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Simulation of ground-water flow in the Mojave River basin, California

The proximity of the Mojave River ground-water basin to the highly urbanized Los Angeles region has led to rapid growth in population and, consequently, to an increase in the demand for water. The Mojave River, the primary source of surface water for the region, normally is dry-except for a small stretch of perennial flow and periods of flow after intense storms. Thus, the region relies almost entirely on ground water to meet its agricultural and municipal needs. Ground-water withdrawal since the late 1800's has resulted in discharge, primarily from pumping wells, that exceeds natural recharge. To better understand the relation between the regional and the floodplain aquifer systems and to develop a management tool that could be used to estimate the effects that future stresses may have on the ground-water system, a numerical ground-water flow model of the Mojave River ground-water basin was developed, in part, on the basis of a previously developed analog model. The ground-water flow model has two horizontal layers; the top layer (layer 1) corresponds to the floodplain aquifer and the bottom layer (layer 2) corresponds to the regional aquifer. There are 161 rows and 200 columns with a horizontal grid spacing of 2,000 by 2,000 feet. Two stress periods (wet and dry) per year are used where the duration of each stress period is a function of the occurrence, quantity of discharge, and length of stormflow from the headwaters each year. A steady-state model provided initial conditions for the transient-state simulation. The model was calibrated to transient-state conditions (1931-94) using a trial-and-error approach. The transient-state simulation results are in good agreement with measured data. Under transient-state conditions, the simulated floodplain aquifer and regional aquifer hydrographs matched the general trends observed for the measured water levels. The simulated streamflow hydrographs matched wet stress period average flow rates and times of no flow at the Barstow and Afton Canyon gages. Steady-state particle-tracking was used to estimate travel times for mountain-front and streamflow recharge. The simulated travel times for mountain-front recharge to reach the area west of Victorville were about 5,000 to 6,000 years; this result is in reasonable agreement with published results. Steady-state particle-tracking results for streamflow recharge indicate that in most subareas along the river, the particles quickly leave and reenter the river. The complaint that resulted in the adjudication of the Mojave River ground-water basin alleged that the cumulative water production upstream of the city of Barstow had overdrafted the ground-water basin. In order to ascertain the effect of pumping on ground-water and surface-water relations along the Mojave River, two pumping simulations were compared with the 1931-90 transient-state simulation (base case). The first simulation assumed 1931-90 pumping in the upper region (Este, Oeste, Alto, and Transition zone model subareas) but with no pumping in the remainder of the basin, and the second assumed 1931-90 pumping in the lower region (Centro, Harper Lake, Baja, Coyote Lake, and Afton Canyon model subareas) but with no pumping in remainder of the basin. In the upper region, assuming pumping only in the upper region, there was no change in storage, recharge from the Mojave River, ground-water discharge to the Mojave River, or evapotranspiration when compared with the base case. In the lower region, assuming pumping only in the upper region, there was storage accretion, decreased recharge from the Mojave River, increased ground-water discharge to the Mojave River, and increased evapotranspiration when compared with the base case. In the upper region, assuming pumping only in the lower region, there was storage accretion, decreased recharge from the Mojave River, increased ground-water discharge to the Mojave River, and increased evapotranspiration when compared with the base case. In the lower region, assuming pumping only in the lower region, there was less storage depletion, increased recharge from the Mojave River, increased ground-water discharge to the Mojave River, and increased evapotranspiration when compared with the base case. Overall, pumping in the lower region does not negatively affect the upper region; however, pumping in the upper region negatively affects the lower region by decreasing recharge from the Mojave River. Streamflow, pumpage, and water-level data from calendar years 1995-99 were used to validate the calibrated ground-water flow model, that is, to test that the ground-water flow model will duplicate measured data for a noncalibration period without modification of the model parameters. In general, the simulated results are in good agreement with the measured data, and the simulated hydrographs for wells in the floodplain and regional aquifers follow the measured water-level trends. Simulated streamflow data for the 1995-99 wet and dry stress periods at the Lower Narrows, Barstow, and Afton Canyon were compared with the measured data for average streamflow for the same periods; in general, the model reflects 1995-99 streamflow conditions. The simulation results also indicate that the streambed conductance values calibrated to the 1931-94 conditions reasonably simulate the 1995-99 conditions and therefore can be used for predictive purposes. To visualize the magnitude, spatial distribution, and timing of water-level changes in the basin through time, simulated hydraulic heads for 1932-99 were compared with simulated hydraulic heads for 1931. Greater than average annual inflows to the Mojave River from the headwaters during the late 1930's and throughout much of the 1940's resulted in simulated hydraulic heads that were higher than the 1931 hydraulic heads along the Mojave River in most model subareas. Parts of the Baja and Harper Lake model subareas had declines in the simulated hydraulic head because of the increase in agricultural pumpage. By 1960, the simulated hydraulic heads were lower than the simulated hydraulic heads for 1931 in all model subareas of the floodplain and the regional aquifers because of pumpage. After 1960, the size and the magnitude of the areas of the regional aquifer for which simulated hydraulic heads were lower than those for 1931 continued to increase until the end of the simulation (1999). Along the Mojave River, hydraulic heads fluctuated in the floodplain aquifer in response to recharge during years with large inflows with little apparent effect on the simulated hydraulic heads in the regional aquifer. Three water-management alternatives were evaluated to determine their effect on ground-water resources using the calibrated ground-water flow model. The water-management alternatives consider the artificial recharge of imported water allocated to the Mojave Water Agency (MWA): the first assumes that zero percent of the MWA allocation is available (alternative 1), the second assumes that 50 percent of the MWA allocation is available (alternative 2), and the third assumes that 100 percent of the MWA allocation is available (alternative 3). Each of the three water-management alternatives were evaluated for a 20-year drought. Streamflow conditions were simulated using the 20-year drought of 1945-64 with associated calibrated stream parameters. Management alternative 1 results in a reduction in ground-water recharge from the Mojave River compared with average recharge for 1995-99; this reduction is reflected in simulated hydraulic-head declines between 1999 and 2019 of as much as 45 feet. Management alternatives 2 and 3 result in no change in recharge from the Mojave River for management alternative 2 and a small increase for management alternative 3 when compared with recharge for management alternative 1. The artificial recharge of imported water causes increases in simulated hydraulic head for both management alternatives at each of the artificial-recharge sites. Some of the increases are related to water that recharges into areas of low transmissivity which implies that the recharge operations may benefit from being distributed over a larger area.

