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Placing prairie pothole wetlands along spatial and temporal continua to improve integration of wetland function in ecological investigations

We evaluated the efficacy of using chemical characteristics to rank wetland relation to surface and groundwater along a hydrologic continuum ranging from groundwater recharge to groundwater discharge. We used 27 years (1974–2002) of water chemistry data from 15 prairie pothole wetlands and known hydrologic connections of these wetlands to groundwater to evaluate spatial and temporal patterns in chemical characteristics that correspond to the unique ecosystem functions each wetland performed. Due to the mineral content and the low permeability rate of glacial till and soils, salinity of wetland waters increased along a continuum of wetland relation to groundwater recharge, flow-through or discharge. Mean inter-annual specific conductance (a proxy for salinity) increased along this continuum from wetlands that recharge groundwater being fresh to wetlands that receive groundwater discharge being the most saline, and wetlands that both recharge and discharge to groundwater (i.e., groundwater flow-through wetlands) being of intermediate salinity. The primary axis from a principal component analysis revealed that specific conductance (and major ions affecting conductance) explained 71% of the variation in wetland chemistry over the 27 years of this investigation. We found that long-term averages from this axis were useful to identify a wetland’s long-term relation to surface and groundwater. Yearly or seasonal measurements of specific conductance can be less definitive because of highly dynamic inter- and intra-annual climate cycles that affect water volumes and the interaction of groundwater and geologic materials, and thereby influence the chemical composition of wetland waters. The influence of wetland relation to surface and groundwater on water chemistry has application in many scientific disciplines and is especially needed to improve ecological understanding in wetland investigations. We suggest ways that monitoring in situ wetland conditions could be linked with evolving remote sensing technology to improve our ability to better inform decisions affecting wetland sustainability and provide periodic inventories of wetland ecosystem services to document temporal trends in wetland function and how they respond to contemporary land-use change.

North Dakota

Spectral reflectance and emissivity features of broad leaf plants: Prospects for remote sensing in the thermal infrared (8.0-14.0 μm)

Field emissivity measurements were made of leaves collected from nine deciduous tree and agricultural plant species. The data show, for the first time, that it is possible to discriminate subtle spectral emissivity features of leaves from the natural background emission. Under conditions of controlled measurement geometry (leaves arranged to cover a flat surface), the field emissivity spectra agreed fairly well with emissivity values calculated from laboratory directional hemispherical reflectance measurements. Spectral features associated with a variety of leaf chemical constituents, including cellulose, cutin, xylan, silica, and oleanolic acid could be identified in the field emissivity data. Structural aspects of leaf surfaces also influenced spectral behavior, notably the abundance of trichomes, as well as wax thickness and texture. Field spectral measurements made at increasing distances from natural plant canopies showed progressive attenuation of the spectral emissivity features. This attenuation is ascribed to increased multiple scattering that superimposes an opposite-in-sign reflected component on the emittance, and to the increasing number of canopy voids within the instrument field of view. Errors associated with the removal of atmospheric features and with the non-isotropic thermal characteristics of canopies also contribute to the loss of spectral information at greater measurement distances. In contrast to visible and short-wave infrared data, thermal infrared spectra of broad leaf plants show considerable spectral diversity, suggesting that such data eventually could be utilized to map vegetation composition. However, remotely measuring the subtle emissivity features of leaves still presents major challenges. To be successful, sensors operating in the 8–14 μm atmospheric window must have high signal-to-noise and a small enough instantaneous field of view to allow measurements of only a few leaf surfaces. Methods for atmospheric compensation, temperature–emissivity separation, and spectral feature analysis also will need to be refined to allow the recognition, and perhaps, exploitation of leaf thermal infrared spectral properties.

