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At least 73 records · Page 4Linked to original sources

Landscape-scale quantification of fire-induced change in canopy cover following mountain pine beetle outbreak and timber harvest

Across the western United States, the three primary drivers of tree mortality and carbon balance are bark beetles, timber harvest, and wildfire. While these agents of forest change frequently overlap, uncertainty remains regarding their interactions and influence on specific subsequent fire effects such as change in canopy cover. Acquisition of pre- and post-fire Light Detection and Ranging (LiDAR) data on the 2012 Pole Creek Fire in central Oregon provided an opportunity to isolate and quantify fire effects coincident with specific agents of change. This study characterizes the influence of pre-fire mountain pine beetle (MPB; Dendroctonus ponderosae ) and timber harvest disturbances on LiDAR-estimated change in canopy cover. Observed canopy loss from fire was greater (higher severity) in areas experiencing pre-fire MPB (Δ 18.8%CC) than fire-only (Δ 11.1%CC). Additionally, increasing MPB intensity was directly related to greater canopy loss. Canopy loss was lower for all areas of pre-fire timber harvest (Δ 3.9%CC) than for fire-only, but among harvested areas, the greatest change was observed in the oldest treatments and the most intensive treatments [i.e., stand clearcut (Δ 5.0%CC) and combination of shelterwood establishment cuts and shelterwood removal cuts (Δ 7.7%CC)]. These results highlight the importance of accounting for and understanding the impact of pre-fire agents of change such as MPB and timber harvest on subsequent fire effects in land management planning. This work also demonstrates the utility of multi-temporal LiDAR as a tool for quantifying these landscape-scale interactions.

Oregon↗

Methylmercury production in and export from agricultural wetlands in California, USA: the need to account for physical transport processes into and out of the root zone

Concentration and mass balance analyses were used to quantify methylmercury (MeHg) loads from conventional (white) rice, wild rice, and fallowed fields in northern California's Yolo Bypass. These analyses were standardized against chloride to distinguish transport pathways and net ecosystem production (NEP). During summer, chloride loads were both exported with surface water and moved into the root zone at a 2:1 ratio. MeHg and dissolved organic carbon (DOC) behaved similarly with surface water and root zone exports at ~ 3:1 ratio. These trends reversed in winter with DOC, MeHg, and chloride moving from the root zone to surface waters at rates opposite and exceeding summertime root zone fluxes. These trends suggest that summer transpiration advectively moves constituents from surface water into the root zone, and winter diffusion, driven by concentration gradients, subsequently releases those constituents into surface waters. The results challenge a number of paradigms regarding MeHg. Specifically, biogeochemical conditions favoring microbial MeHg production do not necessarily translate to synchronous surface water exports; MeHg may be preserved in the soils allowing for release at a later time; and plants play a role in both biogeochemistry and transport. Our calculations show that NEP of MeHg occurred during both summer irrigation and winter flooding. Wild rice wet harvesting and winter flooding of white rice fields were specific practices that increased MeHg export, both presumably related to increased labile organic carbon and disturbance. Outflow management during these times could reduce MeHg exports. Standardizing MeHg outflow:inflow concentration ratios against natural tracers (e.g. chloride, EC) provides a simple tool to identify NEP periods. Summer MeHg exports averaged 0.2 to 1 μg m − 2 for the different agricultural wetland fields, depending upon flood duration. Average winter MeHg exports were estimated at 0.3 μg m − 2 . These exports are within the range reported for other shallow aquatic systems.

California↗

Modeling carbon dynamics in vegetation and soil under the impact of soil erosion and deposition

Soil erosion and deposition may play important roles in balancing the global atmospheric carbon budget through their impacts on the net exchange of carbon between terrestrial ecosystem and the atmosphere. Few models and studies have been designed to assess these impacts. In this study, we developed a general ecosystem model, Erosion-Deposition-Carbon-Model (EDCM), to dynamically simulate the influences of rainfall-induced soil erosion and deposition on soil organic carbon (SOC) dynamics in soil profiles. EDCM was applied to several landscape positions in the Nelson Farm watershed in Mississippi, including ridge top (without erosion or deposition), eroding hillslopes, and depositional sites that had been converted from native forests to croplands in 1870. Erosion reduced the SOC storage at the eroding sites and deposition increased the SOC storage at the depositional areas compared with the site without erosion or deposition. Results indicated that soils were consistently carbon sources to the atmosphere at all landscape positions from 1870 to 1950, with lowest source strength at the eroding sites (13 to 24 gC m-2 yr-1), intermediate at the ridge top (34 gC m-2 yr-1), and highest at the depositional sites (42 to 49 gC m-2 yr-1). During this period, erosion reduced carbon emissions via dynamically replacing surface soil with subsurface soil that had lower SOC contents (quantity change) and higher passive SOC fractions (quality change). Soils at all landscape positions became carbon sinks from 1950 to 1997 due to changes in management practices (e.g., intensification of fertilization and crop genetic improvement). The sink strengths were highest at the eroding sites (42 to 44 gC m-2 yr-1 , intermediate at the ridge top (35 gC m-2 yr-1), and lowest at the depositional sites (26 to 29 gC m-2 yr-1). During this period, erosion enhanced carbon uptake at the eroding sites by continuously taking away a fraction of SOC that can be replenished with enhanced plant residue input. Overall, soil erosion and deposition reduced CO2 emissions from the soil into the atmosphere by exposing low carbon-bearing soil at eroding sites and by burying SOC at depositional sites. The results suggest that failing to account for the impact of soil erosion and deposition may potentially contribute to an overestimation of both the total historical carbon released from soils owing to land use change and the contemporary carbon sequestration rates at the eroding sites.

