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Ground-water hydrology of the Punjab region of West Pakistan, with emphasis on problems caused by canal irrigation

Rising water tables and the salinization of land as the result of canal irrigation threaten the agricultural economy of the Punjab. Since 1954 the Water and Soils Investigation Division of the West Pakistan Water and Power Development Authority has inventoried the water and soils resources of the Punjab and investigated the relations between irrigation activities, the natural hydrologic factors, and the incidence of waterlogging and subsurface-drainage problems. This report summarizes the findings of the investigation, which was carried out under a cooperative agreement between the Government of Pakistan and the U.S. Agency for International Development, and its predecessor, the U.S. International Cooperation Administration. Leakage from the canal systems, some of which have been in operation for more than 100 years, is the principal cause of rising water levels and constitutes the major component of ground-water recharge in the Punjab. Geologic studies have shown that virtually the entire Punjab is underlain to depths of 1,000 feet or more by unconsolidated alluvium, which is saturated to within a few feet of land surface. The alluvium varies in texture from medium sand to silty clay, but sandy sediments predominate. Large capacity wells, yielding 4 cfs or more, can be developed almost everywhere. Ground water occurring within a depth of 500 feet below the surface averages less than 1,000 ppm of dissolved solids throughout approximately two-thirds of the Punjab. It is estimated that the volume of usable ground water in storage in this part of the alluvial aquifer is on the order of 2 billion acre-feet. In the other one-third of the Punjab, total dissolved solids range from 1,000 to about 20,000 ppm. In about one-half of this area (one-sixth of the area of the Punjab) some ground water can be utilized by diluting with surface water from canals. The ground-water reservoir underlying the Punjab is an unexploited resource of enormous economic value. It is recognized that the scientific management of this ground-water reservoir is the key to permanent irrigation agriculture in the Punjab. The West Pakistan Water .and Power Development Authority has prepared a long-range program for reclaiming the irrigated lands of the Punjab. The essential feature of this program is a proposed network of tubewells (drilled wells) located with an .average density of about one per square mile. Groundwater withdrawals will serve the dual purpose of helping to supply irrigation requirements and of providing subsurface drainage. Despite the feasibility and inherent advantages of tubewell reclamation methods, it is inevitable that just as the superposition of the canal system on the native environment caused undesirable side effects, large-scale ground-water withdrawals again will disturb the hydrologic regimen. The distribtution of withdrawals and maintenance of a favorable salt balance are two distinct, but related aspects of the ground-water budget that present potential hazards that must be considered in the design and management of the tubewell projects. The availability of ground water for irrigation diminishes from northeast to southwest, or downgradient along the doab (an area lying between two rivers) and is negligible in the centers of the lower parts of the doabs, where the ground water is too highly mineralized for use. Ground-water supplies must be developed in areas where they are available and it might become necessary, under a program of maximum exploitation of ground-water resources, to transfer supplies from outside sources to points of use in the lower parts of the doabs. Several factors inherent in the tubewell system will tend to depreciate the quality of ground water with time. Among these are the addition of salts leached from the soils, increased concentration of salts due .to repeated cycles of recirculation, and the possible lateral and upward encroachment of saline water in response to pumping. It is reasonably ce

Water Supply Paper↗

Are the Columbia River Basalts, Columbia Plateau, Idaho, Oregon, and Washington, USA, a viable geothermal target? A preliminary analysis

The successful development of a geothermal electric power generation facility relies on (1) the identification of sufficiently high temperatures at an economically viable depth and (2) the existence of or potential to create and maintain a permeable zone (permeability >10 -14 m 2 ) of sufficient size to allow efficient long-term extraction of heat from the reservoir host rock. If both occur at depth under the Columbia Plateau, development of geothermal resources there has the potential to expand both the magnitude and spatial extent of geothermal energy production. However, a number of scientific and technical issues must be resolved in order to evaluate the likelihood that the Columbia River Basalts, or deeper geologic units under the Columbia Plateau, are viable geothermal targets. Recent research has demonstrated that heat flow beneath the Columbia Plateau Regional Aquifer System may be higher than previously measured in relatively shallow (<600 m depth) wells, indicating that sufficient temperatures for electricity generation occur at depths 5 km. The remaining consideration is evaluating the likelihood that naturally high permeability exists, or that it is possible to replicate the high average permeability (approximately 10 -14 to 10 -12 m 2 ) characteristic of natural hydrothermal reservoirs. From a hydraulic perspective, Columbia River Basalts are typically divided into dense, impermeable flow interiors and interflow zones comprising the top of one flow, the bottom of the overlying flow, and any sedimentary interbed. Interflow zones are highly variable in texture but, at depths <600 m, some of them form highly permeable regional aquifers with connectivity over many tens of kilometers. Below depths of ~600 m, permeability reduction occurs in many interflow zones, caused by the formation of low-temperature hydrothermal alteration minerals (corresponding to temperatures above ~35 °C). However, some high permeability (>10-14 m 2 ) interflows are documented at depths up to ~1,400 m. If the elevated permeability in these zones persists to greater depths, they may provide natural permeability of sufficient magnitude to allow their exploitation as conventional geothermal reservoirs. Alternatively, if the permeability in these interflow zones is less than 10-14 m 2 at depth, it may be possible to use hydraulic and thermal stimulation to enhance the permeability of both the interflow zones and the natural jointing within the low-permeability interior portions of individual basalt flows in order to develop Enhanced/Engineered Geothermal System (EGS) reservoirs. The key challenge for an improved Columbia Plateau geothermal assessment is acquiring and interpreting comprehensive field data that can provide quantitative constraints on the recovery of heat from the Columbia River Basalts at depths greater than those currently tested by deep boreholes.

