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At least 667 records · Page 37Linked to original sources

Trondhjemitic, 1.35-1.31 Ga gneisses of the Mount Holly Complex of Vermont: evidence for an Elzevirian event in the Grenville Basement of the United States Appalachians

A newly recognized suite of trondhjemite–tonalite and dacitic gneiss forms a 10 km wide belt of rocks within the Mount Holly Complex in the central part of the Green Mountain massif of Vermont. Field relationships and chemistry indicate that these gneisses are calc-alkaline, volcanic, and hypabyssal plutonic rocks older than the Middle Proterozoic regional deformation that affected the Mount Holly Complex. U–Pb zircon dates indicate ages as great as 1.35 Ga for crystallization of the volcanic protoliths and for intrusion of crosscutting trondhjemite. Tonalitic plutonism continued until 1.31 Ga.Map-scale contacts between the trondhjemitic–tonalitic–dacitic gneisses and the paragneiss sequence of the Mount Holly Complex are sharp, suggesting that the volcanic rocks of the trondhjemite–tonalite suite underlie the paragneiss units and do not intrude them. These relationships suggest that the trondhjemite–tonalite suite is either considerably older than, and unconformable beneath, the paragneiss cover rocks or represents a volcanic edifice slightly older than the deposition of the sedimentary precursor to the paragneiss units. The paragneiss and tonalite–trondhjemite gneisses are both intruded by younger granitoids that were intruded at about 1.25 Ga during strong dynamothermal metamorphism.The trondhjemitic gneisses of the Mount Holly Complex of Vermont have high Al 2 O 3 and low Yb contents and light rare-earth element enrichment patterns that are more characteristic of continental than oceanic volcanic arcs. The Mount Holly intrusives and volcanics may have formed during 1.35–1.31 Ga ensialic volcanic-arc activity, contemporaneous with ensimatic arc activity during the early part of the Elzevirian phase of the Grenville orogeny. In Vermont, later deformation and granite intrusion at about 1.25 Ga coincide with the major pulse of the Elzevirian orogeny and associated trondhjemitic plutonism in the Central Metasedimentary Belt of eastern Canada.

Vermont↗

U–Pb geochronology of Late Cretaceous and early Tertiary plutons in the northern Coast Mountains batholith

U–Pb geochronologic studies demonstrate that steeply dipping, sheetlike tonalitic plutons along the western margin of the northern Coast Mountains batholith were emplaced between ~83 and ~57 (perhaps ~55) Ma. Less elongate tonalitic–granodioritic bodies in central portions of the batholith yield ages of 59–58 Ma, coeval with younger phases of the tonalitic sheets. Large granite–granodiorite bodies in central and eastern portions of the batholith were emplaced at 51–48 Ma. Trends in ages suggest that the tonalitic bodies generally become younger southeastward and that, at the latitude of Juneau, plutonism migrated northeastward across the batholith at ~0.9 km/Ma. Variations in the age, shape, location, and degree of fabric development among the various plutons indicate that Late Cretaceous – Paleocene tonalitic bodies were emplaced into a steeply dipping, dip-slip shear zone that was active along the western margin of the batholith. Postkinematic Eocene plutons were emplaced at shallow crustal levels. Inherited zircon components in these plutons range in age from mid-Paleozoic to Early Proterozoic and are coeval with detrital zircons in adjacent metasedimentary rocks. These old zircons, combined with evolved Nd isotopic signatures for most plutons, record assimilation of continental crustal or supracrustal rocks during the generation and (or) ascent of the plutons.

Alaska↗

Submarine sedimentary features on a fjord delta front, Queen Inlet, Glacier Bay, Alaska

Side-scan sonar images provide a view of an actively changing delta front in a marine outwash fjord in Glacier Bay, Alaska. Numerous interconnected gullies and chute-like small channels form paths for the transport of sand and coarse silt from the braided glacial outwash streams on the delta plain to the sinuous turbidity-current channels incised into the fjord floor. These turbidity-current channels carry coarse sediment through the fjord and into the adjoining glacial trunk valley. Several sedimentary processes affect the development of this delta front: overflow plumes deposit fine sediment; sediment gravity flows result from episodic delivery of large loads of coarse sediment; and mass movement may be triggered by earthquakes and, more regularly, by spring-tidal drawdown or hydraulic loading.

