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USGS2014

Late Devonian–Mississippian(?) Zn-Pb(-Ag-Au-Ba-F) deposits and related aluminous alteration zones in the Nome Complex, Seward Peninsula, Alaska

Stratabound base-metal sulfide deposits and occurrences are present in metasedimentary rocks of the Neoproterozoic and Paleozoic Nome Complex on south-central Seward Peninsula, Alaska. Stratabound and locally stratiform deposits including Aurora Creek (Zn-Au-Ba-F), Wheeler North (Pb-Zn-Ag-Au-F), and Nelson (Zn-Pb- Cu-Ag), consist of lenses typically 0.5–2.0 m thick containing disseminated to semimassive sulfides. Host strata of the Aurora Creek and Wheeler North deposits are variably calcareous and graphitic siliciclastic metasedimentary rocks of Middle Devonian or younger age based on detrital zircon geochronology; the Nelson deposit is within Ordovician–Devonian marble (Till et al., this volume, Chapter 4). Deformed veins such as Quarry (Zn-Pb-Ag-Ba-F) and Galena (Pb-Zn-Ag-F) occur in a unit composed mainly of marble and schist; fossil and detrital zircon data indicate that this unit contains rocks of Ordovician, Silurian, and Devonian age. None of these Zn- and Pbrich deposits or occurrences has spatially associated metavolcanic or intrusive rocks. All were deformed and metamorphosed to blueschist facies and then retrograded to greenschist facies during the Jurassic and Early Cretaceous Brookian orogeny. Disseminated Cu-rich deposits including Copper King (Cu-Bi-Sb-Pb-Ag-Au) and Wheeler South (Cu-Ag-Au) occur in silicified carbonate rocks and have textures that indicate a pre- to syn-metamorphic origin. The Zn- and Pb-rich sulfide deposits and occurrences consist mainly of pyrite, sphalerite, and/or galena in a gangue of quartz and carbonate. Minor minerals include arsenopyrite, chalcopyrite, magnetite, pyrrhotite, tetrahedrite, barite, fluorite, and chlorite; gold and electrum are trace to minor constituents locally. Sphalerite is uniformly unzoned and commonly aligned in the dominant foliation. These textures, together with the presence of folded layers of barite at Aurora Creek and folded sulfi de layers at Wheeler North, indicate that mineralization in the stratabound deposits predated deformation and metamorphism. Electron microprobe (EMP) analyses of the carbonate gangue show three major compositions comprising siderite, ankerite, and lesser dolomite. The Cu-rich deposits differ in containing chalcopyrite and bornite in a quartzose matrix. Altered wall rocks surrounding the Zn- and Pb-rich deposits and occurrences have aluminous assemblages composed of muscovite + chloritoid + siderite + chlorite + quartz ± tourmaline ± ilmenite ± apatite ± monazite. Muscovite within these assemblages and in sulfide-rich samples is phengitic and locally enriched in barium; chloritoid at Aurora Creek is enriched in zinc. Minor minerals including pyrite, sphalerite, galena, chalcopyrite, barite, and hyalophane occur as fine-grained disseminations. These altered rocks vary from small lenses a few meters thick to large zones tens of meters in thickness that extend along strike, discontinuously, for 4 km or more. Whole-rock geochemical analyses of the altered rocks from deposit-proximal and deposit-distal settings reveal generally lower SiO 2 /Al 2 O 3 ratios and higher Fe 2 O 3 T /MgO ratios compared to those of unaltered clastic metasedimentary rocks of the Nome Complex and of average shale or graywacke. The deposit-proximal samples are also characterized by anomalously high Zn, Pb, Hg, and Sb, relative to the unaltered metasediments. These data, together with mass change calculations, suggest that the aluminous rocks formed as replacements of permeable graywacke in semi-conformable alteration zones, beneath the seafloor contemporaneously with Zn-and/or Pb-rich sulfide mineralization. Exposures of all three stratabound Zn-Pb deposits show evidence of deformation and recrystallization that occurred in a largely brittle deformational regime. This evidence includes small faults and veins that cut foliation and localized zones of breccia. Sulfide minerals, fluorite, quartz, chlorite, and carbonate minerals crystallized within these structures, which probably formed during Cretaceous deformation of the Nome Complex. Previous studies of the Zn-Pb(-Ag-Au-Ba-F) deposits and occurrences have invoked models of epigenetic veins, volcanogenic massive sulfides (VMS), or carbonate- replacement deposits (CRD). In contrast, our field and laboratory data (including sulfur isotopes; Shanks et al., this volume) suggest that these Zn- and/or Pb-rich deposits represent different levels of sediment-hosted, seafloor-hydrothermal systems, with stratabound and locally stratiform deposits such as Aurora Creek and Wheeler North having formed on the seafloor and/or in the shallow subsurface like many sedimentary-exhalative (SEDEX) deposits worldwide. The deformed veins such as Quarry and Galena are interpreted to have formed deep in the subsurface, possibly as feeders to overlying SEDEX deposits such as Aurora Creek. Formation of all of the Zn- and Pb-rich deposits and occurrences took place during episodic rifting of the continental margin between the Ordovician and Mississippian(?). Regional relationships are consistent with at least some of the deposits having formed in Late Devonian–Mississippian(?) time.

