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USGS2026

Composite samples for perfluorooctanesulfonate in fish may change contaminant threshold decisions

The widespread occurrence and persistence of the per- and polyfluoroalkyl substances (PFAS) in the environment may pose significant health risks to humans. Fish consumption is a direct pathway for exposure, prompting extensive monitoring. In the United States and Europe, fish consumption advisories for PFAS generally focus on perfluorooctanesulfonate (PFOS), the most frequent and abundant PFAS compound reported in fish. However, PFAS analysis is costly, leading monitoring programs to frequently use composite samples (i.e., combining different fish of the same species). This financial saving comes at an analytical cost of lost information on individual variation. It is unclear how this may influence threshold-based decisions. To test this, we used a modeling approach (i.e., Monte Carlo) based on aggregated data distributions from freshwater fish species. We simulated the measurement of PFOS for individual fish compared to composite means (three, five, and 10 fish) at different levels of error structure. These values were then compared to a typical do-not-eat threshold of 200 ng•g wet mass −1 and four metrics were estimated: (i) the probability of detecting a PFOS concentration above the threshold, (ii) the maximum simulated PFOS concentration, (iii) the number of false negative samples, and (iv) the rate of false negative samples. These results show that the probability of assigning PFOS levels above or below the threshold is shifted by masking individual value contributions in a composite sample. Because true individual contaminant loads are variable, composite sampling is a more conservative metric for contaminant thresholds. The model suggested that the greater the variability, the lower the detection probability for truly contaminated samples. Our study may help to inform sampling for monitoring programs aimed at managing human exposure to PFAS.

Integrated Environmental Assessment and Management↗
USGS1996

Plan for assessment of the occurrence, status, and distribution of volatile organic compounds in aquifers of the United States

The occurrence of volatile organic compounds (VOCs) in water is of national concern because of their relatively high aqueous solubility, mobility, and persistence, because many are known or suspected carcinogens, because of their widespread use, and because they have been found in drinking-water supplies. Because of this national concern, VOCs were selected for National investigation (hereafter termed "National Synthesis") by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program in 1994. The broad goals of this National Synthesis are to: (1) describe current water- quality conditions with respect to VOCs; (2) define trends, or lack of trends, in VOCs in surface and ground water; and (3) identify, describe, and explain causal relations among the occurrence and distribution of VOCs in surface water and ground water, and natural and human factors. The National Synthesis of VOCs in ground water has three objectives: (1) to describe their occurrence, status, and distribution; (2) to determine relations among VOCs in shallow ground water and natural and human factors; and (3) to determine, compare, and contrast the occurrence, transformation, transport, and fate of selected VOCs in the hydrologic cycle for several regionally or nationally important aquifer systems. The description of VOC occurrence, status, and distribution in ground water focuses on major aquifers of the United States. Occurrence describes the presence or absence of VOCs, their frequency of occurrence, and their ranges of concentrations. Status compares the concentrations of VOCs detected in relation to water-quality regulations or advisories, such as Maximum Contaminant Levels, Proposed Maximum Contaminant Levels, Maximum Contaminant Level Goals, and Health Advisories. Distribution describes the variability of VOCs in ground water, areally and by depth. This report describes the study design for conducting such an assessment. The assessment focuses on aquifers, or parts of aquifers, that are currently used or have the potential to be used as sources of water supplies, using data collected as part of local, State, and Federal ground-water monitoring programs since 1985. Assessment by aquifer and comparison of results among aquifers will be completed for those aquifers for which adequate spatial or depth-related data are available. Assessment of VOCs in aquifers also will be completed at regional and national scales. A set of criteria for well-network design, well construction, sample-collection methods, and methods of laboratory analysis must be met before VOC data are used for assessment. An appropriate well-network design will provide a generally unbiased, random, equal-area distribution of sampling sites throughout the aquifer, or part of the aquifer, of interest. Well-construction information must be sufficient to ensure that the hydrogeologic unit (or units) represented by the water level measured and the hydrologic unit (or units) contributing water to the well are known. In addition, the well construction and pumping equipment in the well need to be of a type that are not likely to affect concentrations of VOCs in the water sample. VOC data will be considered suitable for use in the occurrence assessment if nationally accepted methods for collection and analysis were used and if the quantitation level for VOC analytes was less than about 5 micrograms per liter; laboratory analysis was done by a laboratory certified by the U.S. Environ- mental Protection Agency; and the sample was collected from untreated (raw) water at or near the well head before being held in a pressure tank or holding tank.

Open-File Report↗
USGS1994

Agricultural pesticides in six drainage basins used for public water supply in New Jersey, 1990