Global Biogeochemical Cycles↗

Degradation of RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) in contrasting coastal marine habitats: Subtidal non-vegetated (sand), subtidal vegetated (silt/eel grass), and intertidal marsh

Hundreds of explosive-contaminated marine sites exist globally, many of which contain the common munitions constituent hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Quantitative information about RDX transformation in coastal ecosystems is essential for management of many of these sites. Isotopically labelled RDX containing 15 N in all 3 nitro groups was used to track the fate of RDX in three coastal ecosystem types. Flow-through mesocosms representing subtidal vegetated (silt/eel grass), subtidal non-vegetated (sand) and intertidal marsh ecosystems were continuously loaded with isotopically labelled RDX for 16–17 days. Sediment, pore-water and overlying surface water were analyzed to determine the distribution of RDX, nitroso-triazine transformation products (NXs) and nitrogen containing complete mineralization products, including ammonium, nitrate+nitrite, nitrous oxide and nitrogen gas. The marsh, silt, and sand ecotypes transformed 94%, 90% and 76% of supplied RDX, respectively. Total dissolved NXs accounted for 2%–4% of the transformed 15 N-RDX. The majority of RDX transformation in the water column was by mineralization to inorganic N (dissolved and evaded; 64%–78% of transformed 15 N-RDX). RDX was mineralized primarily to N 2 O (62–74% of transformed 15 N-RDX) and secondarily to N 2 (1–2% of transformed 15 N-RDX) which exchanged with the atmosphere. Transformation of RDX was favored in carbon-rich lower redox potential sediments of the silt and marsh mesocosms where anaerobic processes of iron and sulfate reduction were most prevalent. RDX was most persistent in the carbon-poor sand mesocosm. Partitioning of 15 N derived from RDX onto sediment and suspended particulates was negligible in the overall mass balance of RDX transformation (2%–3% of transformed 15 N-RDX). The fraction of 15 N derived from RDX that was sorbed or assimilated in sediment was largest in the marsh mesocosm (most organic carbon), and smallest in the sand mesocosm (largest grain size and least organic carbon). Sediment redox conditions and available organic carbon stores affect the fate of RDX in different coastal marine habitats.

Connecticut, New York↗

From pools to flow: The PROMISE framework for new insights on soil carbon cycling in a changing world

Soils represent the largest terrestrial reservoir of organic carbon, and the balance between soil organic carbon (SOC) formation and loss will drive powerful carbon‐climate feedbacks over the coming century. To date, efforts to predict SOC dynamics have rested on pool‐based models, which assume classes of SOC with internally homogenous physicochemical properties. However, emerging evidence suggests that soil carbon turnover is not dominantly controlled by the chemistry of carbon inputs, but rather by restrictions on microbial access to organic matter in the spatially heterogeneous soil environment. The dynamic processes that control the physicochemical protection of carbon translate poorly to pool‐based SOC models; as a result, we are challenged to mechanistically predict how environmental change will impact movement of carbon between soils and the atmosphere. Here, we propose a novel conceptual framework to explore controls on belowground carbon cycling: P robabilistic R epresentation of O rganic M atter I nteractions within the S oil E nvironment (PROMISE). In contrast to traditional model frameworks, PROMISE does not attempt to define carbon pools united by common thermodynamic or functional attributes. Rather, the PROMISE concept considers how SOC cycling rates are governed by the stochastic processes that influence the proximity between microbial decomposers and organic matter, with emphasis on their physical location in the soil matrix. We illustrate the applications of this framework with a new biogeochemical simulation model that traces the fate of individual carbon atoms as they interact with their environment, undergoing biochemical transformations and moving through the soil pore space. We also discuss how the PROMISE framework reshapes dialogue around issues related to SOC management in a changing world. We intend the PROMISE framework to spur the development of new hypotheses, analytical tools, and model structures across disciplines that will illuminate mechanistic controls on the flow of carbon between plant, soil, and atmospheric pools.

Global Change Biology↗

The effects of cheatgrass invasion on US Great Basin carbon storage depend on interactions between plant community composition, precipitation seasonality, and soil climate regime

