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Preparing for today's and tomorrow's water-resources challenges in eastern Long Island, New York

Freshwater is a vital natural resource. Although New York is a water-rich State, the wise and economical use of water resources is needed to ensure that there is enough water of adequate quality for both human and ecological needs—both for today and for tomorrow. Nowhere in New York is this more evident than in Nassau and Suffolk Counties on Long Island, where the public water supply is obtained from the sole-source aquifers located directly beneath the nearly 3 million people who live there. In 2023, in eastern Long Island’s Suffolk County, groundwater was pumped from these aquifers by more than 1,100 public water-supply wells to meet the needs of about 1.5 million people.

New York

Geohydrology of the Cross-Florida Barge Canal area, with special reference to the Ocala vicinity

The Cross-Florida Barge Canal route commences at Palatka on the St. Johns River, about 75 miles upstream from the Atlantic Ocean, and extends 110 miles southwestward across Peninsular Florida into deep water in the Gulf of Mexico near Yankeetown. The canal will be equipped with five locks, each 600 feet long and 84 feet wide, and the channel will be a minimum of 12 feet deep and 150 feet wide. From near Ocala northeastward, the canal channel will replace much of the natural channel of the Oklawaha River, and will be excavated into beds of the so-called shallow sand aquifer of Miocene age and younger, which overlies limestone of the Floridan aquifer. Westward from Ocala, most of the canal will be excavated below the potentiometric surface into limestone and dolomite of the Floridan aquifer. Water levels of Rodman, Eureka, and Inglis Pools will be controlled by dams and spillways with the limited exchange of water between the pools and the aquifers. The water levels in the Summit Pools will fluctuate with the natural changes in the ground-water level of the Floridan aquifer, although the stage of the pool will be controlled partly by the stage held in the Eureka Pool. A dynamic inflow-outflow relationship will exist between the Summit Pool and the Floridan aquifer. The Floridan aquifer in the canal area is 1,000 to 1,200 feet thick and consists of limestone and dolomite of middle Eocene Miocene age, including from older to younger, the Lake City, Avon Park, and Ocala limestones plus permeable sandy, dolomitic limestone in the lower part of the Hawthorn Formation. It is possible that most of the flow to the two major springs in the area occurs in the upper 100 feet or so of the aquifer in the Ocala Limestone. The aquifer is underlain by the Oldsmar limestone of early Eocene age and is overlain by sand, clayey sand, clay and shell beds of Miocene through Holocene age, in thickness from a few feet to 300 feet. The permeable beds overlying the Floridan aquifer constitute the shallow aquifer, while the poorly permeable ones act as confining beds where the Floridan aquifer is under artesian conditions. A north-south line drawn separating the head of Silver Springs on the west from the Oklawaha River on the east marks the approximate western limit of a continuous blanket of materials of Miocene-Pliocene(?) age covering the rocks of the Floridan aquifer. East of the line, much of the aquifer is under artesian conditions, particularly in the Oklawaha River valley, although in some areas east of the valley, direct recharge through thick permeable Miocene-Pliocene(?) sands occurs. West of the line, only scattered remnants of a once continuous Miocene-Pliocene(?) cover remain. Lack of the cover is a result of erosion on the crest and flank of the Ocala Uplift, a broad northwest-southeast trending anticlinal upwarp, the axis of which is crossed by the canal route in the Dunnellon area. Over most of this area the Floridan aquifer is unconfined and receives direct recharge through a cover of a few tens of feet of sand and clayey sand of Quaternary age. Tensional stresses during the structural evolution of the Ocala Uplift produced an intersecting system of fractures and normal faults in rocks of the Floridan aquifer. The fractures and faults are important controls for orientation of solution channels and, therefore, for development of ground-water circulation patterns. When the system surface streams, which once drained the Barge Canal area, eroded the poorly permeable Miocene-Pliocene(?) cover from the flanks of the Ocala Uplift, surface runoff was reduced and precipitation began to directly infiltrate the underlying limestones. Now only principal streams remain, such as the Oklawaha and Withlacoochee Rivers and a few short tributaries, while one of the most highly developed subsurface drainage systems in the world has evolved in cavernous limestone of the Floridan aquifer. Two of the larger freshwater springs in the world now discharge from the Floridan aquifer in the canal area. Silver Springs near Ocala discharges an average 531 mgd (million gallons per day) down the 4-mile long Silver River, which flows on poorly permeable beds to the Oklawaha River. Rainbow Springs near Dunnellon discharges on average 468 mgd from numerous orifices in the bed of the 5-mile-long Rainbow River, which flows into the Withlacoochee River. The heads of the springs have migrated to their present positions partly because of a tendency of ground-water levels to decline as permeability in the aquifer is increased due to removal of limestone by solution, and because of mechanical erosion of the limestone in the vicinity of the spring heads. Also, points of principal spring discharges have shifted in the past due to changes in ground-water levels in response to changes in sea level. The subsurface drainage system is continuing to evolve today, as evidenced in part by frequent occurrence of new sinkholes and by the presence of significant amounts of calcium bicarbonate in the spring waters. Rodman Pool, at the east end of the canal, is separated from the Floridan aquifer by poorly permeable materials. The pool's operating water level will be only a few feet above the potentiometric surface at the downstream end, and at or slightly below the potentiometric surface at the upstream end. Little exchange of water between the Rodman Pool and the Floridan aquifer is expected. Eureka