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At least 667 records · Page 37Linked to original sources

Influence of sediment chemistry and sediment toxicity on macroinvertebrate communities across 99 wadable streams of the Midwestern USA

Simultaneous assessment of sediment chemistry, sediment toxicity, and macroinvertebrate communities can provide multiple lines of evidence when investigating relations between sediment contaminants and ecological degradation. These three measures were evaluated at 99 wadable stream sites across 11 states in the Midwestern United States during the summer of 2013 to assess sediment pollution across a large agricultural landscape. This evaluation considers an extensive suite of sediment chemistry totaling 274 analytes (polycyclic aromatic hydrocarbons, organochlorine compounds, polychlorinated biphenyls, polybrominated diphenyl ethers, trace elements, and current-use pesticides) and a mixture assessment based on the ratios of detected compounds to available effects-based benchmarks. The sediments were tested for toxicity with the amphipod Hyalella azteca (28-d exposure), the midge Chironomus dilutus (10-d), and, at a few sites, with the freshwater mussel Lampsilis siliquoidea (28-d). Sediment concentrations, normalized to organic carbon content, infrequently exceeded benchmarks for aquatic health, which was generally consistent with low rates of observed toxicity. However, the benchmark-based mixture score and the pyrethroid insecticide bifenthrin were significantly related to observed sediment toxicity. The sediment mixture score and bifenthrin were also significant predictors of the upper limits of several univariate measures of the macroinvertebrate community (EPT percent, MMI (Macroinvertebrate Multimetric Index) Score, Ephemeroptera and Trichoptera richness) using quantile regression. Multivariate pattern matching (Mantel-like tests) of macroinvertebrate species per site to identified contaminant metrics and sediment toxicity also indicate that the sediment mixture score and bifenthrin have weak, albeit significant, influence on the observed invertebrate community composition. Together, these three lines of evidence (toxicity tests, univariate metrics, and multivariate community analysis) suggest that elevated contaminant concentrations in sediments, in particular bifenthrin, is limiting macroinvertebrate communities in several of these Midwest streams.

Science of the Total Environment↗

Sources and temporal dynamics of arsenic in a New Jersey watershed, USA

We examined potential sources and the temporal dynamics of arsenic (As) in the slightly alkaline waters of the Wallkill River, northwestern New Jersey, where violations of water-quality standards have occurred. The study design included synoptic sampling of stream water and bed sediments in tributaries and the mainstem, hyporheic-zone/ground water on the mainstem, and seasonal and diurnal sampling of water at selected mainstem sites. The river valley is bordered by gneiss and granite highlands and shale lowlands and underlain by glacial deposits over faulted dolomites and the Franklin Marble. Ore bodies in the Marble, which have been mined for rare Zn ore minerals, also contain As minerals. Tributaries, which drain predominantly forested and agricultural land, contributed relatively little As to the river. The highest concentrations of As (up to 34 μg/L) emanated from the outlet of man-made Lake Mohawk at the river's headwaters; these inputs varied substantially with season—high during warm months, low during cold months, apparently because of biological activity in the lake. Dissolved As concentrations were lower (3.3 μg/L) in river water than those in ground water discharging into the riverbed (22 μg/L) near the now-closed Franklin Mine. High total As concentrations (100–190 mg/kg) on the < 0.63 μm fraction of bed sediments near the mine apparently result from sorption of the As in the ground-water discharge as well as from the As minerals in the streambed. As concentrations in river water were diluted during high stream flow in fall, winter and spring, and concentrated during low flow in summer. In unfiltered samples from a wetlands site, diurnal cycles in trace-element concentrations occurred; As concentrations appeared to peak during late afternoon as pH increased, but Fe, Mn, and Zn concentrations peaked shortly after midnight. The temporal variability of As and its presence at elevated concentrations in ground water and sediments as well as streamwater demonstrate the importance of (1) sampling a variety of media and (2) determining the time scales of As variability to fully characterize its passage through a river system.

