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USGS2007

A Precipitation-Runoff Model for the Blackstone River Basin, Massachusetts and Rhode Island

A Hydrological Simulation Program-FORTRAN (HSPF) precipitation-runoff model of the Blackstone River Basin was developed and calibrated to study the effects of changing land- and water-use patterns on water resources. The 474.5 mi2 Blackstone River Basin in southeastern Massachusetts and northern Rhode Island is experiencing rapid population and commercial growth throughout much of its area. This growth and the corresponding changes in land-use patterns are increasing stress on water resources and raising concerns about the future availability of water to meet residential and commercial needs. Increased withdrawals and wastewater-return flows also could adversely affect aquatic habitat, water quality, and the recreational value of the streams in the basin. The Blackstone River Basin was represented by 19 hydrologic response units (HRUs): 17 types of pervious areas (PERLNDs) established from combinations of surficial geology, land-use categories, and the distribution of public water and public sewer systems, and two types of impervious areas (IMPLNDs). Wetlands were combined with open water and simulated as stream reaches that receive runoff from surrounding pervious and impervious areas. This approach was taken to achieve greater flexibility in calibrating evapotranspiration losses from wetlands during the growing season. The basin was segmented into 50 reaches (RCHRES) to represent junctions at tributaries, major lakes and reservoirs, and drainage areas to streamflow-gaging stations. Climatological, streamflow, water-withdrawal, and wastewater-return data were collected during the study to develop the HSPF model. Climatological data collected at Worcester Regional Airport in Worcester, Massachusetts and T.F. Green Airport in Warwick, Rhode Island, were used for model calibration. A total of 15 streamflow-gaging stations were used in the calibration. Streamflow was measured at eight continuous-record streamflow-gaging stations that are part of the U.S. Geological Survey cooperative streamflow-gaging network, and at seven partial-record stations installed in 2004 for this study. Because the model-calibration period preceded data collection at the partial-record stations, a continuous streamflow record was estimated at these stations by correlation with flows at nearby continuous-record stations to provide additional streamflow data for model calibration. Water-use information was compiled for 1996-2001 and included municipal and commercial/industrial withdrawals, private residential withdrawals, golf-course withdrawals, municipal wastewater-return flows, and on-site septic effluent return flows. Streamflow depletion was computed for all time-varying ground-water withdrawals prior to simulation. Water-use data were included in the model to represent the net effect of water use on simulated hydrographs. Consequently, the calibrated values of the hydrologic parameters better represent the hydrologic response of the basin to precipitation. The model was calibrated for 1997-2001 to coincide with the land-use and water-use data compiled for the study. Four long-term stations (Nipmuc River near Harrisville, Rhode Island; Quinsigamond River at North Grafton, Massachusetts; Branch River at Forestdale, Rhode Island; and Blackstone River at Woonsocket, Rhode Island) that monitor flow at 3.3, 5.4, 19, and 88 percent of the total basin area, respectively, provided the primary model-calibration points. Hydrographs, scatter plots, and flow-duration curves of observed and simulated discharges, along with various model-fit statistics, indicated that the model performed well over a range of hydrologic conditions. For example, the total runoff volume for the calibration period simulated at the Nipmuc River near Harrisville, Rhode Island; Quinsigamond River at North Grafton, Massachusetts; Branch River at Forestdale, Rhode Island; and Blackstone River at Woonsocket, Rhode Island streamflow-gaging stations differed from the observed runoff v

