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Results for “Emerging Contaminants”

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At least 73 records · Page 4Linked to original sources
USGS2014

Featured collection introduction: contaminants of emerging concern II

This collection of 13 articles focuses on CECs, and each of the articles highlights a specific aspect of this broad topic. The articles were solicited from researchers who participated in the second summer specialty conference on this topic, organized by the American Water Resources Association. The title of the conference was “CECs in Water Resources II: Research, Engineering and Community Action,” and the conference, as well as the articles in this featured collection, focus on a better and more comprehensive understanding of these contaminants. The conference was held in Denver, Colorado, on June 25-27, 2012, and approximately 125 conference attendees participated in an interdisciplinary forum of more than 75 presentations including keynote or plenary presentations by Dana Kolpin, Jorg Drewes, Heiko Schoenfuss, Chris Metcalfe, Vicki Blazer, and Tyrone Hayes. The first conference was held in 2007 and also produced a featured collection of articles (Battaglin and Kolpin, 2009).

Journal of the American Water Resources Associatio↗
USGS2010

Evaluating the behavior of gadolinium and other rare earth elements through large metropolitan sewage treatment plants

A primary pathway for emerging contaminants (pharmaceuticals, personal care products, steroids, and hormones) to enter aquatic ecosystems is effluent from sewage treatment plants (STP), and identifying technologies to minimize the amount of these contaminants released is important. Quantifying the flux of these contaminants through STPs is difficult. This study evaluates the behavior of gadolinium, a rare earth element (REE) utilized as a contrasting agent in magnetic resonance imaging (MRI), through four full-scale metropolitan STPs that utilize several biosolids thickening, conditioning, stabilization, and dewatering processing technologies. The organically complexed Gd from MRIs has been shown to be stable in aquatic systems and has the potential to be utilized as a conservative tracer in STP operations to compare to an emerging contaminant of interest. Influent and effluent waters display large enrichments in Gd compared to other REEs. In contrast, most sludge samples from the STPs do not display Gd enrichments, including primary sludges and end-product sludges. The excess Gd appears to remain in the liquid phase throughout the STP operations, but detailed quantification of the input Gd load and residence times of various STP operations is needed to utilize Gd as a conservative tracer.

Environmental Science & Technology↗
USGS2017

Groundwater resources of the Devils Postpile National Monument—Current conditions and future vulnerabilities

This study presents an extensive database on groundwater conditions in and around Devils Postpile National Monument. The database contains chemical analyses of springs and the monument water-supply well, including major-ion chemistry, trace element chemistry, and the first information on a list of organic compounds known as emerging contaminants. Diurnal, seasonal, and annual variations in groundwater discharge and chemistry are evaluated from data collected at five main monitoring sites, where streams carry the aggregate flow from entire groups of springs. These springs drain the Mammoth Mountain area and, during the fall months, contribute a significant fraction of the San Joaquin River flow within the monument. The period of this study, from fall 2012 to fall 2015, includes some of the driest years on record, though the seasonal variability observed in 2013 might have been near normal. The spring-fed streams generally flowed at rates well below those observed during a sequence of wet years in the late 1990s. However, persistence of flow and reasonably stable water chemistry through the recent dry years are indicative of a sizeable groundwater system that should provide a reliable resource during similar droughts in the future. Only a few emerging contaminants were detected at trace levels below 1 microgram per liter (μg/L), suggesting that local human visitation is not degrading groundwater quality. No indication of salt from the ski area on the north side of Mammoth Mountain could be found in any of the groundwaters. Chemical data instead show that natural mineral water, such as that discharged from local soda springs, is the main source of anomalous chloride in the monument supply well and in the San Joaquin River. The results of the study are used to develop a set of recommendations for future monitoring to enable detection of deleterious impacts to groundwater quality and quantity

California↗
USGS2014

Occurrence of contaminants of emerging concern along the California coast (2009-10) using passive sampling devices

Three passive sampling devices (PSDs), polar organic chemical integrative samplers (POCIS), polyethylene devices (PEDs), and solid-phase microextraction (SPME) samplers were used to sample a diverse set of chemicals in the coastal waters of San Francisco Bay and the Southern California Bight. Seventy one chemicals (including fragrances, phosphate flame retardants, pharmaceuticals, PAHs, PCBs, PBDEs, and pesticides) were measured in at least 50% of the sites. The chemical profile from the San Francisco Bay sites was distinct from profiles from the sites in the Southern California Bight. This distinction was not due to a single compound or class, but by the relative abundances/concentrations of the chemicals. Comparing the PSDs to mussel ( Mytilus spp.) tissues, a positive correlation exists for the 25 and 26 chemicals in common for the PEDs and SPME, respectively. Diphenhydramine was the only common chemical out of 40 analyzed in both POCIS and tissues detected at a common site.