Alaska↗

USGS2014

Sulfur and oxygen isotopic study of Paleozoic sediment-hosted Zn-Pb(-Ag-Au-Ba-F) deposits and associated hydrothermal alteration zones in the Nome Complex, Seward Peninsula, Alaska

Results of sulfur and oxygen isotope studies of sedimentary exhalative (SEDEX) Zn-Pb(-Ag-Au-Ba-F) deposits hosted in metamorphosed Paleozoic clastic and carbonate rocks of the Nome Complex, Seward Peninsula, Alaska, are consistent with data for similar deposits worldwide. Stable isotopic studies of the Nome Complex are challenging because the rocks have undergone Mesozoic blueschist- and greenschist-facies metamorphism and deformation at temperatures estimated from 390–490 °C. Studies of sulfur and oxygen isotopes in other areas suggest that, in the absence of chemical and mineralogical evidence for metasomatism, the principal effect of metamorphism is re-equilibration between individual minerals at the temperature of metamorphism, which commonly leads to a narrowing of the overall range of isotope values for a suite of rocks, but generally does not significantly modify the average whole rock value for that suite. Sulfur isotope studies of the stratabound and locally stratiform sulfide lenses at the Aurora Creek-Christophosen deposit, which is of possible Late Devonian-early Carboniferous age, show a large range of δ34Ssulfide values from -9.7 to 39.4‰, suggesting multiple sulfur sources and possibly complex processes of sulfide formation that may include bacterial sulfate reduction, thermochemical sulfate reduction, and Rayleigh distillation. Low δ34S values probably represent bacterial sulfide minerals remobilized from the host metasedimentary rocks either during the original seafloor mineralization or are related to a Cretaceous mineralizing event that produced Au-vein and base-metal replacement deposits; the latter process is supported by Pb isotope data. The Wheeler North deposit is similar to Aurora Creek-Christophosen but does not have negative δ34S values. It also probably formed in an euxinic sub-basin. The stratabound Nelson deposit, and the deformed veins at the Galena and Quarry deposits, may be older than the Aurora Creek-Christophosen and Wheeler North deposits. The Nelson deposit has a lower and narrower range of δ34S values (1.9 to 10.4‰), averaging about 8‰. The Galena and Quarry veins display δ34S values that are similar to those of the stratabound Nelson deposit. Barite samples from the Aurora Creek-Christophosen, Wheeler North, and Quarry deposits have 34S-enriched δ34S values between 25 and 30‰ that are consistent with derivation of the sulfur from coeval (Paleozoic) seawater sulfate. Given their δ34S values, it is likely that the Aurora Creek-Christophosen and Wheeler North deposits formed in closed sub-basins with euxinic conditions that led to extreme Rayleigh distillation to produce the very large range and very high δ34S values. The Nelson deposit probably formed within an anoxic but not euxinic sub-basin. At Nelson, sulfide was likely derived by a subsurface thermochemical sulfate reduction (TSR) reaction, similar to reactions that are inferred to have produced the sulfides in the Galena and Quarry deposits, which are interpreted as feeder veins for the stratabound deposits. Calculations of oxygen isotope temperatures are based on the assumption that evolved seawater with δ18O of 3‰ was the mineralizing and altering fluid related to the formation of the sulfide deposits. Temperatures of aluminous alteration and sulfide mineralization were between 109 and 209 °C, determined on the basis of oxygen isotope fractionations between the mineralizing fluid and proportionate amounts of quartz and muscovite in the rocks. These temperature estimates agree well with known temperatures of SEDEX mineralization worldwide. Sulfur isotope values also are generally consistent with the known ranges in SEDEX deposits worldwide (δ34S ≈ -5 to 25‰).

