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Modeled coastal-ocean pathways of land-sourced contaminants in the aftermath of Hurricane Florence

Extreme precipitation during Hurricane Florence, which made landfall in North Carolina in September 2018, led to breaches of hog waste lagoons, coal ash pits, and wastewater facilities. In the weeks following the storm, freshwater discharge carried pollutants, sediment, organic matter, and debris to the coastal ocean, contributing to beach closures, algae blooms, hypoxia, and other ecosystem impacts. Here, the ocean pathways of land-sourced contaminants following Hurricane Florence are investigated using the Regional Ocean Modeling System (ROMS) with a river point source with fixed water properties from a hydrologic model (WRF-Hydro) of the Cape Fear River Basin, North Carolina's largest watershed. Patterns of contaminant transport in the coastal ocean are quantified with a finite duration tracer release based on observed flooding of agricultural and industrial facilities. A suite of synthetic events also was simulated to investigate the sensitivity of the river plume transport pathways to river discharge and wind direction. The simulated Hurricane Florence discharge event led to westward (downcoast) transport of contaminants in a coastal current, along with intermittent storage and release of material in an offshore (bulge) or eastward (upcoast) region near the river mouth, modulated by alternating upwelling and downwelling winds. The river plume patterns led to a delayed onset and long duration of contaminants affecting beaches 100 km to the west, days to weeks after the storm. Maps of the onset and duration of hypothetical water quality hazards for a range of weather conditions may provide guidance to managers on the timing of swimming/shellfishing advisories and water quality sampling.

Journal of Geophysical Research: Oceans

Application of near-surface geophysics as part of a hydrologic study of a subsurface drip irrigation system along the Powder River floodplain near Arvada, Wyoming

Rapid development of coalbed natural gas (CBNG) production in the Powder River Basin (PRB) of Wyoming has occurred since 1997. National attention related to CBNG development has focused on produced water management, which is the single largest cost for on-shore domestic producers. Low-cost treatment technologies allow operators to reduce their disposal costs, provide treated water for beneficial use, and stimulate oil and gas production by small operators. Subsurface drip irrigation (SDI) systems are one potential treatment option that allows for increased CBNG production by providing a beneficial use for the produced water in farmland irrigation. Water management practices in the development of CBNG in Wyoming have been aided by integrated geophysical, geochemical, and hydrologic studies of both the disposal and utilization of water. The U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) and the U.S. Geological Survey (USGS) have utilized multi-frequency airborne, ground, and borehole electromagnetic (EM) and ground resistivity methods to characterize the near-surface hydrogeology in areas of produced water disposal. These surveys provide near-surface EM data that can be compared with results of previous surveys to monitor changes in soils and local hydrology over time as the produced water is discharged through SDI. The focus of this investigation is the Headgate Draw SDI site, situated adjacent to the Powder River near the confluence of a major tributary, Crazy Woman Creek, in Johnson County, Wyoming. The SDI system was installed during the summer of 2008 and began operation in October of 2008. Ground, borehole, and helicopter electromagnetic (HEM) conductivity surveys were conducted at the site prior to the installation of the SDI system. After the installation of the subsurface drip irrigation system, ground EM surveys have been performed quarterly (weather permitting). The geophysical surveys map the heterogeneity of the near-surface geology and hydrology of the study area. The geophysical data are consistent between surveys using different techniques and between surveys carried out at different times from 2007 through 2011. This paper summarizes geophysical results from the 4-year monitoring study of the SDI system.

Wyoming

Mapping and measuring land-cover characteristics of New River Basin, Tennessee, using Landsat digital tapes

Land-cover information is needed to select subbasins within the New River basin, Tennessee, for the study of hydrologic processes and also is needed to transfer study results to other sites affected by coal mining. It was believed that data recorded by the first Earth Resources Technology Satellite (Landsat-1) could be processed to yield the needed land-cover information. This study demonstrates that digital computer processing of the spectral information contained in each picture element (pixel) of 1.1 acres (4,500 m2) can produce maps and tables of the areal extent of selected land-cover categories. The distribution of water, rock, agricultural areas, evergreens, bare earth, hardwoods, and uncategorized areas, is portrayed on a map of the entire New River basin (1:62,500 scale) and on 15 quadrangles (1:24,000 scale). Although some categories are a mixture of land-cover types, they portray the predominant component named. Tables quantify the area of each category and indicate that agriculture covers 5 percent of the basin, evergreens cover 7 percent, bare earth covers 6 percent, three categories of hardwoods cover 81 percent, and water, rock, and uncategorized areas each cover less than 1 percent of the basin.