New Jersey↗

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in the composition of moving water and by the effects of particulate suspended material. Some constituents are unstable and require onsite determination or sample preservation. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, the most probable forms of elements and ions in solution, solubilitycontrols, expected concentration ranges, and other chemical factors. Mechanisms that control concentrations of elements commonly present in amounts less than a few tens of micrograms per liter cannot always be easily ascertained, but present information suggests that many are controlled by solubility of their hydroxides or carbonates or by sorption on solid particles. Many dissolved organic compounds can now be specifically determined. Chemical analyses may be grouped and statistically evaluated by means, medians, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among water, probable sources of solutes, areal water-quality regimen, temporal and spatial variation, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrogeologic characteristics, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 80 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also used in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Human activities may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of seawater in groundwater aquifers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural-water composition is required for rational management of water quality.

Water Supply Paper↗

Per- and polyfluoroalkyl substances (PFAS) in drinking water in Southeast Los Angeles: Industrial legacy and environmental justice

Per - and polyfluoroalkyl substances (PFAS) are persistent chemicals of increasing concern to human health. PFAS contamination in water systems has been linked to a variety of sources including hydrocarbon fire suppression activities, industrial and military land uses, agricultural applications of biosolids, and consumer products. To assess PFAS in California tap water, we collected 60 water samples from inside homes in four different geographic regions, both urban and rural. We selected mostly small water systems with known history of industrial chemical or pesticide contamination and that served socioeconomically disadvantaged communities. Thirty percent of the tap water samples (18) had a detection of at least one of the 32 targeted PFAS and most detections (89 %) occurred in heavily industrialized Southeast Los Angeles (SELA). The residents of SELA are predominately Latino and low-income. Concentrations of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) ranged from 6.8 to 13.6 ng/L and 9.4–17.8 ng/L, respectively in SELA and were higher than State (PFOA: 0.007 ng/L; PFOS: 1.0 ng/L) and national health-based goals (zero). To look for geographic patterns, we mapped potential sources of PFAS contamination, such as chrome plating facilities, airports, landfills, and refineries, located near the SELA water systems; consistent with the multiple potential sources in the area, no clear spatial associations were observed. The results indicate the importance of systematic testing of PFAS in tap water, continued development of PFAS regulatory standards and advisories for a greater number of compounds, improved drinking-water treatments to mitigate potential health threats to communities, especially in socioeconomically disadvantaged and industrialized areas.

California↗

Patterns and predictability in the intra-annual organic carbon variability across the boreal and hemiboreal landscape

Factors affecting total organic carbon (TOC) concentrations in 215 watercourses across Sweden were investigated using parameter parsimonious regression approaches to explain spatial and temporal variabilities of the TOC water quality responses. We systematically quantified the effects of discharge, seasonality, and long-term trend as factors controlling intra-annual (among year) and inter-annual (within year) variabilities of TOC by evaluating the spatial variability in model coefficients and catchment characteristics (e.g. land cover, retention time, soil type). Catchment area (0.18–47,000 km 2 ) and land cover types (forests, agriculture and alpine terrain) are typical for the boreal and hemiboreal zones across Fennoscandia. Watercourses had at least 6 years of monthly water quality observations between 1990 and 2010. Statistically significant models (p < 0.05) describing variation of TOC in streamflow were identified in 209 of 215 watercourses with a mean Nash-Sutcliffe efficiency index of 0.44. Increasing long-term trends were observed in 149 (70%) of the watercourses, and intra-annual variation in TOC far exceeded inter-annual variation. The average influences of the discharge and seasonality terms on intra-annual variations in daily TOC concentration were 1.4 and 1.3 mg l − 1 (13 and 12% of the mean annual TOC), respectively. The average increase in TOC was 0.17 mg l − 1 year − 1 (1.6% year − 1 ). Multivariate regression with over 90 different catchment characteristics explained 21% of the spatial variation in the linear trend coefficient, less than 20% of the variation in the discharge coefficient and 73% of the spatial variation in mean TOC. Specific discharge, water residence time, the variance of daily precipitation, and lake area, explained 45% of the spatial variation in the amplitude of the TOC seasonality. Because the main drivers of temporal variability in TOC are seasonality and discharge, first-order estimates of the influences of climatic variability and change on TOC concentration should be predictable if the studied catchments continue to respond similarly.