Virginia

Remote sensing of bush honeysuckle in the Middle Blue River Basin, Kansas City, Missouri, 2016–17

Amur honeysuckle bush ( Lonicera maackii ) and Morrow’s honeysuckle ( Lonicera morrowii ) are two of the most aggressively invasive species to become established throughout areas along the Blue River in metropolitan Kansas City, Missouri. These two large, spreading shrubs (locally referred to as bush honeysuckle in the Kansas City metropolitan area) colonize the understory, crowd out native plants, and may be allelopathic, producing a chemical that restricts growth of native species. Removal efforts have been underway for more than a decade by local conservation groups such as Bridging The Gap and Heartland Conservation Alliance, who are concerned with the loss of native species diversity associated with the spread of bush honeysuckle. Bush honeysuckle produces leaves early in the spring before almost all other vegetation and retains leaves late in the fall after almost all other species have lost their leaves. Appropriately timed imagery can be used during early spring and late fall to map the extent of bush honeysuckle. Using multispectral imagery collected in February 2016 and true color aerial imagery collected in March 2016, a coverage map of bush honeysuckle was made to investigate the extent of bush honeysuckle in a study area along the middle reach of the Blue River in the Kansas City metropolitan area in Jackson County, Missouri. The coverage map was further classified into unlikely, low-, and high-density bush honeysuckle density at a 30-foot cell size. The unlikely density class correctly predicted the absence and approximate density of bush honeysuckle for 86 percent of the field-verification points, the low-density class predicted the presence and approximate density with 73-percent confidence, and the high-density class was predicted with 67-percent confidence.

Missouri

Evidence for a diagenetic origin of Vera Rubin Ridge, Gale Crater, Mars: Summary and synthesis of Curiosity's exploration campaign

This paper provides an overview of the Curiosity rover's exploration at Vera Rubin ridge (VRR) and summarizes the science results. VRR is a distinct geomorphic feature on lower Aeolis Mons (informally known as Mount Sharp) that was identified in orbital data based on its distinct texture, topographic expression, and association with a hematite spectral signature. Curiosity conducted extensive remote sensing observations, acquired data on dozens of contact science targets, and drilled three outcrop samples from the ridge, as well as one outcrop sample immediately below the ridge. Our observations indicate that strata composing VRR were deposited in a predominantly lacustrine setting and are part of the Murray formation. The rocks within the ridge are chemically in family with underlying Murray formation strata. Red hematite is dispersed throughout much of the VRR bedrock, and this is the source of the orbital spectral detection. Gray hematite is also present in isolated, gray‐colored patches concentrated toward the upper elevations of VRR, and these gray patches also contain small, dark Fe‐rich nodules. We propose that VRR formed when diagenetic event(s) preferentially hardened rocks, which were subsequently eroded into a ridge by wind. Diagenesis also led to enhanced crystallization and/or cementation that deepened the ferric‐related spectral absorptions on the ridge, which helped make them readily distinguishable from orbit. Results add to existing evidence of protracted aqueous environments at Gale crater and give new insight into how diagenesis shaped Mars' rock record.

