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Sand mining impacts on long-term dune erosion in southern Monterey Bay

Southern Monterey Bay was the most intensively mined shoreline (with sand removed directly from the surf zone) in the U.S. during the period from 1906 until 1990, when the mines were closed following hypotheses that the mining caused coastal erosion. It is estimated that the yearly averaged amount of mined sand between 1940 and 1984 was 128,000 m 3 /yr, which is approximately 50% of the yearly average dune volume loss during this period. To assess the impact of sand mining, erosion rates along an 18 km range of shoreline during the times of intensive sand mining (1940–1990) are compared with the rates after sand mining ceased (1990–2004). Most of the shoreline is composed of unconsolidated sand with extensive sand dunes rising up to a height of 46 m, vulnerable to the erosive forces of storm waves. Erosion is defined here as a recession of the top edge of the dune. Recession was determined using stereo-photogrammetry, and LIDAR and GPS surveys. Long-term erosion rates vary from about 0.5 m/yr at Monterey to 1.5 m/yr in the middle of the range, and then decrease northward. Erosion events are episodic and occur when storm waves and high tides coincide, allowing swash to undercut the dune and resulting in permanent recession. Erosion appears to be correlated with the occurrence of El Niños. The calculated volume loss of the dune in southern Monterey Bay during the 1997–98 El Niño winter was 1,820,000 m 3 , which is almost seven times the historical annual mean dune erosion of 270,000 m 3 /yr. The alongshore variation in recession rates appears to be a function of the alongshore gradient in mean wave energy and depletions by sand mining. After cessation of sand mining in 1990, the erosion rates decreased at locations in the southern end of the bay but have not significantly changed at other locations.

California

Coastal-zone hazard maps and recommendations: Eastern Puerto Rico

A series of coastal zone hazard maps cover the area impacted by Hurricane Hugo (1989) in eastern Puerto Rico. The mapping strategy was to develop a tool for quick visualization of multiple hazards for use by coastal planners, managers, property owners, and potential property owners. The Puerto Rico shoreline is heavily developed in places and also highly compartmentalized in terms of shoreline types, geology, and adjacent shelf conditions. Hazards such as coastal erosion, storm surge, riverine flooding, landsliding, and seismic impact also may be compartmentalized. From a management perspective, resources therefore can be allocated on a compartment-by-compartment basis. Six types of hazards were considered in this investigation: (1) shoreline-setting hazards (long-term coastal problems), (2) marine hazards (short-term impacts of coastal storms), (3) earthquake and slope hazards (ground shaking, landslides, and liquefaction), (4) riverine hazards (historical floods), (5) development hazards (high-density development at risk or lowdensity development in extreme-hazard settings), and (6) engineering hazards (special cases in which shoreline engineering projects such as breakwaters or sand mining have significant detrimental effects on portions of the shoreline). Shoreline segments were ranked as being at extreme, high, moderate, or low risk, depending on the number of hazards present within that segment. These rankings are likely to change, gradually over decades with natural coastal evolution, more rapidly as human development infringes on the coastal zone, or in an instant during a severe storm. The hazard maps provide a basis for hazard mitigation and management recommendations.

Puerto Rico

Geologic map of the Lower Valley quadrangle, Caribou County, Idaho

The Lower Valley 7.5-minute quadrangle, located in the core of the Southeast Idaho Phosphate Resource Area, includes Mississippian to Triassic marine sedimentary rocks, Pliocene to Pleistocene basalt, and Tertiary to Holocene surficial deposits. The Mississippian to Triassic marine sedimentary sequence was deposited on a shallow shelf between an emergent craton to the east and the Antler orogenic belt to the west. The Meade Peak Phosphatic Shale Member of the Permian Phosphoria Formation hosts high-grade deposits of phosphate that were the subject of geologic studies through much of the 20th century. Open-pit mining of the phosphate has been underway within and near the Lower Valley quadrangle for several decades.