Idaho, Oregon, Washington↗

Effects of the earthquake of March 27, 1964, at Seward, Alaska

Seward, in south-central Alaska, was one of the towns most devastated by the Alaska earthquake of March 27, 1964. The greater part of Seward is built on an alluvial fan-delta near the head of Resurrection Bay on the southeast coast of the Kenai Peninsula. It is one of the few ports in south-central Alaska that is ice free all year, and the town’s economy is almost entirely dependent upon its port facilities. The Alaska earthquake of March 27, 1964, magnitude approximately 8.3–8.4, began at 6:36 p.m. Its epicenter was in the northern part of the Prince William Sound area; focal depth was 20–50 km. Strong ground motion at Seward lasted 3–4 minutes. During the shaking, a strip of land 50–400 feet wide along the Seward waterfront, together with docks and other harbor facilities, slid into Resurrection Bay as a result of large-scale submarine landsliding. Fractures ruptured the ground for'severa1 hundred feet back from the landslide scarps. Additional ground was fractured in the Forest Acres subdivision and on the alluvial floor of the Resurrection River valley; fountaining and sand boils accompanied the ground fracturing. Slide-generated wares, possibly seiche waves, and seismic sea waves crashed onto shore; ware runup was as much as 30 feet above mean lower low water and caused tremendous damage; fire from burning oil tanks added to the destruction. Damage from strong ground motion itself was comparatively minor. Tectonic subsidence of about 3.6 feet resulted in low areas being inundated at high tide. Thirteen people were killed and five were injured as a result of the earthquake. Eighty-six houses were totally destroyed and 260 were heavily damaged. The harbor facilities were almost completely destroyed, and the entire economic base of the town was wiped out. The total cost to replace the destroyed public and private facilities was estimated at $22 million. Seward lies on the axis of the Chugach Mountains geosyncline. The main structural trend in the mapped area, where the rocks consist almost entirely of graywacke and phyllite, is from near north to N. 20° E. Beds and cleavage of the rocks commonly dip 70° W. or NW. to near vertical. Locally, the rocks are complexly folded or contorted. So major faults were found in the mapped area, but small faults, shear zones, and joints are common. Surficial deposits of the area hare been divided for mapping into the following units: drift deposits, alluvial fan deposits, valley alluvium, intertidal deposits, landslide deposits, and artificial fill. Most of these units intergrade and were deposited more or less contemporaneously. The drift deposits consist chiefly of till that forms moraines along the lower flanks of the Resurrection River valley and up tributary valleys. The till is predominantly silt and sand and lesser amounts of clay-size particles, gravel, cobbles, and boulders. Glacial outwash and stratified ice-contact deposits constitute the remainder of the drift deposits. Fans and fan-deltas have been deposited at the valley mouths of tributary streams. Some, including the one upon which Seward built, project into Resurrection Bay, and deltaic-type deposits form their distal edges. The larger fans—composed chiefly of loosely compacted and poorly sorted silt, sand, and gravel—form broad aprons having low gradients. The fan deposits range in thickness from about 100 feet to possibly several hundred feet and, at least in some places, lie on a platform of compact drift. Smaller fans at the mouths of several canyons have steep gradients and considerable local relief. Valley alluvium, deposited chiefly by the Resurrection River, consists mostly of coarse sand and fine to medium gravel. In the axial part of the valley it is probably more than 100 feet thick. Near the head of Resurrection Bay, the alluvium is underlain by at least 75 feet of marine deltaic sediments, which are in turn underlain by 600 or more feet of drift in the deepest part of the bedrock valley. Beach, deltaic, and estuarine sediments, deposited on intertidal flats at the head of the bay and along far1 margins that extend into the bay, arc mapped as intertidal deposits. They consist mostly of silt, sand, and fine gravel, and lesser amounts of clay-size particles. The earthquake reactivated old slides and trigged new ones in the mountains. Rock and snow avalanches, debris flows, and creep of talus deposits characterized slide activity on the steeper slops. The Seward waterfront had been extended before the earthquake by adding artificial fill consisting of loose sand and gravel; part of the lagoon area had been filled with refuse. After the earth- quake, fill, consisting of silt and sand dredged from the head of the bay, was pumped onto part of the lagoon area and also on land at the northwest corner of the bay. Response to the disaster was immediate and decisive. City, State, and Federal agencies, as well as other organizations and individuals, gave unstintingly of their time and facilities. Within a few days, there was temporary restoration of water, sewerage, and electrical facilities. The U.S. Army Corps of Engineers was authorized to select sites and construct a new dock for the Alaska Railroad, a new small-boat basin, and related facilities. The firm of Shannon and Wilson, Inc., under contract to the Corps of Engineers, investigated subsurface soils extensively to determine the factors responsible for the sliding along the Seward waterfront and to assist in site selection for reconstruction of the destroyed harbor facilities. Borings also made along the Seward waterfront and at the head of the bay, and laboratory tests were conducted on pertinent samples. These studies were augmented by geophysical studies both on land and in the bay. In addition, the Corps of Engineers made shallow borings on the intertidal flats at the head of the bay and performed pile-driving and load tests. Borings also were drilled and test pits were dug in the subdivision of Forest Acres. Sliding along the Seward waterfront markedly deepened the water along the former shoreline. Post-earthquake slopes of the bay floor immediately offshore also are steeper in places than before the earthquake. The strong ground motion of the earthquake triggered the landsliding, but several factors may have contributed to the magnitude and characteristics of the slides. These factors are: (1) the long duration of strong ground motion, (2) the grain size and texture of the material involved in the sliding, (3) the probability that the finer grained materials liquefied and flowed seaward, and (4) the added load of manmade facilities built on the edge of the shore, Secondary effects of the slides themselves—sudden drawdown of water, followed by the weight of returning waves—also may have contributed to the destruction. Submarine sliding at the northwest corner of the bay occurred in fine-grained deltaic deposits whose frontal slopes probably were in metastable equilibrium under static conditions. Uplift pressures from aquifers under hydrostatic head, combined with the probable liquefaction characteristics of the sediments when vibrated by strong ground motion, probably caused the material to slide and flow seaward as a heavy slurry. Under static conditions, no major shoreline or submarine landsliding is expected in the Seward area; in the event of another severe earthquake, however, additional sliding is likely along the Seward waterfront and also in the deltaic deposits at the northwest corner of the bay. Fractured ground in back of the present shoreline along the Seward waterfront is an area of incipient landslides that would be unstable under strong shaking. For this reason the Scientific and Engineering Task Force placed the area in a high-risk classification and recommended no repair, rehabilitation, or new construction in this area involving use of Federal funds; it was further recommended that the area should be reserved for park or other uses that do not involve large congregations of people. The deltaic deposits at the head of the bay probably also would be susceptible to sliding during another large earthquake. This sliding would result in further landward retreat of the present shoreline toward the new railroad dock. Specifications for the new dock, whose seaward end is now approximately 1,100 feet from the back scarp of the subaqueous landslide, require design pro- visions to withstand seismic shock up to certain limits. Earthquake-induced fracturing of the ground in the subdivision of Forest Acres was confined to the lower part of a broad alluvial fan. There, sewer and water lines were ruptured and the foundations of some homes were heavily damaged. Landsliding, such as occurred along the shoreline of the bay, was not a contributing cause of the fracturing. Two hypotheses are offered to explain the fracturing: 1. Seismic energy was transformed into visible surface waves of such amplitude that the strength of surface layer was exceeded and rupturing occurred; tensional and compressional stresses alternately opened and closed the fractures and forced out water and mud. 2. Compaction by vibration of the fine-grained deposits of the fan caused ground settlement and fracturing; ground water under temporary hydrostatic head was forced to the surface as fountains and carried the finer material with it. Water waves that crashed onto shore, while shaking was still continuing, were generated chiefly by onshore and offshore landsliding. Waves that overran the shores about 25 minutes after shaking stopped and that continued to arrive for the next several hours are believed to be seismic sea waves (tsunamis) that originated in an uplifted area in the Gulf of Alaska. During the time of seismic sea-wave activity and perhaps preceding it, seiche wares also may have been generated within Resurrection Bay and complicated the wave effects along the shoreline.