California↗

Ground-water resources and water-supply alternatives in the Wawona area of Yosemite National Park, California

Planning efforts to implement the 1980 General Management Plan, which recommends relocating park administrative facilities and employee housing from Yosemite Valley in Yosemite National Park, California, have focused on the availability of water at potential relocation sites within the park. Ground-water resources and water-supply alternatives in the Wawona area, one of several potential relocation sites, were evaluated between June 1991 and October 1993. Ground water flowing from Biledo Spring near the headwaters of Rainier Creek, about 5 miles southeast of Wawona, is probably the most reliable source of good quality ground water for Wawona. A dilute calcium bicarbonate ground water flows from the spring at about 250 gallons per minute. No Giardia was detected in a water sample collected from Biledo Spring in July 1992. The concentration of dissolved 222 radon at Biledo Spring was 420 picoCuries per liter, exceeding the primary drinking-water standard of 300 picoCuries per liter proposed by the U.S. Environmental Protection Agency. This concentration, however, was considerably lower than the concentrations of dissolved 222 radon measured in ground water at Wawona. The median value for 15 wells sampled at Wawona was 4,500 picoCuries per liter. Water-quality samples from 45 wells indicate that ground water in the South Fork Merced River valley at Wawona is segregated vertically. Shallow wells produce a dilute calcium sodium bicarbonate water that results from chemical dissolution of minerals as water flows through fractured granitic rock from hillside recharge areas toward the valley floor. Tritium concentrations indicate that ground water in the shallow wells originated as precipitation after the 1960's when testing of atmospheric nuclear devices stopped. Ground water from the deep flowing wells in the valley floor is older sodium calcium chloride water. This older water probably originated either as precipitation during a climatically cooler period or as precipitation from altitudes between 1,400 and 3,700 feet higher than precipitation that recharged the local shallow ground-water-flow system. Chloride and associated cations in the deepground-water-flow system may result from upward leakage of saline ground water or from leaching of saline fluid inclusions in the granitic rocks. Water-level and pressure-gage measurements for 38 wells in the South Fork Merced River valley also indicate that the ground water in the valley is segregated vertically. Hydraulic head in deep fractures is as much as 160 feet above the valley floor. Vertical hydraulic gradients between the shallow and deep systems are as high as 4.5 feet per foot in one of two test holes drilled for this study. Measurements of in situ stress in the two test holes indicate that the vertical segregation of ground water may be related to pressures in the earth that squeeze horizontal fractures closed at depth. Fractures within a few hundred feet of land surface are poorly connected to fractures deeper beneath the valley. About 100 privately owned wells currently are in use at Wawona; but, the ground-water-flow system may not be an adequate source of good quality ground water for relocated park facilities. Yields from existing wells are low (median 4-5 gallons per minute) and traditional methods for locating high-yielding wells in fractured rocks have not been successful in this area. Concentrations of dissolved 222 radon (median 4,500 picoCuries per liter) are high, and the development of deep ground water could cause deeper saline water to migrate upward into producing wells. The South Fork Merced River, the primary source of water supply for Wawona, does not meet current demands during late summer and autumn. Data collected between 1958 and 1968 indicate that 25 percent of the time discharge of the South Fork River at Wawona during the dry season (August through October) was less than 2 cubic feet per second-the discharge rate at which the National Park Service is restricted from withdrawing water from the river. the river, however, could be relied on for additional water supply if facilities were constructed to divert and store water during periods of high flow for use later in the year.

California↗

Hydrogeology of the Cambrian-Ordovician aquifer system in the northern Midwest, United States with a section on ground-water quality