Canadian Journal of Earth Sciences↗

Suspension freezing of bottom sediment and biota in the Northwest Passage and implications for Arctic Ocean sedimentation

Ice observations and sediment collected in a summer transit through the Northwest Passage provide insights on suspension freezing, the most important sediment entrainment mechanism for the Arctic Ocean. No evidence was seen for entrainment by bottom adfreezing, bluff slumping, river flooding, dragging ice keels, or significant eolian transport from land to sea. Lack of eolian sediment loading in the Northwest Passage, together with that already reported for northern Alaska, eliminates wind as an important source for fine sediment in the pack of the Beaufort Gyre and related parts of the Transpolar Drift. Muddy sediment with pebbles and cobbles, algae with holdfasts, ostracodes with appendages, and well-preserved mollusks and sea urchins were collected from two sites in a 50 km long stretch of turbid ice. These materials indicate that suspension freezing reaching to a water depth of 25–30 m during the previous fall was responsible for entrainment. This mechanism requires rapid ice formation in open, shallow water during a freezing storm, when the ocean becomes supercooled, and frazil and anchor ice attach to and ultimately lift sediment and living organisms to the sea surface. The mechanism, already known to be important in the Beaufort Sea, probably also affects wide, shallow Siberian shelves and leads to cross-shelf transport of shallow-water organisms and dropstones with "glacial striations" toward deep basins. This makes distinguishing glacial–interglacial cycles more difficult.

Nunavut↗

Petrology and isotopic composition of Quaternary basanites dredged from the Bering Sea continental margin near Navarin Basin

Quaternary basanites were recovered from shallow water depth from the continental margin of the Bering Sea (58°39.0′N, 177°12.9′W) near Navarin Basin. The basanites are highly vesicular flow rock and hyaloclastites similar to other alkalic volcanic rocks erupted repeatedly during the late Cenozoic on islands in the Bering Sea region and in mainland Alaska. K–Ar ages for the basanites indicate at least two episodes of volcanism at about 1.1 and 0.4 Ma. Similar alkalic volcanism occurred sporadically at geographically widely separated centers in the Bering Sea region for at least the past 6 Ma. Chemically, these alkalic lavas are intraplate basalts similar to those erupted from oceanic islands and in some continental settings. Trace-element data indicate these alkalic lavas have been generated by small, but variable, amounts of partial melting of a meta-somatized lherzolite source. The relatively primitive compositions (MgO > 9%), presence of mantle-derived xenoliths in some alkalic lavas, and presence of forsteritic olivine with low CaO and high NiO suggest that magma rose rapidly from greath depth without spending time in large, long-lived magma chambers. Although lavas from different volcanic centers in the Bering Sea region are similar with respect to major elements and many trace-element ratios, isotopic compositions indicate heterogeneities in the source. The Navarin basanites have higher 87 Sr/ 86 Sr and lower 143 Nd/ 144 Nd values than any other lavas so far reported from this region. The 207 Pb/ 204 Pb isotopic ratios indicate involvement of a crustal component, which may have resulted from metasomatism associated with subduction-related magmatic activity during the Early Eocene in this region. Although some volcanic episodes appear to have occurred roughly synchronously at geographically widely separated centers, no large-scale regional extension nor presence of large mantle plumes are indicated. Instead, alkalic volcanism apparently resulted from upwelling and decompressional melting of small isolated mantle diapirs in response to local lithospheric attenuation associated with jostling of blocks during adjustment to regional stresses.

