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At least 703 records · Page 39Linked to original sources

Polycyclic aromatic hydrocarbons, aliphatic hydrocarbons, trace elements and monooxygenase activity in birds nesting on the North Platte River, Casper, Wyoming, USA

Tree swallow (Tachycineta bicolor) and house wren (Troglodytes aedon) eggs and chicks were collected near a refinery site on the North Platte River, Casper, Wyoming, USA and at a reference site 10 km upstream. Total polycylic aromatic hydrocarbon (PAH) concentrations in swallow and wren chicks were higher at the refinery site than at the reference site. Polycylic aromatic hydrocarbon concentrations in sediment and chick dietary samples were consistent with these findings. The general lack of methylated PAHs in sediment, diet, and bird carcasses suggested that the PAHs were derived from combustion and not from petroleum. The predominance of odd numbered aliphatic hydrocarbons and the low ratios (≤ 0.25) of pristane: n -C 17 and phytane: n -C 18 in chick and diet samples also suggested that swallow and wren chicks were not being chronically exposed to petroleum. Mean ethoxyresorufin- O -dealkylase and benzyloxyresorufin- O -dealkylase activities in tree swallow livers averaged nine times higher at the refinery site than at the reference site and were probably induced by exposure to PAHs. Trace element concentrations in eggs and livers of swallows and wrens were similar or greater at the reference site than at the refinery site. Selenium, strontium, and boron concentrations were elevated in eggs and livers of swallows and wrens at both the refinery and reference sites.

Wyoming↗

Finite-element modelling of physics-based hillslope hydrology, Keith Beven, and beyond

Keith Beven is a voice of reason on the intelligent use of models and the subsequent acknowledgement/assessment of the uncertainties associated with environmental simula-tion. With several books and hundreds of papers, Keith’s work is widespread, well known, and highly referenced. Four of Keith’s most notable contributions are the iconic TOPMODEL (Beven and Kirkby, 1979), classic papers on macropores and preferential flow (Beven and Germann, 1982, 2013), two editions of the rainfall-runoff modelling bible (Beven, 2000a, 2012), and the selection/commentary for the first volume from the Benchmark Papers in Hydrology series (Beven, 2006b). Remarkably, the thirty-one papers in his benchmark volume, entitled Streamflow Generation Processes, are not tales of modelling wizardry but describe measurements designed to better understand the dynamics of near-surface systems (quintessential Keith). The impetus for this commentary is Keith’sPhD research (Beven, 1975), where he developed a new finite-element model and conducted concept-development simu-lations based upon the processes identified by, for example, Richards (1931), Horton (1933), Hubbert (1940), Hewlett and Hibbert (1963), and Dunne and Black (1970a,b). Readers not familiar with the different mechanisms of streamflow generation are referred to Dunne (1978).

Hydrological Processes↗

A 15 000-year record of climate change in northern New Mexico, USA, inferred from isotopic and elemental contents of bog sediments

Elemental (C, N, Pb) and isotopic ( δ 13 C, δ 15 N) measurements of cored sediment from a small bog in northern New Mexico reveal changes in climate during the Late Pleistocene and Holocene. Abrupt increases in Pb concentration and δ 13 C values ca. 14 420 cal. YBP indicate significant runoff to the shallow lake that existed at that time. Weathering and transport of local volcanic rocks resulted in the delivery of Pb-bearing minerals to the basin, while a 13 C-enriched terrestrial vegetation source increased the δ 13 C values of the sedimentary material. Wet conditions developed over a 300 a period and lasted for a few hundred years. The Younger Dryas period (ca. 12 700–11 500 cal. YBP) caused a reduction in terrestrial productivity reflected in decreasing C/N values, δ 15 N values consistently greater than 0‰ and low organic content. By contrast, aquatic productivity increased during the second half of this period, evidenced by increasing δ 13 C values at the time of highest abundance of algae. Dry conditions ca. 8 000–6 000 cal. YBP were characterised by low organic carbon content and high Pb concentrations, the latter suggesting enhanced erosion and aeolian transport of volcanic rock. The range in δ 13 C, δ 15 N and C/N values in the sedimentary record fall within the range of modern plants, except during the periods of runoff and drought. The sedimentary record provides evidence of natural climate variability in northern New Mexico, including short- (multi-centennial) and long-(millennial) term episodes during the Late Pleistocene and Holocene.

