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Orogenic gold and geologic time: A global synthesis

Orogenic gold deposits have formed over more than 3 billion years of Earth's history, episodically during the Middle Archean to younger Precambrian, and continuously throughout the Phanerozoic. This class of gold deposit is characteristically associated with deformed and metamorphosed mid-crustal blocks, particularly in spatial association with major crustal structures. A consistent spatial and temporal association with granitoids of a variety of compositions indicates that melts and fluids were both inherent products of thermal events during orogenesis. Including placer accumulations, which are commonly intimately associated with this mineral deposit type, recognized production and resources from economic Phanerozoic orogenic-gold deposits are estimated at just over one billion ounces gold. Exclusive of the still-controversial Witwatersrand ores, known Precambrian gold concentrations are about half this amount. The recent increased applicability of global paleo-reconstructions, coupled with improved geochronology from most of the world's major gold camps, allows for an improved understanding of the distribution pattern of orogenic gold in space and time.

Ore Geology Reviews↗

Geologic and geophysical evidence for the influence of deep crustal structures on Paleozoic tectonics and the alignment of world-class gold deposits, north-central Nevada, USA

Geologic data concur with geophysical and isotopic data that suggest the presence of deep crustal fault zones along the Battle Mountain-Eureka (BME) trend and elsewhere in Nevada. The fault zones may have originated during Proterozoic rifting of the continent and were likely substantially reactivated and modified during Paleozoic tectonism. Five distinct Paleozoic structural and stratigraphic domains are defined that demonstrate the complexity of Paleozoic tectonic events and also lead to hypotheses about ways in which the margin could have been modified. The current locations of these domains adjacent to the geophysically and isotopically defined indicators of the buried continent edge corroborate their interactions with the continental margin. During the Tertiary, preexisting crustal fault zones were intersected and reopened during episodes of extension and served as the conduits for deep-sourced, gold-rich fluids, which were disseminated into Paleozoic slope facies sedimentary rocks, forming sediment-hosted Carlin-type and other deposits. Multiple factors including the locations of these deep-seated structures, the original configuration of the lower Paleozoic continental margin of Nevada, and its subsequent reactivation during the Paleozoic all were fundamental controls on the location of younger mineral deposits. A clearer understanding of the original configuration of the margin and of the effects of subsequent Paleozoic and Mesozoic tectonic events on the margin would provide insight into the locations of these and other prospective mineral belts. ?? 2002 Elsevier Science B.V. All rights reserved.

Ore Geology Reviews↗

New Mexico structural zone - An analogue of the Colorado mineral belt

Updated aeromagnetic maps of New Mexico together with current knowledge of the basement geology in the northern part of the state (Sangre de Cristo and Sandia–Manzano Mountains)—where basement rocks were exposed in Precambrian-cored uplifts—indicate that the northeast-trending Proterozoic shear zones that controlled localization of ore deposits in the Colorado mineral belt extend laterally into New Mexico. The shear zones in New Mexico coincide spatially with known epigenetic precious- and base-metal ore deposits; thus, the mineralized belts in the two states share a common inherited basement tectonic setting. Reactivation of the basement structures in Late Cretaceous–Eocene and Mid-Tertiary times provided zones of weakness for emplacement of magmas and conduits for ore-forming solutions. Ore deposits in the Colorado mineral belt are of both Late Cretaceous–Eocene and Mid-Tertiary age; those in New Mexico are predominantly Mid-Tertiary in age, but include Late Cretaceous porphyry-copper deposits in southwestern New Mexico. The mineralized belt in New Mexico, named the New Mexico structural zone, is 250-km wide. The northwest boundary is the Jemez subzone (or the approximately equivalent Globe belt), and the southeastern boundary was approximately marked by the Santa Rita belt. Three groups (subzones) of mineral deposits characterize the structural zone: (1) Mid-Tertiary porphyry molybdenite and alkaline-precious-metal deposits, in the northeast segment of the Jemez zone; (2) Mid-Tertiary epithermal precious-metal deposits in the Tijeras (intermediate) zone; and (3) Late Cretaceous porphyry-copper deposits in the Santa Rita zone. The structural zone was inferred to extend from New Mexico into adjacent Arizona. The structural zone provides favorable sites for exploration, particularly those parts of the Jemez subzone covered by Neogene volcanic and sedimentary rocks.