A reconnaissance study of six drainage basins in New Jersey was conducted to evaluate the presence of pesticides from agricultural runoff in surface water. In the first phase of the study, surface-water public-supply drainage basins throughout New Jersey that could be affected by pesticide applications were identified by use of a Geographic Information System. Six basins--Lower Mine Hill Reservoir, South Branch of the Raritan River, Main Branch of the Raritan River, Millstone River, Manasquan River, and Matchaponix Brook--were selected as those most likely to be affected by pesticides on the basis of calculated pesticide-application rates and percentage of agricultural land. The second phase of the project was a short-term water-quality reconnaissance of the six drainage basins to determine whether pesticides were present in the surface waters. Twenty-eight surface-water samples (22 water-quality samples, 3 sequentially collected samples, and 3 trip blanks), and 6 samples from water-treatment facilities were collected. Excluding trip blanks, samples from water-treatment facilities, and sequentially collected samples, the pesticides detected in the samples and the percentage of samples in which they were detected, were as follows: atrazine and metolachlor, 86 percent; alachlor, 55 percent; simazine, 45 percent; diazinon, 27 percent; cyanazine and carbaryl, 23 percent; linuron and isophenfos, 9 percent; and chlorpyrifos, 5 percent.Diazinon, detected in one stormflow sample collected from Matchaponix Brook on August 6, 1990, was the only compound to exceed the U.S. Environmental Protection Agency's recommended Lifetime Health Advisory Limit. Correlation between ranked metolachlor concentrations and ranked flow rates was high, and 25 percent of the variance in metolachlor concentrations can be attributed to variations in flow rate. Pesticide residues were detected in samples of pretreated and treated water from water-treatment facilities. Concentrations of all pesticides detected in the treated water were lessthan the U.S. Environmental Protection Agency's recommended Lifetime Health Advisory Limits.

Water-Resources Investigations Report↗
USGS2009

Results of the Analyses for 1,4-Dioxane of Groundwater Samples Collected in the Tucson Airport Remediation Project Area, South-Central Arizona, 2006-2009

Extensive groundwater contamination resulting from industrial activities led to the listing of the Tucson International Airport Area (TIAA) as a Superfund Site by the U.S. Environmental Protection Agency (USEPA) in 1983. Early investigations revealed elevated levels of volatile organic compounds (VOCs), including the chlorinated solvents trichloroethylene and perchloroethylene, in wells in the area. Several responsible parties were identified, and cleanup activities were initiated in the late 1980s using technology designed for removal of VOCs. In 2002, the compound 1,4-dioxane was discovered in wells in the TIAA area. Since then, 1,4-dioxane has been detected throughout the TIAA area at levels exceeding the USEPA Drinking Water Health Advisory value of 3 micrograms per liter (ug/L; U.S. Environmental Protection Agency, 2006). Chemical properties of 1,4-dioxane make it relatively unaffected by the treatment technologies employed in the TIAA area. In 2006, the U.S. Geological Survey (USGS) Arizona Water Science Center, in cooperation with the U.S. Air Force Center for Engineering and the Environment, began an investigation into the extent of groundwater contamination by 1,4-dioxane in the area. Five rounds of groundwater sampling in the TIAA area have been completed by the USGS since that time, yielding a total of 210 samples. Results from these analyses indicate less than reportable concentrations of 1,4-dioxane in 30 percent of the samples, with 46 percent of the samples having concentrations at or above the USEPA Drinking Water Health Advisory level.

Open-File Report↗
USGS1993

Hydrologic and land-use factors associated with herbicides and nitrate in near-surface aquifers

Selected herbicides, atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) metabolites, and NO − 3 were examined in near-surface unconsolidated and bedrock aquifers in the midcontinental USA to study the hydrogeologic, spatial, and seasonal distribution of these contaminants. Groundwater samples were collected from 303 wells during the spring and late summer of 1991. At least one herbicide or atrazine metabolite was detected in 24% of the samples collected for herbicide analysis (reporting limit 0.05 µ g/L). No herbicide concentration exceeded the USEPA's maximum contaminant level (MCL) or health advisory level. The most frequently detected compound was the at razine metabolite deethylatrazine [2-amino-4-chloro-6-(isopropylamino)-s-triazine] followed by atrazine, deisopropylatrazine [2-amino-4-chloro-6-(ethylamino)-s-triazine], prometon (2,4-bis(isopropylamino)-6-methyoxy-s-triazine), metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1methylethyl)acetamide], alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide], metribuzin [4-amino-6-( tert -butyl)-3-methylthio- as -triazine-5(4H)-one], simazine [2-chloro-4,6-bis(ethylamino)-s-triazine], and cyanazine [2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropionitrile]. Nitrite plus nitrate, as nitrogen (N), exceeding 3.0 mg/L (excess NO − 3 ), was found in 29% of the samples, and 6% had − 3 exceeding the MCL of 10 mg/L. Ammonium as N was detected in excess of 0.01 mg/L in 78% of the samples. A nonlinear increase in the frequency of atrazine detection occurred with decreases in reporting limit. The frequency of atrazine residue detection (atrazine + deethylatrazine + deisopropylatrazine) was 25% greater than for atrazine alone. Herbicide detections and excess NO − 3 were notably lacking in the eastern part of the study region where it was estimated that herbicide and fertilizer use were among the largest in the region. Prometon, the second most frequently detected herbicide, was associated with non-agricultural land use. Herbicide and excess NO − 3 were more frequent in unconsolidated aquifers than in bedrock aquifers. Aquifer depth, as direct measurement of proximity to recharge sources, was inversely related to frequency of herbicide detection and excess NO − 3 .

