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Relations of Water Quality to Agricultural Chemical Use and Environmental Setting at Various Scales - Results from Selected Studies of the National Water-Quality Assessment Program

In 1991, the U.S. Geological Survey (USGS) began studies of 51 major river basins and aquifers across the United States as part of the National Water-Quality Assessment (NAWQA) Program to provide scientifically sound information for managing the Nation's water resources. The major goals of the NAWQA Program are to assess the status and long-term trends of the Nation's surface- and ground-water quality and to understand the natural and human factors that affect it (Gilliom and others, 1995). In 2001, the NAWQA Program began a second decade of intensive water-quality assessments. The 42 study units for this second decade were selected to represent a wide range of important hydrologic environments and potential contaminant sources. These NAWQA studies continue to address the goals of the first decade of the assessments to determine how water-quality conditions are changing over time. In addition to local- and regional-scale studies, NAWQA began to analyze and synthesize water-quality status and trends at the principal aquifer and major river-basin scales. This fact sheet summarizes results from four NAWQA studies that relate water quality to agricultural chemical use and environmental setting at these various scales: * Comparison of ground-water quality in northern and southern High Plains agricultural settings (principal aquifer scale); * Distribution patterns of pesticides and degradates in rain (local scale); * Occurrence of pesticides in shallow ground water underlying four agricultural areas (local and regional scales); and * Trends in nutrients and sediment over time in the Missouri River and its tributaries (major river-basin scale).

Fact Sheet↗

Double exposure and dynamic vulnerability: Assessing economic well-being, ecological change and the development of the oil and gas industry in coastal Louisiana

The oil and gas industry has been a powerful driver of economic change in coastal Louisiana for the latter half of the 20th century and into the 21st. Yet, the overall impact of the industry on the economic well-being of host communities is varied, both spatially and temporally. While the majority of Louisiana’s oil and gas production now occurs offshore, processing the extracted product is an energy-intensive undertaking requiring an expansive network of land-based infrastructure. Despite the positive economic aspects of this development, there are also potential negatives posed to coastal ecosystems and to communities located adjacent to oil and gas infrastructure. This research utilizes a double exposure framework to explore the relationship between oil and gas infrastructure development, fish and shellfish habitat, and economic well-being in Louisiana’s coastal zone from 1950 to 2010. The approach followed four main steps: (1) Developing a hazardousness of place model to identify areas of magnified risk due to the combined hazards of multiple potential exposure sites related to the extraction and processing of crude oil and natural gas; (2) developing a model of ecological functioning to measure the ability of aquatic habitat to support key fish and shellfish species; (3) utilizing an integrated community economic well-being index to assess change on a decadal timescale; and (4) analyzing selected oil-dependent communities to illustrate how change processes occurring in different energy sectors result in differential outcomes. The results suggest that, for many communities, the dependence on the oil and gas industry has increased economic well-being but also increased sensitivity to natural and human-induced changes, including fluctuating economic conditions, environmental stress, coastal habitat destruction, and increasing social and economic pressures.

Louisiana↗

Population ecology of Roosevelt elk: Conservation and management in Redwood National and State Parks. Butch Weckerly. 2017. University of Nevada Press, Reno, Nevada, USA. 224 pp. $54.95 hardback. ISBN 978- 1943859504.

Long-term research on large ungulate populations typically conjures perceptions of extensive (and expensive) animal capture and telemetry work, and subsequent advanced modeling of resource selection and population dynamics that inform management decisions. In contrast, studies lacking a telemetry component are often limited to animal behavior or natural history. Although compelling from a standpoint of advancing understanding of ecological and evolutionary processes, results from the latter can be unfairly labeled as esoteric because they are not easily transferable to resource managers or may not provide exceptional interest to a general public drawn to these charismatic megafuana. Such dichotomies are not predetermined, however, because study conditions exist where dedicated academic researchers on tight budgets can achieve results relevant to ecology and management.

