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At least 703 records · Page 39Linked to original sources

Comparison of two cell lysis procedures for recovery of microcystins in water samples from silver lake in Dover, Delaware, with microcystin producing cyanobacterial accumulations

A collaboration was developed between Abraxis, LLC, the State of Delaware Department of Natural Resources and Environmental Control Division of Water Resources Environmental Laboratory, the University of Delaware, and the United States Geological Survey to investigate the efficacy of the QuikLyse procedure developed by Abraxis, LLC as an alternative cell-lysis technique suitable for use with an existing liquid chromatography/tandem mass spectrometry research method developed at the United States Geological Survey Organic Geochemistry Research Laboratory to analyze cyanotoxins. A comparison of three sequential freeze/thaw cycles versus QuikLyse, a proprietary chemical lysis procedure was conducted on four water samples collected from Silver Lake in Dover, Delaware. Results from the Abraxis Microcystins-DM enzyme-linked immunosorbent assay and liquid chromatography/tandem mass spectrometry were tabulated as a function of the cell lysis technique. Stastical comparison of percent relative standard deviations showed no significant difference (alpha = 0.05) between both cell-lysis techniques when measured by enzyme-linked immunosorbent assay or liquid chromatography/tandem mass spectrometry for three of the four samples.

Delaware↗

Towards policy relevant environmental modeling: contextual validity and pragmatic models

"What makes for a good model?" In various forms, this question is a question that, undoubtedly, many people, businesses, and institutions ponder with regards to their particular domain of modeling. One particular domain that is wrestling with this question is the multidisciplinary field of environmental modeling. Examples of environmental models range from models of contaminated ground water flow to the economic impact of natural disasters, such as earthquakes. One of the distinguishing claims of the field is the relevancy of environmental modeling to policy and environment-related decision-making in general. A pervasive view by both scientists and decision-makers is that a "good" model is one that is an accurate predictor. Thus, determining whether a model is "accurate" or "correct" is done by comparing model output to empirical observations. The expected outcome of this process, usually referred to as "validation" or "ground truthing," is a stamp on the model in question of "valid" or "not valid" that serves to indicate whether or not the model will be reliable before it is put into service in a decision-making context. In this paper, I begin by elaborating on the prevailing view of model validation and why this view must change. Drawing from concepts coming out of the studies of science and technology, I go on to propose a contextual view of validity that can overcome the problems associated with "ground truthing" models as an indicator of model goodness. The problem of how we talk about and determine model validity has much to do about how we perceive the utility of environmental models. In the remainder of the paper, I argue that we should adopt ideas of pragmatism in judging what makes for a good model and, in turn, developing good models. From such a perspective of model goodness, good environmental models should facilitate communication, convey—not bury or "eliminate"—uncertainties, and, thus, afford the active building of consensus decisions, instead of promoting passive or self-righteous decisions.

Open-File Report↗

Spatial patterns of development drive water use

Water availability is becoming more uncertain as human populations grow, cities expand into rural regions and the climate changes. In this study, we examine the functional relationship between water use and the spatial patterns of developed land across the rapidly growing region of the southeastern United States. We quantified the spatial pattern of developed land within census tract boundaries, including multiple metrics of density and configuration. Through non‐spatial and spatial regression approaches we examined relationships and spatial dependencies between the spatial pattern metrics, socio‐economic and environmental variables and two water use variables: a) domestic water use, and b) total development‐related water use (a combination of public supply, domestic self‐supply and industrial self‐supply). Metrics describing the spatial patterns of development had the highest measure of relative importance (accounting for 53% of model's explanatory power), explaining significantly more variance in water use compared to socio‐economic or environmental variables commonly used to estimate water use. Integrating metrics characterizing the spatial pattern of development into water use models is likely to increase their utility and could facilitate water‐efficient land use planning.