Journal of Environmental Quality↗
USGS1994

Hydrologic Instrumentation Facility of the U.S. Geological Survey, annual report for fiscal year 1993

The Hydrologic lnstrumentation Facility (HIF) of the U.S. Geological Survey (USGS) has nationwide responsibility for all aspects of hydrologic field instrumentation in support of Survey data-collection programs. Each year the HIF publishes a report to inform Water Resources Division (WRD) personnel of progress made by the HIF in fulfilling its mission to improve instrumentation services to the Division. The report for fiscal year 1993 (FY93) describes the activities of the HIF, including major accomplish- ments for the year; personnel actions; active projects (reported by section--Technical Services Section, Administrative Services Section, Field Coordination, Applications and Development Section, Test and Evaluation Section, Field Service and Supply Section); and planned activities for the coming year. Also presented in the appendixes are detailed listings of the memberships of the Instrumentation Committee and the Instrumentation Technical Advisory Subcommittee; district, sub- district, and field office visits by HIF personnel; professional and technical meetings attended by HIF personnel; vendor visits; and reports prepared by HIF personnel.

Open-File Report↗
USGS2007

Predicting and validating the motion of an ash cloud during the 2006 eruption of Mount Augustine volcano

On 11 January 2006, Mount Augustine volcano in southern Alaska began erupting after 20- year repose. The Anchorage Forecast Office of the National Weather Service (NWS) issued an advisory on 28 January for Kodiak City. On 31 January, Alaska Airlines cancelled all flights to and from Anchorage after multiple advisories from the NWS for Anchorage and the surrounding region. The Alaska Volcano Observatory (AVO) had reported the onset of the continuous eruption. AVO monitors the approximately 100 active volcanoes in the Northern Pacific. Ash clouds from these volcanoes can cause serious damage to an aircraft and pose a serious threat to the local communities, and to transcontinental air traffic throughout the Arctic and sub-Arctic region. Within AVO, a dispersion model has been developed to track the dispersion of volcanic ash clouds. The model, Puff, was used operational by AVO during the Augustine eruptive period. Here, we examine the dispersion of a volcanic ash (or aerosol) cloud from Mount Augustine across Alaska from 29 January through the 2 February 2006. We present the synoptic meteorology, the Puff predictions, and measurements from aerosol samplers, laser radar (or lidar) systems, and satellites. Aerosol samplers revealed the presence of volcanic aerosols at the surface at sites where Puff predicted the ash clouds movement. Remote sensing satellite data showed the development of the ash cloud in close proximity to the volcano consistent with the Puff predictions. Two lidars showed the presence of volcanic aerosol with consistent characteristics aloft over Alaska and were capable of detecting the aerosol, even in the presence of scattered clouds and where the ash cloud is too thin/disperse to be detected by remote sensing satellite data. The lidar measurements revealed the different trajectories of ash consistent with the Puff predictions. Dispersion models provide a forecast of volcanic ash cloud movement that might be undetectable by any other means but are still a significant hazard. Validation is the key to assessing the accuracy of any predictions. The study highlights the use of multiple and complementary observations used in detecting the trajectory ash cloud, both at the surface and aloft in the atmosphere.

Alaska↗
USGS2017

Synthesis of data from high-frequency nutrient and associated biogeochemical monitoring for the Sacramento–San Joaquin Delta, northern California

Executive Summary This report is the second in a series of three reports that provide information about high-frequency (HF) nutrient and biogeochemical monitoring in the Sacramento–San Joaquin Delta of northern California (Delta). The purpose of this report is to synthesize the data available from a nutrient and water-quality HF (about every 15 minutes) monitoring network operated by the U.S. Geological Survey in the northern Delta. In this report, we describe the network and focus on the purpose of each station. We then present and discuss the available data, at various timescales—first at the monthly, seasonal, and inter-annual timescales, and second, for comparison, at the tidal and event timescales. As expected, we determined that there is substantial variability in nitrate-N concentrations at short timescales within hours, but also significant variability at longer timescales such as months or years. Resolving this variability is made possible by the HF data, with the largest variability caused by storms, tides, and diel biological processes. Given this large temporal variability, calculations of cumulative nutrient fluxes (for example, daily, monthly, or annual loads) is difficult without HF data. For example, in the Cache Slough, calculation of the annual load without the tidal variability resulted in a 30 percent underestimation of the true annual load value. We conclude that HF measurements are important for accurate determination of fluxes and loads in tidal environments, but, more importantly, provide important insights into processes and rates of nutrient cycling. This report, along with the other two reports of this series (Bergamaschi and others, 2017; Kraus, Bergamaschi, and others, 2017), was drafted in cooperation with the Delta Regional Monitoring Program to help scientists, managers, and planners understand how HF data improve our understanding of nutrient sources and sinks, drivers, and effects in the Delta. The first report in the series (Kraus, Bergamaschi, and others, 2017) provides an introduction to the reasons for and fundamental concepts behind using HF monitoring measurements, including a brief summary of nutrient status and trends in the Delta and an extensive literature review showing how and where other research and monitoring programs have used HF monitoring to improve our understanding of nutrient cycling. The report covers the various technologies available for HF nutrient monitoring and presents the different ways HF monitoring instrumentation may be used for fixed station and spatial assessments. Finally, it presents numerous examples of how HF measurements are currently (2017) being used in the Delta to examine how nutrients and nutrient cycling are related to aquatic habitat conditions. The third report in the series (Bergamaschi and others, 2017) provides the background, principles, and considerations for designing an HF nutrient-monitoring network for the Delta to address high-priority, nutrient-management questions. The report starts with discussion of the high‑priority management questions to be addressed, continues through discussion of the questions and considerations that place demands and constraints on network design, discusses the principles applicable to network design, and concludes with the presentation of three example nutrient-monitoring network designs for the Delta, proposed to address high-priority questions identified by the Delta Regional Monitoring Program (Delta Regional Monitoring Program Technical Advisory Committee, 2015).