Idaho

Assessment of gray whale feeding grounds and sea floor interaction in the northeastern Bering Sea

A dense ampeliscid amphipod community in Chirikov Basin and around St. Lawrence Island in the northeastern Bering Sea has been outlined by summarizing biological studies, analyzing bioturbation in sediment samples, and examining sea floor photos and videotapes. The amphipod population is associated with a homogeneous, relict fine-grained sand body 0.10-1.5 m thick that is deposited during the marine transgression over the Bering land bridge 8,000-10,000 yr B.P. Modern current and water mass movements and perhaps whale feeding activity prevent modern deposition in this area. The distribution of the transgressive sand sheet, associated amphipod community and feeding gray whales mapped by aerial survey correlate closely with three types of sea-floor pits observed on high (500 kHz) and low (105 kHz) resolution side-scan sonar; they are attributed to gray whale feeding traces and their subsequent current scour modification. The fresh and modified feeding pits are present in 22,000 km2 of the basin and they cover a total of 2 to 18% of the sea floor in different areas of the feeding region. The smallest size class of pits approximates whale mouth gape size and is assumed to represent fresh whale feeding pits. Fresh feeding disturbance of the sea floor is estimated to average about 5.7% for a full feeding season. Combined with information that 34% of the measured benthic biomass is amphipod prey species, and calculating the number of gray whale feeding days in the Alaskan waters plus amount consumed per day, it can be estimated that Chirikov Basin, 2% of the feeding area, supplies a minimum of 5.3 to 7.1% of the gray whale's food resource in the Bering Sea and Arctic Ocean. If a maximum of 50% of the fresh feeding features are assumed to be missed because they parallel side-scan beam paths, then a maximum whale food resource of 14.2% is possible in northeastern Bering Sea. Because of side-scan techniques and possible higher amphipod biomass estimates, a reasonable minimum estimate of the total whale food resource in northeastern Bering Sea is 10%. These data show that side-scan sonar is a powerful new technique for analyzing marine mammal benthic feeding grounds. Sonographs reveal that the gray whales profoundly disturb the substrate and initiate substantial further erosion by bottom currents, all of which enhances productivity of the prey species and results in a 'farming of the sea floor'. In turn, because of the high concentration of whale prey species in a prime feeding ground that is vulnerable to the development of petroleum and mining for sand, great care is required in the exploitation of these resources in the Chirikov Basin.

Open-File Report

A 20-year record of water chemistry in an alpine setting, Mount Emmons, Colorado, USA

From 1997 to the present, the U.S. Geological Survey and other agencies have been collecting water samples for chemical analyses on Mount Emmons in central Colorado, USA. The geology of Mount Emmons is dominated by Upper Cretaceous to Paleogene sediments of marine to continental origin, with felsic intrusive rocks interrupting the sedimentary block. Extensive sulphide-rich alteration accompanied the intrusive events and forms an alteration halo in the sediments. Weathering of these sulphide minerals has led to numerous springs and seeps with a naturally low pH and high concentrations of metals, especially Fe and Zn. Superimposed on the natural geochemical signature are acid, metal-rich drainages from several mines and drill holes. Thus, streams on Mt. Emmons have a mix of natural and anthropogenic metal sources. Nearly 450 samples compose the database, with numerous sample locations replicated from the late 1990s to the present. Although there does not appear to be any temporal pattern in the data, consistent spatial variations are observed that allow us to characterize the natural and anthropogenic water sources.