Pool, just upstream from Rodman Pool, will also be separated from the Floridan aquifer by poorly permeable beds. However, the stage of the pool will be about 15 feet higher than the natural potentiometric surface at the pool's downstream end, and some seepage into the Floridan aquifer is anticipated through faults and leaky parts of the poorly permeable beds, with a consequent rise in ground-water levels in areas adjacent to the lower end of the pool. Possibilities for particulate contamination of the aquifer will tend to be minimized because of the filtering capacity of the materials through which water must pass to reach the aquifer, although the natural filter will not preclude movement into the aquifer of contaminants which might become dissolved in the pool waters. No significant interchange of water between the pool and the aquifer is expected at the upstream end of the Eureka Pool. Present construction plans indicate an operating stage for Eureka Pool which will range between 38 and 40 feet above mean sea level, although it is possible to dredge the pool deep enough to permit a range in stage of 36 to 40 feet. A backwater effect extending up Silver River from the Eureka Pool is expected to regulate the stage at the head of Silver Springs between 39 and 44 feet above mean sea level if the pool ranges between 36 and 40 feet. If Eureka Pool ranges only between 38 and 40 feet, the range of stage at the head of the springs should be about 41 to 44 feet above mean sea level. From Inglis Lock west, the canal will have direct connection with the Gulf, and canal stage will fluctuate with the Gulf tide. Since the canal stage will be slightly lower than the adjacent ground-water levels along much of the reach, there will be some ground-water inflow to the canal. No significant changes in the existing ground-water regime are expected in the vicinity of Inglis Pool, the first step up in the canal east of the Gulf. Existing ground-water and surface-water levels in the area will not change appreciable, and the natural stage and flow of Rainbow Springs, which will flow by way of Rainbow River into Inglis Pool, should not be affected by canal operations. A possible adverse effect of the canal on the Inglis Pool area could result if sea water is locked up from the Gulf through Inglis Lock. However, the high step of 25 feet at the lock, flushing action of continuous flow from Inglis Pool to the lower reaches of the Withlacoochee River, and use of possible preventive locking procedures should minimize the problem. The potential for adverse effects on the ground-water regime is greatest in the area of the Summit Pool. Through most of the length of the pool, the canal channel will be excavated into limestone of the Floridan aquifer to depths of 12 to 27 feet below the potentiometric surface. Changes that will take place in the ground-water flow system in the Silver Springs drainage area, once the canal is completed, were estimated by flow-net analysis. Variation in aquifer transmissivity was determined by calculating transmissivity in 25 different flow cells surrounding Silver Springs. Transmissivity in the 25 cells averages about 15,600,000 gpd/ft [2,090,000 ft2/day (feet squared)], but transmissivity in the six cells through which the Summit Pool passes ranges from 9,000,000 to 44,000,000 gpd/ft (1,210,000 to 5,900,000 ft2/day). Transmissivity was used to compute static stage of the Summit Pool under given ground-water level conditions. Had the canal existed in May 1968 and had the stage of Eureka Pool been held at 36 feet at the time, the static stage in Summit Pool would have been about 42.1 feet above mean sea level. Thus, a conceptual model of the changes in the potentiometric surface wrought by the finished canal was drawn, and zones of ground-water inflow and outflow were delineated. Most outflow from the Summit Pool to the aquifer should be limited to one 4-mile-long zone along the north side of the pool, about 5 miles south of Silver Springs. It is estimated that a water volume equivalent to about 8 percent of the daily flow of Silver Springs will enter the Summit Pool each day from the southern one-third of the Silver Springs drainage area. A like amount will reenter the aquifer at the main zone of outflow and move toward Silver Springs at an estimated average velocity of about 200 feet per day, if something close to the natural static stage of the pool is maintained by return pumpage of the lockage losses. At a velocity of 200 feet per day, water from the Summit Pool would discharge at Silver Springs about 140 days later. However, any estimate of velocity in the highly cavernous limestone aquifer in the area should be used with caution, because difficult to measure changes in porosity and thickness of major zones of flow may cause large variations in velocity. If all lockage losses are returned to the Summit Pool by pumping from Eureka Pool, no net loss from the Silver Springs drainage area, except for some evaporation from the water surface in the canal and possible leakage around locks, will result from canal operations. The zone of outflow from the Summit Pool to the aquifer will be in a natural potentiometric trough, and the zone of inflow will be in a potentiometric ridge area. The equilibrium water level in the pool will tend to be about 1 foot higher than the altitude of the lowest level in the pre-canal potentiometric trough, and about 2 feet lower than the highest level on the pre-canal potentiometric ridge. West of the Silver Springs drainage area just east of Dunnellon Lock, in the area of a local potentiometric high, the water level in the Summit Pool is expected to be about 15 feet below the natural potentiometric surface. In most areas 2 to 3 miles away from the Summit Pool, effects of the canal on the natural potentiometric surface should be slight. The stage of the Summit Pool, judging from the 36-year record for ground-water level changes and the anticipated indirect effect of the controlled stage in Eureka Pool, should have a maximum of about 10.5 feet with a maximum water level of about 51.5 feet above mean sea level and a minimum of about 41.0 feet above mean sea level. Of particular importance in the Summit Pool is an implementation of well planned construction and operational procedures designed to minimize risks of ground-water contamination.