Arizona, California, Colorado, Idaho, Montana, New↗

Lithogeochemistry of Carlin-type gold mineralization in the Gold Bar district, Battle Mountain-Eureka trend, Nevada

The Gold Bar district contains five Carlin-type gold deposits and four resources for a combined gold endowment of 1.6 M oz [50 t]. The gold deposits are hosted in Devonian carbonate rocks below parautochthonous and allochthonous Paleozoic siliciclastic rocks emplaced during the Early Mississippian Antler orogeny. The district is in the Battle Mountain-Eureka trend, a long-lived structural feature that localized intrusions and ore deposits of different types and ages. The whole-rock geochemistry of four different mineralized and unmineralized Devonian carbonate rock units (two favorable and two unfavorable) were determined and interpreted in the context of the regional geology. A combination of basic statistics, R-mode factor analysis, isocon plots, and alteration diagrams were utilized to (1) identify favorable geochemical attributes of the host rocks, (2) characterize alteration and associated element enrichments and depletions, and (3) identify the mechanism of gold precipitation. This approach also led to the recognition of other types of alteration and mineralization in host rocks previously thought to be solely affected by Carlin-type mineralization. Unit 2 of the Upper Member of the Denay Formation, with the highest Al2O3, Fe2O3 and SiO2 contents and the lowest CaO content, is the most favorable host rock. Based on the high regression coefficients of data arrays on X-Y plots that project toward the origin, Al2O3 and TiO2 were immobile and K2O and Fe2O3 were relatively immobile during alteration and mineralization. Specific element associations identified by factor analysis are also prominent on isocon diagrams that compare the composition of fresh and altered equivalents of the same rock units. The most prominent associations are: Au, As, Sb, SiO2, TI, -CaO and -LOI, the main gold mineralizing event and related silicification and decalcification; Cd, Zn, Ag, P, Ni and Tl, an early base metal event; and MgO, early dolomitization. Alteration diagrams, consisting of X-Y plots of SiO2/Al2O3, K2O/Al2O3, CO2/Al2O3, that documented in classic Carlin-type gold deposits in the region, but the size of the deposits and the intensity of alteration and mineralization are less. The presence of other types of mineralization in the Gold Bar district is also common to most of the other Carlin-type districts located in major mineral belts. The approach used in this study is well suited to the interpretation of multi-element geochemical data from other study areas with superimposed alteration and mineralization. ?? 2002 Elsevier Science B.V. All rights reserved.

Ore Geology Reviews↗

Orogenic gold deposits: a proposed classification in the context of their crustal distribution and relationship to other gold deposit types

The so-called 'mesothermal' gold deposits are associated with reginally metamorphosed terranes of all ages. Ores were formed during compressional to transpressional deformation processes at convergent plate margins in accretionary and collisional orogens. In both types of orogen, hydrated marine sedimentary and volcanic rocks have been added to continental margins during tens to some 100 million years of collision. Subduction-related thermal events, episodically raising geothermal gradients within the hydrated accretionary sequences, initiate and drive long-distance hydrothermal fluid migration. The resulting gold-bearing quartz veins are emplaced over a unique depth range for hydrothermal ore deposits, with gold deposition from 15-20 km to the near surface environment. On the basis of this broad depth range of formation, the term 'mesothermal' is not applicable to this deposit types as a whole. Instead, the unique temporal and spatial association of this deposit type with orogeny means that the vein systems are best termed orogenic gold deposits. Most ores are post-orogenic with respect to to tectonism of their immediate host rocks, but are simultaneously syn-orogenic with respect to ongoing deep-crustal, subduction-related thermal processes and the prefix orogenic satisfies both these conditions. On the basis of their depth of formation, the orogenic deposits are best subdivided into epizonal (<6 km), mesozonal (6-12 km) and hypozonal (>12 km) classes.