Scientific Investigations Report↗
USGS2007

Simulations of Ground-Water Flow and Residence Time near Woodbury, Connecticut

Water withdrawn for public use from glacial stratified deposits in Woodbury, Connecticut, is a mixture of water from different source areas, each having a characteristic water-quality signature. The physical processes leading to this mixture were explored using a numerical model to simulate steady-state ground-water source areas and residence times for a public water-supply well (PSW-1) in Woodbury. Upland areas contribute water to the well that is primarily from undeveloped and agricultural land. Valley bottoms contribute water to the well that is primarily from developed land. From 1985 to 2002, 6 percent of the contributing recharge area to the well changed from agricultural and undeveloped to developed land. The pattern of recharge areas and land use causes stratification of ground water by residence time and by characteristic water quality, which is related to land use. As land use changes with time, the water-quality signature of developed land moves deeper into the aquifer. Predicted nitrate concentrations decreased from 1985 to 1995 because of the conversion from agricultural land to developed land, but then began to increase after 1995 because of the conversion of undeveloped land to developed land. Total dissolved solids concentrations, on the other hand, increased from 1985 to 2002 because agriculture is associated with lower total dissolved solids concentrations than is developed land. About 40 percent of the water withdrawn from PSW-1 originated as upland recharge before flowing through glacial deposits in the valley. About 44 percent of the water originated as recharge in either fluvial deposits (mean residence time 7 years) or deltaic deposits (mean residence time 4 years). About 16 percent of the water originated as recharge through storm drains with ground-water discharge (often known as 'dry wells'). The residence time for water that originated as recharge in dry wells is 2 to 4 years, and the mean residence time is 3 years. Dry wells are a fast pathway for water to enter the aquifer and provide a significant amount of water to PSW-1; therefore, PSW-1 is more susceptible to contamination in runoff from the commercial area, which enters the dry wells, than to recharge elsewhere in the area. Water withdrawn from a well is a mixture of waters with different residence times, and a single residence time does not fully characterize the susceptibility of the well to recent contamination. The mean simulated flow-weighted residence time in PSW-1 is 6 years, which compares reasonably well with the apparent residence time measured using tritium/helium data of 6 and 7 years (samples for age dating were collected twice from this well). There are at least two modes to the distribution of ages, one mode with residence times less than 5 years and one mode with residence times greater than 5 years. About 34 percent of the ground-water in PSW-1 is younger than 5 years and 56 percent of the water is from 5 to 9 years. The estimated nitrate loading rate from a single-family septic system is 18 grams per day. If each household in the contributing recharge area contributes nitrate at that loading rate to the well PSW-1, each additional septic system in the contributing recharge area is responsible for a 0.045-milligram-per-liter increase in nitrate at PSW-1 at the current pumping rate. Uncertainty in the predicted contributing recharge area can be propagated through the analysis using a Monte Carlo technique. There is a greater degree of certainty in the delineation of the recharge area near the well, and as one moves from the well toward the recharge areas, the uncertainty in the model increases. The area that possibly contributes water to the well using the Monte Carlo model is much larger than the recharge area delineated using the optimal parameter estimates. Within the probabilistic recharge area, the number of septic systems could be twice the number initially estimated.

Scientific Investigations Report↗
USGS1998

Hydrogeology, water quality, water budgets, and simulated responses to hydrologic changes in Santa Rosa and San Simeon Creek ground-water basins, San Luis Obispo County, California

Santa Rosa and San Simeon Creeks are underlain by thin, narrow ground-water basins that supply nearly all water used for local agricultural and municipal purposes. The creeks discharge to the Pacific Ocean near the northwestern corner of San Luis Obispo County, California. The basins contain heterogeneous, unconsolidated alluvial deposits and are underlain by relatively impermeable bedrock. Both creeks usually stop flowing during the summer dry season, and most of the pumpage during that time is derived from ground-water storage. Annual pumpage increased substantially during 1956?88 and is now a large fraction of basin storage capacity. Consequently, dry-season water levels are lower and the water supply is more vulnerable to drought. The creeks are the largest source of ground-water recharge, and complete basin recharge can occur within the first few weeks of winter streamflow. Agricultural and municipal pumpages are the largest outflows and cause dry-season water-level declines throughout the San Simeon Basin. Pumping effects are more localized in the Santa Rosa Basin because of subsurface flow obstructions. Even without pumpage, a large quantity of water naturally drains out of storage at the upper ends of the basins during the dry season. Ground water is more saline in areas close to the coast than in inland areas. Although seawater intrusion has occurred in the past, it probably was not the cause of high salinity in 1988?89. Ground water is very hard, and concentrations of dissolved solids, chloride, iron, and manganese exceed drinking-water standards in some locations. Probability distributions of streamflow were estimated indirectly from a 120-year rainfall record because the periods of record for local stream-gaging stations were wetter than average. Dry-season durations with recurrence intervals between 5 and 43 years are likely to dry up some wells but not cause seawater intrusion. A winter with no streamflow is likely to occur about every 32 years and to result in numerous dry wells, seawater intrusion, and subsidence. Digital ground-water-flow models were used to estimate several items in the ground-water budgets and to investigate the effects of pumpage and drought. The models also were used to investigate the hydrologic effects of selected water-resources management alternatives. Selection of alternatives was not constrained by issues related to water rights, which were under dispute during the study. Increases in the area and intensity of irrigation could increase agricultural water demand by 26 to 35 percent, an increase that would lower water levels by as much as 10 feet and possibly cause subsidence in the lower Santa Rosa Basin. An additional municipal well in the lower Santa Rosa Basin could withdraw 100 acre-feet per year without causing seawater intrusion, but subsidence might occur. Transferring 270 acre-feet per year of treated wastewater from a percolation area near the coast to an area about 0.5 mile upstream of the municipal well field in the San Simeon Basin could raise upstream water levels by as much as 12 feet without causing significant water-table mounding or seawater intrusion. Decreases in agricultural pumping after a winter without streamflow could prevent seawater intrusion while allowing municipal pumping to continue at normal rates.

