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The wind-forced response on a buoyant coastal current: Observations of the western Gulf of Maine plume

The Freshwater plume in the western Gulf of Maine is being studied as part of an interdisciplinary investigation of the physical transport of a toxic alga. A field program was conducted in the springs of 1993 and 1994 to map the spatial and temporal patterns of salinity, currents and algal toxicity. The observations suggest that the plume's cross-shore structure varies markedly as a function of fluctuations in alongshore wind forcing. Consistent with Ekman drift dynamics, upwelling favorable winds spread the plume offshore, at times widening it to over 50 km in offshore extent, while downwelling favorable winds narrow the plume width to as little as 10 km. Using a simple slab model, we find qualitative agreement between the observed variations of plume width and those predicted by Ekman theory for short time scales of integration. Near surface current meters show significant correlations between cross-shore currents and alongshore wind stress, consistent with Ekman theory. Estimates of the terms in the alongshore momentum equation calculated from moored current meter arrays also indicate a dominant Ekman balance within the plume. A significant correlation between alongshore currents and winds suggests that interfacial drag may be important, although inclusion of a Raleigh drag term does not significantly improve the alongshore momentum balance.

Gulf of Maine↗

Dutrochus, a new microdomatid (Gastropoda) genus from the Middle Devonian (Eifelian) of west-central Alaska

A new gastropod genus, Dutrochus , is established for members of the family Microdomatidae that are characterized by a reticulate ornament of spiral cords and intersecting, finer collabral threads, with all but one spiral cord being of nearly equal strength, and the single remaining cord being of stronger (nearly twice the order) magnitude and being situated at the periphery. It is represented by the type and only known species, Dutrochus alaskensis n. gen. and sp., from the upper part (lower Middle Devonian; lower Eifelian) of the Lower? and Middle Devonian Cheeneetnuk Limestone, McGrath A-5 quadrangle, west-central Alaska. The genus is very close and nearly homeomorphic to the Permian microdomatid genus Glyptospira , but differs from the latter in possessing an extremely strong, peripheral spiral cord and an extremely thick, multi-layered apertural margin.

Journal of Paleontology↗

Electrical conductivity of electrolytes applicable to natural waters from 0 to 100 degrees C

The electrical conductivities of 34 electrolyte solutions found in natural waters ranging from (10 -4 to 1) mol•kg -1 in concentration and from (5 to 90) °C have been determined. High-quality electrical conductivity data for numerous electrolytes exist in the scientific literature, but the data do not span the concentration or temperature ranges of many electrolytes in natural waters. Methods for calculating the electrical conductivities of natural waters have incorporated these data from the literature, and as a result these methods cannot be used to reliably calculate the electrical conductivity over a large enough range of temperature and concentration. For the single-electrolyte solutions, empirical equations were developed that relate electrical conductivity to temperature and molality. For the 942 molar conductivity determinations for single electrolytes from this study, the mean relative difference between the calculated and measured values was 0.1 %. The calculated molar conductivity was compared to literature data, and the mean relative difference for 1978 measurements was 0.2 %. These data provide an improved basis for calculating electrical conductivity for most natural waters.

Journal of Chemical and Engineering Data↗

Biochemical composition of three algal species proposed as food for captive freshwater mussels

To identify potential diets for rearing captive freshwater mussels, the protein, carbohydrate (CHO), and lipid contents of two green algae, Neochloris oleoabundans, Bracteacoccus grandis, and one diatom, Phaeodactylum tricornutum, were compared at different growth stages. The fatty acid and sterol composition were also identified. Protein was greatest (55-70%) for all species at late log growth stage (LL), and declined in late stationary (LS) growth. CHO was greatest at LS stage for all species (33.9-56.4% dry wt). No significant change in lipid levels occurred with growth stage, but tended to increase in N. oleoabundans. Mean lipid content differed significantly in the order: N. oleoabundans > P. tricornutum > B. grandis. Total fatty acids (TFA) were higher at LS stage compared to other stages in the two green algae, and stationary stage in the diatom. Mean unsaturated fatty acids (UFA) as %TFA was significantly higher in N. oleoabundans than the other species. The green algae contained high percentages of C-18 polyunsaturated fatty acids (PUFAs), while the diatom was abundant in C-16 saturated and mono-unsaturated fatty acids and C-20 PUFA fatty acids. Growth stage had no effect on sterol concentration of any species. B. grandis showed significantly higher sterol levels than the other species except P. tricornutum at S stage. B. grandis was characterized by predominantly ??5, C-29 sterols, while N. oleoabundans synthesized ??5,7, ??5,7,22, and ??7, C-28 sterols. P. tricornutum produced primarily a ??5,22, C-28 sterol, and a small amount of a ??7,22, C-28 sterol.

