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Nutrients in the nexus

Synthetic nitrogen (N) fertilizer has enabled modern agriculture to greatly improve human nutrition during the twentieth century, but it has also created unintended human health and environmental pollution challenges for the twenty-first century. Averaged globally, about half of the fertilizer-N applied to farms is removed with the crops, while the other half remains in the soil or is lost from farmers’ fields, resulting in water and air pollution. As human population continues to grow and food security improves in the developing world, the dual development goals of producing more nutritious food with low pollution will require both technological and socio-economic innovations in agriculture. Two case studies presented here, one in sub-Saharan Africa and the other in Midwestern United States, demonstrate how management of nutrients, water, and energy is inextricably linked in both small-scale and large-scale food production, and that science-based solutions to improve the efficiency of nutrient use can optimize food production while minimizing pollution. To achieve the needed large increases in nutrient use efficiency, however, technological developments must be accompanied by policies that recognize the complex economic and social factors affecting farmer decision-making and national policy priorities. Farmers need access to affordable nutrient supplies and support information, and the costs of improving efficiencies and avoiding pollution may need to be shared by society through innovative policies. Success will require interdisciplinary partnerships across public and private sectors, including farmers, private sector crop advisors, commodity supply chains, government agencies, university research and extension, and consumers.

Journal of Environmental Studies and Sciences

Thermal conductivity of hydrate-bearing sediments

A thorough understanding of the thermal conductivity of hydrate-bearing sediments is necessary for evaluating phase transformation processes that would accompany energy production from gas hydrate deposits and for estimating regional heat flow based on the observed depth to the base of the gas hydrate stability zone. The coexistence of multiple phases (gas hydrate, liquid and gas pore fill, and solid sediment grains) and their complex spatial arrangement hinder the a priori prediction of the thermal conductivity of hydrate-bearing sediments. Previous studies have been unable to capture the full parameter space covered by variations in grain size, specific surface, degree of saturation, nature of pore filling material, and effective stress for hydrate-bearing samples. Here we report on systematic measurements of the thermal conductivity of air dry, water- and tetrohydrofuran (THF)-saturated, and THF hydrate–saturated sand and clay samples at vertical effective stress of 0.05 to 1 MPa (corresponding to depths as great as 100 m below seafloor). Results reveal that the bulk thermal conductivity of the samples in every case reflects a complex interplay among particle size, effective stress, porosity, and fluid-versus-hydrate filled pore spaces. The thermal conductivity of THF hydrate–bearing soils increases upon hydrate formation although the thermal conductivities of THF solution and THF hydrate are almost the same. Several mechanisms can contribute to this effect including cryogenic suction during hydrate crystal growth and the ensuing porosity reduction in the surrounding sediment, increased mean effective stress due to hydrate formation under zero lateral strain conditions, and decreased interface thermal impedance as grain-liquid interfaces are transformed into grain-hydrate interfaces.

Journal of Geophysical Research B: Solid Earth

Air permeability and trapped-air content in two soils

To improve understanding of hysteretic air permeability relations, a need exists for data on the water content dependence of air permeability, matric pressure, and air trapping (especially for wetting-drying cycles). To obtain these data, a special instrument was designed. The instrument is a combination of a gas permeameter (for air permeability determination), a suction plate apparatus (for retentivity curve determination), and an air pycnometer (for trapped-air-volume determination). This design allowed values of air permeability, matric pressure, and air trapping to be codetermined, i.e., determined at the same values of water content using the same sample and the same inflow-outflow boundaries. Such data were obtained for two nonswelling soils. The validity of the air permeability determinations was repeatedly confirmed by rigorous tests of Darcy's law. During initial drying from complete water saturation, supplementary measurements were made to assess the magnitude of gas slip. The extended Darcy equation accurately described the measured flux gradient relations for each condition of absolute gas pressure tested. Air permeability functions exhibited zero-permeability regions at high water contents as well as an abruptly appearing hysteresis at low water contents. Measurements in the zero-permeability regions revealed that the total amount of air in general exceeded the amount of trapped air. This indicates that the medium' s air space is partitioned into three measurable domains: through-flowing air, locally accessible air (i.e., air accessible from only one flow boundary), and trapped air. During repeated wetting and drying, the disappearance and reappearance of air permeability coincided closely with the reappearance and disappearance, respectively, of trapped air. The observed relation between critical features of the air permeability functions and those of the air-trapping functions suggest that water-based blockages play a significant role in the disruption of gas-phase connectivity and in preventing air flow, and must be considered in any effectual model of air permeability relations.

