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At least 703 records · Page 39Linked to original sources

Determination of sensible heat flux over sparse canopy using thermal infrared data

Surface temperatures, T s , were estimated for a natural vegetative surface in Owens Valley, California, with infrared thermometric observations collected from an aircraft. The region is quite arid and is composed primarily of bushes (∼30%) and bare soil (∼70%). Application of the bulk transfer equation for the estimation of sensible heat, H , gave unsatisfactory values when compared to Bowen ratio and eddy correlation methods over a particular site. This was attributed to the inability with existing data to properly evaluate the resistance to heat transfer, r ah . To obtain appropriate r ah -values the added resistance to heat transfer, kB −1 , was allowed to vary although there is both theoretical and experimental evidence that kB −1 for vegetative surfaces can be treated as constant. The present data indicate that for partial canopy cover under arid conditions kB −1 may be a function of T s measured radiometrically. The equation determining kB −1 was simplified and tested over another arid site with good results; however, this had a limited data set (i.e., 6 data points). The dimensionless kB −1 equation is simplified for use over full canopy cover and is shown to give satisfactory estimates of H over a fully-grown wheat crop.

Agricultural and Forest Meteorology↗

Deposition, erosion, and bathymetric change in South San Francisco Bay: 1858-1983

Since the California Gold Rush of 1849, sediment deposition, erosion, and the bathymetry of South San Francisco Bay have been altered by both natural processes and human activities. Historical hydrographic surveys can be used to assess how this system has evolved over the past 150 years. The National Ocean Service (NOS) (formerly the United States Coast and Geodetic Survey (USCGS), collected five hydrographic surveys of South San Francisco Bay from 1858 to 1983. Analysis of these surveys enables us to reconstruct the surface of the bay floor for each time period and quantify spatial and temporal changes in deposition, erosion, and bathymetry. The creation of accurate bathymetric models involves many steps. Sounding data was obtained from the original USCGS and NOS hydrographic sheets and were supplemented with hand drawn depth contours. Shorelines and marsh areas were obtained from topographic sheets. The digitized soundings and shorelines were entered into a Geographic Information System (GIS), and georeferenced to a common horizontal datum. Using surface modeling software, bathymetric grids with a horizontal resolution of 50 m were developed for each of the five hydrographic surveys. Prior to conducting analyses of sediment deposition and erosion, we converted all of the grids to a common vertical datum and made adjustments to correct for land subsidence that occurred from 1934 to 1967. Deposition and erosion that occurred during consecutive periods was then computed by differencing the corrected grids. From these maps of deposition and erosion, we calculated volumes and rates of net sediment change in the bay. South San Francisco Bay has lost approximately 90 x 106 m3 of sediment from 1858 to 1983; however within this timeframe there have been periods of both deposition and erosion. During the most recent period, from 1956 to 1983, sediment loss approached 3 x 106 m3/yr. One of the most striking changes that occurred from 1858 to 1983 was the conversion of more than 80% of the tidal marsh to salt ponds, agricultural, and urban areas. In addition, there has been a decline of approximately 40% in intertidal mud flat area. Restoration of these features will require a detailed understanding of the morphology and sediment sources of this complex system.

California↗

Size of the California Brown Pelican Metapopulation During a Non-El Nino Year

Overall, we estimated a total metapopulation within the geographical range of the California brown pelican subspecies (Pelecanus occidentalis californicus) as about 70,680 ? 2,640 breeding pairs (mean ? SD). Little change in at least three decades is indicated in the total metapopulation south of the Southern California Bight (SCB) subpopulation, but significant improvements in the breeding subpopulation size in the SCB reported elsewhere, support the present high numbers observed in this northernmost subpopulation. The largest breeding aggregation within the entire range (consisting of three immediately adjacent sub-colonies), at the San Lorenzo Archipelago, consisted of about 17,225 breeding pairs, or about 24.4% of the metapopulation in 2006. Other, smaller colonies are no less important, however, although each subpopulation defined by us seemed to have a single or small number of large 'core' breeding colonies, plus many smaller colonies (for example, in 2006, one colony consisted of only 2 breeding pairs). Small colonies (< about 70 nests) comprised about 35.6% of the total occupied colonies, but only about 0.87% of the total estimated numbers (values corrected for detectability). The modal colony-size throughout the range was much smaller (about 230 to 1,300 breeding pairs, depending on subpopulation), indicating that small, scattered colonies and sub-colonies, especially on the range peripheries, function in brown pelican population dynamics and are no less important from a conservation viewpoint. These smaller breeding colonies probably represent some colonies of antiquity, but also range expansions and contractions that occur within the typically-defined metapopulation, and local manifestations of source-sink phenomena. Given such dynamics, even unoccupied islands within the range in 2006 have conservation importance from the viewpoint of such dynamics as potential alternate nesting sites. Natural variations in the estimated population levels seem to be related to the natural cycles of El Ni?o/Southern Oscillation (ENSO) phenomena where very low breeding populations (as low as no nesting in many areas) might be expected to occur in these same areas censused in 2006 at least 40% of the time. From the 2006 aerial survey, extensive commercial and sport-fishing activity, resort/tourist developments and associated human activities along the coastal areas and at offshore islands, and extensive aquacultural (and to a lesser degree, agricultural) developments seen from the Rio Colorado Delta region, Sonora, south at least through San Blas, Nayarit (the southern terminus of our 2006 aerial survey) may result in substantial loss of breeding habitat. Juvenile (young of the 2005 breeding season) plus subadult brown pelicans comprised 28.1% ? 0.33% (mean ? 95% CI) of the total numbers in age-ratio samples. Thus, our overall metapopulation estimate for P. o. californicus in 2006 was 195,900 ? 7,225 individuals.