GSA Special Papers↗

USGS2014

A previously unrecognized path of early Holocene base flow and elevated discharge from Lake Minong to Lake Chippewa across eastern Upper Michigan

It has long been hypothesized that flux of fresh meltwater from glacial Lake Minong in North America's Superior Basin to the North Atlantic Ocean triggered rapid climatic shifts during the early Holocene. The spatial context of recent support for this idea demands a reevaluation of the exit point of meltwater from the Superior Basin. We used ground penetrating radar (GPR), foundation borings from six highway bridges, a GIS model of surface topography, geologic maps, U.S. Department of Agriculture–Natural Resources Conservation Service soils maps, and well logs to investigate the possible linkage of Lake Minong with Lake Chippewa in the Lake Michigan Basin across eastern Upper Michigan. GPR suggests that a connecting channel lies buried beneath the present interlake divide at Danaher. A single optical age hints that the channel aggraded to 225 m as elevated receipt of Lake Agassiz meltwater in the Superior Basin began to wane <10.6 ka. The large supply of sediment required to accommodate aggradation was immediately available at the channel's edge in the littoral shelves of abandoned Lake Algonquin and in distal parts of post-Algonquin fans. As discharge decreased further, the aggraded channel floor was quickly breached and interbasin flow to Lake Chippewa was restored. Basal radiocarbon ages on wood from small lakes along the discharge path and a GIS model of Minong's shoreline are consistent with another transgression of Minong after ca. 9.5 ka. At the peak of the latter transgression, the southeastern rim of the Superior Basin (Nadoway Drift Barrier) failed, ending Lake Minong. Upon Minong's final drop, aggradational sediments were deposited at Danaher, infilling the prior breach.

Michigan↗

USGS2014

Coastal geology and recent origins for Sand Point, Lake Superior

Sand Point is a small cuspate foreland located along the southeastern shore of Lake Superior within Pictured Rocks National Lakeshore near Munising, Michigan. Park managers’ concerns for the integrity of historic buildings at the northern periphery of the point during the rising lake levels in the mid-1980s greatly elevated the priority of research into the geomorphic history and age of Sand Point. To pursue this priority, we recovered sediment cores from four ponds on Sand Point, assessed subsurface stratigraphy onshore and offshore using geophysical techniques, and interpreted the chronology of events using radiocarbon and luminescence dating. Sand Point formed at the southwest edge of a subaqueous platform whose base is probably constructed of glacial diamicton and outwash. During the post-glacial Nipissing Transgression, the base was mantled with sand derived from erosion of adjacent sandstone cliffs. An aerial photograph time sequence, 1939–present, shows that the periphery of the platform has evolved considerably during historical time, infl uenced by transport of sediment into adjacent South Bay. Shallow seismic refl ections suggest slump blocks along the leading edge of the platform. Light detection and ranging (LiDAR) and shallow seismic refl ections to the northwest of the platform reveal large sand waves within a deep (12 m) channel produced by currents fl owing episodically to the northeast into Lake Superior. Ground-penetrating radar profi les show transport and deposition of sand across the upper surface of the platform. Basal radiocarbon dates from ponds between subaerial beach ridges range in age from 540 to 910 cal yr B.P., suggesting that Sand Point became emergent during the last ~1000 years, upon the separation of Lake Superior from Lakes Huron and Michigan. However, optically stimulated luminescence (OSL) ages from the beach ridges were two to three times as old as the radiocarbon ages, implying that emergence of Sand Point may have begun earlier, ~2000 years ago. The age discrepancy appears to be the result of incomplete bleaching of the quartz grains and an exceptionally low paleodose rate for the OSL samples. Given the available data, the younger ages from the radiocarbon analyses are preferred, but further work is necessary to test the two age models.