Water Resources Research

Environmental controls, emergent scaling, and predictions of greenhouse gas (GHG) fluxes in coastal salt marshes

Coastal salt marshes play an important role in mitigating global warming by removing atmospheric carbon at a high rate. We investigated the environmental controls and emergent scaling of major greenhouse gas (GHG) fluxes such as carbon dioxide (CO 2 ) and methane (CH 4 ) in coastal salt marshes by conducting data analytics and empirical modeling. The underlying hypothesis is that the salt marsh GHG fluxes follow emergent scaling relationships with their environmental drivers, leading to parsimonious predictive models. CO 2 and CH 4 fluxes, photosynthetically active radiation (PAR), air and soil temperatures, well water level, soil moisture, and porewater pH and salinity were measured during May–October 2013 from four marshes in Waquoit Bay and adjacent estuaries, MA, USA. The salt marshes exhibited high CO 2 uptake and low CH 4 emission, which did not significantly vary with the nitrogen loading gradient (5–126 kg · ha −1 · year −1 ) among the salt marshes. Soil temperature was the strongest driver of both fluxes, representing 2 and 4–5 times higher influence than PAR and salinity, respectively. Well water level, soil moisture, and pH did not have a predictive control on the GHG fluxes, although both fluxes were significantly higher during high tides than low tides. The results were leveraged to develop emergent power law‐based parsimonious scaling models to accurately predict the salt marsh GHG fluxes from PAR, soil temperature, and salinity (Nash‐Sutcliffe Efficiency = 0.80–0.91). The scaling models are available as a user‐friendly Excel spreadsheet named Coastal Wetland GHG Model to explore scenarios of GHG fluxes in tidal marshes under a changing climate and environment.

Massachusetts

Seasonal movement of the Slumgullion landslide determined from global positioning system surveys and field instrumentation, July 1998-March 2002

Measurements of landslide movement made by global positioning system surveys and extensometers over a 3.5-year period show that the Slumgullion landslide in the San Juan Mountains of southwest Colorado moved throughout the monitoring period, but that daily velocities varied on a seasonal basis. Landslide velocities peaked in the early spring and summer in response to snowmelt and summer thunderstorms, respectively. Velocities were slowest in mid-winter when air and soil temperatures were coldest and precipitation was generally low and/or in the form of snow with a low water content. We hypothesize that the seasonal variability in velocities is due to ground-water levels and corresponding pore pressures that decrease when surface water is unavailable or cannot infiltrate frozen landslide material, and increase when surface water from melting snow or rainfall infiltrates unfrozen landslide material. We also suggest that patches of bouldery debris and fractures (created by continuous movement of the landslide) are conduits through which surface water can infiltrate, regardless of the frozen or unfrozen state of the landslide matrix material. Therefore, the availability of surface water is more important than landslide temperature in controlling the rate of landslide movement. This hypothesis is supported by field instrumentation data that show (1) landslide velocities coinciding with precipitation amounts regardless of the depth of freezing of landslide material, (2) spring and annual landslide velocities that were greatest when the depth of freezing was also the greatest, and (3) a rapid (several weeks or less) velocity and pore pressure response to rainfall. The persistent, but seasonally variable movement of the landslide, fits the bathtub model for landslide movement described by Baum and Reid [Baum, R.L., Reid, M.E., 2000. Ground water isolation by low-permeability clays in landslide shear zones. In: Bromhead, E.N., Dixon, N., Ibsen, M.-L. (Eds.), Landslides in Research, Theory and Practice. Proc. 8th Int. Symp. on Landslides, Cardiff, Wales, vol. 1, 139-144]. In their model, the landslide is isolated both mechanically and hydrologically from adjacent materials by low permeability clays. These clays cause the landslide to retain water. Our data support this model by suggesting that pore pressures at the basal landslide surface are always adequate to maintain landslide movement and that any infiltration of water at the surface of the landslide is adequate to rapidly increase landslide velocity. ?? 2002 Elsevier Science B.V. All rights reserved.

Engineering Geology

Satellite psychrometric formulation of the operational simplified surface energy balance (SSEBop) model for quantifying and mapping evapotranspiration

Remote sensing-based evapotranspiration (ET) can be derived using various methods, from soil moisture accounting to vegetation-index based approaches to simple and complex surface energy balance techniques. Due to the complexity of fully representing and parameterizing ET sub-processes, different models tend to diverge in their estimations. However, most models appear to provide reasonable estimations that can meet user requirements for seasonal water use estimation and drought monitoring. One such model is the Operational Simplified Surface Energy Balance (SSEBop). This study presents a formulation of the SSEBop model using the psychrometric principle for vapor pressure/relative humidity measurements where the “dry-bulb” and “wet-bulb” equivalent readings can be obtained from satellite-based land surface temperature estimates. The difference in temperature between the dry (desired location) and wet limit (reference value) is directly correlated to the soil-vegetation composite moisture status (surface humidity) and thus producing a fractional value (0-1) to scale the reference ET. The reference ET is independently calculated using available weather data through the standardized Penman-Monteith equation. Satellite Psychrometric Approach (SPA) explains the SSEBop model more effectively than the energy balance principle because SSEBop does not solve all terms of the surface energy balance such as sensible and ground-heat fluxes. The SPA explanation demonstrates the psychrometric constant for the air can be readily adapted to a comparable constant for the surface, thus allowing the creation of a “surface” psychrometric constant that is unique to a location and day-of-year. This new surface psychrometric constant simplifies the calculation and explanation of satellite-based ET for several applications in agriculture and hydrology. The SPA formulation of SSEBop was found to be an enhancement of the ET equation formulated in 1977 by pioneering researchers. With only two key parameters, improved model results can be obtained using a one-time calibration for any bias correction. The model can be set up quickly for routine monitoring and assessment of ET at landscape scales and beyond.