Alaska↗

Lessons learned from wetlands research at the Cottonwood Lake Study Area, Stutsman County, North Dakota, 1967–2021

Depressional wetlands in the Prairie Pothole Region of North America have a long history of investigation owing to their importance in maintaining migratory-bird populations, especially waterfowl. One area of particularly intensive study is the Cottonwood Lake study area in Stutsman County, North Dakota. Studies at the Cottonwood Lake study area began in 1967 and continue through the present (2022). During this period of scientific discovery, meteorological conditions at the Cottonwood Lake study area varied greatly and included one of the most severe droughts of the 20th century and one of the wettest periods in the past 500 years. Persistent wet conditions that began in 1993 have contributed to state changes in many of the study area’s larger wetlands to lake-like conditions, whereas the smaller wetlands returned to seasonally ponded conditions during relatively dry years interspersed within the longer-term wet period. Additionally, some nonwetland areas of the study area developed wetland plant, hydrology, and soil characteristics during the 1993-to-present (2022) wet period. The persistently high stages of water in the larger wetlands since 1993 contributed to a buildup of dissolved solids and increases in salinity with time following an initial decrease in salinity caused by the dilution of dissolved solids within a larger volume of water. During 2021, drought conditions similar to the 1988 to 1992 period may develop if conditions persist. However, meteorological changes during the past 30 years have persisted long enough to be considered a change in climate conditions at the study area and, if such wet conditions continue, would represent a change from conditions that occurred in the past two millennia. During the period of study covered in this report (1967–2021), biotic communities responded in a variety of ways to subtle and marked changes in ponded-water depths, permanence, and salinity among the different wetland types in the study area. This report provides background information on the Cottonwood Lake study area and its context within the Prairie Pothole Region, documents techniques used to quantify environmental conditions and biotic communities, describes major trends that have been observed, presents significant findings as “lessons learned,” discusses recent modeling advances, and highlights key messages to managers. The Wetland Continuum concept was used as a framework to place research findings within an ecological context and to highlight the dynamic nature of prairie-pothole wetland ecosystems.

North Dakota↗

Tectonic setting and metallogenesis of volcanogenic massive sulfide deposits in the Bonnifield Mining District, Northern Alaska Range: Chapter B in Recent U.S. Geological Survey studies in the Tintina Gold Province, Alaska, United States, and Yukon, Canada--results of a 5-year project

This paper summarizes the results of field and laboratory investigations, including whole-rock geochemistry and radiogenic isotopes, of outcrop and drill core samples from volcanogenic massive sulfide (VMS) deposits and associated metaigneous rocks in the Wood River area of the Bonnifield mining district, northern Alaska Range (see fig. 1 of Editors’ Preface and Overview). U-Pb zircon igneous crystallization ages from felsic rocks indicate a prolonged period of Late Devonian to Early Mississippian (373&plusmn;3 to 357&plusmn;4 million years before present, or Ma) magmatism. This magmatism occurred in a basinal setting along the ancient Pacific margin of North America. The siliceous and carbonaceous compositions of metasedimentary rocks, Precambrian model ages based on U-Pb dating of zircon and neodymium ages, and for some units, radiogenic neodymium isotopic compositions and whole-rock trace-element ratios similar to those of continental crust are evidence for this setting. Red Mountain (also known as Dry Creek) and WTF, two of the largest VMS deposits, are hosted in peralkaline metarhyolite of the Mystic Creek Member of the Totatlanika Schist. The Mystic Creek Member is distinctive in having high concentrations of high-field-strength elements (HFSE) and rare-earth elements (REE), indicative of formation in a within-plate (extensional) setting. Mystic Creek metarhyolite is associated with alkalic, within-plate basalt of the Chute Creek Member; neodymium isotopic data indicate an enriched mantle component for both members of this bimodal (rhyolite-basalt) suite. Anderson Mountain, the other significant VMS deposit, is hosted by the Wood River assemblage. Metaigneous rocks in the Wood River assemblage span a wide compositional range, including andesitic rocks, which are characteristic of arc volcanism. Our data suggest that the Mystic Creek Member likely formed in an extensional, back-arc basin that was associated with an outboard continental-margin volcanic arc that included rocks of the Wood River assemblage. We suggest that elevated HFSE and REE trace-element contents of metavolcanic rocks, whose major-element composition may have been altered, are an important prospecting tool for rocks of VMS deposit potential in east-central Alaska.

Alaska;Yukon↗

The United Nations framework classification for fossil energy and mineral reserves and resources 2009

Effective resource management in a globalizing economy requires accurate assessments of fossil energy and minerals resources. The recoverable quantities must be described and categorized in a manner that is consistent with scientific and social/economic information describing the economy as well as with the information describing the projects to recover them. A number of different standards have evolved over time in response to various professional needs Under a mandate given by the United Nations Economic and Social Council, the United Nations Economic Commission for Europe (UNECE) has cooperated with Governments, regulatory agencies, industry, international organizations, and professional organizations (including Committee for Mineral Reserves International Reporting Standards (CRIRSCO), the Society of Petroleum Engineers (SPE), the American Association of Petroleum Geologists (AAPG), and the Society of Petroleum Evaluation Engineers (SPEE)), as well as with outstanding experts, to define a global classification for extractive activities (including oil, gas, heavy oil and bitumen extraction) that reflects the principal concerns of existing petroleum and mineral classifications. The United Nations Framework Classification for Fossil Energy and Mineral Reserves and Resources-2009 (UNFC-2009) aims to serve the following four principal needs: 1. The needs in international energy and mineral studies to formulate robust and long-sighted policies. 2. The needs of governments in managing their resources accordingly, allowing market prices to be transferred to the wellhead with as little loss as possible. 3. The industries' needs for information while deploying technology, management and finance to secure energy supplies and capture value efficiently within the established frameworks to serve its host countries, shareholders and stakeholders. 4. The financial community's need for information to allocate capital appropriately, providing reduced costs and improved long-sightedness through the application of lower risk-compensated discount factors. The projects are categorised with respect to economic and social viability, project feasibility and maturity and uncertainty with respect to the quantities addressed. The categorisation of projects rather than of accumulations provides coherence with other critical management information such as production, cash flows, value and demand for various input factors. This key aspect of UNFC-2009 reflects the critical relationship between the quantities that can be recovered economically and the recovery processes (projects) that must be implemented to achieve those recoveries. It facilitates the recognition of potential wastage of resources through flaring or inefficient recovery processes and therefore also the potential for improvement. Copyright 2011, Society of Petroleum Engineers.

Conference Paper↗

Economic geology of the Bingham mining district, Utah

The field work of which this report represents the final results was first undertaken in the summer of the year 1900. This district had long been selected by the writer as worthy of special economic investigation, as well on account of the importance of its products as because of its geological structure and the peculiar relations of its ore deposits. It was not, however, until the summer mentioned above that the means at the disposal of the Survey, both pecuniary and scientific, justified its undertaking. As originally planned, the areal or surface geology was to have been worked out by Mr. Keith, who had already spent many years in unraveling the complicated geological structure of the Appalachian province, while Mr. Boutwell, who had more recently become attached to the Survey, was to have charge of the underground geology, or a study of the ore deposits, under the immediate supervision of the writer. When the time came for actually taking the field, it was found that the pressure of other work would not permit Mr. Keith to carry out fully the part allotted to him, and in consequence a part of his field work has fallen to Mr. Boutwell. Field work was commenced by the writer and Mr. Boutwell early in July, 1900. Mr. Keith joined the party on August 10, but was obliged to leave for other duties early in September. Mr. Boutwell carried on his field work continuously from July until December, taking up underground work after the snowfall had rendered work on the surface geology impracticable. The geological structure had proved to be unexpectedly intricate and complicated, so that, on the opening of the field season of 1901, it was found necessary to make further study in the light of results already worked out, and Mr. Boutwell spent some weeks in the district in the early summer of 1901. His field work that year, partly in California and partly in Arizona, as assistant to Mr. Waldemar Lindgren, lasted through the summer and winter and well into the spring of 1902, so that but little time , was left before he was obliged to take the field again in his study of the Park City district of Utah. Mr. Keith had been too closely occupied with his Appalachian work to complete his part,' and thus the publication of this report has been unusually delayed. While the delay is a cause for regret, this regret is much tempered by the consideration that had the report been published earlier many facts brought to light during the vigorous development of the region in late years, which have an important bearing upon the structure and genesis of the ore deposits, could not have been used in its preparation.