Ore Geology Reviews↗

Tectonic setting of synorogenic gold deposits of the Pacific Rim

More than 420 million oz of gold were concentrated in circum-Pacific synorogenic quartz loades mainly during two periods of continental growth, one along the Gondwanan margin in the Palaeozoic and the other in the northern Pacific basin between 170 and 50 Ma. These ores have many features in common and can be grouped into a single type of lode gold deposit widespread throughout clastic sedimentary-rock dominant terranes. The auriferous veins contain only a few percent sulphide minerals, have gold:silver ratios typically greater than 1:1, show a distinct association with medium grade metamorphic rocks, and may be associated with large-scale fault zone. Ore fluids are consistently of low salinity and are CO2-rich. In the early and middle Palaeozoic in the southern Pacific basin, a single immense turbidite sequence was added to the eastern margin of Gondwanaland. Deformation of these rocks in southeastern Australia was accompanied by deposition of at least 80 million oz of gold in the Victorian sector of the Lachlan fold belt mainly during the Middle and Late Devonian. Lesser Devonian gold accumulations characterized the more northerly parts of the Gondwanan margin within the Hodgkinson-Broken River and Thomson fold belts. Additional lodes were emplaced in this flyschoid sequence in Devonian or earlier Palaeozoic times in what is now the Buller Terrane, Westland, New Zealand. Minor post-Devonian growth of Gondwanaland included terrane collision and formation of gold-bearing veins in the Permian in Australia's New England fold belt and in the Jurassic-Early Cretaceous in New Zealand's Otago schists. Collision and accretion of dozens of terranes for a 100-m.y.-long period against the western margin of North America and eastern margin of Eurasia led to widespread, lattest Jurassic to Eocene gold veining in the northern Pacific basin. In the former location, Late Jurassic and Early Cretaceous veins and related placer deposits along the western margin of the Sierra Nevada batholith have yielded more than 100 million oz of gold. Additional significant ore-forming events during the development of North America's Cordilleran orogen included those in the Klamath Mountains region, California in the Late Jurassic and Early Cretaceous; the Klondike district, Yukon by the Early Cretaceous; the Nome and Fairbanks districts, Alaska, and the Bridge River district, British Columbia in the middle Cretaceous; and the Juneau gold belt, Alaska in the Eocene. Gold-bearing veins deposited during the Late Jurassic and Early Cretaceous terrane collision that formed the present-day Russian Far East have been the source for more than 130 million oz of placer gold. The abundance of gold-bearing quartz-carbonate veins throughout the Gondwanan, North American and Eurasian continental margins suggests the migration and concentration of large fluid volumes during continental growth. Such volumes could be released during orogenic heating of hydrous silicate mineral phases within accreted marine strata. The common temporal association between gold veining and magmatism around the Pacific Rim reflects these thermal episodes. Melting of the lower thickened crust during arc formation, slab rollback and extensional tectonism, and subduction of a slab window beneath the seaward part of the forearc region can all provide the required heat for initation of the ore-forming processes.

