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Carbon dioxide mineralization feasibility in the United States

Geologic carbon dioxide (CO 2 ) storage is one of many methods for stabilizing the increasing concentration of CO 2 in the Earth’s atmosphere. The injection of CO 2 in deep subsurface sedimentary reservoirs is the most commonly discussed method; however, the potential for CO 2 leakage can create long-term stability concerns. This report discusses the feasibility of an alternative form of geologic CO 2 storage: CO 2 mineralization. In this method, CO 2 reacts with rocks and minerals to form solid and stable carbonate rocks. New pilot projects and laboratory-based kinetics experiments have revealed that this method, both in situ and ex situ, may be a viable option for storage. In situ storage targets in-place rocks at the surface or subsurface. Ex situ storage targets industrial byproducts at the surface like mine tailings. Environmental risks include induced seismicity for in situ methods if pressure is not managed properly, as well as potential water and land use effects. However, there are fewer long-term CO 2 -leakage concerns for mineralization methods compared to saline storage methods and therefore potentially lower long-term monitoring costs. The costs and benefits of CO 2 mineralization are compared to those of CO 2 storage in saline reservoirs using estimates of pressure-limited dynamic storage capacity. This report highlights the regional potential of areas in the United States for in situ and ex situ storage, as well as their proximity to potential sources of CO 2 . Especially suitable targets include asbestos or other ultramafic mine tailings, in situ ultramafic rocks on the East and West Coasts, the Columbia River basalts in the Pacific Northwest, the Midcontinent Rift basalts in the midcontinent, and the basaltic Hawaiian Islands.

Scientific Investigations Report↗

Bathymetry and capacity of Blackfoot Reservoir, Caribou County, Idaho, 2011

The U.S. Geological Survey (USGS), in cooperation with the Shoshone-Bannock Tribes, surveyed the bathymetry and selected above-water sections of Blackfoot Reservoir, Caribou County, Idaho, in 2011. Reservoir operators manage releases from Government Dam on Blackfoot Reservoir based on a stage-capacity relation developed about the time of dam construction in the early 1900s. Reservoir operation directly affects the amount of water that is available for irrigation of agricultural land on the Fort Hall Indian Reservation and surrounding areas. The USGS surveyed the below-water sections of the reservoir using a multibeam echosounder and real-time kinematic global positioning system (RTK-GPS) equipment at full reservoir pool in June 2011, covering elevations from 6,090 to 6,119 feet (ft) above the North American Vertical Datum of 1988 (NAVD 88). The USGS used data from a light detection and ranging (LiDAR) survey performed in 2000 to map reservoir bathymetry from 6,116 to 6,124 ft NAVD 88, which were mostly in depths too shallow to measure with the multibeam echosounder, and most of the above-water section of the reservoir (above 6,124 ft NAVD 88). Selected points and bank erosional features were surveyed by the USGS using RTK-GPS and a total station at low reservoir pool in September 2011 to supplement and verify the LiDAR data. The stage-capacity relation was revised and presented in a tabular format. The datasets show a 2.0-percent decrease in capacity from the original survey, due to sedimentation or differences in accuracy between surveys. A 1.3-percent error also was detected in the previously used capacity table and measured water-level elevation because of questionable reference elevation at monitoring stations near Government Dam. Reservoir capacity in 2011 at design maximum pool of 6,124 ft above NAVD 88 was 333,500 acre-ft.

Idaho↗

Land-Cover Trends of the Sierra Nevada Ecoregion, 1973-2000

The U.S. Geological Survey has developed and is implementing the Land Cover Trends project to estimate and describe the temporal and spatial distribution and variability of contemporary land-use and land-cover change in the United States. As part of the Land Cover Trends project, the purpose of this study was to assess land-use/land-cover change in the Sierra Nevada ecoregion for the period 1973 to 2000 using a probability sampling technique and satellite imagery. We randomly selected 36 100-km2 sample blocks to derive thematic images of land-use/land-cover for five dates of Landsat imagery (1973, 1980, 1986, 1992, 2000). We visually interpreted as many as 11 land-use/land-cover classes using a 60-meter minimum mapping unit from the five dates of imagery yielding four periods for analysis. Change-detection results from post-classification comparison of our mapped data showed that landscape disturbance from fire was the dominant change from 1973-2000. The second most-common change was forest disturbance resulting from harvest of timber resources by way of clear-cutting. The rates of forest regeneration from temporary fire and harvest disturbances coincided with the rates of disturbance from the previous period. Relatively minor landscape changes were caused by new development and reservoir drawdown. Multiple linear regression analysis suggests that land ownership and the proportion of forest and developed cover types were significant determinants of the likelihood of direct human-induced change occurring in sampling units. Driving forces of change include land ownership, land management such as fire suppression policy, and demand for natural resources.

Scientific Investigations Report↗

Are we running out of water?