Journal of Geophysical Research: Planets

Ground-water recharge in the arid and semiarid southwestern United States

Ground-water recharge in the arid and semiarid southwestern United States results from the complex interplay of climate, geology, and vegetation across widely ranging spatial and temporal scales. Present-day recharge tends to be narrowly focused in time and space. Widespread water-table declines accompanied agricultural development during the twentieth century, demonstrating that sustainable ground-water supplies are not guaranteed when part of the extracted resource represents paleorecharge. Climatic controls on ground-water recharge range from seasonal cycles of summer monsoonal and winter frontal storms to multimillennial cycles of glacial and interglacial periods. Precipitation patterns reflect global-scale interactions among the oceans, atmosphere, and continents. Large-scale climatic influences associated with El Niño and Pacific Decadal Oscillations strongly, but irregularly, control weather in the study area, so that year-to-year variations in precipitation and ground-water recharge are large and difficult to predict. Proxy data indicate geologically recent periods of naturally occurring multidecadal droughts unlike any in the modern instrumental record. Any anthropogenically induced climate change will likely reduce ground-water recharge through diminished snowpack at higher elevations. Future changes in El Niño and monsoonal patterns, both crucial to precipitation in the study area, are highly uncertain in current models. Current land-use modifications influence ground-water recharge through vegetation, irrigation, and impermeable area. High mountain ranges bounding the study area—the San Bernadino Mountains and Sierra Nevada to the west, and the Wasatch and southern Colorado Rocky Mountains to the east—provide external geologic controls on ground-water recharge. Internal geologic controls stem from tectonic processes that led to numerous, variably connected alluvial-filled basins, exposure of extensive Paleozoic aquifers in mountainous recharge areas, and distinct modes of recharge in the Colorado Plateau and Basin and Range subregions. The chapters in this professional paper present (first) an overview of climatic and hydrogeologic framework (chapter A), followed by a regional analysis of ground-water recharge across the entire study area (chapter B). These are followed by an overview of site-specific case studies representing different subareas of the geographically diverse arid and semiarid southwestern United States (chapter C); the case studies themselves follow in chapters D–K. The regional analysis includes detailed hydrologic modeling within the framework of a high-resolution geographic-information system (GIS). Results from the regional analysis are used to explore both the distribution of ground-water recharge for mean climatic conditions as well as the influence of two climatic patterns—the El Niño-Southern Oscillation and Pacific Decadal Oscillation—that impart a high degree of variability to the hydrologic cycle. Individual case studies employ a variety of geophysical and geochemical techniques to investigate recharge processes and relate the processes to local geologic and climatic conditions. All of the case studies made use of naturally occurring tracers to quantify recharge. Thermal and geophysical techniques that were developed in the course of the studies are presented in appendices. The quantification of ground-water recharge in arid settings is inherently difficult due to the generally low amount of recharge, its spatially and temporally spotty nature, and the absence of techniques for directly measuring fluxes entering the saturated zone from the unsaturated zone. Deep water tables in arid alluvial basins correspond to thick unsaturated zones that produce up to millennial time lags between changes in hydrologic conditions at the land surface and subsequent changes in recharge to underlying ground water. Recent advances in physical, chemical, isotopic, and modeling techniques have fostered new types of recharge assessments. Chemical and isotopic techniques include an increasing variety of environmental tracers that are useful and robust. Physically based techniques include the use of heat as a tracer and computationally intensive geophysical imaging tools for characterizing hydrologic conditions in the unsaturated zone. Modeling-based techniques include spatially distributed water-budget computations using high-resolution remotely sensed and ground-based geographic data. Application of these techniques to arid and semiarid settings in the southwestern United States reveals distinct patterns of recharge corresponding to geologic setting, climatic and vegetative history, and land use. Analysis of recharge patterns shows that large expanses of alluvial basin floors are drying out under current climatic conditions, with little to no recharge to underlying ground water. Ground-water recharge occurs mainly beneath upland catchments in which thin soils overlie permeable bedrock, ephemeral channels in which flow may average only several hours per year, and active agricultural areas. The chapters in this professional paper represent a coordinated attempt to develop a better understanding of one of the Nation's most critical yet difficult-to-quantify renewable resources.

Professional Paper

Actinide abundances in ordinary chondrites

Measurements of 244 Pu fission Xe, U, Th, and light REE (LREE) abundances, along with modal petrographic determinations of phosphate abundances, were carried out on equilibrated ordinary chondrites in order to define better the solar system Pu abundance and to determine the degree of variation of actinide and LREE abundances. Our data permit comparison of the directly measured Pu/ U ratio with that determined indirectly as ( Pu / Nd ) × ( Nd / U ) assuming that Pu behaves chemically as a LREE. Except for Guareña, and perhaps H chondrites in general, Pu concentrations are similar to that determined previously for St. Séverin, although less precise because of higher trapped Xe contents. Trapped 130 Xe 136 Xe "> 130 Xe 136 Xe ratios appear to vary from meteorite to meteorite, but, relative to AVCC, all are similar in the sense of having less of the interstellar heavy Xe found in carbonaceous chondrite acid residues. The Pu/U and Pu/Nd ratios are consistent with previous data for St. Séverin, but both tend to be slightly higher than those inferred from previous data on Angra dos Reis. Although significant variations exist, the distribution of our Th/U ratios, along with other precise isotope dilution data for ordinary chondrites, is rather symmetric about the CI chondrite value; however, actinide/(LREE) ratios are systematically lower than the CI value. Variations in actinide or LREE absolute and relative abundances are interpreted as reflecting differences in the proportions and/or compositions of more primitive components (chondrules and CAI materials?) incorporated into different regions of the ordinary chondrite parent bodies. The observed variations of Th/U, Nd/U, or Ce/U suggest that measurements of Pu/U on any single equilibrated ordinary chondrite specimen, such as St. Séverin, should statistically be within ±20–30% of the average solar system value, although it is also clear that anomalous samples exist.