California↗
USGS2014

Mycotoxins: diffuse and point source contributions of natural contaminants of emerging concern to streams

To determine the prevalence of mycotoxins in streams, 116 water samples from 32 streams and three wastewater treatment plant effluents were collected in 2010 providing the broadest investigation on the spatial and temporal occurrence of mycotoxins in streams conducted in the United States to date. Out of the 33 target mycotoxins measured, nine were detected at least once during this study. The detections of mycotoxins were nearly ubiquitous during this study even though the basin size spanned four orders of magnitude. At least one mycotoxin was detected in 94% of the 116 samples collected. Deoxynivalenol was the most frequently detected mycotoxin (77%), followed by nivalenol (59%), beauvericin (43%), zearalenone (26%), β-zearalenol (20%), 3-acetyl-deoxynivalenol (16%), α-zearalenol (10%), diacetoxyscirpenol (5%), and verrucarin A (1%). In addition, one or more of the three known estrogenic compounds (i.e. zearalenone, α-zearalenol, and β-zearalenol) were detected in 43% of the samples, with maximum concentrations substantially higher than observed in previous research. While concentrations were generally low (i.e. < 50 ng/L) during this study, concentrations exceeding 1000 ng/L were measured during spring snowmelt conditions in agricultural settings and in wastewater treatment plant effluent. Results of this study suggest that both diffuse (e.g. release from infected plants and manure applications from exposed livestock) and point (e.g. wastewater treatment plants and food processing plants) sources are important environmental pathways for mycotoxin transport to streams. The ecotoxicological impacts from the long-term, low-level exposures to mycotoxins alone or in combination with complex chemical mixtures are unknown

Science of the Total Environment↗
USGS2017

Nationwide reconnaissance of contaminants of emerging concern in source and treated drinking waters of the United States: Pharmaceuticals

Mobile and persistent chemicals that are present in urban wastewater, such as pharmaceuticals, may survive on-site ormunicipal wastewater treatment and post-discharge environmental processes. These pharmaceuticals have the potential to reach surface and groundwaters, essential drinking-water sources. A joint, two-phase U.S. Geological Survey-U.S. Environmental Protection Agency study examined source and treated waters from 25 drinking-water treatment plants from across the United States. Treatment plants that had probable wastewater inputs to their source waters were selected to assess the prevalence of pharmaceuticals in such source waters, and to identify which pharmaceuticals persist through drinking-water treatment. All samples were analyzed for 24 pharmaceuticals in Phase I and for 118 in Phase II. In Phase I, 11 pharmaceuticals were detected in all source-water samples, with amaximumof nine pharmaceuticals detected in any one sample. The median number of pharmaceuticals for all 25 samples was five. Quantifiable pharmaceutical detections were fewer, with a maximum of five pharmaceuticals in any one sample and a median for all samples of two. In Phase II, 47 different pharmaceuticals were detected in all source-water samples, with a maximum of 41 pharmaceuticals detected in any one sample. The median number of pharmaceuticals for all 25 samples was eight. For 37 quantifiable pharmaceuticals in Phase II, median concentrations in source water were below 113 ng/L.

Science of the Total Environment↗
USGS2009

Reproductive health of bass in the potomac, USA, drainage: Part 2. Seasonal occurrence of persistent and emerging organic contaminants

The seasonal occurrence of organic contaminants, many of which are potential endocrine disruptors, entering the Potomac River, USA, watershed was investigated using a two-pronged approach during the fall of 2005 and spring of 2006. Passive samplers (semipermeable membrane device and polar organic chemical integrative sampler [POCIS]) were deployed in tandem at sites above and below wastewater treatment plant discharges within the watershed. Analysis of the samplers resulted in detection of 84 of 138 targeted chemicals. The agricultural pesticides atrazine and metolachlor had the greatest seasonal changes in water concentrations, with a 3.1 - to 91 -fold increase in the spring compared with the level in the previous fall. Coinciding with the elevated concentrations of atrazine in the spring were increasing concentrations of the atrazine degradation products desethylatrazine and desisopropylatrazine in the fall following spring and summer application of the parent compound. Other targeted chemicals (organochlorine pesticides, polycyclic aromatic hydrocarbons, and organic wastewater chemicals) did not indicate seasonal changes in occurrence or concentration; however, the overall concentrations and number of chemicals present were greater at the sites downstream of wastewater treatment plant discharges. Several fragrances and flame retardants were identified in these downstream sites, which are characteristic of wastewater effluent and human activities. The bioluminescent yeast estrogen screen in vitro assay of the POCIS extracts indicated the presence of chemicals that were capable of producing an estrogenic response at all sampling sites. ?? 2009 SETA.