Tennessee

Influence of rock composition on the geochemistry of stream and spring waters from mountainous watersheds in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado

The ranges of geochemical baselines for stream and spring waters were determined and maps were constructed showing acid-neutralizing capacity and potential release of total dissolved solids for streams and spring waters for watersheds underlain by each of ten different rock composition types in the Gunnison, Uncompahgre, and Grand Mesa National Forests, Colorado (GMUG). Water samples were collected in mountainous headwater watersheds that have comparatively high precipitation and low evapotranspiration rates and that generally lack extensive ground-water reservoirs. Mountainous headwaters react quickly to changes in input of water from rain and melting snow and they are vulnerable to anthropogenic impact. Processes responsible for the control and mobility of elements in the watersheds were investigated. The geochemistry of water from the sampled watersheds in the GMUG, which are underlain by rocks that are relatively unmineralized, is compared to the geochemistry of water from the mineralized Redcloud Peak area. The water with the highest potential for release of total dissolved solids is from watersheds that are underlain by Paleozoic sedimentary rocks; that high potential is caused primarily by gypsum in those rocks. Water that has the highest acid-neutralizing capacity is from watersheds that are underlain by Paleozoic sedimentary rocks. The water from watersheds underlain by the Mancos Shale has the next highest acid-neutralizing capacity. Water that has the lowest acid-neutralizing capacity is from watersheds that are underlain by Tertiary ash-flow tuff. Tertiary sedimentary rocks containing oil shale, the Mesavede Formation containing coal, and the Mancos Shale all contain pyrite with elevated metal contents. In these mountainous head-water areas, water from watersheds underlain by these rock types is only slightly impacted by oxidation of pyrite, and over-all it is of good chemical quality. These geochemical baselines demonstrate the importance of rock composition in determining the types of waters that are in the headwater areas. The comparison of these geochemical baselines to later geochemical base-lines will allow recognition of any significant changes in water quality that may occur in the future.

Colorado

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Geology of anthracite in the southwestern part of the Mount Carmel quadrangle, Pennsylvania

This report is the second to be prepared as a result of a geologic investigation of the anthracite fields of Pennsylvania begun after consultation with the Bureau of Topographic and Geologic Surveys of the Commonwealth of Pennsylvania. This report and others in preparation will show (1) the location of coal outcrops, (2) the depth, pitch, and other structural features of representative coal beds, (3) the natural and artificial barriers between mines and the structural relationships between the various coal basins, and (4) the correlation of the beds, the stratigraphic intervals between them, and the thickness, continuity, and other physical characteristics of the coal. The reports will bring up to date and amplify the Grand Atlas of the Anthracite Fields published by the Second Geological Survey of Pennsylvania in 1884-1885, and the reports that supplemented that atlas. It is expected that the reports will aid operators who are mining either on the surface or underground, or who are formulating plans for control of mine water. It is hoped that these reports will also direct attention to overlooked or unutilized reserves of coal. A preceding report described the west-central part of the Mount Carmel quadrangle (Rothrock et al., 1950) and it is planned to publish similar reports on other unit areas as they are completed.

Pennsylvania

Hydrology of area 46, Northern Great Plains and Rocky Mountain coal provinces, North Dakota

This report is one of a series that describes the hydrology of coal provinces nationwide. The Northern Great Plains and Rocky Mountain Coal Provinces are divided into 20 separate reporting areas which are numbered 43 to 62. This report provides general hydrologic information for Area 46 using a brief text with accompanying maps, charts, or graphs. This information may be used to describe the hydrology of the general area of any existing or proposed mine. Some of the more obvious hydrologic problems of coal development that will need to be addressed before development are disruption of aquifers and potential contamination of streams, aquifers, and the atmosphere. Area 46 is in northwestern North Dakota and is composed of parts or all of 14 hydrologic units based on surface-water drainage basins. The area is drained by the Missouri and Souris Rivers. Lignite-bearing rocks of late Paleocene age underlie nearly all of Area 46. The thickest and most continuous lignite beds occur in the Sentinel Butte and Tongue River Members of the Fort Union Formation. Alluvial deposits and a veneer of glacial drift of late Pleistocene age overlie the lignite-bearing rocks. The climate of the area is semiarid. Mean annual precipitation ranges from 13.9 to 17.8 inches. Mean annual temperatures range from 37.7°F at Bowbells to 40.9°F at Williston. Mean monthly temperatures at Williston range from 8.3°F to 70°F. The growing season is about 125 days. A fairly comprehensive data base for streamflow and water quality in streams is available for Area 46. Many of the small-stream monitoring sites have been operated during the last few years to provide a data base before coal development. With the exception of the Missouri River, which is controlled by several dams, both the quantity and quality of water varies greatly in all streams. A ground-water observation network for water levels and water quality has been established through county ground-water resource investigations and other ground-water studies and provides an adequate data base. Three activities within the U.S. Geological Survey identify and provide access to hydrologic data. These are the National Water-Data Exchange (NAWDEX), the National Water-Data Storage and Retrieval System (WATSTORE), and the Office of Water-Data Coordination (OWDC).