The Cambrian-Ordovician aquifer system contains the most extensive and continuous aquifers in the northern Midwest of the United States. It is the source of water for many municipalities, industries, and rural water users. Since the beginning of ground-water development from the aquifer system in the late 1800's, hydraulic heads have declined hundreds of feet in the heavily pumped Chicago-Milwaukee area and somewhat less in other metropolitan areas. The U.S. Geological Survey has completed a regional assessment of this aquifer system within a 161,000-square-mile area encompassing northern Illinois, northwestern Indiana, Iowa, southeastern Minnesota, northern Missouri, and Wisconsin. Consolidated sedimentary rocks in the northern Midwest range in age from Precambrian to Cretaceous and crop out in generally concentric, arcuate patterns, dipping away from structural highs (arches) on the Precambrian basement in northern Minnesota and Wisconsin toward structural lows (basins) to the south and east. The sedimentary bedrock is generally overlain by a veneer of glacial drift. Thickness of the sedimentary sequence increases to about 5,000 feet in the Forest City basin of southwestern Iowa and to about 14,000 and more than 15,000 feet in the Illinois and Michigan basins, respectively. Cambrian and Ordovician age rocks, mainly marine sandstone and carbonate rocks, compose much of the sedimentary sequence and form the Cambrian-Ordovician aquifer system. The aquifer system lies on the Precambrian basement, regarded as a regional confining unit. Six hydrogeologic units are defined; they are arranged as alternating pairs of an aquifer and an overlying confining. unit. The units are named using the predominant geologic nomenclature of the upper Mississippi Valley, which includes most of the study area. In the southern quarter of the area, the hydrogeologic units consist of equivalent formations of the Ozark area (mostly carbonate rocks). The uppermost part of the aquifer system is the Maquoketa confining unit, which consists of the Maquoketa Shale and the underlying dolomite and shale of the Galena Dolomite and the Decorah, Platteville, and Glenwood Formations. The underlying St. Peter-Prairie du Chien-Jordan aquifer is an important source of ground water in the western part of the area in Iowa and Minnesota, where the uniform Jordan Sandstone is hydraulically connected to overlying fractured dolomite of the Prairie du Chien Group. The unit is less important in the eastern part of Wisconsin and Illinois because the Jordan Sandstone is absent and the Prairie du Chien Group is thin or absent due to pre-St. Peter Sandstone erosion. Equivalent rocks in northern Missouri-the Roubidoux Formation and the Gasconade and Eminence Dolomites-are mainly carbonate rocks that are somewhat permeable and contain some sandstone. The St. Lawrence and Franconia Formations underlying the St. Peter-Prairie du Chien-Jordan aquifer consist generally of silty and shaly, fine-grained, poorly sorted, and dolomitic sandstones that restrict vertical movement of ground water and form a regional confining unit. In the southern and eastern parts of the area, the Potosi and Derby-Doerun Dolomites and the upper part of the Davis Formation are the equivalent rocks (mainly carbonate rocks). In the east-central part of the area in Illinois and Wisconsin, the Ironton-Galesville aquifer forms the most important aquifer of the Cambrian-Ordovician aquifer system, contributing about one-third of the yield from wells in the aquifer system in the Chicago area. The aquifer terminates to the west, south, and east, where the sandstones grade into less permeable carbonate rocks in central Iowa, central Illinois, and northwestern Indiana, respectively. The underlying Eau Claire Formation and its partial equivalent to the southwest, the Bonneterre Formation, form an important confining unit above the Mount Simon aquifer throughout much of the study area. Siltstone and shale are fairly common in the upper part of the Eau Claire Formation but less so in its northernmost extent in Wisconsin. Dolomite content increases southward and westward, where a middle dolomite facies grades laterally into the Bonneterre in Missouri, southwestern Minnesota, extreme south-central Wisconsin, and possibly in western Iowa. The basal unit in the Cambrian-Ordovician aquifer system, the Mount Simon aquifer, is present throughout the study area, except where it is absent over local highs of the Precambrian basement. It consists primarily of the Mount Simon Sandstone in the north and its equivalent in northern Missouri, the Lamotte Sandstone. The underlying Hinckley Sandstone of Precambrian age is included in Minnesota, as is the overlying Elmhurst Sandstone Member of the Eau Claire Formation in northern Illinois. The aquifer increases greatly in thickness and the water is progressively more saline away from the northern structural highs toward the basins. Much of the movement and discharge of ground water in the northern Midwest occurs in local, unconfined, shallow flow systems within a few miles of points of recharge. The rest of the water is semiconfined or confined in intermediate or regional flow systems within the bedrock, where flow is deeper, slower, and traverses much longer distances from recharge areas to discharge areas. The major areas of recharge to regional confined flow are in northwestern Iowa, southeastern Minnesota, western, southern, and eastern Wisconsin, and northern Illinois. Although the rate of flow is small, significant recharge to the Cambrian-Ordovician aquifer system also occurs as leakage through the Maquoketa confining unit, where the vertical hydraulic gradient is downward. Ground water in much of the confined aquifer system moves laterally from recharge areas toward the major river valleys and Lake Michigan or down dip toward the structural basins. The longest flow paths extend as much as 400 miles from northwestern Iowa southeast toward the Illinois basin or to the Mississippi River and Missouri River valleys near their confluence. Other major confined flow is from eastern Wisconsin toward the Michigan basin and southward flow from northeastern Illinois toward the Illinois basin. Regional ground-water discharge from the aquifer system is mainly diffuse upward leakage from confined aquifers along flow paths toward the structural basins. Very saline water around and brines within the basins restrict regional flow into the basins, forcing ground water to discharge upward. Water in intermediate flow systems discharges upward to the major river valleys. Original heads of more than 100 feet above land surface were recorded in the aquifer system near Lake Michigan in eastern Wisconsin and at Dubuque, Iowa, along the Mississippi River. The Cambrian-Ordovician aquifer system was developed rapidly in the late 1800's after the first deep well was drilled in Chicago in 1864. Many flowing wells were not controlled, which caused water levels in deep wells to decline, and many no longer flowed by the early 1900's. Heads in the aquifers have declined very little in most of the recharge or unconfined areas since ground-water withdrawal began, but major declines have occurred in confined areas. The largest declines in head are at Chicago, Illinois, Milwaukee and Green Bay, Wisconsin, and Mason City, Iowa, where the aquifer system is confined by the Maquoketa confining unit. The composite head in the aquifer system declined more than 900 feet in the deepest cones of depression in the Chicago area from 1864 to 1980 and about 375 feet in the cone at Milwaukee from 1880 to 1980. More than 200 feet of decline has occurred at Mason City. The head declined as much as 440 feet in Green Bay from 1886 to 1957, when the city discontinued use of its deep wells and began using water from Lake Michigan. The largest centers of pumping are in the Chicago and Twin Cities (Minneapolis-St. Paul, Minnesota) metropolitan areas about 180 million gallons per day each in 1980. Pumpage exceeded 10 million gallons per day in only a few other areas in 1980. Ground water in the Cambrian-Ordovician aquifer system in the northern Midwest is characterized by an extreme range of mineralization, but its quality in most of the area is good. The major cations are calcium, magnesium, and sodium, and the major anions are bicarbonate, sulfate, and chloride. Sodium, sulfate, and chloride distributions are closely related to the distribution pattern of dissolved solids but not in the same proportion. Dissolved-solids concentration is generally less than 1,000 milligrams per liter in the recharge areas of Wisconsin, southern Minnesota, northeastern Iowa, and north-central Illinois where the aquifer system crops out or subcrops beneath glacial drift. Ground water there is the Ca-Mg-HC03 type, derived from and identical to that in the overlying glacial drift. In northwestern Iowa and southwestern Minnesota, the water in both the glacial drift and the Cambrian-Ordovician aquifer system is a Ca-Na-S04HC03 type, derived from oxidation of pyrite in the overlying Cretaceous Dakota Formation. Transition to higher dissolved solids in the confined areas commonly is accompanied by increased sulfate concentration and· the occurrence of Ca-Na-S04-type water. Salinity of the ground water increases progressively toward the .basins, where dissolved solids exceed 200,000 milligrams per liter. Saline water is present in the Mount Simon aquifer near Lake Michigan in eastern Wisconsin and northeastern Illinois but occurs in successively younger rocks to the east and south as they dip toward the basins. Similarly, salinity increases down dip in Iowa to the southwest and south; however, regional ground-water flow in Iowa is from northwest to southeast. Much of the ground water in the confined aquifer system is isotopically depleted in 0180 and OD with respect to modern precipitation-an indication that the water originated as precipitation in a much colder climate than the present and probably was derived from recharge of glacial meltwater. On the basis of o34S values for sulfur in sulfate, it is believed that isostatic loading from glacial ice over the Michigan basin reversed the hydraulic gradient to trend westward, opposite from the present gradient, causing saline water in the Michigan basin to discharge westward through the present recharge areas. Natural water-quality problems in the Cambrian-Ordovician aquifer system are mainly the high dissolved-solids concentrations and associated high concentrations of sulfate and chloride, which limit the use of the water for municipal and domestic purposes in much of the confined aquifer system in central and southern Illinois, Indiana, southern and western Iowa, and northern Missouri. Another concern is that radium activity exceeds normal background concentrations of a few picocuries per liter in much of the confined aquifer system in eastern Wisconsin, northeastern Illinois, and central Iowa. Other common problems are high hardness and locally excessive concentrations of iron and hydrogen sulfide.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Evaluating data worth for ground-water management under uncertainty