Ore Geology Reviews↗

Stable isotope, chemical, and mineral compositions of the Middle Proterozoic Lijiaying Mn deposit, Shaanxi Province, China

The Lijiaying Mn deposit, located about 250 km southwest of Xian, is a high-quality ore characterized by low P and Fe contents and a mean Mn content of about 23%. The ore deposit occurs in shallow-water marine sedimentary rocks of probable Middle Proterozoic age. Carbonate minerals in the ore deposit include kutnahorite, calcite, Mn calcite, and Mg calcite. Carbon (−0.4 to −4.0‰) and oxygen (−3.7 to −12.9‰) isotopes show that, with a few exceptions, those carbonate minerals are not pristine low-temperature marine precipitates. All samples are depleted in rare earth elements (REEs) relative to shale and have negative Eu and positive Ce anomalies on chondrite-normalized plots. The Fe/Mn ratios of representative ore samples range from about 0.034 to <0.008 and P/Mn from 0.0023 to <0.001. Based on mineralogical data, the low ends of those ranges of ratios are probably close to ratios for the pure Mn minerals. Manganese contents have a strong positive correlation with Ce anomaly values and a moderate correlation with total REE contents. Compositional data indicate that kutnahorite is a metamorphic mineral and that most calcites formed as low-temperature marine carbonates that were subsequently metamorphosed. The braunite ore precursor mineral was probably a Mn oxyhydroxide, similar to those that formed on the deep ocean-floor during the Cenozoic. Because the Lijiaying precursor mineral formed in a shallow-water marine environment, the atmospheric oxygen content during the Middle Proterozoic may have been lower than it has been during the Cenozoic.

Ore Geology Reviews↗

Composition and origin of Early Cambrian Tiantaishan phosphorite-Mn carbonate ores, Shaanxi Province, China

The Tiantaishan phosphorite-Mn carbonate ores occur in the Early Cambrian Tananpo Formation in complexly folded and faulted rocks located in southern Shaanxi Province. About 65 x 106 tonnes of 17% P2O5 ore reserves exist and Mn-ore reserves are about 8.3 x 106 tonnes of +18% Mn. The stratigraphic sequence in ascending order consists of black phyllite, black to gray phosphorite ore, black phyllite, rhodochrostone ore, Mn mixed-carbonates, and dolostone. Data are presented from microprobe mineral chemistry, whole-rock chemistry, stable isotopes of carbonates, X-ray mineralogy, petrographic and SEM observations, and statistical analysis of chemical data. The dominant ore-forming minerals are hydroxy- and carbonate fluorapatite and Ca rhodochrosite, with Mg kutnahorite and dolomite comprising the Mn mixed-carbonate section. Pyrite occurs in all rock types and alabandite (MnS) occurs throughout the rhodochrostone section. The mean P2O5 content of phosphorite is 31% and argillaceous phosphorite is 16%, while the mean MnO content of rhodochrostone ore is 37%. Phosphorite ores are massive, spheroidal, laminated, and banded, while rhodochrostone ores have oolitic, spheroidal, and granular fabrics. The most distinguishing characteristics of the ores are high total organic carbon (TOC) contents (mean 8.4%) in the phosphorite and high P2O5 contents (mean 2.7%) in the rhodochrostone ore. The atypically high TOC contents in the Tiantaishan phosphorite probably result from very strong productivity leading to high sedimentation rates accompanied by weak reworking of sediments; poor utilization of the organic matter by bacteria; and/or partial replacement of bacterial or algal mats by the apatite. The depositional setting of the ores was the margin of an epicontinental seaway created as a direct consequence of global processes that included break-up of a supercontinent, formation of narrow seaways, creation of extensive continental shelves, overturn of stagnant, metal-rich deep-ocean waters, and marine transgression. Water depth increased from deposition of the black phyllite sequence through deposition of the Mn mixed-carbonate sequence, then shallowed again during deposition of the overlying dolostone sequence. Bottom waters were mostly dysoxic to suboxic, but fluctuated from oxic to anoxic. Productivity was high during deposition of the black phyllite sequence, increased during precipitation of phosphorite, and then decreased to moderate levels during precipitation of rhodochrostone ores. Biosilica contributions occur in each lithology, but are greatest in rhodochrostone. Changes in sedimentation were determined by changes in water depth, productivity, upwelling, sea-level change, and ventilation of the depositional basin. The source of the phosphorus was organic matter produced in great quantities during deposition of the black phyllite and phosphorite sequences in a zone of coastal upwelling. Organic matter accumulation was rapid. Globally, Mn was supplied by overturn of stagnant, metal-rich deep-ocean waters, which were redistributed to areas of coastal upwelling and seaways; that process may have been initiated by latest Proterozoic glaciations which would have promoted density stratification and accumulation and storage of metals. Regionally, Mn was supplied by terrigenous input into the shallow seaway and hydrothermal input into the deeper water parts of that seaway. Locally, Mn sources included leaching and transport of metals from the sediment column. Manganese was stored locally in low-oxygen (not anoxic) seawater prior to Mn-ore formation. The source of the carbon in the Mn carbonates and dolostones was predominantly seawater bicarbonate and secondarily CO2 derived from the oxidation of organic matter in the bacterially mediated diagenetic zone of sulfate reduction.