Water supplies are not running out, but time is getting short to stem waste of water and destructive exploitation of the environment before harm is done that may be irreparable. Most of the world's water is oceanic brine. Of the waters on the land, most is frozen in Antarctica and Greenland. Only a small part of continental water is available for use and management. The discharge of rivers to the sea is a close measure of the availability of liquid water, but ground-water reservoirs have important functions as inexpensive equalizers of water supply. Soil moisture is a major factor in the water economy, and its function usually is overlooked in assessments of water use and future water demand. Despite outcries of water shortage, the principal use of water in advanced countries is as a medium for waste disposal. In reality, despite regional maldistribution of water, United States supplies are adequate, given rational management. Also, contrary to common belief, water pollution is primarily a problem of economics, not of health. A paramount problem in most parts of the world is the shortage of water development and management facilities, not a shortage of water. The International Hydrological Decade is a program to awaken people everywhere to the crucial importance of water in man's future and to promote rational approach to water problems.

Circular↗

Summary appraisals of the nation's ground-water resources – California region

Most people in the California Region live in a semiarid or arid climate, with precipitation less than the potential evapotranspiration- environments of perennial water deficiency. The deficiency becomes most onerous during the characteristically rainless summers and during recurrent droughts that may continue for 10--20 years. However, water from winter rain and snow can be stored for use during the dry summer months, and water stored during a wet climatic period can be used in a succeeding dry period; moreover, perennial deficiency can be overcome by bringing water from areas of perennial surplus. Ground-water reservoirs have especial significance in arid and semiarid regions as repositories where water is stored or can be stored with minimum loss by evaporation. Nearly all the ground-water reservoirs of the California Region are in alluvial sediments of valleys and plains that flank the mountain ranges. The largest, underlying the vast Central Valley, occupies 10 percent of the area of the region, has an estimated usable capacity exceeding 100 million acre-feet (125 cubic kilometres), and has an annual pumpage from wells of about 13 million acre-feet (16 cubic kilometres). Another 10 percent of the region is occupied by 55 developed ground-water reservoirs that are widely distributed; aggregate annual pumpage from them is about 3 1/2 million acre-feet (4 cubic kilometres). In the southeastern desert about 60 ground-water reservoirs occupy still another 10 percent of the region; these have been explored only enough to show that most have some usable water, but current use is negligible. In northeastern California and adjacent Oregon and Nevada, ground-water reservoirs are identified only in valleys and lowlands where wells are feasible, but basaltic rocks of the Cascade Range and Modoc Plateau are excellent aquifers distributed over an area constituting about 15 percent of the region. In sum, slightly less than half the California Region is underlain by ground-water reservoirs, either in valley fill or in volcanic rocks, which can yield significant quantities of water to wells. The rest of the California Region includes the mountains, canyons, slopes, and foothills of the Sierra Nevada, Coast Ranges, and Basin Ranges, whose consolidated rocks and products of their weathering may be permeable locally but are not generally so. Here, the prevailing method of ground-water development is still mostly trial and error, and while in many places a well can yield enough water for a family, some families might have to do without amenities such as flush toilets and automatic washers. For more than half a century the California Region has led all others in North America in pumping of ground water as well as in the area, variety, yield, and export of crops irrigated by water from wells. It has led in the development and use of deep-well turbine pumps for large yield and in the drilling of water wells to great depths. At the same time, such developments have resulted in the elimination of artesian pressures that produced thousands of flowing wells in the 19th century and led to the wide distribution of "falling water tables." Also, California was first to induce encroachment of seawater into wells (in 1906); first to recognize subsidence of land caused by pumping from wells (in 1933), generating news about land sinking in San Jose, Long Beach, and along the Delta-Mendota and Friant-Kern Canals; and first to experience pollution of ground-water reservoirs by brines, chemicals, industrial wastes, and petroleum byproducts including gasoline. The region has led in research in several fields leading to solution of many of these problems. Ground-water problems developed rapidly after World War II with booming population, agriculture, industry, and water demand during several years of regionwide drought. Water levels in wells trended downward almost everywhere as a natural effect of the drought and at accelerated rates in areas of pumping for new enterprises or to supplement subnormal surface-water supplies. The declines in many pumping areas exceeded 100 feet (30 metres), and in some confined aquifers the potentiometric surface was drawn down more than 330 feet (100 metres). The depletion of ground-water storage has had "permanent" side effects, including subsidence of the land exceeding 10 feet (3 metres) in extensive areas, and seawater intrusion that ended the useful lives of many wells along the coast and as much as 6 miles (10 kilometres) inland. Some problems have been solved, but these solutions have at times created other problems. Many ground-water reservoirs have gone through one or more stages - exploration for productive aquifers, exploitation and development for use of the water, restriction to the perennial supply or "safe" yield, importation of surface water, artificial recharge of ground water, conjunctive use of surface and ground water, protection of water quality, and integrated management of use and disposal of water. This evolutionary sequence is unique for each reservoir, and so generalizations become difficult in a regional appraisal; also, the changes with time are significant and varied, and knowledge of prior events is a prerequisite in an appraisal of the resource in a specific year. As of 1970, water levels in many wells had risen significantly from the minimum levels of record reached during the 1960's or earlier; only in areas of new development and in desert areas of long-continued "mining" of nonreplenished water was ground-water storage still being depleted. Land subsidence has continued at diminishing rates and practically has come to a halt in some areas; invading seawater has been stopped or nudged back in most places where problems were significant. The current, favorable situation has been helped by climatic variations, from drought in 1945-52 and exceedingly dry years in 1959 and 1961 to above-normal precipitation in 1969 and 1970; but most of the serious problems have been solved by human efforts, including especially the implementation of the California Water Plan, transporting water from areas of perennial surplus to areas where it is used in lieu of ground water or for ground-water replenishment. All major urban areas now import water to supplement or replace the water pumped from wells. Extensive agricultural areas that formerly were irrigated solely by ground water now obtain some of their water from surface reservoirs and canals, especially in the Central Valley. With surface water available as an alternative supply, well owners can view their ground water with complacency. But complacency can lead to neglect and carelessness and consequent deterioration of the ground-water resource by pollution. Claiming heritage from the English Common Law, the existing California law grants to the landowner (riparian) and private enterprise (appropriator) rights to the water stored in ground-water reservoirs or discharged from them, including the base flow of streams. Ground-water development has been by private and local enterprise, and the California legislature has protected and encouraged local responsibility, control, and management of ground water. As to surface water, a constitutional amendment in 1928 limited riparian rights to the quantities of water that were "reasonably required for the beneficial use to be served." The surpluses have become public waters which are collected, stored, transported, and delivered under various contracts by Federal, State, and other agencies. The agencies have not stored water underground because of uncertainty as to their rights, but some local agencies have been encouraged with favorable pricing schedules to undertake the artificial recharge and management of ground-water reservoirs. Thus, conjunctive use of surface and ground water has become a matter of interagency negotiation. Of all the constraints on effective use of ground-water reservoirs, the most formidable may be the attitudes of people. Assurance of water supply is vital in areas of water deficiency, and Government has assumed increasing responsibility for the welfare of people in these areas. Unfortunately, when Government provides this assurance, most beneficiaries demand continued subsidy to the exclusion of perhaps cheaper private development. Indeed, as the water resources are presently segregated-with private rights predominant in ground water and public interest dominant in surface water-ground-water development has suffered for lack of public concern. The region has the scientific and technologic capability for effective use of groundwater reservoirs, as shown by the achievements and programs of several districts, but many districts are not organized or staffed for such comprehensive management and will need assistance and scientific expertise available from State and Federal agencies. Those agencies, in turn, may not have the scientific data that are essential to prevent haphazard activities and to enable programs to be organized for the most effective and attractive utilization of the water resources. In these days of increasing concern over pollution, existing data are generally inadequate to assess the natural deterioration of ground waters as a basis for defining pollution.