North Carolina, South Carolina↗

Effects of environmental clutter on synthesized chiropteran echolocation signals in an anechoic chamber

Ultrasonic bat detectors are useful for research and monitoring purposes to assess occupancy and relative activity of bat communities. Environmental “clutter” such as tree boles and foliage can affect the recording quality and identification of bat echolocation calls collected using ultrasonic detectors. It can also affect the transmission of calls and recognition by bats when using acoustic lure devices to attract bats to mist-nets. Bat detectors are often placed in forests, yet automatic identification programs are trained on call libraries using echolocation passes recorded largely from open spaces. Research indicates that using clutter-recorded calls can increase classification accuracy for some bat species and decrease accuracy for others, but a detailed understanding of how clutter impacts the recording and identification of echolocation calls remains elusive. To clarify this, we experimentally investigated how two measures of clutter (i.e., total basal area and number of stems of simulated woody growth, as well as recording angle) affected the recording and classification of a synthesized echolocation signal under controlled conditions in an anechoic chamber. Recording angle (i.e., receiver position relative to emitter) significantly influenced the probability of correct classification and differed significantly for many of the call parameters measured. The probability of recording echo pulses was also a function of clutter but only for the detector angle at 0° from the emitter that could receive deflected pulses. Overall, the two clutter metrics were overshadowed by proximity and angle of the receiver to the sound source but some deviations from the synthesized call in terms of maximum, minimum, and mean frequency parameters were observed. Results from our work may aid efforts to better understand underlying environmental conditions that produce false-positive and -negative identifications for bat species of interest and how this could be used to adjust survey accuracy estimates. Our results also help pave the way for future research into the development of acoustic lure technology by exploring the effects of environmental clutter on ultrasound transmission.

Acoustics↗

Mapping of suspended sediment transport using acoustic methods in a Pantanal tributary

Generally, fluvial systems are used for different objectives including energy production, water supply, recreation, and navigation. Thus, many impacts must be considered with their use. An understanding of sediment dynamics in fluvial systems is often of value for a variety of objectives, given that erosion and depositional processes can change the fluvial system morphology and can substantially alter the fluvial environment. In this sense, sediment monitoring is important because it helps to explain and quantify sediment dynamics in the environment. Hence, this study presents an innovative sediment monitoring technique: the use of the acoustic Doppler current profiler, commonly used to obtain discharge measurements, to obtain suspended sediment concentration (SSC). This paper aims to describe the application of additional corrections to the ADP-M9 signal to obtain SSC from measurement campaigns that used the ADP only for discharge measurements. The analyses were based on traditional sediment sampling methods and discharge measurements, with the ADP-M9, from 7 field campaigns at the Taquari River, a major tributary from the Alto Paraguay Basin, in the Pantanal Biome, known as the largest freshwater wetland system in the world. The correlation was assessed considering the following: (a) the equipment frequency operation mode (Smart Pulse or Fixed Frequency) and (b) by checking the influence of the sediment attenuation coefficient. Furthermore, extrapolation was conducted in filtered and unmeasured areas of the ADP to map the suspended sediment concentration over the entire cross section. Results indicate that ADP correlations can be an effective tool for estimating SSC in the Taquari River when samples cannot be collected. Correlations could be applied to past and future ADP measurements made at the location where the correlation was created, as long as similar environmental conditions are present as when the correlation was developed. The described technique can expand the amount of sediment data available at a monitoring site even with reduced traditional sampling and by leveraging instruments used for other monitoring purposes.

Taquari River Basin↗

Effects of Changes in Irrigation Practices and Aquifer Development on Groundwater Discharge to the Jobos Bay National Estuarine Research Reserve near Salinas, Puerto Rico