Arizona

Effects of coal-bed methane discharge waters on the vegetation and soil ecosystem in Powder River Basin, Wyoming

Coal-bed methane (CBM) co-produced discharge waters in the Powder River Basin of Wyoming, resulting from extraction of methane from coal seams, have become a priority for chemical, hydrological and biological research during the last few years. Soil and vegetation samples were taken from affected and reference sites (upland elevations and wetted gully) in Juniper Draw to investigate the effects of CBM discharge waters on soil physical and chemical properties and on native and introduced vegetation density and diversity. Results indicate an increase of salinity and sodicity within local soil ecosystems at sites directly exposed to CBM discharge waters. Elevated concentrations of sodium in the soil are correlated with consistent exposure to CBM waters. Clay-loam soils in the study area have a much larger specific surface area than the sandy soils and facilitate a greater sodium adsorption. However, there was no significant relation between increasing water sodium adsorption ratio (SAR) values and increasing sediment SAR values downstream; however, soils exposed to the CBM water ranged from the moderate to severe SAR hazard index. Native vegetation species density was highest at the reference (upland and gully) and CBM affected upland sites. The affected gully had the greatest percent composition of introduced vegetation species. Salt-tolerant species had the greatest richness at the affected gully, implying a potential threat of invasion and competition to established native vegetation. These findings suggest that CBM waters could affect agricultural production operations and long-term water quality.

Wyoming

Contaminant exposure and potential effects on terrestrial vertebrates residing in the National Capital Region network and Mid-Atlantic network

Part of the mission of the National Park Service is to preserve the natural resources, processes, systems, and associated values of its units in an unimpaired condition. Environmental contamination and pollution processes are well recognized stressors addressed by its management policies and plans. A recent study indicates that contemporary terrestrial vertebrate ecotoxicological data are lacking for 59 of 126 Park Service units located in coastal watersheds exhibiting serious water quality problems or high vulnerability to pollution. Based upon these findings, a more in-depth evaluation of contaminant threats and ecotoxicological data gaps related to terrestrial vertebrates was undertaken at 23 Inventory and Monitoring National Park units in National Capital Region and Mid-Atlantic Networks. Ecotoxicological data were compiled for each park unit through literature searches and meetings with Park Service personnel. Information on contemporary and on persistent legacy pollutants in air, water, soil, and terrestrial vertebrates (amphibians, reptiles, birds and mammals) were evaluated. To identify contaminant threats in proximity to the 23 Park Service study units, data was gathered on National Priority List Superfund sites, Section 303(d) Impaired Waterbodies, the number and relative toxicity of current use pesticides and herbicides, Toxic Release Inventory sites and discharge of priority pollutants, and Fish Consumption Advisories. A metric was derived that described the quality and quantity of existing data for each park, and in combination with known contaminant threats, park units in need of additional study were identified. Results demonstrated that over half of the Park Service study units are near Toxic Release Inventory sites discharging dioxins, polychlorinated biphenyls, lead or mercury into air or water, and fish consumption advisories are in effect at or near 22 of the 23 study units. Pesticide and herbicide use at the park units is minimal, with the exception of those units with significant agricultural leases. Despite highly regulated use, many of the pesticides and herbicides applied are believed to be highly toxic to amphibians, and some of the compounds are also highly toxic to birds. Only 70 reports were found that describe terrestrial vertebrate ecotoxicology data on or near the study units. Of the greater than 75,000 compounds in commerce in the United States, existing terrestrial vertebrate exposure and effects data in the pr esent study were limited to 58 legacy organochlorine pesticides, polychlorinated biphenyls and individual congeners, insecticides and rodenticides, metals, and some contemporary compounds (e.g., polybrominated diphenyl ether flame retardants, and alkylphenol and ethoxylate surfactants). Based upon these and other findings, ecotoxicological monitoring and research investigations of terrestrial vertebrates are warranted at several National Parks. These include Shenandoah National Park, Richmond National Battlefield, Chesapeake & Ohio Canal National Historic Park, Valley Forge National Historic Park, Hopewell Furnace National Historic Site, Monocacy National Battlefield, and Harpers Ferry National Historic Park. The types of investigations vary according to the species present at these parks and potential contaminant threats, but should focus on contemporary use pesticides and herbicides, polychlorinated biphenyls, mercury, lead, and perhaps, emerging contaminants including antibiotics, flame retardants, pharmaceuticals, and surfactants. Other management recommendations include additional training for natural resource staff members in the area of ecotoxicology, inclusion of terrestrial vertebrate contaminant monitoring and the Contaminant Assessment Process (U.S. Geological Survey Biomonitoring of Environmental Status and Trends Project) into the National Park Service Vital Signs Program, development of protocols for hand ling and toxicological analysis of dead or seemingly affected wildlife, consideration of some alternative methods and compounds for pest management and weed control, and use of non-toxic fishing tackle by visitors.