Open-File Report↗

In-situ arsenic removal during groundwater recharge through unsaturated alluvium

OBJECTIVES The purpose of this study was to determine the feasibility and sustainability of in-situ removal of arsenic from water infiltrated through unsaturated alluvium. BACKGROUND Arsenic is naturally present in aquifers throughout the southwestern United States and elsewhere. In January 2006, the U.S. Environmental Protection Agency (EPA) lowered the Maximum Contaminant Level (MCL) for arsenic from 50 to 10 micrograms per liter (g/L). This raised concerns about naturally-occurring arsenic in groundwater. Although commercially available systems using sorbent iron or aluminum oxide resins are available to treat high-arsenic water, these systems are expensive to build and operate, and may generate hazardous waste. Iron and aluminum oxides occur naturally on the surfaces of mineral grains that compose alluvial aquifers. In areas where alluvial deposits are unsaturated, these oxides may sorb arsenic in the same manner as commercial resins, potentially providing an effective low-cost alternative to commercially engineered treatment systems. APPROACH The Antelope Valley within the Mojave Desert of southern California contains a shallow water-table aquifer with arsenic concentrations of 5 g/L, and a deeper aquifer with arsenic concentrations of 30 g/L. Water was pumped from the deep aquifer into a pond and infiltrated through an 80 m-thick unsaturated zone as part of field-scale and laboratory experiments to treat high-arsenic groundwater and recharge the shallow water table aquifer at the site. The field-scale recharge experiment included the following steps: 1) construction of a recharge pond 2) test drilling for sample collection and instrument installation adjacent to the pond 3) monitoring downward migration of water infiltrated from the pond 4) monitoring changes in selected trace-element concentrations as water infiltrated through the unsaturated zone Data from instruments within the borehole adjacent to the pond were supplemented with borehole and surface geophysical data to evaluate the lateral spreading of water as it moved downward through the unsaturated zone. Three laboratory studies were undertaken. Sequential extraction was used to evaluate the abundance of iron, aluminum, and manganese oxides and selected trace elements on operationally defined sites on the surfaces of mineral grains collected before and after infiltration from the pond. Secondly, radio-labeled arsenic-73 microcosm experiments evaluated the potential for incorporation of arsenic sorbed to exchange sites on mineral grains into less reactive crystalline mineral structures with time. Finally, column studies evaluated arsenic sorption and the pH dependence of sorption for selected unsaturated zone materials. RESULTS/CONCLUSIONS Between December 2010 and July 2012, more than 120,000 cubic meters (m3 ) (about 97 acre-feet) of high-arsenic groundwater was pumped from the deep aquifer into a 0.11 hectare (about 0.27 acres) pond and infiltrated though an 80-meter (about 260 feet) thick unsaturated zone to recharge a water-table aquifer. Arsenic concentrations were lowered from 30 to 2 g/L as water infiltrated though the unsaturated zone at the site. Some uranium, possibly associated with past agricultural land use at the site, was mobilized to concentrations as high as 66 g/L within the unsaturated zone during the experiment. Uranium was resorbed and the high uranium concentrations did not reach the water table at the site. Concentrations of other trace elements, including antimony, chromium, vanadium, and selenium were low throughout the study. Infiltration rates from the pond were as high as 0.4 meters per day (1.1 feet per day, ft/d), and the wetting front moved downward about 25 centimeters per day (cm/d) (0.8 ft/d) to a depth of about 50 m (about 165 feet). Clay layers at that depth slowed the downward movement of the wetting front to about 5 cm/d (0.16 ft/d). Lateral movement of the wetting front was monitored using sequential direct-current (DC) surface and sequential electromagnetic (EM) and DC borehole resistivity. Most lateral movement occurred on a clay layer about 50 m (about 165 feet) below land surface. Infiltrated water reached the water table in January 2013. At the water table, the “wetted footprint” of water infiltrated from the pond, indicated by surface resistivity data, was about 13 hectares (about 32 acres). On the basis of data collected at the site, there is enough sorbent material to operate this pond and treat groundwater having an arsenic concentration of 30 g/L to 2 g/L for about 500 years. Toxicity Characteristic Leaching Procedure (TCLP) data showed arsenic concentrations to be below hazardous levels beneath the pond after the experiment. Pond maintenance may be required to keep infiltration rates high, and prevent accumulation of organic material on the pond bottom, although organic material on the pond bottom may increase removal of other trace elements in infiltrated water including chromium, selenium, and vanadium. Laboratory results are consistent with the field data and show sorption of arsenic in 10 cm (0.3 feet) columns to about 2 g/L over a pH range of 6 to 8, and at influent arsenic concentrations as high as 300 g/L, without breakthrough in 50 pore volumes. Column results suggest that the insitu treatment may remove arsenic in a range of hydrogeologic settings, and would not necessarily be restricted to alkaline alluvial aquifers common throughout the southwestern United States. Radiolabeled arsenic-73 experiments show that although arsenic is initially weakly sorbed (and potentially mobile), with time arsenic is incorporated into amorphous materials. One year after sorption onto surface exchange sites, most sorbed arsenic is incorporated into crystalline oxide minerals on the surfaces of primary mineral grains and is less mobile. Results of the study suggest that long-term land use restrictions on sites used for in-situ treatment of arsenic may not be needed to control water applied to surface materials. This minimizes some regulatory concerns about future land use at sites used for in-situ arsenic treatment. However, future land uses that may alter reduction-oxidation conditions in the subsurface should be avoided, such as infiltration of stormwater recharge or recharge with other water having high organic carbon concentrations (including unsewered residential land use, dairy or other confined animal operations).

Report↗

A comparative analysis of OpenET for evaluating evapotranspiration in California almond orchards

The almond industry in California faces water management challenges that are being exacerbated by droughts, climate change, and groundwater sustainability legislation. The Tree-crop Remote sensing of Evapotranspiration eXperiment (T-REX) aims to explore opportunities to improve precision irrigation management for woody perennial cropping systems. Almond orchards in the California Central Valley were equipped with eddy covariance flux measurements to evaluate satellite remote sensing-based evapotranspiration (RSET) models. OpenET provides high-resolution (30-m spatial and daily temporal) RSET data, synthesizing decades of research for practical water management. This study provides an evaluation of OpenET performance at six almond sites covering a large range in soils, age, and variety. It also compares OpenET ensemble evapotranspiration (ET) data with applied irrigation and precipitation records over an additional 148 almond orchards located in the Central Valley of California. Results show OpenET models, including the ensemble ET value, produced reasonable and actionable ET values, with overall coefficient of determination (R 2 ) and mean absolute error values of 0.73- and 0.95-mm d −1 at the daily time step, respectively. However, given the temporal sampling of Landsat (8-day revisit) and the interpolation methods used, the assessed ET models had difficulty in capturing short-term variability in almond ET; for example, the rapid decline in measured ET observed as a response to lack of irrigation preceding and during almond harvest. The study also drew attention to the spatial complexity in scenarios where irrigated orchards are surrounded by hot/dry areas, causing discrepancies between measured and modeled ET values. In comparison with irrigation records, OpenET ensemble ET was capable of quantifying water input (applied irrigation + precipitation) in almond orchards to within 13 % when evaluating monthly data. Initial results presented here reinforce the idea that RSET models, such as in OpenET, are powerful tools, yet their application requires nuanced understanding and careful consideration of local conditions.

California↗

Satellite-based water use dynamics using historical Landsat data (1984–2014) in the southwestern United States

Remote sensing-based field-scale evapotranspiration (ET) maps are useful for characterizing water use patterns and assessing crop performance. The relative impact of climate variability and water management decisions are better studied and quantified using historical data that are derived using a set of consistent datasets and methodology. Historical (1984–2014) Landsat-based ET maps were generated for major irrigation districts in California, i.e., Palo Verde and eight other sub-basins in parts of the middle and lower Central Valley. A total of 3396 Landsat images were processed using the Operational Simplified Surface Energy Balance (SSEBop) model that integrates weather and remotely sensed images to estimate monthly and annual ET within the study sites over the 31 years. Model output evaluation and validation using gridded-flux data and water balance ET approaches indicated relatively good correspondence (R 2 up to 0.88, root mean square error as low as 14 mm/month) between SSEBop ET and validation datasets. In a pairwise comparison, annual variability of agro-hydrologic parameters of actual evapotranspiration ( ET a ), land surface temperature ( T s ), and runoff ( Q ) were found to be more variable than their corresponding climatic counterparts of atmospheric water demand ( ET o ), air temperature ( T a ), and precipitation ( P ), revealing process differences between regional climatic drivers and localized agro-hydrologic responses. However, only T a showed a consistent increase (up to 1.2 K) over study sites during the 31 years, whereas other climate variables such as ET o and P showed a generally neutral trend. This study demonstrates a useful application of “Big Data” science where large volumes of historical Landsat and weather datasets were used to quantify and understand the relative importance of water management and climate variability in crop water use dynamics in regards to the linkages among water management decisions, hydrologic processes and economic transactions. Irrigation district-wide ET a estimates were used to compute historical crop water use volumes and monetary equivalents of water savings for the Palo Verde Irrigation District (PVID). During the peak crop fallowing year in PVID, the water saved reached a maximum of ~ 107,200 acre-feet in 2011 with an estimated monetary payout value of $20.5 million. A significant decreasing trend in actual ET despite an increasing atmospheric demand in PVID highlights the role of management decisions in affecting local hydrologic processes. This study has importance for planning water resource allocation, managing water rights, sustaining agricultural production, and quantifying impacts of climate and land use/land cover changes on water resources. With increased computational efficiency, similar studies can be conducted in other parts of the world to help policy and decision makers understand and quantify various aspects of water resources management.

