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At least 649 records · Page 36Linked to original sources

Soil microbial community composition is correlated to soil carbon processing along a boreal wetland formation gradient

Climate change is modifying global biogeochemical cycles. Microbial communities play an integral role in soil biogeochemical cycles; knowledge about microbial composition helps provide a mechanistic understanding of these ecosystem-level phenomena. Next generation sequencing approaches were used to investigate changes in microbial functional groups during ecosystem development, in response to climate change, in northern boreal wetlands. A gradient of wetlands that developed following permafrost degradation was used to characterize changes in the soil microbial communities that mediate C cycling: a bog representing an “undisturbed” system with intact permafrost, and a younger bog and an older bog that formed following the disturbance of permafrost thaw. Reference 16S rRNA databases and several diversity indices were used to assess structural differences among these communities, to assess relationships between soil microbial community composition and various environmental variables including redox potential and pH. Rates of potential CO2 and CH4 gas production were quantified to correlate sequence data with gas flux. The abundance of organic C degraders was highest in the youngest bog, suggesting higher rates of microbial processes, including potential CH4 production. In addition, alpha diversity was also highest in the youngest bog, which seemed to be related to a more neutral pH and a lower redox potential. These results could potentially be driven by increased niche differentiation in anaerobic soils. These results suggest that ecosystem structure, which was largely driven by changes in edaphic and plant community characteristics between the “undisturbed” permafrost bog and the two bogs formed following permafrost thaw, strongly influenced microbial function.

European Journal of Soil Biology↗

Detecting spatial patterns of rivermouth processes using a geostatistical framework for near-real-time analysis

This paper proposes a geospatial analysis framework and software to interpret water-quality sampling data from towed undulating vehicles in near-real time. The framework includes data quality assurance and quality control processes, automated kriging interpolation along undulating paths, and local hotspot and cluster analyses. These methods are implemented in an interactive Web application developed using the Shiny package in the R programming environment to support near-real time analysis along with 2- and 3-D visualizations. The approach is demonstrated using historical sampling data from an undulating vehicle deployed at three rivermouth sites in Lake Michigan during 2011. The normalized root-mean-square error (NRMSE) of the interpolation averages approximately 10% in 3-fold cross validation. The results show that the framework can be used to track river plume dynamics and provide insights on mixing, which could be related to wind and seiche events.

Lake Michigan↗

The importance of both geological and pedological processes in control of grain size and sedimentation rates in Peoria Loess

The loess-paleosol succession in the Peoria Loess in southern Illinois is characterized as alternating loess layers and weathering bands, known as paleosol A horizons. The fast loess accumulation during the late Wisconsin glaciation interacted with the incipient pedogenesis and caused unclear boundaries of loess-paleosol alternations in soil horizonation and mineralogy. Parameters of grain size distribution, sedimentation rate, matrix carbonate content and diffuse reflectance (i.e. soil colors and iron oxides) are used in this paper to discuss the geological and pedological influences for the Peoria Loess in Keller Farm section in southern Illinois. The multi-proxy analysis revealed that many paleosol A horizons, defined by the diffuse reflectance variability, contain finer-grained materials with a relatively higher sedimentation rate. It suggests that glaciofluvial sediments were available in the source areas for uploading eolian dust during the temporary ice sheet retreats. The denser vegetation and wetter surface soils on the loess deposit area could increase the dust trapping efficiency and caused a greater accumulation rate of loess deposits. The coarser-grained materials and slower sedimentation rate are often found in loess layers. It suggests that strong surface winds transported the coarser-grained materials from local dust sources and sparse vegetation and dry surface soils reduced the dust trapping efficiency during the ice sheet readvance. The strong interactions between the geological and pedological processes played an important role on the loess-paleosol alternations in southern Illinois during the late Wisconsin glaciation. ?? 2006 Elsevier B.V. All rights reserved.