Journal of Applied Phycology↗

Basis for paleoenvironmental interpretation of magnetic properties of sediment from Upper Klamath Lake (Oregon): Effects of weathering and mineralogical sorting

Studies of magnetic properties enable reconstruction of environmental conditions that affected magnetic minerals incorporated in sediments from Upper Klamath Lake. Analyses of stream sediment samples from throughout the catchment of Upper Klamath Lake show that alteration of Fe-oxide minerals during subaerial chemical weathering of basic volcanic rocks has significantly changed magnetic properties of surficial deposits. Titanomagnetite, which is abundant both as phenocrysts and as microcrystals in fresh volcanic rocks, is progressively destroyed during weathering. Because fine-grained magnetite is readily altered due to large surface-to-volume ratios, weathering causes an increase in average magnetic grain size as well as reduction in the quantity of titanomagnetite both absolutely and relative to hematite. Hydrodynamic mineralogical sorting also produces differences in magnetic properties among rock and mineral grains of differing sizes. Importantly, removal of coarse silicate and Fe-oxide grains by sorting concentrated extremely fine-grained magnetite in the resulting sediment. The effects of weathering and sorting of minerals cannot be completely separated. These processes combine to produce the magnetic properties of a non-glacial lithic component of Upper Klamath Lake sediments, which is characterized by relatively low magnetite content and coarse magnetic grain size. Hydrodynamic sorting alone causes significant differences between the magnetic properties of glacial flour in lake sediments and of fresh volcanic rocks in the catchment. In comparison to source volcanic rocks, glacial flour in the lake sediment is highly enriched in extremely fine-grained magnetite.

Journal of Paleolimnology↗

Thermal signature, eruption style, and eruption evolution at Pele and Pillan on Io

The Galileo spacecraft has been periodically monitoring volcanic activity on Io since June 1996, making it possible to chart the evolution of individual eruptions. We present results of coanalysis of Near-Infrared Mapping Spectrometer (NIMS) and solid-state imaging (SSI) data of eruptions at Pele and Pillan, especially from a particularly illuminating data set consisting of mutually constraining, near-simultaneous NIMS and SSI observations obtained during orbit C9 in June 1997. The observed thermal signature from each hot spot, and the way in which the thermal signature changes with time, tightly constrains the possible styles of eruption. Pele and Pillan have very different eruption styles. From September 1996 through May 1999, Pele demonstrates an almost constant total thermal output, with thermal emission spectra indicative of a long-lived, active lava lake. The NIMS Pillan data exhibit the thermal signature of a “Pillanian” eruption style, a large, vigorous eruption with associated open channel, or sheet flows, producing an extensive flow field by orbit C10 in September 1997. The high mass eruption rate, high liquidus temperature (at least 1870 K) eruption at Pillan is the best candidate so far for an active ultramafic (magnesium-rich, “komatiitic”) flow on Io, a style of eruption never before witnessed. The thermal output per unit area from Pillan is, however, consistent with the emplacement of large, open-channel flows. Magma temperature at Pele is ≥1600 K. If the magma temperature is 1600 K, it suggests a komatiitic-basalt composition. The power output from Pele is indicative of a magma volumetric eruption rate of ∼250 to 340 m 3 s −1 . Although the Pele lava lake is considerably larger than its terrestrial counterparts, the power and mass fluxes per unit area are similar to active terrestrial lava lakes.

Journal of Geophysical Research E: Planets↗

Topographic stress perturbations in southern Davis Mountains, west Texas 1. Polarity reversal of principal stresses

We have applied a previously developed analytical stress model to interpret subsurface stress conditions inferred from acoustic televiewer logs obtained in two municipal water wells located in a valley in the southern Davis Mountains near Alpine, Texas. The appearance of stress-induced breakouts with orientations that shift by 90° at two different depths in one of the wells is explained by results from exact solutions for the effects of valleys on gravity and tectonically induced subsurface stresses. The theoretical results demonstrate that above a reference depth termed the hinge point, a location that is dependent on Poisson's ratio, valley shape, and magnitude of the maximum horizontal tectonic stress normal to the long axis of the valley, horizontal stresses parallel to the valley axis are greater than those normal to it. At depths below this hinge point the situation reverses and horizontal stresses normal to the valley axis are greater than those parallel to it. Application of the theoretical model at Alpine is accommodated by the fact that nearby earthquake focal mechanisms establish an extensional stress regime with the regional maximum horizontal principal stress aligned perpendicular to the valley axis. We conclude that the localized stress field associated with a valley setting can be highly variable and that breakouts need to be examined in this context when estimating the orientations and magnitudes of regional principal stresses.