Maryland, Pennsylvania, Virginia

Chemistry of unsaturated zone gases sampled in open boreholes at the crest of Yucca Mountain, Nevada: Data and basic concepts of chemical and physical processes in the mountain

Boreholes open to the unsaturated zone at the crest of Yucca Mountain, Nevada, were variously sampled for CO 2 (including 13 C and 14 C), CH 4 , N 2 , O 2 , Ar, CFC-11, CFC-12, and CFC-113 from 1986 to 1993. Air enters the mountain in outcrops, principally on the eastern slope, is enriched in CO 2 by mixing with soil gas, and is advected to the mountain crest, where it returns to the atmosphere. The CFC data indicate that travel times of the advecting gas in the shallow Tiva Canyon hydrogeologic unit are ≤5 years. The 14 C activities are postbomb to depths of 100 m, indicating little retardation of 14 CO 2 in the shallow flow systems. The 14 C activities from 168 to 404 m in the Topopah Spring hydrogeologic unit are 85–90 pMC at borehole USW-UZ6. The CFC data show that the drilling of USW-UZ6 in 1984 has altered the natural system by providing a conduit through the Paintbrush Nonwelded unit, allowing flow from Topopah Spring outcrops in Solitario Canyon on the west to USW-UZ6, upward in the borehole through the Paintbrush, to the shallow Tiva Canyon flow systems, and out of the mountain.

Nevada

Coastal impacts, adaptation, and vulnerabilities: a technical input to the 2013 National Climate Assessment

The coast has long provided communities with a multitude of benefits including an abundance of natural resources that sustain economies, societies, and ecosystems. Coasts provide natural harbors for commerce, trade, and transportation; beaches and shorelines that attract residents and tourists; and wetlands and estuaries that are critical for fisheries and water resources. Coastal ecosystems provide critical functions to cycle and move nutrients, store carbon, detoxify wastes, and purify air and water. These areas also mitigate floods and buffer against coastal storms that bring high winds and salt water inland and erode the shore. Coastal regions are critical in the development, transportation, and processing of oil and natural gas resources and, more recently, are being explored as a source of energy captured from wind and waves. The many benefits and opportunities provided in coastal areas have strengthened our economic reliance on coastal resources. Consequently, the high demands placed on the coastal environment will increase commensurately with human activity. Because 35 U.S. states, commonwealths, and territories have coastlines that border the oceans or Great Lakes, impacts to coastline systems will reverberate through social, economic, and natural systems across the U.S. Impacts on coastal systems are among the most costly and most certain consequences of a warming climate (Nicholls et al., 2007). The warming atmosphere is expected to accelerate sea-level rise as a result of the decline of glaciers and ice sheets and the thermal expansion of sea water. As mean sea level rises, coastal shorelines will retreat and low-lying areas will tend to be inundated more frequently, if not permanently, by the advancing sea. As atmospheric temperature increases and rainfall patterns change, soil moisture and runoff to the coast are likely to be altered. An increase in the intensity of climatic extremes such as storms and heat spells, coupled with other impacts of climate change and the effects of human development, could affect the sustainability of many existing coastal communities and natural resources. This report, one of a series of technical inputs for the third NCA conducted under the auspices of the U.S. Global Change Research Program, examines the known effects and relationships of climate change variables on the coasts of the U.S. It describes the impacts on natural and human systems, including several major sectors of the U.S. economy, and the progress and challenges to planning and implementing adaptation options. Below we present the key findings from each chapter of the report, beginning with the following key findings from Chapter 1: Introduction and Context.