Arizona, California↗

Attributes for MRB_E2RF1 Catchments by Major River Basins in the Conterminous United States: Artificial Drainage (1992) and Irrigation (1997)

This tabular data set represents the estimated area of artifical drainage for the year 1992 and irrigation types for the year 1997 compiled for every MRB_E2RF1 catchment of Major River Basins (MRBs, Crawford and others, 2006). The source data sets were derived from tabular National Resource Inventory (NRI) data sets created by the National Resources Conservation Service (NRCS, U.S. Department of Agriculture, 1995, 2000). Artificial drainage is defined as subsurface drains and ditches. Irrigation types are defined as gravity and pressure. Subsurface drains are described as conduits, such as corrugated plastic tubing, tile, or pipe, installed beneath the ground surface to collect and/or convey drainage. Surface drainage field ditches are described as graded ditches for collecting excess water. Gravity irrigation source is described as irrigation delivered to the farm and/or field by canals or pipelines open to the atmosphere; and water is distributed by the force of gravity down the field by: (1) A surface irrigation system (border, basin, furrow, corrugation, wild flooding, etc.) or (2) Sub-surface irrigation pipelines or ditches. Pressure irrigation source is described as irrigation delivered to the farm and/or field in pump or elevation-induced pressure pipelines, and water is distributed across the field by: (1) Sprinkle irrigation (center pivot, linear move, traveling gun, side roll, hand move, big gun, or fixed set sprinklers), or (2) Micro irrigation (drip emitters, continuous tube bubblers, micro spray or micro sprinklers). NRI data do not include Federal lands and are thus excluded from this dataset. The tabular data for drainage were spatially apportioned to the National Land Cover Dataset (NLCD, Kerie Hitt, U.S. Geological Survey, written commun., 2005) and the tabular data for irrigation were spatially apportioned to an enhanced version of the National Land Cover Dataset (NLCDe, Nakagaki and others, 2007). The MRB_E2RF1 catchments are based on a modified version of the U.S. Environmental Protection Agency's (USEPA) ERF1_2 and include enhancements to support national and regional-scale surface-water quality modeling (Nolan and others, 2002; Brakebill and others, 2011). Data were compiled for every MRB_E2RF1 catchment for the conterminous United States covering New England and Mid-Atlantic (MRB1), South Atlantic-Gulf and Tennessee (MRB2), the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy (MRB3), the Missouri (MRB4), the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf (MRB5), the Rio Grande, Colorado, and the Great basin (MRB6), the Pacific Northwest (MRB7) river basins, and California (MRB8).

Data Series↗

Simulation of ground-water flow and land subsidence in the Antelope Valley ground-water basin, California

Antelope Valley, California, is a topographically closed basin in the western part of the Mojave Desert, about 50 miles northeast of Los Angeles. The Antelope Valley ground-water basin is about 940 square miles and is separated from the northern part of Antelope Valley by faults and low-lying hills. Prior to 1972, ground water provided more than 90 percent of the total water supply in the valley; since 1972, it has provided between 50 and 90 percent. Most ground-water pumping in the valley occurs in the Antelope Valley ground-water basin, which includes the rapidly growing cities of Lancaster and Palmdale. Ground-water-level declines of more than 200 feet in some parts of the ground-water basin have resulted in an increase in pumping lifts, reduced well efficiency, and land subsidence of more than 6 feet in some areas. Future urban growth and limits on the supply of imported water may continue to increase reliance on ground water. To better understand the ground-water flow system and to develop a tool to aid in effectively managing the water resources, a numerical model of ground-water flow and land subsidence in the Antelope Valley ground-water basin was developed using old and new geohydrologic information. The ground-water flow system consists of three aquifers: the upper, middle, and lower aquifers. The aquifers, which were identified on the basis of the hydrologic properties, age, and depth of the unconsolidated deposits, consist of gravel, sand, silt, and clay alluvial deposits and clay and silty clay lacustrine deposits. Prior to ground-water development in the valley, recharge was primarily the infiltration of runoff from the surrounding mountains. Ground water flowed from the recharge areas to discharge areas around the playas where it discharged either from the aquifer system as evapotranspiration or from springs. Partial barriers to horizontal ground-water flow, such as faults, have been identified in the ground-water basin. Water-level declines owing to ground-water development have eliminated the natural sources of discharge, and pumping for agricultural and urban uses have become the primary source of discharge from the ground-water system. Infiltration of return flows from agricultural irrigation has become an important source of recharge to the aquifer system. The ground-water flow model of the basin was discretized horizontally into a grid of 43 rows and 60 columns of square cells 1 mile on a side, and vertically into three layers representing the upper, middle, and lower aquifers. Faults that were thought to act as horizontal-flow barriers were simulated in the model. The model was calibrated to simulate steady-state conditions, represented by 1915 water levels and transient-state conditions during 1915-95 using water-level and subsidence data. Initial estimates of the aquifer-system properties and stresses were obtained from a previously published numerical model of the Antelope Valley ground-water basin; estimates also were obtained from recently collected hydrologic data and from results of simulations of ground-water flow and land subsidence models of the Edwards Air Force Base area. Some of these initial estimates were modified during model calibration. Ground-water pumpage for agriculture was estimated on the basis of irrigated crop acreage and crop consumptive-use data. Pumpage for public supply, which is metered, was compiled and entered into a database used for this study. Estimated annual pumpage peaked at 395,000 acre-feet (acre-ft) in 1952 and then declined because of declining agricultural production. Recharge from irrigation-return flows was estimated to be 30 percent of agricultural pumpage; the irrigation-return flows were simulated as recharge to the regional water table 10 years following application at land surface. The annual quantity of natural recharge initially was based on estimates from previous studies. During model calibration, natural recharge was reduced from the initial

Water-Resources Investigations Report↗

Ground-water quality in the carbonate-rock aquifer of the Great Basin, Nevada and Utah, 2003

The carbonate-rock aquifer of the Great Basin is named for the thick sequence of Paleozoic limestone and dolomite with lesser amounts of shale, sandstone, and quartzite. It lies primarily in the eastern half of the Great Basin and includes areas of eastern Nevada and western Utah as well as the Death Valley area of California and small parts of Arizona and Idaho. The carbonate-rock aquifer is contained within the Basin and Range Principal Aquifer, one of 16 principal aquifers selected for study by the U.S. Geological Survey’s National Water- Quality Assessment Program. Water samples from 30 ground-water sites (20 in Nevada and 10 in Utah) were collected in the summer of 2003 and analyzed for major anions and cations, nutrients, trace elements, dissolved organic carbon, volatile organic compounds (VOCs), pesticides, radon, and microbiology. Water samples from selected sites also were analyzed for the isotopes oxygen-18, deuterium, and tritium to determine recharge sources and the occurrence of water recharged since the early 1950s. Primary drinking-water standards were exceeded for several inorganic constituents in 30 water samples from the carbonate-rock aquifer. The maximum contaminant level was exceeded for concentrations of dissolved antimony (6 μg/L) in one sample, arsenic (10 μg/L) in eleven samples, and thallium (2 μg/L) in one sample. Secondary drinking-water regulations were exceeded for several inorganic constituents in water samples: chloride (250 mg/L) in five samples, fluoride (2 mg/L) in two samples, iron (0.3 mg/L) in four samples, manganese (0.05 mg/L) in one sample, sulfate (250 mg/L) in three samples, and total dissolved solids (500 mg/L) in seven samples. Six different pesticides or metabolites were detected at very low concentrations in the 30 water samples. The lack of VOC detections in water sampled from most of the sites is evidence thatVOCs are not common in the carbonate-rock aquifer. Arsenic values for water range from 0.7 to 45.7 μg/L, with a median value of 9.6 μg/L. Factors affecting arsenic concentration in the carbonate-rock aquifer in addition to geothermal heating are its natural occurrence in the aquifer material and time of travel along the flow path. Most of the chemical analyses, especially for VOCs and nutrients, indicate little, if any, effect of overlying land-use patterns on ground-water quality. The water quality in recharge areas for the aquifer where human activities are more intense may be affected by urban and/or agricultural land uses as evidenced by pesticide detections. The proximity of the carbonate-rock aquifer at these sites to the land surface and the potential for local recharge to occur through the fractured rock likely results in the occurrence of these and other land-surface related contaminants in the ground water. Water from sites sampled near outcrops of carbonate-rock aquifer likely has a much shorter residence time resulting in a potential for detection of anthropogenic or land-surface related compounds. Sites located in discharge areas of the flow systems or wells that are completed at a great depth below the land surface generally show no effects of land-use activities on water quality. Flow times within the carbonate-rock aquifer, away from recharge areas, are on the order of thousands of years, so any contaminants introduced at the land surface that will not degrade along the flow path have not reached the sampled sites in these areas.

