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Water-quality assessment of part of the Upper Mississippi River basin, Minnesota and Wisconsin: Environmental setting and study design

The Upper Mississippi River Basin is diverse in ways that can control the areal distribution and flow of water and the distribution and concentration of constituents that affect water quality. A review of the environmental setting of the Upper Mississippi River Basin study unit of the National Water-Quality Assessment Program is intended to put water quality in perspective with the geology, soils, climate, hydrology, ecology and historical uses of the land and provides a basis for the sampling design of the study. The Upper Mississippi River Basin study unit encompasses about 47,000 square miles and includes all of the basin upstream from Lake Pepin. The climate of the study unit is subhumid continental with cold dry winters and warm, moist summers. Average annual precipitation ranges from 22 inches in the western part of the study unit to 32 inches in the east. Annual runoff ranges from less than 2 inches in the west to 14 inches in the northeast. The physiography of the study unit includes the Superior Upland and the Central Lowland Provinces. The Wisconsin Driftless Area and the Dissected Till Plains are unique physiographic sections of the Central Lowland Province. Hydrogeologic units in glacial deposits include surficial and buried sand and gravel aquifers and confining units. Bedrock aquifers and confining units are part of a thick sequence of sedimentary rocks that can be divided into major aquifers separated by confining units. The population of the study unit was about 3,640,000 as of 1990 and increased 16 percent between 1970 and 1990. Seventy-five percent of the population lives in the Twin Cities metropolitan area. An average of 413 million gallons of water per day was used 59 percent from ground water and 41 percent from surface water. Land use and land cover in the study unit consists of forested, agricultural, and urban areas. About 63 percent of the land area is agricultural. The quality of water in streams and ground water are affected by both natural and anthropogenic factors. The quality of water is generally satisfactory for most domestic, public, industrial, and irrigation uses. Most water is of the calcium-magnesium-bicarbonate type. The initial six-year phase of the Upper Mississippi River Basin National Water-Quality Assessment, lasting from 1994 to 1999, focuses on data collection and analysis in a 19,500 square-mile area in Minnesota and Wisconsin that includes the Twin Cities metropolitan area. The study design focuses on factors that have an influence on or a potential influence on the water quality in that area. The most significant contaminants include nutrients, pesticides, synthetic-organic compounds, and trace metals. Environmental stratification consists of dividing the study unit into subareas with homogeneous characteristics to assess natural and anthropogenic factors affecting water quality. The assessment of water quality in streams and in aquifers is based on the sampling design that compares water quality within homogeneous subareas defined by subbasins or aquifer boundaries. The study unit is stratified at four levels for the surface-water component: glacial deposit composition, surficial geology, general land use and land cover, and secondary land use. Ground-water studies emphasize shallow ground water where quality is most likely influenced by overlying land use and land cover. Stratification for ground-water sampling is superimposed on the distribution of shallow aquifers. For each aquifer and surface-water basin this stratification forms the basis for the proposed sampling design used in the Upper Mississippi River Basin National Water-Quality Assessment.

Minnesota, Wisconsin

The Partners in Flight handbook on species assessment Version 2017

Partners in Flight (PIF) is a cooperative venture of federal, state, provincial, and territorial agencies, industry, non-governmental organizations, researchers, and many others whose common goal is the conservation of North American birds (www.partnersinflight.org). While PIF has focused primarily on landbirds, it works in conjunction with other bird partners to promote coordinated conservation of all birds. PIF follows an iterative, adaptive planning approach that develops a sound scientific basis for decision-making and a logical process for setting, implementing, and evaluating conservation objectives (Pashley et al. 2000, Rich et al. 2004, Berlanga et al. 2010). The steps include: 1. Assessing conservation vulnerability of all bird species; 2. Identifying species most in need of conservation attention at continental and regional scales; 3. Setting of numerical population objectives for species of continental and regional importance; 4. Identifying conservation needs and recommended actions for species and habitats of importance; 5. Implementing strategies for meeting species and habitat objectives at continental and regional scales; 6. Evaluating success, making revisions, and setting new objectives for the future. The 2017 PIF Handbook on Species Assessment (2017 PIF Handbook) documents assessment rules and scores used in the Partners in Flight Landbird Conservation Plan: 2016 Revision for Canada and Continental United States (Rosenberg et al. 2016) and The State of North America’s Birds 2016 (NABCI 2016). It updates previous versions of the handbook (Panjabi et al. 2012, 2005, 2001) developed to accompany other PIF applications including Saving Our Shared Birds: Partners in Flight Tri-National Vision for Landbird Conservation (Berlanga et al. 2010) and the North American Landbird Conservation Plan (Rich et al. 2004). All current and past scores, data sources, and other related information are contained in databases hosted by the Bird Conservancy of the Rockies. Scores can be viewed online and downloaded as excel files, including archived versions (http://pif.birdconservancy.org/acad). The current accompanying Avian Conservation Assessment Database (ACAD) holds assessment scores and data for all 1585 native and 18 well-established non-native bird species found in mainland North America south to Panama plus adjacent islands and oceans. The taxonomy follows the American Ornithological Society’s 7th Edition Checklist of North and Middle American Birds, including updates though the 57th supplement, published in 2016 (http://checklist.aou.org/). The ACAD builds on archived PIF databases that hosted only data on the 882 landbirds native to Canada, USA and Mexico. This handbook is presented in two principal sections. Part I details the factors and scoring used by PIF to assess the vulnerability of species at continental and regional scales (i.e. step 1 of the planning approach above). Each assessment factor is based on biological criteria that evaluate distinct components of vulnerability throughout the life cycle of each species across its range. Part II describes the process of how the factors and the corresponding scores can be combined to highlight conservation needs (i.e. step 2 of the planning approach above). Both the scores and the process have evolved over time (Hunter et al. 1992, Carter et al. 2000, Panjabi et al. 2001, 2005, 2012) and continue to be updated in response to external review (Beissinger et al. 2000), broad partner expertise, and the emergence of new data and analytical tools.