Science of the Total Environment↗

Organic matter integration, overprinting, and the relative fraction of optically active organic carbon in a human-impacted watershed

Rivers continually integrate terrestrial organic matter (OM) into their waters, in a process that transfers 1.9 Pg C yr –1 as the primary linkage between oceanic and terrestrial carbon cycles. Yet rivers are not simple, conservative OM integrators. Patchy local land uses (wetlands, bogs, agriculture) release OM that can disproportionately alter river biogeochemistry and overprint upstream carbon. These releases are quantifiable at the plot scale but remain unpredictable across river reaches and watersheds, critically inhibiting our ability to scale up terrestrial-aquatic linkages to regional/global carbon cycling models. We evaluated OM overprinting distance along a human-influenced watershed to quantify river integration of terrestrial OM and to bridge the quantification gap between habitats and waterway biogeochemistry. We investigated changes in dissolved organic carbon (DOC) concentration and dissolved organic matter (DOM) composition (lignin phenols, fluorescence excitation-emission spectra using parallel factor analysis [PARAFAC], and the relative fraction of optically active DOM [EEM DOC ]). DOC concentrations increased continually ( p < 0.001) downstream, from median 1.0 mg L –1 at 30 km (headwaters) to 3.3 mg L –1 at the river mouth. This rate of increase corresponded to a DOC overprinting distance—the longitudinal distance over which DOC concentrations double—of 13 km. Mainstem DOC overprinting distance ranged from 8 km (winter, rainy season) to 21 km (summer, dry season with irrigation), highlighting stronger overprinting during increased hydraulic connectivity. Stronger overprinting also correlated to higher EEM DOC ( p < 0.001). Overprinting distance effectively quantifies river integration of DOM along the terrestrial-aquatic interface, helping to refine bottom-up carbon cycle estimates, inform upscaling of site-specific fluxes, and to track land use and climate influence on river biogeochemistry.

California↗

Nitrate exposure from drinking water and dietary sources among Iowa farmers using private wells

Nitrate levels are increasing in water resources across the United States and nitrate ingestion from drinking water has been associated with adverse health risks in epidemiologic studies at levels below the maximum contaminant level (MCL). In contrast, dietary nitrate ingestion has generally been associated with beneficial health effects. Few studies have characterized the contribution of both drinking water and dietary sources to nitrate exposure. The Agricultural Health Study is a prospective cohort of farmers and their spouses in Iowa and North Carolina. In 2018–2019, we assessed nitrate exposure for 47 farmers who used private wells for their drinking water and lived in 8 eastern Iowa counties where groundwater is vulnerable to nitrate contamination. Drinking water and dietary intakes were estimated using the National Cancer Institute Automated Self-Administered 24-Hour Dietary Assessment tool. We measured nitrate in tap water and estimated dietary nitrate from a database of food concentrations. Urinary nitrate was measured in first morning void samples in 2018–19 and in archived samples from 2010 to 2017 (minimum time between samples: 2 years; median: 7 years). We used linear regression to evaluate urinary nitrate concentrations in relation to total nitrate, and drinking water and dietary intakes separately. Overall, dietary nitrate contributed the most to total intake (median: 97 %; interquartile range [IQR]: 57–99 %). Among 15 participants (32 %) whose drinking water nitrate concentrations were at/above the U.S. Environmental Protection Agency MCL (10 mg/L NO 3 -N), median intake from water was 44 % (IQR: 26–72 %). Total nitrate intake was the strongest predictor of urinary nitrate concentrations (R 2 = 0.53). Drinking water explained a similar proportion of the variation in nitrate excretion (R 2 = 0.52) as diet (R 2 = 0.47). Our findings demonstrate the importance of both dietary and drinking water intakes as determinants of nitrate excretion.