Michigan↗

USGS2015

Regional seismic-wave propagation from the M5.8 23 August 2011, Mineral, Virginia, earthquake

The M5.8 23 August 2011 Mineral, Virginia, earthquake was felt over nearly the entire eastern United States and was recorded by a wide array of seismic broadband instruments. The earthquake occurred ~200 km southeast of the boundary between two distinct geologic belts, the Piedmont and Blue Ridge terranes to the southeast and the Valley and Ridge Province to the northwest. At a dominant period of 3 s, coherent postcritical P-wave (i.e., direct longitudinal waves trapped in the crustal waveguide) arrivals persist to a much greater distance for propagation paths toward the northwest quadrant than toward other directions; this is probably related to the relatively high crustal thickness beneath and west of the Appalachian Mountains. The seismic surface-wave arrivals comprise two distinct classes: those with weakly dispersed Rayleigh waves and those with strongly dispersed Rayleigh waves. We attribute the character of Rayleigh wave arrivals in the first class to wave propagation through a predominantly crystalline crust (Blue Ridge Mountains and Piedmont terranes) with a relatively thin veneer of sedimentary rock, whereas the temporal extent of the Rayleigh wave arrivals in the second class are well explained as the effect of the thick sedimentary cover of the Valley and Ridge Province and adjacent Appalachian Plateau province to its northwest. Broadband surface-wave ground velocity is amplified along both north-northwest and northeast azimuths from the Mineral, Virginia, source. The former may arise from lateral focusing effects arising from locally thick sedimentary cover in the Appalachian Basin, and the latter may result from directivity effects due to a northeast rupture propagation along the finite fault plane.

GSA Special Papers↗

USGS2015

Widespread groundwater-level offsets caused by the M w 5.8 Mineral, Virginia, earthquake of 23 August 2011

Groundwater levels were offset in bedrock observation wells, measured by the U.S. Geological Survey or others, as far as 553 km from the M w 5.8 Mineral, Virginia (USA), earthquake on 23 August 2011. Water levels dropped as much as 0.47 m in 34 wells and rose as much as 0.15 m in 12 others. In some wells, which are as much as 213 m deep, the water levels recovered from these deviations in hours to days, but in others the water-level offset may have persisted. The groundwater-level offsets occurred in locations where the earthquake was at least weakly felt, and the maximum water-level excursion increased with felt intensity, independent of epicentral distance. Coseismic static strain from the earthquake was too small and localized to have contributed significantly to the groundwater-level offsets. The relation with intensity is consistent with ground motion from seismic waves leading to the water-level offsets. Examination of the hydrographs indicates that short-period ground motion most likely affected the permeability of the bedrock aquifers monitored by the wells.

GSA Special Papers↗

USGS2015

Geotechnical aspects in the epicentral region of the 2011, M w 5.8 Mineral, Virginia earthquake

A reconnaissance team documented the geotechnical and geological aspects in the epicentral region of the M w (moment magnitude) 5.8 Mineral, Virginia (USA), earthquake of 23 August 2011. Tectonically and seismically induced ground deformations, evidence of liquefaction, rock slides, river bank slumps, ground subsidence, performance of earthen dams, damage to public infrastructure and lifelines, and other effects of the earthquake were documented. This moderate earthquake provided the rare opportunity to collect data to help assess current geoengineering practices in the region, as well as to assess seismic performance of the aging infrastructure in the region. Ground failures included two marginal liquefaction sites, a river bank slump, four minor rockfalls, and a ~4-m-wide, ~12-m-long, ~0.3-m-deep subsidence on a residential property. Damage to lifelines included subsidence of the approaches for a bridge and a water main break to a heavily corroded, 5-cm-diameter valve in Mineral, Virginia. Observed damage to dams, landfills, and public-use properties included a small, shallow slide in the temporary (“working”) clay cap of the county landfill, damage to two earthen dams (one in the epicentral region and one further away near Bedford, Virginia), and substantial structural damage to two public school buildings.

