdrawals ranged from 3.987 million gallons per day in March 2018 to 7.767 million gallons per day in September 2016. The median per capita domestic water use rate was 46.0 gallons per capita per day.

Rhode Island

Magnitude and frequency of floods in the Suwannee River Water Management District, Florida

Flood-frequency statistics for 2-, 5-, 10-, 25-, 50-. 100-, 200-, and 500-year recurrence intervals, based on three methods of analysis, are presented for 25 continuous-record and seven peak flow partial-record gaging stations in the Suwannee River Water Management District. The first method, for gaged stations, utilizes station records; the second method, for ungaged sites, utilizes regional regression analysis; and the third method uses a weighted combination of the station and regional values. Because the weighted values utilize two more or less independent estimates of the peak flow statistic, they are considered more accurate than the station estimates or the regression estimates alone. Also, the use of another weighting scheme to improve estimates of flood frequency statistics at ungaged sites is demonstrated. The karstic nature of much of the Suwannee River Water Management District significantly attenuates flood peaks in some streams by providing substantial subsurface storage when river stages are high. At such times, springs discharging into rivers may reverse flow temporarily and become sinks.

Florida

Predictions of groundwater PFAS occurrence at drinking water supply depths in the United States

Per- and polyfluoroalkyl substances (PFAS), known colloquially as “forever chemicals”, have been associated with adverse human health effects and have contaminated drinking water supplies across the United States owing to their long-term and widespread use. People in the United States may unknowingly be drinking water that contains PFAS because of a lack of systematic analysis, particularly in domestic water supplies. We present an extreme gradient boosting model for predicting the occurrence of PFAS in groundwater at the depths of drinking water supply for the conterminous United States. Our model results indicate that 71 to 95 million people in the conterminous United States potentially rely on groundwater with detectable concentrations of PFAS for their drinking-water supplies prior to any treatment.

conterminous United States

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Water resources related to breccia pipe uranium mining in the Grand Canyon region

Introduction In the arid Grand Canyon region, water resources are limited to primarily the Colorado River and associated tributaries and to groundwater in the form of seeps and springs. Groundwater resources in the region supply water for human use and support diverse and rich ecosystems in the locations immediately surrounding the seeps and springs. Throughout the region, uranium resources occur and may interact with water resources in both mined and unmined uranium deposits. There is a need to better understand groundwater in the region and the effects from uranium mining in order to better manage the limited water resources in the area. This Fact Sheet summarizes results from U.S. Geological Survey studies that were conducted on this topic from 2012 to 2023.

Arizona

Global performance of remote sensing-based and reanalysis-driven models to estimate open water evaporation

Evaporation plays an essential role in the water cycle, influencing local and regional climates while directly impacting water availability in lakes. However, directly measuring evaporation over water bodies remains challenging due to the high costs of installing and maintaining the required in situ instrumentation. Although several remote sensing algorithms have been providing evaporation estimates, the lack of a global validation hinders our understanding of their relative uncertainties and performances across different regions. Here, we analyze the performance of a suite of models that leverage satellite data and meteorological reanalysis to estimate evaporation over lakes worldwide. We compare 3 remote sensing-based models, 1 reanalysis-driven model and 1 ensemble approach, using in situ observations from 27 lakes representing a diverse range of geographic and climatic regions. Our results demonstrate that, overall, the ensemble outperformed any individual model in terms of accuracy, with a RMSE and a bias of 1.3 and 0.3 mm day −1 , respectively. These findings highlight the benefits of using an ensemble approach to estimate open water evaporation with satellite-based models at the global scale, leveraging the unique strengths of each model. For the individual models, differences in the representation of heat storage changes and advection effects led to lower values of RMSE and bias, depending on the location and depth of the lakes. This study sets the path for future improvement of open water evaporation algorithms globally, while remote sensing techniques are proven satisfactory to monitoring of water loss in lakes globally, an essential step toward effective large-scale water resources management.

Water Resources Research

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida

Uranium analysis of single drops of natural waters using the fission-track technique

The fission-track technique has been applied to uranium analysis of natural waters using a single drop of water. Samples may be collected in the field by evaporating a drop of water on a detector, and samples may then be analyzed by returning the detector to the laboratory. A sample collecting kit has been assembled, which facilitates the designed sampling method. Some unique advantages of this technique are picogram sensitivity (10 -12 g) for uranium on single drops of water, maintenance of sample integrity during transport and storage, and the ability to discern whether the uranium is in solution or in the suspended material. Counting the tracks is the most time-consuming part of the analysis, but it can be reduced by using automatic counting systems. The analytical error is generally ± 10 percent over the entire range of concentrations.

Open-File Report