Book

Soil water retention and maximum capillary drive from saturation to oven dryness

This paper provides an alternative method to describe the water retention curve over a range of water contents from saturation to oven dryness. It makes two modifications to the standard Brooks and Corey [1964] (B-C) description, one at each end of the suction range. One expression proposed by Rossi and Nimmo [1994] is used in the high-suction range to a zero residual water content. (This Rossi-Nimmo modification to the Brooks-Corey model provides a more realistic description of the retention curve at low water contents.) Near zero suction the second modification eliminates the region where there is a change in suction with no change in water content. Tests on seven soil data sets, using three distinct analytical expressions for the high-, medium-, and low-suction ranges, show that the experimental water retention curves are well fitted by this composite procedure. The high-suction range of saturation contributes little to the maximum capillary drive, defined with a good approximation for a soil water and air system as H cM = ∫ 0 ∞ K rw dh c , where k rw is relative permeability (or conductivity) to water and h c is capillary suction, a positive quantity in unsaturated soils. As a result, the modification suggested to describe the high-suction range does not significantly affect the equivalence between Brooks-Corey (B-C) and van Genuchten [1980] parameters presented earlier. However, the shape of the retention curve near “natural saturation” has a significant impact on the value of the capillary drive. The estimate using the Brooks-Corey power law, extended to zero suction, will exceed that obtained with the new procedure by 25 to 30%. It is not possible to tell which procedure is appropriate. Tests on another data set, for which relative conductivity data are available, support the view of the authors that measurements of a retention curve coupled with a speculative curve of relative permeability as from a capillary model are not sufficient to accurately determine the (maximum) capillary drive. The capillary drive is a dynamic scalar, whereas the retention curve is of a static character. Only measurements of infiltration rates with time can determine the capillary drive with precision for a given soil.

Water Resources Research

The United States National Climate Assessment - Alaska Technical Regional Report

The Alaskan landscape is changing, both in terms of effects of human activities as a consequence of increased population, social and economic development and their effects on the local and broad landscape; and those effects that accompany naturally occurring hazards such as volcanic eruptions, earthquakes, and tsunamis. Some of the most prevalent changes, however, are those resulting from a changing climate, with both near term and potential upcoming effects expected to continue into the future. Alaska's average annual statewide temperatures have increased by nearly 4°F from 1949 to 2005, with significant spatial variability due to the large latitudinal and longitudinal expanse of the State. Increases in mean annual temperature have been greatest in the interior region, and smallest in the State's southwest coastal regions. In general, however, trends point toward increases in both minimum temperatures, and in fewer extreme cold days. Trends in precipitation are somewhat similar to those in temperature, but with more variability. On the whole, Alaska saw a 10-percent increase in precipitation from 1949 to 2005, with the greatest increases recorded in winter. The National Climate Assessment has designated two well-established scenarios developed by the Intergovernmental Panel on Climate Change (Nakicenovic and others, 2001) as a minimum set that technical and author teams considered as context in preparing portions of this assessment. These two scenarios are referred to as the Special Report on Emissions Scenarios A2 and B1 scenarios, which assume either a continuation of recent trends in fossil fuel use (A2) or a vigorous global effort to reduce fossil fuel use (B1). Temperature increases from 4 to 22°F are predicted (to 2070-2099) depending on which emissions scenario (A2 or B1) is used with the least warming in southeast Alaska and the greatest in the northwest. Concomitant with temperature changes, by the end of the 21st century the growing season is expected to lengthen by 15-25 days in some areas of Alaska, with much of that corresponding with earlier spring snow melt. Future projections of precipitation (30-80 years) over Alaska show an increase across the State, with the largest changes in the northwest and smallest in the southeast. Because of increasing temperatures and growing season length, however, increased precipitation may not correspond with increased water availability, due to temperature related increased evapotranspiration. The extent of snow cover in the Northern Hemisphere has decreased by about 10 percent since the late 1960s, with stronger trends noted since the late 1980s. Alaska has experienced similar trends, with a strong decrease in snow cover extent occurring in May. When averaged across the State, the disappearance of snow in the spring has occurred from 4 to 6 days earlier per decade, and snow return in fall has occurred approximately 2 days later per decade. This change appears to be driven by climate warming rather than a decrease in winter precipitation, with average winter temperatures also increasing by about 2.5°F. The extent of sea ice has been declining, as has been widely published in both national and scientific media outlets, and is projected to continue to decline during this century. The observed decline in annual sea ice minimum extent (September) has occurred more rapidly than was predicted by climate models and has been accompanied by decreases in ice thickness and in the presence of multi-year ice. This decrease was first documented by satellite imagery in the late 1970s for the Bering and Chukchi Seas, and is projected to continue, with the potential for the disappearance of summer sea ice by mid- to late century. A new phenomenon that was not reported in previous assessments is ocean acidification. Uptake of carbon dioxide (CO2) by oceans has a significant effect on marine biogeochemistry by reducing seawater pH. Ocean acidification is of particular concern in Alaska, because cold sea water absorbs CO2 more rapidly than warm water, and a decrease in sea ice extent has allowed increased sea surface exposure and more uptake of CO2 into these northern waters. Ocean acidification will likely affect the ability of organisms to produce and maintain shell material, such as aragonite or calcite (calcium carbonate minerals structured from carbonate ions), required by many shelled organism, from mollusks to corals to microscopic organisms at the base of the food chain. Direct biological effects in Alaska further along the food chain have yet to be studied and may vary among organisms. Some of the potentially most significant changes to Alaska that could result from a changing climate are the effects on the terrestrial cryosphere - particularly glaciers and permafrost. Alaskan glaciers are changing at a rapid rate, the primary driver appearing to be temperature. Statewide, glaciers lost 13 cubic miles of ice annually from the 1950s to the 1990s, and that rate doubled in the 2000s. However, like temperature and precipitation, glacier ice loss is not spatially uniform; most glaciers are losing mass, yet some are growing (for example Hubbard Glacier in southeast Alaska). Alaska glaciers with the most rapid loss are those terminating in sea water or lakes. With this increasing rate of melt, the contribution of surplus fresh water entering into the oceans from Alaska's glaciers, as well as those in neighboring British Columbia, Canada, is approximately 20 percent of that contributed by the Greenland Ice Sheet. Permafrost degradation (that is, the thawing of ice-rich soils) is currently (2012) impacting infrastructure and surface-water availability in areas of both discontinuous and continuous ground ice. Over most of the State, the permafrost is warming, with increasing temperatures broadly consistent with increasing air temperatures. On the Arctic coastal plain of Alaska, permafrost temperatures showed some cooling in the 1950s and 1960s but have been followed by a roughly 5°F increase since the 1980s. Many areas in the continuous permafrost zone have seen increases in temperature in the seasonally active layer and a decrease in re-freezing rates. Changes in the discontinuous permafrost zone are initially much more observable due to the resulting thermokarst terrain (land surface formed as ice rich permafrost thaws), most notable in boreal forested areas. Climate warming in Alaska has potentially broad implications for human health and food security, especially in rural areas, as well as increased risk for injury with changing winter ice conditions. Additionally, such warming poses the potential for increasing damage to existing water and sanitation facilities and challenges for development of new facilities, especially in areas underlain by permafrost. Non-infectious and infectious diseases also are becoming an increasing concern. For example, from 1999 to 2006 there was a statistically significant increase in medical claims for insectbite reactions in five of six regions of Alaska, with the largest percentage increase occurring in the most northern areas. The availability and quality of subsistence foods, normally considered to be very healthy, may change due to changing access, changing habitats, and spoilage of meat in food storage cellars. These and other trends and potential outcomes resulting from a changing climate are further described in this report. In addition, we describe new science leadership activities that have been initiated to address and provide guidance toward conducting research aimed at making available information for policy makers and land management agencies to better understand, address, and plan for changes to the local and regional environment. This report cites data in both metric and standard units due to the contributions by numerous authors and the direct reference of their data.