Open-File Report

Potentiometric surface and water quality in the Principal Aquifer, Mississippian Plateaus region, Kentucky

The Mississippian Plateaus region is the outcrop area of rocks of Mississippian age which extends as a broad arcuate band around the Western Coal Field in westcentral Kentucky. Much of the area is characterized by plains of low relief containing numerous sinkholes, subsurface drainage, and a low density of surface streams. The principal aquifer consists of a thick sequence of limestones extending downward stratigraphically from the base of the Chesterian Series to the black shales at the top of the Devonian rocks. Well yields range from several gallons per minute to as much as 500 gallons per minute in some karst areas where secondary openings are well developed. The potentiometric map indicates that ground-water movement generally conforms to the surface drainage pattern. The actual direction of movement varies from river basin to river basin. Most water from the principal aquifer is a calcium magnesium bicarbonate type and is generally good relative to current drinking water standards. The lower St Louis Limestone, in places, yields a calcium magnesium sulfate water that is corrosive and has a strong hydrogen sulfide odor. The karst areas of the principal aquifer are vulnerable to contamination because of the well-developed subsurface drainage. Urban areas, industries, and agriculture are sources of contaminants that can be easily flushed into the ground-water system. (USGS)

Water-Resources Investigations Report

Use of digital land-cover data from the Landsat satellite in estimating streamflow characteristics in the Cumberland Plateau of Tennessee

Characteristics of Streamflow at ungaged sites in coal-mining areas of the Cumberland Plateau may be estimated with regression equations that relate streamflow characteristics to the physiographic and climatic characteristics of the corresponding drainage basins. An experiment was performed to compare the accuracy of equations using basin characteristics derived from maps and climatological records (control group equations) with the accuracy of equations using basin characteristics derived from digital processing of Landsat spectral data as well as maps and climatological records (experimental group equations). Results of this experiment show that (with the exception of low flows and four of six annual peak logarithms) drainage area can explain more than 90 percent of the variance in all streamflow characteristics in both groups of equations. Seventeen of 39 experimental group equations that have two basin characteristics each are different from the corresponding control group equations. Five of the 17 differing experimental group equations have no counterpart in the control group because of lack of significance in control group basin characteristics, seven are slightly more accurate, and five are not measurably different in accuracy. When the equations in both groups are arranged into six flow categories, there is no substantial difference in accuracy between equations using basin characteristics derived from maps and climatological records (control group) and equations using basin characteristics derived from Landsat tapes as well as maps and climatological records (experimental group) for this particular study area, the Cumberland Plateau of Tennessee.

Tennessee

Hydrogeologic atlas of aquifers in Indiana

Aquifers in 12 water-management basins of Indiana are identified in a series of 104 hydrogeologic sections and 12 maps that show the thickness and configuration of aquifers. The vertical distribution of water-bearing units and a generalized potentiometric profile are shown along 3,500 miles of section lines that were constructed from drillers' logs of more than 4,200 wells. The horizontal scale of the sections is 1:125,000. Maps of aquifers showing the areal distribution of each aquifer type were drawn at a scale of 1:500,000. Unconsolidated aquifers are the most widely used aquifers in Indiana and include surficial, buried, and discontinuous layers of sand and gravel. Most of the surficial sand and gravel is in large outwash plains in northern Indiana and along the major rivers. Buried sand and gravel aquifers are interbedded with till deposits in much of the northern two-thirds of Indiana. Discontinuous sand and gravel deposits are present as isolated lenses, primarily in glaciated areas. The bedrock aquifers generally have lower yields than most of the sand and gravel aquifers; however, bedrock aquifers are areally widespread and are an important source of water. Bedrock aquifer types consist of carbonates; sandstones; complexly interbedded sandstones, siltstones, shales, limestones, and coals; and an upper weathered zone in low permeability rock. Carbonate aquifers underlie about one-half of Indiana and are the most productive of the bedrock aquifers. The other principal bedrock aquifer type, sandstone, underlies large areas in the southwestern one-fifth of Indiana. No aquifer is known to be present in the southeastern corner of Indiana.