Journal of Quaternary Science↗

The complex variable boundary element method: Applications

The complex variable boundary element method (CVBEM) is used to approximate several potential problems where analytical solutions are known: A modelling result produced from the CVBEM is a measure of relative error in matching the known boundary condition values of the problem. A CVBEM error-reduction algorithm is used to reduce the relative error of the approximation by adding nodal points in boundary regions where error is large. From the-test problems, overall error is reduced significantly by utilizing the adaptive integration algorithm.

International Journal for Numerical Methods in Eng↗

Applying the silver-tube introduction method for thermal conversion elemental analyses and a new δ 2 H value for NBS 22 oil

The δ 2 H VSMOW–SLAP value of total hydrogen of the international measurement standard NBS 22 oil was determined by a new method of sealing water in silver tubes for use in a thermal conversion elemental analysis (TC/EA) reduction unit. The isotopic fractionation of water due to evaporation is virtually non-existent in this silver-tube method. A new value for the δ 2 H VSMOW–SLAP of NBS 22 oil, calibrated with isotopic reference waters, was determined to be −116.9 ± 0.8‰ (1σ and n = 31).

Rapid Communications in Mass Spectrometry↗

Optimization of on-line hydrogen stable isotope ratio measurements of halogen- and sulfur-bearing organic compounds using elemental analyzer–chromium/high-temperature conversion isotope ratio mass spectrometry (EA-Cr/HTC-IRMS)

Rationale: Accurate hydrogen isotopic analysis of halogen- and sulfur-bearing organics has not been possible with traditional high-temperature conversion (HTC) because the formation of hydrogen-bearing reaction products other than molecular hydrogen (H2) is responsible for non-quantitative H2 yields and possible hydrogen isotopic fractionation. Our previously introduced, new chromium-based EA-Cr/HTC-IRMS (Elemental Analyzer–Chromium/High-Temperature Conversion Isotope Ratio Mass Spectrometry) technique focused primarily on nitrogen-bearing compounds. Several technical and analytical issues concerning halogen- and sulfur-bearing samples, however, remained unresolved and required further refinement of the reactor systems. Methods: The EA-Cr/HTC reactor was substantially modified for the conversion of halogen- and sulfur-bearing samples. The performance of the novel conversion setup for solid and liquid samples was monitored and optimized using a simultaneously operating dual-detection system of IRMS and ion trap MS. The method with several variants in the reactor, including the addition of manganese metal chips, was evaluated in three laboratories using EA-Cr/HTC-IRMS (on-line method) and compared with traditional uranium-reduction-based conversion combined with manual dual-inlet IRMS analysis (off-line method) in one laboratory. Results: The modified EA-Cr/HTC reactor setup showed an overall H2-recovery of more than 96% for all halogen- and sulfur-bearing organic compounds. All results were successfully normalized via two-point calibration with VSMOW-SLAP reference waters. Precise and accurate hydrogen isotopic analysis was achieved for a variety of organics containing F-, Cl-, Br-, I-, and S-bearing heteroelements. The robust nature of the on-line EA-Cr/HTC technique was demonstrated by a series of 196 consecutive measurements with a single reactor filling. Conclusions: The optimized EA-Cr/HTC reactor design can be implemented in existing analytical equipment using commercially available material and is universally applicable for both heteroelement-bearing and heteroelement-free organic-compound classes. The sensitivity and simplicity of the on-line EA-Cr/HTC-IRMS technique provide a much needed tool for routine hydrogen-isotope source tracing of organic contaminants in the environment. Copyright © 2016 John Wiley & Sons, Ltd.

Rapid Communications in Mass Spectrometry↗

Hazard assessment of selenium and other trace elements in wild larval razorback sucker from the Green River, Utah