California↗

Drilling and testing the DOI-04-1A coalbed methane well, Fort Yukon, Alaska

The need for affordable energy sources is acute in rural communities of Alaska where costly diesel fuel must be delivered by barge or plane for power generation. Additionally, the transport, transfer, and storage of fuel pose great difficulty in these regions. Although small-scale energy development in remote Arctic locations presents unique challenges, identifying and developing economic, local sources of energy remains a high priority for state and local government. Many areas in rural Alaska contain widespread coal resources that may contain significant amounts of coalbed methane (CBM) that, when extracted, could be used for power generation. However, in many of these areas, little is known concerning the properties that control CBM occurrence and production, including coal bed geometry, coalbed gas content and saturation, reservoir permeability and pressure, and water chemistry. Therefore, drilling and testing to collect these data are required to accurately assess the viability of CBM as a potential energy source in most locations. In 2004, the U.S. Geological Survey (USGS) and Bureau of Land Management (BLM), in cooperation with the U.S. Department of Energy (DOE), the Alaska Department of Geological and Geophysical Surveys (DGGS), the University of Alaska Fairbanks (UAF), the Doyon Native Corporation, and the village of Fort Yukon, organized and funded the drilling of a well at Fort Yukon, Alaska to test coal beds for CBM developmental potential. Fort Yukon is a town of about 600 people and is composed mostly of Gwich'in Athabascan Native Americans. It is located near the center of the Yukon Flats Basin, approximately 145 mi northeast of Fairbanks.