Florida

Evaluation of best management practices at an edge-of-field site in the Eagle Creek watershed, Ohio, 2012–20

In 2010, the U.S. Geological Survey worked in partnership with the Great Lakes Restoration Initiative and the Natural Resources Conservation Service to identify farm fields in priority watersheds—watersheds critically important to Great Lake health. Intensive best management practices were implemented in five States to test the efficacy of best management practices, also referred to as agricultural conservation practices, to reduce sediment and nutrient runoff on agricultural fields. These fields were chosen as representatives of the priority watersheds because their farming practices and geographical conditions were common among farms in those watersheds. A farm site located near Findlay, Ohio, in the Eagle Creek watershed used two conservation practices, cover crop (Natural Resources Conservation Service practice standard 340) and variable rate technology (VRT; Natural Resources Conservation Service practice standard 590), which represent common practices in the Maumee priority watershed. This study monitored surface runoff and subsurface tile runoff at the Eagle Creek watershed site. The effects of cover crop and VRT nutrient application on sediment and nutrient runoff were assessed from October 2012 to September 2020. Cover crops were applied in fall of 2016, 2017, and 2018, coinciding with VRT applications. The following parameters were analyzed as part of the study: runoff discharge; peak discharge; and concentrations and loads of total phosphorus, particulate phosphorus, dissolved reactive phosphorus, and suspended sediment. High peak runoff events disproportionally affected nutrient concentrations and loads in runoff. A threshold of the 85th percentile of the peak discharge was chosen to assess the effect of cover crop and VRT nutrient application on nutrient mitigation at each gage. Runoff events below the 85th percentile were considered small, and runoff events over the 85th percentile were considered large. Concentrations from collected water-quality samples were used for the analysis; estimated concentrations were excluded from the statistical evaluation. All surface runoff parameters during small runoff events, except surface runoff volume, were significantly lower in the period with cover crops and VRT implementation. Contrarily, subsurface runoff parameters during small events were not statistically different between the periods with and without cover crops and VRT implementation. Surface and subsurface parameters during large events were also not statistically different between the periods with and without cover crops and VRT implementation. These results indicate cover crops and VRT may improve water quality during small runoff events, but additional best management practices that mitigate large runoff events may lead to greater water-quality improvement given the contribution of large events to overall losses.