Water-Resources Investigations Report

Geologic studies in Alaska by the U.S. Geological Survey, 1997

The eight papers that follow continue the series of U.S. Geological Survey (USGS) reports on investigations in the geologic sciences in Alaska. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from all parts of the State (fig. 1), which serves to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics Resources, Geologic Framework, and Environment and Climate. Such an organization is intended to reflect the scope and objectives of USGS programs currently active in Alaska. Resource papers include one that presents detailed observations from a Mississippian Zn-Pb-Cu-Ag occurrence in the Brooks Range (Werdon). Mineralogic, chemical, and isotopic data provide the basis for a proposed relationship between this vein-breccia deposit and the shale-hosted massive sulfide deposit type, which includes the active Red Dog mine in the western Brooks Range. Also included under the topic of Resources is a paper that presents geochemical and isotopic data from the Greens Creek and Woewodski Island volcanogenic massive sulfide deposits in southeastern Alaska (Newberry and Brew). The depositional environment and sedimentological setting of Tertiary coal beds in the Matanuska and Susitna Valleys is the focus of a third paper under the topic of Resources (Flores and others). Geologic Framework studies provide background information that is the scientific basis for present and future studies of the environment, mineral and energy resources, paleoclimate, and hazards in Alaska. One paper presents the results of sedimentologic and paleontologic comparisons of lower Paleozoic, deep-water-facies rock units in central Alaska (Dumoulin and others). The authors show which of these units are likely to correlate with one another, suggest likely source regions, and provide a structural restoration of units that have been fragmented by large fault motions. A second framework paper provides a map, rock descriptions, and chemical compositions of volcanic rocks in a newly recognized, geologically young volcanic center in the Aleutian volcanic arc (Hildreth and others). A third paper presents an interesting summary of gravity changes that occurred in south-central Alaska during the great earthquake of 1964 and for the following 25 years (Barnes). Gravity changes correlate with land-elevation changes in some cases, but not in others, which means that different processes are responsible for the gravity changes.

Alaska

Selected annotated bibliography of the geology of uraniferous and radioactive native bituminous substances, exclusive of coals, in the United States

Native bituminous substances are divided into two groups, 1) bitumens and, 2) pyrobitumens. Bitumens are composed principally of hydrocarbons substantially free from oxygenated bodies, are fusible, and are soluble in carbon disulfide. Native bitumens occur in liquid and solid forms. The native liquid bitumens include all petroleums or crude oils. Native solid bitumens include native waxes such as ozocerite, asphalts or petroleum tars, and asphaltites such as gilsonite and grahamite. Pyrobitumens are composed principally of hydrocarbons which may contain oxygenated bodies. They are infusible and are insoluble, or nearly insoluble, in carbon disulfide. Native pyrobitumens are divided into an oxygen-containing group including peats, lignites, and coals, and an essentially oxygen-free, asphaltic group including such substances as wurtzilite, albertite, impsonite, and ingramite. Thucholites, which are carbonaceous substances that may contain uranium, thorium, and rare earths, commonly are considered to be pyrobitumens. Their compositions are variable and may fall into either the oxygen-containing or oxygen-free group. All varieties of native bituminous substances may be associated with mineral matter. The nomenclature of bitumens and pyrobitumens is used very loosely in the literature. This circumstance arises from the difficulty in recognizing many of these substances by visual examination, and because many of them can be identified accurately only by chemical methods. Inasmuch as some of the chemical procedures are time-consuming and satisfactory analytical methods have not been devised for all these substances, geologists generally have not obtained precise identifications but rather have used names that appeared most appropriate to the circumstances. It is expected that future research will show many substances called "asphaltite," "thucholite," etc., to be incorrectly identified. The nomenclature used by the authors of the various references of this bibliography is followed without deviation or further discussion. The stratigraphic nomenclature also is that used by the authors. In this bibliography emphasis is placed on reports dealing with the uranium contents and radioactivity of native bituminous substances rather than on mineralogical and chemical studies of these substances. The distribution of the substances described in the references is shown on the accompanying map. The indicated presence of these substances does not infer that they contain sufficient radioactive elements to constitute ores.