Contaminant investigations of the Green River in northeastern Utah have documented selenium contamination at sites receiving irrigation drainage. The Green River provides critical habitat for four endangered fishes including the largest extant riverine population of endangered razorback sucker. Although 2175 larval razorback suckers were collected from the river between 1992 and 1996, very few juveniles have been captured within recent decades. Selenium concentrations were measured in larval razorback suckers collected from five sites in the Green River (Cliff Creek, Stewart Lake Drain, Sportsman's Drain, Greasewood Corral, and Old Charlie Wash) to assess the potential for adverse effects on recruitment of larvae to the juvenile stage and the adult population. Larvae from all sites contained mean selenium concentrations ranging from 4.3 to 5.8 ??g/g. These values were at or above the proposed toxic threshold of 4 ??g/g for adverse biological effects in fish, which was derived from several laboratory and field studies with a wide range of fish species. At two sites, Cliff Creek and Stewart Lake Drain, selenium concentrations in larvae increased over time as fish grew, whereas selenium concentrations decreased as fish grew at Sportsman's Drain. Evaluation of a 279-larvae composite analyzed for 61 elements demonstrated that selenium and, to a lesser extent, vanadium were elevated to concentrations reported to be toxic to a wide range of fish species. Elevated selenium concentrations in larval razorback suckers from the five sites suggest that selenium contamination may be widespread in the Green River, and that survival and recruitment of larvae to the juvenile stage may be limited due to adverse biological effects. Selenium contamination may be adversely affecting the reproductive success and recruitment of endangered razorback sucker.

Ecotoxicology and Environmental Safety↗

Spatial data reduction through element -of-interest (EOI) extraction

Any large, multifaceted data collection that is challenging to handle with traditional management practices can be branded ‘Big Data.’ Any big data containing geo-referenced attributes can be considered big geospatial data. The increased proliferation of big geospatial data is currently reforming the geospatial industry into a data-driven enterprise. Challenges in the big spatial data domain can be summarized as the ‘Big Vs’ – variety, volume, velocity, veracity and value. Big spatial data sources can be considered in two broad classes, active and passive, as each is impacted to varying degrees. Some of these challenges may be alleviated by reducing unprocessed, or minimally processed, (raw) data to features, which we refer to as the extraction of Elements of Interest (EOI). In fact, many applications require EOI extraction from raw data to enable their basic employment. This chapter presents current state-of-the-art methods to create EOI from some types of georeferenced big data. We classify the data types into two realms: active and passive. Active data are those collected specifically for the purpose to which they are applied. Passive data are those collected for purposes other than those for which they are utilized, included those ‘collected’ for no particular purpose at all. The chapter then presents use cases from both the active and passive spatial realms, including the active applications of terrain feature extraction from digital elevation models and vegetation mapping from remotely-sensed imagery and passive applications like building identification from VGI and point-of-interest data mining from social networks for land use classification. Finally, the chapter concludes with future research needs.

Book chapter↗

Can we determine the biological availability of sediment-bound trace elements?

It is clear from available data that the susceptibility of biological communities to trace element contamination differs among aquatic environments. One important reason is that the bioavailability of metals in sediments appears to be altered by variations in sediment geochemistry. However, methods for explaining or predicting the effect of sediment geochemistry upon metal bioavailability are poorly developed. Experimental studies demonstrate that ingestion of sediments and uptake from solution may both be important pathways of metal bioaccumulation in deposit/detritus feeding species. Relative importance between the two is geochemistry dependent. Geochemical characteristics of sediments also affect metal concentrations in the tissues of organisms collected from nature, but the specific mechanisms by which these characteristics influence metal bioavailability have not been rigorously demonstrated. Several prerequisites are necessary to better understand the processes that control metal bioavailability from sediments. 1) improved computational or analytical methods for analyzing distribution of metals among components of the sediments; 2) improved computational methods for assessing the influences of metal form in sediments on sediment-water metal exchange; and 3) a better understanding of the processes controlling bioaccumulation of metals from solution and food by metazoan species directly exposed to the sediments. Such capabilities would allow mechanistic explanations essential to the development of practical tools sought for determining sediment quality criteria for metals.

Hydrobiologia↗

Platinum-group elements in rocks from the voikar-syninsky ophiolite complex, Polar Urals, U.S.S.R.

Analyses of platinum-group elements (PGE) in rocks collected from the Voikar-Syninsky ophiolite in the Polar Urals suggest that the distribution and geochemistry of PGE in this Paleozoic ophiolite are similar to those in Mesozoic ophiolites from elsewhere. Chondrite-normalized PGE patterns for chromitite, the tectonite unit, and ultramafic and mafic cumulate unit have negative slopes. These results are similar to those found for chromitites from other ophiolites; stratiform chromities show positive slopes. If the magmas that form both types of chromitite originate from similar mantle source material with respect to PGE content, the processes involved must be quite different. However, the distinct chondrite-normalized PGE patterns may reflect differing source materials. ?? 1983 Springer-Verlag.