A decision framework is presented for assessing the value of ground-water sampling within the context of ground-water management under uncertainty. The framework couples two optimization models-a chance-constrained ground-water management model and an integer-programing sampling network design model-to identify optimal pumping and sampling strategies. The methodology consists of four steps: (1) The optimal ground-water management strategy for the present level of model uncertainty is determined using the chance-constrained management model; (2) for a specified data collection budget, the monitoring network design model identifies, prior to data collection, the sampling strategy that will minimize model uncertainty; (3) the optimal ground-water management strategy is recalculated on the basis of the projected model uncertainty after sampling; and (4) the worth of the monitoring strategy is assessed by comparing the value of the sample information-i.e., the projected reduction in management costs-with the cost of data collection. Steps 2-4 are repeated for a series of data collection budgets, producing a suite of management/monitoring alternatives, from which the best alternative can be selected. A hypothetical example demonstrates the methodology's ability to identify the ground-water sampling strategy with greatest net economic benefit for ground-water management.A decision framework is presented for assessing the value of ground-water sampling within the context of ground-water management under uncertainty. The framework couples two optimization models - a chance-constrained ground-water management model and an integer-programming sampling network design model - to identify optimal pumping and sampling strategies. The methodology consists of four steps: (1) The optimal ground-water management strategy for the present level of model uncertainty is determined using the chance-constrained management model; (2) for a specified data collection budget, the monitoring network design model identifies, prior to data collection, the sampling strategy that will minimize model uncertainty; (3) the optimal ground-water management strategy is recalculated on the basis of the projected model uncertainty after sampling; and (4) the worth of the monitoring strategy is assessed by comparing the value of the sample information - i.e., the projected reduction in management costs - with the cost of data collection. Steps 2-4 are repeated for a series of data collection budgets, producing a suite of management/monitoring alternatives, from which the best alternative can be selected. A hypothetical example demonstrates the methodology's ability to identify the ground-water sampling strategy with greatest net economic benefit for ground-water management.