Alaska↗

Hydrologic effects of reducing irrigation to maintain a permanent pool in John Martin Reservoir, Arkansas River Valley, Colorado

The U.S. Geological Survey has evaluated a plan by the Colorado Division of Wildlife to maintain a permanent pool of 10,000 acre-feet (1.2x10 7 cubic metres) in John Martin Reservoir on the Arkansas River. The proposed pool would be maintained through the use of water formerly diverted by the Catlin Canal Company to irrigate land in the Arkansas River valley. This plan was evaluated using a mathematical simulation model developed to test management alternatives in a stream-aquifer system. A 25-year period from 1949 through 1973 was simulated using monthly time intervals. Based on this simulation, it is concluded that (1) the proposed change in water use would be adequate to maintain a permanent pool of the proposed size, (2) surface-water diversions by most other canals in the study area would increase slightly under the proposed plan, (3) the flow of the Arkansas River at the Colorado-Kansas State line would increase slightly under the proposed plan, and (4) the ground-water system would not be significantly affected by the proposed change in water-use plan.

Colorado↗

Hydrologic and ecological investigations in the School Branch watershed, Hendricks County, Indiana—Water years 2016–2018

School Branch in Hendricks County in central Indiana, is a small stream with a variety of agricultural and suburban land uses that drains into the Eagle Creek Reservoir, a major source of drinking water for Indianapolis, Indiana. The School Branch watershed has become the focus of a collaborative partnership of Federal, State, and local agencies; a university research center; and agricultural producers to understand the effects of land use and management practices on water quality and water quantity in the watershed. The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, contributed to the School Branch partnership with the operation of three streamgages (03353415 School Branch at Maloney Road near Brownsburg, Indiana; 03353420 School Branch at County Road 750 North at Brownsburg, Indiana; and 03353430 School Branch at Noble Drive at Brownsburg, Indiana) and the operation of a continuous water-quality gage (also known as a supergage) at County Road 750 North that measured dissolved oxygen, pH, temperature, specific conductance, turbidity, nitrate, and orthophosphate. Additional efforts included the use of passive samplers to identify wastewater indicators; assessment of fish and macroinvertebrate communities and stream habitat to identify ecological impairment; sampling for nutrients and sediment to estimate loads; and using major ions, stable isotopes and nested groundwater monitoring wells at County Road 750 North to determine hydrologic connectivity between the groundwater and surface water. The objectives of this study were to collect surface and groundwater data to analyze the hydrology and water quality within the watershed. Total nitrogen yields were highest at the upstream site, Maloney Road, and indicated a mixture of nitrogen sources in the watershed. Differences found in total nitrogen loading patterns throughout the watershed may be linked to differences in hydrology and land-use management from site to site. The groundwater and surface water were shown to be highly connected, and except for some low-flow periods, the water was flowing from groundwater to the stream for most of the study period. Fish and macroinvertebrate communities show improvement from upstream to downstream, with increases in diversity, richness, and species sensitive to poor water quality and habitat. These increases were most likely due to improved habitat quality at the downstream station.

Indiana↗

Continuous estimation of baseflow in snowmelt-dominated streams and rivers in the Upper Colorado River Basin: A chemical hydrograph separation approach

Effective science-based management of water resources in large basins requires a qualitative understanding of hydrologic conditions and quantitative measures of the various components of the water budget, including difficult to measure components such as baseflow discharge to streams. Using widely available discharge and continuously collected specific conductance (SC) data, we adapted and applied a long established chemical hydrograph separation approach to quantify daily and representative annual baseflow discharge at fourteen streams and rivers at large spatial (> 1,000 km 2 watersheds) and temporal (up to 37 years) scales in the Upper Colorado River Basin. On average, annual baseflow was 21-58% of annual stream discharge, 13-45% of discharge during snowmelt, and 40-86% of discharge during low-flow conditions. Results suggest that reservoirs may act to store baseflow discharged to the stream during snowmelt and release that baseflow during low-flow conditions, and that irrigation return flows may contribute to increases in fall baseflow in heavily irrigated watersheds. The chemical hydrograph separation approach, and associated conceptual model defined here provide a basis for the identification of land use, management, and climate effects on baseflow.

Colorado, Utah↗

Post-Wildfire Hydrologic Hazards in the Wildland Urban Interface of Colorado and the Western United States

Following a wildfire, such as the 2002 Missionary Ridge fire, a number of hydrologic hazards may develop that can have an important impact on water resources, businesses, homes, reservoirs, roads, and utilities in the wildland urban interface (areas where homes and commercial developments are interspersed with wildlands) in mountainous areas of the Western United States. This fact sheet describes these hazards and identifies approaches to quantify them, thus enabling land and resource managers to plan for and mitigate the effects of these hazards. The fact sheet has been produced in association with the U.S. Geological Survey (USGS) Fire Science Thrust program and the Colorado Front Range Demonstration Project (CFRDP). The current (2007) focus of the CFRDP is on the Three Lakes watershed in Grand County, Colorado, which has applicability to many similar forested, mountain areas in the Western United States.