Ore Geology Reviews↗

Ordovician reef-hosted Jiaodingshan Mn-Co deposit and Dawashan Mn deposit, Sichuan Province, China

The Jiaodingshan Mn-Co and Dawashan Mn deposits are located in the approximately 2-m thick Daduhe unit of the Wufengian strata of Late Ordovician (Ashgill) age. Paleogeographic reconstruction places the deposits at the time of their formation in a gulf between Chengdu submarine rise and the Kangdian continent. The Jiaodingshan and Dawashan deposits occur in algal-reef facies, the former in an atoll-like structure and the latter in a pinnacle reef. Ores are mainly composed of rhodochrosite, kutnahorite, hausmannite, braunite, manganosite, and bementite. Dark red, yellowish-pink, brown, green-gray, and black ores are massive, banded, laminated, spheroidal, and cryptalgal (oncolite, stromatolite, algal filaments) boundstones. Blue, green, and red algal fossils show in situ growth positions. Samples of high-grade Jiaodingshan and Dawashan ores assay as much as 66.7% MnO. Jiaodingshan Mn carbonate ores have mean contents of Ba, Co, and Pb somewhat higher than in Dawashan ores. Cobalt is widely distributed and strongly enriched in all rock types as compared to its crustal mean content. Cobalt is correlated with Cu, Ni, and MgO in both deposits and additionally with Ba and Zn in the Dawashan deposit. The δ 13 C(PDB) values of Mn carbonate ores (-7.8 to -16.3‰) indicate contributions of carbon from both seawater bicarbonate and the bacterial degradation of organic matter, the latter being 33% to 68%, assuming about -24‰ for the δ 13 C(PDB) of the organic matter. Host limestones derived carbon predominantly from seawater bicarbonate δ 13 13C(PDB) of +0.2 to -7‰). NW-trending fault zones controlled development of lithofacies, whereas NE-trending fault zones provided pathways for movement of fluids. The source of Co, Ni, and Cu was mainly from weathering of mafic and ultramafic rocks on the Kangdian continent, whereas contemporaneous volcanic eruptions were of secondary importance. The reefs were likely mineralized during early diagenesis under shallow burial. The reefs were highly porous and acted as the locus for metasomatic replacement by Mn that combined with CO 2 produced during oxidation of organic matter in the zone of sulfate reduction and seawater bicarbonate. That metasomatic replacement formed the rhodochrosite ores.

Ore Geology Reviews↗

Tungsten resources of the northern Rocky Mountains, Montana and Idaho— A synthesis and quantitative assessment of skarn-hosted resources