Water-Resources Investigations Report↗
USGS2000

Application of nonlinear least-squares regression to ground-water flow modeling, west-central Florida

A nonlinear least-squares regression technique for estimation of ground-water flow model parameters was applied to an existing model of the regional aquifer system underlying west-central Florida. The regression technique minimizes the differences between measured and simulated water levels. Regression statistics, including parameter sensitivities and correlations, were calculated for reported parameter values in the existing model. Optimal parameter values for selected hydrologic variables of interest are estimated by nonlinear regression. Optimal estimates of parameter values are about 140 times greater than and about 0.01 times less than reported values. Independently estimating all parameters by nonlinear regression was impossible, given the existing zonation structure and number of observations, because of parameter insensitivity and correlation. Although the model yields parameter values similar to those estimated by other methods and reproduces the measured water levels reasonably accurately, a simpler parameter structure should be considered. Some possible ways of improving model calibration are to: (1) modify the defined parameter-zonation structure by omitting and/or combining parameters to be estimated; (2) carefully eliminate observation data based on evidence that they are likely to be biased; (3) collect additional water-level data; (4) assign values to insensitive parameters, and (5) estimate the most sensitive parameters first, then, using the optimized values for these parameters, estimate the entire data set.

Water-Resources Investigations Report↗
USGS2005

Ground-water modeling of pumping effects near regional ground-water divides and river/aquifer systems - Results and implications of numerical experiments

Agreements between United States governors and Canadian territorial premiers establish water-management principles and a framework for protecting Great Lakes waters, including ground water, from diversion and consumptive uses. The issue of ground-water diversions out of the Great Lakes Basin by large-scale pumping near the divides has been raised. Two scenario models, in which regional ground-water flow models represent major aquifers in the Great Lakes region, were used to assess the effect of pumping near ground-water divides. The regional carbonate aquifer model was a generalized model representing northwestern Ohio and northeastern Indiana; the regional sandstone aquifer model used an existing calibrated ground-water flow model for southeastern Wisconsin. Various well locations and pumping rates were examined. Although the two models have different frameworks and boundary conditions, results of the models were similar. There was significant diversion of ground water across ground-water divides due to pumping within 10 miles of the divides. In the regional carbonate aquifer model, the percentage of pumped water crossing the divide ranges from about 20 percent for a well 10 miles from the divide to about 50 percent for a well adjacent to the divide. In the regional sandstone aquifer model, the percentages range from about 30 percent for a well 10 miles from the divide to about 50 percent for a well adjacent to the divide; when pumping on the west side of the divide, within 5 mi of the predevelopment divide, results in at least 10 percent of the water being diverted from the east side of the divide. Two additional scenario models were done to examine the effects of pumping near rivers. Transient models were used to simulate a rapid stage rise in a river during pumping at a well in carbonate and glacial aquifers near the river. Results of water-budget analyses indicate that induced infiltration, captured streamflow, and underflow were important for both glacial and carbonate aquifers; however, in many cases, traveltimes from the river to the well will limit river water from physically entering the well.

Scientific Investigations Report↗
USGS1995

Hydrogeology, simulated ground-water flow, and ground-water quality at two landfills in Bristol, Vermont