Journal of Wildlife Management↗

CO2 time series patterns in contrasting headwater streams of North America

We explored the underlying patterns of temporal stream CO 2 partial pressure ( p CO 2 ) variability using highfrequency sensors in seven disparate headwater streams distributed across the northern hemisphere. We also compared this dataset of [40,000 p CO 2 records with other published records from lotic systems. Individual stream sites exhibited relatively distinct p CO 2 patterns over time with few consistent traits across sites. Some sites showed strong diel variability, some exhibited increasing p CO 2 with increasing discharge, whereas other streams had reduced p CO 2 with increasing discharge or no clear response to changes in flow. The only ‘‘universal’’ signature observed in headwater streams was a late summer p CO 2 maxima that was likely driven by greatest rates of organic matter respiration due to highest annual temperatures. However, we did not observe this seasonal pattern in a southern hardwood forest site, likely because the region was transitioning from a severe drought. This work clearly illustrates the heterogeneous nature of headwater streams, and highlights the idiosyncratic nature of a non-conservative solute that is jointly influenced by physics, hydrology, and biology. We suggest that future researchers carefully select sensor locations (within and among streams) and provide additional contextual information when attempting to explain p CO 2 patterns.

Alaska, Colorado, Georgia, Puerto Rico, Vermont, W↗

Geochemistry of amino acids in shells of the clam Saxidomus

Concentrations of amino acids and their corresponding d l "> dl enantiomeric ratios have been measured in shells of the bivalve mollusk Saxidomus from eleven localities, ranging in age from modern to probably more than 500,000 yr, along the Pacific coast of North America. Natural logarithms of amino acid concentrations correlate well with d l "> dl ratios, and the relationship provides a possible guide to the selection of fossils for use in amino acid dating. The relative order of the extents of racemization of amino acids at any given time appears to change with increasing sample age. Application of the amino acid dating method to shells from Whidbey Island, Washington, yields an age of about 80,000 yr, in contrast to the previously determined radiocarbon age of 36,000 yr which was measured on some shell carbonate and considered a minimum age. The amino acid age is compatible with the geologic record in the area.

Alaska, Washington↗

A new method of calculating electrical conductivity with applications to natural waters

A new method is presented for calculating the electrical conductivity of natural waters that is accurate over a large range of effective ionic strength (0.0004–0.7 mol kg −1 ), temperature (0–95 °C), pH (1–10), and conductivity (30–70,000 μS cm −1 ). The method incorporates a reliable set of equations to calculate the ionic molal conductivities of cations and anions (H + , Li + , Na + , K + , Cs + , NH 4 + , Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ , F − , Cl − , Br − , SO 4 2- , HCO 3 - , CO 3 2- , NO 3 - , and OH − ), environmentally important trace metals (Al 3+ , Cu 2+ , Fe 2+ , Fe 3+ , Mn 2+ , and Zn 2+ ), and ion pairs (HSO 4 - , NaSO 4 - , NaCO 3 - , and ). These equations are based on new electrical conductivity measurements for electrolytes found in a wide range of natural waters. In addition, the method is coupled to a geochemical speciation model that is used to calculate the speciated concentrations required for accurate conductivity calculations. The method was thoroughly tested by calculating the conductivities of 1593 natural water samples and the mean difference between the calculated and measured conductivities was −0.7 ± 5%. Many of the samples tested were selected to determine the limits of the method and include acid mine waters, geothermal waters, seawater, dilute mountain waters, and river water impacted by municipal waste water. Transport numbers were calculated and H + , Na + , Ca 2+ , Mg 2+ , NH 4 + , K + , Cl − , SO 4 2- , HCO 3 - , CP 3 2- , F − , Al 3+ , Fe 2+ , NO 3 - , and substantially contributed (>10%) to the conductivity of at least one of the samples. Conductivity imbalance in conjunction with charge imbalance can be used to identify whether a cation or an anion measurement is likely in error, thereby providing an additional quality assurance/quality control constraint on water analyses.