Since 1990, about 75 acres of black mangroves have died in the Jobos Bay National Estuarine Research Reserve near Salinas, Puerto Rico. Although many factors can contribute to the mortality of mangroves, changes in irrigation practices, rainfall, and water use resulted in as much as 25 feet of drawdown in the potentiometric surface of the aquifer in the vicinity of the reserve between 1986 and 2002. To clarify the issue, the U.S. Geological Survey, in cooperation with the Puerto Rico Department of Natural and Environmental Resources, conducted a study to ascertain how aquifer development and changes in irrigation practices have affected groundwater levels and groundwater flow to the Mar Negro area of the reserve. Changes in groundwater flow to the mangrove swamp and bay from 1986 to 2004 were estimated in this study by developing and calibrating a numerical groundwater flow model. The transient simulations indicate that prior to 1994, high irrigation return flows more than offset the effect of reduced groundwater withdrawals. In this case, the simulated discharge to the coast in the modeled area was 19 million gallons per day. From 1994 through 2004, furrow irrigation was completely replaced by micro-drip irrigation, thus eliminating return flows and the simulated average coastal discharge was 7 million gallons per day, a reduction of 63 percent. The simulated average groundwater discharge to the coastal mangrove swamps in the reserve from 1986 to 1993 was 2 million gallons per day, compared to an average simulated discharge of 0.2 million gallons per day from 1994 to 2004. The average annual rainfall for each of these periods was 38 inches. The groundwater discharge to the coastal mangrove swamps in the Jobos Bay National Estuarine Research Reserve was estimated at about 0.5 million gallons per day for 2003-2004 because of higher than average annual rainfall during these 2 years. The groundwater flow model was used to test five alternatives for increasing groundwater discharge to the coastal mangrove swamps to approximately 1.4 million gallons per day: (1) artificially recharging the aquifer with injection wells or (2) by increasing irrigation return flow by going back to furrow irrigation; (3) termination of groundwater withdrawals near the mangroves; (4) reduction of groundwater withdrawals at irrigation wells by 50 percent; and (5) a combination of alternatives 2 and 4 increasing irrigation return flows and decreasing irrigation withdrawals. Each alternative assumed average climatic conditions and groundwater withdrawals at 2004 rates. Alternative 1 required 1.5 million gallons per day of injected water. Alternative 2 required flooding 958 acres with a rate of 1.84 million gallons per day if no crops are grown. Alternative 3 required the termination of 2.44 million gallons per day of withdrawals to achieve 1.34 million gallons per day of discharge to the mangroves. Alternative 4 did not achieve the objective with only 0.80 million gallons per day simulated discharge to the mangroves, while requiring a 1.26 million gallon per day reduction in groundwater withdrawals. Alternative 5 required flooding fields with additional 1.13 million gallons of day and the same reduction in groundwater withdrawals, but did achieve the objective of about 1.4 million gallons per day discharge to the mangroves. Alternative 1, incorporating injection wells near the reserve required the least amount of water to raise groundwater levels and maintain discharge of 1.4 million gallons per day through the mangroves.

Scientific Investigations Report↗

Advancing estuarine ecological forecasts: Seasonal hypoxia in Chesapeake Bay

Ecological forecasts are quantitative tools that can guide ecosystem management. The coemergence of extensive environmental monitoring and quantitative frameworks allows for widespread development and continued improvement of ecological forecasting systems. We use a relatively simple estuarine hypoxia model to demonstrate advances in addressing some of the most critical challenges and opportunities of contemporary ecological forecasting, including predictive accuracy, uncertainty characterization, and management relevance. We explore the impacts of different combinations of forecast metrics, drivers, and driver time windows on predictive performance. We also incorporate multiple sets of state-variable observations from different sources and separately quantify model prediction error and measurement uncertainty through a flexible Bayesian hierarchical framework. Results illustrate the benefits of (1) adopting forecast metrics and drivers that strike an optimal balance between predictability and relevance to management, (2) incorporating multiple data sources in the calibration data set to separate and propagate different sources of uncertainty, and (3) using the model in scenario mode to probabilistically evaluate the effects of alternative management decisions on future ecosystem state. In the Chesapeake Bay, the subject of this case study, we find that average summer or total annual hypoxia metrics are more predictable than monthly metrics and that measurement error represents an important source of uncertainty. Application of the model in scenario mode suggests that absent watershed management actions over the past decades, long-term average hypoxia would have increased by 7% compared to 1985. Conversely, the model projects that if management goals currently in place to restore the Bay are met, long-term average hypoxia would eventually decrease by 32% with respect to the mid-1980s.