Geochimica et Cosmochimica Acta

Application of imaging spectroscopy for mineral exploration in Alaska: A study over porphyry Cu deposits in the eastern Alaska Range

The U.S. Geological Survey tested the utility of imaging spectroscopy (also referred to as hyperspectral remote sensing) as an aid to regional mineral exploration efforts in remote parts of Alaska. Airborne imaging spectrometer data were collected in 2014 over unmined porphyry Cu deposits in the eastern Alaska Range using the HyMap™ sensor. Maps of the distributions of predominant minerals, made by matching reflectance signatures in the remotely sensed data to reference spectra in the shortwave infrared region, do not uniquely discriminate individual rock units. However, they do highlight hydrothermal alteration associated with porphyry deposits and prospects hosted mostly within the Nabesna pluton. In and around porphyry Cu deposits at Orange Hill and Bond Creek, unique spectral signatures are related to variations in chlorite and white mica abundance and their chemical composition. This is best revealed in the longer-wavelength 2,200-nm Al-OH absorption feature positions in pixels spectrally dominated by white mica proximal to porphyry deposits. Similar spectral signatures of chlorite and white mica wavelength positions were also recognized away from the porphyry deposits; follow-up sampling identified these satellite areas to also contain Cu-Mo-Au mineralized rock. Our study confirms that airborne imaging spectroscopy has application for regional mineral exploration in exposed mountainous terrain in Alaska.

Alaska

Hyperspectral analysis of rocky surfaces on the Earth and other planetary systems: Chapter 27

This book is focused on studies of vegetation on Earth using hyperspectral remote sensing methods. However, it is appropriate to extend the application of these methods out to other rocky bodies in our Solar System for a variety of reasons. First, minerals, soils, and rocks form the substrate on which vegetation grows on Earth. Compositional analyses of these components with hyperspectral data provide essential background information for distinguishing, identifying, and removing their effects on vegetation spectra. Second, variation in distribution, chemical and physical properties among soil and rock, has been demonstrated to have a significant effect on factors such as moisture retention, dust production, and the presence and distribution of biological species ranging from bacteria, fungi, grasses, shrubs, trees, and small mammals to humans [1]. These factors in turn can have profound influences on human health.

Book chapter

Remote sensing studies of the Dionysius region of the Moon

The Dionysius region is located near the western edge of Mare Tranquillitatis and is centered on Dionysius crater, which exhibits a well-developed dark ray system. Proposed origins for these dark rays included impact melt deposits and dark primary ejecta. The region also contains extensive deposits of Cayley-type light plains. Clementine multispectral images and a variety of spacecraft photography were utilized to investigate the composition and origin of geologic units in the Dionysius region. The portions of the dark rays for which spectral and chemical data were obtained are composed of mare debris contaminated with minor amounts of highland material. Both five-point spectra and values of the optical maturity (OMAT) parameter indicate that the dark rays are dominated by mare basalts, not glassy impact melts. The high-albedo rays associated with Dionysius exhibit FeO and TiO2 values that are lower than those of the adjacent dark ray surfaces and OMAT values that indicate that bright ray surfaces are not fully mature. The high-albedo rays are bright largely because of the contrast in albedo between ray material containing highlands-rich ejecta and the adjacent mare-rich surfaces. The mafic debris ejected by Dionysius was derived from a dark, iron-rich unit exposed high on the inner wall of the crater. This layer probably represents a mare deposit that was present at the surface of the preimpact target site. With one possible exception, there is no evidence for buried mare basalts associated with Cayley plains in the region.