Mineral resource assessments performed by the U.S. Geological Survey provide a synthesis of available information about the location of known and suspected mineral deposits. This study focuses on skarn-hosted tungsten resources in the northern Rocky Mountain region of east-central Idaho and western Montana which have seen moderate tungsten trioxide production in the past from a variety of mineralization styles including skarn, vein and replacement, and wolframite-quartz veins. The area’s geology is dominated by large Cretaceous and Tertiary plutons that are emplaced into a belt of Mesoproterozoic to Permian sedimentary rock and affected by tectonism related to the Sevier and later Laramide orogenies. Known tungsten skarn mineral sites are associated with contacts between Cretaceous plutons and calcareous and argillaceous sedimentary or metasedimentary rocks, including two skarn deposits in Montana (Calvert and Browns Lake) that are consistent with an updated grade and tonnage model. This study (1) delineates permissive tracts where undiscovered tungsten skarn deposits may occur within 1 kilometer of the surface; (2) presents a tungsten mineral site dataset from a variety of public sources; (3) evaluates currently available geochemical, geophysical, and radiometric age data in support of tract delineation; (4) provides probabilistic estimates of the amount of tungsten and tungsten-mineralized rock that could be contained in undiscovered deposits within one major tract; (5) estimates the value of total undiscovered deposits using economic filter analysis; and (6) provides a synthesis of metallogenic controls on regional tungsten skarn and granitoid-related mineral deposits. Two permissive tracts were delineated: the Great Falls tectonic zone (GFTZ)-Cretaceous tract, for which a quantitative assessment was performed, and the Bitterroot tract, which was assessed in a qualitative manner. The quantitative three-part assessment, conducted in August 2019, indicates that undiscovered tungsten resources might exist in skarn-type deposits within the study area. Using a negative binomial function, a mean of 4 undiscovered deposits was calculated from panel estimates. Simulation results that combine an updated grade and tonnage model with estimates of undiscovered deposits include the amounts of ore and contained tungsten trioxide at different levels of uncertainty. A mean of 250,000 metric tons and median of 200,000 metric tons contained tungsten trioxide was calculated for the undiscovered deposits within the GFTZ-Cretaceous tract. The value of undiscovered deposits was estimated using a new economic filter that considers factors such as mine type, deposit depth, deposit geometry, metallurgical recovery rate, cutoff grade, and tract area. A review of the regional Archean to Paleogene geology suggests that ore metal (copper, molybdenum, and tungsten) variations in intrusion-related deposits of Montana and Idaho may be controlled by a number of factors including the age and composition of underlying basement terranes, depth of emplacement, pluton chemistry and degree of fractionation, redox conditions, and aqueous fluid-melt partition coefficients.

Idaho, Montana↗

The timing of ore formation in southeast Missouri: Rb-Sr glauconite dating at the Magmont mine, Viburnum trend

Seven Bonneterre and Davis Formation glauconite samples from the Magmont mine area, Viburnum Trend, southeast Missouri, yield a 359 + or - 22-m.y. Rb-Sr isochron with an initial 87 Sr/ 86 Sr ratio of 0.7234 + or - 0.0273 (2 sigma). Gangue calcite from the ore zone has an 87 Sr/ 86 Sr ratio of approximately 0.7112. The isochron age for the Magmont glauconite samples is about 30 percent younger than the age of their Cambrian host rocks.The Rb/Sr ratios for Magmont glauconite samples are typical of many early Paleozoic glauconites but distinctly lower than ratios for glauconites from unmineralized localities in basinal Bonneterre facies, some distance from the Vibrunum Trend. Because the Rb-Sr data from Magmont glauconite samples define an isochron, it appears that the glauconites behaved as a cogenetic suite which was isotopically homogenized 359 m.y. ago. It is very unlikely that episodic or incomplete loss or exchange of radiogenic strontium, or the addition of rubidium, would result in the formation of an isochron. Addition of common strontium (mixing) will lower and produce a greater spread in Rb/Sr ratios but will not significantly change the calculated Rb-Sr isochron age for the glauconites. Because the total thickness of stratigraphic cover in the southeast Missouri region has never exceeded a kilometer, it is unlikely that the anomalously young glauconite isochron age resulted from heating associated with deep burial. Mississippi Valley-type ore fluids offer a hot, chemically reactive medium which could promote isotopic homogenization in glauconites. Therefore, the 359-m.y. age probably reflects a real geologic event, most likely the time of ore formation in southeast Missouri. A review of other attempts at dating early Paleozoic glauconites from the midcontinental United States indicates that all Rb-Sr and K-Ar glauconite ages are 10 to greater than 30 percent younger than their known stratigraphic ages. These glauconites are from Paleozoic formations on the stable craton, and again, resetting due to burial metamorphism is unlikely. Because there was no immediately obvious explanation for the discordant young ages, early Paleozoic glauconites were simply considered to be unsuitable geochronometers. It is suggested that the anomalously young radiometric ages for early Paleozoic glauconites record disturbances in the Rb-Sr and K-Ar isotopic systems, the result of Mississippi Valley-type fluid migration in the midcontinent region.