Nevada, Utah↗

Attributes for NHDPlus Catchments (Version 1.1) for the Conterminous United States: NLCD 2001 Imperviousness

This data set represents the mean percent impervious surface from the Imperviousness Layer of the National Land Cover Dataset 2001 (LaMotte and Wieczorek, 2010), compiled for every catchment of NHDPlus for the conterminous United States. The source data set represents imperviousness for the conterminous United States for 2001. The Imperviousness Layer of the National Land Cover Data Set for 2001 was produced through a cooperative project conducted by the Multi-Resolution Land Characteristics (MRLC) Consortium. The MRLC Consortium is a partnership of Federal agencies (http://www.mrlc.gov), consisting of the U.S. Geological Survey (USGS), the National Oceanic and Atmospheric Administration (NOAA), the U.S. Environmental Protection Agency (USEPA), the U.S. Department of Agriculture (USDA), the U.S. Forest Service (USFS), the National Park Service (NPS), the U.S. Fish and Wildlife Service (USFWS), the Bureau of Land Management (BLM), and the USDA Natural Resources Conservation Service (NRCS). The NHDPlus Version 1.1 is an integrated suite of application-ready geospatial datasets that incorporates many of the best features of the National Hydrography Dataset (NHD) and the National Elevation Dataset (NED). The NHDPlus includes a stream network (based on the 1:100,00-scale NHD), improved networking, naming, and value-added attributes (VAAs). NHDPlus also includes elevation-derived catchments (drainage areas) produced using a drainage enforcement technique first widely used in New England, and thus referred to as "the New England Method." This technique involves "burning in" the 1:100,000-scale NHD and when available building "walls" using the National Watershed Boundary Dataset (WBD). The resulting modified digital elevation model (HydroDEM) is used to produce hydrologic derivatives that agree with the NHD and WBD. Over the past two years, an interdisciplinary team from the U.S. Geological Survey (USGS), and the U.S. Environmental Protection Agency (USEPA), and contractors, found that this method produces the best quality NHD catchments using an automated process (USEPA, 2007). The NHDPlus dataset is organized by 18 Production Units that cover the conterminous United States. The NHDPlus version 1.1 data are grouped by the U.S. Geologic Survey's Major River Basins (MRBs, Crawford and others, 2006). MRB1, covering the New England and Mid-Atlantic River basins, contains NHDPlus Production Units 1 and 2. MRB2, covering the South Atlantic-Gulf and Tennessee River basins, contains NHDPlus Production Units 3 and 6. MRB3, covering the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy River basins, contains NHDPlus Production Units 4, 5, 7 and 9. MRB4, covering the Missouri River basins, contains NHDPlus Production Units 10-lower and 10-upper. MRB5, covering the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf River basins, contains NHDPlus Production Units 8, 11 and 12. MRB6, covering the Rio Grande, Colorado and Great Basin River basins, contains NHDPlus Production Units 13, 14, 15 and 16. MRB7, covering the Pacific Northwest River basins, contains NHDPlus Production Unit 17. MRB8, covering California River basins, contains NHDPlus Production Unit 18.

Data Series↗

Attributes for NHDPlus Catchments (Version 1.1) for the Conterminous United States: NLCD 2001 Land Use and Land Cover

This data set represents the estimated area of land use and land cover from the National Land Cover Dataset 2001 (LaMotte, 2008), compiled for every catchment of NHDPlus for the conterminous United States. The source data set represents land use and land cover for the conterminous United States for 2001. The National Land Cover Data Set for 2001 was produced through a cooperative project conducted by the Multi-Resolution Land Characteristics (MRLC) Consortium. The MRLC Consortium is a partnership of Federal agencies (http://www.mrlc.gov), consisting of the U.S. Geological Survey (USGS), the National Oceanic and Atmospheric Administration (NOAA), the U.S. Environmental Protection Agency (USEPA), the U.S. Department of Agriculture (USDA), the U.S. Forest Service (USFS), the National Park Service (NPS), the U.S. Fish and Wildlife Service (USFWS), the Bureau of Land Management (BLM), and the USDA Natural Resources Conservation Service (NRCS). The NHDPlus Version 1.1 is an integrated suite of application-ready geospatial datasets that incorporates many of the best features of the National Hydrography Dataset (NHD) and the National Elevation Dataset (NED). The NHDPlus includes a stream network (based on the 1:100,00-scale NHD), improved networking, naming, and value-added attributes (VAAs). NHDPlus also includes elevation-derived catchments (drainage areas) produced using a drainage enforcement technique first widely used in New England, and thus referred to as "the New England Method." This technique involves "burning in" the 1:100,000-scale NHD and when available building "walls" using the National Watershed Boundary Dataset (WBD). The resulting modified digital elevation model (HydroDEM) is used to produce hydrologic derivatives that agree with the NHD and WBD. Over the past two years, an interdisciplinary team from the U.S. Geological Survey (USGS), and the U.S. Environmental Protection Agency (USEPA), and contractors, found that this method produces the best quality NHD catchments using an automated process (USEPA, 2007). The NHDPlus dataset is organized by 18 Production Units that cover the conterminous United States. The NHDPlus version 1.1 data are grouped by the U.S. Geologic Survey's Major River Basins (MRBs, Crawford and others, 2006). MRB1, covering the New England and Mid-Atlantic River basins, contains NHDPlus Production Units 1 and 2. MRB2, covering the South Atlantic-Gulf and Tennessee River basins, contains NHDPlus Production Units 3 and 6. MRB3, covering the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy River basins, contains NHDPlus Production Units 4, 5, 7 and 9. MRB4, covering the Missouri River basins, contains NHDPlus Production Units 10-lower and 10-upper. MRB5, covering the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf River basins, contains NHDPlus Production Units 8, 11 and 12. MRB6, covering the Rio Grande, Colorado and Great Basin River basins, contains NHDPlus Production Units 13, 14, 15 and 16. MRB7, covering the Pacific Northwest River basins, contains NHDPlus Production Unit 17. MRB8, covering California River basins, contains NHDPlus Production Unit 18.