Fact Sheet↗

Recent changes in stream flashiness and flooding, and effects of flood management in North Carolina and Virginia

The southeastern United States has undergone anthropogenic changes in landscape structure, with the potential to increase (e.g., urbanization) and decrease (e.g., reservoir construction) stream flashiness and flooding. Assessment of the outcome of such change can provide insight into the efficacy of current strategies and policies to manage water resources. We (1) examined trends in precipitation, floods, and stream flashiness and (2) assessed the relative influence of land cover and flow-regulating features (e.g., best management practices and artificial water bodies) on stream flashiness from 1991 to 2013. We found mean annual precipitation decreased, which coincided with decreasing trends in floods. In contrast, stream flashiness, overall, showed an increasing trend during the period of study. However, upon closer examination, 20 watersheds showed stable stream flashiness, whereas 5 increased and 6 decreased in flashiness. Urban watersheds were among those that increased or decreased in flashiness. Watersheds that increased in stream flashiness gained more urban cover, lost more forested cover and had fewer best management practices installed than urban watersheds that decreased in stream flashiness. We found best management practices are more effective than artificial water bodies in regulating flashy floods. Flashiness index is a valuable and straightforward metric to characterize changes in streamflow and help to assess the efficacy of management interventions.

North Carolina, Virginia↗

Satellite monitoring of cyanobacterial harmful algal bloom frequency in recreational waters and drinking water sources

Cyanobacterial harmful algal blooms (cyanoHAB) cause extensive problems in lakes worldwide, including human and ecological health risks, anoxia and fish kills, and taste and odor problems. CyanoHABs are a particular concern in both recreational waters and drinking water sources because of their dense biomass and the risk of exposure to toxins. Successful cyanoHAB assessment using satellites may provide an indicator for human and ecological health protection. In this study, methods were developed to assess the utility of satellite technology for detecting cyanoHAB frequency of occurrence at locations of potential management interest. The European Space Agency's MEdium Resolution Imaging Spectrometer (MERIS) was evaluated to prepare for the equivalent series of Sentinel-3 Ocean and Land Colour Imagers (OLCI) launched in 2016 as part of the Copernicus program. Based on the 2012 National Lakes Assessment site evaluation guidelines and National Hydrography Dataset, the continental United States contains 275,897 lakes and reservoirs >1 ha in area. Results from this study show that 5.6% of waterbodies were resolvable by satellites with 300 m single-pixel resolution and 0.7% of waterbodies were resolvable when a three by three pixel (3 × 3-pixel) array was applied based on minimum Euclidian distance from shore. Satellite data were spatially joined to U.S. public water surface intake (PWSI) locations, where single-pixel resolution resolved 57% of the PWSI locations and a 3 × 3-pixel array resolved 33% of the PWSI locations. Recreational and drinking water sources in Florida and Ohio were ranked from 2008 through 2011 by cyanoHAB frequency above the World Health Organization’s (WHO) high threshold for risk of 100,000 cells mL −1 . The ranking identified waterbodies with values above the WHO high threshold, where Lake Apopka, FL (99.1%) and Grand Lake St. Marys, OH (83%) had the highest observed bloom frequencies per region. The method presented here may indicate locations with high exposure to cyanoHABs and therefore can be used to assist in prioritizing management resources and actions for recreational and drinking water sources.

Florida, Ohio↗

Sediment deposition and selected water-quality characteristics in Cedar Lake and Lake Olathe, Northeast Kansas, 2000