Mineralium Deposita↗

Trace-element and Sr, Nd, Pb, and O isotopic composition of Pliocene and Quaternary alkali basalts of the Patagonian Plateau lavas of southernmost South America

The Pliocene and Quaternary Patagonian alkali basalts of southernmost South America can be divided into two groups. The "cratonic" basalts erupted in areas of Cenozoic plateau volcanism and continental sedimentation and show considerable variation in 87Sr/86Sr (0.70316 to 0.70512), 143Nd/144Nd (e{open}Nd) and 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios (18.26 to 19.38, 15.53 to 15.68, and 38.30 to 39.23, respectively). These isotopic values are within the range of oceanic island basalts, as are the Ba/La, Ba/Nb, La/Nb, K/Rb, and Cs/Rb ratios of the "cratonic" basalts. In contrast, the "transitional" basalts, erupted along the western edge of the outcrop belt of the Pliocene and Quaternary plateau lavas in areas that were the locus of earlier Cenozoic Andean orogenic arc colcanism, have a much more restricted range of isotopic composition which can be approximated by 87Sr/86Sr=0.7039??0.0004, e{open}Nd, 206Pb/204Pb=18.60??0.08, 207Pb/204Pb=15.60??0.01, and 208Pb/204Pb=38.50??0.10. These isotopic values are similar to those of Andean orogenic are basalts and, compared to the "cratonic" basalts, are displaced to higher 87Sr/86Sr at a given 143Nd/144Nd and to higher 207Pb/204Pb at a given 208Pb/204Pb. The "transitional" basalts also have Ba/La, Ba/Nb, La/Nb, and Cs/Rb ratios higher than the "cratonic" and oceanic island basalts, although not as high as Andean orogenic are basalts. In contrast to the radiogenic isotopes, ??18O values for both groups of the Patagonian alkali basalts are indistinguishable and are more restricted than the range reported for Andean orogenic are basalts. Whole rock ??18O values calculated from mineral separates for both groups range from 5.3 to 6.5, while measured whole rock ??18O values range from 5.1 to 7.8. The trace element and isotopic data suggest that decreasing degrees of partial melting in association with lessened significance of subducted slabderived components are fundamental factors in the west to east transition from arc to back-arc volcanism in southern South America. The "cratonic" basalts do not contain the slab-derived components that impart the higher Ba/La, Ba/Nb, La/Nb, Cs/Rb, 87Sr/86Sr at a given 143Nd/144Nd, 207Pb/204Pb at a given 208Pb/204Pb, and ??18O to Andean orogenic arc basalts. Instead, these basalts are formed by relatively low degrees of partial melting of heterogeneous lower continental lithosphere and/or asthenosphere, probably due to thermal and mechanical pertubation of the mantle in response to subduction of oceanic lithosphere below the western margin of the continent. The "transitional" basalts do contain components added to their source region by either (1) active input of slab-derived components in amounts smaller than the contribution to the mantle below the arc and/or with lower Ba/La, Ba/Nb, La/Nb, and Cs/Rb ratios than below the arc due to progressive downdip dehydration of the subducted slab; or (2) subarc source region contamination processes which affected the mantle source of the "transitional" basalts earlier in the Cenozoic. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Determination of total, commonality, and uniqueness of interpreted structural elements from remotely sensed data in Alaska

Statistical analysis is conducted to determine the unique value of real- and synthetic-aperture side-looking airborne radar (SLAR) to detect interpreted structural elements. SLAR images were compared to standard and digitally enhanced Landsat multispectral scanner (MSS) images and to aerial photographs. After interpretation of the imagery, data were cumulated by total length in miles and by frequency of counts. Maximum uniqueness is obtained first from real-aperture SLAR, 58.3% of total, and, second, from digitally enhanced Landsat MSS images, 54.1% of total. ?? 1986 Plenum Publishing Corporation.