Journal of Geophysical Research E: Planets

Hyperspectral remote sensing of vegetation

Hyperspectral narrow-band (or imaging spectroscopy) spectral data are fast emerging as practical solutions in modeling and mapping vegetation. Recent research has demonstrated the advances in and merit of hyperspectral data in a range of applications including quantifying agricultural crops, modeling forest canopy biochemical properties, detecting crop stress and disease, mapping leaf chlorophyll content as it influences crop production, identifying plants affected by contaminants such as arsenic, demonstrating sensitivity to plant nitrogen content, classifying vegetation species and type, characterizing wetlands, and mapping invasive species. The need for significant improvements in quantifying, modeling, and mapping plant chemical, physical, and water properties is more critical than ever before to reduce uncertainties in our understanding of the Earth and to better sustain it. There is also a need for a synthesis of the vast knowledge spread throughout the literature from more than 40 years of research.

Book

Utah's geologic and geomorphic analogs to Mars—An overview for planetary exploration

Utah offers spectacular geologic features and valuable analog environments and processes for Mars studies. Horizontal strata of the Colorado Plateau are analogous to Mars because the overprint of plate tectonics is minimal, yet the effects of strong ground motion from earthquakes or impacts are preserved in the sedimentary record. The close proximity of analog environments and lack of vegetative cover are advantages for field and remote-sensing studies. Dry, desert climate and modern wind processes of Utah are comparable to Mars and its current surface. Analogs in Utah include eolian, sabkha and saline bodies, glacial, lacustrine, spring, alluvial, fluvial, delta, and outflow channel depositional environments, as well as volcanic landforms and impact craters. Analogous secondary processes producing modification features include: diagenetic concretions, weathering and soils, sinkholes, sapping, knobs and pinnacles, crusts and varnish, and patterned grounds. Utah's physical and chemical environments are analogous to conditions on Mars where water existed and could support microorganisms. The development of Mars includes: ancient and modern depositional records, burial and diagenesis, uplift and tectonic alteration, and modern sculpting or weathering of the surface exposures. Recent satellite images are providing unprecedented details that rival the outcrop scale. Analogs in Utah are prime field localities that can be utilized in planning future robotic and human missions to Mars, and for teaching the next generation of planetary explorers.

Utah

Water-quality conditions during low flow in the lower Youghiogheny River basin, Pennsylvania, October 5-7, 1998

In October 1998, a chemical synoptic survey was conducted by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, National Energy Technology Laboratory, in the Lower Youghiogheny River Basin in Pennsylvania to give a snapshot of present (1998) water quality during low-flow conditions. Water samples from 38 sites—12 mainstem sites, 22 tributaries, and 4 mine discharges that discharge directly to the Youghiogheny River—were used to identify sources of contaminants from mining operations. Specific conductance, water temperature, pH, and dissolved oxygen were measured in the field at each site and concentrations of major ions and trace elements were measured in the laboratory.z Unaccounted for gains and losses in streamflow were measured during the study. Unaccounted for losses in streamflow might be attributed to water loss through streambed fractures. Extensive mine tunnels are present in the basin and loss of water to these tunnels seems likely. Unaccounted for gains in streamflow may be from unmeasured tributaries or surface seeps, but most of the gains are suspected to come from artesian flow through fractures in the streambed from underground mine pools. Influent flows of rust-colored water were noted in some river sections. The pH values for all the samples collected during this survey were above 5.8, and most (33 of 38 samples) were above 7.0. Samples from the four mine-discharge sites also had pH values between 6.3 and 6.7. The lowest pH (5.8) was in a tributary, Galley Run. All 38 sampling sites had net alkalinity. The alkalinity load in the Youghiogheny River increased between Connellsville and McKeesport from 35 to 79 tons per day. Above Smithton, the measured alkalinity load in the Lower Youghiogheny River agreed well with the estimated alkalinity load. Below Smithton, measured alkalinity loads in the Lower Youghiogheny River are greater than calculated loads, resulting in unaccounted for gains in alkalinity. These gains are believed to be from seeps in the streambed. Approximately one-third of the load of total alkalinity in the Youghiogheny River at McKeesport is attributed to Sewickley Creek, which contributes 14 tons per day. Sulfate concentrations in the Youghiogheny River steadily increase from 33 milligrams per liter at Connellsville to 77 milligrams per liter near McKeesport. The measured concentrations of sulfate exceeded Pennsylvania water-quality standards at four tributary sites (Galley Run, Hickman Run, Sewickley Creek, and Gillespie Run) and all four mine-discharge sites but not at any main-stem sites. A large increase in sulfate load between West Newton and Sutersville can be attributed almost entirely to the contribution from Sewickley Creek (49 tons per day). Approximately 25 percent of the load measured between Connellsville and McKeesport is unaccounted for. These gains are believed to be from seeps in the streambed from underground mine pools. Similar patterns also were observed for loads of sodium, calcium, and magnesium. Unmeasured inputs from mine drainage are believed to be the source of these loads. Elevated concentrations (above background levels) of chemicals associated with drainage from coal-mining operations were measured in samples from tributaries, especially from Galley Run, Gillespie Run, and Sewickley Creek, and from the mine-discharge sites. The synoptic survey conducted for this study was successful in identifying generalized reaches of the Youghiogheny River where unaccounted for loads of constituents associated with mining activities are entering the river. However, the survey was not able to pinpoint the location of these loads. Remote-sensing techniques, such as thermal infrared imaging by the National Energy Technology Laboratory, could be useful for determining the precise locations of these inputs.