Texas↗

The crustal structure from the Altai Mountains to the Altyn Tagh fault, northwest China

[1] We present a new crustal section across northwest China based on a seismic refraction profile and geologic mapping. The 1100‐km‐long section crosses the southern margin of the Chinese Altai Mountains, Junggar Accretional Belt and eastern Junggar basin, easternmost Tianshan Mountains, and easternmost Tarim basin. The crustal velocity structure and Poisson's ratio (σ), which provide a constraint on crustal composition, were determined from P and S wave data. Despite the complex geology, the crustal thickness along the entire profile is nearly uniform at 50 km. The thickest crust (56 km) occurs at the northern end of the profile beneath the Altai Mountains and the thinnest (46 km) crust is beneath the Junggar basin. Beneath surficial sediments, the crust is found to have three layers with P wave velocities ( V p ) of 6.0–6.3, 6.3–6.6, and 6.9–7.0 km/s, respectively. The southern half of the profile, including the eastern Tianshan Mountains and eastern margin of the Tarim basin, shows low P wave velocities and σ = 0.25 to a depth of 30 km, which suggests a quartz‐rich, granitic upper crustal composition. The northern half of the profile below the Altai Mountains and Junggar Accretional Belt has a higher Poisson's ratio of σ = 0.26–0.27 to a depth of 30 km, indicative of an intermediate crustal composition. The entire 1100‐km‐long profile is underlain by a 15–30 km thick high velocity (6.9–7.0 km/s; σ = 0.26–0.28) lower‐crustal layer that we interpret to have a bulk composition of mafic granulite. At the southern end of the profile, a 5‐km‐thick midcrustal low‐velocity layer ( V p = 5.9 km/s, σ = 0.25) underlies the Tianshan and the region to the south, and may be indicative of a near‐horizontal detachment interface. P n velocities are ∼7.7–7.8 km/s between the Tianshan and the Junggar basin, and ∼7.9–8.0 km/s below the Altai Mountains and eastern margin of the Tarim basin. We interpret the consistent three‐layer stratification of the crust to indicate that the crust has undergone partial melting and differentiation after Paleozoic terrane accretion. The thickness (50 km) of the crust appears to be related to compression resulting from the Indo‐Asian collision.

Altai Mountains↗

Nitrogen and carbon flow from rock to water: Regulation through soil biogeochemical processes, Mokelumne River watershed, California, and Grand Valley, Colorado

Soil denitrification is an ecologically important nitrogen removal mechanism that releases to the atmosphere the greenhouse gas N2O, an intermediate product from the reduction of NO3- to N 2. In this study we evaluate the relationship between soil carbon and denitrification potential in watersheds with bedrock acting as a nonpoint source of nitrogen, testing the hypothesis that nitrate leaching to stream water is in part regulated by denitrification. Two sites, one in a Mediterranean climate and the other in an arid climate, were investigated to understand the interplay between carbon and denitrification potential. Both sites included carbonaceous bedrock with relatively high nitrogen concentrations (> 1,000 mg N kg-1) and had low background nitrogen concentrations in surface and groundwater. There was a net accumulation of carbon and nitrogen in soil relative to the corresponding bedrock, with the exception of carbonaceous shale from the arid site. There the concentration of carbon in the soil (15,620 mg C kg-1) was less than the shale parent (22,460 mg C kg-1), consistent with the bedrock being a source of soil carbon. Rates of denitrification potential (0.5-83 ??g N kg-1 hr-1) derived from laboratory incubations appeared to be related to the ratio of dissolved organic carbon and nitrate extracted from soils. These data indicate that microbial processes such as denitrification can help maintain background nitrogen concentrations to tens of ??M N in relatively undisturbed ecosystems when nitrogen inputs from weathering bedrock are accompanied by sufficient organic carbon concentrations to promote microbial nitrogen transformations.

Journal of Geophysical Research F: Earth Surface↗

Nearshore wave-induced cyclical flexing of sea cliffs

[1] Evolution of a tectonically active coast is driven by geomorphically destructive energy supplied by ocean waves. Wave energy is episodic and concentrated; sea cliffs are battered by the geomorphic wrecking ball every 4-25 s. We measure the response of sea cliffs to wave assault by sensing the ground motion using near-coastal seismometers. Sea cliffs respond to waves in two distinct styles. High-frequency motion (20 Hz) reflects the natural frequency of the sea cliff as it rings in response to direct wave impact. Low-frequency motion in the 0.1-0.05 Hz (10-20 s) band consistently agrees with the dominant nearshore wave period. Integrating microseismic velocities suggests 50 ??m and 10 ??m displacements in horizontal and vertical directions, respectively. Displacement ellipsoids exhibit simultaneous downward and seaward sea cliff motion with each wave. Video footage corroborates the downward sea cliff flex in response to the imposed water load on the wave cut platform. Gradients in displacement amplitudes documented using multiple seismometers suggest longitudinal and shear strain of the flexing sea cliff on the order of 0.5-4 ?? strains during each wave loading cycle. As this sea cliff flexure occurs approximately 3 million times annually, it has the potential to fatigue the rock through cyclical loading. Local sea cliff retreat rates of 10 cm/yr imply that a given parcel of rock is flexed through roughly 109 cycles of increasing amplitude before exposure to direct wave attack at the cliff face. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