Iowa↗

Patterns of primary production and ecological drought in Yellowstone

Introduction: Photosynthesis converts sunlight into stored energy in millions of leaves, flowers and seeds that maintain the web of life in Yellowstone. This transformation of energy fixes carbon, supplies organic matter to soils, and can become fuel for wildfire. As the first link of the food chain, new plant biomass is called primary production and provides energy to consumers, including wildlife. While Yellowstone is a mountain environment with deep winter snowpack, the park can get very dry in some years as evidenced by massive wildfires in 1988 and 2016. Droughts like these not only contribute to fire potential, but they affect primary production, the food chain and likely will play an increasingly important role in transforming vegetation structure and composition in the future. Meteorological, agricultural, and hydrological drought have been assessed quantitatively for many years, but key indicators of drought in wildland ecosystems have not been formally defined until recently (Crausbay et al., 2017). One promising new method to do this is by measuring how vegetation responds to negative effects of drought, and positive effects of favorable conditions that offset negative effects of drought. The balance of drought stress and growth has important implications for future vegetation condition as the climate of Yellowstone changes. Monitoring primary production, and predicting future vegetation changes are needed to provide a comprehensive view of park health and anticipate future ecosystem changes (Crabtree et al. 2009, Nemani et al. 2009). Although an important indicator of ecosystem condition, primary production can be time and resource-intensive to monitor in wildland settings using traditional ground-based methods such as clipping and weighing. Fortunately, ground-based methods can be complemented and enhanced by monitoring primary production with satellite imagery. Measurements of solar radiation reflectance in visible and near infra-red wavelengths can indicate primary production at frequent weekly intervals from the Moderate Resolution Imaging Spectrometer (MODIS) on satellites operated by NASA. The Greater Yellowstone Inventory and Monitoring Network (GRYN) uses this information to track changes in primary production across Yellowstone over time. They link these measurements to vegetation types, soils, and climate to understand where and when changes in production have occurred and may occur in the future.

Yellowstone National Park↗

Could changes in the agricultural landscape of northeastern China have influenced the long-distance transmission of highly pathogenic avian influenza H5Nx viruses?

In the last few years, several reassortant subtypes of highly pathogenic avian influenza viruses (HPAI H5Nx) have emerged in East Asia. These new viruses, mostly of subtype H5N1, H5N2, H5N6, and H5N8 belonging to clade 2.3.4.4, have been found in several Asian countries and have caused outbreaks in poultry in China, South Korea, and Vietnam. HPAI H5Nx also have spread over considerable distances with the introduction of viruses belonging to the same 2.3.4.4 clade in the U.S. (2014–2015) and in Europe (2014–2015 and 2016–2017). In this paper, we examine the emergence and spread of these new viruses in Asia in relation to published datasets on HPAI H5Nx distribution, movement of migratory waterfowl, avian influenza risk models, and land-use change analyses. More specifically, we show that between 2000 and 2015, vast areas of northeast China have been newly planted with rice paddy fields (3.21 million ha in Heilongjiang, Jilin, and Liaoning) in areas connected to other parts of Asia through migratory pathways of wild waterfowl. We hypothesize that recent land use changes in northeast China have affected the spatial distribution of wild waterfowl, their stopover areas, and the wild-domestic interface, thereby altering transmission dynamics of avian influenza viruses across flyways. Detailed studies of the habitat use by wild migratory birds, of the extent of the wild–domestic interface, and of the circulation of avian influenza viruses in those new planted areas may help to shed more light on this hypothesis, and on the possible impact of those changes on the long-distance patterns of avian influenza transmission.