Virginia↗

USGS2014

Ground-motion site effects from multimethod shear-wave velocity characterization at 16 seismograph stations deployed for aftershocks of the August 2011 Mineral, Virginia earthquake

We characterize shear-wave velocity versus depth (Vs profile) at 16 portable seismograph sites through the epicentral region of the 2011 M w 5.8 Mineral (Virginia, USA) earthquake to investigate ground-motion site effects in the area. We used a multimethod acquisition and analysis approach, where active-source horizontal shear (SH) wave reflection and refraction as well as active-source multichannel analysis of surface waves (MASW) and passive-source refraction microtremor (ReMi) Rayleigh wave dispersion were interpreted separately. The time-averaged shear-wave velocity to a depth of 30 m (Vs30), interpreted bedrock depth, and site resonant frequency were estimated from the best-fit Vs profile of each method at each location for analysis. Using the median Vs30 value (270–715 m/s) as representative of a given site, we estimate that all 16 sites are National Earthquake Hazards Reduction Program (NEHRP) site class C or D. Based on a comparison of simplified mapped surface geology to median Vs30 at our sites, we do not see clear evidence for using surface geologic units as a proxy for Vs30 in the epicentral region, although this may primarily be because the units are similar in age (Paleozoic) and may have similar bulk seismic properties. We compare resonant frequencies calculated from ambient noise horizontal:vertical spectral ratios (HVSR) at available sites to predicted site frequencies (generally between 1.9 and 7.6 Hz) derived from the median bedrock depth and average Vs to bedrock. Robust linear regression of HVSR to both site frequency and Vs30 demonstrate moderate correlation to each, and thus both appear to be generally representative of site response in this region. Based on Kendall tau rank correlation testing, we find that Vs30 and the site frequency calculated from average Vs to median interpreted bedrock depth can both be considered reliable predictors of weak-motion site effects in the epicentral region.

Virginia↗

USGS2014

Site response in the eastern United States: A comparison of Vs30 measurements with estimates from horizontal:vertical spectral ratios

Earthquake damage is often increased due to local ground-motion amplification caused by soft soils, thick basin sediments, topographic effects, and liquefaction. A critical factor contributing to the assessment of seismic hazard is detailed information on local site response. In order to address and quantify the site response at seismograph stations in the eastern United States, we investigate the regional spatial variation of horizontal:vertical spectral ratios (HVSR) using ambient noise recorded at permanent regional and national network stations as well as temporary seismic stations deployed in order to record aftershocks of the 2011 Mineral, Virginia, earthquake. We compare the HVSR peak frequency to surface measurements of the shear-wave seismic velocity to 30 m depth (Vs30) at 21 seismograph stations in the eastern United States and find that HVSR peak frequency increases with increasing Vs30. We use this relationship to estimate the National Earthquake Hazards Reduction Program soil class at 218 ANSS (Advanced National Seismic System), GSN (Global Seismographic Network), and RSN (Regional Seismograph Networks) locations in the eastern United States, and suggest that this seismic station–based HVSR proxy could potentially be used to calibrate other site response characterization methods commonly used to estimate shaking hazard.

GSA Special Papers↗

USGS2014

Subsurface geologic features of the 2011 central Virginia earthquakes revealed by airborne geophysics

Characterizing geologic features associated with major earthquakes provides insights into mechanisms contributing to fault slip and assists evaluation of seismic hazard. We use high-resolution airborne geophysical data combined with ground sample measurements to image subsurface geologic features associated with the 2011 moment magnitude (M w ) 5.8 central Virginia (USA) intraplate earthquake and its aftershocks. Geologic mapping and magnetic data analyses suggest that the earthquake occurred near a complex juncture of geologic contacts. These contacts also intersect a >60-km-long linear gravity gradient. Distal aftershocks occurred in tight, ~1-km-wide clusters near other obliquely oriented contacts that intersect gravity gradients, in contrast to more linearly distributed seismicity observed at other seismic zones. These data and corresponding models suggest that local density contrasts (manifested as gravity gradients) modified the nearby stress regime in a manner favoring failure. However, along those gradients seismic activity is localized near structural complexities, suggesting a significant contribution from variations in associated rock characteristics such as rheological weakness and/or rock permeability, which may be enhanced in those areas. Regional magnetic data show a broader bend in geologic structures within the Central Virginia seismic zone, suggesting that seismic activity may also be enhanced in other nearby areas with locally increased rheological weaknesses and/or rock permeability. In contrast, away from the M w 5.8 epicenter, geophysical lineaments are nearly continuous for tens of kilometers, especially toward the northeast. Continuity of associated geologic structures probably contributed to efficient propagation of seismic energy in that direction, consistent with moderate to high levels of damage from Louisa County to Washington, D.C., and neighboring communities.