Chesapeake Bay↗

Influence of sulfur-bearing polyatomic species on high precision measurements of Cu isotopic composition

An increased interest in high precision Cu isotope ratio measurements using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) has developed recently for various natural geologic systems and environmental applications, these typically contain high concentrations of sulfur, particularly in the form of sulfate (SO 4 2- ) and sulfide (S). For example, Cu, Fe, and Zn concentrations in acid mine drainage (AMD) can range from 100??g/L to greater than 50mg/L with sulfur species concentrations reaching greater than 1000mg/L. Routine separation of Cu, Fe and Zn from AMD, Cu-sulfide minerals and other geological matrices usually incorporates single anion exchange resin column chromatography for metal separation. During chromatographic separation, variable breakthrough of SO 4 2- during anion exchange resin column chromatography into the Cu fractions was observed as a function of the initial sulfur to Cu ratio, column properties, and the sample matrix. SO 4 2- present in the Cu fraction can form a polyatomic 32 S- 14 N- 16 O- 1 H species causing a direct mass interference with 63 Cu and producing artificially light ?? 65 Cu values. Here we report the extent of the mass interference caused by SO 4 2- breakthrough when measuring ?? 65 Cu on natural samples and NIST SRM 976 Cu isotope spiked with SO 4 2- after both single anion column chromatography and double anion column chromatography. A set of five 100??g/L Cu SRM 976 samples spiked with 500mg/L SO 4 2- resulted in an average ?? 65 Cu of -3.50?????5.42??? following single anion column separation with variable SO 4 2- breakthrough but an average concentration of 770??g/L. Following double anion column separation, the average SO 4 2- concentration of 13??g/L resulted in better precision and accuracy for the measured ?? 65 Cu value of 0.01?????0.02??? relative to the expected 0??? for SRM 976. We conclude that attention to SO 4 2- breakthrough on sulfur-rich samples is necessary for accurate and precise measurements of ?? 65 Cu and may require the use of a double ion exchange column procedure. ?? 2010.

Chemical Geology↗

Museum metabarcoding: a novel method revealing gut helminth communities of small mammals across space and time

Natural history collections spanning multiple decades provide fundamental historical baselines to measure and understand changing biodiversity. New technologies such as next generation DNA sequencing (NGS) have considerably increased the potential of museum specimens to address significant questions regarding the impact of environmental changes on host and parasite/pathogen dynamics. We developed a new technique to identify intestinal helminth parasites and applied it to shrews (Eulipotyphla: Soricidae) because they are ubiquitous, occupy diverse habitats, and host a diverse and abundant parasite fauna. Notably, we included museum specimens preserved in various ways to explore the efficacy of using metabarcoding analyses that may enable identification of helminth symbiont communities from historical archives. We successfully sequenced the parasite communities (using 12S mtDNA, 16S mtDNA, 28S rDNA) of 23 whole gastrointestinal (GI) tracts. All GI tracts were obtained from the Museum of Southwestern Biology (MSB), USA, and from recent field collections, varying both in time since fixation (ranging from 4 months to 16 years) and preservation method (70% or 95% ethanol stored at room temperature, or flash frozen in liquid nitrogen and stored at -80°C). Our proof of concept demonstrates the feasibility of applying NGS techniques to authoritatively identify the parasite/pathogen communities within whole GI tracts from museum specimens of varying age and fixation, and the value of future preservation of host-associated whole GI tracts in public research archives. This powerful approach facilitates future comparative examinations of the distributions and interactions among multiple associated groups of organisms through time and space.

International Journal for Parasitology↗

Selenium toxicity: cause and effects in aquatic birds

There are several manners in which selenium may express its toxicity: (1) an important mechanism appears to involve the formation of CH3Se- which either enters a redox cycle and generates superoxide and oxidative stress, or forms free radicals that bind to and inhibit important enzymes and proteins. (2) Excess selenium as selenocysteine results in inhibition of selenium methylation metabolism. As a consequence, concentrations of hydrogen selenide, an intermediate metabolite, accumulate in animals and are hepatotoxic, possibly causing other selenium-related adverse effects. (3) It is also possible that the presence of excess selenium analogs of sulfur-containing enzymes and structural proteins play a role in avian teratogenesis. l-selenomethionine is the most likely major dietary form of selenium encountered by aquatic birds, with lesser amounts of l-selenocysteine ingested from aquatic animal foods. The literature is suggestive that l-selenomethionine is not any more toxic to adult birds than other animals. l-Selenomethionine accumulates in tissue protein of adult birds and in the protein of egg white as would be expected to occur in animals. There is no suggestion from the literature that the levels of l-selenomethionine that would be expected to accumulate in eggs in the absence of environmental concentration of selenium pose harm to the developing embryo. For several species of aquatic birds, levels of Se as selenomethionine in the egg above 3 ppm on a wet weight basis result in reduced hatchability and deformed embryos. The toxicity of l-selenomethionine injected directly into eggs is greater than that found from the entry of l-selenomethionine into the egg from the normal adult diet. This suggests that there is unusual if not abnormal metabolism of l-selenomethionine in the embryo not seen when l-selenomethionine is present in egg white protein where it likely serves as a source of selenium for glutathione peroxidase synthesis in the developing aquatic chick.