Geochimica et Cosmochimica Acta↗

Internships, employment opportunities, and research grants

As an unbiased, multidisciplinary science organization, the U.S. Geological Survey (USGS) is dedicated to the timely, relevant, and impartial study of the health of our ecosystems and environment, our natural resources, the impacts of climate and land-use change, and the natural hazards that threaten us. Opportunities for undergraduate and graduate students and faculty to participate in USGS science are available in the selected programs described below. Please note: U.S. citizenship is required for all government positions. This publication has been superseded by USGS General Information Product 165 Grant Opportunities for Academic Research and Training and USGS General Information Product 166 Student and Recent Graduate Employment Opportunities . This publication is proceeded by USGS General Information Product 80 Internships, Employment Opportunities, and Research Grants published in 2008.

General Information Product↗

Internships, employment opportunities, and research grants

As an unbiased, multidisciplinary science organization that focuses on biology, geography, geology, geospatial information, and water, the U.S. Geological Survey (USGS) is dedicated to the timely, relevant, and impartial study of the landscape, our natural resources, and the natural hazards that threaten us. Opportunities for undergraduate and graduate students and faculty to participate in USGS science are available through the selected programs described below. Please note: U.S. citizenship is required for all positions, although some noncitizens may be eligible in rare circumstances.

General Information Product↗

Hydrologic Drought Decision Support System (HyDroDSS)

The hydrologic drought decision support system (HyDroDSS) was developed by the U.S. Geological Survey (USGS) in cooperation with the Rhode Island Water Resources Board (RIWRB) for use in the analysis of hydrologic variables that may indicate the risk for streamflows to be below user-defined flow targets at a designated site of interest, which is defined herein as data-collection site on a stream that may be adversely affected by pumping. Hydrologic drought is defined for this study as a period of lower than normal streamflows caused by precipitation deficits and (or) water withdrawals. The HyDroDSS is designed to provide water managers with risk-based information for balancing water-supply needs and aquatic-habitat protection goals to mitigate potential effects of hydrologic drought. This report describes the theory and methods for retrospective streamflow-depletion analysis, rank correlation analysis, and drought-projection analysis. All three methods are designed to inform decisions made by drought steering committees and decisionmakers on the basis of quantitative risk assessment. All three methods use estimates of unaltered streamflow, which is the measured or modeled flow without major withdrawals or discharges, to approximate a natural low-flow regime. Retrospective streamflow-depletion analysis can be used by water-resource managers to evaluate relations between withdrawal plans and the potential effects of withdrawal plans on streams at one or more sites of interest in an area. Retrospective streamflow-depletion analysis indicates the historical risk of being below user-defined flow targets if different pumping plans were implemented for the period of record. Retrospective streamflow-depletion analysis also indicates the risk for creating hydrologic drought conditions caused by use of a pumping plan. Retrospective streamflow-depletion analysis is done by calculating the net streamflow depletions from withdrawals and discharges and applying these depletions to a simulated record of unaltered streamflow. Rank correlation analysis in the HyDroDSS indicates the persistence of hydrologic measurements from month to month for the prediction of developing hydrologic drought conditions and quantitatively indicates which hydrologic variables may be used to indicate the onset of hydrologic drought conditions. Rank correlation analysis also indicates the potential use of each variable for estimating the monthly minimum unaltered flow at a site of interest for use in the drought-projection analysis. Rank correlation analysis in the HyDroDSS is done by calculating Spearman’s rho for paired samples and the 95-percent confidence limits of this rho value. Rank correlation analysis can be done by using precipitation, groundwater levels, measured streamflows, and estimated unaltered streamflows. Serial correlation analysis, which indicates relations between current and future values, can be done for a single site. Cross correlation analysis, which indicates relations among current values at one site and current and future values at a second site, also can be done. Drought-projection analysis in the HyDroDSS indicates the risk for being in a hydrologic drought condition during the current month and the five following months with and without pumping. Drought-projection analysis also indicates the potential effectiveness of water-conservation methods for mitigating the effect of withdrawals in the coming months on the basis of the amount of depletion caused by different pumping plans and on the risk of unaltered flows being below streamflow targets. Drought-projection analysis in the HyDroDSS is done with Monte Carlo methods by using the position analysis method. In this method the initial value of estimated unaltered streamflows is calculated by correlation to a measured hydrologic variable (monthly precipitation, groundwater levels, or streamflows from an index station identified with the rank correlation analysis). Then a pseudorandom number generator is used to create 251 six-month-long flow traces by using a bootstrap method. Serial correlation of the estimated unaltered monthly minimum streamflows determined from the rank correlation analysis is preserved within each flow trace. The sample of unaltered streamflows indicates the risk of being below flow targets in the coming months under simulated natural conditions (without historic withdrawals). The streamflow-depletion algorithms are then used to estimate risks of flow being below targets if selected pumping plans are used. This report also describes the implementation of the HyDroDSS. The HyDroDSS was developed as a Microsoft Access® database application to facilitate storage, handling, and use of hydrologic datasets with a simple graphical user interface. The program is implemented in the database by using the Visual Basic for Applications® (VBA) programming language. Program source code for the analytical techniques is provided in the HyDroDSS and in electronic text files accompanying this report. Program source code for the graphical user interface and for data-handling code, which is specific to Microsoft Access® and the HyDroDSS, is provided in the database. An installation package with a run-time version of the software is available with this report for potential users who do not have a compatible copy of Microsoft Access®. Administrative rights are needed to install this version of the HyDroDSS. A case study, to demonstrate the use of HyDroDSS and interpretation of results for a site of interest, is detailed for the USGS streamgage on the Hunt River (station 01117000) near East Greenwich in central Rhode Island. The Hunt River streamgage was used because it has a long record of streamflow and is in a well-studied basin with a substantial amount of hydrologic and water-use data including groundwater pumping for municipal water supply.