A study was done to describe the hydrogeology of unconsolidated deposits, simulated ground-water flow, and ground-water quality at two landfills in Bristol, Vermont. The study area is characterized by a glacial delta greater than 200 feet thick on the west flank of the Green Mountains. An upper unconfined, coarse-grained glacial aquifer and a lower fine-grained glacial aquifer are separated throughout most of the study area by a sand, silt, and clay confining unit. A two-layer ground-water flow model was designed and calibrated to estimate ground-water-flow paths form the aquifers beneath the landfills. Large upward head gradients of 0.03 to 0.30 foot per foot are the result of ground water leaking from the underlying bedrock aquifer, which caused ground-water flow to concentrate in the upper aquifer. Most simulated ground-water-flow paths in the lower glacial aquifer beneath the landfills crossed into the upper aquifer. Simulated ground- water-flow paths in the upper aquifer, beneath the landfills, remained in the upper aquifer. Ground water characterized as landfill leachate, or influenced by landfill leachate, has a median specific conductance of 700 microseimens per centimeter at 25 degrees Celsius. Landfill leachate contained mean concentrations 1.5 to 10 times the background concentrations of common constituents and metals, including calcium, potassium, sodium, chloride, iron, magnesium, and manganese. Trace metals detected in the leachate included copper, nickel, zinc, cobalt, lead, and arsenic. Ten volatile organic compounds were found at four observation wells associated with one landfill and three volatile organic compounds were found at two observation wells associated with the record landfill. No one volatile organic compound was consistently found and detections were generally at or near detection limits.

Water-Resources Investigations Report↗
USGS2003

Estimated Ground-Water Withdrawals from the Death Valley Regional Flow System, Nevada and California, 1913-98

Ground-water withdrawals from 1913 through 1998 from the Death Valley regional flow system have been compiled to support a regional, three-dimensional, transient ground-water flow model. Withdrawal locations and depths of production intervals were estimated and associated errors were reported for 9,300 wells. Withdrawals were grouped into three categories: mining, public-supply, and commercial water use; domestic water use; and irrigation water use. In this report, groupings were based on the method used to estimate pumpage. Cumulative ground-water withdrawals from 1913 through 1998 totaled 3 million acre-feet, most of which was used to irrigate alfalfa. Annual withdrawal for irrigation ranged from 80 to almost 100 percent of the total pumpage. About 75,000 acre-feet was withdrawn for irrigation in 1998. Annual irrigation withdrawals generally were estimated as the product of irrigated acreage and application rate. About 320 fields totaling 11,000 acres were identified in six hydrographic areas. Annual application rates for high water-use crops ranged from 5 feet in Penoyer Valley to 9 feet in Pahrump Valley. The uncertainty in the estimates of ground-water withdrawals was attributed primarily to the uncertainty of application rate estimates. Annual ground-water withdrawal was estimated at about 90,000 acre-feet in 1998 with an assigned uncertainty bounded by 60,000 to 130,000 acre-feet.

Water-Resources Investigations Report↗
USGS2003

Questa baseline and pre-mining ground-water quality investigation. 3. Historical ground-water quality for the Red River Valley, New Mexico

Historical ground-water quality data for 100 wells in the Red River Valley between the U.S. Geological Survey streamflow-gaging station (08265000), near Questa, and Placer Creek east of the town of Red River, New Mexico, were compiled and reviewed. The tabulation included 608 water-quality records from 23 sources entered into an electronic database. Groundwater quality data were first collected at the Red River wastewater-treatment facility in 1982. Most analyses, however, were obtained between 1994 and 2002, even though the first wells were developed in 1962. The data were evaluated by considering (a) temporal consistency, (b) quality of sampling methods, (c) charge imbalance, and (d) replicate analyses. Analyses that qualified on the basis of these criteria were modeled to obtain saturation indices for gypsum, calcite, fluorite, gibbsite, manganite, and rhodocrosite. Plots created from the data illustrate that water chemistry in the Red River Valley is predominantly controlled by calcite dissolution, congruent gypsum dissolution, and pyrite oxidation.

New Mexico↗
USGS2001

Hydrogeology, model description, and flow analysis of the Mississippi River alluvial aquifer in northwestern Mississippi