Data Series↗

Population biology of bluegills, Lepomis macrochirus, in lotic habitats on the irrigated San Joaquin Valley floor

Rapid expansion of irrigated agriculture in the western United States has prompted concerns for aquatic resources. Although the impacts of irrigation activities on quality and quantity of river water are well documented (e.g., high turbidity from soil erosion, eutrophication from nutrient runoff, pesticide contamination, reduced dis- charge), their effects on fish populations are still poorly understood. We studied the food, growth, and relative weight (a measure of body condition) of bluegills, Lepo- mis macrochirus, in relation to environmental factors in reaches of the San Joaquin and Merced rivers that have been affected to varying degrees by irrigation return flows. Fry of bluegills ate mostly cladocerans and copepods; fingerlings and larger fish ate immature aquatic insects, terrestrial insects, amphipods, and mollusks. Bluegill stomachs were fuller and contained a higher diversity of forage taxa in habitats with low turbidity and conductivity, weak buffering capacity, and low nutrient levels; bluegills also ate a more diverse diet where the potential forage supply (benthic macroinvertebrates) was most diverse. Bluegills attained mean total lengths of about 42 mm at age I, 86 mm at age 11, 116 mm at age III, 153 mm at age IV, and 166 mm at age V. Mean relative weight ranged from 96-111. Growth rate and relative weight were not significantly correlated with environmental or dietary variables. On the basis of our study, we concluded that environmental degradation from irrigation activities affected the diet of bluegills primarily by modifying the food supply, but growth rate and body condition were not affected.

California↗

Status and understanding of groundwater quality in the northern Sierra Nevada foothills domestic-supply aquifer study units, 2015–17—California GAMA Priority Basin Project

Groundwater quality in the northern Sierra Nevada foothills region of California was investigated as part of California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring Assessment Priority Basin Project (GAMA-PBP). The region was divided into two study units: the Yuba-Bear watersheds (YBW) study unit and the American-Cosumnes-Mokelumne watersheds (ACMW) study unit. The GAMA-PBP made a spatially unbiased assessment of aquifer systems used for domestic drinking-water supply in the study region, which are predominantly composed of fractured, hard-rock aquifers of varying lithology. These assessments characterized the quality of raw groundwater to evaluate ambient conditions in the domestic-supply aquifer and not the quality of treated drinking water. The study included three components: (1) a status assessment , which characterized the quality of groundwater resources used for domestic drinking-water supply in the YBW and ACMW study units; (2) an understanding assessment , which evaluated natural and anthropogenic explanatory factors that could potentially affect groundwater quality in the study region; and (3) a comparative assessment between the groundwater resources used for domestic and public drinking-water supply in the study region. The status assessment was based on data collected by the GAMA-PBP from 74 sites in the YBW study unit during 2015–16 and 67 sites in the ACMW study unit from 2016 to 2017. To contextualize water-quality results, concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. The status assessment used a grid-based method to estimate proportions of groundwater resources with concentrations approaching or exceeding benchmark thresholds. This method provides spatially unbiased results and allows inter-comparability with similar groundwater-quality assessments. Inorganic constituents with health-based benchmarks were present at high relative concentration (RC), meaning they exceeded the benchmark threshold, in 5.4 and 10 percent of domestic-supply aquifer systems in the YBW and ACMW study units, respectively. Inorganic constituents with aesthetic-based benchmarks were detected at high-RCs in 20 and 28 percent of the YBW and ACMW study units, respectively. The inorganic constituents present at high RC were arsenic, barium, boron, molybdenum, strontium, nitrate, adjusted gross-alpha particle activity, chloride, total dissolved solids, specific conductance, iron, manganese, and hardness. Groundwater samples were tested for presence or absence of three microbial indicators (total coliform, Escherichia coli , and Enterococci ). At least one microbial indicator was present in 26 and 28 percent of the YBW and ACMW study units, respectively. At least one organic constituent was detected in 30 and 42 percent of the YBW and ACMW study units, respectively. Organic constituents were not present at high RC, but tetrachloroethene (PCE), trichloroethene (TCE), and toluene were detected in the YBW study unit at moderate RC (between the benchmark concentration and one-tenth of the benchmark concentration). Methyl tert -butyl ether (MTBE) and chloroform were present at low RC (less than one-tenth of the benchmark concentration) in the YBW and ACMW study units with detection frequencies greater than 10 percent. Perchlorate, a constituent of special interest, was detected in 31 and 41 percent of the YBW and ACMW study units, respectively, at either low or moderate RCs. Relations among select water-quality constituents and potential explanatory factors were evaluated using statistical and graphical approaches. Nitrate, microbial indicators, and perchlorate were all correlated to elevation-dependent variables relating to climate, land use, and recharge condition. Isotopic and dissolved noble-gas tracers indicated these water-quality constituents are associated with recharge conditions associated with irrigation during the summer dry-season, which is common in areas of rural-residential or agricultural land uses. Higher concentrations of iron and manganese were primarily associated with anoxic groundwater in aquifers of metasedimentary lithology. Increased hardness was primarily associated with anoxic groundwater in aquifers of mafic-ultramafic or metavolcanics lithologies at lower elevations in the study region in the Melones fault zone. Chloroform and MTBE were associated with shallow groundwater (wells depths less than 130 m) under oxic and anoxic redox conditions, respectively. The comparative assessment evaluated differences between the aquifer systems used for domestic- and public-supply in study region based on (1) well-construction characteristics, and (2) water quality. Analysis of over 60,000 well-completion reports in the study region showed that although domestic-supply wells span the deepest depth zones in regional aquifers, median depths for public-supply wells were significantly greater than those of domestic-supply wells in both study units. Water-quality data from more than 300 public-supply wells in the study region were assessed using a spatially weighted method for calculation aquifer-scale proportions and compared with the domestic-supply assessment results. Detections of inorganic constituents at high RC and detection frequencies for organic constituents were generally similar between the domestic- and public-supply aquifer systems in both study units, with a few notable exceptions in the ACMW study unit: nitrate was greater for the public- compared to domestic-supply aquifer system and both manganese, hardness, and MTBE were greater in the domestic- compared to public-supply aquifer system. These differences are likely related to contrasting land uses, aquifer lithologies, landscape positions, and depths characterizing domestic- and public-supply wells in the ACMW study unit. Overall, fewer samples from domestic-supply wells in the northern Sierra Nevada foothills exceeded health-based benchmarks compared to aesthetic-based benchmarks for groundwater quality. Exceedences of health-based benchmarks were primarily caused by nitrate and coliform bacteria, which were associated with recharge from diverted surface water used primarily for irrigation. Exceedences of aesthetic-based benchmarks were primarily caused by iron, managanese, and hardness, which were associated with geologic factors. Regional irrigation practices and aquifer lithology can affect groundwater quality in fractured-rock aquifers in the northern Sierra Nevada foothills used for domestic drinking-water supply.