Rhode Island↗

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri↗

Magnitude and frequency of floods in Nebraska

Estimates of flood characteristics with recurrence intervals up to 100 years can be obtained at most sites in Nebraska by use of techniques presented in this report. Instructions, equations, and graphs are presented to aid the design engineer in estimating the magnitude and frequency of floods. For natural-flow streams, the estimating equations and graphical solutions are based on regional relations between floods of a specific return period and selected basin characteristics. Nebraska was subdivided into five hydrologic regions by means of regressions and residuals from the regressions. The boundaries of Regions 1 and 2 were determined to a great extent by differences in soil type. The divisions between Region 2 and Region 4 were also determined by differences in soil type. Boundaries of Region 3 and Region 5 are along or near basin divides. Flood magnitude and frequency solution diagrams are presented for major controlled streams such as the North Platte, South Platte, Platte, and Republican Rivers. Flood information on small controlled streams is limited to available station data. Flood characteristics are tabulated for 303 gaging stations having 13 or more years of record. These flood characteristics provide the best information on floods at these gaged sites. Observed maximum flood peaks at 303 gaging stations with 13 or more years of record and significant peaks at 57 short-term stations and 31 miscellaneous sites are useful in designing flood-control works for maximum safety from flood damage. Comparison is made with maximum observed floods in the United States.

Nebraska↗

Occurrence and distribution of nitrate and herbicides in the Iowa River alluvial aquifer, Iowa: May 1984 to November 1985

From May 1984 to November 1985, the U.S. Geological Survey, in cooperation with the University of Iowa Hygienic Laboratory and the Iowa Department of Natural Resources, Geological Survey Bureau, investigated nitrate and herbicides in the Iowa River alluvial aquifer. The occurrence and distribution of nitrate and selected herbicides were determined in the Iowa River alluvial aquifer, a sand and gravel aquifer beneath agricultural land along the Iowa River in Iowa County, Iowa. Test drilling and water-quality sampling of the aquifer indicated that the areal distribution of nitrate in the aquifer is variable. Nitrate (as nitrogen) concentrations range from less than 0.10 to 79 milligrams per liter. Although nitrate distribution is variable, extensive aquifer contamination by nitrate is not apparent. Median nitrate concentrations were 5.9 milligrams per liter for municipal wells and 7.2 milligrams per liter for area streams, but were less than 2.0 milligrams per liter for test wells and domestic wells. Atrazine, cyanazine, metribuzin, alachlor, metolachlor, and trifluralin were detected in ground-water samples. Maximum concentration of atrazine in ground-water samples was 2.4 micrograms per liter; maximum concentration of metribuzin was 8.1 micrograms per liter. Area streams also contained herbicides in concentrations generally larger than concentrations in ground water. At a municipal well adjacent to a stream, similar seasonal concentrations of atrazine were detected for both ground- and surface-water samples. Surface water sometimes may be a source of nitrate and herbicides to adjacent ground water. Detailed sampling of vertical profiles using well nests indicated that the distribution of nitrate and selected herbicides is not vertically homogeneous. Generally, larger nitrate concentrations were detected at shallow depths in the aquifer; at greater depths, the nitrate concentrations were near the detection limit. Herbicides were detected in a pattern similar to that determined for nitrate. The true areal distribution of nitrate may be masked by inconsistent depths of sampling or incomplete vertical sampling. Variations in nitrate concentrations with depth possibly are because local aquifer flow is predominantly horizontal and may limit significant vertical dispersion of nitrate and herbicides, and because nitrate may not act conservatively in ground water and may be removed from the system by denitrification. For nested wells, the seasonal variations of nitrate and herbicides were greater at the shallower sampling depths for domestic and test wells. Seasonal variations of nitrate and herbicides illustrate that these constituents move quickly from surface application to shallow underlying aquifers. These constituents can be detected in ground water soon after chemical applications, usually within 6 weeks.