Colorado

Water-quality characteristics in the Black Hills area, South Dakota

This report summarizes the water-quality characteristics of ground-water and surface-water in the Black Hills area. Differences in groundwater quality by aquifer and differences in surfacewater quality by water source are presented. Ground-water characteristics are discussed individually for each of the major aquifers in the Black Hills area, referred to herein as the Precambrian, Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Characteristics for minor aquifers also are discussed briefly. Surface-water characteristics are discussed for hydrogeologic settings including headwater springs, crystalline core sites, artesian springs, and exterior sites. To characterize the water quality of aquifers and streams in the Black Hills area, data from the U.S. Geological Survey National Water Information System water-quality database were examined. This included samples collected as part of the Black Hills Hydrology Study as well as for other studies within the time frame of October 1, 1930, to September 30, 1998. Tables of individual results are not presented in this report, only summaries. Constituents summarized and discussed include physical properties, common ions, nutrients, trace elements, and radionuclides. Comparisons of concentration levels are made to drinking-water standards as well as beneficial-use and aquatic-life criteria. Ground water within the Black Hills and surrounding area generally is fresh and hard to very hard. Concentrations exceeding various Secondary and Maximum Contaminant Levels may affect the use of the water in some areas for many aquifers within the study area. Concentrations that exceed Secondary Maximum Contaminant Levels (SMCL's) generally affect the water only aesthetically. Radionuclide concentrations may be especially high in some of the major aquifers used within the study area and preclude the use of water in some areas. The sodiumadsorption ratio and specific conductance may affect irrigation use for some wells. High concentrations of iron and manganese are the only concentrations that may hamper the use of water from Precambrian aquifers. The principal deterrents to use of water from the Deadwood aquifer are the high concentrations of radionuclides as well as iron and manganese. Iron, manganese, and hardness may deter use of water from the Madison aquifer as well as dissolved solids and sulfate in downgradient wells (generally deeper than 2,000 feet). Iron, manganese, and hardness may also deter use of the Minnelusa aquifer. Water from the Minnekahta aquifer generally is suitable for all water uses although it is hard to very hard. High concentrations of dissolved solids, iron, sulfate, and manganese may hamper the use of water from the Inyan Kara aquifer. In the southern Black Hills, radium-226 and uranium concentrations also may preclude use of water from the Inyan Kara aquifer. Suitability for irrigation may be affected by high specific conductance and sodium-adsorption ratio for the Inyan Kara. Surface-water quality within the Black Hills and surrounding area generally is very good but the water is hard to very hard. Concentrations of some constituents in the study area tend to be higher exterior to the Black Hills, primarily due to influences from the Cretaceous-age marine shales, including dissolved solids, sodium, sulfate, selenium, and uranium. Headwater springs have relatively constant discharge, specific conductance, dissolved solids, and concentrations of most other constituents. Concentrations at crystalline core sites are very similar to those found in samples from Precambrian aquifers. Some high nitrate concentrations greater than the Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) have occurred at Annie Creek near Lead, which have been attributed to mining impacts. Trace elements generally are low with the exception of arsenic, for which 60 percent of samples exceed the proposed MCL of 10 ug/L (micrograms per liter) and one sample

Water-Resources Investigations Report

Historical development of the gravity method in exploration

The gravity method was the first geophysical technique to be used in oil and gas exploration. Despite being eclipsed by seismology, it has continued to be an important and sometimes crucial constraint in a number of exploration areas. In oil exploration the gravity method is particularly applicable in salt provinces, overthrust and foothills belts, underexplored basins, and targets of interest that underlie high-velocity zones. The gravity method is used frequently in mining applications to map subsurface geology and to directly calculate ore reserves for some massive sulfide orebodies. There is also a modest increase in the use of gravity techniques in specialized investigations for shallow targets. Gravimeters have undergone continuous improvement during the past 25 years, particularly in their ability to function in a dynamic environment. This and the advent of global positioning systems (GPS) have led to a marked improvement in the quality of marine gravity and have transformed airborne gravity from a regional technique to a prospect-level exploration tool that is particularly applicable in remote areas or transition zones that are otherwise inaccessible. Recently, moving-platform gravity gradiometers have become available and promise to play an important role in future exploration. Data reduction, filtering, and visualization, together with low-cost, powerful personal computers and color graphics, have transformed the interpretation of gravity data. The state of the art is illustrated with three case histories: 3D modeling of gravity data to map aquifers in the Albuquerque Basin, the use of marine gravity gradiometry combined with 3D seismic data to map salt keels in the Gulf of Mexico, and the use of airborne gravity gradiometry in exploration for kimberlites in Canada.

Geophysics

Ore genesis constraints on the Idaho Cobalt Belt from fluid inclusion gas, noble gas isotope, and ion ratio analyses