Virginia↗

USGS2015

Geologic framework and evidence for neotectonism in the epicentral area of the 2011 Mineral, Virginia, earthquake

The epicenters of the main shock and associated aftershocks of the 2011 moment magnitude, M w 5.8 Mineral, Virginia (USA), earthquake, and the updip projection of the possible fault plane that triggered the quakes, are contained in the areas of 2 adjoining 7.5′ quadrangles in the central Virginia Piedmont. These quadrangles have therefore been the focus of concentrated geologic study in the form of bedrock and surficial mapping and near-surface trenching in order to identify potential seismogenic structures. Bedrock mapping has outlined a series of northeast-southwest–trending lithologic belts that include the Ordovician Chopawamsic and Quantico Formations, the narrow neck of the Late Ordovician Ellisville pluton, and mélange zone III of the Mine Run Complex. The region was affected by at least two ductile deformational events, one in the early Paleozoic that was broadly synchronous with the intrusion of the pluton, and one later in the Paleozoic. The earlier deformation produced the Quantico synclinorium and other regional folds, and the later deformation produced faults with associated high-strain zones. Two of these faults have been trenched at their intersection along the east-dipping eastern contact of the Ellisville neck, near where the causative fault for the earthquake projects to the surface. The trenches have exposed abundant evidence of post-Paleozoic fracturing and faulting, including brecciated quartz-tourmaline veins, slickensided thrust and strike-slip faults, and clay-filled fractures. Fluvial and colluvial gravels that overlie these brittle structures have yielded optically stimulated luminescence ages ranging from ca. 27 to 10 ka. These structures are likely representative of surface features associated with Quaternary earthquakes in the Central Virginia seismic zone.

GSA Special Papers↗

USGS2015

Stafford fault system: 120 million year fault movement history of northern Virginia

The Stafford fault system, located in the mid-Atlantic coastal plain of the eastern United States, provides the most complete record of fault movement during the past ~120 m.y. across the Virginia, Washington, District of Columbia (D.C.), and Maryland region, including displacement of Pleistocene terrace gravels. The Stafford fault system is close to and aligned with the Piedmont Spotsylvania and Long Branch fault zones. The dominant southwest-northeast trend of strong shaking from the 23 August 2011, moment magnitude M w 5.8 Mineral, Virginia, earthquake is consistent with the connectivity of these faults, as seismic energy appears to have traveled along the documented and proposed extensions of the Stafford fault system into the Washington, D.C., area. Some other faults documented in the nearby coastal plain are clearly rooted in crystalline basement faults, especially along terrane boundaries. These coastal plain faults are commonly assumed to have undergone relatively uniform movement through time, with average slip rates from 0.3 to 1.5 m/m.y. However, there were higher rates during the Paleocene–early Eocene and the Pliocene (4.4–27.4 m/m.y), suggesting that slip occurred primarily during large earthquakes. Further investigation of the Stafford fault system is needed to understand potential earthquake hazards for the Virginia, Maryland, and Washington, D.C., area. The combined Stafford fault system and aligned Piedmont faults are ~180 km long, so if the combined fault system ruptured in a single event, it would result in a significantly larger magnitude earthquake than the Mineral earthquake. Many structures most strongly affected during the Mineral earthquake are along or near the Stafford fault system and its proposed northeastward extension.