Utah↗

Groundwater flow in the Brunswick/Glynn County area, Georgia, 2000-04

An existing regional steady-state model for coastal Georgia, and parts of South Carolina and Florida, was revised to evaluate the local effects of pumping on the migration of high chloride (saline) water in the Upper Floridan aquifer located in the Brunswick/Glynn County, Georgia (Ga.) area. Revisions were focused on enhancing the horizontal and vertical resolution of the regional model grid in the vicinity of saline water. Modifications to the regional model consisted of (1) limiting grid size to a maximum of 500 feet (ft) per side in the vicinity of chloride contamination; (2) representing the upper and lower Brunswick aquifers with distinct model layers; (3) similarly, representing upper and lower water-bearing zones of the Upper Floridan aquifer with distinct model layers in Glynn and Camden Counties, Ga.; and (4) establishing new hydraulic-property zones in the Upper Floridan aquifer. The revised model simulated steady-state conditions that were assumed to exist during 2000 and 2004. Calibration of the revised steady-state model using pumping rates from 2000 indicates a "good" match (&plusmn;10 ft) based on 181 observations, with median residuals (simulated minus observed water levels) in each of the active model layers ranging from -8.62 to 4.67 ft, and root mean square error (RMSE) ranging from 10.9 to 11.4 ft. In the Brunswick/Glynn County area, groundwater-level residuals in the upper water-bearing zone of the Upper Floridan aquifer (layer 7) indicate an "excellent" match (&plusmn;5 ft) based on 41 observations with a median residual of -0.35 ft and RMSE of 4.32 ft. Calibration of the revised steady-state model using 2004 pumping rates and adjusted specified-head input values in the Floridan aquifer system indicates a "good" match (-10 ft) based on 88 observations, with median residuals in each of the active model layers ranging from -6.31 to -2.05 ft, and RMSE ranging from -6.95 to 14.5 ft. In the Brunswick/Glynn County area, groundwater-level residuals in the upper water-bearing zone of the Upper Floridan aquifer (layer 7) indicate an "excellent" match (&plusmn;5 ft) based on 32 observations with a median residual of -1.50 ft and RMSE of 5.34 ft. Simulated potentiometric surfaces for 2000 and 2004 indicate coastward groundwater flow in the Upper and Lower Floridan aquifers influenced by pumping centers at Savannah, Jesup, and Brunswick, Ga., and indicate steep potentiometric gradients to the west and north of the Gulf Trough. In the Brunswick/Glynn County area, simulated industrial production wells located north of downtown Brunswick intercept local groundwater flow in the upper and lower water-bearing zones of the Upper Floridan aquifer and have created a cone of depression that locally alters the regional coastward flow direction. Maps of simulated water-level change during the 2000-04 period show differences in groundwater levels in the Upper Floridan aquifer that range from -2.5 ft to more than 5 ft in areas of coastal Georgia, and more than 20 ft near the Georgia-Florida State Line. Positive values indicate higher simulated water levels during 2004 than during 2000, which were caused by reduced pumping in the Upper Floridan aquifer prompted by the shutdown of a paper mill near the southern model boundary in 2002 and increased recharge following a prolonged drought during 1998-2002. Simulated potentiometric profiles for 2000 and 2004 were used to evaluate the potentiometric gradients in the upper water-bearing zone of the Upper Floridan aquifer (layer 7) near the chloride plume in the downtown Brunswick area. Four potentiometric profiles were constructed for 2000 to compare the simulated and observed water levels in 13 wells and were oriented outward from a primary well field. The simulated potentiometric gradients from the four profiles for 2000 ranged from 3.6 to 5.2 feet per mile (ft/mi) compared to observed values ranging from 4.1 to 5.6 ft/mi. The five potentiometric profiles constructed for 2004 allowed for a similar comparison using simulated and observed water levels in 18 wells. The simulated potentiometric gradients from the five profiles for 2000 ranged from 3.6 to 11.1 ft/mi compared to observed values ranging from 3.8 to 10.2 ft/mi. Simulated potentiometric gradients were higher for 2004 than for 2000 because of the inclusion of a well located within the cone of depression near downtown Brunswick. Composite-scaled sensitivities of the model parameters indicate the revised model is most sensitive to pumping rates, followed by the horizontal hydraulic conductivity in the Upper Floridan aquifer for zones along coastal Georgia. The revised model is least sensitive to the horizontal hydraulic conductivity of the confining units and vertical hydraulic conductivity of the aquifers. For parameters defined by hydraulic-property zones in the upper and lower water-bearing zones of the Upper Floridan aquifer, such as horizontal hydraulic conductivity, model sensitivity was not as great in the Brunswick/Glynn County area as other areas along coastal Georgia. The model exhibited more sensitivity to these parameters however, than to parameters representing the majority of zones defining the vertical hydraulic conductivity of the confining units, which originally were assumed to govern upward migration of chloride contamination into this aquifer. Analysis of simulated water-budget components for 2000 and 2004 indicate that specified-head boundaries in the Floridan aquifer system to the south and southwest of the regional model area control about 70 percent of inflows and nearly 50 percent of outflows to the model region. Other water-budget components indicate an 80-million-gallon-per-day decrease in pumping from the Floridan aquifer system during this period.

Georgia↗

Results from the Department of the Interior Strategic Sciences Group Technical Support for the 2018 Kīlauea Eruption