The Idaho cobalt belt is a 60-km-long alignment of deposits composed of cobaltite, Co pyrite, chalcopyrite, and gold with anomalous Nb, Y, Be, and rare-earth elements (REEs) in a quartz-biotite-tourmaline gangue hosted in Mesoproterozoic metasedimentary rocks of the Lemhi Group. It is the largest cobalt resource in the United States with historic production from the Blackbird Mine. All of the deposits were deformed and metamorphosed to upper greenschist-lower amphibolite grade in the Cretaceous. They occur near a 1377 Ma anorogenic bimodal plutonic complex. The enhanced solubility of Fe, Co, Cu, and Au as chloride complexes together with gangue biotite rich in Fe and Cl and gangue quartz containing hypersaline inclusions allows that hot saline fluids were involved. The isotopes of B in gangue tourmaline are suggestive of a marine source, whereas those of Pb in ore suggest a U ± Th-enriched source. The ore and gangue minerals in this belt may have trapped components in fluid inclusions that are distinct from those in post-ore minerals and metamorphic minerals. Such components can potentially be identified and distinguished by their relative abundances in contrasting samples. Therefore, we obtained samples of Co and Cu sulfides, gangue quartz, biotite, and tourmaline and post-ore quartz veins as well as Cretaceous metamorphic garnet and determined the gas, noble gas isotope, and ion ratios of fluid inclusion extracts by mass spectrometry and ion chromatography. The most abundant gases present in extracts from each sample type are biased toward the gas-rich population of inclusions trapped during maximum burial and metamorphism. All have CO 2 /CH 4 and N 2 /Ar ratios of evolved crustal fluids, and many yield a range of H 2 -CH 4 -CO 2 -H 2 S equilibration temperatures consistent with the metamorphic grade. Cretaceous garnet and post-ore minerals have high R H and R S values suggestive of reduced sulfidic conditions. Most extracts have anomalous 4 He produced by decay of U and Th and 38 Ar produced by nucleogenic production from 41 K. In contrast, some ore and gangue minerals yield significant SO 2 and have low R H and R S values of a more oxidized fluid. Three extracts from gangue quartz have high helium R/R A values indicative of a mantle source and neon isotope compositions that require nucleogenic production of 22 Ne in fluorite from U ± Th decay. Two extracts from gangue quartz have estimated 40 K/ 40 Ar that permit a Precambrian age. Extracts from gangue quartz in three different ore zones are biased toward the hypersaline population of inclusions and have a tight range of ion ratios (Na, K, NH 4 , Cl, Br, F) suggestive of a single fluid. Their Na, Cl, Br ratios suggest this fluid was a mixture of magmatic and basinal brine. Na-K-Ca temperatures (279°–347°C) are similar to homogenization temperatures of hypersaline inclusions. The high K/Na of the brine may be due to albitization of K silicate minerals in country rocks. Influx of K-rich brines is consistent with the K metasomatism necessary to form gangue biotite with high Cl. An extract from a post-ore quartz vein is distinct and has Na, Cl, Br ratios that resemble metamorphic fluids in Cretaceous silver veins of the Coeur d’Alene district in the Belt Basin. The results show that in some samples, for certain components, it is possible to “see through” the Cretaceous metamorphic overprint. Of great import for genetic models, the volatiles trapped in gangue quartz have 3 He derived from a mantle source and 22 Ne derived from fluorite, both of which may be attributed to nearby ~1377 Ma basalt-rhyolite magmatism. The brine trapped in gangue quartz is a mixture of magmatic fluid and evaporated seawater. The former requires a granitic intrusion that is present in the bimodal intrusive complex, and the latter equatorial paleolatitudes that existed in the Mesoproterozoic. The results permit genetic models involving heat and fluids from the neighboring bimodal plutonic complex and convection of basinal brine in the Lemhi Group. While the inferred fluid sources in the Idaho cobalt belt are similar in many respects to those in iron oxide copper-gold deposits, the fluids were more reduced such that iron was fixed in biotite and tourmaline instead of iron oxides.

Idaho

Drilling results at the Farah Garan ancient mine, southwestern Saudi Arabia

The Farah Garan ancient mine is located at fat 17?41'00'' N., long 43?38'15'' E. in the southwestern part of the Kingdom of Saudi Arabia. Three diamond drill holes intersected base-metal sulfides, which are present both as conformable layers in Precambrian tuffaceous volcanic rocks and as fracture fillings, irregularly shaped masses, disseminations, and clots in intensely hydrothermally altered and brecciated fault zones. The sulfides probably formed through volcanic processes in a shallow-marine environment and subsequently were greatly modified by tectonism and hydrothermal activity. Drill hole F.G.-1 intersected sparse base and precious metal minerals along a length of 30 m; several narrow, isolated zones contain as much as 22 grams per metric ton (g/t) silver, 1.25 percent copper, and 3.10 percent zinc. Drill hole F.G.-2 intersected low-grade base and precious metal minerals along a length of 50 m. Within this zone, a 10-m interval contains an average of 0.15 g/t gold, 10.7 g/t silver, and 0.86 percent zinc. Drill hole F.G.-3 cut commercial-grade base and precious metal minerals in a 3.55-m interval that contains an average of 20.06 g/t gold, 32.75 g/t silver, and 6.28 percent zinc. Additional exploration, including drilling and laboratory studies, is recommended to further define potential tonnages of base and precious metals intersected in drill hole F.G.-3 and to learn more about their genesis and mineral form. Arsenic and antimony are locally abundant in both drillcore and surface samples. Because of its weathering characteristics, mobility, and association with precious metals, arsenic commonly is a pathfinder for gold. Approximately 1,100 splits of surface samples collected in the Farah Garan area are stored at the Directorate General of Mineral Resources-U. S. Geological Survey chemical laboratory in Jiddah, and any further exploration should include assaying these samples for arsenic and antimony by wet-chemical analysis ?