California↗
USGS2017

An introduction to high-frequency nutrient and biogeochemical monitoring for the Sacramento–San Joaquin Delta, northern California

Executive Summary This report is the first in a series of three reports that provide information about high-frequency (HF) nutrient and biogeochemical monitoring in the Sacramento–San Joaquin Delta of northern California (Delta). This first report provides an introduction to the reasons for and fundamental concepts behind collecting HF measurements, and describes the benefits associated with a real-time, continuous, HF, multi-parameter water quality monitoring station network that is co-located with flow stations. It then provides examples of how HF nutrient measurements have improved our understating of nutrient sources and cycling in aquatic systems worldwide, followed by specific examples from the Delta. These examples describe the ways in which HF instrumentation may be used for both fixed-station and spatial assessments. The overall intent of this document is to describe how HF measurements currently (2017) are being used in the Delta to examine the relationship between nutrient concentrations, nutrient cycling, and aquatic habitat conditions. The second report in the series (Downing and others, 2017) summarizes information about HF nutrient and associated biogeochemical monitoring in the northern Delta. The report synthesizes data available from the nutrient and water quality monitoring network currently operated by the U.S. Geological Survey in this ecologically important region of the Delta. In the report, we present and discuss the available data at various timescales—first, at the monthly, seasonal, and inter-annual timescales; and, second, for comparison, at the tidal and event (for example, storms, reservoir releases, phytoplankton blooms) timescales. As expected, we determined that there is substantial variability in nitrate concentrations at short timescales within hours, but also significant variability at longer timescales such as months or years. This multi-scale, high variability affects calculation of fluxes and loads, indicating that HF monitoring is necessary for understanding and assessing flux-based processes and outcomes in tidal environments, such as the Delta. The third report in the series (Bergamaschi and others, 2017) provides information about how to design HF nutrient and biogeochemical monitoring for assessment of nutrient inputs and dynamics in the Delta. The report provides background, principles, and considerations for designing an HF nutrient-monitoring network for the Sacramento–San Joaquin Delta to address high-priority, nutrient-management questions. The report starts with high-priority management questions to be addressed, continues with questions and considerations that place demands and constraints on network design, discusses the principles applicable to network design, and concludes with the presentation of three example nutrient‑monitoring network designs for the Delta. For the three example networks, we assess how they would address high-priority questions identified by the Delta Regional Monitoring Program (Delta Regional Monitoring Program Technical Advisory Committee, 2015).

California↗
USGS2010

Concentration of 1,4-Dioxane in Wells Sampled During 2002-2009 in the Vicinity of the Tucson International Airport Area Superfund Site, Arizona

Extensive groundwater contamination resulting from industrial activities led to the listing of the Tucson International Airport Area as a Superfund Site in 1983. Early investigations revealed elevated levels of volatile organic compounds (VOCs) including the chlorinated solvents trichloroethylene (TCE) and perchloroethylene (PCE) in wells in the area. Several responsible parties were identified and cleanup activities were begun in the late 1980s using technology designed for removal of VOCs. In 2002, the compound 1,4-dioxane was discovered in wells in the Tucson Airport Remediation Project (TARP) area. Since then, 1,4-dioxane has been detected throughout the TARP area, in some cases exceeding the U.S. Environmental Protection Agency (USEPA) drinking water advisory level of 3 ?g/L.

Scientific Investigations Map↗
USGS2008

Physicochemical properties and chemical characteristics of water, bed sediment, and mussel tissue from selected streams near the Redleg and Peason Ridge impact areas, Fort Polk Military Reservation, Louisiana, June 2001 - November 2003