Economic Geology↗

Volcanogenic uranium deposits: Geology, geochemical processes, and criteria for resource assessment

Felsic volcanic rocks have long been considered a primary source of uranium for many kinds of uranium deposits, but volcanogenic uranium deposits themselves have generally not been important resources. Until the past few years, resource summaries for the United States or the world generally include volcanogenic in the broad category of "other deposits" because they comprised less than 0.5 percent of past production or estimated resources. Exploration in the United States from the 1940s through 1982 discovered hundreds of prospects in volcanic rocks, of which fewer than 20 had some recorded production. Intensive exploration in the late 1970s found some large deposits, but low grades (less than about 0.10 percent U 3 O 8 ) discouraged economic development. A few deposits in the world, drilled in the 1980s and 1990s, are now known to contain large resources (>20,000 tonnes U 3 O 8 ). However, research on ore-forming processes and exploration for volcanogenic deposits has lagged behind other kinds of uranium deposits and has not utilized advances in understanding of geology, geochemistry, and paleohydrology of ore deposits in general and epithermal deposits in particular. This review outlines new ways to explore and assess for volcanogenic deposits, using new concepts of convection, fluid mixing, and high heat flow to mobilize uranium from volcanic source rocks and form deposits that are postulated to be large. Much can also be learned from studies of epithermal metal deposits, such as the important roles of extensional tectonics, bimodal volcanism, and fracture-flow systems related to resurgent calderas. Regional resource assessment is helped by genetic concepts, but hampered by limited information on frontier areas and undiscovered districts. Diagnostic data used to define ore deposit genesis, such as stable isotopic data, are rarely available for frontier areas. A volcanic environment classification, with three classes (proximal, distal, and pre-volcanic structures), permits use of geologic features on 1:500,000 to 1:100,000 scale maps. Geochemical databases for volcanic rocks are postulated to be more effective than databases for stream sediments or surface radioactivity, both of which tend to be inconsistent because of variable leaching of uranium from soils. Based on empirical associations, spatial associations with areas of wet paleoclimate, adjacent oil and gas fields, or evaporite beds are deemed positive. Most difficult to estimate is the location of depositional traps and reduction zones, in part because they are mere points at regional scale. Grade and tonnage data are reviewed and discussed for 32 deposits in the world. Experience of mining engineers and geologists in Asia suggests that tonnages could be higher than presently known in the Western Hemisphere. Geological analysis, and new data from Asia, suggest a typical or median deposit tonnage of about 5,000 tonnes U 3 O 8 , and an optimistic forecast of discoveries in the range of 5,000 to 20,000 tonnes U 3 O 8 . The likely grade of undiscovered deposits could be about 0.15 percent U 3 O 8 , based on both western and eastern examples. Volcanic terrane is under-explored, relative to other kinds of uranium deposits, and is considered a favorable frontier area for new discoveries.