Journal of Water Resources Planning and Management↗

Effectiveness of riparian buffers in controlling ground-water discharge of nitrate to streams in selected hydrogeologic settings of the North Carolina Coastal Plain

Water-quality and hydrologic information were collected along ground-water flow paths from two well-drained and two poorly drained Coastal Plain settings in North Carolina to evaluate the relative effectiveness of riparian buffers in reducing discharge of nitrate to streams. At one well-drained site with a 100 m buffer, little or no effect was detected on surface-water quality by discharging ground water because extensive woody vegetation in the buffer was able to take up not only most nitrate, but also most ground water before discharging to the stream during the growing season (March-October). At the second well-drained site, ground water discharging to the stream from the side with a buffer contained about 2 mg/L of nitrate-nitrogen after passing through the bed of the stream compared to 6 mg/L in ground water discharging from the side with no buffer. In the poorly drained settings, nitrate in ground water decreased from about 6 mg/L in the recharge area to less than 0.02 mg/L downgradient from the riparian buffer. Ground water discharging from the side with no buffer contained 0.83 mg/L. Riparian buffers appear effective in reducing nitrate in ground water discharging to Coast Plain streams.

North Carolina↗

Characterization and simulation of ground-water flow in the Kansas River Valley at Fort Riley, Kansas, 1990-98

Hydrologic data and a ground-water flow model were used to characterize ground-water flow in the Kansas River alluvial aquifer at Fort Riley in northeast Kansas. The ground-water flow model was developed as a tool to project ground-water flow and potential contaminant-transport paths in the alluvial aquifer on the basis of past hydrologic conditions. The model also was used to estimate historical and hypothetical ground-water flow paths with respect to a private- and several public-supply wells. The ground-water flow model area extends from the Smoky Hill and Republican Rivers downstream to about 2.5 miles downstream from the city of Ogden. The Kansas River Valley has low relief and, except for the area within the Fort Riley Military Reservation, is used primarily for crop production. Sedimentary deposits in the Kansas River Valley, formed after the ancestral Kansas River eroded into bedrock, primarily are alluvial sediment deposited by the river during Quaternary time. The alluvial sediment consists of as much as about 75 feet of poorly sorted, coarse-to-fine sand, silt, and clay, 55 feet of which can be saturated with ground water. The alluvial aquifer is unconfined and is bounded on the sides and bottom by Permian-age shale and limestone bedrock. Hydrologic data indicate that ground water in the Kansas River Valley generally flows in a downstream direction, but flow direction can be quite variable near the Kansas River due to changes in river stage. Ground-water-level changes caused by infiltration of precipitation are difficult to detect because they are masked by larger changes caused by fluctuation in Kansas River stage. Ratios of strontium isotopes Sr87 and Sr86 in water collected from wells in the Camp Funston Area indicate that the ground water along the northern valley wall originates, in part, from upland areas north of the river valley. Water from Threemile Creek, which flows out of the uplands north of the river valley, had Sr87:Sr86 ratios similar to those in ground water from wells in the northern Camp Funston Area. In addition, comparison of observed water levels from wells CF90-06, CF97-101, and CF97-401 in the Camp Funston Area and ground-water levels simulated for these wells using floodwave-response analysis indicates that ground-water inflow from bedrock is a hydraulic stress that, in addition to the changing stage in the Kansas River, acts on the aquifer. This hydraulic stress seems to be located near the northern valley wall because the effect of this stress is greater for well CF97-101, which is the well closest to the valley wall. Ground-water flow was simulated using a modular, three-dimensional, finite-difference ground-water flow model (MODFLOW). Particle tracking, used to visualize ground-water flow paths in the alluvial aquifer, was accomplished using MODPATH. Forward-in-time particle tracking indicated that, in general, particles released near the Kansas River followed much more variable paths than particles released near the valley wall. Although particle tracking does not simulate solute transport, this increased path variability indicates that, near the river, ground-water contaminants could follow many possible paths towards the river, whereas more distant from the river, ground-water contaminants likely would follow a narrower corridor. Particle tracks in the Camp Funston Area indicate that, for the 1990-98 simulation period, contaminants from the ground-water study sites in the Camp Funston Area would be unlikely to move into the vicinity of Ogden's supply wells. Backward-in-time particle tracking indicated that the flow-path and recharge areas for model cells corresponding to Ogden's supply wells lie near the northern valley wall and extend into the northern Camp Funston Area. The flow-path and recharge areas for model cells corresponding to Morris County Rural Water District wells lie within Clarks Creek Valley and probably extend outside the model area. Three hypothetical simulations, i

Water-Resources Investigations Report↗

Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin— Ground-water quality in an urban part of the Twin Cities Metropolitan area, Minnesota, 1996