Ohio

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Temperate wetlands lose climate-cooling capacity under warming

Temperate inland wetlands have long been viewed as climate regulators, with sustained CO₂ sequestration offsetting continuous CH₄ emissions over centennial–millennial timescales. However, the net climatic effect of these opposing fluxes remains uncertain under anthropogenic warming as they differ in both magnitude and atmospheric lifetime. We combine 19,000 CH₄ chamber measurements from 202 temperate inland wetlands with carbon burial rates from 16 dated sediment cores in North America’s Prairie Pothole Region to estimate greenhouse gas dynamics over two centuries. Here we show that CH₄ emissions rise by ~1.39 kg CH₄ ha⁻¹ yr⁻¹ over the historical period and are projected to approach 950 kg CH₄ ha⁻¹ yr⁻¹ under high-forcing scenarios by 2100, while CO₂ sequestration is expected to decline by ~0.3 kg CO₂ ha⁻¹ yr⁻¹, driving a shift toward persistent net CO₂-equivalent source behaviour and a weakening of the long-term cooling effect that wetlands have provided under natural conditions.

Prairie Pothole Region

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Global geologic map of Europa

Discovered by Galileo Galilei more than 400 years ago and imaged in detail by the Voyager 2 Galileo spacecraft, Jupiter’s icy moon Europa has been a source of intrigue. A range of science investigations indicate that it contains the key ingredients for habitability, notably energy, chemistry, and liquid water. Europa’s surface is geologically complex and, based on the dearth of impact craters, interpreted to be as young as ~60 Ma. The array of geologic features that characterize the surface include extensive ridged plains, regions of broad disruption termed chaotic terrain, long, quasi-linear ridges that span thousands of kilometers, and bands as much as 60 kilometers wide and that extend 100s of kilometers. These features, along with other geophysical measurements, indicate the presence of a global briny liquid water ocean beneath the ice shell. It was not until the arrival of the Galileo spacecraft in 1995 that the true nature and level of complexity of the surface was revealed. Although image data returned by Galileo provided insight into the structure of a variety of regions, the entire satellite has yet to be observed at a regional scale (less than 250 meters per pixel) and the detailed geologic nature of much of its surface remains a mystery. Establishing the global context of the distribution and timing of Europan geologic units forms a basis to understand regional and local scale processes, serves as a tool for the planning of future missions, and most of all is essential to gaining insight into the potential habitability of this icy world.

Scientific Investigations Map

A methodology to estimate CO2 and energy gas storage resources in depleted conventional gas reservoirs

Depleted hydrocarbon reservoirs are subsurface geological structures capable of sequestering vast quantities of carbon dioxide (CO 2 ) as well as storing other energy gases for later usage, such as natural gas, and potentially hydrogen (H 2 ). Here we outline a methodology to quantify multi-gas storage resources in depleted conventional gas reservoirs for usage in assessments by the United States Geological Survey (USGS) at the scale of sedimentary basins. The methodology consists first of quantifying accessible pore volume in a depleted reservoir for natural gas storage using up to three equations. Input data are derived from commonly reported or estimated reservoir parameters and natural gas production volumes, and equations may be combined in linear models to improve pore volume estimates. Storage estimates from these equations are tested and validated for 31 reservoirs in the Michigan Basin Province, USA that were previously converted to underground gas storage facilities and have known (federally reported) natural gas storage capacities. Secondly, natural gas storage capacities can be transformed via fluid substitution calculations to estimate the storage resources for non-native fluids, applied here for, CO 2 , H 2 , and methane-H 2 blends, accounting for molecule-specific deviations from ideal gas behavior at reservoir pressures and temperatures as well as differing storage efficiencies. Importantly, the storage of non-native fluids may not be appropriate in all depleted gas reservoir settings due to potential risks like leakage, in particular in the case of H 2 storage, requiring additional knowledge of caprock sealing capacity. Given this caveat, we demonstrate the fluid substitution method for natural gas reservoirs of the Northern Niagaran Reef and Southern Niagaran Reef USGS plays in the Michigan Basin Province, as these trends of Silurian pinnacle reefs are capped with tight-sealing evaporite facies. The deterministic equations outlined from this methodology can be incorporated into future probabilistic USGS gas storage assessments for CO 2 , H 2 , and natural gas resources in the United States.