Iowa↗

Scanning the horizon for invasive plant threats using a data-driven approach

Early detection and eradication of invasive plants are more cost-effective than managing well-established invasive plant populations and their impacts. However, there is high uncertainty around which taxa are likely to become invasive in a given area. Horizon scanning that combines a data-driven approach with rapid risk assessment and consensus building among experts can help identify invasion threats. We performed a horizon scan of potential invasive plant threats to Florida, USA—a state with a high influx of introduced species, conditions that are generally favorable for plant establishment, and a history of negative impacts from invasive plants. We began with an initial list of 2128 non-native plant taxa that are known invaders or crop pests. We built on previous invasive species horizon scans by developing data-based criteria to prioritize 100 taxa for rapid risk assessment. The semi-automated prioritization process included selecting taxa “on the horizon” (i.e., not yet in the target location and not on a noxious weed list) with climate matching, naturalization history, “weediness” record, and global commonness. We derived overall invasion risk scores with rapid risk assessment by evaluating the likelihood of each of the taxa arriving, establishing, and having an impact in Florida. Then, following a consensus-building discussion, we identified six plant taxa as high risk, with overall risk scores ranging from 75 to 100 out of a possible 125. The six taxa are globally distributed, easily transported to new areas, found in regions with climates similar to Florida’s, and can impact native plant communities, human health, or agriculture. Finally, we evaluated our initial and final lists for potential biases. Assessors tended to assign higher risk scores to taxa that had more available information. In addition, we identified biases towards four plant families and certain geographical regions of origin. Our horizon scan approach identified taxa conforming to metrics of high invasion risk and used a methodology refined for plants that can be applied to other locations.

NeoBiota↗

Estimation of annual indices from roadside surveys

Most of the surveys presently used to estimate population trends on a large geographic scale depend upon repeated visits to a number of randomly selected routes or monitoring points. As these surveys cannot be analyzed by modeling annual mean densities among routes within a region, no natural annual index of population density exists for the region. We discuss two possible methodologies for estimating annual indices of abundance. In the context of the route-regression methodology, in which trends are estimated for each route and regional population trends are estimated as weighted averages of route trends, it is possible to find average residual distances between the predicted trends on each route and the actual data points. Adding these average residuals to the regional predicted values provides a measure of average distance from the actual data points to the predicted trends. A linear model approach can also be used to estimate annual indices, in which a regional slope parameter can be fit to the data in combination with annual effects. Bootstrapping can be used to provide some measure of the variability of these annual effects. These methods provide similar results in an example using Breeding Bird Survey data for scissor-tailed flycatcher (Tyrannlls forficatus) trends in Arkansas and Oklahoma.