In the spring of 1996, the Upper Mississippi River Basin Study Unit of the National Water-Quality Assessment Program drilled 30 shallow monitoring wells in a study area characterized by urban residential and commercial land uses. The monitoring wells were installed in sandy river-terrace deposits adjacent to the Mississippi River in Anoka and Hennepin Counties, Minnesota, in areas where urban development primarily occurred during the past 30 years. Analyses of sediments collected during well drilling indicated that at most well sites the aquifer materials had relatively high hydraulic conductivities (ranging from 0.01 to 238 feet per day), and relatively low organic carbon contents (0.10 to 41 grams per kilogram), indicating a high susceptibility to leaching of fertilizers and organic substances used on the land surface. Sediment pH values, which can affect leaching of pesticides, were generally alkaline, ranging from 5.1 to 9.6. Ground-water levels ranged from 2.39 to 23.14 feet below land surface, and indicated that shallow ground water flows primarily toward the Mississippi River. Dissolved-oxygen concentrations in water samples from the wells were generally less than 3 milligrams per liter (mg/L) and specific conductances were generally greater than 600 microsiemens per centimeter. Calcium, magnesium, sodium, bicarbonate, chloride, and sulfate were the primary dissolved constituents in the water samples. Sodium and chloride concentrations were generally greater than commonly reported in the region, probably due to leaching of sodium chloride applied to roads during the winter. Most tracemetal concentrations in ground-water samples were less than 10 micrograms per liter (μg/L), but concentrations of iron and manganese commonly exceeded Secondary Maximum Contaminant Levels set by the U.S. Environmental Protection Agency of 300 and 50 μg/L, respectively. Mineral saturation indices indicated that calcite, dolomite, and gypsum were slightly undersaturated in most water samples, and that quartz, and many oxides and hydroxides of iron and manganese were oversaturated in all of the water samples. Concentrations of nitrate nitrogen, the primary nutrient of concern in ground water, ranged from less than 0.05 to 16 mg/L, with a median concentration of 1.4 mg/L. Dissolved phosphorus concentrations ranged from less than 0.01 to 1.5 mg/L in the water samples, with a median concentration of 0.02 mg/L. Water from one well was oversaturated with respect to hydroxyapatite, a phosphatic mineral used as a fertilizer. Pesticide compounds were detected in water samples from 16 wells, but concentrations of those compounds were less than 1.0 μg/L. Prometon, an herbicide commonly used for right-of-way weed control, was detected in water samples from 10 of the wells. Atrazine, and its metabolite deethylatrazine, were detectable in water samples from 6 and 8 wells, respectively. Atrazine is commonly applied to land planted with corn and is detectable in rainfall and air samples in concentrations of less than 1 ng/L in the urban land use study area. Other detected pesticide compounds, which are used in agriculture, right-of-way weed control, or lawn care included: tebuthiuron, EPTC, p , p '-DDE, metolachlor, simazine, bentazon, and bromacil. Volatile organic compounds were detected in water samples from 26 wells, but the concentrations of most of those compounds were less than 1 μg/L. Carbon disulfide, which may be produced by bacteria in soils, was the most commonly detected volatile organic compound in water samples from the wells. Other detected volatile organic compounds included: methyl chloride, acetone, dichlorofluoromethane, tetrahydrofuran, trichlorofluoromethane, methyl iodide, 1,1-dichloroethane, chloroform, toluene, trichloroethane, trichloroethene, cis -1,2-dichloroethene, methylene chloride, bromodichloromethane, benzene, methylisobutylketone, ethyl ether, and tetrachloroethene. Tritium concentrations, analyzed in water samples from 15 of the 30 wells, indicated that shallow ground water has been recharged since the mid-1950's, and that shallow ground water should be affected by urban development that has taken place over the past 40 years. Land uses in the urban land use study area affected the concentrations of some water-quality constituents. Concentrations of nitrate and chloride, and frequencies of detection of pesticides and of volatile organic compounds, were greater in water samples from the surficial sand and gravel aquifer underlying the urban land use study area than in water samples from similar aquifers from part of the Upper Mississippi River Basin National Water-Quality Assessment study unit. Land uses within 500-meter radii of each well were quantified by digitizing overlays of aerial photographs that were verified and updated in the field. Concentrations of magnesium and sulfate were greater in ground water beneath areas of denser residential development, which may be a natural artifact of better drainage and a deeper water table in those areas. Frequencies of detection of some pesticides and volatile organic compounds were greater in water from wells with greater proportions of industrial and transportation land uses. Ground water in areas with less dense residential development, mostly the more recently-developed areas, tended to have greater concentrations of agricultural herbicides and some nutrients probably a relict of previous agricultural land use.

Minnesota↗

Estimating ground-water exchange with lakes using water-budget and chemical mass-balance approaches for ten lakes in ridge areas of Polk and Highlands counties, Florida

Water budget and chemical mass-balance approaches were used to estimate ground-water exchange with 10 lakes in ridge areas of Polk and Highlands Counties, Florida. At each lake, heads were monitored in the surficial aquifer system and deeper Upper Floridan aquifer, lake stage and rainfall were measured continuously, and lakes and wells were sampled three times between October 1995 and December 1996. The water-budget approach computes net ground-water flow (ground-water inflow minus outflow) as the residual of the monthly waterbudget equation. Net ground-water flow varied seasonally at each of the 10 lakes, and was notably different between lakes, illustrating short-term differences in ground-water fluxes. Monthly patterns in net ground-water flow were related to monthly patterns of other hydrologic variables such as rainfall, ground-water flow patterns, and head differences between the lake and the Upper Floridan aquifer. The chemical mass-balance approach combines the water budget and solute or isotope mass-balance equations, and assumes steady-state conditions. Naturally occurring tracers that were analyzed for include calcium, magnesium, sodium, potassium, chloride, and bromide, the isotopes deuterium and oxygen-18. Chloride and sodium were the most successful solute tracers; however, their concentrations in ground water typically varied spatially, and in places were similar to that in lake water, limiting their sensitivity as tracers. In contrast, the isotopes were more robust tracers because the isotopic composition of ground water was relatively uniform and was distinctly different from the lake water. Groundwater inflow computed using the chemical massbalance method varied significantly between lakes, and ranged from less than 10 to more than 150 inches per year. Both water-budget and chemical mass-balance approaches had limitations, but the multiple lines of evidence gained using both approaches improved the understanding of the role of ground water in the water budget of the lakes.

Water-Resources Investigations Report↗

U.S. Geological Survey ground-water studies in Minnesota

Nearly 700 million gallons of ground water are withdrawn every day in Minnesota, mostly for public supply, irrigation, and domestic and commercial use. About 94 percent of the public water-supply systems in the State use ground water and 75 percent of all Minnesotans obtain their domestic supplies from ground water. The major issues related to this important resource in Minnesota are: Availability of ground water and effects of developing water supplies from wells in buried-drift aquifers, Ground-water contamination from hazardous wastes, and Effects of land use on ground-water quality.