Alaska↗

Geology, geochemistry, and geochronology of the central Giants Range batholith, northeastern Minnesota

The Giants Range batholith is a large composite granitoid body that intrudes deformed supracrustal rocks in the western part of the Wawa Subprovince of the Archean Superior Province. Peak fabric development in the supracrustal rocks coincides with D 2 deformation, the product of regional transpression across the southern Superior Province. U–Pb zircon ages on two phases of the Giants Range batholith bracket D 2 deformation to an interval between 2685 and 2669 Ma. Two well-exposed components of the central part of the Giants Range batholith are the pre- to syn-D 2 Britt granodiorite, which contains a linear D 2 metamorphic fabric, and the syn- to post-D 2 Shannon Lake granite, which cuts deformation fabrics in the Britt granodiorite and the supracrustal rocks. Geochemical discrimination plots imply emplacement of the Britt granodiorite in an arc environment and the Shannon Lake granite in a collision setting. Zircons yield U–Pb ages of 2681 ± 4 and 2685 ± 4 Ma for the Britt granodiorite and 2674 ± 5 and 2674 ± 27 Ma for the Shannon Lake granite. Timing of D 2 deformation near the Giants Range batholith corresponds well with similar rocks exposed along strike 170 km to the east near Shebandowan Lake, Ontario, where the end of D 2 deformation has been bracketed between 2692 and 2681 Ma. The slightly younger ages for D 2 deformation in Minnesota reflect later volcanic-arc development and associated plutonism than at Shebandowan Lake, possibly due to oblique convergence along a westward-migrating tectonic front.

Canadian Journal of Earth Sciences↗

Seismic images of a tectonic subdivision of the Greenville Orogen beneath lakes Ontario and Erie

New seismic data from marine air-gun and Vibroseis profiles in Lake Ontario and Lake Erie provide images of subhorizontal Phanerozoic sediments underlain by a remarkable series of easterly dipping reflections that extends from the crystalline basement to the lower crust. These reflections are interpreted as structural features of crustal-scale subdivisions within the Grenville Orogen. Broadly deformed, imbricated, and overlapping thrust sheets within the western Central Metasedimentary Belt are succeeded to the west by a complex zone of easterly dipping, apparent thrust faults that are interpreted as a southwest subsurface extension of the boundary zone between the Central Metasedimentary Belt and the Central Gneiss Belt. The interpreted Central Metasedimentary Belt boundary zone has a characteristic magnetic anomaly that provides a link from the adjacent ends of lakes Ontario and Erie to structures exposed 150 km to the north. Less reflective, west-dipping events are interpreted as structures within the eastern Central Gneiss Belt. The seismic interpretation augments current tectonic models that suggest the exposed ductile structures formed at depth as a result of crustal shortening along northwest-verging thrust faults. Relatively shallow reflections across the boundary region suggest local, Late Proterozoic extensional troughs containing post-Grenville sediments, preserved possibly as a result of pre-Paleozoic reactivation of basement structures.

Lake Erie, Lake Ontario↗

Deep structure beneath Lake Ontario: Crustal-scale Grenville subdivisions

Lake Ontario marine seismic data reveal major Grenville crustal subdivisions beneath central and southern Lake Ontario separated by interpreted shear zones that extend to the lower crust. A shear zone bounded transition between the Elzevir and Frontenac terranes exposed north of Lake Ontario is linked to a seismically defined shear zone beneath central Lake Ontario by prominent aeromagnetic and gravity anomalies, easterly dipping wide-angle reflections, and fractures in Paleozoic strata. We suggest the central Lake Ontario zone represents crustal-scale deformation along an Elzevir–Frontenac boundary zone that extends from outcrop to the south shore of Lake Ontario.Seismic images from Lake Ontario and the exposed western Central Metasedimentary Belt are dominated by crustal-scale shear zones and reflection geometries featuring arcuate reflections truncated at their bases by apparent east-dipping linear reflections. The images show that zones analogous to the interpreted Grenville Front Tectonic Zone are also present within the Central Metasedimentary Belt and support models of northwest-directed crustal shortening for Grenvillian deep crustal deformation beneath most of southeastern Ontario.A Precambrian basement high, the Iroquoian high, is defined by a thinning of generally horizontal Paleozoic strata over a crestal area above the basement shear zone beneath central Lake Ontario. The Iroquoian high helps explain the peninsular extension into Lake Ontario forming Prince Edward County, the occurrence of Precambrian inlier outcrops in Prince Edward County, and Paleozoic fractures forming the Clarendon–Linden structure in New York.