Alaska

Environmentalism and natural aggregate mining

Sustaining a developed economy and expanding a developing one require the use of large volumes of natural aggregate. Almost all human activity (commercial, recreational, or leisure) is transacted in or on facilities constructed from natural aggregate. In our urban and suburban worlds, we are almost totally dependent on supplies of water collected behind dams and transported through aqueducts made from concrete. Natural aggregate is essential to the facilities that produce energy—hydroelectric dams and coal-fired powerplants. Ironically, the utility created for mankind by the use of natural aggregate is rarely compared favorably with the environmental impacts of mining it. Instead, the empty quarries and pits are seen as large negative environmental consequences. At the root of this disassociation is the philosophy of environmentalism, which flavors our perceptions of the excavation, processing, and distribution of natural aggregate. The two end-member ideas in this philosophy are ecocentrism and anthropocentrism. Ecocentrism takes the position that the natural world is a organism whose arteries are the rivers—their flow must not be altered. The soil is another vital organ and must not be covered with concrete and asphalt. The motto of the ecocentrist is “man must live more lightly on the land.” The anthropocentrist wants clean water and air and an uncluttered landscape for human use. Mining is allowed and even encouraged, but dust and noise from quarry and pit operations must be minimized. The large volume of truck traffic is viewed as a real menace to human life and should be regulated and isolated. The environmental problems that the producers of natural aggregate (crushed stone and sand and gravel) face today are mostly difficult social and political concerns associated with the large holes dug in the ground and the large volume of heavy truck traffic associated with quarry and pit operations. These concerns have increased in recent years as society's demand for living space has encroached on the sites of production; in other words, the act of production has engendered condemnation. Many other environmental problems that are associated with dust and noise and blasting from quarry and pit operations have been reduced through the efficient use of technology. Recycling concrete in buildings, bridges, and roads and asphaltic pavements will ultimately reduce the demand for virgin natural aggregate. The impact created by the large holes in the ground required for the mining of natural aggregate can be greatly reduced by planning their reclamation before mining begins.