The Lake Olathe watershed, located in northeast Kansas, was investigated using bathymetric survey data and reservoir bottom-sediment cores to determine sediment deposition, water-quality trends, and transport of nutrients (phosphorus and nitrogen species), selected trace elements, selected pesticides, and diatoms as indicators of eutrophic (organic-enriched and depleted oxygen supply) conditions. To determine sediment deposition and loads, bathymetric data from Cedar Lake and Lake Olathe, both located in the Lake Olathe watershed, were collected in 2000 and compared to historical topographic data collected when the lakes were built. Approximately 338 acre-feet of sediment deposition has occurred in Cedar Lake since dam closure in 1938, and 317 acre-feet has occurred at Lake Olathe since 1956. Mean annual sediment deposition was 5.45 acre-feet per year (0.89 acre-feet per year per square mile) for Cedar Lake and 7.0 acre-feet per year (0.42 acre-feet per year per square mile) for Lake Olathe. Mean annual sediment loads for the two reservoirs were 9.6 million pounds per year for Cedar Lake and 12.6 million pounds per year for Lake Olathe. Mean concentrations of total phosphorus in bottom-sediment samples from Cedar Lake ranged from 1,370 to 1,810 milligrams per kilogram, and concentrations in bottom-sediment samples from Lake Olathe ranged from 588 to 1,030 milligrams per kilogram. The implication of large total phosphorus concentrations in the bottom sediment of Cedar Lake is that inflow into Cedar Lake is rich in phosphorus and that adverse water-quality conditions could affect water quality in downstream Lake Olathe through discharge of water from Cedar Lake to Lake Olathe via Cedar Creek. Mean annual phosphorus loads transported from the Lake Olathe watershed were estimated to be 14,700 pounds per year for Cedar Lake and 9,720 pounds per year for Lake Olathe. The mean annual phosphorus yields were estimated to be 3.74 pounds per acre per year for Cedar Lake and 0.91 pound per acre per year for Lake Olathe. Phosphorus yields in the Cedar Lake watershed were largest of the six Kansas impoundment watersheds recently studied. Concentrations of total ammonia plus organic nitrogen as nitrogen in bottom sediment increased from upstream to downstream in both Cedar Lake and Lake Olathe. Mean concentrations of total ammonia plus organic nitrogen as nitrogen (N) ranged from 2,000 to 2,700 milligrams per kilogram in bottom-sediment samples from Cedar Lake and from 1,300 to 2,700 milligrams per kilogram in samples from Lake Olathe. There was no statistical significance between total ammonia plus organic nitrogen as nitrogen and depth of bottom sediment. Concentrations of six trace elements in bottom sediment from Cedar Lake and Lake Olathe (arsenic, chromium, copper, lead, nickel, and zinc) exceeded the U.S. Environmental Protection Agency Threshold Effects Levels (TELs) sediment-quality guidelines for aquatic organisms in sediment except for one lead concentration. Probable Effects Levels (PELs) for trace elements, however, were not exceeded at either lake. Organochlorine and organophosphate insecticides were not detected in bottom-sediment samples from either Cedar Lake or Lake Olathe, but the acetanilide herbicides alachlor and metolachlor were detected in sediment from both lakes. The U.S. Environmental Protection Agency has not proposed TEL or PEL guideline concentrations for bottom sediment for any of the organophosphate, acetanilide, or triazine pesticides. The diatoms (microscopic, single-celled organisms) Cyclotella bodanica , an indicator of low organic-enriched water, and Cyclotella meneghiniana , an indicator of organic-enriched water, were both present in bottom sediment from Lake Olathe. The presence of both of these diatoms suggests varying periods of low and high eutrophication in Lake Olathe from 1956 to 2000. The concentrations of two species in bottom sediment from Cedar Lake, Aulacoseira cf alpigena and Cyclotella meneghiniana , as well as two species in sediment from Lake Olathe, Aulacoseira cf alpigena and Stephanodiscus nigare , increased in sediment cores from the older bottom material to the more recent deposition near the top of the sediment cores. These diatom species indicate eutrophic conditions, and the increased concentration of these diatom species from the bottom of the cores to the sediment/water interface suggests that historically these lakes have been and continue to be eutrophic at times. Comparison of constituent trends between Cedar Lake and Lake Olathe using reservoir bottom sediment was not possible because sediment from Cedar Lake was suspected of having been disturbed. However, trends that may be reflective of historical changes in water quality were not detected in sediment from either Cedar Lake or Lake Olathe for total phosphorus, trace elements (except lead), and organochlorine or organophosphate pesticides. A slight increasing trend in the concentration of total ammonia plus organic nitrogen as nitrogen was seen in the sediment profile from Lake Olathe but not in the profile from Cedar Lake. The acetanilide herbicides alachlor and metolachlor were more prevalent in more recently deposited sediment in Cedar Lake and Lake Olathe, as was the triazine herbicide atrazine in Lake Olathe bottom sediment, suggesting a possible increasing trend in lake-inflow water concentrations. Trends in water-quality characteristics can be used by the Lake Olathe watershed managers to document historical changes in the watershed such as changes in land use, the suspension of the use of chlorinated insecticides, such as DDT and chlordane, and the use of hydrophobic fertilizers. The investigation described in this report provides a baseline of water-quality information to compare future changes in water quality or other watershed activities. With the addition of bathymetric surveys and the inclusion of additional reservoirs, reservoir sediment investigations can be used to estimate historical loads of phosphorus and other constituents in future water-quality assessments throughout Kansas.

Kansas↗

The rising tide of ocean diseases: Unsolved problems and research priorities

New studies have detected a rising number of reports of diseases in marine organisms such as corals, molluscs, turtles, mammals, and echinoderms over the past three decades. Despite the increasing disease load, microbiological, molecular, and theoretical tools for managing disease in the world's oceans are under-developed. Review of the new developments in the study of these diseases identifies five major unsolved problems and priorities for future research: (1) detecting origins and reservoirs for marine diseases and tracing the flow of some new pathogens from land to sea; (2) documenting the longevity and host range of infectious stages; (3) evaluating the effect of greater taxonomic diversity of marine relative to terrestrial hosts and pathogens; (4) pinpointing the facilitating role of anthropogenic agents as incubators and conveyors of marine pathogens; (5) adapting epidemiological models to analysis of marine disease.