Virginia↗

USGS2015

The modern muds of Laguna Mar Chiquita (Argentina): Particle size and geochemical trends from a large saline lake in the "thick-skinned" Andean foreland

Laguna Mar Chiquita (central Argentina; ~latitude 31°S, longitude 63°W) provides an outstanding opportunity to examine organic facies development and petroleum source-rock potential in a modern thick-skinned foreland basin lake. In this case study, we define profundal, paleodelta, and lake-margin depositional environments based on trends in bathymetry and lake-floor sediment particle size. Sedimentary geochemical analyses indicate that organic carbon–rich muds accumulate in profundal environments during the extant lake-level highstand. The lateral variability of organic facies is minimal. The quality of organic facies is controlled by lake level and depositional environment, both of which dictate patterns of algal productivity, siliciclastic dilution, and early diagenesis. We present conceptual models of lacustrine source rocks in both thick-skinned and thin-skinned foreland basins based on modern analog data from both Laguna Mar Chiquita and other lakes in the central Andean foreland. Over relatively short time intervals (10 2 –10 4 yr), climatically driven water-level fluctuations influence the source-rock potential of these basins. Over time intervals >10 5 yr, contraction and lateral migration of the basin flexural profile control stratal stacking patterns and the potential for hydrocarbon play development.

Laguna Mar Chiquita↗

USGS2015

Petrology and diagenetic history of the upper shale member of the Late Devonian-Early Mississippian Bakken Formation, Williston Basin, North Dakota

The organic-rich upper shale member of the upper Devonian–lower Mississippian Bakken Formation (Williston Basin, North Dakota, USA) has undergone significant diagenetic alteration, irrespective of catagenesis related to hydrocarbon generation. Alteration includes precipitation of numerous cements, replacement of both detrital and authigenic minerals, multiple episodes of fracturing, and compaction. Quartz authigenesis occurred throughout much of the member, and is represented by multiple generations of microcrystalline quartz. Chalcedonic quartz fills radiolarian microfossils and is present in the matrix. Sulfide minerals include pyrite and sphalerite. Carbonate diagenesis is volumetrically minor and includes thin dolomite overgrowths and calcite cement. At least two generations of fractures are observed. Based on the authigenic minerals and their relative timing of formation, the evolution of pore waters can be postulated. Dolomite and calcite resulted from early postdepositional aerobic oxidation of some of the abundant organic material in the formation. Following aerobic oxidation, conditions became anoxic and sulfide minerals precipitated. Transformation of the originally opaline tests of radiolaria resulted in precipitation of quartz, and quartz authigenesis is most common in more distal parts of the depositional basin where radiolaria were abundant. Because quartz authigenesis is related to the distribution of radiolaria, there is a link between diagenesis and depositional environment. Furthermore, much of the diagenesis in the upper shale member preceded hydrocarbon generation, so early postdepositional processes were responsible for occlusion of significant original porosity in the member. Thus, diagenetic mineral precipitation was at least partly responsible for the limited ability of these mudstones to provide porosity for storage of hydrocarbons.

North Dakota↗

USGS2015

Karst mapping in the United States: Past, present and future

The earliest known comprehensive karst map of the entire USA was published by Stringfield and LeGrand (1969), based on compilations of William E. Davies of the U.S. Geological Survey (USGS). Various versions of essentially the same map have been published since. The USGS recently published new digital maps and databases depicting the extent of known karst, potential karst, and pseudokarst areas of the United States of America including Puerto Rico and the U.S. Virgin Islands (Weary and Doctor, 2014). These maps are based primarily on the extent of potentially karstic soluble rock types, and rocks with physical properties conducive to the formation of pseudokarst features. These data were compiled and refined from multiple sources at various spatial resolutions, mostly as digital data supplied by state geological surveys. The database includes polygons delineating areas with potential for karst and that are tagged with attributes intended to facilitate classification of karst regions. Approximately 18% of the surface of the fifty United States is underlain by significantly soluble bedrock. In the eastern United States the extent of outcrop of soluble rocks provides a good first-approximation of the distribution of karst and potential karst areas. In the arid western states, the extent of soluble rock outcrop tends to overestimate the extent of regions that might be considered as karst under current climatic conditions, but the new dataset encompasses those regions nonetheless. This database will be revised as needed, and the present map will be updated as new information is incorporated.