At the request of the U.S. Army Joint Readiness Training Center and Fort Polk, the U.S. Geological Survey collected and analyzed water, bed-sediment, and mussel-tissue samples from selected streams near the Redleg impact area (RIA) and Peason Ridge impact areas (PRIA) at the Fort Polk Military Reservation (Reservation), Louisiana. from June 2001 through November 2003. Samples were collected from 13 sites, including 2 reference sites. Water was analyzed for physicochemical properties; water and bed sediment were analyzed for major inorganic ions, cyanide, perchlorate, trace elements, total organic carbon, nutrients, and explosive compounds; and mussel tissue from three sites was analyzed for explosive compounds only. The two reference sites, one near the RIA and one near the PRIA, were selected to provide baseline data for these areas. Streams near the RIA were acidic and low in buffering capacity. with pH measurements ranging from 5.0 to 6.6. Cation concentrations were less than or equal to E3.3J mg/L (E, estimated; J, method blank contamination; milligrams per liter), and anion concentrations were less than or equal to E7.3 mg/L. Field measurements and major inorganic ions concentrations were similar to the RIA reference site and to previously sampled nearby streams, indicating streams near the RIA were typical of streams near the eastern part of the Main Post. Streams near the PRIA were slightly acidic to neutral and low in buffering capacity, with pH measurements ranging from 5.7 to 6.9. Cation concentrations were less than or equal to 6.2 mg/L, and anion concentrations were less than or equal to 16 mg/L. Streams near the PRIA were higher than the RIA for most physicochemical properties and constituents, hut typical of streams near the headwaters of the Calcasieu River. All concentrations of sulfate, chloride, and fluoride were less than the U.S. Environmental Protection Agency (USEPA) Secondary Drinking-Water Regulations (SDWR) of 250, 250, and 2.0 mg/L, respectively. Concentrations of cations calcium, magnesium. and potassium for sites near both the RIA and PRIA were higher in depositional bed-sediment samples than in bulk samples. Higher cation concentrations were likely due to higher clay and organic content in the depositional samples. The trace elements detected in the highest concentrations in water and bed sediment were aluminum, iron, and manganese. All aluminum concentrations in water were within the range or greater than the USEPA SDWR range from 50 to 200 ug/L (micrograms per liter). All but four iron concentrations in water exceeded the SDWR. Manganese concentrations in seven water samples at the RIA sites and four samples at the PRIA sites were greater than the SDWR. These concentrations of cations were consistent with soil characteristics and low pH measurements of stream water and rainfall in the area. All other trace-element concentrations in water were less than regulatory guidelines and regulations except the USEPA Maximum Contaminant Level Goal of 0 ug/L for arsenic and lead and 0.5 u/L for thallium. Arsenic, lead, and thallium concentrations were similar to those detected in blank samples or those reported for the reference sites. The Canadian Council of Ministers of the Environment (CCME) has established bed-sediment guidelines for seven trace elements: arsenic, cadmium, chromium, copper, lead, mercury, and zinc. No concentrations exceeded the CCME Probable Effect Level, and only one arsenic concentration of 8.87 mg/kg (milligrams per kilogram), in a depositional sample from one of the RIA sites, exceeded the CCME Interim Sediment Quality Guideline of 5.9 mg/kg. The median concentrations of total organic carbon in water were 5.3 mg/L at the RIA and 4.0 mg/L at the PRIA, and both concentrations were less than the average dissolved organic carbon concentration of 5.75 mg/L for all world rivers. All detected nutrient concentrations in water were less than USEPA guidelines and regulations. The largest nutrient concentrations in water and bed-sediment samples were total organic nitrogen, measured as total Kjeldahl nitrogen; they included a maximum concentration of 0.53 mg/L in water at the RIA sites, E0.38 mg/L in water at the PRIA sites, 294 mg/kg in hulk bed sediment. and 1,740 mg/kg in depositional bed sediment. Four explosive compounds, 1,3,5-trinitrobenzene, 2,4,6-trinitrotoluene, RDX (hexahydro-1,3,5-trinitro-1,3,5- triazine), and tetryl, were detected in water near the RIA; one compound, HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7- tetrazocine), was detected in bed sediment near the PRIA; and one compound, nitroglycerin, was detected in mussel tissue near the RIA. The most frequently detected explosive compound, RDX, was detected in 10 water samples from 5 sites near the RIA. Concentrations of explosive compounds in water were less than USEPA Health Advisories available for reference.

Louisiana↗
USGS2007

Mercury speciation in piscivorous fish from mining-impacted reservoirs

Guadalupe Reservoir (GUA), California, and Lahontan Reservoir (LAH), Nevada, U.S. are both affected either directly or indirectly by the legacy of gold and silver mining in the Sierra Nevada during the nineteenth century. Analysis of total mercury in fish from these lentic systems consistently indicate elevated concentrations (>1 μg·g-1 wet weight; hereinafter, all concentrations are reported as wet weight unless indicated otherwise) well above the U.S. Environmenal Protection Agency's human consumption advisory level for fish (<0.3 μg·g-1). Replicate X-ray absorption near edge structure (XANES) analyses on largemouth bass and hybrid striped bass from GUA and LAH were performed to determine predominant chemical species of mercury accumulated by these high-trophic-level piscivores that are exposed to elevated mercury through trophic transfer in mining-impacted lentic systems. Despite distinct differences in mercury source, the proximity of the source, and concentrations of complexing ligands, results of XANES analysis clearly indicated that mercury accumulated in these individual fish from the two reservoirs were dominated by methylmercury cysteine complexes. These findings are consistent with results from commercial fish species inhabiting marine environments which are presumed to include differing mercury sources (e.g., atmospheric, hydrothermal, or benthic). The dominance of methylmercury cysteine complexes in muscle tissues of fish obtained from such contrasting environments and exposure conditions suggests that a generic toxicological model for the consumption of fish could be applicable over a wide range of ecologic settings.