Trace Elements Investigations

Summary of the San Juan structural basin regional aquifer-system analysis, New Mexico, Colorado, Arizona, and Utah

Ground-water resources are the only source of water in most of the San Juan structural basin and are mainly used for municipal, industrial, domestic, and stock purposes. Industrial use increased dramatically during the late 1970's and early 1980's because of increased exploration and development of uranium and coal resources. The San Juan structural basin is a northwest-trending, asymmetric structural depression at the eastern edge of the Colorado Plateau. The basin contains as much as 14,000 feet of sedimentary rocks overlying a Precambrian basement complex. The sedimentary rocks dip basinward from the basin margins toward the troughlike structural center, or deepest part of the basin. Rocks of Triassic age were selected as the lower boundary for the study. The basin is well defined by structural boundaries in many places with structural relief of as much as 20,000 feet reported. Faulting is prevalent in parts of the basin with displacement of several thousand feet along major faults. The regional aquifers in the basin generally are coincident with the geologic units that have been mapped. Data on the hydrologic properties of the regional aquifers are minimal. Most data were collected on those aquifers associated with uranium and coal resource production. These data are summarized in table format in the report. The regional flow system throughout most of the basin has been affected by the production of oil or gas and subsequent disposal of produced brine. To date more than 26,000 oil- or gas- test holes have been drilled in the basin, the majority penetrating no deeper than the bottom of the Cretaceous rocks. The general water chemistry of the regional aquifers is based on available data. The depositional environments are the major factor controlling the quality of water in the units. The dominant ions are generally sodium, bicarbonate, and sulfate. A detailed geochemical study of three sandstone aquifers--Morrison, Dakota, and Gallup--was undertaken in the northwestern part of the study area. Results of this study indicate that water chemistry changed in individual wells over short periods of time, not expected in a regional flow system. The chemistry of the water is affected by mixing of recharge, ion filtrate, or very dilute ancient water, and by leakage of saline water. The entire system of ground-water flow and its controlling factors has been defined as the conceptual model. A steady-state, three-dimensional ground-water flow model was constructed to simulate modern predevelopment flow in the post-Jurassic rocks of the regional flow system. In the ground-water flow model, 14 geologic units or combinations of geologic units were considered to be regional aquifers, and 5 geologic units or combinations of geologic units were considered to be regional confining units. The model simulated flow in 12 layers (hydrostratigraphic units) and used harmonic-mean vertical leakance to indirectly simulate aquifer connection across 3 other hydrostratigraphic confining units in addition to coupling the 12 units.

Water-Resources Investigations Report

Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs

This report, prepared in cooperation with the Pennsylvania Department of Environmental Protection (PaDEP), the Eastern Pennsylvania Coalition for Abandoned Mine Reclamation, and the Dauphin County Conservation District, provides estimates of water budgets and groundwater volumes stored in abandoned underground mines in the Western Middle Anthracite Coalfield, which encompasses an area of 120 square miles in eastern Pennsylvania. The estimates are based on preliminary simulations using a groundwater-flow model and an associated geographic information system that integrates data on the mining features, hydrogeology, and streamflow in the study area. The Mahanoy and Shamokin Creek Basins were the focus of the study because these basins exhibit extensive hydrologic effects and water-quality degradation from the abandoned mines in their headwaters in the Western Middle Anthracite Coalfield. Proposed groundwater withdrawals from the flooded parts of the mines and stream-channel modifications in selected areas have the potential for altering the distribution of groundwater and the interaction between the groundwater and streams in the area. Preliminary three-dimensional, steady-state simulations of groundwater flow by the use of MODFLOW are presented to summarize information on the exchange of groundwater among adjacent mines and to help guide the management of ongoing data collection, reclamation activities, and water-use planning. The conceptual model includes high-permeability mine voids that are connected vertically and horizontally within multicolliery units (MCUs). MCUs were identified on the basis of mine maps, locations of mine discharges, and groundwater levels in the mines measured by PaDEP. The locations and integrity of mine barriers were determined from mine maps and groundwater levels. The permeability of intact barriers is low, reflecting the hydraulic characteristics of unmined host rock and coal. A steady-state model was calibrated to measured groundwater levels and stream base flow, the latter at many locations composed primarily of discharge from mines. Automatic parameter estimation used MODFLOW-2000 with manual adjustments to constrain parameter values to realistic ranges. The calibrated model supports the conceptual model of high-permeability MCUs separated by low-permeability barriers and streamflow losses and gains associated with mine infiltration and discharge. The simulated groundwater levels illustrate low groundwater gradients within an MCU and abrupt changes in water levels between MCUs. The preliminary model results indicate that the primary result of increased pumping from the mine would be reduced discharge from the mine to streams near the pumping wells. The intact barriers limit the spatial extent of mine dewatering. Considering the simulated groundwater levels, depth of mining, and assumed bulk porosity of 11 or 40 percent for the mined seams, the water volume in storage in the mines of the Western Middle Anthracite Coalfield was estimated to range from 60 to 220 billion gallons, respectively. Details of the groundwater-level distribution and the rates of some mine discharges are not simulated well using the preliminary model. Use of the model results should be limited to evaluation of the conceptual model and its simulation using porous-media flow methods, overall water budgets for the Western Middle Anthracite Coalfield, and approximate storage volumes. Model results should not be considered accurate for detailed simulation of flow within a single MCU or individual flooded mine. Although improvements in the model calibration were possible by introducing spatial variability in permeability parameters and adjusting barrier properties, more detailed parameterizations have increased uncertainty because of the limited data set. The preliminary identification of data needs includes continuous streamflow, mine discharge rate, and groundwater levels in the mines and adjacent areas. Data collected whe