Biological Report↗

Base of principal aquifer for parts of the North Platte, South Platte, and Twin Platte Natural Resources Districts, western Nebraska

Water resources in the North and South Platte River valleys of Nebraska, including the valley of Lodgepole Creek, are critical to the social and economic health of the area, and for the recovery of threatened and endangered species in the Platte River Basin. Groundwater and surface water are heavily used resources, and uses are regulated in the study area. Irrigation is the dominant water use and, in most instances, is supplied by both groundwater and surface-water sources. The U.S. Geological Survey and its partners have collaborated to use airborne geophysical surveys for areas of the North and South Platte River valleys including the valley of Lodgepole Creek in western Nebraska. The objective of the surveys was to map the aquifers and underlying bedrock topography of selected areas to help improve the understanding of groundwater–surface-water relations to guide water-management decisions. This project was a cooperative study involving the North Platte Natural Resources District, the South Platte Natural Resources District, the Twin Platte Natural Resources District, the Conservation and Survey Division of the University of Nebraska-Lincoln, and the Nebraska Environmental Trust. This report presents the interpreted base-of-aquifer surface for part of the area consisting of the North Platte Natural Resources District, the South Platte Natural Resources District, and the Twin Platte Natural Resources District. The interpretations presented herein build on work done by previous researchers from 2008 to 2009 by incorporating additional airborne electromagnetic survey data collected in 2010 and additional test holes from separate, related studies. To make the airborne electromagnetic data useful, numerical inversion was used to convert the measured data into a depth-dependent subsurface resistivity model. An interpretation of the elevation and configuration of the base of aquifer was completed in a geographic information system that provided x, y, and z coordinates. The process of interpretation involved manually picking locations (base-of-aquifer elevations) on the displayed airborne electromagnetic-derived resistivity profile by the project geophysicist, hydrologist, and geologist. These locations, or picks, of the base-of-aquifer elevation (typically the top of the Brule Formation of the White River Group) were then stored in a georeferenced database. The pick was made by comparing the inverted airborne electromagnetic-derived resistivity profile to the lithologic descriptions and borehole geophysical logs from nearby test holes. The database of interpretive picks of the base-of-aquifer elevation was used to create primary input for interpolating the new base-of-aquifer contours. The automatically generated contours were manually adjusted based on the interpreted location of paleovalleys eroded into the base-of-aquifer surface and associated bedrock highs, many of which were unmapped before this study. When contours are overlain by the water-table surface, the saturated thickness of the aquifer can be computed, which allows an estimate of total water in storage. The contours of the base-of-aquifer surface presented in this report may be used as the lower boundary layer in existing and future groundwater-flow models. The integration of geophysical data into the contouring process facilitated a more continuous and spatially comprehensive view of the hydrogeologic framework.

Nebraska↗

Investigating the Environmental Effects of Agriculture Practices on Natural Resources: Scientific Contributions of the U.S. Geological Survey to Enhance the Management of Agricultural Landscapes

The U.S. Geological Survey (USGS) enhances and protects the quality of life in the United States by advancing scientific knowledge to facilitate effective management of hydrologic, biologic, and geologic resources. Results of selected USGS research and monitoring projects in agricultural landscapes are presented in this Fact Sheet. Significant environmental and social issues associated with agricultural production include changes in the hydrologic cycle; introduction of toxic chemicals, nutrients, and pathogens; reduction and alteration of wildlife habitats; and invasive species. Understanding environmental consequences of agricultural production is critical to minimize unintended environmental consequences. The preservation and enhancement of our natural resources can be achieved by measuring the success of improved management practices and by adjusting conservation policies as needed to ensure long-term protection.

Fact Sheet↗

Dissolved methane in groundwater, Upper Delaware River Basin, Pennsylvania and New York, 2007-12