Water-Resources Investigations Report

Model for simulation of residual stress in rock

Rocks in mines, quarries, and many outcrops commonly show evidence of being under high stress. Saw cuts and drillholes close in, partly mined coal bursts violently, and pillars crush and rock spalls in mines even at moderate depths. Similarly, strong and massive rocks such as granite and sandstone naturally divide themselves into sheets that lie more or less parallel to their outward topographic form. The sheets may be either convex or concave. Thin plates of bare rock surfaces bow up and buckle. Such effects often cannot be explained by the obvious loads now acting on the rock, that is, by loads resulting from overburden, topographic irregularities, or stress concentration around openings. The stresses exceed those that would result from such loads. Two interpretations of such excess stresses have been made. In one, the stresses are assigned in origin to now active tectonic forces. In the other, they are regarded as leftover and locked in from some previous state at which higher pressures prevailed. These two sources may both operate and they generally cannot be distinguished easily in the field. There are other complicating sources of stress such as temperature gradients and chemical alteration. Nevertheless, some bodies of rock, by exfoliating, show evidence of high internal stress even though they are practically unweathered and so isolated topographically that the presence in them of significant stress due to exterior loads or active tectonic forces seems unlikely. Moreover, completely isolated rocks are known to change density shape, or size; to expand under constant compressive stress; and even to disintegrate without the intervention of weathering processes. The stresses involved here must be truly residual in the sense long used by metallurgists; that is, residual stresses in a body are those that remain, aside from the effect of gravity or temperature gradients, even after the boundaries are freed from loads. Residual stress within rock can exist only in a system of internally balanced forces. The existence of such balanced forces has been recognized for a long time--at least 180 years--to judge from an incomplete survey of the literature. Discussions have been presented more recently by Voight, Friedman, Emery, Price, Denkhaus, Kieslinger, and other engineers and geologists. Briefly, a simple version of the concept is that if a granite crystallizes at depth and is then unloaded by uplift and erosion, the compressed mineral grains cannot completely relax, owing to interlocking boundaries and mutual interference. A sandstone that becomes cemented while constituent grains are under high pressure cannot completely relax when cut free. Thus, a balance is achieved between forces of expansion in the interior of the crystalline grains and those of restraint at grain boundaries or in the cement.

Conference Paper

Influence of permafrost distribution on groundwater flow in the context of climate-driven permafrost thaw: Example from Yukon Flats Basin, Alaska, United States