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Regional and other general factors bearing on evaluation of earthquake and other geologic hazards to coastal communities of southeastern Alaska

The great Alaska earthquake of March 27, 1964, brought into sharp focus the need for engineering geologic studies in seismically active regions. As a result, nine communities in southeastern Alaska were selected for reconnaissance investigations as an integral part of an overall program to evaluate earthquake and other geologic hazards in most of the larger Alaska coastal communities. This report gives background information on the regional and other general factors that bear on these evaluations. Southeastern Alaska, about 525 miles long and averaging about 125 miles in width, consists of a narrow mainland strip and numerous islands. For the most part, it is a region of rugged relief with numerous glaciers capping many of the higher mountainous areas and with long linear fiords forming the inland waterways. A maritime climate prevails with mild winters and cool summers. The southeastern part of the region receives the highest precipitation in the continental United States. Ketchikan, with a population of 6,994 in 1970, is the largest city. Geology and structure of the area are complex. Igneous, metamorphic, and sedimentary rocks crop out and range in age from Paleozoic to Tertiary. Surficial deposits of Pleistocene and Holocene age mantle many areas. All of southeastern Alaska, except probably the highest peaks, was covered by glacier ice advances of late Pleistocene age. Major deglaciation was well advanced by 10,000 years ago--a time which approximately marks the end of the Pleistocene and the beginning of the Holocene. There followed a period of warm climate called the Hypsithermal, which in southeastern Alaska began 7,000-8,000 years ago and ended about 4,800-3,500 years ago. Glaciers in most places receded back of their present positions. The Hypsithermal was followed by an interval (termed Neoglaciation) of cooler climate and resurgence of glacier ice which continues to the present, although most glaciers are now rapidly receding. During the past 10,000 years worldwide sea level has risen about 100 feet, but during the past 4,000 years it has risen only about 10 feet or about 0.03 inch per year. With sea level used as a datum, the amount of sea-level rise must be added to the apparent uplift of land for the time under consideration to determine the actual amount of land uplift. The widespread presence of emergent marine deposits, several hundred feet above sea level, demonstrates that the land in southeastern Alaska has been uplifted since the last major deglaciation. The greatest known has been uplifted since the last major deglaciation. The greatest known uplift is in the vicinity of Juneau where glaciomarine deposits are present 750 feet above present sea level. Part of southeastern Alaska is presently undergoing one of the most rapid rates of uplift of any place in the world. The fastest emergence is occurring in the Glacier Bay area where the land is being uplifted relative to sea level approximately 3.9 cm per year. Most or all of the uplift appears to be due to rebound as a result of deglaciation. Southeastern Alaska lies within the circum-Pacific earthquake belt, one of the world's greatest zones of seismic activity. During historic time, there have been five earthquakes in the region with magnitudes of 8 or greater, three with magnitudes of 7 to 8, eight with magnitudes of 6 to 7, more than 15 with magnitudes of 5 to 6, and about 140 recorded earthquakes with magnitudes smaller than 5 or of unassigned magnitudes. All of the earthquakes with magnitudes 8 or greater, and a large proportion of the others, appear to be related to the active Fairweather- Queen Charlotte Islands fault system or its western extension, the Chugach-St. Elias fault. Earthquake epicenters on the Denali fault system, the other major fault system in southeastern Alaska, are few in comparison. However, because high microearthquake activity has been recorded recently on this system and earthquakes of moderate size have occurred on some of its segments, the Denali fault system probably should not be dismissed as a relict fault system of no current tectonic importance. There are numerous other known faults, as well as lineaments that may be faults of varying degrees of tectonic activity in southeastern Alaska, adjacent Canada, and eastern Alaska. One of these elements is the Totschunda fault system, which connects with the Denali fault system in eastern Alaska; it has been very active during Holocene time but few historical earthquake epicenters appear to be related to it. Both historical seismicity and geologic conditions, such as frequency and recency of faulting, must be considered together to permit an assessment of the future earthquake probability of an area. Data are too few for both factors for an accurate evaluation to be made of earthquake probability in southeastern Alaska. However, information compiled in the form of strain-release and seismic-zone maps permit some generalizations. Thus, it is tentatively concluded that most, if not all, of southeastern Alaska should be placed in seismic zone 3, a zone in which earthquakes of magnitude greater than 6 will occur from time to time and where there may be major damage to manmade structures. Inferred effects from future earthquakes in southeastern Alaska include: (1) surface displacement along faults and other tectonic land-level changes, (2) ground shaking, (3) compaction, (4) liquefaction in cohesionless materials, (5) reaction of sensitive and quick clays, (6) water-sediment ejection and associated subsidence and ground fracturing, (7) earthquake-induced sub aerial slides and slumps, (8) earthquake induced subaqueous slides, (9) effects on glaciers and related features, (10) effects on ground water and stream flow, and (11) tsunamis, seiches, and other abnormal water waves. Because of the reconnaissance nature of our studies in the coastal communities and the sparsity of laboratory data on physical properties of geologic units in each area studied, the inferred effects must be largely empirical and generalized. Therefore, the inferences are based in large part upon the effects of past major earthquakes in Alaska and elsewhere, particularly upon the well-documented effects of the Alaska earthquake of March 27, 1964. Buildings, highways, bridges, tunnels, harbor facilities, pipelines, canals, and other manmade structures may be severely damaged or destroyed by fault displacement or related tectonic land-level changes in southeastern Alaska. Direct damage from fault rupture would be restricted virtually to structures built directly athwart the fault. In California and Nevada, fault rupture almost always accompanies shocks of magnitude 6.5 or greater. The Alaska earthquake of March 27, 1964, and the Chilean earthquake of May 22, 1960, dramatically illustrated the severe adverse effects that can result from uplift or subsidence over a wide area. The variable most responsible for the degree of shaking at any epicentral distance is the type of ground. Generally, shaking is considerably greater in poorly consolidated deposits than in hard bedrock, particularly if the deposits are water saturated. Severe shaking of alluvial deposits and manmade fill, with resultant heavy damage, is well documented from the records of many past earthquakes. Damage commonly has been heavy as a result of ground settlement caused by compaction of loose sediments by shaking during an earthquake. This has been especially true where compaction was accompanied by tectonic downdrop of land, such as occurred during the Chilean earthquake of 1960 and the Alaska earthquake of 1964. Loosely emplaced manmade fill, deltaic deposits, beach deposits, and alluvial deposits may be susceptible to compaction in southeastern Alaska during a severe earthquake. Liquefaction of sand and silt is a fairly common effect of large earthquakes. It was well illustrated at Niigata, Japan, during the earthquake of June 16, 1964, and resulted in extensive damage. When part of a sloping soil mass liquefies, the entire mass can undergo catastrophic failure and can flow as a high-density liquid. In southeastern Alaska, deltaic deposits probably would be most susceptible to liquefaction. Sensitive and quick clays, which lose a considerable part of their strength when shaken, commonly fail during an earthquake and become rapid earthflows. Extensive studies were made of the sensitivity of the Bootlegger Cove Clay at Anchorage because of the marked loss of shear strength and dramatic failures of the deposits during the Alaska earthquake of 1964. If similar sensitive clays are present in some places in southeastern Alaska, they most likely are in some of the emergent fine-grained marine deposits; supporting data to confirm their presence, however, are largely lacking. Records of some 50 major earthquakes show that in at least half of the instances water and sediment have been ejected from surficial deposits Water-sediment ejection and associated subsidence and ground fracturing commonly cause extensive damage to the works of man. Ejecta may fill basements and other low-lying parts of buildings. Agricultural land can be covered with a blanket of infertile soils, and small ponds can be filled or made shallow. In southeastern Alaska these phenomena are most likely to occur on valley floors, deltas, tidal flats, alluvial fans, swamps, and lakeshores. Earthquake-induced sliding on land generally is confined to steep slopes but may take place in fine-grained deposits on moderately to nearly flat surfaces if the deposits are subject to liquefaction. A large rockslide triggered by the Lituya Bay, Alaska, earthquake of July 10, 1958, generated a wave that surged up the opposite wall of the inlet to a record height of 1,740 feet. During the Hebgen Lake, Montana, earthquake of August 17, 1959, a spectacular rockslide plunged into the Madison River canyon, buried 28 people, dammed the river, and created a large lake. Earthquake-records are replete with accounts of sliding of surficial deposits during moderate to large earthquakes. Most or all of the general factors that favor subaerial landsliding are present in southeastern Alaska. Earthquake-induced subaqueous slides can produce adverse effects both nearshore and some distance offshore. Nearshore sliding may progress shoreward and destroy harbor facilities and other structures, commonly with substantial loss of life. Disastrous large submarine slides occurred along the fronts of deltas in Seward and Valdez during the Alaska earthquake of 1964. In similar fashion, the largest submarine slides in southeastern Alaska likely will be triggered along the larger delta fronts. Sliding farther offshore can constitute a threat to navigation because of changes in water depths. Also underwater sliding can break communication cables. Glaciers were not greatly affected by the Alaska earthquake of 1964 despite the fact that about 20 percent of the area that underwent strong shaking is covered by ice. In contrast, the cataclysmic avalanche of ice and rock that fell from a high glacier-covered peak in Peru during the earthquake of May 31, 1970, produced devastating effects downvalley on man and his works in the form of mudflows. Most towns in southeastern Alaska are sufficiently distant from glaciers so as not be to directly affected. Both the Alaska earthquake of 1964 and the Hebgen Lake, Montana, earthquake of 1959 significantly affected ground- and surface-water regimens. Water levels in some wells declined whereas in others flow increased. Some springs discharged at a rate three times as much as normal; flow of others decreased or stopped. Discharge of many streams increased markedly. Most or all of the effects described above could occur in parts of southeastern Alaska during future large earthquakes. Tsunamis, seiches, and other abnormal water waves associated with large earthquakes commonly cause vast property damage and heavy loss of life. Tsunami effects can be devastating to coastal areas as far as many thousands of miles from their generation source. Seiche effects generally are confined to inland bodies of water or to relatively enclosed coastal bodies of water. Abnormal waves generated by submarine sliding or by subaerial sliding into water generally produce only local effects but may be highly devastating. Tsunami waves resulting from the Chilean earthquake of 1960 inflicted extensive damage and loss of life on coastal communities throughout a large part of southern Chile, and significant runups and damage were recorded in many places throughout the Pacific Ocean area. The tsunami waves generated by the Alaska earthquake of 1964 struck with devastating force along a broad stretch of the Alaska coast and produced heavy property damage and loss of life as far away as Crescent City, Calif. Seiche waves generated by that earthquake reached runup heights of 20-30 feet on some lakes in Alaska, and water-level fluctuations were recorded on streams, reservoirs, lakes, and swimming pools in States bordering the Gulf of Mexico. Waves generated by submarine sliding struck violently at a number of places during or immediately after the quake and were the major cause of loss of life and damage to property. Slide-generated waves probably would have a higher destructive potential in southeastern Alaska than either tsunami waves or seiche waves because of their possibly higher local runups and because they can hit the shores almost without warning during or immediately after an earthquake. Nonearthquake-related geologic hazards, although generally far less dramatic than those related to earthquakes, tend to occur so much more frequently or persistently that their aggregate effects can be significant. Three kinds of geologic hazards of this type are discussed: (1) nonearthquake-induced landsliding and subaqueous sliding, (2) flooding, and (3) land uplift. The potential for nonearthquake-triggered landsliding in southeastern Alaska ranges widely from place to place. Past sliding generally furnishes the clue in the prediction of where and in what materials future sliding will occur. Fast-moving rockslides, debris slides, and mudflows can be expected to occur from time to time on steep slopes and be highly destructive to highways, power plants, pipelines, buildings, and other facilities located on a slope or at its base. Present slow downslope movement of talus can be expected to continue at the same general rate unless conditions are changed by man or there are climatic changes. Snow and debris avalanches can be especially hazardous during winter months. Long-inactive landslides may be triggered into renewed activity or new slides may be created by man-induced modifications. Accelerated slope erosion and debris flows may follow large-scale clearing and cutting of timber. Subaqueous sliding can be expected to occur periodically along fronts of deltas and on other oversteepened underwater slopes. Floods have been common in parts of southeastern Alaska because of heavy precipitation and rapid runoff from steep slopes with resulting heavy damage to roads and other facilities. Continued damage can be expected in the future unless more remedial measures are taken. Current uplift of land in southeastern Alaska, although probably not affecting man significantly in a short period of time, may have some adverse long-term effects. These long-term effects should be borne in mind when facilities such as docks and boat harbors are constructed on or near the shore, where there is a critical relation between height of land and water.