Mathematical Geology↗

Genetic implications of minor-element and Sr-isotope geochemistry of alkaline rock complexes in the Wet Mountains area, Fremont and Custer counties, Colorado

Concentrations of Rb, Sr, and REE (rare earth elements), and Sr-isotopic ratios in rocks of the Cambrian alkaline complexes in the Wet Mountains area, Colorado, show that rocks formed as end-products of a variety of magmas generated from different source materials. The complexes generally contain a bimodal suite of cumulus mafic-ultramafic rocks and younger leucocratic rocks that include nepheline syenite and hornblende-biotite syenite in the McClure Mountain Complex, nepheline syenite pegmatite in the Gem Park Complex, and quartz syenite in the complex at Democrat Creek. The nepheline syenite and hornblende-biotite syenite at McClure Mountain (535??5m.y.) are older than the syenitic rocks at Democrat Creek (511??8m.y.). REE concentrations indicate that the nepheline syenite at McClure Mountain cannot be derived from the hornblende-biotite syenite, which it intrudes, or from the associated mafic-ultramafic rocks. REE also indicate that mafic-ultramafic rocks at McClure Mountain have a source distinct from that of the mafic-ultramafic rocks at Democrat Creek. In the McClure Mountain Complex, initial87Sr/86Sr ratios for mafic-ultramafic rocks (0.7046??0.0002) are similar to those of hornblende-biotite syenite (0.7045??0.0002), suggesting a similar magmatic source, whereas ratios for carbonatites (0.7038??0.0002) are similar to those of nepheline syenite (0.7038??0.0002). At Democrat Creek, initial ratios of syenitic rocks (0.7032??0.0002) and mafic-ultramafic rocks (0.7028??0.0002) are different from those of corresponding rocks at McClure Mountain. ?? 1982 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Measurements of210Pb,137Cs, organic carbon and trace elements in sediments of the Illinois and Mississippi rivers

Radiometric dating of sediment accumulations by137Cs and210Pb has been successfully initiated in the Illinois and Mississippi Rivers. Sedimentation rates measured at 13 locations range from 0.7 to 3.6 cm/y. Chemical analysis has been completed for up to 45 major and trace elements in core samples. The upper Illinois River contains higher metal levels than the Mississippi River. The amount of carbon (energy) lost to sediments in large floodplain rivers is estimated between 370 and 4000 g/m2/y. ?? 1987 Akade??miai Kiado??.

Journal of Radioanalytical and Nuclear Chemistry A↗

Trace elements in seep waters along Whitewood Creek, South Dakota, and their toxicity to fathead minnows

Whitewood Creek, located in the Black Hills of southwestern South Dakota, has a long history of contamination from mining activity. Gold exploration began in the 1870s, and has continued since that time. Whitewood Creek received direct releases of tailings from 1870 to 1977 from Gold Run Creek in Lead, SD. It has been estimated that approximately 100 million to 1 billion tons of mining, milling, and ore processing wastes have been released by mining activity in the last century in to Whitewood Creek, the Belle Fourche river, and the Cheyenne River (Fox Consultants, Inc. 1984). Tailings deposition has altered the geomorphology of Whitewood Creek, and deposits up to 4.6 m. deep, have become stabilized by vegetation. Several other streams in the Black Hills also have been adversely affected by mining operations (Rahn 1996). As water leaches through rock strata that are disturbed by surface and subsurface mining, it dissolves inorganic elements and carries them to the groundwater. Groundwater movement through the extensive tailings deposits in the Whitewood Creek valley enter the creek at various seeps along its downstream course to the Belle Fourche river, and the Belle Fourche River itself, which empties into the Cheyenne River and eventually into Lake Oahe.

South Dakota↗

Metals and trace elements in giant garter snakes (Thamnophis gigas) from the Sacramento Valley, California, USA

The giant garter snake (GGS; Thamnophis gigas ) is a federally listed threatened species endemic to wetlands of the Central Valley of California. Habitat destruction has been the main factor in the decline of GGS populations, but the effects of contaminants on this species are unknown. To contribute to the recovery of these snakes, the U.S. Geological Survey (USGS) began studies of the life history and habitat use of GGSs in 1995. During a series of investigations conducted from 1995 to the present, specimens of dead GGSs were opportunistically collected from the Colusa National Wildlife Refuge (CNWR), the Natomas Basin, and other sites in northern California. Whole snakes were stored frozen for potential future analysis. As funding became available, we analyzed tissues of 23 GGSs to determine the concentrations of total mercury (Hg) and other trace elements in livers and concentrations of Hg in brains and tail clips. Mercury concentrations (μg/g, wet weight) ranged from 0.08 to 1.64 in livers, 0.01 to 0.18 in brains, and 0.02 to 0.32 in tail clips. In livers, geometric mean concentrations (μg/g, dry weight) of arsenic (25.7) and chromium (1.02) were higher than most values from studies of other snakes. Mercury concentrations in tail clips were positively correlated with concentrations in livers and brains, with the most significant correlations occurring at the Natomas Basin and when Natomas and CNWR were combined. Results indicate the value of using tail clips as a nonlethal bioindicator of contaminant concentrations.