Geoderma↗

Post-project geomorphic assessment of a large process-based river restoration project

This study describes channel changes following completion of the Provo River Restoration Project (PRRP), the largest stream restoration project in Utah and one of the largest projects in the United States in which a gravel-bed river was fully reconstructed. We summarize project objectives and the design process, and we analyze monitoring data collected during the first 7 years after project completion. Post-project channel adjustment during the study period included two phases: (i) an initial phase of rapid, but small-scale, adjustment during the first years after stream flow was introduced to the newly constructed channel and (ii) a subsequent period of more gradual topographic adjustment and channel migration. Analysis of aerial imagery and ground-survey data demonstrate that the channel has been more dynamic in the downstream 4 km where a local source contributes a significant annual supply of bed material. Here, the channel migrates and exhibits channel adjustments that are more consistent with project objectives. The upstream 12 km of the PRRP are sediment starved, the channel has been laterally stable, and this condition may not be consistent with large-scale project objectives.

Utah↗

Pb-Sr isotopic and geochemical constraints on sources and processes of lead contamination in well waters and soil from former fruit orchards, Pennsylvania, USA: A legacy of anthropogenic activities

Isotopic discrimination can be an effective tool in establishing a direct link between sources of Pb contamination and the presence of anomalously high concentrations of Pb in waters, soils, and organisms. Residential wells supplying water containing up to 1600 ppb Pb to houses built on the former Mohr orchards commercial site, near Allentown, PA, were evaluated to discern anthropogenic from geogenic sources. Pb (n = 144) and Sr (n = 40) isotopic data and REE (n = 29) data were determined for waters from residential wells, test wells (drilled for this study), and surface waters from pond and creeks. Local soils, sediments, bedrock, Zn-Pb mineralization and coal were also analyzed (n = 94), together with locally used Pb-As pesticide (n = 5). Waters from residential and test wells show overlapping values of 206 Pb/ 207 Pb, 208 Pb/ 207 Pb and 87 Sr/ 86 Sr. Larger negative Ce anomalies (Ce/Ce*) distinguish residential wells from test wells. Results show that residential and test well waters, sediments from residential water filters in water tanks, and surface waters display broad linear trends in Pb isotope plots. Pb isotope data for soils, bedrock, and pesticides have contrasting ranges and overlapping trends. Contributions of Pb from soils to residential well waters are limited and implicated primarily in wells having shallow water-bearing zones and carrying high sediment contents. Pb isotope data for residential wells, test wells, and surface waters show substantial overlap with Pb data reflecting anthropogenic actions (e.g., burning fossil fuels, industrial and urban processing activities). Limited contributions of Pb from bedrock, soils, and pesticides are evident. High Pb concentrations in the residential waters are likely related to sediment build up in residential water tanks. Redox reactions, triggered by influx of groundwater via wells into the residential water systems and leading to subtle changes in pH, are implicated in precipitation of Fe oxyhydroxides, oxidative scavenging of Ce(IV), and desorption and release of Pb into the residential water systems. The Pb isotope features in the residences and the region are best interpreted as reflecting a legacy of industrial Pb present in underlying aquifers that currently supply the drinking water wells.

Pennsylvania↗

Observations of the northern seasonal polar cap on Mars: I. Spring sublimation activity and processes

Spring sublimation of the seasonal CO 2 northern polar cap is a dynamic process in the current Mars climate. Phenomena include dark fans of dune material propelled out onto the seasonal ice layer, polygonal cracks in the seasonal ice, sand flow down slipfaces, and outbreaks of gas and sand around the dune margins. These phenomena are concentrated on the north polar erg that encircles the northern residual polar cap. The Mars Reconnaissance Orbiter has been in orbit for three Mars years, allowing us to observe three northern spring seasons. Activity is consistent with and well described by the Kieffer model of basal sublimation of the seasonal layer of ice applied originally in the southern hemisphere. Three typical weak spots have been identified on the dunes for escape of gas sublimed from the bottom of the seasonal ice layer: the crest of the dune, the interface of the dune with the interdune substrate, and through polygonal cracks in the ice. Pressurized gas flows through these vents and carries out material entrained from the dune. Furrows in the dunes channel gas to outbreak points and may be the northern equivalent of southern radially-organized channels (“araneiform” terrain), albeit not permanent. Properties of the seasonal CO 2 ice layer are derived from timing of seasonal events such as when final sublimation occurs. Modification of dune morphology shows that landscape evolution is occurring on Mars today, driven by seasonal activity associated with sublimation of the seasonal CO 2 polar cap.