Aquatic Toxicology↗

Exploring the potential of electrospray-Orbitrap for stable isotope analysis using nitrate as a model

Widely used isotope ratio mass spectrometers have limited capabilities to measure metabolites, drugs, or small polyatomic ions without the loss of structural isotopic information. A new approach has recently been introduced that uses electrospray ionization Orbitrap to measure multidimensional isotope signatures of intact polar compounds. Using nitrate as a model compound, this study aims to establish performance metrics for comparisons with conventional IRMS at the natural abundance level. We present a framework on how to convert isotopolog intensities to δ values that are commonly used in the isotope geochemistry community. The quantification of seven nitrate isotopologs provides multiple pathways for obtaining the primary N and O δ values including non-mass-dependent O isotope variations, as well as opportunities to explore nonrandom isotopic distributions (i.e., clumping effects) within molecular nitrate. Using automation and the adaptation of measurement principles that are specific to isotope ratio analysis, nitrate δ15NAIR, δ18OVSMOW, and δ17OVSMOW were measured with a long-term precision of 0.4‰ or better for isotopic reference materials and purified nitrate from environmental samples. In addition, we demonstrate promising results for unpurified environmental samples in liquid form. With these new developments, this study connects the two largely disparate mass spectrometry fields of bioanalytical MS and isotope ratio MS, thus providing a route to measure new isotopic signatures in diverse organic and inorganic solutes.

Analytical Chemistry↗

Historical and future land use effects on N 2 O and NO emissions using an ensemble modeling approach: Costa Rica's Caribbean lowlands as an example

[1] The humid tropical zone is a major source area for N 2 O and NO emissions to the atmosphere. Local emission rates vary widely with local conditions, particularly land use practices which swiftly change with expanding settlement and changing market conditions. The combination of wide variation in emission rates and rapidly changing land use make regional estimation and future prediction of biogenic trace gas emission particularly difficult. This study estimates contemporary, historical, and future N 2 O and NO emissions from 0.5 million ha of northeastern Costa Rica, a well-documented region in the wet tropics undergoing rapid agricultural development. Estimates were derived by linking spatially distributed environmental data with an ecosystem simulation model in an ensemble estimation approach that incorporates the variance and covariance of spatially distributed driving variables. Results include measures of variance for regional emissions. The formation and aging of pastures from forest provided most of the past temporal change in N 2 O and NO flux in this region; future changes will be controlled by the degree of nitrogen fertilizer application and extent of intensively managed croplands.

Global Biogeochemical Cycles↗

Atmospheric mineral dust in dryland ecosystems: Applications of environmental magnetism

Magnetic properties of shallow (<10‐cm depth), fine‐grained surficial sediments contrast greatly with those of immediately underlying bedrock across much of the dry American Southwest. At 26 study sites in fine‐grained (<63 μ m) surficial sediments isolated from alluvial inputs, isothermal remanent magnetization (IRM; mean of 67 samples = 6.72 × 10 −3 Am 2 kg −1 ) is more than two orders of magnitude greater than that for underlying Paleozoic and Mesozoic sedimentary rocks. This contrast is mainly caused by the presence of silt‐size, titanium‐bearing magnetite particles in the surficial deposits and their absence in bedrock. Because of their size, composition, and isolated location, the magnetite particles represent a component of atmospheric dust likely deposited over the past few centuries. The positive correlation of sediment‐IRM values with amounts of potential plant nutrients reveals the importance of atmospheric dust to soil fertility over much of the American Southwest. Subsequent disturbance of landscapes, by domestic livestock grazing as an example, commonly results in wind erosion, which then depletes exposed surfaces of original aeolian magnetite and associated fine‐grained sediment. Declines in soil fertility and water‐holding capacity in these settings can be estimated in some field settings via decreases in magnetic susceptibility, relative to nearby undisturbed areas. Along gentle hillslope gradients of the Colorado Plateau, field measures for aeolian magnetite demonstrate that the redistribution of deposited atmospheric dust influences landscape‐level patterns in the distribution of invasive exotic plant species. Our results indicate that environmental magnetism has high potential for assessing the development and degradation of dry landscapes elsewhere.