Frontiers in Veterinary Science↗

The life and scientific contributions of Lyman J. Briggs

Lyman J. Briggs (1874–1963), an early twentieth century physicist at the U.S. Department of Agriculture (USDA), made many significant contributions to our understanding of soil-water and plant-water interactions. He began his career at the Bureau of Soils (BOS) in 1896. At age 23, Briggs published (1897) a description of the roles of surface tension and gravity in determining the state of static soil moisture. Concepts he presented remain central to this subject more than 100 yr later. With J.W. McLane, Briggs developed the “moisture equivalent” concept (a precursor to the idea of field capacity) and a centrifuge apparatus for measuring it. Briggs left the BOS at the end of 1905, under pressure from Milton Whitney, and moved to the Bureau of Plant Industry. Briggs' multi-state experiments with H.L. Shantz on water-use efficiencies showed that in a climate like that of the Great Plains, plants use water more productively in the cooler north than in the warmer south. In 1920, he moved from the USDA to the National Bureau of Standards (NBS), rising to Director in 1933. Among his other contributions to the American scientific community was his leadership, beginning in 1939, of a top secret committee that evolved into the Manhattan Project to develop an atomic bomb during World War II. A life-long baseball fan, Briggs at age 84, studied the speed, spin, and deflection of the curve ball, aided by manager Cookie Lavagetto and the pitching staff of the Washington Senators; he published these findings in a paper in the American Journal of Physics in 1959.

Soil Science Society of America Journal↗

Using scenarios to evaluate vulnerability of grassland communities to climate change in the Southern Great Plains of the United States

Scenario planning is a useful tool for identifying key vulnerabilities of ecological systems to changing climates, informed by the potential outcomes for a set of divergent, plausible, and relevant climate scenarios. We evaluated potential vulnerabilities of grassland communities to changing climate in the Southern Great Plains (SGP) and the Landscape Conservation Design pilot area (LCD) for the U.S. Fish and Wildlife Service, Science Applications Program, Great Plains Landscape Conservation Cooperative. Four climate scenarios (warm-dry, warm-wet, hot-dry, and hot-wet) from atmospheric-ocean general circulation models were selected to represent a suite of plausible future climatic conditions. For each scenario, and for contemporary climatic conditions, we predicted the spatial patterns of relative productivity for indicator grass species using statistical models of relative above-ground net primary productivity (hereafter, productivity) based on temperature, precipitation, and soil texture (percent sand, silt, or clay). Two indicator grass species were selected to represent each of four focal grassland communities: semi-desert grasslands, shortgrass prairie, mixed-grass prairie, and tallgrass prairie. Changes in spatial patterning of bioclimatic conditions conducive for each indicator species as predicted for each climate scenario relative to current land use were used to evaluate potential vulnerability and conservation opportunities for grassland communities. Specifically, the following questions were addressed for each focal grassland community: (1) Where is the productivity of each species predicted to increase, decrease, or remain stable relative to estimated contemporary productivity for the SGP and LCD pilot area, (2) where is the productivity of the two indicator species for each community predicted to increase, decrease, or remain stable, (3) which grassland communities are most vulnerable to changes in composition and vertical structure, (4) how do current land-use patterns contribute to potential vulnerabilities of grassland communities for the climate scenarios evaluated, and (5) how can managers use the vulnerabilities identified to evaluate conservation opportunities in the SGP and LCD? Current land-use patterns, in combination with the potential effects of a changing climate, pose greater risks to mixed-grass and tallgrass prairies of the SGP compared to semi-desert grasslands and shortgrass prairie. For most climate scenarios evaluated, bioclimatic conditions conducive to the taller species were predicted to contract within some or all the current distribution of mixed-grass and tallgrass prairies within the SGP. An increase in precipitation, however, could potentially ameliorate the negative effects of increasing temperatures as evidenced by higher productivity for the hot-wet scenario compared to the other scenarios for the most vulnerable species. Compounding their greater vulnerability to increasing temperatures coupled with decreasing precipitation, the mixed-grass and tallgrass prairies have been greatly fragmented and converted, primarily by agriculture. In contrast, the climate scenarios evaluated are generally conducive to stable or increasing productivity of indicator species for semi-desert grasslands and shortgrass prairie. In addition, conversion and fragmentation of semi-desert grasslands and shortgrass prairie were relatively low. These results suggest that the synergistic effects of land use and changing climatic conditions could have the greatest effects on the composition and structure of mixed-grass and tallgrass prairies in the SGP. ScienceBase data release files that support this report are available at https://doi.org/10.5066/P9DGJHEP (Manier and others, 2019).