GSA Special Papers↗

USGS2016

Geologic history of the Black Hills caves, South Dakota

Cave development in the Madison aquifer of the Black Hills has taken place in several stages. Mississippian carbonates first underwent eogenetic (early diagenetic) reactions with interbedded sulfates to form breccias and solution voids. Later subaerial exposure allowed oxygenated meteoric water to replace sulfates with calcite and to form karst and small caves. All were later buried by ~2 km of Pennsylvanian–Cretaceous strata. Groundwater flow and speleogenesis in the Madison aquifer were renewed by erosional exposure during Laramide uplift. Post-Laramide speleogenesis enlarged paleokarst voids. Most interpretations of this process in the Black Hills invoke rising thermal water, but they fail to account for the cave patterns. Few passages extend downdip below the present water table or updip to outcrops. None reaches the base of the Madison Limestone, and few reach the top. Major caves underlie a thin cover of basal Pennsylvanian–Permian Minnelusa Formation (interbedded quartzarenite and carbonates). Water infiltrating through the Minnelusa Formation dissolves carbonates in a nearly closed system, producing low p CO 2 , while recharge directly into Madison outcrops has a much higher p CO 2 . Both are at or near calcite saturation when they enter caves, but their mixture is undersaturated. The caves reveal four phases of calcite deposition: eogenetic ferroan calcite (Mississippian replacement of sulfates); white scalenohedra in paleovoids deposited during deep post-Mississippian burial; palisade crusts formed during blockage of springs by Oligocene–Miocene continental sediments; and laminated crusts from late Pleistocene water-table fluctuations. The caves reveal more than 300 m.y. of geologic history and a close relationship to regional geologic events.

South Dakota, Wyoming↗

USGS2016

Natural graphite demand and supply - Implications for electric vehicle battery requirements

Electric vehicles have been promoted to reduce greenhouse gas emissions and lessen U.S. dependence on petroleum for transportation. Growth in U.S. sales of electric vehicles has been hindered by technical difficulties and the high cost of the lithium-ion batteries used to power many electric vehicles (more than 50% of the vehicle cost). Groundbreaking has begun for a lithium-ion battery factory in Nevada that, at capacity, could manufacture enough batteries to power 500,000 electric vehicles of various types and provide economies of scale to reduce the cost of batteries. Currently, primary synthetic graphite derived from petroleum coke is used in the anode of most lithium-ion batteries. An alternate may be the use of natural flake graphite, which would result in estimated graphite cost reductions of more than US$400 per vehicle at 2013 prices. Most natural flake graphite is sourced from China, the world's leading graphite producer. Sourcing natural flake graphite from deposits in North America could reduce raw material transportation costs and, given China's growing internal demand for flake graphite for its industries and ongoing environmental, labor, and mining issues, may ensure a more reliable and environmentally conscious supply of graphite. North America has flake graphite resources, and Canada is currently a producer, but most new mining projects in the United States require more than 10 yr to reach production, and demand could exceed supplies of flake graphite. Natural flake graphite may serve only to supplement synthetic graphite, at least for the short-term outlook.

GSA Special Papers↗

USGS2016

U.S. Geological Survey assessment of global potash production and resources—A significant advancement for global development and a sustainable future.

During the past 15 yr, the global requirement for fertilizers has grown considerably, mainly due to demand by a larger and wealthier world population for more and higher-quality food. The demand and price for potash as a primary fertilizer ingredient have increased in tandem, because of the necessity to increase the quantity and quality of food production on the decreasing amount of available arable land. The primary sources of potash are evaporates, which occur mainly in marine salt basins and a few brine-bearing continental basins. World potash resources are large, but distribution is inequitable and not presently developed in countries where population and food requirements are large and increasing. There is no known substitute for potash in fertilizer, so knowledge of the world’s potash resources is critical for a sustainable future. The U.S. Geological Survey recently completed a global assessment of evaporite-hosted potash resources, which included a geographic information system–based inventory of known potash resources. This assessment included permissive areas or tracts for undiscovered resources at a scale of 1:1,000,000. Assessments of undiscovered potash resources were conducted for a number of the world’s evaporite-hosted potash basins. The data collected provide a major advance in our knowledge of global potash resources that did not exist prior to this study. The two databases include: (1) potash deposits and occurrences, and (2) potash tracts (basins that contain these deposits and occurrences and potentially undiscovered potash deposits). Data available include geology, mineralogy, grade, tonnage, depth, thickness, areal extent, and structure, as well as numerous pertinent references.

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