Open-File Report

Preliminary geologic map of the Cherry Hill quadrangle, Dinwiddie, Sussex, and Greensville Counties, Virginia

The Cherry Hill 7.5-minute quadrangle straddles the Coastal Plain and Piedmont Provinces along the Tidewater Fall Line. Rocks of the eastern Piedmont Roanoke Rapids terrane crop out in the western part of the quadrangle and consist of greenschist- to amphibolite-facies Neoproterozoic felsic to intermediate metavolcanic rocks, some of which contain flattened quartz phenocrysts and are locally isoclinally folded; greenstone that locally preserves primary layering; and intrusive metadiorite and metagabbro, much of which has been altered to amphibolite. Most of these rocks are strongly foliated and jointed. Greenschist-facies metasiltstone that preserves primary bedding also occurs locally in the Roanoke Rapids terrane. Neoproterozoic mica schist, middle Paleozoic foliated metagranite, and late Paleozoic massive and porphyritic granite crop out in the eastern part of the quadrangle and are part of the Dinwiddie terrane and the late Paleozoic De Witt pluton. Upper greenschist- to lower amphibolite-facies mica schist consists of stringers and boudins of vein quartz and contains porphyroclasts of staurolite that preserve an earlier foliation as inclusion trails. Porphyroblasts of garnet, staurolite, and kyanite also occur locally. Foliation in granites of the De Witt pluton may be magmatic. Separating the Dinwiddie terrane from the Roanoke Rapids terrane are greenschist-facies, highly strained granitic mylonite and bodies of less deformed granite within the Nottoway River fault zone, which is a strand of the eastern Piedmont fault system. Paleozoic pegmatite dikes and quartz veins cross-cut rocks of the Dinwiddie terrane, and quartz veins and Jurassic diabase dikes cross-cut rocks of the Roanoke Rapids terrane. Sand and gravel deposits of the Atlantic Coastal Plain overlie Piedmont rocks. Two units assigned to the upper part of the Neogene Chesapeake Group occur at elevations up to 295 feet (90 meters) above sea level atop the Richmond plain in the central part of the quadrangle. Two units of the Quaternary Bacons Castle Formation occupy the Essex plain and Norge uplands at elevations up to 180 feet (55 meters) above sea level in the eastern part of the quadrangle. In the western part of the quadrangle, multiple levels of terrace deposits are the fluvial equivalent of estuarine to marine units of the Atlantic Coastal Plain to the east. Holocene alluvium occurs along creeks and the Nottoway River. Quaternary colluvial deposits occur locally. Numerous Carolina bays pock the landscape of the Richmond and Essex plains, and three abandoned channelways represent former locations of Sappony Creek, one of the major drainages of the quadrangle. Brittle faults juxtapose Piedmont basement rocks against Neogene sediments of the upper part of the Chesapeake Group. These Cenozoic faults were first uncovered in mine excavations in the late 1990s; new mapping indicates that many of these faults are reactivated silicified cataclasite zones that occur throughout the Piedmont basement rocks. Silicified cataclasites and associated quartz veins are typically mineralized with iron and iron sulfide minerals. The quadrangle was the focus of extensive mining for heavy minerals, including ilmenite and zircon, in upland Atlantic Coastal Plain deposits beginning in the mid-1990s. Other mineral resources, including precious metals, clay for structural brick, crushed stone, and building stone for millstones, have also been prospected or quarried in the quadrangle.