Colorado, Kansas, Nebraska, New Mexico, Oklahoma, ↗

Negative effects of excessive soil phosphorus on floristic quality in Ohio wetlands

Excessive soil nutrients, often from agricultural runoff, have been shown to negatively impact some aspects of wetland plant communities. We measured plant-available phosphorus (Mehlich-3: MeP) in soil samples, and assessed the vascular plant community and habitat degradation at 27 emergent and 13 forested wetlands in Ohio, USA. We tested two hypotheses: (1) that an index of vegetation biological integrity based on floristic quality was lower in wetlands with higher concentrations of MeP in the soil, and (2) that higher concentrations of MeP occurred in wetlands with more habitat degradation (i.e., lower quality), as estimated by a rapid assessment method. Hypothesis (1) was supported for emergent, but not for forested wetlands. Hypothesis (2) was marginally supported ( P = 0.09) for emergent, but not supported for forested wetlands. The results indicate that the effect of concentration of phosphorus in wetland soils and the quality of plant species assemblages in wetlands is more complex than shown in site-specific studies and may depend in part on degree of disturbance in the surrounding watershed and dominant wetland vegetation type. Woody plants in forested wetlands are typically longer lived than herbaceous species in the understory and emergent wetlands, and may persist despite high inputs of phosphorus. Further, the forested wetlands were typically surrounded by a wide band of forest vegetation, which may provide a barrier against sedimentation and the associated phosphorus inputs to the wetland interior. Our results indicate that inferences about soil nutrient conditions made from rapid assessment methods for assessing wetland habitat condition may not be reliable.

Ohio↗

What controls suspended-sediment concentration and export in flooded agricultural tracts in the Sacramento-San Joaquin Delta?

We investigated wind-wave and suspended-sediment dynamics in Little Holland Tract and Liberty Island, two subsided former agricultural tracts in the Cache Slough complex in the northern Sacramento-San Joaquin Delta which were restored to tidal shallows to improve habitat. Turbidity, and thus suspended-sediment concentration (SSC), is important to habitat quality because some species of native fishes, including the Delta Smelt, are found preferentially in more turbid waters. Data from October 2015 to August 2016 show that average SSC was greater within Little Holland Tract than in the primary breach that connects the basin to surrounding channels: approximately twice as great at a shallower station farther from the breach and 15% greater at a deeper station closer to the breach. Suspended-sediment concentration within Little Holland Tract was directly related to wave shear stress and inversely related to water depth, based on linear regression. We used measurements of suspended-sediment flux (SSF) through the largest levee breaches to assess whether the enhanced SSC within Little Holland Tract is exported to surrounding waters, thus potentially increasing turbidity over a wider region. Cumulatively, sediment is exported through the Little Holland Tract breaches in winter and imported in summer, consistent with regional patterns in sediment flux, indicating that wind-wave re-suspension within the basin does not control sediment flux from Little Holland Tract on seasonal time-scales. Some sediment was exported during wind-wave events, and results show that sediment export is greater when primary breaches are located downwind of the basin rather than upwind.