Geochemistry, Geophysics, Geosystems↗

History of wildlife toxicology and the interpretation of contaminant concentrations in tissues

The detection and interpretation of contaminants in tissues of wildlife belongs to the field of toxicology, a scientific discipline with a long, intriguing, and illustrious history. Concern over poisoning of wildlife began in the late nineteenth century, and initially focused more on identifying environmental problems than determining contaminant concentrations in tissues. Endpoint measurements were characterized for sensitivity, specificity, variability, clarity of interpretation, validity, and applicability to field sampling. The use of stable isotopes to identify the environmental source of a metal is a recent development in the field of wildlife toxicology. The chemical forms of Mercury may be changed within some organs (e.g., demethylation by liver), further complicating interpretation of wildlife tissue concentrations. The field of wildlife toxicology has been shaped by chemical use and misuse, ecological mishaps, and research in the allied field of human toxicology. The development and use of new chemicals, and unexpected and unpredicted contamination problems continue to drive this discipline.

Book chapter↗

Water for the Nation: An overview of the USGS Water Resources Division

The Water Resources Division (WRD) of the U.S. Geological Survey (USGS) provides reliable, impartial, timely information needed to understand the Nation's water resources. WRD actively promotes the use of this information by decisionmakers to: * Minimize the loss of life and property as a result of water-related hazards such as floods, droughts, and land movement. * Effectively manage ground-water and surface-water resources for domestic, agricultural, commercial, industrial, recreational, and ecological uses. * Protect and enhance water resources for human health, aquatic health, and environmental quality. * Contribute to wise physical and economic development of the Nation's resources for the benefit of present and future generations.

General Information Product↗

Introductory text

The U.S. Geological Survey (USGS) provides information on the current use and flow of minerals and mineral-based materials in the U.S. and world economies. This Data Series report on “Historical Global Statistics for Mineral and Material Commodities” contains information on the production of selected commodities from 1990 to the most current year. The data may be used in the analysis of socioeconomic developments and trends and in the study of environmental issues associated with the extraction and processing of the selected commodities. This report on global statistics includes U.S. data and is a companion to Data Series 140 on “Historical Statistics for Mineral and Material Commodities in the United States.”

Data Series↗

Long-term trends in naturalized rainbow trout ( Oncorhynchus mykiss ) populations in the upper Esopus Creek, Ulster County, New York, 2009–15

The U.S. Geological Survey, in cooperation with Cornell Cooperative Extension of Ulster County, New York State Energy Research and Development Authority, the New York State Department of Environmental Conservation, and the New York City Department of Environmental Protection, surveyed fish communities annually on the main stem and tributaries of the upper Esopus Creek, Ulster County, New York, from 2009 to 2015. This report summarizes the density, biomass, and size structure of rainbow trout ( Oncorhynchus mykiss ) and brown trout ( Salmo trutta ) populations from the 2015 surveys along with data from the preceding 6 years. The mean density of rainbow trout populations in 2015 was 98 fish per 0.1 hectare, which was the highest value observed since 2010, and the mean biomass of rainbow trout populations in 2015 was 864 grams per 0.1 hectare, which was the highest value observed since 2012.

New York↗

USGS Western Coastal and Marine Geology Team

The Western Coastal and Marine Geology Team of the U.S. Geological Survey (USGS) studies the coasts of the western United States, including Alaska and Hawai‘i. Team scientists conduct research, monitor processes, and develop information about coastal and marine geologic hazards, environmental conditions, habitats, and energy and mineral resources. This information helps managers at all levels of government and in the private sector make informed decisions about the use and protection of national coastal and marine resources.

Fact Sheet↗