Understanding the role of permafrost in controlling groundwater flow paths and fluxes is central in studies aimed at assessing potential climate change impacts on vegetation, species habitat, biogeochemical cycling, and biodiversity. Recent field studies in interior Alaska show evidence of hydrologic changes hypothesized to result from permafrost degradation. This study assesses the hydrologic control exerted by permafrost, elucidates modes of regional groundwater flow for various spatial permafrost patterns, and evaluates potential hydrologic consequences of permafrost degradation. The Yukon Flats Basin (YFB), a large (118,340 km 2 ) subbasin within the Yukon River Basin, provides the basis for this investigation. Model simulations that represent an assumed permafrost thaw sequence reveal the following trends with decreasing permafrost coverage: (1) increased groundwater discharge to rivers, consistent with historical trends in base flow observations in the Yukon River Basin, (2) potential for increased overall groundwater flux, (3) increased spatial extent of groundwater discharge in lowlands, and (4) decreased proportion of suprapermafrost (shallow) groundwater contribution to total base flow. These trends directly affect the chemical composition and residence time of riverine exports, the state of groundwater-influenced lakes and wetlands, seasonal river-ice thickness, and stream temperatures. Presently, the YFB is coarsely mapped as spanning the continuous-discontinuous permafrost transition that model analysis shows to be a critical threshold; thus, the YFB may be on the verge of major hydrologic change should the current permafrost extent decrease. This possibility underscores the need for improved characterization of permafrost and other hydrogeologic information in the region via geophysical techniques, remote sensing, and ground-based observations.

Alaska

Overview of the Mars Pathfinder Mission and assessment of landing site predictions

Chemical analyses returned by Mars Pathfinder indicate that some rocks may be high in silica, implying differentiated parent materials. Rounded pebbles and cobbles and a possible conglomerate suggest fluvial processes that imply liquid water in equilibrium with the atmosphere and thus a warmer and wetter past. The moment of inertia indicates a central metallic core of 1300 to 2000 kilometers in radius. Composite airborne dust particles appear magnetized by freeze-dried maghemite stain or cement that may have been leached from crustal materials by an active hydrologic cycle. Remote-sensing data at a scale of generally greater than ∼1 kilometer and an Earth analog correctly predicted a rocky plain safe for landing and roving with a variety of rocks deposited by catastrophic floods that are relatively dust-free.

Science

Plant phenolics and absorption features in vegetation reflectance spectra near 1.66 μm

Past laboratory and field studies have quantified phenolic substances in vegetative matter from reflectance measurements for understanding plant response to herbivores and insect predation. Past remote sensing studies on phenolics have evaluated crop quality and vegetation patterns caused by bedrock geology and associated variations in soil geochemistry. We examined spectra of pure phenolic compounds, common plant biochemical constituents, dry leaves, fresh leaves, and plant canopies for direct evidence of absorption features attributable to plant phenolics. Using spectral feature analysis with continuum removal, we observed that a narrow feature at 1.66 μm is persistent in spectra of manzanita, sumac, red maple, sugar maple, tea, and other species. This feature was consistent with absorption caused by aromatic C- H bonds in the chemical structure of phenolic compounds and non-hydroxylated aromatics. Because of overlapping absorption by water, the feature was weaker in fresh leaf and canopy spectra compared to dry leaf measurements. Simple linear regressions of feature depth and feature area with polyphenol concentration in tea resulted in high correlations and low errors (% phenol by dry weight) at the dry leaf ( r 2 = 0.95, RMSE = 1.0%, n = 56), fresh leaf ( r 2 = 0.79, RMSE = 2.1%, n = 56), and canopy ( r 2 = 0.78, RMSE = 1.0%, n = 13) levels of measurement. Spectra of leaves, needles, and canopies of big sagebrush and evergreens exhibited a weak absorption feature centered near 1.63 μm, short ward of the phenolic compounds, possibly consistent with terpenes. This study demonstrates that subtle variation in vegetation spectra in the shortwave infrared can directly indicate biochemical constituents and be used to quantify them. Phenolics are of lesser abundance compared to the major plant constituents but, nonetheless, have important plant functions and ecological significance. Additional research is needed to advance our understanding of the spectral influences of plant phenolics and terpenes relative to dominant leaf biochemistry (water, chlorophyll, protein/nitrogen, cellulose, and lignin).