The prospect of natural gas development from the Marcellus and Utica Shales has raised concerns about freshwater aquifers being vulnerable to contamination. Well owners are asking questions about subsurface methane, such as, “Does my well water have methane and is it safe to drink the water?” and “Is my well system at risk of an explosion hazard associated with a combustible gas like methane in groundwater?” This newfound awareness of methane contamination of water wells by stray gas migration is based upon studies such as Molofsky and others (2011) who document the widespread natural occurrence of methane in drinking-water wells in Susquehanna County, Pennsylvania. In the same county, Osborn and others (2011) identified elevated methane concentrations in selected drinking-water wells in the vicinity of Marcellus Shale gas-development activities, although pre-development groundwater samples were not available for comparison. A compilation of dissolved methane concentrations in groundwater for New York State was published by Kappel and Nystrom (2012). Recent work documenting the occurrence and distribution of methane in groundwater was completed in southern Sullivan County, Pennsylvania (Sloto, 2013). Additional work is ongoing with respect to monitoring for stray gases in groundwater (Jackson and others, 2013). These studies and their results indicate the importance of collecting baseline or pre-development data. While such data are being collected in some areas, published data on methane in groundwater are sparse in the Upper Delaware River Basin of Pennsylvania, New York, and New Jersey. To manage drinking-water resources in areas of gas-well drilling and hydraulic fracturing in the Upper Delaware River Basin, the natural occurrence of methane in the tri-state aquifers needs to be documented. The purpose of this report is to present data on dissolved methane concentrations in the groundwater in the Upper Delaware River Basin. The scope is restricted to data for Pennsylvania and New York, no U.S. Geological Survey (USGS) methane analyses are presently available for northwestern New Jersey.

New York;Pennsylvania↗

Apparent Resistivity and Estimated Interaction Potential of Surface Water and Groundwater along Selected Canals and Streams in the Elkhorn-Loup Model Study Area, North-Central Nebraska, 2006-07

In 2005, the State of Nebraska adopted new legislation that in part requires local Natural Resources Districts to include the effect of groundwater use on surface-water systems in their groundwater management plan. In response the U.S. Geological Survey, in cooperation with the Upper Elkhorn, Lower Elkhorn, Upper Loup, Lower Loup, Middle Niobrara, Lower Niobrara, Lewis and Clark, and Lower Platte North Natural Resources Districts, did a study during 2006-07 to investigate the surface-water and groundwater interaction within a 79,800-square-kilometer area in north-central Nebraska. To determine how streambed materials affect surface-water and groundwater interaction, surface geophysical and lithologic data were integrated at four sites to characterize the hydrogeologic conditions within the study area. Frequency-domain electromagnetic and waterborne direct- current resistivity profiles were collected to map the near-surface hydrogeologic conditions along sections of Ainsworth Canal near Ainsworth, Nebraska; Mirdan and Geranium Canals near Ord, Nebraska; North Loup River near Ord, Nebraska; and Middle Loup River near Thedford, Nebraska. Lithologic data were collected from test holes at each site to aid interpretation of the geophysical data. Geostatistical analysis incorporating the spatial variability of resistivity was used to account for the effect of lithologic heterogeneity on effective hydraulic permeability. The geostatistical analysis and lithologic data descriptions were used to make an interpretation of the hydrogeologic system and derive estimates of surface-water/groundwater interaction potential within the canals and streambeds. The estimated interaction potential at the Ainsworth Canal site and the Mirdan and Geranium Canal site is generally low to moderately low. The sediment textures at nearby test holes typically were silt and clay and fine-to-medium sand. The apparent resistivity values for these sites ranged from 2 to 120 ohm-meters. The vertical and horizontal variability of the apparent resistivity data were consistently low. Low resistive variability indicates little lithologic heterogeneity for either canal site. The surface-water/groundwater interaction-potential estimates are in agreement with the narrow frequency distribution of resistivity, low apparent resistivities, low spatial heterogeneity, and test-hole grain-size ranges. The estimated surface-water/groundwater interaction potential at the North Loup and Middle Loup River sites is moderate to moderately high. The sediment textures at nearby test holes were predominantly fine, medium, and coarse sand with some silt and silty to sandy clay. The apparent resistivity values for these sites ranged from 34 to 1,338 ohm-meters. The vertical variability of the resistivity data was moderately high. The horizontal variability at these sites is low to moderately low. The higher resistive variability at these sites indicates generally greater lithologic heterogeneity than at either the Ainsworth Canal site or the Mirdan and Geranium Canal site. The surface-water/groundwater interaction-potential estimates are in agreement with the generally moderate to high apparent resistivity, the greater spatial heterogeneity, and the variable lithologic texture. A higher interaction potential as compared to the canal sites is expected because of the higher subsurface resistivity and greater lithologic heterogeneity.

Scientific Investigations Report↗