Michigan

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Landslide-channel feedbacks amplify channel widening during floods

Channel widening is a major hazard during floods, particularly in confined mountainous catchments. However, channel widening during floods is not well understood and not always explained by hydraulic variables alone. Floods in mountainous regions often coincide with landslides triggered by heavy rainfall, yet landslide-channel interactions during a flood event are not well known or documented. Here we demonstrate with an example from the Great Colorado Flood in 2013, a 1000 year precipitation event, how landslide-channel feedbacks can substantially amplify channel widening and flood risk. We use a combination of DEM differencing, field analysis, and multiphase flow modeling to document landslide-channel interaction during the flood event in which sediment delivered by landslides temporarily dammed the channel before failing and generating substantial channel widening. We propose that such landslide-flood interactions will become increasingly important to account for in flood hazard assessment as flooding and landsliding both increase with extreme rainfall under climate change.

Colorado

Magnitude and frequency of floods in the Suwannee River Water Management District, Florida

Flood-frequency statistics for 2-, 5-, 10-, 25-, 50-. 100-, 200-, and 500-year recurrence intervals, based on three methods of analysis, are presented for 25 continuous-record and seven peak flow partial-record gaging stations in the Suwannee River Water Management District. The first method, for gaged stations, utilizes station records; the second method, for ungaged sites, utilizes regional regression analysis; and the third method uses a weighted combination of the station and regional values. Because the weighted values utilize two more or less independent estimates of the peak flow statistic, they are considered more accurate than the station estimates or the regression estimates alone. Also, the use of another weighting scheme to improve estimates of flood frequency statistics at ungaged sites is demonstrated. The karstic nature of much of the Suwannee River Water Management District significantly attenuates flood peaks in some streams by providing substantial subsurface storage when river stages are high. At such times, springs discharging into rivers may reverse flow temporarily and become sinks.

Florida

Groundwater quality near the Placerita Oil Field, California, 2018

Groundwater-quality data and potential fluid-migration pathways near the Placerita Oil Field in Los Angeles County, California, were examined by the U.S. Geological Survey to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with groundwater resources. Six of the 13 new groundwater samples collected for this study contained petroleum hydrocarbons, thermogenic gas, inorganic chemical signatures, and (or) isotopic values consistent with potential mixing with fluids from hydrocarbon-bearing formations. For historical groundwater samples, benzene was the most detected petroleum hydrocarbon. The historical groundwater samples with a benzene concentration greater than 0.5 micrograms per liter were from environmental monitoring wells at industrial or commercial facilities unrelated to oil and gas development that, in many cases, have identified soil or groundwater contamination and were not typically analyzed for other constituents that could provide additional lines of evidence for potential mixing with oil-field fluids. Methane was not detected in any of the 12 historical samples with a reported measurement. Reviewing historical data revealed factors that could potentially adversely affect groundwater quality in the study area. These factors include modified hydraulic gradients caused by large volumes of water extracted from the main production area and reinjected downgradient into nonproducing zones, well-barrier failures in wells constructed in the northern part of the oil field before the 1970s, well-barrier failures in produced-water disposal wells downgradient from the main production area, and naturally occurring hydrocarbons at shallow intervals. The groundwater samples most geochemically similar to samples from hydrocarbon-bearing formations were in areas where hydrocarbons are naturally occurring at shallow intervals and where oil development is at shallow depths. Additional data for hydraulic heads, water quality, and formation temperatures at multiple depths in areas with large injection volumes and well-integrity issues are needed to evaluate whether those factors have contributed to mixing between fluids from oil-producing or injection formations and groundwater resources.