Icarus↗

Numerical methods for improving sensitivity analysis and parameter estimation of virus transport simulated using sorptive-reactive processes

Using one- and two-dimensional homogeneous simulations, this paper addresses challenges associated with sensitivity analysis and parameter estimation for virus transport simulated using sorptive-reactive processes. Head, flow, and conservative- and virus-transport observations are considered. The paper examines the use of (1) observed-value weighting, (2) breakthrough-curve temporal moment observations, and (3) the significance of changes in the transport time-step size. The results suggest that (1) sensitivities using observed-value weighting are more susceptible to numerical solution variability, (2) temporal moments of the breakthrough curve are a more robust measure of sensitivity than individual conservative-transport observations, and (3) the transport-simulation time step size is more important than the inactivation rate in solution and about as important as at least two other parameters, reflecting the ease with which results can be influenced by numerical issues. The approach presented allows more accurate evaluation of the information provided by observations for estimation of parameters and generally improves the potential for reasonable parameter-estimation results. ?? 2004 Elsevier B.V. All rights reserved.

Journal of Contaminant Hydrology↗

Recharge processes drive sulfate reduction in an alluvial aquifer contaminated with landfill leachate

Natural attenuation of contaminants in groundwater depends on an adequate supply of electron acceptors to stimulate biodegradation. In an alluvial aquifer contaminated with leachate from an unlined municipal landfill, the mechanism of recharge infiltration was investigated as a source of electron acceptors. Water samples were collected monthly at closely spaced intervals in the top 2 m of the saturated zone from a leachate-contaminated well and an uncontaminated well, and analyzed for δ 18 O, δ 2 H, non-volatile dissolved organic carbon (NVDOC), SO 4 2− , NO 3 − and Cl − . Monthly recharge amounts were quantified using the offset of the δ 18 O or δ 2 H from the local meteoric water line as a parameter to distinguish water types, as evaporation and methanogenesis caused isotopic enrichment in waters from different sources. Presence of dissolved SO 4 2− in the top 1 to 2 m of the saturated zone was associated with recharge; SO 4 2− averaged 2.2 mM, with maximum concentrations of 15 mM. Nitrate was observed near the water table at the contaminated site at concentrations up to 4.6 mM. Temporal monitoring of δ 2 H and SO 4 2− showed that vertical transport of recharge carried SO 4 2− to depths up to 1.75 m below the water table, supplying an additional electron acceptor to the predominantly methanogenic leachate plume. Measurements of δ 34 S in SO 4 2− indicated both SO 4 2− reduction and sulfide oxidation were occurring in the aquifer. Depth-integrated net SO 4 2− reduction rates, calculated using the natural Cl − gradient as a conservative tracer, ranged from 7.5 × 10 − 3 to 0.61 mM·d − 1 (over various depth intervals from 0.45 to 1.75 m). Sulfate reduction occurred at both the contaminated and uncontaminated sites; however, median SO 4 2− reduction rates were higher at the contaminated site. Although estimated SO 4 2− reduction rates are relatively high, significant decreases in NVDOC were not observed at the contaminated site. Organic compounds more labile than the leachate NVDOC may be present in the root zone, and SO 4 2− reduction may be coupled to methane oxidation. The results show that sulfur (and possibly nitrogen) redox processes within the top 2 m of the aquifer are directly related to recharge timing and seasonal water level changes in the aquifer. The results suggest that SO 4 2− reduction associated with the infiltration of recharge may be a significant factor affecting natural attenuation of contaminants in alluvial aquifers.