Environmental Toxicology and Chemistry↗
USGS2014

Contaminants of emerging concern in the lower Stillaguamish River Basin, Washington, 2008-11

A series of discrete water-quality samples were collected in the lower Stillaguamish River Basin near the city of Arlington, Washington, through a partnership with the Stillaguamish Tribe of Indians. These samples included surface waters of the Stillaguamish River, adjacent tributary streams, and paired inflow and outflow sampling at three wastewater treatment plants in the lower river basin. Chemical analysis of these samples focused on chemicals of emerging concern, including wastewater compounds, human-health pharmaceuticals, steroidal hormones, and halogenated organic compounds on solids and sediment. This report presents the methods used and data results from the chemical analysis of these samples

Washington↗
USGS2018

Contaminants of emerging concern in the environment: Where we have been and what does the future hold?

In 1962, Rachel Carson’s book Silent Spring alerted the nation to the dangers of manmade chemicals and indiscriminate use of pesticides. DDT was the culprit and its use threatened a variety of wildlife, including the national bird, bald eagles. In 1969, pressured by scientists and the public, the United States banned almost all uses of DDT; however, DDT was just the tip of the chemical iceberg. In 1996, Theo Colborn’s book, Our Stolen Future, again alerted the public to the dangers of chemical exposure. Endocrine-disrupting chemicals were identified as concerns because exposure to extremely small concentrations can have adverse effects on people and wildlife by interfering with chemical messaging systems, affecting things like sexual development and reproduction.

Water Resources Impact↗
USGS2014

Cross-ecosystem impacts of stream pollution reduce resource and contaminant flux to riparian food webs

The effects of aquatic contaminants are propagated across ecosystem boundaries by aquatic insects that export resources and contaminants to terrestrial food webs; however, the mechanisms driving these effects are poorly understood. We examined how emergence, contaminant concentration, and total contaminant flux by adult aquatic insects changed over a gradient of bioavailable metals in streams and how these changes affected riparian web-building spiders. Insect emergence decreased 97% over the metal gradient, whereas metal concentrations in adult insects changed relatively little. As a result, total metal exported by insects (flux) was lowest at the most contaminated streams, declining 96% among sites. Spiders were affected by the decrease in prey biomass, but not by metal exposure or metal flux to land in aquatic prey. Aquatic insects are increasingly thought to increase exposure of terrestrial consumers to aquatic contaminants, but stream metals reduce contaminant flux to riparian consumers by strongly impacting the resource linkage. Our results demonstrate the importance of understanding the contaminant-specific effects of aquatic pollutants on adult insect emergence and contaminant accumulation in adults to predict impacts on terrestrial food webs.

Ecological Applications↗
USGS2013

Water quality status and trends in the United States

Information about water quality is vital to ensure long-term availability and sustainability of water that is safe for drinking and recreation and suitable for industry, irrigation, fish, and wildlife. Protecting and enhancing water quality is a national priority, requiring information on water-quality status and trends, progress toward clean water standards, continuing problems, and emerging challenges. In this brief review, we discuss U.S. Geological Survey assessments of nutrient pollution, pesticides, mixtures of organic wastewater compounds (known as emerging contaminants), sediment-bound contaminants (like lead and DDT), and mercury, among other contaminants. Additionally, aspects of land use and current and emerging challenges associated with climate change are presented. Climate change must be considered, as water managers continue their efforts to maintain sufficient water of good quality for humans and for the ecosystem.

Book chapter↗
USGS2003

Pharmaceuticals, hormones, personal-care products, and other organic wastewater contaminants in water resources: Recent research activities of the U.S. Geological Survey's toxic substances hydrology program

Recent decades have brought increasing concerns for potential contamination of water resources that could inadvertently result during production, use, and disposal of the numerous chemicals offering improvements in industry, agriculture, medical treatment, and even common household products. Increasing knowledge of the environmental occurrence or toxicological behavior of these contaminants from various studies in Europe, United States, and elsewhere has resulted in increased concern for potential adverse environmental and human health effects (Daughton and Ternes, 1999). Ecologists and public health experts often have incomplete understandings of the toxicological significance of many of these contaminants, particularly long-term, low-level exposure and when they occur in mixtures with other contaminants (Daughton and Ternes, 1999; K&uuml;mmerer, 2001). In addition, these &lsquo;emerging contaminants&rsquo; are not typically monitored or assessed in ambient water resources. The need to understand the processes controlling the transport and fate of these contaminants in the environment, and the lack of knowledge of the significance of long-term exposures have increased the need to study environmental occurrence down to trace (nanogram per liter) levels. Furthermore, the possibility that mixtures of environmental contaminants may interact synergistically or antagonistically has increased the need to characterize the types of mixtures that are found in our waters. The U.S. Geological Survey&rsquo;s Toxic Substances Hydrology Program (Toxics Program) is developing information and tools on emerging water-quality issues that will be used to design and improve water-quality monitoring and assessment programs of the USGS and others, and for proactive decision-making by industry, regulators, the research community, and the public (http://toxics.usgs.gov/regional/emc.html). This research on emerging water-quality issues includes a combination of laboratory work to develop new analytical capabilities as well as field work on the occurrence, fate, and effects of these contaminants.