On May 3, 2018 Hawai'i’s Kīlauea volcano erupted, ultimately covering 35 square kilometers (13.5 square miles) of land in lava, destroying over 700 homes in multiple subdivisions, and displacing over 2500 residents in the Puna District on the southeast flank of the volcano. Simultaneously, Kīlauea’s summit experienced its largest collapse in 200 years, with a total of 500 meters (1,640 feet) subsidence and tens of earthquakes each day rattling surrounding communities. These simultaneous events impacted residential, agricultural, business, tourist, and scientific areas. Hawai'i Volcanoes National Park closed, slowing tourism and the local economy. The building housing the United States Geological Survey (USGS) Hawai'ian Volcano Observatory also closed, displacing scientists responsible for monitoring the erupting volcano. The eruption lasted 107 days, one of the longest eruptions in recent history in lower Puna. Throughout the eruption, uncertainty regarding the duration of the event, its extent, and total damage remained high. This uncertainty led to social tensions and fatigue across the affected community, responders, and local officials. At the direction of the USGS Director, serving as the Science Advisor to the Secretary of the of the Interior, the Department of the Interior (DOI, hereafter also referred to as “the Department”) Strategic Sciences Group (SSG) convened a multidisciplinary group of 13 experts in Hilo, Hawai'i, on July 17-19, 2018. The SSG was charged with considering the cascading short- and long-term social, economic, and environmental consequences of the 2018 Kīlauea eruption to DOI resources, employees, and facilities as well as to the surrounding communities. Established in 2012, the SSG is designed to complement ongoing response efforts by providing strategic science to identify potential social, environmental, and economic consequences and potential interventions during a crisis event affecting Departmental resources. This activation of the SSG was funded by the USGS. It was the first official activation of the SSG since it supported Hurricane Sandy recovery in 2013 and provided the unique opportunity to test new methods, including bolstering the social science expertise on the team and interacting directly with stakeholders before, during, and after deployment. The SSG Kīlauea Team developed three scenarios focused on 1) the impacts of continued seismicity and deformation at the summit; 2) vog (volcanic smog); and 3) the eruption in the lower East Rift Zone. Across all scenarios, areas of concern included human health (physical and mental); biosecurity (for example, protecting threatened and endangered species); infrastructure (impacts caused by seismic activity, vog, and lava); communications (internal and public-facing); long-term planning (related to tourism, access, housing); and ongoing needs for community engagement and empowerment. The SSG Kīlauea Team identified 59 potential actions for mitigation. Highlights of these actions were delivered to stakeholders during briefings in August and September 2018. Examples of potential actions included: ● Seize opportunities to develop new partnerships within and outside of DOI to address facilities issues caused by seismic damage and park closure. ● Educate community members and new workers to increase early detection of invasive species and establish new wash stations to address biosecurity threats to the park posed by more frequent commuting from new temporary Hilo locations. ● Create a "vog officer" position to ensure coordination and consistency in communication about vog hazards across federal, state, and county agencies. It is important to note that the potential actions are suggestions and are not intended to be prescriptive. The SSG uses “blue sky thinking” when developing these potential actions to encourage creative approaches to problem solving. In some cases, some of the suggested potential actions derived by the SSG are actions that were already underway, or already under consideration and helped to affirm 3 activities by different stakeholders. In other cases, the actions may be new ideas. Some were applicable to immediate response, while others are more relevant to long-term recovery. This report details the results from the July 2018 activation of the SSG. It includes background on Kīlauea and the 2018 eruption, an overview of SSG methodology, and a complete list of the potential actions to mitigate cascading consequences identified by the SSG. Importantly, Appendix 4 includes several rapidly assembled “issue papers” on a variety of topics for consideration for recovery and future preparedness and response activities. This report is designed to be used by both the Department and more broadly by partners, including the Federal Emergency Management Agency, Hawai'i County, Hawai'i Department of Health, and the Hawai'i Emergency Management Agency.

Hawaii↗

Effects of biodiversity on ecosystem functioning: a consensus of current knowledge

Humans are altering the composition of biological communities through a variety of activities that increase rates of species invasions and species extinctions, at all scales, from local to global. These changes in components of the Earth's biodiversity cause concern for ethical and aesthetic reasons, but they also have a strong potential to alter ecosystem properties and the goods and services they provide to humanity. Ecological experiments, observations, and theoretical developments show that ecosystem properties depend greatly on biodiversity in terms of the functional characteristics of organisms present in the ecosystem and the distribution and abundance of those organisms over space and time. Species effects act in concert with the effects of climate, resource availability, and disturbance regimes in influencing ecosystem properties. Human activities can modify all of the above factors; here we focus on modification of these biotic controls. The scientific community has come to a broad consensus on many aspects of the relationship between biodiversity and ecosystem functioning, including many points relevant to management of ecosystems. Further progress will require integration of knowledge about biotic and abiotic controls on ecosystem properties, how ecological communities are structured, and the forces driving species extinctions and invasions. To strengthen links to policy and management, we also need to integrate our ecological knowledge with understanding of the social and economic constraints of potential management practices. Understanding this complexity, while taking strong steps to minimize current losses of species, is necessary for responsible management of Earth's ecosystems and the diverse biota they contain. Based on our review of the scientific literature, we are certain of the following conclusions: 1) Species' functional characteristics strongly influence ecosystem properties. Functional characteristics operate in a variety of contexts, including effects of dominant species, keystone species, ecological engineers, and interactions among species (e.g., competition, facilitation, mutualism, disease, and predation). Relative abundance alone is not always a good predictor of the ecosystem-level importance of a species, as even relatively rare species (e.g., a keystone predator) can strongly influence pathways of energy and material flows. 2) Alteration of biota in ecosystems via species invasions and extinctions caused by human activities has altered ecosystem goods and services in many well-documented cases. Many of these changes are difficult, expensive, or impossible to reverse or fix with technological solutions. 3) The effects of species loss or changes in composition, and the mechanisms by which the effects manifest themselves, can differ among ecosystem properties, ecosystem types, and pathways of potential community change. 4) Some ecosystem properties are initially insensitive to species loss because (a) ecosystems may have multiple species that carry out similar functional roles, (b) some species may contribute relatively little to ecosystem properties, or (c) properties may be primarily controlled by abiotic environmental conditions. 5) More species are needed to insure a stable supply of ecosystem goods and services as spatial and temporal variability increases, which typically occurs as longer time periods and larger areas are considered. We have high confidence in the following conclusions: 1) Certain combinations of species are complementary in their patterns of resource use and can increase average rates of productivity and nutrient retention. At the same time, environmental conditions can influence the importance of complementarity in structuring communities. Identification of which and how many species act in a complementary way in complex communities is just beginning. 2) Susceptibility to invasion by exotic species is strongly influenced by species composition and, under similar environmental conditions, generally decreases with increasing species richness. However, several other factors, such as propagule pressure, disturbance regime, and resource availability also strongly influence invasion success and often override effects of species richness in comparisons across different sites or ecosystems. 3) Having a range of species that respond differently to different environmental perturbations can stabilize ecosystem process rates in response to disturbances and variation in abiotic conditions. Using practices that maintain a diversity of organisms of different functional effect and functional response types will help preserve a range of management options. Uncertainties remain and further research is necessary in the following areas: 1) Further resolution of the relationships among taxonomic diversity, functional diversity, and community structure is important for identifying mechanisms of biodiversity effects. 2) Multiple trophic levels are common to ecosystems but have been understudied in biodiversity/ecosystem functioning research. The response of ecosystem properties to varying composition and diversity of consumer organisms is much more complex than responses seen in experiments that vary only the diversity of primary producers. 3) Theoretical work on stability has outpaced experimental work, especially field research. We need long-term experiments to be able to assess temporal stability, as well as experimental perturbations to assess response to and recovery from a variety of disturbances. Design and analysis of such experiments must account for several factors that covary with species diversity. 4) Because biodiversity both responds to and influences ecosystem properties, understanding the feedbacks involved is necessary to integrate results from experimental communities with patterns seen at broader scales. Likely patterns of extinction and invasion need to be linked to different drivers of global change, the forces that structure communities, and controls on ecosystem properties for the development of effective management and conservation strategies. 5) This paper focuses primarily on terrestrial systems, with some coverage of freshwater systems, because that is where most empirical and theoretical study has focused. While the fundamental principles described here should apply to marine systems, further study of that realm is necessary. Despite some uncertainties about the mechanisms and circumstances under which diversity influences ecosystem properties, incorporating diversity effects into policy and management is essential, especially in making decisions involving large temporal and spatial scales. Sacrificing those aspects of ecosystems that are difficult or impossible to reconstruct, such as diversity, simply because we are not yet certain about the extent and mechanisms by which they affect ecosystem properties, will restrict future management options even further. It is incumbent upon ecologists to communicate this need, and the values that can derive from such a perspective, to those charged with economic and policy decision-making.