Virginia

A Servicewide Benthic Mapping Program for National Parks

In 2007, the National Park Service (NPS) Inventory and Monitoring Program directed the initiation of a benthic habitat mapping program in ocean and coastal parks in alignment with the NPS Ocean Park Stewardship 2007-2008 Action Plan. With 74 ocean and Great Lakes parks stretching over more than 5,000 miles of coastline across 26 States and territories, this Servicewide Benthic Mapping Program (SBMP) is essential. This program will deliver benthic habitat maps and their associated inventory reports to NPS managers in a consistent, servicewide format to support informed management and protection of 3 million acres of submerged National Park System natural and cultural resources. The NPS and the U.S. Geological Survey (USGS) convened a workshop June 3-5, 2008, in Lakewood, Colo., to discuss the goals and develop the design of the NPS SBMP with an assembly of experts (Moses and others, 2010) who identified park needs and suggested best practices for inventory and mapping of bathymetry, benthic cover, geology, geomorphology, and some water-column properties. The recommended SBMP protocols include servicewide standards (such as gap analysis, minimum accuracy, final products) as well as standards that can be adapted to fit network and park unit needs (for example, minimum mapping unit, mapping priorities). SBMP Mapping Process. The SBMP calls for a multi-step mapping process for each park, beginning with a gap assessment and data mining to determine data resources and needs. An interagency announcement of intent to acquire new data will provide opportunities to leverage partnerships. Prior to new data acquisition, all involved parties should be included in a scoping meeting held at network scale. Data collection will be followed by processing and interpretation, and finally expert review and publication. After publication, all digital materials will be archived in a common format. SBMP Classification Scheme. The SBMP will map using the Coastal and Marine Ecological Classification Standard (CMECS) that is being modified to include all NPS needs, such as lacustrine ecosystems and submerged cultural resources. CMECS Version III (Madden and others, 2010) includes components for water column, biotic cover, surface geology, sub-benthic, and geoform. SBMP Data Archiving. The SBMP calls for the storage of all raw data and final products in common-use data formats. The concept of 'collect once, use often' is essential to efficient use of mapping resources. Data should also be shared with other agencies and the public through various digital clearing houses, such as Geospatial One-Stop (http://gos2.geodata.gov/wps/portal/gos). To be most useful for managing submerged resources, the SBMP advocates the inventory and mapping of the five components of marine ecosystems: surface geology, biotic cover, geoform, sub-benthic, and water column. A complete benthic inventory of a park would include maps of bathymetry and the five components of CMECS. The completion of mapping for any set of components, such as bathymetry and surface geology, or a particular theme (for example, submerged aquatic vegetation) should also include a printed report.

Open-File Report

The application of induced polarization techniques to detect metal-bearing offshore anthropogenic waste and unexploded ordnance

Raw sewage and industrial waste have been dumped into sensitive estuaries, bays, and sounds for centuries. The full extents of the resulting sludge deposits are largely unknown, because they move in response to tidal and long‐shore currents, and because they are often buried by younger inert sediments. USGS field and laboratory measurements of toxic mine waste and organic effluent samples suggest that anthropogenic wastes typically contain finely‐divided metal and metal‐sulfide particles. The anoxic environment provided by anthropogenic wastes promotes the growth of anaerobic bacteria, creating a self‐reducing environment. We suggest that the finely‐divided metal and metal‐sulfide particles are the products of bacterial reduction and precipitation. The fine‐grained metallic precipitates are ideal targets for a surface‐effect electrochemical detection methodology called Induced Polarization (IP). A USGS‐patented (1998/2001) marine IP streamer technology has recently been commercialized and used to map “black smoker” sulfide deposits and their disseminated halos in the Bismarck Sea (2005), and titanium‐sand deposits offshore of South Africa (2007). The marine induced polarization system can do this mapping in three dimensions, more rapidly (it is towed at 3 knots), and with far higher resolution that land‐based measurements or vibracoring. Laboratory‐scale studies at the USGS suggest that anthropogenic wastes may display a specific multi‐frequency IP spectral signature that may be applicable to waste‐deposit mapping.