Archives of Environmental Contamination and Toxico↗

On the occurrence, trace element geochemistry, and crystallization history of zircon from in situ ocean lithosphere

We characterize the textural and geochemical features of ocean crustal zircon recovered from plagiogranite, evolved gabbro, and metamorphosed ultramafic host-rocks collected along present-day slow and ultraslow spreading mid-ocean ridges (MORs). The geochemistry of 267 zircon grains was measured by sensitive high-resolution ion microprobe-reverse geometry at the USGS-Stanford Ion Microprobe facility. Three types of zircon are recognized based on texture and geochemistry. Most ocean crustal zircons resemble young magmatic zircon from other crustal settings, occurring as pristine, colorless euhedral (Type 1) or subhedral to anhedral (Type 2) grains. In these grains, Hf and most trace elements vary systematically with Ti, typically becoming enriched with falling Ti-in-zircon temperature. Ti-in-zircon temperatures range from 1,040 to 660°C (corrected for a TiO2 ≈ 0.7, a SiO2 ≈ 1.0, pressure ≈ 2 kbar); intra-sample variation is typically ~60–150°C. Decreasing Ti correlates with enrichment in Hf to ~2 wt%, while additional Hf-enrichment occurs at relatively constant temperature. Trends between Ti and U, Y, REE, and Eu/Eu* exhibit a similar inflection, which may denote the onset of eutectic crystallization; the inflection is well-defined by zircons from plagiogranite and implies solidus temperatures of ~680–740°C. A third type of zircon is defined as being porous and colored with chaotic CL zoning, and occurs in ~25% of rock samples studied. These features, along with high measured La, Cl, S, Ca, and Fe, and low (Sm/La) N ratios are suggestive of interaction with aqueous fluids. Non-porous, luminescent CL overgrowth rims on porous grains record uniform temperatures averaging 615 ± 26°C (2SD, n = 7), implying zircon formation below the wet-granite solidus and under water-saturated conditions. Zircon geochemistry reflects, in part, source region; elevated HREE coupled with low U concentrations allow effective discrimination of ~80% of zircon formed at modern MORs from zircon in continental crust. The geochemistry and textural observations reported here serve as an important database for comparison with detrital, xenocrystic, and metamorphosed mafic rock-hosted zircon populations to evaluate provenance.

Contributions to Mineralogy and Petrology↗

Material properties and triggering mechanisms of an andesitic lava dome collapse at Shiveluch Volcano, Kamchatka, Russia, revealed using the finite element method

Shiveluch volcano (Kamchatka, Russia) is an active andesitic volcano with a history of explosive activity, dome extrusion, and structural collapse during the Holocene. The most recent major (> 1 km 3 ) dome collapse occurred in November 1964, producing a ~ 1.5 km 3 debris avalanche that traveled over 15 km from the vent and triggered a phreatic explosion followed by a voluminous (~ 0.8 km 3 ) eruption of juvenile pyroclastic material. Seismic records suggest that the collapse was likely triggered by a magnitude 5.1 earthquake associated with the ascent of magma into the edifice. The geomechanical properties of the pre-1964 dome are unknown; accordingly, the mechanics of the collapse are poorly understood. This project employs numerical slope stability modeling using the finite element method to constrain probable ranges of geomechanical properties for the materials involved in the collapse, considering earthquake loading as the most likely triggering mechanism. Model results show good agreement with the 1964 collapse geometry considering Geological Strength Index and horizontal pseudo-static seismic coefficient ranges of 30–60 and 0.05–0.15 g, respectively, representing variably fractured and altered dome rocks under moderate earthquake loading, confirming that ground acceleration alone could have triggered the dome collapse. Deep-seated rotational sliding is the dominant failure mode, but local extension within the dome during failure appears to play an important role in the development of the collapse. The findings of this work allow for better forward modeling of potential future collapses, the results of which can be incorporated into regional hazard and risk assessments.

Shiveluch Volcano↗