Ecological Monographs↗

Comparison of ASTER- and AVIRIS-derived mineral and vegetation maps of the White Horse replacement alunite deposit and surrounding area, Marysvale volcanic field, Utah

This report presents and compares mineral and vegetation maps of parts of the Marysvale volcanic field in west-central Utah that were published in a recent paper describing the White Horse replacement alunite deposit. Detailed, field-verified maps of the deposit were produced from Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data acquired from a low-altitude Twin Otter turboprop airborne platform. Reconnaissance-level maps of surrounding areas including the central and northern Tushar Mountains, Pahvant Range, and portions of the Sevier Plateau to the east were produced from visible, near-infrared, and shortwave-infrared data acquired by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor carried aboard the Terra satellite platform. These maps are also compared to a previously published mineral map of the same area generated from AVIRIS data acquired from the high-altitude NASA ER-2 jet platform. All of the maps were generated by similar analysis methods, enabling the direct comparison of the spatial scale and mineral composition of surface geologic features that can be identified using the three types of remote sensing data. The high spatial (2-17 meter) and spectral (224 bands) resolution AVIRIS data can be used to generate detailed mineral and vegetation maps suitable for geologic and geoenvironmental studies of individual deposits, mines, and smelters. The lower spatial (15-30 meter) and spectral (9 bands) resolution ASTER data are better suited to less detailed mineralogical studies of lithology and alteration across entire hydrothermal systems and mining districts, including regional mineral resource and geoenvironmental assessments. The results presented here demonstrate that minerals and mineral mixtures can be directly identified using AVIRIS and ASTER data to elucidate spatial patterns of mineralogic zonation; AVIRIS data can enable the generation of maps with significantly greater detail and accuracy. The vegetation mapping results suggest that ASTER data may provide an efficient alternative to spectroscopic data for studies of burn severity after wildland fires. A new, semiautomated methodology for the analysis of ASTER data is presented that is currently being applied to ASTER data coverage of large areas for regional assessments of mineral-resource potential and mineral-environmental effects. All maps are presented in a variety of digital formats, including jpeg, pdf, and ERDAS Imagine (.img). The Imagine format files are georeferenced and suitable for viewing with other geospatial data in Imagine, ArcGIS, and ENVI. The mineral and vegetation maps are attributed so that the material identified for a pixel can be determined easily in ArcMap by using the Identify tool and in Imagine by using the Inquire Cursor tool.

Utah↗

Long-term continuous acoustical suspended-sediment measurements in rivers - Theory, application, bias, and error

It is commonly recognized that suspended-sediment concentrations in rivers can change rapidly in time and independently of water discharge during important sediment‑transporting events (for example, during floods); thus, suspended-sediment measurements at closely spaced time intervals are necessary to characterize suspended‑sediment loads. Because the manual collection of sufficient numbers of suspended-sediment samples required to characterize this variability is often time and cost prohibitive, several “surrogate” techniques have been developed for in situ measurements of properties related to suspended-sediment characteristics (for example, turbidity, laser-diffraction, acoustics). Herein, we present a new physically based method for the simultaneous measurement of suspended-silt-and-clay concentration, suspended-sand concentration, and suspended‑sand median grain size in rivers, using multi‑frequency arrays of single-frequency side‑looking acoustic-Doppler profilers. The method is strongly grounded in the extensive scientific literature on the incoherent scattering of sound by random suspensions of small particles. In particular, the method takes advantage of theory that relates acoustic frequency, acoustic attenuation, acoustic backscatter, suspended-sediment concentration, and suspended-sediment grain-size distribution. We develop the theory and methods, and demonstrate the application of the method at six study sites on the Colorado River and Rio Grande, where large numbers of suspended-sediment samples have been collected concurrently with acoustic attenuation and backscatter measurements over many years. The method produces acoustical measurements of suspended-silt-and-clay and suspended-sand concentration (in units of mg/L), and acoustical measurements of suspended-sand median grain size (in units of mm) that are generally in good to excellent agreement with concurrent physical measurements of these quantities in the river cross sections at these sites. In addition, detailed, step-by-step procedures are presented for the general river application of the method. Quantification of errors in sediment-transport measurements made using this acoustical method is essential if the measurements are to be used effectively, for example, to evaluate uncertainty in long-term sediment loads and budgets. Several types of error analyses are presented to evaluate (1) the stability of acoustical calibrations over time, (2) the effect of neglecting backscatter from silt and clay, (3) the bias arising from changes in sand grain size, (4) the time-varying error in the method, and (5) the influence of nonrandom processes on error. Results indicate that (1) acoustical calibrations can be stable for long durations (multiple years), (2) neglecting backscatter from silt and clay can result in unacceptably high bias, (3) two frequencies are likely required to obtain sand-concentration measurements that are unbiased by changes in grain size, depending on site-specific conditions and acoustic frequency, (4) relative errors in silt-and-clay- and sand-concentration measurements decrease substantially as concentration increases, and (5) nonrandom errors may arise from slow changes in the spatial structure of suspended sediment that affect the relations between concentration in the acoustically ensonified part of the cross section and concentration in the entire river cross section. Taken together, the error analyses indicate that the two-frequency method produces unbiased measurements of suspended-silt-and-clay and sand concentration, with errors that are similar to, or larger than, those associated with conventional sampling methods.

Arizona, Texas↗

Major winter and nonwinter floods in selected basins in New York and Pennsylvania

The scientific design of flood-control works is based on an evaluation of the hydrologic factors basic to flood events, particularly how rainfall and snow runoff, soil conditions, and channel influences can combine to produce greater or lesser floods. For this purpose an analysis of the pertinent hydrologic data is needed. The methods of analysis adopted should conform as closely as possible to those already in use and must be adapted to the quality of the available information. Maximum floods in 8 basins in New York and Pennsylvania during the winter and nonwinter months were studied, a total of 21 floods. The most outstanding winter flood of record in the North Atlantic region was that of March 1936. Rainfall plus snow melt in the basins studied ranged between 3.04 and 6.87 inches, and associated volumes of direct runoff from 1.88 to 5.63 inches. Winter floods have a common characteristic in their relation to freezing temperature. The antecedent periods, representing a period of snow accumulation and frost penetration, are below freezing, and the flood itself is contemporaneous with a period of above-freezing temperatures, usually associated with rain, during which the previously accumulated snow is melted. A second common characteristic of major winter floods is their tendency to be associated with widespread causal meteorologic conditions. There was a more complete conversion of rainfall and snow melt into runoff during the winter storms studied than during the wettest nonwinter flood. Snow melt during winter floods ranged from 0.04 to 0.07 inch per degree-day above 32° F. The depth of mean areal rainfall produced by the nonwinter storms studied ranged from 3.05 to 4.96 inches. The maximum 24-hour quantity at single stations was 14 inches, which was measured during the storm of July 1935 in New York. The volume of direct runoff ranged between 1.39 and 3.41 inches. The portion of rainfall that was converted into runoff varied in accordance with the rate of antecedent base flow, expressed in second-feet per square mile, and emphasized the influence of antecedent conditions. The average volume of direct runoff during winter floods was 4.24 inches, and the average during nonwinter floods was 2.44 inches. The latter, however, were more concentrated as to time, tending to compensate for large volume of runoff in winter, so that the crest rates of direct runoff averaged 0.056 inches per hour during the winter and 0.051 inches during the nonwinter period.