Conference Paper

A geologic framework for mineralization in the western Brooks Range

The Brooks Range is a 950-km-long north-vergent fold and thrust belt, which was formed during Mesozoic convergence of the continental Arctic Alaska terrane and the oceanic Angayucham terrane and was further shortened and uplifted in Tertiary time. The Arctic Alaska terrane consists of parautochthonous rocks and the Endicott Mountains and De Long Mountains subterranes. The Endicott Mountains allochthon of the western Brooks Range is the setting for many sulfide and barite occurrences, such as the supergiant Red Dog zinc-lead mine. Mineralization is sediment hosted and most commonly is present in black shale and carbonate turbidites of the Mississippian Kuna Formation. The reconstructed Kuna basin is a 200 by +600 km feature that represents the culmination of a remarkable chain of events that includes three fluvial-deltaic and two or more orogenic cycles, Middle Devonian to Mississippian episodes of extension and igneous activity, and the emergence of a seaward Lower Proterozoic landmass that may have constituted a barrier to marine circulation. Mississippian extension and related horst-and-graben architecture in the western Brooks Range is manifested in part by strong facies variability between coeval units of allochthons and structural plates. Shallow marine to possibly nonmarine arkose, platform to shelf carbonate, slope-to-basin shale, chert and carbonate turbidites, and submarine volcanic rocks are all represented in Mississippian time. The structural setting of Mississippian sedimentation, volcanism, and mineralization in the Kuna basin may be comparable to documented Devono-Mississippian extensional sags or half-grabens in the subsurface north of the Brooks Range. Climate, terrestrial ecosystems, multiple fluvial-deltaic aquifers, and structural architecture affected the liberation, movement, and redeposition of metals in ways that are incompletely understood.

Alaska

U. S. PHOSPHATE INDUSTRY: REVISED PROSPECTS AND POTENTIAL.

Although the United States is the world's largest producer and exporter of phosphates, serious doubts have arisen in recent years that U. S. deposits could sustain this important role. The development of borehole mining; i. e. , extracting the phosphate matrix as a slurry through a drill hole, however, is cause for optimism. Commercial borehole mining is still years away, but the potential advantages are numerous and important. Recent surveys also suggest that offshore deposits and deeply buried onshore deposits much exceed previous estimates. On the basis of the new technology and revised resource estimates, one can easily see the potential for increased production from U. S. deposits.

Marine Technology Society Journal

Characterizing sedimentary organic carbon in a hydrothermal spreading center, the Escanaba Trough

Sediments in critical marine mineral environments are of wide importance due to their preservation of both marine minerals and organic carbon (OC) stocks. However, OC storage and cycling is often overlooked in mineral system studies. This work characterizes sedimentary OC within the Escanaba Trough, a hydrothermal sulfide system off the coast of northern California. By utilizing ROV-based push coring, we collected sediments near and far from high temperature, low temperature, and inactive vents. We applied a multipronged organic geochemical approach, measuring bulk sediment, OC fractions of varying labilities, and biomarkers to tease apart the storage, source, and cycling of OC within this complex system. In contrast to past work indicating a primarily terrestrial source to deeper, Pleistocene sediments, our results suggest a primarily marine source in surface sediments at least 50 m away from active venting. Near active venting, we see evidence of locally produced chemosynthetic OC in addition to the background marine source. This chemosynthetic OC appears to be rapidly remineralized and supports more complex deep-sea food webs compared to hemipelagic sites. Still, the greatest contribution of labile OC was observed at inactive vent sites, which we suggest is due to hydrothermal fluid alteration of more labile OC at actively venting sites. Depending on fluid temperature, hydrothermally altered OC is either preserved in the sediments as petroleum or migrated with fluid flow. Considering inactive sites are those most likely to be targeted by potential mining, we suggest additional studies could verify if these results apply at other sedimented seafloor massive sulfide systems.