California↗

Improving spatio-temporal benefit transfers for pest control by generalist predators in cotton in the southwestern U.S.

Given rapid changes in agricultural practice, it is critical to understand how alterations in ecological, technological, and economic conditions over time and space impact ecosystem services in agroecosystems. Here, we present a benefit transfer approach to quantify cotton pest-control services provided by a generalist predator, the Mexican free-tailed bat ( Tadarida brasiliensis mexicana ), in the southwestern United States. We show that pest-control estimates derived using (1) a compound spatial – temporal model – which incorporates spatial and temporal variability in crop pest-control service values – are likely to exhibit less error than those derived using (2) a simple-spatial model (i.e., a model that extrapolates values derived for one area directly, without adjustment, to other areas) or (3) a simple-temporal model (i.e., a model that extrapolates data from a few points in time over longer time periods). Using our compound spatial–temporal approach, the annualized pest-control value was \$12.2 million, in contrast to an estimate of \$70.1 million (5.7 times greater), obtained from the simple-spatial approach. Using estimates from one year (simple-temporal approach) revealed large value differences (0.4 times smaller to 2 times greater). Finally, we present a detailed protocol for valuing pest-control services, which can be used to develop robust pest-control transfer functions for generalist predators in agroecosystems.

Arizona, California, Kansas, New Mexico, Oklahoma,↗

Chemical contaminants in water and sediment near fish nesting sites in the Potomac River basin: determining potential exposures to smallmouth bass (Micropterus dolomieu)

The Potomac River basin is an area where a high prevalence of abnormalities such as testicular oocytes (TO), skin lesions, and mortality has been observed in smallmouth bass (SMB, Micropterus dolomieu). Previous research documented a variety of chemicals in regional streams, implicating chemical exposure as one plausible explanation for these biological effects. Six stream sites in the Potomac basin (and one out-of-basin reference site) were sampled to provide an assessment of chemicals in these streams. Potential early life-stage exposure to chemicals detected was assessed by collecting samples in and around SMB nesting areas. Target chemicals included those known to be associated with important agricultural and municipal wastewater sources in the Potomac basin. The prevalence and severity of TO in SMB were also measured to determine potential relations between chemistry and biological effects. A total of 39 chemicals were detected at least once in the discrete-water samples, with atrazine, caffeine, deethylatrazine, simazine, and iso-chlorotetracycline being most frequently detected. Of the most frequently detected chemicals, only caffeine was detected in water from the reference site. No biogenic hormones/sterols were detected in the discrete-water samples. In contrast, 100 chemicals (including six biogenic hormones/sterols) were found in a least one passive-water sample, with 25 being detected at all such samples. In addition, 46 chemicals (including seven biogenic hormones/sterols) were found in the bed-sediment samples, with caffeine, cholesterol, indole, para-cresol, and sitosterol detected in all such samples. The number of herbicides detected in discrete-water samples per site had a significant positive relation to TO rank (a nonparametric indicator of TO), with significant positive relations between TO rank and atrazine concentrations in discrete-water samples and to total hormone/sterol concentration in bed-sediment samples. Such significant correlations do not necessarily imply causation, as these chemical compositions and concentrations likely do not adequately reflect total SMB exposure history, particularly during critical life stages.

Potomac River Basin↗

Distribution of selenium in soils of agricultural fields, western San Joaquin Valley, California