International Journal of Applied Earth Observation

Developing integrated methods to address complex resource and environmental issues

Introduction This circular provides an overview of selected activities that were conducted within the U.S. Geological Survey (USGS) Integrated Methods Development Project, an interdisciplinary project designed to develop new tools and conduct innovative research requiring integration of geologic, geophysical, geochemical, and remote-sensing expertise. The project was supported by the USGS Mineral Resources Program, and its products and acquired capabilities have broad applications to missions throughout the USGS and beyond. In addressing challenges associated with understanding the location, quantity, and quality of mineral resources, and in investigating the potential environmental consequences of resource development, a number of field and laboratory capabilities and interpretative methodologies evolved from the project that have applications to traditional resource studies as well as to studies related to ecosystem health, human health, disaster and hazard assessment, and planetary science. New or improved tools and research findings developed within the project have been applied to other projects and activities. Specifically, geophysical equipment and techniques have been applied to a variety of traditional and nontraditional mineral- and energy-resource studies, military applications, environmental investigations, and applied research activities that involve climate change, mapping techniques, and monitoring capabilities. Diverse applied geochemistry activities provide a process-level understanding of the mobility, chemical speciation, and bioavailability of elements, particularly metals and metalloids, in a variety of environmental settings. Imaging spectroscopy capabilities maintained and developed within the project have been applied to traditional resource studies as well as to studies related to ecosystem health, human health, disaster assessment, and planetary science. Brief descriptions of capabilities and laboratory facilities and summaries of some applications of project products and research findings are included in this circular. The work helped support the USGS mission to “provide reliable scientific information to describe and understand the Earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life.” Activities within the project include the following: Spanned scales from microscopic to planetary; Demonstrated broad applications across disciplines; Included life-cycle studies of mineral resources; Incorporated specialized areas of expertise in applied geochemistry including mineralogy, hydrogeology, analytical chemistry, aqueous geochemistry, biogeochemistry, microbiology, aquatic toxicology, and public health; and Incorporated specialized areas of expertise in geophysics including magnetics, gravity, radiometrics, electromagnetics, seismic, ground-penetrating radar, borehole radar, and imaging spectroscopy. This circular consists of eight sections that contain summaries of various activities under the project. The eight sections are listed below: Laboratory Facilities and Capabilities, which includes brief descriptions of the various types of laboratories and capabilities used for the project; Method and Software Development, which includes summaries of remote-sensing, geophysical, and mineralogical methods developed or enhanced by the project; Instrument Development, which includes descriptions of geophysical instruments developed under the project; Minerals, Energy, and Climate, which includes summaries of research that applies to mineral or energy resources, environmental processes and monitoring, and carbon sequestration by earth materials; Element Cycling, Toxicity, and Health, which includes summaries of several process-oriented geochemical and biogeochemical studies and health-related research activities; Hydrogeology and Water Quality, which includes descriptions of innovative geophysical, remote-sensing, and geochemical research pertaining to hydrogeology and water-quality applications; Hazards and Disaster Assessment, which includes summaries of research and method development that were applied to natural hazards, human-caused hazards, and disaster assessments; and Databases and Framework Studies, which includes descriptions of fundamental applications of geophysical studies and of the importance of archived data.

Circular

Ecological benefits of integrative weed management of Melaleuca quinquenervia in Big Cypress National Preserve

The southern tip of North America coalesces into one of the world’s largest freshwater wetlands, the Everglades, Florida, USA. Though this region is much like an island, home to high biodiversity and endemism, it is also the site of a century of development and associated landscape-scale species invasions. Melaleuca quinquenervia (hereafter melaleuca), a tree native to tropical Australia, was planted extensively throughout south Florida as street trees, levee stabilizers, and later to reduce standing water in marshy areas. Through extensive cooperation with the United States Department of Agriculture’s Australian Biological Control Laboratory, several biological control agents were released, three of which later successfully established. Herein we examine evidence that plant community shifts determined from vegetation surveys and remotely sensed images reflect changes from melaleuca-dominated wetlands (before management) to native communities (after management). Melaleuca-dominated community types decreased from 1990 to 2020 by more than 99%. Vegetation surveys also reflect an increase in cypress wetlands, pinelands, and open water wetlands, all of which were dominated by melaleuca in previous decades. We also found the normalized difference vegetation index (NDVI) increased in melaleuca-invaded wetlands during peak infestations but decreased again after communities recovered to sawgrass-dominated wetlands. These responses are concomitant with the development of integrative management techniques for melaleuca that include mechanical, chemical, and biological control. Our results confirm previous findings that biological control likely augments conventional management methods by limiting recovery of invasive species.

Florida