Alaska↗

Organic carbon trends, loads, and yields to the Sacramento-San Joaquin Delta, California, water years 1980 to 2000

Organic carbon, nutrient, and suspended sediment concentration data were analyzed for the Sacramento and San Joaquin River Basins for the period 1980-2000. The data were retrieved from three sources: the U.S. Geological Survey's National Water Information System, the U.S. Environmental Protection Agency's Storage and Retrieval System, and the California Interagency Ecological Program's relational database. Twenty sites were selected, all of which had complete records of daily streamflow data. These data met the minimal requirements of the statistical programs used to estimate trends, loads, and yields. The seasonal Kendall program was used to estimate trends in organic carbon, nutrient, and suspended sediment. At all 20 sites, analyses showed that in the 145 analyses for the seven constituents, 95 percent of the analyses had no significant trend. Dissolved organic carbon (DOC) concentrations were significant only for four sites: the American River at Sacramento, the Sacramento River sites near Freeport, Orestimba Creek at River Roads near Crows Landing, and the San Joaquin River near Vernalis. Loads were calculated using two programs, ESTIMATOR and LOADEST2. The 1998 water year was selected to describe loads in the Sacramento River Basin. Organic carbon, nutrient, and suspended sediment loads at the Sacramento River sites near Freeport included transported loads from two main upstream sites: the Sacramento River at Verona and the American River at Sacramento. Loads in the Sacramento River Basin were affected by the amount of water diverted to the Yolo Bypass (the amount varies annually, depending on the precipitation and streamflow). Loads at the Sacramento River sites near Freeport were analyzed for two hydrologic seasons: the irrigation season (April to September) and the nonirrigation season (October to March). DOC loads are lower during the irrigation season then they are during the nonirrigation season. During the irrigation season, water with low concentrations of DOC is released from reservoirs and used for irrigation. On the other hand, during the nonirrigation season, streamflow results from surface water runoff and has higher concentrations of organic carbon, nutrients, and suspended sediment. The 1986 and 1987 water years were selected to describe loads in the San Joaquin River Basin. Organic carbon, nutrient, and suspended sediment loads in the San Joaquin River near Vernalis included transported loads from upstream sites, such as the Mud and Salt Sloughs, the Merced River at River Roads Bridge near Newman, the Tuolumne River at Modesto, and the Stanislaus River at Ripon. Loads at the San Joaquin River near Vernalis also were analyzed for the two seasons. The DOC load for the San Joaquin River at Vernalis is slightly higher during the irrigation season. Yields were calculated in an attempt to rank the subbasins in the Sacramento and San Joaquin River Basins. Five sites delivered streamflow from agricultural and urban sources that had relatively high yields of organic carbon: Sacramento Slough near Knights Landing, Arcade Creek near Del Paso Heights, Salt Slough, Mud Slough, and Colusa Basin Drain at Road 99E near Knights Landing.