Frontiers in Ecology and the Environment↗

Design of a naturalized flow regime—An example from the Lower Missouri River, USA

group of river managers, stakeholders, and scientists met during summer 2005 to design a more naturalized flow regime for the Lower Missouri River (LMOR). The objective was to comply with requirements under the U.S. Endangered Species Act to support reproduction and survival of threatened and endangered species, with emphasis on the endangered pallid sturgeon ( Scaphirhynchus albus ), while minimizing negative effects to existing social and economic benefits of prevailing river management. Specific hydrograph requirements for pallid sturgeon reproduction are unknown, hence much of the design process was based on features of the natural flow regime. Environmental flow components (EFCs) extracted from the reference natural flow regime were used to design and assess performance of alternative flow regimes. The design process incorporated a primary stage in which conceptual hydrographs were developed and assessed for their general ecological and social-economic performance. The second stage accounted for hydroclimatic variation by coding the conceptual hydrographs into reservoir release rules, adding constraints for downstream flooding and low-storage precludes, and running the rules through 100 years of hydroclimatic simulation. The output flow regimes were then evaluated for presumed ecological benefits based on how closely they resembled EFCs in the reference natural flow regime. Flow regimes also were assessed for social-economic cost indicators, including days of flooding of low-lying agricultural land, days over flood stage, and storage levels in system reservoirs. Our experience with flow-regime design on the LMOR underscored the lack of confidence the stakeholders place in the value of the natural flow regime as a measure of ecosystem benefit in the absence of fundamental scientific documentation. Stakeholders desired proof of ecological benefits commensurate with the certainty of economic losses. We also gained insight into the processes of integrating science into a collaborative management exercise. Although the 2005 collaborative effort failed to reach a consensus among stakeholders on a naturalized flow regime, the process was successful in pilot-testing a design approach; it helped focus scienctific efforts on key knowledge gaps; and it demonstrated the potential for collaborations among scientists, stakeholders, and managers in river management decision making.

Lower Missouri River↗

Mercury and methylmercury in reservoirs in Indiana

Mercury (Hg) is an element that occurs naturally, but evidence suggests that human activities have resulted in increased amounts being released to the atmosphere and land surface. When Hg is converted to methylmercury (MeHg) in aquatic ecosystems, MeHg accumulates and increases in the food web so that some fish contain levels which pose a health risk to humans and wildlife that consume these fish. Reservoirs unlike natural lakes, are a part of river systems that are managed for flood control. Data compiled and interpreted for six flood-control reservoirs in Indiana showed a relation between Hg transport, MeHg formation in water, and MeHg in fish that was influenced by physical, chemical, and biological differences among the reservoirs. Existing information precludes a uniform comparison of Hg and MeHg in all reservoirs in the State, but factors and conditions were identified that can indicate where and when Hg and MeHg levels in reservoirs could be highest. As part of a statewide monitoring network for Hg and MeHg in Indiana streams, 66 water samples were collected from four reservoir tailwater sites (downstream near the dams) on a quarterly schedule for 5 years. The reservoirs were Brookville Lake, Cagles Mill Lake, J. Edward Roush Lake, and Mississinewa Lake. Particulate-bound Hg concentrations were significantly lower in tailwater samples than in samples from free-flowing streams in the statewide network. (Free-flowing streams were not affected by dams and were not upstream from these reservoirs.) These data indicated the reduced flow velocity of water upstream from dams was allowing particulate-bound Hg to settle out of the water in the reservoir pools. The concentration ratios of MeHg to Hg were significantly higher in the tailwater samples than in samples from free-flowing streams, and the MeHg to Hg ratios were significantly higher in summer than in other seasons. To evaluate the conditions related to MeHg formation, pools of three reservoirs (Brookville Lake, Monroe Lake, and Patoka Lake) were investigated during summer hydrologic conditions. Water temperature and dissolved oxygen were measured from the water surface to the lake bottom at 10 to 17 transects across each reservoir to identify three thermal strata, defined by water temperature, dissolved oxygen concentration, and depth. Depth-specific water samples were collected from these thermal strata throughout each reservoir, from the headwaters to the dam and from the tailwater. Mercury concentrations higher than 0.04 nanogram per liter (ng/L) were detected in all 53 samples, and MeHg concentrations higher than 0.04 ng/L were detected in 53 percent of the samples. The investigation found a zone of water below 8 or 9 meters, with temperatures less than 18 degrees Celsius and dissolved oxygen less than 3.5 milligrams per liter, extending through nearly half the reservoir area in Monroe Lake and Patoka Lake. This zone had abundant dissolved MeHg and concentration ratios of dissolved MeHg to Hg that ranged from 25 to 82 percent. This zone also had water with pH less than 7 and decreased dissolved sulfate, conditions indicating sulfate reduction by microorganisms that promoted a high potential for the conversion of Hg to MeHg. Reservoir outflow came from this zone at Monroe Lake and contributed to a tailwater concentration ratio for dissolved MeHg to Hg of 56 percent. Reservoir outflow at Patoka Lake was not from this zone, and dissolved MeHg was not detected in the tailwater. In contrast, samples from the summer pool at Brookville Lake had no MeHg detections even though Hg was detected, probably because the water pH higher than 7 inhibited sulfate reduction and did not promote the conversion of Hg to MeHg. Mercury and MeHg concentrations and the concentration ratios of MeHg to Hg in water varied among the six reservoirs in Indiana, and the differences were related to a combination of factors that could apply to other reservoirs. In areas with moderate to high rates of atmospheric Hg wet and dry deposition, Hg runoff and transport to streams and reservoirs was potentially highest for reservoirs with heavily forested watersheds in steep terrains of near-surface bedrock. Methylmercury concentrations and concentration ratios of MeHg to Hg were highest for reservoirs with the longest summer pools and highest inflow-to-outflow retention times, where water-chemistry conditions favoring sulfate reduction promoted conversion of Hg to MeHg. Methylmercury (reported as Hg) in fish-tissue samples collected for the State fish consumption advisory program was used to describe MeHg food-web accumulation and magnification in the reservoirs. The highest percentages of fish-tissue samples with Hg concentrations that exceeded the criterion of 0.30 milligram per kilogram for protection of human health were from Monroe Lake (38 percent) and Patoka Lake (33 percent). A review of the number and size of fish species caught from these two reservoirs resulted in two implications for fish consumption by humans. First, the highest numbers of fish harvested for potential human consumption were species more likely to have MeHg concentrations lower than the human-health criterion (crappie, bluegill, and catfish). Second, although largemouth bass were likely to have MeHg concentrations higher than the human-health criterion, they were caught and released more often than they were harvested. However, the average size largemouth bass (in both reservoirs) and above-average size walleye (in Monroe Lake) that were harvested for potential human consumption were likely to have MeHg concentrations higher than the human-health criterion.