Lake Ontario↗

Intraglacial volcanism in the Wells Gray–Clearwater volcanic field, east-central British Columbia, Canada

Small-volume, subaerial, subaqueous and subglacial basaltic eruptions occurred in the Wells Gray–Clearwater area during Quaternary time. Part of this time, significant thicknesses of glacial ice were present. Dating of intraglacial volcanic features corroborates other evidence of an Early Pleistocene, Cordilleran-wide ice sheet. Of the intraglacial volcanoes investigated, three were studied in detail and of these, two probably erupted during the Fraser glaciation (11–20 ka), when maximum ice level exceeded 2100 m elevation. Major-element and sulphur concentrations were measured in glass from the volcanoes to provide insight into vent conditions at the time of eruption. Hyalo Ridge (2102 m elevation, whole-rock K–Ar age of 0.02 ± 0.01 Ma) is a small volcanic edifice capped by lava flows with coherent pillowed lavas and interbedded hyaloclastite exposed over nearly 400 m altitude on its east flank. Low sulphur content (<0.03 wt.%) in pillow rim glasses indicates that the lavas are degassed. It is interpreted that the vent built above the water (or ice) surface then fed lava flows that crossed a shoreline and produced pillowed flows. Pyramid Mountain is a volcanic cone 240 m high, comprised of glassy, vesicular, lapilli-tuff breccia. The highly alkalic glass contains 0.1 wt.% S (considered high), and indicates a high original volatile content and drastic quenching, probably during phreatomagmatic eruption from a meltwater-flooded vent. East of the Clearwater River a sequence of massive pillowed flows and pillow joint-block breccias is exposed from 880 to 1320 m elevation (0.27 ± 0.05 Ma). The vent location is unknown. Moderate S content (0.040–0.055 wt.%) indicates that the lavas were erupted in shallow water and are largely degassed. The S content of glass in dykes cutting the pillow breccias is low. The dykes are interpreted as lava that has flowed laterally or down into cracks

British Columbia↗

A 12 000 year radiocarbon date of deglaciation from the Continental Divide of northwestern Montana

During the Pinedale (Late Wisconsinan) glaciation, an outlet glacier from a mountain ice field flowed eastward across the Continental Divide through Marias Pass in northwestern Montana. This outlet glacier was the major source of the Two Medicine glacier, a large piedmont glacier that extended from the mountain front east about 55 km onto the plains. An accelerator mass spectrometry radiocarbon age of 12 194 ± 145 BP (AA-9530) was obtained from a wood fragment, underlying a Glacier Peak tephra and a Mount Saint Helens set J tephra in a section of lake sediments, near Marias Pass. This radiocarbon age provides a minimum date of deglaciation for the Marias Pass area that is about 800 years older than a previous estimate. Furthermore, the radiocarbon age indicates that the Two Medicine glacier was no longer being supplied by its major source and if it still existed was only as a dying, stagnant ice mass.

Idaho, Montana↗

The southern limit of Cordilleran ice in the Colville and Pend Oreille valleys of northeastern Washington during the Late Wisconsin glaciation