The Mississippi River alluvial aquifer underlies a 7,000-square-mile area of the Mississippi River alluvial plain in northwestern Mississippi, an area locally known as the Delta. The alluvial aquifer is the most heavily pumped aquifer in Mississippi, and wells yielding more than 2,000 gallons per minute are common. About 98 percent of the pumpage from the alluvial aquifer is for agriculture. The sand and gravel that form the alluvial aquifer averages about 110 feet in thickness. The aquifer is confined over most of the Delta, and the upper confining unit averages about 25 feet in thickness. The average depth to water in the alluvial aquifer during fall 1999 was about 25 feet. The alluvial aquifer receives lateral recharge at the western boundary from the Mississippi River and at the eastern boundary from aquifers that directly underlie the Bluff Hills. The alluvial aquifer receives water vertically from precipitation, internal streams and lakes, and locally from the Cockfield and Sparta aquifers where they directly underlie the alluvial aquifer. The alluvial aquifer also discharges water to the underlying aquifers, and during extended periods with no surface runoff, to the Mississippi River and to the internal streams and lakes. The magnitude of recharge from the Mississippi River, precipitation, and internal lakes and streams can vary greatly depending upon hydrologic and climatic conditions. The U.S. Geological Survey modular threedimensional finite-difference ground-water flow model, MODFLOW, was used to simulate the Mississippi River alluvial aquifer flow system in northwestern Mississippi. The model uses one layer with a rectangular-grid and 1-mile square cells to represent the alluvial aquifer. The model was calibrated and verified by using spring and fall water-level measurements from January 1988 through December 1996. The values of selected model calibration-derived parameters for the alluvial aquifer are hydraulic conductivity, 425 feet per day; specific yield, 0.32; and storage coefficient, 0.016. The model showed that the aquifer lost water from storage at an average rate of 404 cubic feet per second during the 9-year simulation period. During this period, the average pumpage rate was 1,270 million gallons per day (1,980 cubic feet per second). Simulated areal recharge from precipitation averaged 2.6 inches per year (1,360 cubic feet per second). Vertical recharge from the internal streams and lakes and lateral recharge from aquifers underlying the Bluff Hills averaged 113 and 108 cubic feet per second, respectively. Model results indicated that net recharge from the Mississippi River and from aquifers directly underlying the alluvial aquifer was small.

Mississippi↗
USGS2002

Simulated pond-aquifer interactions under natural and stressed conditions near Snake Pond, Cape Cod, Massachusetts

A numerical model was used to simulate pond-aquifer interactions under natural and stressed conditions near Snake Pond, Cape Cod, Massachusetts. Simulation results show that pond-bottom hydraulic conductivity, which represents the degree of hydraulic connection between the pond and the aquifer, is an important control on these interactions. As this parameter was incrementally increased from 10 to 350 feet per day, the rate of ground-water inflow into the pond under natural conditions increased by about 250 percent, the associated residence times of water in the pond decreased by about 50 percent, and ground-water inflow to the pond shifted closer to the pond shore. Most ground-water inflow (90 to 98 percent) was in the upper model layer, which corresponded to shallow, near-shore areas of the pond, over the entire range of pond-bottom hydraulic conductivity. Ground-water flow paths into the pond became more vertical, the contributing area to the pond became larger, and the pond captured water from greater depths in the aquifer as the hydraulic conductivity of the pond bottom was increased. The pond level, however, remained nearly constant, and regional ground-water levels and gradients differed little over the range of pond-bottom hydraulic conductivity, indicating that calibrated models with similar head solutions can have different pond-aquifer interaction characteristics. Hydrologic stresses caused by a simulated plume-containment system that specifies the extraction and injection of large volumes of ground water near the pond increased the pond level by about 0.4 foot and ground-water inflow rates into the pond by about 25 percent. Several factors related to the operation of the simulated containment system are affected by the hydraulic conductivity of the pond bottom. With increasing pond-bottom hydraulic conductivity, the amount of injected water that flows into Snake Pond increased and the amount of water recirculated between extraction and injection wells decreased. Comparison of simulations in which pond-bottom hydraulic conductivity was varied throughout the pond and simulations in which hydraulic conductivity was varied only in areas corresponding to shallow, near-shore areas of the pond indicate that the simulated hydraulic conductivity of the pond bottom in deeper parts of the pond had little effect on pond-aquifer interactions under both natural and stressed conditions.

Massachusetts↗
USGS1988

Recharge to the Eagle Valley ground-water basin by streamflow in Vicee Canyon, west-central Nevada

Recharge to groundwater could be increased by adding imported water to natural surface water flow in Vicee Canyon, in Eagle Valley, Nevada, where municipal pumping has caused as much as 50 ft of water level decline since 1972. Measurements of infiltration rates, percolation rates, and hydraulic conductivity indicate that the area could be conducive to artificial recharge from infiltration of augmented streamflow. Runoff creates natural infiltration beds on the floor of Vicee Canyon, but baseflow causes channelization and armoring of the stream channel, reducing infiltration rates from about 4 inches to 1 inch/hour. A water balance of the streamflow in Vicee Canyon indicates that 60 to 70% becomes recharge, and the remainder is lost to evaporation from a nearby gravel pit and evapotranspiration on the canyon floor. Estimates of recharge from measurements in the unsaturated and saturated zones account for about 45% of the total streamflow. Application of a groundwater flow model indicates that at present pumping rates, water levels below Vicee Canyon and at a nearby municipal well may rise about 15-30 ft after 5 years as a result of about 1 cu ft/sec of augmented streamflow infiltration. (USGS)