Environmental Science & Technology↗
USGS2019

Evaluation of recommended revisions to Bulletin 17B

For the past 36 years, Bulletin 17B, published by the Interagency Committee on Water Data in 1982, has guided flood-frequency analyses in the United States. During this period, much has been learned about both hydrology and statistical methods. In keeping with the tradition of periodically updating the Bulletin 17B guidelines in light of advances in our understanding and methods, the Hydrologic Frequency Analysis Work Group (HFAWG) was charged by the Subcommittee on Hydrology (SOH) of the Advisory Committee on Water Information (ACWI) to consider possible updates to Bulletin 17B. The purpose of this report is to consider the statistical performance of possible revisions to Bulletin 17B procedures. Of particular interest are procedures designed to accommodate more general forms of flood information. The concern is how the proposed procedures would affect the precision, accuracy and robustness of flood-frequency estimates. The investigations reported here focus on techniques for the following: incorporating information related to historical flooding that occurred outside the period of systematic streamgaging; and identification of potentially influential low floods (PILFs). The proposed changes, which mostly involve generalizing Bulletin 17B’s method-of-moments procedures by using the Expected Moments Algorithm (EMA), are relatively modest, at least in the sense that they would not affect the main features of Bulletin 17B. The proposed methods include the following: continued use of the log-Pearson Type 3 (LP3) distribution; continued use of the Method-of-Moments fitting method applied to the logarithms of annual-peak-flow data; and a generalization of the Grubbs-Beck test used in Bulletin 17B to identify low outliers. The new multiple Grubbs-Beck test is sensitive to multiple PILFs. The hydrological literature already provides extensive support for the theory behind the proposed changes. The remaining question is practical: How well do the proposed methods perform under typical and realistic conditions and, specifically, with difficult records occasionally encountered in practice? In order to answer these questions, the HFAWG commissioned the work reported here. The following four major sets of results are provided: Monte Carlo simulations of fitting procedures employing data drawn from simulated LP3 populations; Monte Carlo simulations of fitting procedures employing data drawn from non-LP3 populations that were selected to reflect likely deviations of flood series from LP3 distributions, based on the experience of HFAWG members; a direct comparison of the fitted LP3 distributions for 82 real “test sites” identified by an independent data group as both “typical” and “challenging” for flood-frequency estimation; and simulations of fitting procedures using records obtained by resampling with replacement from the longest of the 82 test-site records. Collectively, these studies provide a reasonably comprehensive, valid, and robust assessment of the properties of the Bulletin 17B methods and proposed alternatives. The experiments and analysis indicate that the flood quantile estimators, proposed as a revision of Bulletin 17B, do the following: perform generally as well as, and in some cases much better than, Bulletin 17B estimators in terms of the mean square error of flood quantiles estimates; allow for incorporation and efficient statistical treatment of broader classes of flood-frequency data and information, including historical information, binomial data and interval data; and generally confirm studies and the theoretical findings reported in the hydrological literature that would support use of updated estimation procedures that have been developed since Bulletin 17B was published.

Open-File Report↗
USGS2020

Energy and minerals division tight oil and gas committee: Activities and commodity report for 2019-2020

In 2019, total daily tight oil and gas production increased in the United States month over month, with annualized growth of 14% for oil and 12% for gas. Those gains leveled off in the first quarter of 2020 due to aggressive price competition and increases in international production. Then came the pandemic with a substantially larger dose of economic turmoil, driving down demand due in part to shelter in place orders and safety concerns around travel. Between March and May, tight oil and gas production dropped by nearly 2 million bpd and almost 5 Bcf/day before beginning to recover. Production has continued to increase for the most part through the second half of 2020, but drilling remains subdued throughout most of the U.S. and uncertainty around long term demand along with the current price environment and general state of the economy has contributed to layoffs throughout the industry. Some shale-gas production has declined recently, but a few areas have seen expansion due to construction of LNG facilities along the East Coast of the U.S. (e.g., the Haynesville Formation). Current U.S. shale-gas production is still higher now than in 2019, with daily production of almost 71 Bcf as of October 2020 driven in large part by increased production from the Marcellus Shale in the Appalachian Basin and shales within the Permian Basin. Shale liquids production is down by around a million bpd to approximately 7.1 million (September 2020; U.S. EIA) from pre-pandemic production levels at the end of 2019 and beginning of 2020. Tight oil production remains dominated by plays in the Permian Basin as well as the Bakken and Eagle Ford Formations. On the development and production front, new enhanced oil recovery approaches for tight shale reservoirs are being more widely implemented. Natural gas or CO2 injection is currently being utilized in the Bakken Formation, Eagle Ford Formation, Anadarko Basin, and the Permian Basin to optimize injection sequences and boost recovery. Refracturing of existing wells to reduce drilling costs, improve production, and prolong well productive life has also begun to occur more widely in developed plays. International interest in exploiting hydrocarbons from unconventional reservoirs continues to develop, with active exploration projects on most continents. Europe remains relatively underexplored as compared to North America, although a total of 141 exploration and appraisal wells with a possible shale-gas exploration component have been spudded, including horizontal legs from vertical wells. Shale exploration has made a breakthrough in China with shale gas output in 2019 of 10 billion cubic meters (35.3 Bcf), 60% of which was produced from Sinopec’s Fuling Shale Gas field. Lacustrine shale oil exploration has also been successful in the Sichuan and Ordos Basins in central China, Junggar and Tarim Basins in northwest China, and Songliao Basin in north China, and Bohai Bay Basins in northeast China as of 2018. South America’s potential as an unconventional shale gas and oil province is mainly in Argentina and Brazil, where the production from Neuquen Basin’s tight shale of the Vaca Muerta Formation has been steadily increasing since 2016, but only 4% of the shale resource has been developed thus far. According to International Energy Agency’s report in 2013, Brazil holds the 9th largest unconventional gas reserves. Brazil has shale oil and gas potential in the Parana, Solimoes and Amazon Basins and is actively producing from the oil shale unit of the Irati Formation. In 2019, the Brazil energy ministry launched REATE 2020 to boost onshore investments that include the expectation of drilling an experimental unconventional well in the northeast region. For this inaugural report, the new AAPG EMD Tight Oil and Gas Committee (TO&G; formerly the Shale Gas & Liquids and Tight Gas Sands committees) has developed new commodity report requirements for contributors. This includes shorter annual reports focused on new developments, play concepts, along with the typical updates on production and new drilling in the play areas they cover. We are also asking contributors to collect background geologic and production related information into a document that summarizes important features of the plays they cover that will be stored on the TO&G webpage along with our commodity reports. TO&G is currently working to expand the number of contributors to cover more play areas and replace committee and advisory board members that have recently stepped down. Changes to committee leadership occurred in October as recent chairs transition to EMD elected positions.