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Geohydrology of the Winchester Subbasin, Riverside County, California

The 20-square-mile Winchester structural subbasin is an alluvium-filled paleocanyon that is as much as 900 feet deep. The alluvial aquifer is composed of detrital material that generally ranges in size from clay to fine gravel; the fine and coarse materials are mixed in some places and inter- bedded in others. The apparent lenticularity of fine- and coarse-grained materials and differing water quality with depth indicate that the aquifer is partly or locally confined. A ground-water divide exists east of the town of Winchester. West of the divide, ground water moves toward and into the South Perris and the Menifee subbasins. East of the divide, ground water moves toward and into the Hemet subbasin. The components of flow direction in the Winchester?Hemet subbasins border area are complex: along the border, some water moves from the southwest corner of the Hemet subbasin into the Winchester subbasin and then eastward subparallel to the border before moving back into the Hemet subbasin. The direction of ground-water movement between the Winchester and Hemet subbasins, and the position of the ground-water divide in the central part of the Winchester subbasin, have changed with time. Prior to about 1974, ground water moved both eastward from the divide and westward from the Hemet subbasin toward a local depression of the water table caused by pumping in the eastern part of the Winchester subbasin. Comparison of spring 1970 and spring 1993 ground-water levels indicates a net rise of as much as 150 feet in the east end of the Winchester subbasin. For this same period, water levels rose about 3 to 20 feet in the western and central parts of the subbasin. Ground-water chemistry in the Winchester subbasin and adjacent subbasins varies areally and vertically. In general, sodium, calcium, chloride, and sulfate are dominant ions. Water quality is generally poor: dissolved-solids concentration exceeded 2,000 milligrams per liter throughout much of the subbasin and was highest west of the town of Winchester. Eastward along the subbasin axis (toward the Hemet subbasin), the dissolved-solids concentration decreases and the pH increases (generally greater than 7.0). Samples from two multiple-well monitoring sites at the west and east ends of the subbasin indicate that the best quality water (dissolved-solids concentrations of 395 and 483 milligrams per liter) is from the deepest wells (perforated near the alluvium- bedrock contact). Samples from the deeper wells in the eastern part of the Winchester subbasin are similar in water type to a sample from a well in the western part of the Hemet subbasin, which suggests that the water may have flowed from the Hemet subbasin; alternatively, the chemistry may reflect the influence of good-quality water flowing from the fractured bedrock basement to the alluvium in the eastern part of the Winchester subbasin. In addition, the potential problem of poor-quality water moving from the Winchester subbasin into the Hemet subbasin may not exist at all depths; fair- to good-quality water may be present below a depth of about 450 feet. Dissolved-solids concentrations in the southwest part of the Hemet subbasin ranged from about 900 milligrams per liter at well 5S/1W-19Q1 about one-quarter mile north of the Winchester?Hemet subbasin boundary to about 3,500 milligrams per liter at well 5S/2W-24C2 near the bedrock outcrops southeast of the Lakeview Mountains. High dissolved-solids concentration in the vicinity of well 5S/2W-24C2 most likely is a result of dissolution of constituents from the aquifer matrix, evaporative processes, and agricultural practices that occur in that vicinity rather than a result of flow from the Winchester subbasin. Aquifer-test results indicate that the transmissivity is about 950 feet squared per day in the eastern part of the Winchester subbasin near the boundary with the Hemet subbasin and about 72 feet squared per day in the western part of the subbasin near the boundary with th

California↗

Metals transport in the Sacramento River, California, 1996-1997; Volume 2: Interpretation of metal loads

Metals transport in the Sacramento River, northern California, from July 1996 to June 1997 was evaluated in terms of metal loads from samples of water and suspended colloids that were collected on up to six occasions at 13 sites in the Sacramento River Basin. Four of the sampling periods (July, September, and November 1996; and May-June 1997) took place during relatively low-flow conditions and two sampling periods (December 1996 and January 1997) took place during high-flow and flooding conditions, respectively. This study focused primarily on loads of cadmium, copper, lead, and zinc, with secondary emphasis on loads of aluminum, iron, and mercury. Trace metals in acid mine drainage from abandoned and inactive base-metal mines, in the East and West Shasta mining districts, enter the Sacramento River system in predominantly dissolved form into both Shasta Lake and Keswick Reservoir. The proportion of trace metals that was dissolved (as opposed to colloidal) in samples collected at Shasta and Keswick dams decreased in the order zinc ≈ cadmium > copper > lead. At four sampling sites on the Sacramento River--71, 256, 360, and 412 kilometers downstream of Keswick Dam--trace-metal loads were predominantly colloidal during both high- and low-flow conditions. The proportion of total cadmium, copper, lead, and zinc loads transported to San Francisco Bay and the Sacramento-San Joaquin Delta estuary (referred to as the Bay-Delta) that is associated with mineralized areas was estimated by dividing loads at Keswick Dam by loads 412 kilometers downstream at Freeport and the Yolo Bypass. During moderately high flows in December 1996, mineralization-related total (dissolved + colloidal) trace-metal loads to the Bay-Delta (as a percentage of total loads measured downstream) were cadmium, 87 percent; copper, 35 percent; lead, 10 percent; and zinc, 51 percent. During flood conditions in January 1997 loads were cadmium, 22 percent; copper, 11 percent; lead, 2 percent; and zinc, 15 percent. During irrigation drainage season from rice fields (May-June 1997) loads were cadmium, 53 percent; copper, 42 percent; lead, 20 percent; and zinc, 75 percent. These estimates must be qualified by the following factors: (1) metal loads at Colusa in December 1996 and at Verona in May-June 1997 generally exceeded those determined at Freeport during those sampling periods. Therefore, the above percentages represent maximum estimates of the apparent total proportion of metals from mineralized areas upstream of Keswick Dam; and (2) for logistics reasons, the Sacramento River was sampled at Tower Bridge instead of at Freeport during January 1997. Available data suggest that trace metal loads from agricultural drainage may be significant during certain flow conditions in areas where metals such as copper and zinc are added as agricultural amendments. Copper loads for sampling periods in July and September 1996 and in May-June 1997 show increases of dissolved and colloidal copper and in colloidal zinc between Colusa and Verona, the reach of the Sacramento River along which the Colusa Basin Drain, the Sacramento Slough, and other agricultural return flows are tributaries. Monthly sampling of these two agricultural drains by the USGS National Water-Quality Assessment Program shows seasonal variations in metal concentrations, reaching maximum concentrations of 4 to 6 micrograms per liter in "dissolved" (0.45-micrometer filtrate) copper concentrations in May 1996, December 1996, and June 1997. The total (dissolved plus colloidal) load of copper from the Colusa Basin Drain in June 1997 was 18 kilograms per day, whereas the copper load in Spring Creek, which drains the inactive mines on Iron Mountain, was 20 kilograms per day during the same sampling period. For comparison, during the January 1997 flood, the copper load in Spring Creek was about 1,100 kilograms per day and the copper load in the Yolo Bypass was about 7,300 kilograms per day. The data clearly indicate that most copper and zinc loads during the January 1997 flood entered the Sacramento River upstream of Colusa, and upstream of the influence of the most intense agricultural drainage return flows in the Sacramento River watershed. This study has demonstrated that some trace metals of environmental significance (cadmium, copper, and zinc) in the Sacramento River are transported largely in dissolved form at upstream sites (below Shasta Dam, below Keswick Dam, and at Bend Bridge) proximal to the mineralized areas of the West Shasta and East Shasta mining districts. In contrast, these trace metals are transported largely in colloidal form at downstream sites (Colusa, Verona, Freeport, and Yolo Bypass). Aluminum, iron, and lead were observed to be transported predominantly in the colloidal phase at all mainstem Sacramento River sampling sites during all sampling periods in this study. Despite continuous water treatment, which has removed 85 to 90 percent of the cadmium, copper, and zinc from the mine drainage at Iron Mountain, Spring Creek remains a significant source of these metals to the Sacramento River system.

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Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

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