The southern limit of the lobes of the Cordilleran ice sheet in the Colville and Pend Oreille valleys of northeastern Washington during the Late Wisconsin (Fraser) glaciation has been placed at widely different positions by various investigators. The confusion that resulted in these different positions is due to the fact that both lobes, at times, terminated in glacial lakes and much of the terminal area of the Pend Oreille River lobe was swept by floods from glacial Lake Missoula. Evidence, presented in this paper, of the southern limit of these two lobes during the Late Wisconsin glaciation consists of ( i ) the southern limit of Late Wisconsinan till, ( ii ) the southern limit of lateral meltwater channels, ( iii ) meltwater channels whose headward areas coincide with the southern limit of Late Wisconsinan till, and ( iv ) reconstructed ice-surface profiles. This evidence suggests that the southern limit of the Colville lobe is represented by a moraine near the town of Springdale, whereas that of the Pend Oreille River lobe is near the town of Newport. The timing and extent of Late Wisconsinan deglaciation in the Colville Valley are provided by radiocarbon ages and Late Pleistocene tephras at sites upglacier from thfe terminal position. These data demonstrate that the Colville lobe had retreated at least 50 km by about 12 450 BP. In the Pend Oreille Valley, the presence of a Glacier Peak tephra layer near the town of lone indicates that the Pend Oreille River lobe had retreated at least 70 km prior to deposition of the tephra.

Washington↗

Block and shear-zone architecture of the Minnesota River Valley subprovince: Implications for late Archean accretionary tectonics

The Minnesota River Valley subprovince of the Superior Province is an Archean gneiss terrane composed internally of four crustal blocks bounded by three zones of east-northeast-trending linear geophysical anomalies. Two of the block-bounding zones are verified regional-scale shears. The geological nature of the third boundary has not been established. Potential-field geophysical models portray the boundary zones as moderately north-dipping surfaces or thin slabs similar in strike and dip to the Morris fault segment of the Great Lakes tectonic zone at the north margin of the subprovince. The central two blocks of the subprovince (Morton and Montevideo) are predominantly high-grade quartzofeldspathic gneiss, some as old as 3.6 Ga, and late-tectonic granite. The northern and southern blocks (Benson and Jeffers, respectively) are judged to contain less gneiss than the central blocks and a larger diversity of syntectonic and late-tectonic plutons. A belt of moderately metamorphosed mafic and ultramafic rocks having some attributes of a dismembered ophiolite is partly within the boundary zone between the Morton and Montevideo blocks. This and the other block boundaries are interpreted as late Archean structures that were reactivated in the Early Proterozoic. The Minnesota River Valley subprovince is interpreted as a late accretionary addition to the Superior Province. Because it was continental crust, it was not subductible when it impinged on the convergent southern margin of the Superior Craton in late Archean time, and it may have accommodated to convergent-margin stresses by dividing into blocks and shear zones capable of independent movement.

Minnesota↗

The Border Ranges fault system in Glacier Bay National Park, Alaska: Evidence for major early Cenozoic dextral strike-slip motion

The Border Ranges fault system of southern Alaska, the fundamental break between the arc basement and the forearc accretionary complex, is the boundary between the Peninsular–Alexander–Wrangellia terrane and the Chugach terrane. The fault system separates crystalline rocks of the Alexander terrane from metamorphic rocks of the Chugach terrane in Glacier Bay National Park. Mylonitic rocks in the zone record abundant evidence for dextral strike-slip motion along north-northwest-striking subvertical surfaces. Geochronologic data together with regional correlations of Chugach terrane rocks involved in the deformation constrain this movement between latest Cretaceous and Early Eocene (~50 Ma). These findings are in agreement with studies to the northwest and southeast along the Border Ranges fault system which show dextral strike-slip motion occurring between 58 and 50 Ma. Correlations between Glacier Bay plutons and rocks of similar ages elsewhere along the Border Ranges fault system suggest that as much as 700 km of dextral motion may have been accommodated by this structure. These observations are consistent with oblique convergence of the Kula plate during early Cenozoic and forearc slivering above an ancient subduction zone following late Mesozoic accretion of the Peninsular–Alexander–Wrangellia terrane to North America.