Report

Environmental presence and persistence of pharmaceuticals: An overview

Emerging contaminants (ECs) in the environment – that is, chemicals with domestic, municipal, industrial, or agricultural sources that are not commonly monitored but may have the potential for adverse environmental effects – is a rapidly growing field of research. The use of “emerging” is not intended to infer that the presence of these compounds in the environment is new. These chemicals have been released into the environment as long as they have been in production or, in the case of hormones and other endogenous compounds, since the rise of animal life. What is emerging is the interest by the scientific and lay communities in the presence of these chemicals in the environment, the analytical capabilities required for detection, and the subtle effects that very small concentrations of these chemicals appear to have on aquatic biota. In December 2006, Environmental Science & Technology devoted an entire special issue (volume 40, number 23) to the topic of ECs, illustrating the increased interest in the subject. Within the EGs, one particular class that has seen a substantial increase in research over the past 10 years is pharmaceuticals and personal-care products (PPCPs). This increased research interest can be demonstrated by several means, including requests for proposals from funding agencies, but the clearest indication of a focused effort to understand the introduction, transformation, and potential health and environmental effects of PPCPs and ECs, in general, is the number of published reports. This increase can be shown by examining six environmental journals that regularly publish PPCP-related papers – Chemosphere , Environmental Science & Technology , Environmental Toxicology and Chemistry , Science of the Total Environment , Water Research , and Water Science and Technology . In 1998 there were 22 papers published on pharmaceuticals, antibiotics, or drugs in these 6 journals; by 2006, this number increased sixfold to 132 papers (Figure 1.1). This growth can be attributed to a number of factors. The presence of pharmaceuticals in surface-water samples from Europe and the United States was documented in several sentinel papers. These ground-breaking works encouraged other scientists to examine the rivers, streams, lakes, and reservoirs in their regions for such chemicals. In addition, the intense public attention paid to news reports on the environmental detections of these chemicals and possible effects of aquatic life has made this issue visible to the wastewater-treatment, drinking-water treatment, and regulatory communities. This has driven the funding bodies associated with these communities to fund studies or request proposals that address the presence, fate, and effects of PPCPs in aquatic systems. The release of the first comprehensive reconnaissance of pharmaceuticals and other wastewater contaminants in the United States provides an example of the intense media interest in this topic. Within 6 days on online publication of this study, 72 newspapers across the United States had published articles describing the results, either locally written or based on international media syndicate reports. There also was substantial concurrent coverage by local and national radio and television outlets, including the Cable News Network, ABC World News Tonight , and National Public Radio. A substantial fraction of these news stories may be attributable to press releases and media briefings prior to publication. However, the interest by television and print journalists in reporting the results of a peer-reviewed journal article to the general public was motivated by the recognition that describing the presence of PPCPs in water supplies would be of interest to the public. To better convey the results of the study published by Koplin et al. to the public, a separate general-interest fact sheet was published to summarize the important points of the study. Because PPCPs are commonly and widely used by individuals, there is likely a preexisting, personal identification with these compounds that does not occur for the wide range of other organic and inorganic contaminants whose presence in the environment has previously been described. This greater public “name recognition” makes itself known through the media to the regulatory and technical community and has prompted interest in sponsoring research that defines the composition and concentrations of PPCPs in potential sources and their fate and effects following relase into the environment. Independent of the drivers that potentially fuel the interest in studies of PPCPs, it is clear that PPCP research has grown beyond surface-water studies to examine issues such as: • Presence in other matrices, such as groundwater, landfill leachates, sediments, and biosolids. • Environmental transport and fate in surface water, groundwater, and soils amended with reclaimed water or biosolids. • PPCP source elucidation, such as wastewater treatment plant (WWTP) effluents, confined animal feeding operations (CAFOs), and aquaculture. • Removal during wastewater and drinking-water treatment. • Effects on aquatic ecosystems, terrestrial ecosystems, and human health. The chapters in this book provide an extensive examination of current environmental pharmaceutical research and are divided into three sections: “Occurrence and Analysis of Pharmaceuticals in the Environment,” “Environment Fate and Transformations of Veterinary Pharmaceuticals,” and “treatment of Pharmaceuticals in Drinking Water and Wastewater.” The purpose of this introductory overview chapter is to outline current (2004-2006) knowledge about the presence and concentration of PPCPs as described in the published literature. Previous reviews should be consulted for discussions on pre-2004 publications. Those reviews will provide the reader with a comprehensive introduction to the topic of PPCPs in the environment. This chapter describes the sources of PPCPs and other organic contaminants often associated with human wastewater into the environment, the range of concentrations present in various environmental compartments, and the potential routes of removal/sequestration. An overview of the sources and fate of veterinary pharmaceuticals will be discussed in Chapter 5, “Fate and Transport of Veterinary Medicines in the Soil Environment.”

Book chapter