Pennsylvania

Principal reference section for part of the Eocene Ghazij Formation, Gishtari Nala area, Mach coal field, Balochistan, Pakistan

The information presented on this sheet was collected as part of a joint U.S. Geological Survey-Geological Survey of Pakistan program sponsored by the U.S. Agency for International Development. As a project within this program, the coal-bearing Ghazij Formation (Eocene) was investigated in the northeastern part of Balochistan east and south of the provincial capital of Quetta. Strata exposed in this area range in age from Permian to Holocene and crop out as a belt of folded and thrusted rocks that form a southeast-facing orocline. In this region of Pakistan, the Ghazij can usually be divided into three parts. The lower part is the thickest (probably more than 1,000 m) and consists of gray-weathering calcareous mudrock (shale, mudstone, and impure claystone) and a few tabular bodies of fine-to medium-grained calcareous sandstone. The middle part (27-300 m) consists of gray-weathering calcareous mudrock and tabular to lenticular bodies of fine- to medium-grained calcareous sandstone; beds of carbonaceous shale and coal are common (in the Mach area, the middle part of the formation also contains numerous individual beds of muddy limestone). The upper part (as thick as 533 m) contains reddish-weathering calcareous mudrock that contains scattered lenticular bodies of fine-to medium-grained calcareous sandstone. Fossil plant debris is common in mudrock of the lower and middle parts of the Ghazij and bivalves and gastropods are common in the middle part of the formation; the upper part of the Ghazij is usually unfossiliferous. Underlying the Ghazij are the carbonate rocks of the Paleocene Dungan Formation (or its equivalent), and overlying the Ghazij are the mostly carbonate rocks of the Eocene Kirthar Formation (or its equivalent). Both contacts can be conformable or unconformable. All of the pre-Neogene rocks in Balochistan are greatly deformed by the collision of India and Asia. The Ghazij is especially susceptible to regional compressional tectonics because it contains large amounts of shale and is sandwiched between two thick carbonate units. As a result, bedding-plane faults and isoclinal folds are very common. As part of our study of the Ghazij Formation, five stratigraphic sections were measured: one near Pir Ismail Ziarat, one in the Sor Range, two in the vicinity of Mach, and one near Johan. Each area's section is published separately.

Balochistan

Availability and Quality of Water from Underground Coal Mines in Johnson and Martin Counties, Kentucky