Journal of Contaminant Hydrology↗

Modeling unsaturated zone flow and runoff processes by integrating MODFLOW-LGR and VSF, and creating the new CFL package

In this paper two modifications to the MODFLOW code are presented. One concerns an extension of Local Grid Refinement (LGR) to Variable Saturated Flow process (VSF) capability. This modification allows the user to solve the 3D Richards’ equation only in selected parts of the model domain. The second modification introduces a new package, named CFL (Cascading Flow), which improves the computation of overland flow when ground surface saturation is simulated using either VSF or the Unsaturated Zone Flow (UZF) package. The modeling concepts are presented and demonstrated. Programmer documentation is included in appendices.

Journal of Hydrology↗

Evaluation of soil zone processes and a novel radiocarbon correction approach for groundwater with mixed sources

Estimates of groundwater age based on 14C is often limited by the uncertainty in geochemical processes that alter the 14C concentration measured in water and the composition (δ13C and 14C) of carbon sources needed to appropriately parametrize 14C adjustment models. Estimated ages for samples that contain a mixture of young and old groundwater will be particularly sensitive to model parametrization as relatively small additions of modern 14C from recent recharge can mask the presence and amount of old groundwater. A novel multi-model approach based on inverse geochemical modeling and lumped parameter modeling of age tracers (3H, 3Hetrit, and SF6) was used to better constrain 14C dilution caused by dissolution of carbonates in the unsaturated zone or shallow parts of the Glacial aquifer, which extends over 2000 miles across the northern contiguous United States. Calibration of 14C inverse geochemical models to LPM computed 14C concentrations in modern water indicated that 14C of soil zone and shallow aquifer carbonates were not 14C-dead (0 pmC), as is typically assumed for 14C correction models. 14C of such carbonates was on average about 53 pmC (ranged 0-110 pmC, n = 72). This information was used to correct 14C concentrations for water recharged entirely before 1950 and water that is a mixture of pre- and post-1950 water. The multi-model approach developed here was compared to an analytical 14C-adjustment model (Revised Fontes and Garnier) that assumed solid carbonates were 14C-dead. 14C corrections using the analytical adjustment model tended to over-correct final 14C concentrations by 21 pmC and underestimates mean ages by 40% for groundwater mixtures. In fact, 14C corrections based on analytical model yielded negative ages (14C > 120 pmC) in nearly 36% of mixed samples. This work presents a new approach to constraining 14C corrections and age estimates of mixtures of young and old groundwater. The new method is applied to three well networks distributed across the spatially expansive Glacial aquifer.

Glacier aquifer system↗

A joint Gaussian process model of geochemistry, geophysics, and temperature for groundwater TDS in the San Ardo Oil Field, California, USA