California

Mineral resources of Du Noir Addition, Washakie Wilderness area, Fremont County, Wyoming

The Du Noir Addition to the Washakie Wilderness area consists of 34,200 acres (13,840 hectares) of scenic mountainous terrain that adjoins the Teton Wilderness and Washakie Wilderness areas. The area was studied in 1973 by the U.S. Geological Survey and U.S. Bureau of Mines to evaluate its mineral, fuel, and geothermal energy potential. This evaluation is based on a search of the geologic literature, claim and production records, and fieldwork including mapping, inspection of claims and prospects, interpretation of aeromagnetic maps, and analyses of bedrock and stream-sediment samples. Flat-lying Eocene volcaniclastic rocks of the Absaroka volcanic field are exposed in about two-thirds of the Du Noir Addition. These volcanics unconformably overlie the deeply eroded, northwest-trending Du Noir anticline in which Paleozoic marine strata of Devonian through Permian age are exposed. Of lesser importance are small deposits of Eocene non-volcanic conglomerate, and basaltic intrusive and extrusive rocks of late Pliocene and possibly younger age. The results of this study indicate that the mineral, fuel, and geothermal potential of the Du Noir Addition are minimal. Low-grade copper-molybdenum mineralization occurs outside the addition, associated with intrusive rocks, but no indications of alteration or mineralization were found within the study area. Anomalous, but not economically important, concentrations of molybdenum and uranium were found in Permian and Eocene carbonaceous shales. Phosphate rock in the Phosphoria Formation occurs in beds too thin to constitute a resource. Large amounts of very pure limestone are present in the Madison Limestone, but equally pure limestone, much closer to transportation facilities, is found throughout this part of Wyoming. That part of the Du Noir anticline in the addition is too deeply eroded to be a likely reservoir of oil and gas. Present data indicates a low potential for geothermal energy in or near the addition.

Wyoming

Metal release from manganese nodules in anoxic seawater and implications for deep-sea mining dewatering operations

The potential mining of deep-sea polymetallic nodules has been gaining increasing attention due to their enrichment in metals essential for a low-carbon future. To date, there have been few scientific studies concerning the geochemical consequences of dewatered mining waste discharge into the pelagic water column, which can inform best practices in future mining operations. Here, we report the results of laboratory incubation experiments that simulate mining discharge into anoxic waters such as those that overlie potential mining sites in the North Pacific Ocean. We find that manganese nodules are reductively dissolved, with an apparent activation energy of 42.8 kJ mol –1 , leading to the release of associated metals in the order manganese > nickel > copper > cobalt > cadmium > lead. The composition of trace metals released during the incubation allows us to estimate a likely trace metal budget from the simulated dewatering waste plume. These estimates suggest that released cobalt and copper are the most enriched trace metals within the plume, up to ∼15 times more elevated than the background seawater. High copper concentrations can be toxic to marine organisms. Future work on metal toxicity to mesopelagic communities could help us better understand the ecological effects of these fluxes of trace metals.

ACS ES&T Water

Documenting the multiple facets of a subsiding landscape from coastal cities and wetlands to the continental shelf

Land subsidence is a settling, sinking, or collapse of the land surface. In the southeastern United States, subsidence is frequently observed as sinkhole collapse in karst environments, wetland degradation and loss in coastal and other low-lying areas, and inundation of coastal urban communities. Human activities such as fluid extraction, mining, and overburden alteration can cause or exacerbate subsidence, which can result in damage to infrastructure and resources. Subsidence is a hazard that takes place throughout the United States; however, a systematic approach to recognize and develop informed responses to the drivers of subsidence has not yet been fully established. To address this problem, the U.S. Geological Survey (USGS) Southeast Region (SER) funded the gathering of a team of interdisciplinary USGS scientists to promote scientific collaboration. Southeast Region scientists welcomed scientists from other regions (see table 1.1 in Appendix 1) in September 2018 at the St. Petersburg Coastal and Marine Science Center (SPCMSC) in Florida for the first workshop of the Subsidence Flex Team (SFT) (see Appendix 2 for agenda). The SFT set out to review subsidence-related research and technology and develop a unifying framework for describing the processes and hazards associated with land subsidence. A more comprehensive understanding of subsidence hazards could help to inform regional vulnerability assessments that would prove invaluable to the public, community developers, policy makers, and resource managers in both inland and coastal states. The SFT analyzed USGS strengths and weaknesses to identify existing infrastructure and capabilities that could be leveraged to create a comprehensive and far-reaching subsidence-monitoring and mitigation program. Over the course of the 2-day workshop, interdisciplinary understandings of the processes and hazards related to subsidence were explored through individual presentations and group discussion. With all perspectives considered, the SFT recommended that subsidence-related research develop scientific approaches and metrics by which the subsidence component can be isolated and quantified in order to protect both the environment and human infrastructure from harm.

Alabama, Florida, Louisiana, Mississippi