Activities and Commodities Report↗
USGS2018

Science support for evaluating natural recovery of polychlorinated biphenyl concentrations in fish from Crab Orchard Lake, Crab Orchard National Wildlife Refuge, Illinois

Introduction Crab Orchard Lake in southern Illinois is one of the largest and most popular recreational lakes in the state. Construction of the nearly 7,000-acre reservoir in the late 1930s created employment opportunities through the Works Progress Administration, and the lake itself was intended to supply water, control flooding, and provide recreational opportunities for local communities (Stall, 1954). In 1942, the Department of War appropriated or purchased more than 20,000 acres of land around Crab Orchard Lake and constructed the Illinois Ordnance Plant, which manufactured bombs and anti-tank mines during World War II. After the war, an Act of Congress transferred the property to the U.S. Department of the Interior. Crab Orchard National Wildlife Refuge was established on August 5, 1947, for the joint purposes of wildlife conservation, agriculture, recreation, and industry. Production of explosives continued, but new industries also moved onsite. More than 200 tenants have held leases with Crab Orchard National Wildlife Refuge and have operated a variety of manufacturing plants (electrical components, plated metal parts, ink, machined parts, painted products, and boats) on-site. Soils, water, and sediments in several areas of the refuge were contaminated with hazardous substances from handling and disposal methods that are no longer acceptable environmental practice (for example, direct discharge to surface water, use of unlined landfills). Polychlorinated biphenyl (PCB) contamination at the refuge was identified in the 1970s, and a PCB-based fish-consumption advisory has been in effect since 1988 for Crab Orchard Lake. The present advisory covers common carp ( Cyprinus carpio ) and channel catfish ( Ictalurus punctatus ); see Illinois Department of Public Health (2017). Some of the most contaminated areas of the refuge were actively remediated, and natural ecosystem recovery processes are expected to further reduce residual PCB concentrations in the lake. The U.S. Fish and Wildlife Service sought technical support to understand environmental drivers of current (2017) PCB residues in fish tissue and patterns in PCB residues through time to inform the fish-consumption advisory for Crab Orchard Lake. This project is planned in two phases (Tasks 1 and 2); the first phase is included in this report. Task 1, reported here, includes a review of existing literature and a brief overview focused on environmental and biochemical/physiological processes that drive PCB residues in fish tissue. This review specifically targets processes that are relevant for freshwater lacustrine environments such as those at Crab Orchard Lake. In addition to discussions of environmental fate, metabolism, and accumulation of PCBs, this review includes a brief scientifically based explanation of approaches used to establish fish-consumption advisories. A planned second task (Task 2) will include a compilation and summary of existing data on PCB residues in fish tissue samples from Crab Orchard Lake. This summary will also place Crab Orchard Lake data in a broader geographic context through a comparison with fish data from other Midwestern lakes. When Task 1 and Task 2 are complete, resource managers will have (a) a synthesis of existing literature that characterizes the processes influencing the fate of residual PCBs remaining in systems such as Crab Orchard Lake, (b) a summary of natural PCB attenuation processes for use in risk communication with the public, and (c) a summary of existing data on PCBs in fish tissues from Crab Orchard Lake, including exploratory plots of tissue residues through time. Overall, this project will provide data to help resource managers better understand the ecological and public health consequences of residual PCBs in Crab Orchard Lake.

Illinois↗
USGS2024

Assessment of per- and polyfluoroalkyl substances in water resources of New Mexico, 2020–21