Decline in availability of fresh groundwater has expanded interest in brackish groundwater resources; however, the distribution of brackish groundwater is poorly understood. Water resources in sedimentary basins across the United States often overlie oil and gas development. Mapping of groundwater total dissolved solids (TDS) using data from oil well geophysical logs has become an important technique for identifying fresh and brackish groundwater. Existing geophysical log analysis methods use porosity and temperature to relate formation resistivity to TDS. Typically, natural geothermal gradients are used to estimate temperature at the location of collected resistivity. However, in thermally enhanced oil fields, steam is injected into the subsurface to mobilize high viscosity oil, creating variable temperature distributions. Furthermore, TDS derived from resistivity also depends on the fractions of dominant ions. Typically, chloride and bicarbonate fractions must be determined. It is also necessary to model TDS across many geologic units with heterogenous porosity distributions. Collectively, each quantity used to estimate TDS (resistivity, porosity, temperature, bicarbonate fraction) varies in space and time, and available data points are rarely collocated. Here, we present a new method of mapping groundwater TDS that continuously models each quantity together with a joint Gaussian process. This method enables mapping fresh and brackish water with practically available data. We apply this method to the San Ardo Oil Field in Monterey County, California, where steam injection occurs. In some areas of the aquifer system overlying the oil zone, the temperature is ∼75 °C, roughly twice the natural background value. Groundwater TDS is typically <1,500 mg/L in the aquifer and increases with depth to ∼9,000 mg/L in the oil-producing zone. A low-permeability clay layer delineates the fresh and brackish water, likely by inhibiting surface recharge from penetrating the deeper zones, allowing higher-TDS connate water to remain in place. Weaker lateral TDS trends may be controlled by recharge patterns associated with the Salinas River. Our model reveals with high certainty that groundwater has freshened in one localized part of the oil-producing zone and suggests with less certainty that more widespread freshening has also occurred. The lowering of TDS was possibly from decades of low-TDS steam injection and the associated fluid production and disposal operations.

California↗

Constraints on magma processes, subsurface conditions, and total volatile flux at Bezymianny Volcano in 2007–2010 from direct and remote volcanic gas measurements

Direct and remote measurements of volcanic gas composition, SO 2 flux, and eruptive SO 2 mass from Bezymianny Volcano were acquired between July 2007 and July 2010. Chemical composition of fumarolic gases, plume SO 2 flux from ground and air-based ultraviolet remote sensing (FLYSPEC), and eruptive SO 2 mass from Ozone Monitoring Instrument (OMI) satellite observations were used along with eruption timing to elucidate magma processes and subsurface conditions, and to constrain total volatile flux. Bezymianny Volcano had five explosive magmatic eruptions between May 2007 and June 2010. The most complete volcanic gas datasets were acquired for the October 2007, December 2009, and May 2010 eruptions. Gas measurements collected prior to the October 2007 eruption have a relatively high ratio of H 2 O/CO 2 (81.2), a moderate ratio of CO 2 /S (5.47), and a low ratio of S/HCl (0.338), along with moderate SO 2 and CO 2 fluxes of 280 and 980 t/d, respectively, and high H 2 O and HCl fluxes of ~ 45,000 and ~ 440 t/d, respectively. These results suggest degassing of shallow magma (consistent with observations of lava extrusion) along with potential minor degassing of a deeper magma source. Gas measurements collected prior to the December 2009 eruption are characterized by relatively low H 2 O/CO 2 (4.13), moderate CO 2 /S (6.84), and high S/HCl (18.7) ratios, along with moderate SO 2 and CO 2 fluxes of ~ 220 and ~ 1000 t/d, respectively, and low H 2 O and HCl fluxes of ~ 1700 and ~ 7 t/d, respectively. These trends are consistent with degassing of a deeper magma source. Fumarole samples collected ~ 1.5 months following the May 2010 eruption are characterized by high H 2 O/CO 2 (63.0), low CO 2 /S (0.986), and moderate S/HCl (6.09) ratios. These data are consistent with degassing of a shallow, volatile-rich magma source, likely related to the May eruption. Passive and eruptive SO 2 measurements are used to calculate a total annual SO 2 mass of 109 kt emitted in 2007, with passive emissions comprising ~ 87–95% of the total. Total annual volatile masses for the study period are estimated to range from 1.1 × 10 6 to 18 × 10 6 t/year. Annual CO 2 masses are ~ 8 to 40 times larger than can be explained by degassing of dissolved CO 2 within eruptive magma, suggesting that the eruptive magma contained a significant quantity of exsolved volatiles sourced either from the eruptive melt or unerupted magma at depth. Variable total volatile fluxes ranging from ~ 3000 t/d in 2009 to ~ 49,000 t/d in 2007 are attributed to variations in the depth of gas exsolution and separation from the melt under open-system degassing conditions. We propose that exsolved volatiles are quickly transported to the surface from ascending magma via permeable flow through a bubble and/or fracture network within the conduit and thus retain their equilibrium composition at the time of segregation from melt. The composition of surface CO 2 and H 2 O emissions from 2007 to 2009 are compared with modeled exsolved fluid compositions for a magma body ascending from entrapment depths to estimate depth of fluid exsolution and separation from the melt. We find that at the time of sample collection magma had already begun ascent from the mid-crustal storage region and was located at maximum depths of ~ 3.7 km in August 2007, approximately 2 months prior to the next magmatic eruption, and ~ 4.6 km in July of 2009 approximately five months prior to the next magmatic eruption. These findings suggest that the exsolved gas composition at Bezymianny Volcano may be used to detect magma ascent prior to eruption.