Alaska↗

40Ar/39Ar geochronology and paleomagnetism of Independence volcano, Absaroka volcanic supergroup, Beartooth mountains, Montana

Independence volcano is a major volcanic complex in the lower part of the Absaroka Volcanic Supergroup (AVS) of Montana and Wyoming. Recently reported Rb–Sr mineral dates from the complex give apparent ages of 91 and 84 Ma, whereas field relationships and the physical and compositional similarity of the rocks with other dated parts of the AVS indicate an Early to Middle Eocene age for eruption and deposition. To resolve the conflict between age assignments based on stratigraphic correlations and Rb–Sr dates, we report new paleomagnetic data and 40 Ar/ 39 Ar dates for Independence volcano. Paleomagnetic data for the stock and an andesite plug that cuts the stock are well grouped, of reverse polarity, and yield a virtual geomagnetic pole that is essentially identical to Late Cretaceous and Tertiary reference poles. The reverse polarity indicates that the magnetization of these rocks is probably younger than the Cretaceous normal superchron, or less than about 83.5 Ma. Hornblende from a volcanic breccia near the base of the volcanic pile gives a 40 Ar/ 39 Ar age of 51.57 Ma, whereas biotites from a dacite sill and a granodiorite stock that forms the core of the volcano give dates that range from 49.96 to 48.50 Ma. These dates record the age of eruption and intrusion of these rocks and clearly show that the age of Independence volcano is Early to Middle Eocene, consistent with stratigraphic relations. We suggest that the Rb–Sr mineral dates from the Independence stock and related intrusions are unreliable.

Montana, Wyoming↗

Trace-element geochemistry of metabasaltic rocks from the Yukon-Tanana Upland and implications for the origin of tectonic assemblages in east-central Alaska

We present major- and trace- element geochemical data for 27 amphibolites and six greenstones from three structural packages in the Yukon-Tanana Upland of east-central Alaska: the Lake George assemblage (LG) of Devono-Mississippian augen gneiss, quartz-mica schist, quartzite, and amphibolite; the Taylor Mountain assemblage (TM) of mafic schist and gneiss, marble, quartzite, and metachert; and the Seventymile terrane of greenstone, serpentinized peridotite, and Mississippian to Late Triassic metasedimentary rocks. Most LG amphibolites have relatively high Nb, TiO2, Zr, and light rare earth element contents, indicative of an alkalic to tholeiitic, within-plate basalt origin. The within-plate affinities of the LG amphibolites suggest that their basaltic parent magmas developed in an extensional setting and support a correlation of these metamorphosed continental-margin rocks with less metamorphosed counterparts across the Tintina fault in the Selwyn Basin of the Canadian Cordillera. TM amphibolites have a tholeiitic or calc-alkalic composition, low normalized abundances of Nb and Ta relative to Th and La, and Ti/V values of <20, all indicative of a volcanic-arc origin. Limited results from Seventymile greenstones indicate a tholeiitic or calc-alkalic composition and intermediate to high Ti/V values (27-48), consistent with either a within-plate or an ocean-floor basalt origin. Y-La-Nb proportions in both TM and Seventymile metabasalts indicate the proximity of the arc and marginal basin to continental crust. The arc geochemistry of TM amphibolites is consistent with a model in which the TM assemblage includes arc rocks generated above a west-dipping subduction zone outboard of the North American continental margin in mid-Paleozoic through Triassic time. The ocean-floor or within-plate basalt geochemistry of the Seventymile greenstones supports the correlation of the Seventymile terrane with the Slide Mountain terrane in Canada and the hypothesis that these oceanic rocks originated in a basin between the continental margin and an arc to the west.

Alaska↗

Permafrost and climate change: Carbon cycle feedbacks from the warming Arctic

Rapid Arctic environmental change affects the entire Earth system as thawing permafrost ecosystems release greenhouse gases to the atmosphere. Understanding how much permafrost carbon will be released, over what time frame, and what the relative emissions of carbon dioxide and methane will be is key for understanding the impact on global climate. In addition, the response of vegetation in a warming climate has the potential to offset at least some of the accelerating feedback to the climate from permafrost carbon. Temperature, organic carbon, and ground ice are key regulators for determining the impact of permafrost ecosystems on the global carbon cycle. Together, these encompass services of permafrost relevant to global society as well as to the people living in the region and help to determine the landscape-level response of this region to a changing climate.