California

Relatively stable pressure effects and time-increasing thermal contraction control Heber geothermal field deformation

Due to geological complexities and observational gaps, it is challenging to identify the governing physical processes of geothermal field deformation including ground subsidence and earthquakes. In the west and east regions of the Heber Geothermal Field (HGF), decade-long subsidence was occurring despite injection of heat-depleted brines, along with transient reversals between uplift and subsidence. These observed phenomena contradict current knowledge that injection leads to surface uplift. Here we show that high-yield production wells at the HGF center siphon fluid from surrounding regions, which can cause subsidence at low-rate injection locations. Moreover, the thermal contraction effect by cooling increases with time and eventually overwhelms the pressure effects of pressure fluctuation and poroelastic responses, which keep relatively stable during geothermal operations. The observed subsidence anomalies result from the siphoning effect and thermal contraction. We further demonstrate that thermal contraction dominates long-term trends of surface displacement and seismicity growth, while pressure effects drive near-instantaneous changes.

California

Shoals and valley plugs in the Hatchie River watershed

Agricultural land use and gully erosion have historically contributed more sediment to the streams of the Hatchie River watershed than those streams can carry. In 1970, the main sedimentation problem in the watershed occurred in the tributary flood plains. This problem motivated channelization projects (U.S. Department of Agriculture, 1970). By the mid-1980's, concern had shifted to sedimentation in the Hatchie River itself where channelized tributaries were understood to contribute much of the sediment. The Soil Conservation Service [Natural Resources Conservation Service (NRCS) since 1996] estimated that 640,000 tons of bedload (sand) accumulates in the Hatchie River each year and identified roughly the eastern two-thirds of the watershed, where loess is thin or absent, as the main source of sand (U.S. Department of Agriculture, 1986a). The U.S. Geological Survey (USGS), in cooperation with the West Tennessee River Basin Authority (WTRBA), conducted a study of sediment accumulation in the Hatchie River and its tributaries. This report identifies the types of tributaries and evaluates sediment, shoal formation, and valley-plug problems. The results presented here may contribute to a better understanding of similar problems in West Tennessee and the rest of the southeastern coastal plain. This information also will help the WTRBA manage sedimentation and erosion problems in the Hatchie River watershed. The source of the Mississippi section of the Hatchie River is in the sand hills southwest of Corinth, Mississippi (fig. 1). This section of the Hatchie River flows northward in an artificial drainage canal, gathering water from tributary streams that also are channelized. The drainage canal ends 2 miles south of the Tennessee State line. The Tennessee section of the Hatchie River winds north and west in a meandering natural channel to the Mississippi River. Although most of the Hatchie River tributaries are also drainage canals, the river's main stem has kept most of its natural character. The Hatchie River flows through a wide valley bottom occupied mostly by riverine wetland. Historically, the valley bottom has supported hardwood forests. Since publication of the first Hatchie River report (U.S. Department of Agriculture, 1970), the channel of the river has become shallower, and flooding has increased (U.S. Department of Agriculture 1986b). These wetter conditions inhibit growth of hardwoods and lead to premature hardwood mortality. The NRCS has predicted that despite efforts to control erosion in the uplands, most of the valley-bottom forest will die. '...swamping may be so prevalent as to change most of the Hatchie River Basin flood plain into a marsh condition, with the only remnants of the present bottomland hardwood timber remaining. (U.S. Department of Agriculture, 1986b). Loss of channel depth has been concentrated in short reaches near tributary mouths. At the mouths of Richland, Porters, Clover, and Muddy Creeks, navigation has become difficult for recreational users (Johnny Carlin, West Tennessee River Basin Authority, oral commun., 1998). As the low-gradient alluvial system of the Hatchie River accumulates sediment, another common outcome has been the formation of valley plugs, areas where 'channels are filled with sediment, and all the additional bedload brought downstream is then spread out over the flood plain until a new channel has been formed' (Happ, 1975). Valley plugs typically form where the slope of a sand-laden tributary decreases downstream, or where the tributary joins its parent stream (Happ and others, 1940; Diehl, 1994, 1997; Smith and Diehl, 2000).