Soils from three agricultural fields in the Panoche Creek alluvial fan area in the western San Joaquin Valley, California, were analyzed for soluble, adsorbed, and total concentrations of selenium (Se) to assess the distribution and forms of Se in relation to the leaching of Se from soils. This assessment is needed to evaluate the importance of soil Se in affecting ground water concentrations. Soil samples were collected from three fields with drainage systems of different ages (6, 15, 1.5 yr) and different Se concentrations in drain water (58, 430, 3700 µg L −1 , respectively). Concentrations of soluble Se and salinity were highest in soils from the field drained for 1.5 yr and lowest in the field drained for 6 yr. Of the total concentration of soil Se from all three fields, the proportion of adsorbed and soluble Se ranged from 1 to 11% and <1 to 63%, respectively. Most of the soluble Se was present as selenate and most of the adsorbed Se was found to be selenite. Consistent with a model of evaporative concentration of Se and salinity in soils and shallow ground water in this area, most of the variance in soluble Se is explained by salinity (r 2 > 0.68) in saturation extracts of soils sampled from below the water table. In contrast, most soluble salts and Se apparently have been leached from the unsaturated soils in the fields drained for 6 and 15 yr. For the leached soils, dissolution and precipitation of evaporite minerals containing Se may no longer control concentrations of soluble Se.

California↗

A critical assessment of human-impact indices based on anthropogenic pollen indicators

Anthropogenic pollen indicators in pollen records are an established tool for reconstructing the history of human impacts on vegetation and landscapes. They are also used to disentangle the influence of human activities and climatic variability on ecosystems. The comprehensive anthropogenic pollen-indicator approach developed by Behre (1981) has been widely used, including beyond its original geographical scope of Central and Western Europe. Uncritical adoption of this approach for other areas is risky because adventives (plants introduced with agriculture) in Central Europe can be apophytes (native plants favoured by human disturbances) in other regions. This problem can be addressed by identifying region-specific, anthropogenic-indicator pollen types and/or developing region-specific, human-impact indices from pollen assemblages. However, understanding of regional variation in the timing and intensity of human impacts is limited by the lack of standardization, validation and intercomparison of such regional approaches. Here we review the most common European anthropogenic pollen-indicator approaches to assess their performance at six sites spanning a continental gradient over the boreal, temperate and Mediterranean biomes. Specifically, we evaluate the human-indicator approaches by using independent archaeological evidence and models. We present new insights into how these methodologies can assist in the interpretation of pollen records as well as into how a careful selection of pollen types and/or indices according to the specific geographical scope of each study is key to obtain meaningful reconstructions of anthropogenic activity through time. The evaluated approaches generally perform better in the regions for which they were developed. However, we find marked differences in their capacity to identify human impact, while some approaches do not perform well even in the regions for which they were developed, others might be used, with due caution, outside their original areas or biomes. We conclude that alongside the increasing wealth of pollen datasets a need to develop novel tools may assist numeric human impact reconstructions.

Quaternary Science Reviews↗

New-generation pesticides are prevalent in California's Central Coast streams

Pesticides are widely recognized as important biological stressors in streams, especially in heavily developed urban and agricultural areas like the Central California Coast region. We assessed occurrence and potential toxicity of pesticides in small streams in the region using two analytical methods: a broad-spectrum (223 compounds) method in use since 2012 and a newly developed method for 30 additional new-generation fungicides and insecticides. At least one pesticide compound was identified in 83 of the 85 streams sampled. About one-half (48%) of the 253 pesticides measured were detected at least once and 27 were detected in 10% or more of samples. Three of the top 4, and 6 of the top 10 most frequently detected compounds (chlorantraniliprole, dinotefuran, boscalid, thiamethoxam, clothianidin and the fluopicolide degradate 2,6-dichlorobenzamide) were analyzed by the new method. Pesticide mixtures were common, with two or more pesticide compounds detected in 81% of samples and 10 or more in 32% of samples. The pesticide count at a site was relatively consistent over the 6-week study. Four sites with mixed land-use in the lower basin (<5 km from the sampling site) tended to have the highest pesticide counts and the highest concentrations. Potential toxicity (assessed by comparison to benchmarks) to invertebrates was much more common than potential toxicity to fish or plants and was associated with a wide array of insecticides. The common occurrence of new-generation pesticides highlights the need to continuously update analytical methods to keep pace with changing pesticide use for a fuller assessment of pesticide occurrence and effects on the environment.

California↗