Annual-grass invasions are transforming desert ecosystems in ways that affect ecosystem carbon (C) balance, but previous studies do not agree on the pattern, magnitude and direction of changes. A recent meta-analysis of 41 articles and 386 sites concludes that invasion by annual grasses such as cheatgrass ( Bromus tectorum L) reduces C in biomass across the Great Basin (Nagy et al., 2021). Reanalysis reveals that whether cheatgrass affects biomass C stocks is not generalizable, but rather depends on the considerable variation in climate across the subject sites. Our analysis suggests that accurate Great Basin-scale estimates of cheatgrass effects on C balance are not yet possible. Addition of climate variables to the meta-analysis reveals that cheatgrass invasion (a) reduced C in above-ground biomass in relatively summer-wet sites but not in summer-dry sites, (b) increased surface soil C in sites with intermediate resistance and resilience classifications (R&R) but not in low R&R sites—that is, mesic/aridic soil climates and (c) did not affect deep soil C. Considering that cheatgrass has expanded most in relatively summer-dry sites and mesic/aridic sites, omission of climate factors leads to model overestimates of cheatgrass effects on C when extrapolating to larger areas. Estimates of cheatgrass effects on C would also be improved if the analysis considered that (a) perennial grasslands are a common community state in the Great Basin that have intermediary C relative to annual grasslands and sagebrush stands, that is the omission of perennial grasslands from analysis inflates the baseline C storage of uninvaded Great Basin ecosystems, and( b) cheatgrass does not often exist in stable monocultures and soil carbon can reflect current or recent presence of other species. Synthesis and applications . Invasions often reveal heterogeneity in ecosystem structure and function that is not otherwise evident, and the heterogeneity can influence estimation of the net impacts of the invaders. For cheatgrass and other invaders, we propose that formally accounting for the spatial variability of invasion on ecosystem functions will improve the estimation of their net effect on ecosystem C, and thus improve prospects for adjusting management practices to optimize C sequestration.

western United States↗

A guide for the laboratory information management system (LIMS) for light stable isotopes--Versions 7 and 8

The reliability and accuracy of isotopic data can be improved by utilizing database software to (i) store information about samples, (ii) store the results of mass spectrometric isotope-ratio analyses of samples, (iii) calculate analytical results using standardized algorithms stored in a database, (iv) normalize stable isotopic data to international scales using isotopic reference materials, and (v) generate multi-sheet paper templates for convenient sample loading of automated mass-spectrometer sample preparation manifolds. Such a database program, the Laboratory Information Management System (LIMS) for Light Stable Isotopes, is presented herein. Major benefits of this system include (i) a dramatic improvement in quality assurance, (ii) an increase in laboratory efficiency, (iii) a reduction in workload due to the elimination or reduction of retyping of data by laboratory personnel, and (iv) a decrease in errors in data reported to sample submitters. Such a database provides a complete record of when and how often laboratory reference materials have been analyzed and provides a record of what correction factors have been used through time. It provides an audit trail for laboratories. LIMS for Light Stable Isotopes is available for both Microsoft Office 97 Professional and Microsoft Office 2000 Professional as versions 7 and 8, respectively. Both source code (mdb file) and precompiled executable files (mde) are available. Numerous improvements have been made for continuous flow isotopic analysis in this version (specifically 7.13 for Microsoft Access 97 and 8.13 for Microsoft Access 2000). It is much easier to import isotopic results from Finnigan ISODAT worksheets, even worksheets on which corrections for amount of sample (linearity corrections) have been added. The capability to determine blank corrections using isotope mass balance from analyses of elemental analyzer samples has been added. It is now possible to calculate and apply drift corrections to isotopic data based on the time of day of analysis. Whereas Finnigan ISODAT software is confined to using only a single peak for calculating delta values, LIMS now enables one to use the mean of two or more reference injections during a continuous flow analysis to calculate delta values. This is useful with Finnigan?s GasBench II online sample preparation system. Concentrations of carbon, nitrogen, and sulfur can be calculated based one or more isotopic reference materials analyzed with a group of samples. Both sample data and isotopic analysis data can now be exported to Excel files. A calculator for determining the amount of sample needed for isotopic analysis based on a previous amount of sample and continuous flow area is now an integral part of LIMS for Light Stable Isotopes. LIMS for Light Stable Isotopes can now assign an error code to Finnigan elemental analyzer analyses in which one of the electrometers has saturated due to analysis of too much sample material, giving rise to incorrect isotopic abundances. Information on downloading this report and downloading code and databases is provided at the Internet addresses: http://water.usgs.gov/software/geochemical.html or http://www.geogr.uni-jena.de/software/geochemical.html in the Eastern Hemisphere.

Open-File Report↗

Plant community, primary productivity, and environmental conditions following wetland re-establishment in the Sacramento-San Joaquin Delta, California

Wetland restoration can mitigate aerobic decomposition of subsided organic soils, as well as re-establish conditions favorable for carbon storage. Rates of carbon storage result from the balance of inputs and losses, both of which are affected by wetland hydrology. We followed the effect of water depth (25 and 55 cm) on the plant community, primary production, and changes in two re-established wetlands in the Sacramento San-Joaquin River Delta, California for 9 years after flooding to determine how relatively small differences in water depth affect carbon storage rates over time. To estimate annual carbon inputs, plant species cover, standing above- and below-ground plant biomass, and annual biomass turnover rates were measured, and allometric biomass models for Schoenoplectus (Scirpus) acutus and Typha spp., the emergent marsh dominants, were developed. As the wetlands developed, environmental factors, including water temperature, depth, and pH were measured. Emergent marsh vegetation colonized the shallow wetland more rapidly than the deeper wetland. This is important to potential carbon storage because emergent marsh vegetation is more productive, and less labile, than submerged and floating vegetation. Primary production of emergent marsh vegetation ranged from 1.3 to 3.2 kg of carbon per square meter annually; and, mid-season standing live biomass represented about half of the annual primary production. Changes in species composition occurred in both submerged and emergent plant communities as the wetlands matured. Water depth, temperature, and pH were lower in areas with emergent marsh vegetation compared to submerged vegetation, all of which, in turn, can affect carbon cycling and storage rates. ?? Springer Science+Business Media B.V. 2009.