Annual Review of Earth Science↗

The distribution of uranium over Europe: Geological and environmental significance

The variation of baseline levels of uranium in soil and stream sediments over Europe is described, based on new data prepared by the Forum of European Geological Surveys (FOREGS). The samples have been collected and analysed according to the protocols established for the International Union of Geological Sciences/International Association of Geochemistry and Cosmochemistry (IUGS/IAGC) Working Group on Global Geochemical Baselines. The baseline levels of U vary between 0??21 to 53 mg kg-1 in topsoils, 0??19 to 30 mg kg-1 in subsoils and < 1 to 59 mg kg-1 in stream sediments. There is generally good agreement between the levels of U in the three sample types, and the median concentration in all three media is approximately 2 mg kg-1. The most anomalous baseline levels occur over the Variscan orogen, especially areas into which late post-orogenic radiothermal high heat production (HHP) granites were emplaced. Spiderdiagrams based on trace element levels and rare earth element (REE) plots, confirm the association between the highest U anomalies and evolved radiothermal granites. High values are also associated with parts of the Alpine terrain especially in Slovenia, where there are historical U workings, and Southern Italy, where high values of U reflect contemporary volcanism. In contrast, much of the Caledonides of North West Europe and the Precambrian of the Baltic Shield and East European craton and its overlying sedimentary cover have very low values, generally < 4 mg kg-1. The results suggest that the main concern for the environment and human health from U, and the Th and K with which it is generally associated, is the naturally occurring total gamma radiation and radon potential associated with radiothermal granites. This is likely to be especially important where the granites are mineralised and have been worked historically, for example in the North West of the Iberian Peninsula where U and its decay products are likely to be more dispersed in the surface environment. The study also indicates the value of multi-element data in distinguishing between anthropogenic and naturally occurring anomalies.

Transactions of the Institution of Mining and Meta↗

Trace metal-rich Quaternary hydrothermal manganese oxide and barite deposit, Milos Island, Greece

The Cape Vani Mn oxide and barite deposit on Milos Island offers an excellent opportunity to study the three-dimensional characteristics of a shallow-water hydrothermal system. Milos Island is part of the active Aegean volcanic arc. A 1 km long basin located between two dacitic domes in northwest Milos is filled with a 35-50 m thick section of Quaternary volcaniclastic and pyroclastic rocks capped by reef limestone that were hydrothermally mineralized by Mn oxides and barite. Manganese occurs as thin layers, as cement of sandstone and as metasomatic replacement of the limestone, including abundant fossil shells. Manganese minerals include chiefly δ-MnO2, pyrolusite and ramsdellite. The MnO contents for single beds range up to 60%. The Mn oxide deposits are rich in Pb (to 3.4%), BaO (to 3.1%), Zn (to 0.8%), As (to 0.3%), Sb (to 0.2%) and Ag (to 10 ppm). Strontium isotopic compositions of the Mn oxide deposits and sulphur isotopic compositions of the associated barite show that the mineralizing fluids were predominantly sea water. The Mn oxide deposit formed in close geographical proximity to sulphide-sulphate-Au-Ag deposits and the two deposit types probably formed from the same hydrothermal system. Precipitation of Mn oxide took place at shallow burial depths and was promoted by the mixing of modified sea water (hydrothermal fluid) from which the sulphides precipitated at depth and sea water that penetrated along faults and fractures in the Cape Vani volcaniclastic and tuff deposits. The hydrothermal fluid was formed from predominantly sea water that was enriched in metals leached from the basement and overlying volcanogenic rocks. The hydrothermal fluids were driven by convection sustained by heat from cooling magma chambers. Barite was deposited throughout the time of Mn oxide mineralization, which occurred in at least two episodes. Manganese mineralization occurred by both focused and diffuse flow, the fluids mineralizing the beds of greatest porosity and filling dilatational fractures along with barite.

Milos Island↗