Water-Resources Investigations Report↗
USGS1978

Computer modeling of ground-water availability in the Pootatuck River Valley, Newtown, Connecticut

A hydrologic analysis of the stratified drift in Newtown, Conn., based on available data, test drilling, seismic refraction profiling, and the stream-aquifer connection was performed using a digital computer model. Simulated pumping indicates that a total of 4.0 million gallons of water per day (Mgal/d) can be withdrawn from the stream-aquifer system. A minimum of 2.5 Mgal/d is available for future development since Fairfield Hills Hospital is capable of withdrawing 1.5 Mgal/d. Induced recharge from the Pootatuck River supplies 65 percent, or 2.6 Mgal/d of the total pumpage, and captured ground-water outflow supplies the remaining 35 percent of 1.4 Mgal/d. The predicted yields are for long-term average hydrologic conditions; usually dry or extended drought periods would significantly reduce the water available from the aquifer. The quality of surface water in the valley as shown by seven samples from five sites, meets the Connecticut standards for public drinking water except for excessive coliform bacteria. Ground-water quality also meets these standards, as indicated by analyses of 20 samples from 14 wells and 1 spring, but high manganese (up to 15 mg/L) and iron (up to 1.7 mg/L) would require treatment prior to use. Trace metals from one surface-water and four ground-water samples are also within these standards, except for the high cadmium concentration of 26 micrograms per liter in water from one well. (Woodard-USGS)

Water-Resources Investigations Report↗
USGS2001

An estimate of chemical loads from ground water to the Grand Calumet River and Indiana Harbor Canal, northwestern Indiana

Chemical loads from ground water to the Grand Calumet River and the Indiana Harbor Canal in northwestern Indiana were estimated to aid in determining the total maximum daily load. Data from two previous studies, completed in 1987 and 1993, were used to compute loads. The first study included a ground-water-flow model. Results from this model were used to determine ground-water fluxes to eight distinct reaches of the Grand Calumet River and the Indiana Harbor Canal at assumed horizontal hydraulic conductivities of 50 and 100 feet per day. In addition, water quality data collected during the first study and a second study that further described the quality of water from wells screened in the Calumet aquifer, were used with the ground-water fluxes to compute estimates of chemical loads for selected constituents contributing to the Grand Calumet River and Indiana Harbor Canal. Constituents included trace elements, polychlorinated biphenyls, pesticides, polynuclear aromatic hydrocarbons, and selected general chemistry properties. Total dissolved solids, sulfate, chloride, and dissolved ammonia as nitrogen had the largest estimated loads to the Grand Calumet River and the Indiana Harbor Canal for any river reach. The estimated loads for total dissolved solids ranged from 239 to 12,800 kilograms per day. Dissolved iron had the largest estimated load for the trace elements and exceeded 1 kilogram per day for all river reaches for which data were available. The majority of ground-water concentrations for polychlorinated biphenyls, pesticides, and polynuclear aromatic hydrocarbons were reported as less than the method reporting limit, resulting in small computed loads to the river and canal.

Indiana↗
USGS1989

Modification of a method-of-characteristics solute-transport model to incorporate decay and equilibrium-controlled sorption or ion exchange

The U.S. Geological Survey computer model of two-dimensional solute transport and dispersion in ground water (Konikow and Bredehoeft, 1978) has been modified to incorporate the following types of chemical reactions: (1) first-order irreversible rate-reaction, such as radioactive decay; (2) reversible equilibrium-controlled sorption with linear, Freundlich, or Langmuir isotherms; and (3) reversible equilibrium-controlled ion exchange for monovalent or divalent ions. Numerical procedures are developed to incorporate these processes in the general solution scheme that uses method-of- characteristics with particle tracking for advection and finite-difference methods for dispersion. The first type of reaction is accounted for by an exponential decay term applied directly to the particle concentration. The second and third types of reactions are incorporated through a retardation factor, which is a function of concentration for nonlinear cases. The model is evaluated and verified by comparison with analytical solutions for linear sorption and decay, and by comparison with other numerical solutions for nonlinear sorption and ion exchange.