This report provides water users with detailed information on the location, quantity, and quality of water available from underground coal mines in the Breathitt Formation of Pennsylvanian age in part of eastern Kentucky. The principal coal seams mined are the Van Lear in Johnson County and the Alma in Martin County. Coal mines that contained water were located by field inventory and coal-mine maps. The principal factors that affect the occurrence of water in coal mines are the size of the recharge area overlying the mine, the intensity and duration of precipitation, and the altitude of the mine relative to that of the nearest perennial stream. Ten above-drainage mines (that is, mines at higher elevations than that of the nearest perennial stream) are considered potential sources of water. Discharge from these mines ranged from 12 to 1,700 gallons per minute. The highest sustained discharge from a mine ranged from 750 to 1,200 gallons per minute. The water in coal mines is part of the hydrologic system and varies seasonally with precipitation. Annual discharge from most above-drainage mines ranged from 3 to 10 percent of annual precipitation on the 1and-surface area above the mine. Eight below-drainage mines are considered potential sources of water. Two were test-pumped at rates of 560 to 620 gallons per minute for as long as 6 hours. After test pumping the Warfield Mining No. 1 mine during September 1977 and March 1978, the recovery (or recharge) rates were significantly different. In September, the recharge rate was about 1,150 gallons per minute, but in March the recharge rate was 103,500 gallons per minute. This difference reflects the seasonal variations in the amount of water available to the ground-water system. Estimates of water stored in below-drainage mines ranged from 22 to 1,462 million gallons. This storage represents a safety factor sufficient to provide water through periods of limited recharge to the mine. Most mine water is of the calcium magnesium sulfate type. In general, water from below-drainage mines had lower concentrations of dissolved constituents and higher pH than water from mines above drainage. The hardness of water ranged from soft to very hard and pH ranged -from 3.1 to 8.0 units. Dissolved iron ranged from 0.01 to 64 milligrams per liter. Phenol concentrations in water from eight coal mines ranged from 0 to 5 micrograms per liter. There seems to be a significant difference in the chemical quality of water from above- and below-drainage mines. The concentration of most constituents was lower in water from below-drainage mines than it was from above-drainage mines. The better quality water from below-drainage mines may reflect (1) lower mineralization resulting from less atmospheric oxygen available to react with pyrite or, (2) the result of sampling only the upper zones of water in below-drainage mines where the water has been diluted by less mineralized surface water or inflow or recharge.

Water-Resources Investigations Report

Summary of Hydrologic Data for the Tuscarawas River Basin, Ohio, with an Annotated Bibliography

The Tuscarawas River Basin drains approximately 2,600 square miles in eastern Ohio and is home to 600,000 residents that rely on the water resources of the basin. This report summarizes the hydrologic conditions in the basin, describes over 400 publications related to the many factors that affect the groundwater and surface-water resources, and presents new water-quality information and a new water-level map designed to provide decisionmakers with information to assist in future data-collection efforts and land-use decisions. The Tuscarawas River is 130 miles long, and the drainage basin includes four major tributary basins and seven man-made reservoirs designed primarily for flood control. The basin lies within two physiographic provinces-the Glaciated Appalachian Plateaus to the north and the unglaciated Allegheny Plateaus to the south. Topography, soil types, surficial geology, and the overall hydrology of the basin were strongly affected by glaciation, which covered the northern one-third of the basin over 10,000 years ago. Within the glaciated region, unconsolidated glacial deposits, which are predominantly clay-rich till, overlie gently sloping Pennsylvanian-age sandstone, limestone, coal, and shale bedrock. Stream valleys throughout the basin are filled with sands and gravels derived from glacial outwash and alluvial processes. The southern two-thirds of the basin is characterized by similar bedrock units; however, till is absent and topographic relief is greater. The primary aquifers are sand- and gravel-filled valleys and sandstone bedrock. These sands and gravels are part of a complex system of aquifers that may exceed 400 feet in thickness and fill glacially incised valleys. Sand and gravel aquifers in this basin are capable of supporting sustained well yields exceeding 1,000 gallons per minute. Underlying sandstones within 300 feet of the surface also provide substantial quantities of water, with typical well yields of up to 100 gallons per minute. Although hydraulic connection between the sandstone bedrock and the sands and gravels in valleys is likely, it has not been assessed in the Tuscarawas River Basin. In 2001, the major land uses in the basin were approximately 40 percent forested, 39 percent agricultural, and 17 percent urban/residential. Between 1992 and 2001, forested land use decreased by 2 percent with correspondingly small increases in agricultural and urban land uses, but from 1980 to 2005, the 13-county area that encompasses the basin experienced a 7.1-percent increase in population. Higher population density and percentages of urban land use were typical of the northern, headwaters parts of the basin in and around the cities of Akron, Canton, and New Philadelphia; the southern area was rural. The basin receives approximately 38 inches of precipitation per year that exits the basin through evapotranspiration, streamflow, and groundwater withdrawals. Recharge to groundwater is estimated to range from 6 to 10 inches per year across the basin. In 2000, approximately 89 percent of the 116 million gallons per day of water used in the basin came from groundwater sources, whereas 11 percent came from surface-water sources. To examine directions of groundwater flow in the basin, a new dataset of water-level contours was developed by the Ohio Department of Natural Resources. The contours were compiled on a map that shows that groundwater flows from the uplands towards the valleys and that the water-level surface mimics surface topography; however, there are areas where data were too sparse to adequately map the water-level surface. Additionally, little is known about deep groundwater that may be flowing into the basin from outside the basin and groundwater interactions with surface-water bodies. Many previous reports as well as new data collected as part of this study show that water quality in the streams and aquifers in the Tuscarawas River Basin has been degraded by urban, suburban, and rural