Bezymianny Volcano↗

Dynamic deformation of Seguam Island, Alaska, 1992--2008, from multi-interferogram InSAR processing

We generated a time-series of ERS-1/2 and ENVISAT interferometric synthetic aperture radar (InSAR) images to study ground surface deformation at Seguam Island from 1992 to 2008. We used the small baseline subset (SBAS) technique to reduce artifacts associated with baseline uncertainties and atmospheric delay anomalies, and processed images from two adjacent tracks to validate our results. Seguam Island comprises the remnants of two late Quaternary calderas, one in the western caldera of the island and one in the eastern part of the island. The western caldera subsided at a constant rate of ~ 1.6 cm/yr throughout the study period, while the eastern caldera experienced alternating periods of subsidence and uplift: ~ 5 cm/year uplift during January 1993–October 1993 (stage 1), ~ 1.6 cm/year subsidence during October 1993–November 1998 (stage 2), ~ 2.0 cm/year uplift during November 1998–September 2000 (stage 3), ~ 1.4 cm/year subsidence during September 2000–November 2005 (stage 4), and ~ 0.8 cm/year uplift during November 2005– July 2007 (stage 5). Source modeling indicates a deflationary source less than 2 km below sea level (BSL) beneath the western caldera and two sources beneath the eastern caldera: an inflationary source 2.5–6.0 km BSL and a deflationary source less than 2 km BSL. We suggest that uplift of the eastern caldera is driven by episodic intrusions of basaltic magma into a poroelastic reservoir 2.5–6.0 km BSL beneath the caldera. Cooling and degassing of the reservoir between intrusions results in steady subsidence of the overlying surface. Although we found no evidence of magma intrusion beneath the western caldera during the study period, it is the site (Pyre Peak) of all historical eruptions on the island and therefore cooling and degassing of intrusions presumably contributes to subsidence there as well. Another likely subsidence mechanism in the western caldera is thermoelastic contraction of lava flows emplaced near Pyre Peak during several historical eruptions, most recently in 1977 and 1992–93.

Alaska↗

Using a process-based model of pre-eruptive seismic patterns to forecast evolving eruptive styles at Sinabung Volcano, Indonesia