Per- and polyfluoroalkyl substances (PFAS) have been detected in public and private drinking-water wells, springs, and surface waters in New Mexico; however, the presence and distribution of PFAS in water resources across the State are not well characterized. From August 2020 to October 2021, the U.S. Geological Survey, in cooperation with the New Mexico Environment Department, collected water-quality samples from groundwater and surface-water sites throughout New Mexico. One hundred and seventeen groundwater wells were sampled from unconfined water-table aquifers for PFAS and a geochemical suite including major ions, trace elements, nutrients, dissolved organic carbon (DOC), stable isotopes of oxygen and hydrogen, tritium, and carbon-14 to provide context for groundwater age and geochemical evolution. Eighteen surface-water samples were analyzed for PFAS, and select samples were analyzed for wastewater tracers, major ions, trace elements, and DOC. Blanks and replicates indicated low bias and variability for PFAS, wastewater tracers, and geochemical compounds. Twenty-seven of the 117 groundwater sites had PFAS concentrations reported above the detection level, and there were no exceedances of the 2016 U.S. Environmental Protection Agency health advisory of 70 nanograms per liter (ng/L) perfluorooctanoic acid plus perfluorooctane sulfonic acid. Twenty-two sites were resampled and showed similar signatures, excluding some springs. Total PFAS concentrations ranged from 0.91 to 80.3 ng/L. The most frequently detected PFAS at groundwater sites were perfluorobutanesulfonic acid (PFBS; 11 sites), perfluoropentanoic acid (10 sites), and perfluorohexanoic acid (9 sites). Correlations were found between certain PFAS compounds that suggest similar sources. PFAS were also correlated with tritium, DOC, and nitrate, which indicated that a presence of anthropogenic compounds could in turn indicate a likelihood of PFAS occurrence. In addition, a cluster analysis showed that varying geochemical processes and sources of anthropogenic compounds likely contribute to the PFAS signature of each groundwater sample. Surface-water samples showed variable total PFAS concentrations ranging from 1.0 to 155.4 ng/L. Sites downstream from urban areas showed numerous PFAS detections. Some undeveloped areas where minimal PFAS detections would be expected had PFAS detections. Correlations between PFAS were found that suggested similar sources. Perfluoropentanoic acid and PFBS were the most frequently detected PFAS, and PFBS had the highest single concentration of 93 ng/L. Results of the study provide an overview of PFAS occurrences in the water resources of New Mexico along with geochemical context and are used to identify areas for further scientific investigations that could further characterize PFAS occurrences in New Mexico.

New Mexico↗
USGS2018

Long Island South Shore Estuary Reserve Coordinated Water Resources Monitoring Strategy

Executive Summary The Long Island South Shore Estuary Reserve Coordinated Water Resources Monitoring Strategy (CWRMS) provides an overview of the water-quality and ecological monitoring within the Reserve and presents suggestions from stakeholders for future data collection, data management, and coordination among monitoring programs. The South Shore Estuary Reserve, hereafter referred to as the Reserve, is a 173-square-mile network of bays and tributaries shaped by the south shore of Long Island (New York) and the barrier islands that was formed as a result of the last ice age (roughly 18,000 years ago). This overview and coordination document is based on information assembled from a series of meetings, a workshop, and individual correspondences with the CWRMS Project Advisory Committee, which was formed in 2015 to help guide the creation of the document, which reflects the current (2017) status of the Reserve and the need for additional data to address its water-quality issues and ecological health and to respond to a changing climate. The U.S. Geological Survey (USGS), in cooperation with the New York State Department of State Office of Planning, Development and Community Infrastructure and the South Shore Estuary Reserve Office, compiled information and recommendations to help stakeholders efficiently evaluate waters currently being monitored and address areas where necessary data are lacking. Water-quality monitoring in the Reserve is ongoing on the Federal, State, and local levels, and coordination among the various programs administered by the U.S. Environmental Protection Agency; National Oceanic and Atmospheric Administration; USGS; Shinnecock Tribal Nation; New York State; Nassau and Suffolk Counties; the Towns of Hempstead, Oyster Bay, Babylon, Islip, Brookhaven, and Southampton; and local universities and nonprofit organizations is necessary to ensure cooperation and efficient use of limited resources. Proper collection and archival of data are critical to the usability of data and methods—a sample of available repositories for monitoring data are provided in this report. Equally important are quality assurances of data and proper techniques of archival such that water and ecological data are collected and analyzed in a consistent manner, regardless of their sources, and that differences in methodologies are identified that might result in discrepancies in the compiled data. Details on monitoring programs, data gaps that are perceived by stakeholders and researchers in the area, and Project Advisory Committee recommendations are provided in this report to promote discussion and coordination. In most cases, resources to fill data gaps are needed, and the use of citizen science volunteers has been shown to help extend programs and provide insight into previously unaddressed areas of concern. This document, in conjunction with the CWRMS website and interactive mapper, is intended to inform the latest iteration of the Comprehensive Management Plan for the Reserve. Moreover, resource managers can use the CWRMS and mapper to identify areas of potential overlap and initiate conversations with stakeholders about addressing needs for additional monitoring of water quality and ecological health in the bays and tributaries of the Reserve.

New York↗
USGS2007

Nowcasting Beach Advisories at Ohio Lake Erie Beaches

Data were collected during the recreational season of 2007 to test and refine predictive models at three Lake Erie beaches. In addition to E. coli concentrations, field personnel collected or compiled data for environmental and water-quality variables expected to affect E. coli concentrations including turbidity, wave height, water temperature, lake level, rainfall, and antecedent dry days and wet days. At Huntington (Bay Village) and Edgewater (Cleveland) during 2007, the models provided correct responses 82.7 and 82.1 percent of the time; these percentages were greater than percentages obtained using the previous day?s E. coli concentrations (current method). In contrast, at Villa Angela during 2007, the model provided correct responses only 61.3 percent of the days monitored. The data from 2007 were added to existing datasets and the larger datasets were split into two (Huntington) or three (Edgewater) segments by date based on the occurrence of false negatives and positives (named ?season 1, season 2, season 3?). Models were developed for dated segments and for combined datasets. At Huntington, the summed responses for separate best models for seasons 1 and 2 provided a greater percentage of correct responses (85.6 percent) than the one combined best model (83.1 percent). Similar results were found for Edgewater. Water resource managers will determine how to apply these models to the Internet-based ?nowcast? system for issuing water-quality advisories during 2008.

Open-File Report↗