Wetlands Ecology and Management↗

Dynamics of land-use change and conservation in the Prairie Pothole Region of the United States: environmental and economic implications with linkages to rural community well-being

Rural America has changed dramatically over the last century, from having over half the population living in rural settings to only 20 percent residing in a rural area today, and outmigration of younger populations from rural communities remains a constant issue for local governing officials. A declining tax base and concurrent rising costs for maintenance and repair of aging infrastructure add further challenges to policy decisions. Reduced enrollment has caused school closures or mergers. Farm consolidation and technical advances reduced the demand for local labor. On the positive side, however, record-high commodity prices have amplified farm income to new heights. The increased revenues can lead to farmers spending additional money within the local region, while at the same time increased transportation of products has impacted local infrastructure such as roads and bridges. Such dynamics present challenges for municipal leaders charged with promoting economic development and balanced spending, while at the same time maintaining the way of life and rural character that are so important to area residents. The Prairie Pothole Region (PPR) of the United States covers much of the Northern Great Plains, including parts of North and South Dakota, Minnesota, Iowa, and a small part of Montana, and extends across a broad swath of Alberta and Saskatchewan. The region is defined largely by its rural character but has experienced extensive land conversion over the last century, with agricultural areas replacing native prairie habitat. Additional pressures arise from oil and gas development, global markets for agricultural production, and increased demands for biofuel feedstocks. Record-high commodity prices increase pressure on the native prairie as farmers look for new cropland acres. The volatility of commodity prices has raised fears over the intensity of land conversion to row-crop agriculture, the economic health and resiliency of rural communities, and ultimately, population dynamics and outmigration of younger generations. Land-use pressures are increased by the exponential growth of oil and gas production in the region, where some 8,200 wells are now in production within the Williston Basin of North Dakota, accompanied by increased population pressures on housing and municipal services. The U.S. Department of Agriculture’s Conservation Reserve Program (CRP)--a cropland retirement program with close to 4.8 million acres enrolled in the PPR--faces uncertainty in upcoming legislative actions, with a large majority of property enrollments scheduled to expire by 2017. The CRP historically has provided improved habitat conditions, reductions of soil damage through erosion and loss of nutrients, and sequestration of millions of tons of atmospheric carbon. In turn, wildlife-related recreation levels have increased in many parts of the PPR, with money spent in local communities. Contemporary resource-management and rural-development planning increasingly emphasize the need for diversification and integration of resource-extractive industries with nonmarket-based recreational and amenity values that tie into quality of life. Ultimately, each community is unique in its environmental, social, economic, and fiscal endowments. One rural-development policy may work better in one community than another. In addition, rural-development issues such as migration, job growth, and taxes are diverse in themselves. The goal of this report is to qualitatively and quantitatively discuss the economic impacts of land-use decisions in rural areas, particularly in the PPR.

Professional Paper↗

Water-budgets and recharge-area simulations for the Spring Creek and Nittany Creek Basins and parts of the Spruce Creek Basin, Centre and Huntingdon Counties, Pennsylvania, Water Years 2000–06

This report describes the results of a study by the U.S. Geological Survey in cooperation with ClearWater Conservancy and the Pennsylvania Department of Environmental Protection to develop a hydrologic model to simulate a water budget and identify areas of greater than average recharge for the Spring Creek Basin in central Pennsylvania. The model was developed to help policy makers, natural resource managers, and the public better understand and manage the water resources in the region. The Groundwater and Surface-water FLOW model (GSFLOW), which is an integration of the Precipitation-Runoff Modeling System (PRMS) and the Modular Groundwater Flow Model (MODFLOW-NWT), was used to simulate surface water and groundwater in the Spring Creek Basin for water years 2000–06. Because the groundwater and surface-water divides for the Spring Creek Basin do not coincide, the study area includes the Nittany Creek Basin and headwaters of the Spruce Creek Basin. The hydrologic model was developed by the use of a stepwise process: (1) develop and calibrate a PRMS model and steady-state MODFLOW-NWT model; (2) re-calibrate the steady-state MODFLOW-NWT model using potential recharge estimates simulated from the PRMS model, and (3) integrate the PRMS and MODFLOW-NWT models into GSFLOW. The individually calibrated PRMS and MODFLOW-NWT models were used as a starting point for the calibration of the fully coupled GSFLOW model. The GSFLOW model calibration was done by comparing observations and corresponding simulated values of streamflow from 11 streamgages and groundwater levels from 16 wells. The cumulative water budget and individual water budgets for water years 2000–06 were simulated by using GSFLOW. The largest source and sink terms are represented by precipitation and evapotranspiration, respectively. For the period simulated, a net surplus in the water budget was computed where inflows exceeded outflows by about 1.7 billion cubic feet (0.47 inches per year over the basin area); storage increased by about the same amount to balance the budget. The rate and distribution of recharge throughout the Spring Creek, Nittany Creek, and Spruce Creek Basins is variable as a result of the high degree of hydrogeologic heterogeneity and karst features. The greatest amount of recharge was simulated in the carbonate-bedrock valley, near the toe slopes of Nittany and Tussey Mountains, in the Scotia Barrens, and along the area coinciding with the Gatesburg Formation. Runoff extremes were observed for water years 2001 (dry year) and 2004 (wet year). Simulated average recharge rates (water reaching the saturated zone as defined in GSFLOW) for 2001 and 2004 were 5.4 in/yr and 22.0 in/yr, respectively. Areas where simulations show large variations in annual recharge between wet and dry years are the same areas where simulated recharge was large. Those areas where rates of groundwater recharge are much higher than average, and are capable of accepting substantially greater quantities of recharge during wet years, might be considered critical for maintaining the flow of springs, stream base flow, or the source of water to supply wells. The slopes of the Bald Eagle, Tussey, and Nittany Mountains are relatively insensitive to variations in recharge, primarily because of reduced infiltration rates and steep slopes.