Minnesota↗

Regional analysis of ground-water recharge

A modeling analysis of runoff and ground-water recharge for the arid and semiarid southwestern United States was performed to investigate the interactions of climate and other controlling factors and to place the eight study-site investigations into a regional context. A distributed-parameter water-balance model (the Basin Characterization Model, or BCM) was used in the analysis. Data requirements of the BCM included digital representations of topography, soils, geology, and vegetation, together with monthly time-series of precipitation and air-temperature data. Time-series of potential evapotranspiration were generated by using a submodel for solar radiation, taking into account topographic shading, cloudiness, and vegetation density. Snowpack accumulation and melting were modeled using precipitation and air-temperature data. Amounts of water available for runoff and ground-water recharge were calculated on the basis of water-budget considerations by using measured- and generated-meteorologic time series together with estimates of soil-water storage and saturated hydraulic conductivity of subsoil geologic units. Calculations were made on a computational grid with a horizontal resolution of about 270 meters for the entire 1,033,840 square-kilometer study area. The modeling analysis was composed of 194 basins, including the eight basins containing ground-water recharge-site investigations. For each grid cell, the BCM computed monthly values of potential evapotranspiration, soil-water storage, in-place ground-water recharge, and runoff (potential stream flow). A fixed percentage of runoff was assumed to become recharge beneath channels operating at a finer resolution than the computational grid of the BCM. Monthly precipitation and temperature data from 1941 to 2004 were used to explore climatic variability in runoff and ground-water recharge. The selected approach provided a framework for classifying study-site basins with respect to climate and dominant recharge processes. The average climate for all 194 basins ranged from hyperarid to humid, with arid and semiarid basins predominating (fig. 6, chapter A, this volume). Four of the 194 basins had an aridity index of dry subhumid; two of the basins were humid. Of the eight recharge-study sites, six were in semiarid basins, and two were in arid basins. Average-annual potential evapotranspiration showed a regional gradient from less than 1 m/yr in the northeastern part of the study area to more than 2 m/yr in the southwestern part of the study area. Average-annual precipitation was lowest in the two arid-site basins and highest in the two study-site basins in southern Arizona. The relative amount of runoff to in-place recharge varied throughout the study area, reflecting differences primarily in soil water-holding capacity, saturated hydraulic conductivity of subsoil materials, and snowpack dynamics. Climatic forcing expressed in El Niño and Pacific Decadal Oscillation indices strongly influenced the generation of precipitation throughout the study area. Positive values of both indices correlated with the highest amounts of runoff and ground-water recharge.

Professional Paper↗

Ground-water flow and saline water in the shallow aquifer system of the southern watersheds of Virginia Beach, Virginia

Population and tourism continues to grow in Virginia Beach, Virginia, but the supply of freshwater is limited. A pipeline from Lake Gaston supplies water for northern Virginia Beach, but ground water is widely used to water lawns in the north, and most southern areas of the city rely solely on ground water. Water from depths greater than 60 meters generally is too saline to drink. Concentrations of chloride, iron, and manganese exceed drinking-water standards in some areas. The U.S. Geological Survey, in cooperation with the city of Virginia Beach, Department of Public Utilities, investigated the shallow aquifer system of the southern watersheds to determine the distribution of fresh ground water, its potential uses, and its susceptibility to contamination. Aquifers and confining units of the southern watersheds were delineated and chloride concentrations in the aquifers and confining units were contoured. A ground-water-flow and solute-transport model of the shallow aquifer system reached steady state with regard to measured chloride concentrations after 31,550 years of freshwater recharge. Model simulations indicate that if freshwater is found in permeable sediments of the Yorktown-Eastover aquifer, such a well field could supply freshwater, possibly for decades, but eventually the water would become more saline. The rate of saline-water intrusion toward the well field would depend on the rate of pumping, aquifer properties, and on the proximity of the well field to saline water sources. The steady-state, ground-water-flow model also was used to simulate drawdowns around two hypothetical well fields and drawdowns around two hypothetical open-pit mines. The chloride concentrations simulated in the model did not approximate the measured concentrations for some wells, indicating sites where local hydrogeologic units or unit properties do not conform to the simple hydrogeology of the model. The Columbia aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer compose the hydrogeologic units of the shallow aquifer system of Virginia Beach. The Columbia and Yorktown-Eastover aquifers are poorly confined throughout most of the southern watersheds of Virginia Beach. The freshwater-to-saline-water distribution probably is in a dynamic equilibrium throughout most of the shallow aquifer system. Freshwater flows continually down and away from the center of the higher altitudes to mix with saline water from the tidal rivers, bays, salt marshes, and the Atlantic Ocean. Fresh ground water from the Columbia aquifer also leaks down through the Yorktown confining unit into the upper half of the Yorktown-Eastover aquifer and flows within the Yorktown-Eastover above saline water in the lower half of the aquifer. Ground-water recharge is minimal in much of the southern watersheds because the land surface generally is low and flat.