Natural Resources Research

Use of ground-based remotely sensed data for surface energy balance evaluation of a semiarid rangeland

An interdisciplinary field experiment was conducted to study the water and energy balance of a semiarid rangeland watershed in southeast Arizona during the summer of 1990. Two subwatersheds, one grass dominated and the other shrub dominated, were selected for intensive study with ground-based remote sensing systems and hydrometeorological instrumentation. Surface energy balance was evaluated at both sites using direct and indirect measurements of the turbulent fluxes (eddy correlation, variance, and Bowen ratio methods) and using an aerodynamic approach based on remote measurements of surface reflectance and temperature and conventional meteorological information. Estimates of net radiant flux density ( R n ), derived from measurements of air temperature, incoming solar radiation, and surface temperature and radiance compared well with values measured using a net radiometer (mean absolute difference (MAD) ≃ 50 W/m 2 over a range from 115 to 670 W/m 2 ). Soil heat flux density ( G ) was estimated using a relation between G / R n and a spectral vegetation index computed from the red and near-infrared surface reflectance. These G estimates compared well with conventional measurements of G using buried soil heat flux plates (MAD ≃ 20 W/m 2 over a range from −13 to 213 W/m 2 ). In order to account for the effects of sparse vegetation, semiempirical adjustments to the single-layer bulk aerodynamic resistance approach were required for evaluation of sensible heat flux density ( H ). This yielded differences between measurements and remote estimates of H of approximately 33 W/m 2 over a range from 13 to 303 W/m 2 . The resulting estimates of latent heat flux density, LE , were of the same magnitude and trend as measured values; however, a significant scatter was still observed: MAD ≃ 40 W/m 2 over a range from 0 to 340 W/m 2 . Because LE was solved as a residual, there was a cumulative effect of errors associated with remote estimates of R n , G , and H .

Water Resources Research

Differential response of carbon fluxes to climate in three peatland ecosystems that vary in the presence and stability of permafrost

Changes in vegetation and soil properties following permafrost degradation and thermokarst development in peatlands may cause changes in net carbon storage. To better understand these dynamics, we established three sites in Alaska that vary in permafrost regime, including a black spruce peat plateau forest with stable permafrost, an internal collapse scar bog formed as a result of thermokarst, and a rich fen without permafrost. Measurements include year-round eddy covariance estimates of carbon dioxide (CO 2 ), water, and energy fluxes, associated environmental variables, and methane (CH 4 ) fluxes at the collapse scar bog. The ecosystems all acted as net sinks of CO 2 in 2011 and 2012, when air temperature and precipitation remained near long-term means. In 2013, under a late snowmelt and late leaf out followed by a hot, dry summer, the permafrost forest and collapse scar bog were sources of CO 2 . In this same year, CO 2 uptake in the fen increased, largely because summer inundation from groundwater inputs suppressed ecosystem respiration. CO 2 exchange in the permafrost forest and collapse scar bog was sensitive to warm air temperatures, with 0.5 g C m −2 lost each day when maximum air temperature was very warm (≥29°C). The bog lost 4981 ± 300 mg CH 4 m −2 between April and September 2013, indicating that this ecosystem acted as a significant source of both CO 2 and CH 4 to the atmosphere in 2013. These results suggest that boreal peatland responses to warming and drying, both of which are expected to occur in a changing climate, will depend on permafrost regime.

Alaska

Seasonal variations in modern speleothem calcite growth in Central Texas, U.S.A

Variations in growth rates of speleothem calcite have been hypothesized to reflect changes in a range of paleoenvironmental variables, including atmospheric temperature and precipitation, drip-water composition, and the rate of soil CO2 delivery to the subsurface. To test these hypotheses, we quantified growth rates of modern speleothem calcite on artificial substrates and monitored concurrent environmental conditions in three caves across the Edwards Plateau in central Texas. Within each of two caves, different drip sites exhibit similar annual cycles in calcite growth rates, even though there are large differences between the mean growth rates at the sites. The growth-rate cycles inversely correlate to seasonal changes in regional air temperature outside the caves, with near-zero growth rates during the warmest summer months, and peak growth rates in fall through spring. Drip sites from caves 130 km apart exhibit similar temporal patterns in calcite growth rate, indicating a controlling mechanism on at least this distance. The seasonal variations in calcite growth rate can be accounted for by a primary control by regional temperature effects on ventilation of cave-air CO2 concentrations and/or drip-water CO2 contents. In contrast, site-to-site differences in the magnitude of calcite growth rates within an individual cave appear to be controlled principally by differences in drip rate. A secondary control by drip rate on the growth rate temporal variations is suggested by interannual variations. No calcite growth was observed in the third cave, which has relatively high values of and small seasonal changes in cave-air CO2. These results indicate that growth-rate variations in ancient speleothems may serve as a paleoenvironmental proxy with seasonal resolution. By applying this approach of monitoring the modern system, speleothem growth rate and geochemical proxies for paleoenviromnental change may be evaluated and calibrated. Copyright ?? 2007, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research

Detection of water quality trends at high, median, and low flow in a Catskill Mountain stream, New York, through a new statistical method