Mississippi, Tennessee

Rainfall intensification amplifies exposure of American Southwest to conditions that trigger postfire debris flows

Short-duration, high-intensity rainfall can initiate deadly and destructive debris flows after wildfire. Methods to estimate the conditions that can trigger debris flows exist and guidance to determine how often those thresholds will be exceeded under the present climate are available. However, the limited spatiotemporal resolution of climate models has hampered efforts to characterize how rainfall intensification driven by global warming may affect debris-flow hazards. We use novel, dynamically downscaled (3.75-km), convection-permitting simulations of short-duration (15-min) rainfall to evaluate threshold exceedance for late 21st-century climate scenarios in the American Southwest. We observe significant increases in the frequency and magnitude of exceedances for regions dominated by cool- and warm-season rainfall. We also observe an increased frequency of exceedance in regions where postfire debris flows have not been documented, and communities are unaccustomed to the hazard. Our findings can inform planning efforts to increase resiliency to debris flows under a changing climate.

Arizona, California, Nevada, New Mexico, Utah

Characterization and simulation of the quantity and quality of water in the Highland Lakes, Texas, 1983-92

The Highland Lakes, located in central Texas, are a series of seven reservoirs on the Colorado River (Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, Lake Marble Falls, Lake Travis, Lake Austin, and Town Lake). The reservoirs provide hydroelectric power for the area. In addition, Lake Austin and Town Lake also provide the public water supply for the Austin metropolitan area. Saline water released from Natural Dam Salt Lake during 1987–89 caused increased concern among water managers that high-salinity water entering the Highland Lakes could result in waterquality problems, necessitating additional treatment of the water. The maximum dissolved solids concentrations for the reservoirs after the saline inflow were about two to three times the average concentrations before the inflow. The maximum concentrations of chloride and sulfate after the inflow were about three to five times the average concentrations before the inflow. The concentrations of dissolved solids, chloride, and sulfate in Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, and Lake Marble Falls were less than the concentrations of the applicable water-quality standards by the end of 1990. Concentrations of these constituents in Lake Travis, Lake Austin, and Town Lake did not decrease to previous levels, which were less than the concentrations of the applicable waterquality standards, until the end of 1991. Constituent concentrations for Lake Buchanan and Inks Lake; for Lake Lyndon B. Johnson and Lake Marble Falls; and for Lake Travis, Lake Austin, and Town Lake were similar because of the relative storage capacities and location of tributary inflows. From the initial increase in constituent concentrations in Lake Buchanan (summer 1987) in response to the saline inflow, the high-salinity water passed through the entire Highland Lakes in about 3.5 years. A mathematical mass-balance model was used to simulate the input and movement of highsalinity water through the Highland Lakes and to estimate monthly mean concentrations of dissolved solids, chloride, and sulfate for wet, average, and dry hydrologic conditions. The simulated median monthly concentrations during the 10-year simulation period for each reservoir generally are larger for the average condition than for the wet condition and generally are larger for the dry condition than for the average condition. The simulated concentrations of dissolved solids, chloride, and sulfate decreased to levels less than the concentrations of the applicable water-quality standards in about 2 to 5 years after the saline water inflow of 1987–89 was simulated for the three hydrologic conditions. Results from the simulations indicate that saline inflows to the Highland Lakes similar to those of the releases from Natural Dam Salt Lake during 1987–89 are unlikely to cause large increases in future concentrations of dissolved solids, chloride, and sulfate in the Highland Lakes. The results also indicate that high-salinity water will continue to be diluted as it is transported downstream through the Highland Lakes, even during extended dry periods.

Texas

Arctic speleothems reveal nearly permafrost-free Northern Hemisphere in the Late Miocene

Arctic warming is happening at nearly four times the global average rate. Long-term trends of permafrost dynamics cannot be estimated directly from monitoring of present-day thaw processes, requiring paleoclimate-proxy information. Here we use cave carbonates (speleothems) from a northern Siberian cave to determine when the Northern Hemisphere was mostly permafrost-free. At present, thick continuous permafrost in this region prevents speleothem growth. In a series of partially eroded caves, speleothems grew during the late Tortonian stage (8.68 ± 0.09 Ma), a time when the geographic position of this site was already similar to today. Paleotemperatures reconstructed from speleothems show that mean annual air temperatures (MAAT) in the region were + 6.6°C to + 11.1°C, when contemporary global MAAT were ~ 4.5 °C higher than modern. Our findings provide direct evidence that warming to Tortonian-like temperatures would leave most of the Northern Hemisphere permafrost-free. This may release up to ~ 130 petagrams of carbon, enhancing further warming.

Siberia