Water-Resources Investigations Report↗
USGS2002

Geohydrology, water quality, and simulation of ground-water flow in the vicinity of a former waste-oil refinery near Westville, Indiana, 1997–2000

Geohydrologic and water-quality data collected during 1997 through 2000 in the vicinity of a former waste-oil refinery near Westville, Indiana, define a plume of 1,4-dioxane in ground water that extends to the southwest approximately 0.8 miles from the refinery site. Concentrations of 1,4-dioxane in the plume ranged from 3 to 31,000 micrograms per liter. Ground water containing 1,4-dioxane is discharged to Crumpacker Ditch, approximately one-half mile west of the refinery site. Concentrations of 1,4-dioxane detected in surface water ranged from 8 to 140 micrograms per liter; 1,4-dioxane also is transported in ground water beneath the ditch. The study area is underlain by glacial deposits of sand and gravel that overlie lacustrine clay and shale. The sand and gravel deposits form an extensive aquifer ranging from 148 to 215 feet thick in the study area. Ground water generally flows from northeast to southwest and the depth to water ranges from about 3 to 36 feet below land surface. The average horizontal hydraulic conductivity of the aquifer, determined from a multiple-well aquifer test, was 121 feet per day, and the transmissivity was 18,600 feet squared per day. Vertical hydraulic conductivity ranged from 24 to 36 feet per day and specific yield ranged from 0.05 to 0.08. Analysis of single-well aquifer tests indicated that horizontal hydraulic conductivity ranged from 0.6 to 127 feet per day and was largest in the lower part of the aquifer. Horizontal gradients averaged about 0.001 feet per foot; estimated ground-water- flow velocities averaged about 0.1 feet per day in the upper and middle parts of the glacial aquifer and about 0.4 feet per day near the bottom of the aquifer. Analytical results of water samples indicate the ground water generally is a calcium-bicarbonate type with a nearly neutral pH. Specific conductivity ranged from 437 to 1,030 microsiemens per centimeter at 25 degrees Celsius in water from wells upgradient from the refinery site and 330 to 3,780 microsiemens per centimeter at 25 degrees Celsius in water from downgradient wells. Barium, iron, manganese, nickel, and zinc commonly were detected in samples of ground water. Volatile organic compounds (including chlorinated solvents and aromatic hydrocarbons) were consistently detected in samples from shallow wells near the boundaries of the former refinery site. Concentrations of 1,4-dioxane were detected in water from wells screened in the upper, middle, and lower parts of the aquifer downgradient from the site and in samples of surface water collected approximately 5 miles downstream from where the plume intersects Crumpacker Ditch. A three-dimensional, four layer groundwater- flow model was constructed and calibrated to match ground-water levels and streamflow measured during December 1997. The model was used to simulate possible mechanisms of contaminant release, the effect of increased pumpage from water-supply wells, and pumping at the leading edge of the plume as a possible means of remediation. Based on simulation of three waste-oil lagoons, a vertical hydraulic conductivity of 0.2 feet per day was required to move contaminants into the bottom layer of the model at a constant leakage rate of about 98 gallons per minute. Simulations of a disposal well in layer 3 of the model indicated an injection rate of 50 gallons per minute was necessary to spread contaminants vertically in the aquifer. Simulated pumping rates of about 300 and 1,000 gallons per minute were required for water supply wells at the Town of Westville and the Westville Correctional Facility to draw water from the plume of 1,4-dioxane. Simulated pumping from hypothetical wells at the leading edge of the plume indicated that three wells, each pumping 25 gallons per minute from model layer 3, would capture the plume of 1,4-dioxane.

Indiana↗
USGS1984

Appraisal of the water resources of the eastern part of the Tulare aquifer, Beadle, Hand, and Spink Counties, South Dakota

A system of glacial outwash aquifers lie in the central James Valley in east-central South Dakota. Within this system, the eastern part of the Tulare aquifer, which has an area of approximately 681 square miles, was simulated by means of a numerical ground-water flow model. The model estimates the yearly average recharge rate for that part of the aquifer lying west of the James River to be approximately 23,000 acre-feet per year. This rate is considerably more than the estimated 1978 yearly average irrigation pumpage rate of 9,800 acre-feet per year. It is expected that, since pumping will reduce discharge from the aquifer through evapotranspiration and flow to the James River, this part of the aquifer would be able to supply irrigation water at recent pumpage rates for an indefinite period. For that part of the aquifer lying east of the river, estimated recharge is 6,800 acre-feet per year; a rate slightly smaller than the estimated 1978 yearly average irrigation pumpage rate of 7,200 acre-feet per year. It is estimated that this part of the aquifer would be able to supply irrigation water at 7,200 acre-feet per year for approximately 50 years, at which time excessive drawdown would begin to cause reduced well yields at several locations. (USGS)