The effects of changes in acid deposition rates resulting from the Clean Air Act Amendments of 1990 should first appear in stream waters during rainstorms and snowmelt, when the surface of the watershed is most hydrologically connected to the stream. Early detection of improved stream water quality is possible if trends at high flow could be separately determined. Trends in concentrations of sulfate (SO 4 2− ), nitrate (NO 3 − ), calcium plus magnesium (Ca 2+ +Mg 2+ ), and acid‐neutralizing capacity (ANC) in Biscuit Brook, Catskill Mountains, New York, were assessed through segmented regression analysis (SRA). The method uses annual concentration‐to‐discharge relations to predict concentrations for specific discharges, then compares those annual values to determine trends at specific discharge levels. Median‐flow trends using SRA were comparable to those predicted by the seasonal Kendall tau test and a multiple regression residual analysis. All of these methods show that stream water SO 4 2− concentrations have decreased significantly since 1983; Ca 2+ +Mg 2+ concentrations have decreased at a steady but slower rate than SO 4 2− ; and ANC shows no trend. The new SRA method, however, reveals trends that differ at specified flow levels. ANC has increased, and NO 3 − concentrations have decreased at high flows, but neither has changed as significantly at low flows. The general downward trend in SO 4 2− flattened at median flow and reversed at high flow between 1997 and 2002. The reversal of the high‐flow SO 4 2− trend is consistent with increases in SO 4 2− concentrations in both precipitation and soil solutions at Biscuit Brook. Separate calculation of high‐flow trends provides resource managers with an early detection system for assessing changes in water quality resulting from changes in acidic deposition.

Water Resources Research

U.S. Geological Survey Subsidence Interest Group conference, Edwards Air Force Base, Antelope Valley, California, November 18-19, 1992; Abstracts and summary

Land subsidence, the loss of surface elevation as a result of the removal of subsurface support, affects every state in the United States. More than 17,000 mi 2 of land in the United States has been lowered by the various processes that produce land subsidence with annual costs from resulting flooding and structural damage that exceed $125 million. It is estimated that an additional $400 million is spent nationwide in attempts to control subsidence. Common causes of land subsidence include the removal of oil, gas, and water from underground reservoirs; dissolution of limestone aquifers (sinkholes); underground mining activities; drainage of organic soils; and hydrocompaction (the initial wetting of dry soils). Overdrafting of aquifers is the major cause of areally extensive land subsidence, and as ground-water pumping increases, land subsidence also will increase. Land subsidence and its effects on engineering structures have been recognized for centuries, but it was not until this century that the processes that produce land subsidence were identified and understood. In 1928, while working with field data from a test of the Dakota Sandstone aquifer, O.E. Meinzer of the U.S. Geological Survey recognized the compressibility of aquifers. Around the same time, Karl Terzaghi, a soil scientist working at Harvard University, developed the one-dimensional consolidation theory that provided a quantitative means of predicting soil compaction resulting from the drainage of compressible soils. Thus, with the recognition of the compressibility of aquifers (Meinzer), and the development of a quantitative means of predicting soil compaction as a consequence of the reduction of intergranular pore pressure (Terzaghi), the theory of aquifer-system compaction was formed. With the widespread availability of electric power in rural areas, and the advent of the deep turbine pump, ground-water withdrawals increased dramatically throughout the country in the 1940's and 1950's. Along with this unprecedented increase in pumpage, substantial amounts of land subsidence were observed in several areas of the United States, most notably in Arizona, California, and Texas. Beginning in 1955, under the direction of Joseph Poland, the Geological Survey began the "Mechanics of Aquifers Project," which focused largely on the processes that resulted in land subsidence due to the withdrawal of ground water. This research team gained international renown as they advanced the scientific understanding of aquifer mechanics and land-subsidence theory. The results of field studies by members of this research group not only verified the validity of the application of Terzaghi's consolidation theory to compressible aquifers, but they also provided definitions, methods of quantification, and confirmation of the interrelation among hydraulic head declines, aquifer-system compaction, and land subsidence. In addition to conducting pioneering research, this group also formed a "center of expertise," providing a focal point within the Geological Survey for the dissemination of technology and scientific understanding in aquifer mechanics. However, when the "Mechanics of Aquifers Project" was phased out in 1984, the focal point for technology transfer no longer existed. Interest among various state and local agencies in land subsidence has persisted, and the Geological Survey has continued to participate in a broad spectrum of cooperative and Federally funded projects in aquifer mechanics and land subsidence. These projects are designed to identify and monitor areas with the potential for land subsidence, to conduct basic research in the processes that control land subsidence and the development of earth fissures, as well as to develop new quantitative tools to predict aquifer-system deformation. In 1989 an ad hoc "Aquifer Mechanics and Subsidence Interest Group" (referred to herein as the "Subsidence Interest Group") was formed

California