Pennsylvania↗

Precipitation, Ground-water Hydrology, and Recharge Along the Eastern Slopes of the Sandia Mountains, Bernalillo County, New Mexico

The spatial and temporal distribution of recharge to carbonate and clastic aquifers along the eastern slopes of the Sandia Mountains was investigated by using precipitation, water-level, dissolved chloride, and specific-conductance data. The U.S. Geological Survey (USGS), in cooperation with the Bernalillo County Public Works Division, conducted a study to assess ground-water conditions and provide technical data that could be used as a basis for management and future planning of eastern Bernalillo County water resources. The intent of the investigation was to improve the current understanding of subsurface mechanisms controlling recharge dynamics in a geologically complex aquifer system. In the Sandia Mountains, precipitation events are generally limited to snowfalls in winter months and monsoon rainfall in late summer. Monthly meteorological data from weather stations in the study area indicate that monsoon rainfall during July and August constitutes close to one-third of annual precipitation totals. Following precipitation and snowmelt events, daily ground-water level data show low-amplitude, long-duration peaks in hydrographs of wells north and west of the Tijeras Fault. Hydrographs of monthly and biannual water-level data from across the study area show seasonal variation and water-level fluctuations in excess of 30 ft during a period of below-average precipitation. Water level observations in 67 percent of wells showing drought-induced water-level declines rebounded to at or near predrought conditions within 6 months of return to normal climate conditions. Cross-correlation of annual hydrologic data shows aquifer response to periods of monsoon recharge to persist from 1 to 6 months following events. The lag time between precipitation input and response of water levels or solute concentrations was largest near the Tijeras and Gutierrez Faults. These results indicate regional faults hydrologically isolate the Tijeras Graben from groundwater recharge originating at high elevations along the eastern slopes of the Sandia Mountains. Recharge rates calculated by using the chloride-mass-balance method for five springs located at the base of the Sandia Mountains ranged from 1 to 23 percent of annual precipitation.

Scientific Investigations Report↗

Simulation of flow and eutrophication in the central Salem River, New Jersey

The central Salem River in New Jersey is subject to periods of water-quality impairment, marked by elevated concentrations of phosphorus and chlorophyll- a , and low concentrations of and large diurnal swings in concentrations of dissolved oxygen. These seasonal eutrophic conditions are controlling factors for water quality in lower reaches, where the river is more lacustrine than in upper reaches, as a result of downstream damming. This biological productivity is supported by nutrient wash-off from agricultural areas in the surrounding watershed. To investigate this impairment, flow measurement and water-quality sampling were conducted during 2007–08 in support of development of a one-dimensional surface-water-quality model that simulates nutrient cycling and transformation processes. The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, used the U.S. Environmental Protection Agency Water Quality Analysis Simulation Program (WASP) to develop a receiving-water-quality model of the central Salem River between Woodstown and Deepwater, New Jersey, from April 2007 to October 2008. The main-stem river and largest tributary were simulated. In the flow model, kinematic wave flow is used to simulate flow in upper reaches and ponded weir flow is used to simulate flow in lower reaches. The water-quality model makes use of a mass-balance equation to simulate the fate and transport of nutrients, phytoplankton chlorophyll- a , dissolved oxygen, and oxygen demands (an indicator rather than a substance) in the river. Model input included channel characteristics, boundary conditions for flow and water quality, environmental parameters, vertical dispersion coefficients, settling rates, and kinetic constants. Inputs were estimated where field data were lacking, notably for tributary flows and nutrient loads. The model was calibrated to observed flow variables and concentrations of dissolved oxygen, chlorophyll- a , and nutrients at sampling locations, with emphasis on growing-season conditions. Calibration was achieved through graphical and statistical comparison of simulated results to observed data. Sensitivity analyses were performed, and model limitations and applicability were evaluated. Simulated results closely matched observed data in most cases, although some were overpredicted slightly. The most important causes of overprediction were estimated tributary flows for the flow model and estimated tributary watershed loads for the water-quality model. Calibration of dissolved-oxygen concentrations was closer, and predicted diurnal variations were consistent with high algal photosynthesis/respiration, although lack of continuous dissolved-oxygen data precluded verifying these predictions. A similar caveat applies to predicted diurnal variations in chlorophyll- a . Simulated limitations on algal growth were consistent with those based on observed data and indicated phosphorus was the main limiting nutrient, except during certain periods when nitrogen was limiting. Two water-quality management scenarios were simulated with the model to assess the effect of point- and nonpoint-source nutrient reductions on water-quality conditions in the river. Scenarios involved (1) a return of watershed land use to predevelopment natural conditions and (2) an extreme reduction in nutrient input. Although the extreme-nutrient-reduction scenario yielded improvements in water quality, the natural-conditions scenario yielded the largest improvements as indicated by minimal violations of surface-water-quality standards or thresholds. However, years may be needed to attain the full benefit of these management scenarios as a result of accumulation of phosphorus and organic carbon in riverbed sediments in lacustrine reaches. The results of this study indicate that the quality of water in the central Salem River will improve if management policies that mitigate the effects of nutrient-loading practices in the watershed, particularly those related to agriculture, are implemented.