Scientific Investigations Report

Hydrogeology and simulation of groundwater flow in the Arbuckle-Simpson aquifer, south-central Oklahoma

The Arbuckle-Simpson aquifer in south-central Oklahoma provides water for public supply, farms, mining, wildlife conservation, recreation, and the scenic beauty of springs, streams, and waterfalls. Proposed development of water supplies from the aquifer led to concerns that large-scale withdrawals of water would cause decreased flow in rivers and springs, which in turn could result in the loss of water supplies, recreational opportunities, and aquatic habitat. The Oklahoma Water Resources Board, in collaboration with the Bureau of Reclamation, the U.S. Geological Survey, Oklahoma State University, and the University of Oklahoma, studied the aquifer to provide the Oklahoma Water Resources Board the scientific information needed to determine the volume of water that could be withdrawn while protecting springs and streams. The U.S. Geological Survey, in coopertion with the Oklahoma Water Resources Board, did a study to describe the hydrogeology and simulation of groundwater flow of the aquifer. The outcrop of the Arbuckle-Simpson aquifer covers an area of about 520 square miles in Carter, Coal, Johnston, Murray, and Pontotoc Counties. Three subdivisions of the aquifer outcrop were designated for this study: the eastern, central, and western Arbuckle-Simpson aquifer. This study emphasized the eastern Arbuckle-Simpson aquifer because it is the largest part of the aquifer by area and volume; most groundwater withdrawals are from the eastern Arbuckle-Simpson aquifer; and the largest (by flow) streams and springs sourced from the aquifer are on the eastern Arbuckle-Simpson aquifer. The aquifer lies in an uplifted area commonly referred to as the Arbuckle Mountains, which is characterized by great thicknesses of mostly carbonate rocks, uplifts, folded structures, and large fault displacements. The Arbuckle-Simpson aquifer is contained in three major rock units of Late Cambrian to Middle Ordovician age: the Timbered Hills, Arbuckle, and Simpson Groups. The aquifer is underlain by low-permeability Cambrian and Proterozoic igneous and metamorphic rocks, and is confined above by younger sedimentary rocks of various ages in areas where the top of the aquifer dips below the surface. The major part of the Arbuckle-Simpson aquifer is the Arbuckle Group, which consists of as much as 6,700 feet of limestone in the western Arbuckle-Simpson aquifer, but which thins to an estimated 3,000 feet of predominantly dolostone in the eastern Arbuckle-Simpson aquifer. Water is obtained from cavities, solution channels, fractures, and intercrystalline porosity in the limestone and dolostone. The overlying Simpson Group, consisting of sandstones, shales, and limestones, is as much as 2,300 feet thick in the western Arbuckle-Simpson aquifer, but generally is less than 1,000 feet thick in the eastern aquifer. Water in the Simpson Group is stored primarily in pore spaces between the sand grains in the sandstones. A digital, three-dimensional geologic framework model was constructed to define the geometric relations of fault blocks and subsurface rock units across complex fault zones of the eastern Arbuckle-Simpson aquifer. Geologic data for the model were obtained from 126 drill holes; stratigraphic contacts and faults defined from a digitized version of the surface geologic map; and fault geometry, stratigraphic thickness, and information compiled from geologic and hydrogeologic reports and maps. Groundwater in the aquifer moves from areas of high head (altitude) to areas of low head along streams and springs. The potentiometric surface in the eastern Arbuckle-Simpson aquifer generally slopes from a topographic high from northwest to the southeast, indicating that regional groundwater flow is predominantly toward the southeast. Freshwater is known to extend beyond the aquifer outcrop near the City of Sulphur, Oklahoma, and Chickasaw National Recreation Area, where groundwater flows west from the outcrop of the eastern Arbuckle-Simpson aquifer and becomes confin

Scientific Investigations Report