Most volcanoes worldwide are not monitored in real-time; for those that are, patterns of pre-eruptive earthquakes coupled with conceptual models of magma ascent enable short-term forecasting of eruption onset. Basic event locations, characterization of background seismicity, and recognition of changes in earthquake types and energy release are most important to successful eruption forecasting. During renewed activity at Sinabung volcano, Indonesia, this approach was used by the Center for Volcanology and Geological Hazards Mitigation (CVGHM) and the USGS Volcano Disaster Assistance Program to forecast eruption onset, identify changes in eruptive styles and raise or lower alert levels and extend or contract evacuation zones. After > 400 years of quiescence, Sinabung began erupting in August 2010. The volcano was unmonitored at the onset of these eruptions, which were phreatic, but soon after a monitoring network was installed by CVGHM. Increasing swarms of high-frequency volcano tectonic (VT) earthquakes were used to forecast continuing phreatic eruptions. Volcanic activity decreased in mid-September 2010, while additional intrusions at depth (inferred from continued distal VT swarms) continued through September 2013, when explosive phreatic eruptions recurred. Explosive eruptions were forecast based on increases in real-time seismic amplitude measurement (RSAM) and VT seismicity. Seismicity changed markedly in late November and early December 2013 with the occurrence of deep earthquakes and an overall transition from low-frequency (LF) dominated and irregular (in time and magnitude) earthquakes to more regular LF and hybrid seismicity – a transition that accompanied the continued rise, eventual emergence and growth of a lava dome in the summit crater. This lava dome was first observed on 18 December. In late December 2013 to early January 2014, the eruptive style changed again as additional ascending magma deformed the summit and the dome grew beyond the capacity of the summit crater, resulting in the en masse collapse of the lava dome (2 Mm3) on 11 January and the largest pyroclastic flow to date. The collapse was forecast on the basis of a several order of magnitude increase in RSAM, continued strong distal VT seismicity, an increase in proximal seismicity, and large-scale observed deformation of the summit area. Similarly, a later collapse of a second summit lava dome on 1 February 2014 was forecast on the basis of increased distal seismicity. Here, we demonstrate how a process-based volcano seismicity model was used in combination with real-time data to forecast the time and magnitude of eruptions, as well as changes in eruption style.

Sinabung Volcano↗

Dating individual zones in phenocrysts from the 2016–2017 eruption of Bogoslof volcano provides constraints on timescales of magmatic processes

We investigate the rates of magmatic processes using clinopyroxene diffusion chronometry on volcanic products erupted in August 2017 at the end of the 9-month eruption of Bogoslof volcano. The eruptive products contain plagioclase, clinopyroxene, and amphibole, all of which exhibit sharp chemical boundaries and are occasionally observed in multi-phase crystal clots with shared zoning boundaries across different mineral phases. At the shared boundaries in crystal clots, clinopyroxene and plagioclase continued to grow but abruptly changed composition from Mg# 81.7 ± 5.8 to 72.9 ± 3.0 and An 82.5±1.4 to An 61.3±5.7 , respectively. Additionally, the sharp boundary marks where amphibole became unstable and began forming a reaction rim. Synthesizing these observations, we were able to determine that the shared boundaries formed as a result of rapid decompression during magma ascent, followed by storage in a shallow cryptodome, where magma accumulated prior to erupting. In order to determine the timescales of magma ascent and subsequent crystal residence times, we applied diffusion chronometry on zoned clinopyroxene phenocrysts using Mg# concentrations at 1056 °C determined from Fe Ti oxide pairs. Our diffusion modeling results show that diffusion began at the stepwise boundaries in clinopyroxenes no more than180 days before the final explosive event. These results were then used to calculate crystal growth rates for shared plagioclase and amphibole rims, as shared zones in crystal clots indicate that the boundaries in all three phases formed contemporaneously. We calculate growth rates of plagioclase crystals (1.7 ± 0.99 × 10 −6 um/s) and amphibole reaction rims (2.8 ± 0.47 × 10 −6 um/s). The calculated natural growth rate of plagioclase was then used to constrain additional magmatic timescales from growth rate chronometry, results of which support our diffusion timescales. Our results indicate that the distinct boundaries in all three mineral phases formed due to ascent-driven decompression followed by shallow emplacement of mafic magma that occurred continually throughout the course of the eruption. By subtracting diffusion timescales from the date that the samples were erupted, the oldest crystal boundaries correspond to March 2017, seemingly correlating with increases in both seismicity and SO 2 emissions. These observations may suggest that our petrochronometric results are supported by interdisciplinary observations.