Indiana↗

The blue carbon reservoirs from Maine to Long Island, NY

In response to the New England Governor and Eastern Canadian Premier 2017 Climate Change Action Plan recommendation to “manage blue carbon resources to preserve and enhance their existing carbon reservoirs,” the U.S. Environmental Protection Agency (EPA) convened a New England Blue Carbon Inventory Workgroup, comprised of a variety of federal, state, academic, and non-profit organizations to develop an inventory of blue carbon stocks from Maine to Long Island, New York. The Workgroup focused its inventory efforts on salt marshes and eelgrass meadows, leveraging existing habitat maps for geographic data. Existing data for soil organic carbon stocks were then used to calculate blue carbon stock estimates. For visual display purposes, sediment carbon heat maps were developed to highlight areas of greatest carbon accumulation. The habitat distribution and sediment carbon heat maps can be accessed on the Northeast Ocean Data Portal (www.northeastoceandata.org/eelgrass) which is a public source of expert-reviewed, interactive maps and data on the ocean ecosystem, economy, and culture of the northeastern United States and can be used to facilitate decision making by government agencies, tribal nations, businesses, non-governmental organizations (NGOs), academic institutions, and individuals. Based on available data and Workgroup calculations, the target geographic area has an estimated 218,222 acres of eelgrass meadows, salt marsh and saline Phragmites, which are estimated to provide a reservoir of 7,523,568 megagrams of blue carbon, or the equivalent to the annual carbon emissions from over 5,944,024 passenger vehicles. Due to data limitations, the carbon stock estimate represents a mere fraction of the actual quantity of accumulated carbon in these habitats. The findings from the Workgroup’s efforts and the resulting map products can help inform land and coastal management policies, fisheries management, and climate change mitigation practices. Further refinements and expansion of data are needed, including more detailed habitat maps, deeper soil core data for soil organic carbon content, and inclusion of more marine flora into calculations.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

Effects of capture depth on walleye hooking mortality during ice fishing

Length-based regulations are a common tool used to limit fishing mortality by controlling the size of fish harvested. While such regulations are helpful in managing fish populations, mortality associated with catch-and-release fishing may negatively impact a fishery. We evaluated factors affecting hooking mortality of walleye ( Sander vitreus ) in 2 mainstem Missouri River reservoirs in South Dakota. Winter walleye hooking mortality was evaluated during the ice fishing season in February and March 2020. After capture, walleye ( n = 55) were placed into holding pens for 12 to 72 h to monitor postrelease mortality. Hooking mortality was found to be 20% following angling. Capture depth, landing time, and time in pen were the most influential variables on probability of hooking mortality ( p m ). We observed a sharp increase in p m for walleye captured at depths from 10 to 12 m, where the probability of mortality for fish increased appreciably from 5 to 37%, respectively. Our findings indicate that hooking mortality during the ice fishing season can be substantial in lakes where walleye angling occurs at depths greater than 10 m.

South Dakota↗