Open-File Report↗

Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast

Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived from environmental studies and existing databases to depict existing conditions and potential environmental concerns associated with mining this deposit type. This geoenvironmental model describes how features of the deposits including host rock; ore and gangue mineralogy; geologic, hydrologic, and climatic settings; and mining methods (legacy open-pit and in situ recovery [ISR]) influence potential environmental effects from mining. Element concentrations in soil and water are compared to regulatory thresholds to depict ambient surface water and groundwater conditions. Although most open-pit operations in this region have been reclaimed, concerns remain about groundwater quality at three of the four former mills that supported former open-pit mines and are undergoing closure activities. The primary environmental concerns with ISR mining are (1) radon gas at active ISR operations, (2) radiation or contaminant leakage during production and transport of ISR resin or yellowcake, (3) uranium excursions into groundwater surrounding active ISR operations, and (4) contamination of groundwater after ISR mining. Although existing regulations attempt to address these concerns, some problems remain. Researchers suggest that reactive transport modeling and a better understanding of geology, stratigraphy, and geochemistry of ISR production areas could minimize excursions into surrounding aquifers and improve results of groundwater restoration.

Texas↗

Review of the use of magnetic concentrates in geochemical exploration

Magnetic concentrates recovered readily by hand magnet from alluvial sediments or panned concentrates have been used successfully in exploration as a geochemical sample medium for Cu, Zn, Co, Cr, Mo, Ni, V, Sn, and Be, particularly in arid environments where alluvial sediments may be contaminated by aeolian debris. Opportunity for this use arose recently as chemical and spectrographic techniques were developed to determine the abundances of a variety of trace elements in Fe-rich media. The use of analytical data from magnetic concentrates was introduced as one of several anomaly-enhancement techniques based on heavy minerals and intended to identify blind ore deposits. An extensive literature, reviewed here, on the relation of the chemical composition of the mineral magnetite, a main component of magnetic concentrates, to geologic conditions of origin, facilitates the interpretation of trace-element data in the context of association with ore deposits.

Open-File Report↗

Geologic characteristics of sediment- and volcanic-hosted disseminated gold deposits - Search for an occurrence model

The current expansion of resource information, particularly on "disseminated" gold, and the improved technologies now available for resource investigations should place us in an enhanced position for developing a better predictive methodology for meeting one of the important responsibilities of the U.S. Geological Survey-to examine and assess the mineral resources of the geologic terranes composing the public (and privately owned) lands of the United States. The first step is systematic organization of these data. Geologic-occurrence models are an effective systematic method by which to organize large amounts of resource information into a logical sequence facilitating its use more effectively in meeting several industry and Survey objectives, which include the exploration for resources and the assessment of resource potential for land-use decisions. Such models also provide a scientific basis for metallogenesis research, which considers the observable features or attributes of ore occurrence and their "fit" into the Earth's resource puzzle. The use of models in making resource assessments/appraisals was addressed by Shawe (1981), who reported the results of a workshop on methods for resource appraisal of Wilderness and Conterminous United States Mineral Appraisal Program (CUSMAP; 1:250,000-scale quadrangles) areas. The Survey's main objective in the 1982 workshop was to evaluate the status of knowledge about disseminated or very fine grained gold deposits and, if possible, to develop an occurrence model(s). This report on the workshop proceedings has three main objectives: (1) Education through the publication of a summary review and presentation of new thinking and observations about the scientific bases for those geologic processes and environments that foster disseminated gold-ore formation; (2) systematic organization of available geologic, geochemical, and geophysical information for a range of typical disseminated gold deposits (including recognition of gaps in those data); and (3) assessment of current understanding (as presented in objective 2) toward formulating an empirical ore-occurrence model for this type of deposit. As such, this volume represents a preliminary first step at classification and provides a source of pertinent background information. Readers of this volume will soon discover, however, that full agreement has not yet been achieved in the interpretation of some of the geologic evidence. The resulting variations in tentative occurrence models for these controversial deposits ultimately will be resolved by filling the gaps in information that have already been identified. Thus, this volume does not report a U.S. Geological Survey consensus; the conclusions expressed in each chapter represent the particular interpretations of the various workshop participants.

Arizona, California, Idaho, Nevada, Utah↗