Alaska↗

Understanding recurrent land use processes and long-term transitions in the dynamic south-central United States, c. 1800 to 2006

Forests have historically been under significant land use pressures that cause periods of degradation, clearance, and recovery. To understand these changes, studies are needed that place trends in a historical landscape context and also examine recent dynamics. Here, we use historical investigation (c. 1800) and an examination of land use and land cover change between 1973 and 2006 to establish a baseline trajectory of the forested system of the south-central United States (US) plains. The study culminates in a highly detailed accounting of the processes and causes of land change between 2001 and 2006. In the study region, the forest transitioned from early low-intensity use, to clearance for farming and timber, to widespread recovery from degradation beginning in the 1930s. By 1970, the region was transitioning from recovered woodlands to an intensive regime of recurrent timber harvest and replanting. The recurring cycle inherent in intensive silviculture has been the main cause of land change for the past several decades, accounting for more than 95% of the total extent of change between 2001 and 2006. The transition to forest recovery in the south-central US was an important historical occurrence. However, the dynamic post-transition landscape needs to be better understood.

Arkansas, Louisiana, Oklahoma, Texas↗

Understanding processes controlling sediment transports at the mouth of a highly energetic inlet system (San Francisco Bay, CA)

San Francisco Bay is one of the largest estuaries along the U.S. West Coast and is linked to the Pacific Ocean through the Golden Gate, a 100 m deep bedrock inlet. A coupled wave, flow and sediment transport model is used to quantify the sediment linkages between San Francisco Bay, the Golden Gate, and the adjacent open coast. Flow and sediment transport processes are investigated using an ensemble average of 24 climatologically derived wave cases and a 24.8 h representative tidal cycle. The model simulations show that within the inlet, flow and sediment transport is tidally dominated and driven by asymmetry of the ebb and flood tides. Peak ebb velocities exceed the peak flood velocities in the narrow Golden Gate channel as a result of flow convergence and acceleration. Persistent flow and sediment gyres at the headland tips are formed that limit sediment transfer from the ebb-tidal delta to the inlet and into the bay. The residual transport pattern in the inlet is dominated by a lateral segregation with a large ebb-dominant sediment transport (and flow) prevailing along the deeper north side of the Golden Gate channel, and smaller flood dominant transports along the shallow southern margin. The seaward edge of the ebb-tidal delta largely corresponds to the seaward extent of strong tidal flows. On the ebb-tidal delta, both waves and tidal forcing govern flow and sediment transport. Wave focusing by the ebb-tidal delta leads to strong patterns of sediment convergence and divergence along the adjacent Ocean Beach.

California↗

Geomorphic process fingerprints in submarine canyons

Submarine canyons are common features of continental margins worldwide. They are conduits that funnel vast quantities of sediment from the continents to the deep sea. Though it is known that submarine canyons form primarily from erosion induced by submarine sediment flows, we currently lack quantitative, empirically based expressions that describe the morphology of submarine canyon networks. Multibeam bathymetry data along the entire passive US Atlantic margin (USAM) and along the active central California margin near Monterey Bay provide an opportunity to examine the fine-scale morphology of 171 slope-sourced canyons. Log–log regression analyses of canyon thalweg gradient (S) versus up-canyon catchment area (A) are used to examine linkages between morphological domains and the generation and evolution of submarine sediment flows. For example, canyon reaches of the upper continental slope are characterized by steep, linear and/or convex longitudinal profiles, whereas reaches farther down canyon have distinctly concave longitudinal profiles. The transition between these geomorphic domains is inferred to represent the downslope transformation of debris flows into erosive, canyon-flushing turbidity flows. Over geologic timescales this process appears to leave behind a predictable geomorphic fingerprint that is dependent on the catchment area of the canyon head. Catchment area, in turn, may be a proxy for the volume of sediment released during geomorphically significant failures along the upper continental slope. Focused studies of slope-sourced submarine canyons may provide new insights into the relationships between fine-scale canyon morphology and down-canyon changes in sediment flow dynamics.

Marine Geology↗