New York, Pennsylvania↗

The Eocene-Oligocene sedimentary record in the Chesapeake Bay impact structure: Implications for climate and sea-level changes on the western Atlantic margin

A multidisciplinary investigation of the Eocene-Oligocene transition in the International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) Eyreville core from the Chesapeake Bay impact basin was conducted in order to document environmental changes and sequence stratigraphic setting. Planktonic foraminifera and calcareous nannofossil biostratigraphy indicate that the Eyreville core includes an expanded upper Eocene (Biozones E15 to E16 and NP19/20 to NP21, respectively) and a condensed Oligocene-Miocene (NP24-NN1) sedimentary sequence. The Eocene-Oligocene contact corresponds to a =3-Ma-long hiatus. Eocene- Oligocene sedimentation is dominated by great diversity and varying amounts of detrital and authigenic minerals. Four sedimentary intervals are identified by lithology and mineral content: (1) A 30-m-thick, smectite- and illite-rich interval directly overlies the Exmore Formation, suggesting long-term reworking of impact debris within the Chesapeake Bay impact structure. (2) Subsequently, an increase in kaolinite content suggests erosion from soils developed during late Eocene warm and humid climate in agreement with data derived from other Atlantic sites. However, the kaolinite increase may also be explained by change to a predominant sediment input from outside the Chesapeake Bay impact structure caused by progradation of more proximal facies belts during the highstand systems tract of the late Eocene sequence E10.Spectral analysis based on gamma-ray and magnetic susceptibility logs suggests infl uence of 1.2 Ma low-amplitude oscillation of the obliquity period during the late Eocene. (3) During the latest Eocene (Biozones NP21 and E16), several lithological contacts (clay to clayey silt) occur concomitant with a prominent change in the mineralogical composition with illite as a major component: This lithological change starts close to the Biozone NP19/20-NP21 boundary and may correspond to sequence boundary E10-E11 as observed in other northwest Atlantic margin sections. It could result from a shift to more distal depositional environments and condensed sedimentation during maximum fl ooding, rather than refl ecting a climatic change in the hinterland. The distinct 1% increase of the oxygen isotopes may correspond to the short-term latest Eocene "precursor isotope event." (4) The abrupt increase of sediment grainsize, carbonate content, and abundance of authigenic minerals (glauconite) across the major unconformity that separates Eocene from Oligocene sediments in the Eyreville core refl ects deposition in shallower settings associated with erosion, winnowing, and reworking. Sediments within the central crater were affected by the rapid eustatic sea-level changes associated with the greenhouse-icehouse transition, as well as by an abrupt major uplift event and possibly enhanced current activity on the northwestern Atlantic margin. ?? 2009 The Geological Society of America.

Chesapeake Bay↗

Methods for estimating magnitude and frequency of floods in Arizona, developed with unregulated and rural peak-flow data through water year 2010

Flooding is among the worst natural disasters responsible for loss of life and property in Arizona, underscoring the importance of accurate estimation of flood magnitude for proper structural design and floodplain mapping. Twenty-four years of additional peak-flow data have been recorded since the last comprehensive regional flood frequency analysis conducted in Arizona. Periodically, flood frequency estimates and regional regression equations must be revised to maintain the accurate estimation of flood frequency and magnitude. Annual peak-flow data collected through water year 2010 were compiled from 448 unregulated streamflow-gaging stations, hereafter referred to as streamgages, in Arizona having a minimum of 10 years of record. Flood frequency estimates were first computed with station (or at-site) skew using the Expected Moments Algorithm with a multiple Grubbs-Beck test to identify multiple potentially influential low flows to fit a Pearson Type III distribution. Next, a multiple step Bayesian least-squares-regression approach was used to determine a new statewide regional skew of &minus;0.09. No basin characteristics analyzed were statistically significant in explaining the variation in skew and as a result, the constant model was chosen as the best regional skew model for the Arizona study area. The mean square error used in Bulletin 17B (B17B) of the Interagency Advisory Committee on Water Data is used to describe the precision of the regional skew. The constant model had a mean square error equal to 0.08, which corresponds to an effective record length of 85 years. This is a marked improvement over a previous Arizona regional skew analysis, with a reported mean square error of 0.31, for a corresponding effective record length of around 17 years. Thus the new regional model had almost five times the information content (as measured by effective record length) of that calculated in USGS Water Supply Paper 2433, published in 1997, or the value of 0.302 reported in the B17B generalized skew map. The flood frequency estimates were recalculated using a weighted skew of the station and regional skew. Station flood frequency estimates for each streamgage are presented for the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities. Geographical information systems were used to compute basin characteristic information for each streamgage for the purpose of developing regional equations to estimate flood statistics at ungaged basins. Five hydrologic flood regions in Arizona were defined in a multivariate regionalization process based on mean basin elevation, mean annual precipitation, and soil permeability. A regional generalized least-squares-regression analysis was used to develop five sets of equations from 344 nonredundant streamgages, corresponding to five regions, for estimating the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities at ungaged basins in Arizona. The regression equations developed for these five regions were based on one or more of the statistically significant explanatory variables: drainage area, mean basin elevation, and mean annual precipitation. Average standard errors of prediction for the regression regions for the five regions ranged from 27 to 122 percent and the pseudo-coefficients of determination (pseudo-R 2 ), a measure of the proportion of peak-flow variation that is explained by the basin characteristics, ranged from 68 to 98 percent. Regression equations for Central Highlands (region 4) had the lowest model error and the greatest pseudo-R 2 metrics. The equations for Colorado Plateau (region 2) regression equations generally had greater model error and lower pseudo-R 2 metrics. The improvement of regional regression equation model error and pseudo-R 2 metrics was related to higher numbers of streamgages, longer period of record, and even spatial coverage within a region. The regional regression equations were integrated into the U.S. Geological Survey&rsquo;s StreamStats program. The StreamStats program is a national map-based web application that allows the public to easily access published flood frequency and basin characteristic statistics. The interactive web application allows a user to select a point within a watershed (gaged or ungaged) and retrieve flood-frequency estimates derived from the current regional regression equations and geographic information system data within the selected basin. StreamStats provides users with an efficient and accurate means for retrieving the most up to date flood frequency and basin characteristic data. StreamStats is intended to provide consistent statistics, minimize user error, and reduce the need for large datasets and costly geographic information system software.