Water-Resources Investigations Report↗

Water resources data, Florida, water year 1996. Volume 2B: South Florida - ground water

Water resources data for 1996 water year in Florida consists of continuous or daily discharge for 319 streams, periodic discharge for 41 streams, continuous or daily stage for 97 streams, periodic stage for 8 streams, peak discharge for 35 streams, and peak stage for 12 streams; continuous or daily elevations for 30 lakes, periodic elevations for 56 lakes; continuous ground-water levels for 417 wells, periodic groundwater levels for 1,370 wells; quality of water data for 113 surface-water sites and 279 wells. The data for South Florida included continuous or daily discharge for 73 streams, continuous or daily stage for 76 streams, peak stage discharge for no streams, continuous elevation for 1 lake; continuous groundwater levels for 222 wells, periodic ground-water levels for 772 wells and no miscellaneous water-level measurements; quality-of-water for 29 surface-water sites and 207 wells. The data represent the National Water Data System records collected by the U.S. Geological Survey and cooperation with local, state, and federal agencies in Florida.

Florida↗

Water resources data, Florida, water year 1997. Volume 2B: South Florida - ground water

Water resources data for 1997 water year in Florida consists of continuous or daily discharge for 341 streams, periodic discharge for 20 streams, continuous or daily stage for 122 streams, periodic stage for 13 streams, peak discharge for 20 streams, and peak stage for 20 streams; continuous or daily elevations for 35 lakes, periodic elevations for 60 lakes; continuous ground-water levels for 398 wells, periodic groundwater levels for 1247 wells; quality of water data for 166 surface-water sites and 298 wells. The data for South Florida included continuous or daily discharge for 74 streams, continuous or daily stage for 123 streams, no peak stage discharge for streams, continuous elevation for 1 lake; continuous groundwater levels for 211 wells, periodic ground-water levels for 361 wells; quality-of-water for 27 surface-water sites and 125 wells. The data represent the National Water Data System records collected by the U.S. Geological Survey and cooperation with local, state, and federal agencies in Florida.

Florida↗

Water resources data, Florida, water year 1998. Volume 2B: South Florida - ground water

Water resources data for 1998 water year in Florida consists of continuous or daily discharge for 307 streams, periodic discharge for 30 streams, continuous or daily stage for 89 streams, periodic stage for 4 streams, peak discharge for 38 streams, and peak stage for 38 streams; continuous or daily elevations for 51 lakes, periodic elevations for 51 lakes; continuous ground-water levels for 439 wells, periodic groundwater levels for 1958 wells; quality of water data for 118 surface-water sites and 267 wells. The data for South Florida included continuous or daily discharge for 73 streams, continuous or daily stage for 45 streams, no peak stage discharge for streams, continuous elevation for 1 lake; continuous groundwater levels for 233 wells, periodic ground-water levels for 329 wells; quality-of-water for 37 surface-water sites and 155 wells. The data represent the National Water Data System records collected by the U.S. Geological Survey and cooperation with local, state, and federal agencies in Florida.

Florida↗

Water resources data, Florida, water year 1999. Volume 2B: South Florida - ground water

Water resources data for 1999 water year in Florida consists of continuous or daily discharge for 354 streams, periodic discharge for 17 streams, continuous or daily stage for 121 streams, periodic stage for 1 streams, peak discharge for 38 streams, and peak stage for 38 streams; continuous or daily elevations for 21 lakes, periodic elevations for 42 lakes; continuous ground-water levels for 408 wells, periodic groundwater levels for 1715 wells; quality of water data for 131 surface-water sites and 198 wells. The data for South Florida included continuous or daily discharge for 75 streams, continuous or daily stage for 45 streams, no peak stage discharge for streams, continuous elevation for 1 lake; continuous groundwater levels for 210 wells, periodic ground-water levels for 215 wells; quality-of-water for 25 surface-water sites and 117 wells. The data represent the National Water Data System records collected by the U.S. Geological Survey and cooperation with local, state, and federal agencies in Florida.

Florida↗

An Excel Workbook for Identifying Redox Processes in Ground Water

The reduction/oxidation (redox) condition of ground water affects the concentration, transport, and fate of many anthropogenic and natural contaminants. The redox state of a ground-water sample is defined by the dominant type of reduction/oxidation reaction, or redox process, occurring in the sample, as inferred from water-quality data. However, because of the difficulty in defining and applying a systematic redox framework to samples from diverse hydrogeologic settings, many regional water-quality investigations do not attempt to determine the predominant redox process in ground water. Recently, McMahon and Chapelle (2008) devised a redox framework that was applied to a large number of samples from 15 principal aquifer systems in the United States to examine the effect of redox processes on water quality. This framework was expanded by Chapelle and others (in press) to use measured sulfide data to differentiate between iron(III)- and sulfate-reducing conditions. These investigations showed that a systematic approach to characterize redox conditions in ground water could be applied to datasets from diverse hydrogeologic settings using water-quality data routinely collected in regional water-quality investigations. This report describes the Microsoft Excel workbook, RedoxAssignment_McMahon&Chapelle.xls, that assigns the predominant redox process to samples using the framework created by McMahon and Chapelle (2008) and expanded by Chapelle and others (in press). Assignment of redox conditions is based on concentrations of dissolved oxygen (O2), nitrate (NO3-), manganese (Mn2+), iron (Fe2+), sulfate (SO42-), and sulfide (sum of dihydrogen sulfide [aqueous H2S], hydrogen sulfide [HS-], and sulfide [S2-]). The logical arguments for assigning the predominant redox process to each sample are performed by a program written in Microsoft Visual Basic for Applications (VBA). The program is called from buttons on the main worksheet. The number of samples that can be analyzed is only limited by the number of rows in Excel (65,536 for Excel 2003 and XP; and 1,048,576 for Excel 2007), and is therefore appropriate for large datasets.

Open-File Report↗