Geohealth News↗
USGS2006

Contaminant exposure and potential effects on terrestrial vertebrates residing in the National Capital Region network and Mid-Atlantic network

Part of the mission of the National Park Service is to preserve the natural resources, processes, systems, and associated values of its units in an unimpaired condition. Environmental contamination and pollution processes are well recognized stressors addressed by its management policies and plans. A recent study indicates that contemporary terrestrial vertebrate ecotoxicological data are lacking for 59 of 126 Park Service units located in coastal watersheds exhibiting serious water quality problems or high vulnerability to pollution. Based upon these findings, a more in-depth evaluation of contaminant threats and ecotoxicological data gaps related to terrestrial vertebrates was undertaken at 23 Inventory and Monitoring National Park units in National Capital Region and Mid-Atlantic Networks. Ecotoxicological data were compiled for each park unit through literature searches and meetings with Park Service personnel. Information on contemporary and on persistent legacy pollutants in air, water, soil, and terrestrial vertebrates (amphibians, reptiles, birds and mammals) were evaluated. To identify contaminant threats in proximity to the 23 Park Service study units, data was gathered on National Priority List Superfund sites, Section 303(d) Impaired Waterbodies, the number and relative toxicity of current use pesticides and herbicides, Toxic Release Inventory sites and discharge of priority pollutants, and Fish Consumption Advisories. A metric was derived that described the quality and quantity of existing data for each park, and in combination with known contaminant threats, park units in need of additional study were identified. Results demonstrated that over half of the Park Service study units are near Toxic Release Inventory sites discharging dioxins, polychlorinated biphenyls, lead or mercury into air or water, and fish consumption advisories are in effect at or near 22 of the 23 study units. Pesticide and herbicide use at the park units is minimal, with the exception of those units with significant agricultural leases. Despite highly regulated use, many of the pesticides and herbicides applied are believed to be highly toxic to amphibians, and some of the compounds are also highly toxic to birds. Only 70 reports were found that describe terrestrial vertebrate ecotoxicology data on or near the study units. Of the greater than 75,000 compounds in commerce in the United States, existing terrestrial vertebrate exposure and effects data in the pr esent study were limited to 58 legacy organochlorine pesticides, polychlorinated biphenyls and individual congeners, insecticides and rodenticides, metals, and some contemporary compounds (e.g., polybrominated diphenyl ether flame retardants, and alkylphenol and ethoxylate surfactants). Based upon these and other findings, ecotoxicological monitoring and research investigations of terrestrial vertebrates are warranted at several National Parks. These include Shenandoah National Park, Richmond National Battlefield, Chesapeake & Ohio Canal National Historic Park, Valley Forge National Historic Park, Hopewell Furnace National Historic Site, Monocacy National Battlefield, and Harpers Ferry National Historic Park. The types of investigations vary according to the species present at these parks and potential contaminant threats, but should focus on contemporary use pesticides and herbicides, polychlorinated biphenyls, mercury, lead, and perhaps, emerging contaminants including antibiotics, flame retardants, pharmaceuticals, and surfactants. Other management recommendations include additional training for natural resource staff members in the area of ecotoxicology, inclusion of terrestrial vertebrate contaminant monitoring and the Contaminant Assessment Process (U.S. Geological Survey Biomonitoring of Environmental Status and Trends Project) into the National Park Service Vital Signs Program, development of protocols for hand ling and toxicological analysis of dead or seemingly affected wildlife, consideration of some alternative methods and compounds for pest management and weed control, and use of non-toxic fishing tackle by visitors.

Maryland, Pennsylvania, Virginia↗
USGS2002

Response to comment on "Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance"

We concur with the response of Eckel to our recent publication in this Journal (1). As the author notes, the topic of emerging contaminants is currently receiving extensive media coverage and scientific notice, but there are earlier reports that foreshadow this current interest. Eckel’s comment regarding the detection of pharmaceuticals and other organic wastewater contaminants (OWC) at a Superfund landfill site (2) is well taken, as other reports confirm the presence of such compounds at waste-disposal and landfill sites (3). In fact, literature from more than 20 years ago documented the occurrence of OWCs in the environment (4-7). A significant difference between these reports and our study is that we have systematically documented the frequent presence and low concentrations of a broad suite of OWCs in a wide variety of streams across the United States.

Environmental Science & Technology↗