New Jersey↗

Intra-seasonal mapping of CO 2 flux in rangelands of northern Kazakhstan at one-kilometer resolution

Algorithms that establish relationships between variables obtained through remote sensing and geographic information system (GIS) technologies are needed to allow the scaling up of site-specific CO2 flux measurements to regional levels. We obtained Bowen ratio-energy balance (BREB) flux tower measurements during the growing seasons of 1998-2000 above a grassland steppe in Kazakhstan. These BREB data were analyzed using ecosystem light-curve equations to quantify 10-day CO2 fluxes associated with gross primary production (GPP) and total respiration (R). Remotely sensed, temporally smoothed normalized difference vegetation index (NDVIsm) and environmental variables were used to develop multiple regression models for the mapping of 10-day CO2 fluxes for the Kazakh steppe. Ten-day GPP was estimated (R 2 = 0.72) by day of year (DOY) and NDVIsm, and 10-day R was estimated (R2 = 0.48) with the estimated GPP and estimated 10-day photosynthetically active radiation (PAR). Regression tree analysis estimated 10-day PAR from latitude, NDVIsm, DOY, and precipitation (R2 = 0.81). Fivefold cross-validation indicated that these algorithms were reasonably robust. GPP, R, and resulting net ecosystem exchange (NEE) were mapped for the Kazakh steppe grassland every 10 days and summed to produce regional growing season estimates of GPP, R, and NEE. Estimates of 10-day NEE agreed well with BREB observations in 2000, showing a slight underestimation in the late summer. Growing season (May to October) mean NEE for Kazakh steppe grasslands was 1.27 Mg C/ha in 2000. Winter flux data were collected during the winter of 2001-2002 and are being analyzed to close the annual carbon budget for the Kazakh steppe. ?? 2004 Springer-Verlag New York, LLC.

Environmental Management↗

U.S. Geological Survey program of offshore resource and geoenvironmental studies, Atlantic-Gulf of Mexico region, from September 1, 1976, to December 31, 1978

Mineral and energy resources of the continental margins of the United States arc important to the Nation's commodity independence and to its balance of payments. These resources are being studied along the continental margins of the Atlantic Ocean and the Gulf of Mexico in keeping with the mission of the U.S. Geological Survey to survey the geologic structures, mineral resources, and products of the national domain.'(Organic Act of 1879). An essential corollary to these resource studies is the study of potential geologic hazards that may be associated with offshore resource exploration and exploitation. In cooperation with the U.S. Bureau of Land Management, the Geological Survey, through its Atlantic-Gulf of Mexico Marine Geology Program, carries out extensive research to evaluate hazards from sediment mobility, shallow gas, and slumping and to acquire information on the distribution and concentration of trace metals and biogenic and petroleum-derived hydrocarbons in sea-floor sediments. All these studies arc providing needed background information, including information on pollutant dispersal, on the nearshore, estuarine, and lacustrine areas that may be near pipeline and nuclear powerplant sites. Users of these data include the Congress, many Federal agencies, the coastal States, private industry, academia, and the concerned public. The results of the regional structural, stratigraphic, and resource studies carried out under the Atlantic-Gulf of Mexico Marine Geology Program have been used by the Geological Survey and the Bureau of Land Management to select areas for future leasing and to aid in the evaluation of tracts nominated for leasing. Resource studies have concentrated mostly on the Atlantic Outer Continental Shelf frontier areas. Geologic detailing of five major basins along the U.S. Atlantic margin, where sediments are as much as 14 km thick, have been revealed by 25,000 km of 24-and 48-channel common-depth-point seismic data, 187,000 km of acromagnetic data, and 39,000 km of gravity data, plus 10,000 samples and logs obtained from U.S. Geological Survey and industry drilling (for example, coreholes of the Atlantic Slope Program, Joint Oceanographic Institutions Deep Earth Sampling, Continental Offshore Stratigraphic Tests, and the Atlantic Margin Coring Program). A sedimentary section of Jurassic and Cretaceous age grades from terrigenous clastic rocks nearshore to carbonate rocks offshore; this section is part of an extensive buried bank-platform complex that could contain large reserves of natural gas and oil. The volume of sediment deposited offshore far exceeds the volume deposited onshore where extensive accumulations of oil, gas, and minerals have been found. Commercial exploratory drilling offshore thus far has been limited to the Baltimore Canyon Trough area off New Jersey, where at least two holes have found gas; leasing has taken place in the Southeast Georgia Embayment, where drilling was scheduled to begin in 1979, and is imminent in the Georges Bank area off New England. In addition, hydrogeologic and hydrochemical data obtained from the drilling studies have delineated freshwater-bearing submarine extensions of land aquifers that are important coastal ground-water resources. Hazards in the Georges Bank area include sand mobility associated with strong currents and storm-driven waves; high concentrations of suspended sediment in the water column that, when mixed with spilled oil, may sink to the bottom; and slumping along the upper slope. In the Baltimore Canyon, high sediment mobility accompanies major winter storms, and slumped material may cover as much as 20 percent of the upper slope. Potentially unstable slope areas are being studied in great detail to provide data on timing, triggering mechanisms, and rates of sediment movement. In the Southeast Georgia Embayment and Blake Plateau Basin, strong Gulf Stream flow poses a major problem to all offshore operations. In the Gulf o