Water-Resources Investigations Report↗
USGS1985

Geohydrology and ground-water flow at Verona Well Field, Battle Creek, Michigan

The city of Battle Creek has 30 wells in the Verona well field capable of yielding 300 to 1,000 gallons per minute each. During summer, total withdrawals are as little as 6,000 gallons per minute. In early 1984, only 9 to 12 of the wells were being used; the remaining wells were contaminated by volatile hydrocarbons. Ground water at and near Verona well field generally flows toward Battle Creek River except where directions are altered by pumping. During summer, especially during periods when withdrawals are as much as 12,000 gallons per minute, a large cone of depression develops and water is drawn to the well field from several thousand feet away. During winter, when withdrawals are as little as 6,000 gallons per minute, the cone is smaller. Ground-water flow is in three aquifers--a sand and gravel aquifer in deposits of Pleistocene age that overlies upper and lower sandstone aquifers of the Marshall Formation of Mississippian age. Model-simulated data that best matched measured data indicate horizontal hydraulic conductivities ranging from 15 to 110 feet per day for the sand and gravel aquifer, 150 feet per day for the upper sandstone aquifer, and 550 feet per day for the lower sandstone aquifer. Recharge was simulated at rates ranging from 8 to 13 inches per year. Model simulations to evaluate the feasibility of installing new supply wells immediately north of the present field indicate that pumping 3,750 gallons per minute from new wells at the site would produce about 7 feet of drawdown in the lower sandstone aquifer in the vicinity of the new wells. Because the new wells tap only the lower sandstone aquifer, the pumping would have little effect on the potentiometric surfaces for the two overlying aquifers.

Michigan↗
USGS2020

Geologic map of the Homestake Reservoir 7.5′ quadrangle, Lake, Pitkin, and Eagle Counties, Colorado

The Homestake Reservoir 7.5' quadrangle lies at the northwestern end of the Upper Arkansas Valley, and headwaters of the Arkansas River, and the Roaring Fork, Fryingpan, and Eagle Rivers of the Colorado River system. The quadrangle lies within tectonic provinces of the 1.4 giga-annum (Ga) Picuris orogeny and includes the late Paleozoic Ancestral Rockies, Late Cretaceous-Paleocene Laramide orogeny, Oligocene-to-Miocene and Pliocene? volcanism, and Miocene to the present Rio Grande rift extensional tectonics. In the eastern half of the quadrangle, high-angle, east-dipping, Neogene normal faults displace Proterozoic rocks, and locally Miocene-to-Pliocene? volcanic rocks. Many quartz veins and hydrothermally altered zones are exposed along the eastern flank of the quadrangle, indicative of the multiple tectonic episodes the region has experienced. The main intent of the map is to unravel the structural complexity by partitioning the structures and volcanism within the appropriate geologic interval. This ultimately permits accurate identification of geomorphic features suitable for chronologies related to landscape evolution studies, seismic and other natural hazard identification, ground and surface water modeling, and paleoclimatic studies. Within the western half of the quadrangle, Mesoproterozoic and Paleoproterozoic igneous and metamorphic rocks of 1.4 Ga St. Kevin Granite and 1.8–1.7 Ga Biotite gneiss and schist, respectively, are uplifted along the generally east-dipping, high-angle Sawatch fault system. In the northwest portion of the quadrangle, strands of the Homestake shear zone have been mapped, dated and assigned to the 1.4 Ga Picuris orogeny of northern New Mexico. 10 Be and 26 Al cosmogenic nuclide ages of the youngest glacial deposits indicate a last glacial maximum age of about 22–21 kilo-annum (ka) and complete deglaciation by about 14 kilo-annum, supported by chronologic studies in adjacent drainages. The Turquoise Lake impounding lateral and terminal moraine complex was deposited during late Pleistocene glacial maximum ~22–21 ka. No late Pleistocene tectonic activity is apparent within the quadrangle.

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