Arizona↗

Petrographic observations on the Exmore breccia, ICDP-USGS drilling at Eyreville, Chesapeake Bay impact structure, USA

The International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) Eyreville A and B drill cores sampled crater fill in the region of the crater moat, ??9 km to the NE of the center of the Chesapeake Bay impact structure, Virginia, USA. They provide a 953 m section (444-1397 m depth) of sedimentary clast breccia and intercalated sedimentary and crystalline megablocks knownas Exmore beds, deposited on top of the impactite sequence between 1397 and 1551 m depth. We petrographically investigated the sandy-clayey groundmass-dominated breccia, which resembles a diamictite ("Exmore breccia"), and which, in its lower parts, carries sedimentary and crystalline blocks. The entire breccia interval is characterizedby the presence of glauconite and bioclastic carbonate, which distinguishes the Exmore breccia from other sandy facies above and below in the stratigraphy. The sediment-clast breccia exhibits strong heterogeneity from sample to sample with respect to groundmass nature, e.g., clay versus sand content, as well as clast content, in general, and shocked clast content, in particular. There is a consistently signifi cantly larger macroscopic sedimentary to crystalline clast content. On the microscopic scale, the intersample sediment to crystalline clast ratios are quite variable. A very small component of shocked material, in the form of shock-deformed quartz, and to an even lesser degree feldspar, and somewhat more abundant but still relatively scarce shardshaped,altered melt particles, is present throughout the section. However, between ??458 and 469 m, and between 514 and 527 m depths, the abundance of such melt particlesis notably enhanced. These sections are also chemically distinct and relatively more mafic than the other parts of the Exmore breccia. It appears that from the time of deposition of the 527 m material, calming of the ocean occurred over the crater area as a result of abatement of resurge activity, so that ejecta from the plume abovethe crater could accumulate within the crater area to a larger degree. Deposition ofejecta fallout from the collapsing ejecta plume was terminated by the time of deposition of the 458 m material. This raises questions about the positioning of the exact upper contact of Exmore breccia to post-Exmore sediment (Chickahominy Formation), which is currently placed at 444 m depth and which possibly should be revisedto 458 m depth. Based on a signifi cant record of granite-derived material with shocked minerals, the shocked debris component seems to be largely derived from crystalline target rocks. This provides further evidence that the basement-derived material of the basal section of the Eyreville drill cores, which is essentially unshocked, is likely of an allochthonous nature and that the drilling did not intersect the actual crater floor. 76??W. ?? 2009 Geological Society of America.

Special Paper of the Geological Society of America↗

The Effect of Selected Cleaning Techniques on Berkshire Lee Marble: A Scientific Study at Philadelphia City Hall

This report describes a scientific investigation of the effects of eight different cleaning techniques on the Berkshire Lee marble component of the facade of the East Center Pavilion at Philadelphia City Hall; the study was commissioned by the city of Philadelphia. The eight cleaning techniques evaluated in this study were power wash (proprietary gel detergent followed by water rinse under pressure), misting (treatment with potable, nebulized water for 24-36 hours), gommage (proprietary Thomann-Hanry low-pressure, air-driven, small-particle, dry abrasion), combination (gommage followed by misting), Armax (sodium bicarbonate delivered under pressure in a water wash), JOS (dolomite powder delivered in a low-pressure, rotary-vortex water wash), laser (thermal ablation), and dry ice (powdered-dry-ice abrasion delivered under pressure). In our study approximately 160 cores were removed from the building for laboratory analysis. We developed a computer program to analyze scanning-electron-micrograph images for the microscale surface roughness and other morphologic parameters of the stone surface, including the near-surface fracture density of the stone. An analysis of more than 1,100 samples cut from the cores provided a statistical basis for crafting the essential elements of a reduced-form, mixed-kinetics conceptual model that represents the deterioration of calcareous stone in terms of self-organized soiling and erosion patterns. This model, in turn, provided a basis for identifying the variables that are affected by the cleaning techniques and for evaluating the extent to which such variables influence the stability of the stone. The model recognizes three classes of variables that may influence the soiling load on the stone, including such exogenous environmental variables as airborne moisture, pollutant concentrations, and local aerodynamics, and such endogenous stone variables as surface chemistry and microstructure (fracturing, roughness, and so on). This study showed that morphologic variables on the mesoscale to macroscale are not generally affected by the choice of a cleaning technique. The long-term soiling pattern on the building is independent of the cleaning technique applied. This study also showed that soluble salts do not play a significant role in the deterioration of Berkshire Lee marble. Although salts were evident in cracks and fissures of the heavily soiled stone, such salts did not penetrate the surface to a depth of more than a few hundred micrometers. The criteria used to differentiate the cleaning techniques were ultimately based on the ability of each technique to remove soiling without altering the texture of the stone surface. This study identified both the gommage and JOS techniques as appropriate for cleaning ashlar surfaces and the combination technique as appropriate for cleaning highly carved surfaces at the entablatures, cornices, and column capitals.

Professional Paper↗

Irrigation-induced contamination of water, sediment, and biota in the western United States-synthesis of data from the National Irrigation Water Quality Program

In October 1985 the U.S. Department of the Interior (DOI), through the National Irrigation Water Quality Program (NIWQP), began a series of field investigations at 26 areas in the Western United States to determine whether irrigation drainage has had harmful effects on fish, wildlife, and humans or has reduced beneficial uses of water. In 1992 NIWQP initiated the Data Synthesis Project to evaluate data collected during the field investigations. Geologic, climatologic, and hydrologic data were evaluated and water, sediment, and biota from the 26 areas were analyzed to identify commonalities and dominant factors that result in irrigation-induced contamination of water and biota. Data collected for the 26 area investigations have been compiled and merged into a common data base. The structure of the data base is designed to enable assessment of relations between contaminant concentrations in water, sediment, and biota. The data base is available to the scientific community through the World Wide Web at URL http://www.usbr.gov/niwqp. Analysis of the data base for the Data Synthesis included use of summary statistics, factor analysis, and logistic regression. A Geographic Information System was used to store and analyze spatially oriented digital data such as land use, geology and evaporation rates. In the U.S. Department of the Interior (DOI) study areas, samples of water, bottom sediment, and biota were collected for trace-element and pesticide analysis. Contaminants most commonly associated with irrigation drainage were identified by comparing concentrations in water with established criteria. For surface water, the criteria used were typically chronic criteria for the protection of freshwater aquatic life. Because ground water can discharge to the surface where wildlife can be exposed to it, the criteria used for ground water were both the maximum contaminant levels (MCL's) for drinking water and the chronic criteria for the protection of freshwater aquatic life. Data collected by the NIWQP studies indicated that, in surface water, filtered and unfiltered samples had nearly the same concentrations of arsenic, boron, molybdenum, and selenium for concentrations greater than about 10 micrograms per liter. Therefore, in this concentration range, filtered concentrations can be directly compared to biological-effect levels developed for unfiltered samples. In the range of 1 to 10 micrograms per liter there may be a tendency for unfiltered arsenic concentrations to be greater than filtered concentrations. For selenium, however, the data suggest differences from equality in that range result from analytical imprecision and not a general tendency for unfiltered concentrations to be greater than filtered concentrations. This relation may not be true in lentic, nutrient-rich waters because in such settings algae can bioaccumulate large amounts of selenium and other trace elements. Selenium was the trace element in surface water that most commonly exceeded chronic criteria for the protection of freshwater aquatic life; more than 40 percent of the selenium concentrations in surface-water samples exceeded the U.S. Environmental Protection Agency (USEPA) aquatic-life chronic criterion (5 micrograms per liter). In 12 of the 26 areas at least 25 percent of the surface water-samples had selenium concentrations that either equaled or exceeded the chronic criterion (5 micrograms per liter). More than 28 percent of boron concentrations and almost 17 percent of the molybdenum concentrations exceeded the aquatic life criteria established by the State of California (550 and 19 micrograms per liter, respectively). In ground water, more than 22 percent of the arsenic concentrations and more than 35 percent of the selenium concentrations exceeded the MCL (10 and 50 micrograms per liter, respectively). Few samples of uranium in surface water exceeded a criterion for the protection of aquatic life (300 micrograms per liter), but 44 percent

Professional Paper↗