Circular↗

Long-term dynamics of production, respiration, and net CO 2 exchange in two sagebrush-steppe ecosystems

We present a synthesis of long-term measurements of CO 2 exchange in 2 US Intermountain West sagebrush-steppe ecosystems. The locations near Burns, Oregon (1995–2001), and Dubois, Idaho (1996–2001), are part of the AgriFlux Network of the Agricultural Research Service, United States Department of Agriculture. Measurements of net ecosystem CO 2 exchange ( F c ) during the growing season were continuously recorded at flux towers using the Bowen ratio-energy balance technique. Data were partitioned into gross primary productivity ( P g ) and ecosystem respiration ( R e ) using the light-response function method. Wintertime fluxes were measured during 1999/2000 and 2000/2001 and used to model fluxes in other winters. Comparison of daytime respiration derived from light-response analysis with nighttime tower measurements showed close correlation, with daytime respiration being on the average higher than nighttime respiration. Maxima of P g and R e at Burns were both 20 g CO 2 ·m −2 ·d −1 in 1998. Maxima of P g and R e at Dubois were 37 and 35 g CO 2 ·m −2 ·d −1 , respectively, in 1997. Mean annual gross primary production at Burns was 1 111 (range 475–1 715) g CO 2 ·m −2 ·y −1 or about 30% lower than that at Dubois (1 602, range 963–2 162 g CO 2 ·m −2 ·y −1 ). Across the years, both ecosystems were net sinks for atmospheric CO 2 with a mean net ecosystem CO 2 exchange of 82 g CO 2 ·m −2 ·y −1 at Burns and 253 g CO 2 ·m −2 ·y −1 at Dubois, but on a yearly basis either site could be a C sink or source, mostly depending on precipitation timing and amount. Total annual precipitation is not a good predictor of carbon sequestration across sites. Our results suggest that F c should be partitioned into P g and R e components to allow prediction of seasonal and yearly dynamics of CO 2 fluxes.

Rangeland Ecology and Management↗

Above- and belowground biomass carbon stock and net primary productivity maps for tidal herbaceous marshes of the United States

Accurate assessments of greenhouse gas emissions and carbon sequestration in natural ecosystems are necessary to develop climate mitigation strategies. Regional and national-level assessments of carbon sequestration require high-resolution data to be available for large areas, increasing the need for remote sensing products that quantify carbon stocks and fluxes. The Intergovernmental Panel on Climate Change (IPCC) provides guidelines on how to quantify carbon flux using land cover land change and biomass carbon stock information. Net primary productivity (NPP), carbon uptake, and storage in vegetation, can also be used to model net carbon sequestration and net carbon export from an ecosystem (net ecosystem carbon balance). While biomass and NPP map products for terrestrial ecosystems are available, there are currently no conterminous United States (CONUS) biomass carbon stock or NPP maps for tidal herbaceous marshes. In this study, we used peak soil adjusted vegetation index (SAVI) values, derived from Landsat 8 composites, and five other vegetation indices, plus a categorical variable for the CONUS region (Pacific Northwest, California, Northeast, Mid-Atlantic, South Atlantic-Gulf, or Everglades), to model spatially explicit aboveground peak biomass stocks in tidal marshes (i.e., tidal palustrine and estuarine herbaceous marshes) for the first time. Tidal marsh carbon conversion factors, root-to-shoot ratios, and vegetation turnover rates, were compiled from the literature and used to convert peak aboveground biomass to peak total (above- and belowground) biomass and NPP. An extensive literature search for aboveground turnover rates produced sparse and variable values; therefore, we used an informed assumption of a turnover rate of one crop per year for all CONUS tidal marshes. Due to the lack of turnover rate data, the NPP map is identical to the peak biomass carbon stock map. In reality, it is probable that turnover rate varies by region, given seasonal length differences; however, the NPP map provides the best available information on spatially explicit CONUS tidal marsh NPP. This study identifies gaps in the scientific knowledge, to support future studies in addressing this lack of turnover data. Across CONUS, average total peak biomass carbon stock in tidal marshes was 848 g C m −2 (871 g C m −2 in palustrine and 838 g C m −2 in estuarine marshes), and based on a median biomass turnover rate of 1, it is expected that the mean NPP annual flux for tidal marshes is similar (e.g., 848 g C m −2 y −1 ). Peak biomass carbon stocks in tidal marshes were lowest in the Florida Everglades region and highest in the California regions. These are the first fine-scale national maps of biomass carbon and NPP for tidal wetlands, spanning all of CONUS. These estimates of CONUS total peak biomass carbon stocks and NPP rates for tidal marshes can support regional- and national-scale assessments of greenhouse gas emissions, as well as natural resource management of coastal wetlands, as part of nature-based climate solution efforts.

Remote Sensing↗

Carbon balance of the terrestrial biosphere in the twentieth century: analyses of CO 2 , climate and land use effects with four process-based ecosystem models

The concurrent effects of increasing atmospheric CO 2 concentration, climate variability, and cropland establishment and abandonment on terrestrial carbon storage between 1920 and 1992 were assessed using a standard simulation protocol with four process-based terrestrial biosphere models. Over the long-term(1920–1992), the simulations yielded a time history of terrestrial uptake that is consistent (within the uncertainty) with a long-term analysis based on ice core and atmospheric CO 2 data. Up to 1958, three of four analyses indicated a net release of carbon from terrestrial ecosystems to the atmosphere caused by cropland establishment. After 1958, all analyses indicate a net uptake of carbon by terrestrial ecosystems, primarily because of the physiological effects of rapidly rising atmospheric CO 2 . During the 1980s the simulations indicate that terrestrial ecosystems stored between 0.3 and 1.5 Pg C yr−1, which is within the uncertainty of analysis based on CO 2 and O 2 budgets. Three of the four models indicated (in accordance with O 2 evidence) that the tropics were approximately neutral while a net sink existed in ecosystems north of the tropics. Although all of the models agree that the long-term effect of climate on carbon storage has been small relative to the effects of increasing atmospheric CO 2 and land use, the models disagree as to whether climate variability and change in the twentieth century has promoted carbon storage or release. Simulated interannual variability from 1958 generally reproduced the El Niño/Southern Oscillation (ENSO)-scale variability in the atmospheric CO 2 increase, but there were substantial differences in the magnitude of interannual variability simulated by the models. The analysis of the ability of the models to simulate the changing amplitude of the seasonal cycle of atmospheric CO 2 suggested that the observed trend may be a consequence of CO 2 effects, climate variability, land use changes, or a combination of these effects. The next steps for improving the process-based simulation of historical terrestrial carbon include (1) the transfer of insight gained from stand-level process studies to improve the sensitivity of simulated carbon storage responses to changes in CO 2 and climate, (2) improvements in the data sets used to drive the models so that they incorporate the timing, extent, and types of major disturbances, (3) the enhancement of the models so that they consider major crop types and management schemes, (4) development of data sets that identify the spatial extent of major crop types and management schemes through time, and (5) the consideration of the effects of anthropogenic nitrogen deposition. The evaluation of the performance of the models in the context of a more complete consideration of the factors influencing historical terrestrial carbon dynamics is important for reducing uncertainties in representing the role of terrestrial ecosystems in future projections of the Earth system.

Global Biogeochemical Cycles↗

Productivity and CO 2 exchange of Great Plains ecoregions. I. Shortgrass steppe: Flux tower estimates

The shortgrass steppe (SGS) occupies the southwestern part of the Great Plains. Half of the land is cultivated, but significant areas remain under natural vegetation. Despite previous studies of the SGS carbon cycle, not all aspects have been completely addressed, including gross productivity, ecosystem respiration, and ecophysiological parameters. Our analysis of 1998 − 2007 flux tower measurements at five Bowen ratio–energy balance (BREB) and three eddy covariance (EC) sites characterized seasonal and interannual variability of gross photosynthesis and ecosystem respiration. Identification of the nonrectangular hyperbolic equation for the diurnal CO 2 exchange, with vapor pressure deficit (VPD) limitation and exponential temperature response, quantified quantum yield α , photosynthetic capacity A max , and respiration rate r d with variation ranges (19 \< α \ < 51 mmol mol − 1 , 0.48 \< A max \ < 2.1 mg CO 2 m − 2 s − 1 , 0.15 \< r d \ < 0.49 mg CO 2 m − 2 s − 1 ). Gross photosynthesis varied from 1 100 to 2 700 g CO 2 m − 2 yr − 1 , respiration from 900 to 3,000 g CO 2 m − 2 yr − 1 , and net ecosystem production from − 900 to + 700 g CO 2 m − 2 yr − 1 , indicating that SGS may switch from a sink to a source depending on weather. Comparison of the 2004 − 2006 measurements at two BREB and two parallel EC flux towers located at comparable SGS sites showed moderately higher photosynthesis, lower respiration, and higher net production at the BREB than EC sites. However, the difference was not related only to methodologies, as the normalized difference vegetation index at the BREB sites was higher than at the EC sites. Overall magnitudes and seasonal patterns at the BREB and the EC sites during the 3-yr period were similar, with trajectories within the ± 1.5 standard deviation around the mean of the four sites and mostly reflecting the effects of meteorology.

Colorado, Wyoming↗